Chapters authored
Chitosan-Based Sustainable Textile Technology: Process, Mechanism, Innovation, and Safety By Jagadish Roy, Fabien Salaün, Stéphane Giraud, Ada Ferri and
Jinping Guan
This chapter reviews relevant findings regarding the activities and contributions of chitosan in different textile processing following the varieties of process, mechanism, and applications. Chitosan is a better candidate in both aspects of biodegradability and efficiency instead of synthetic polymers. The technical and scientific discussions behind the role of chitosan in all the processes and treatments have been explored in the chapter. Over the last few years, enormous efforts and challenges are being practiced in research and industry to design and development of eco-friendly and sustainable technologies. Therefore, the chapter emphasizes on chitosan-based formulations of fibers, fabrics, coatings, and functional textiles.
Part of the book: Biological Activities and Application of Marine Polysaccharides
Solubility of Chitin: Solvents, Solution Behaviors and Their Related Mechanisms By Jagadish C. Roy, Fabien Salaün, Stéphane Giraud, Ada Ferri
Chitin is a natural polysaccharides having a unique molecular arrangement of 2-(acetylamino)-2-deoxy-d-glucose, it possesses multifunctional properties and is suitable for various applications mainly in pharmaceutical, biomedical food, textiles and packaging fields. Therefore, being considered as a superior material for a sustainable future of industrial development, chitin perfectly meets up the demands with diversified functionalities in applications, excellent biocompatibility and biodegradability. Non-toxicity to human and environment (air, water and soil) is a great opportunity for this revolutionary, innovative and sustainable material. Moreover, antibacterial potency and low immunogenicity of chitin have broadened the aspects of research and development on structure-function relationship toward biological tissues and activities. Despite abundance, low cost and availability, many experimental data from potential studies, reproducibility problems of chitin solubility measurement still limit the development of products and access to the market in large volume. Batch-to-batch variability, non-precise characterization and randomly distributed acetyl groups of chitin structure eventually results in a bad reproducibility of chitin solubility. Therefore, the chapter aims to organize the information of chitin structure at molecular level and correlate solubility with chitin structure. Moreover, the dissolution mechanism and solution behaviors in different solvents will be discussed in this chapter.
Part of the book: Solubility of Polysaccharides
An Overview on the Use of Lignin and Its Derivatives in Fire Retardant Polymer Systems By Neeraj Mandlekar, Aurélie Cayla, François Rault, Stéphane Giraud,
Fabine Salaün, Giulio Malucelli and Jin-Ping Guan
Lignin is a highly abundant bio-polymeric material that constitutes cellulose one of major component in cell wall of woody plants. Alternatively, large quantity of lignin is yearly available from numerous pulping and paper industries; this is the key point that justifies its large use for industrial applications. Lignin could be one of the most essential and sustainable bio-resources as raw material for the development of environmentally friendly polymer composite. Owing to its huge chemical structure, lignin can provide additional functionality such as filler, reinforcing agent, compatibilizer, stabilizer, etc. In this study, the fire retardant functionality of lignin has been employed in polymeric materials. Due to high charring capability, lignin is effectively used as carbon source in combination with other flame retardants for designing the intumescent system for polymeric materials. Further in this, several articles related to lignin-based intumescent are reviewed and interesting work formulation as well as meaningful results achieved in the flame retardancy are discussed. More attention is given to the studies concerning the use of current intumescent systems for textile applications by means of coating on fabric/nonwoven and melt blending in bulk polymers.
Part of the book: Lignin
Sol-Gel Microencapsulation Based on Pickering Emulsion By Fabien Salaün, Chloé Butstraen and Eric Devaux
Microencapsulation has been proved to be an efficient technic to entrap and protect active substance in variety fields of application. This process implies two consecutive stages, that is, the emulsion stage, which can be described as a limiting step since it determines the diameter and size distribution of the microcapsules and need to remain stable long enough to allow the membrane to form in the second one. Pickering emulsions are used to improve the stability of the emulsions and to limit the exudation of the active ingredient during membrane formation. The first part of this chapter deals with the description of the Pickering emulsion stabilized with solid particles. The second part focuses on the use of this kind of emulsion in a microencapsulation process, and the last part concerns a study of the influence of the nanosilica particles on microparticle formation obtained from a sol-gel process.
Part of the book: Science and Technology Behind Nanoemulsions
Phase Change Materials for Textile Application By Fabien Salaün
The objective of this chapter is to determine which of the existing PCM families are more suitable for textile thermoregulation while proposing new solutions. Indeed, many of these materials are either limited by their overall enthalpy of phase change or by their thermal window. Thus, it focuses on the study of binary mixing allowing the widening of the temperature range of the phase change and the consolidation of the enthalpy balance by adding chemical species. PCM was microencapsulated to be applied onto textile substrate, before studying the thermal properties.
Part of the book: Textile Industry and Environment
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