Quan Shi

By Zhi Cheng Tan, Quan Shi, Xue Chuan Lv and Bei Ping Liu

In this chapter, the following three rare-earth complexes with amino acids, Eu(Glu)(Im)5(ClO4)3⋅3HClO4⋅6H2O, Nd(Gly)2Cl3⋅3H2O, and La(Glu)(Im)6(ClO4)3⋅4HClO4⋅4H2O, are synthesized and characterized by element analysis, infrared (IR) spectrum, and x-ray diffraction (XRD) analysis. The thermodynamic property studies on these complexes are performed. For the first one, Eu(Glu)(Im)5(ClO4)3⋅3HClO4⋅6H2O, the low temperature heat capacity, phase transition, and thermodynamic functions are determined by adiabatic calorimetry. For the second one, Nd(Gly)2Cl3⋅3H2O, the molar dissolution enthalpy and standard molar enthalpy of formation are determined by isoperibol solution reaction calorimetry. For the third one, La(Glu)(Im)6(ClO4)3⋅4HClO4⋅4H2O, the microcalorimetry is used to investigate the interaction between the complex and the Escherichia coli DH5α to elucidate the biological effects of the complex.

Part of the book: Rare Earth Element

By Zhi Cheng Tan, Quan Shi and Xin Liu

In this chapter, a high-precision fully automated adiabatic calorimeter for heat capacity measurement of condensed materials in the temperature range from 80 to 400 K was described in detail. By using this calorimeter the heat capacity and thermodynamic properties of two kinds of function materials, ionic liquid and nanomaterials, were investigated. The heat capacities of IL [EMIM][TCB] were measured over the temperature range from 78 to 370 K by the high-precision-automated adiabatic calorimeter. Five kinds of nanostructured oxide materials, Al2O3, SiO2, TiO2, ZnO2, ZrO2, and two kinds of nanocrystalline metals: nickel and copper were investigated from heat capacity measurements. It is found that heat capacity enhancement in nanostructured materials is influenced by many factors, such as density, thermal expansion, sample purity, surface absorption, size effect, and so on.

Part of the book: Calorimetry

By Zhicheng Tan, Quan Shi and Xin Liu

In this chapter, four natural polyhydroxy alcohols (polyols), including xylitol, sorbitol, adonitol, and erythritol were selected as the subject of study on phase change materials for thermal energy storage application. The thermodynamic study on these polyols was performed by adiabatic calorimetry (AC), differential scanning calorimetry (DSC), and thermogravimetric analysis (TG). The heat capacities of these polyols were measured in the temperature range from 80 to 400 K by a fully automated high-precision adiabatic calorimeter. The experimental heat capacities of these polyols were fitted to the polynomial equations of heat capacities as a function of temperatures. The thermodynamic property data, such as temperatures, enthalpies, and entropies of the phase transitions, were obtained based on the experimental heat capacities in the phase transition temperature range. According to the thermodynamic relation equations, the standard thermodynamic functions of these polyols, relative to the standard reference temperature 298.15 K, [HT–H298.15] and [ST–S298.15], were calculated with the interval of 5 K. The thermal stability and heat storage capacity of the polyols were also investigated by thermal analysis.

Part of the book: Phase Change Materials and Their Applications