In this chapter, we aim to present an overview of the polymer dielectrics in organic field‐effect transistors and their applications. In the first section, we give a short introduction of polymer dielectrics in organic field‐effect transistors. We illustrate multilayer, hybrid, and cross‐linked polymer dielectrics adopted in organic field‐effect transistors. Then we introduce the available biomaterials engaged as polymer dielectrics in organic field‐effect transistors. We mainly focus on the utilization of silk fibroin, DNA, and DNA base pair dielectrics. We end the chapter by presenting the applications of polymer dielectrics. We elaborate that the polymer dielectrics can function as the electrode buffer layer, as well as the organic field‐effect transistor‐based gas sensor, inverter, and memory.
Part of the book: Polymer Dielectrics