\\n\\n
IntechOpen Book Series will also publish a program of research-driven Thematic Edited Volumes that focus on specific areas and allow for a more in-depth overview of a particular subject.
\\n\\nIntechOpen Book Series will be launching regularly to offer our authors and editors exciting opportunities to publish their research Open Access. We will begin by relaunching some of our existing Book Series in this innovative book format, and will expand in 2022 into rapidly growing research fields that are driving and advancing society.
\\n\\nLaunching 2021
\\n\\nArtificial Intelligence, ISSN 2633-1403
\\n\\nVeterinary Medicine and Science, ISSN 2632-0517
\\n\\nBiochemistry, ISSN 2632-0983
\\n\\nBiomedical Engineering, ISSN 2631-5343
\\n\\nInfectious Diseases, ISSN 2631-6188
\\n\\nPhysiology (Coming Soon)
\\n\\nDentistry (Coming Soon)
\\n\\nWe invite you to explore our IntechOpen Book Series, find the right publishing program for you and reach your desired audience in record time.
\\n\\nNote: Edited in October 2021
\\n"}]',published:!0,mainMedia:{caption:"",originalUrl:"/media/original/132"}},components:[{type:"htmlEditorComponent",content:'With the desire to make book publishing more relevant for the digital age and offer innovative Open Access publishing options, we are thrilled to announce the launch of our new publishing format: IntechOpen Book Series.
\n\nDesigned to cover fast-moving research fields in rapidly expanding areas, our Book Series feature a Topic structure allowing us to present the most relevant sub-disciplines. Book Series are headed by Series Editors, and a team of Topic Editors supported by international Editorial Board members. Topics are always open for submissions, with an Annual Volume published each calendar year.
\n\nAfter a robust peer-review process, accepted works are published quickly, thanks to Online First, ensuring research is made available to the scientific community without delay.
\n\nOur innovative Book Series format brings you:
\n\nIntechOpen Book Series will also publish a program of research-driven Thematic Edited Volumes that focus on specific areas and allow for a more in-depth overview of a particular subject.
\n\nIntechOpen Book Series will be launching regularly to offer our authors and editors exciting opportunities to publish their research Open Access. We will begin by relaunching some of our existing Book Series in this innovative book format, and will expand in 2022 into rapidly growing research fields that are driving and advancing society.
\n\nLaunching 2021
\n\nArtificial Intelligence, ISSN 2633-1403
\n\nVeterinary Medicine and Science, ISSN 2632-0517
\n\nBiochemistry, ISSN 2632-0983
\n\nBiomedical Engineering, ISSN 2631-5343
\n\nInfectious Diseases, ISSN 2631-6188
\n\nPhysiology (Coming Soon)
\n\nDentistry (Coming Soon)
\n\nWe invite you to explore our IntechOpen Book Series, find the right publishing program for you and reach your desired audience in record time.
\n\nNote: Edited in October 2021
\n'}],latestNews:[{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"},{slug:"introducing-intechopen-book-series-a-new-publishing-format-for-oa-books-20210915",title:"Introducing IntechOpen Book Series - A New Publishing Format for OA Books"}]},book:{item:{type:"book",id:"3077",leadTitle:null,fullTitle:"Syntheses and Applications of Carbon Nanotubes and Their Composites",title:"Syntheses and Applications of Carbon Nanotubes and Their Composites",subtitle:null,reviewType:"peer-reviewed",abstract:"Carbon nanotubes are rolled up graphene sheets with a quasi-one-dimensional structure of nanometer-scale diameter. In these last twenty years, carbon nanotubes have attracted much attention from physicists, chemists, material scientists, and electronic device engineers, because of their excellent structural, electronic, optical, chemical and mechanical properties. More recently, demand for innovative industrial applications of carbon nanotubes is increasing. This book covers recent research topics regarding syntheses techniques of carbon nanotubes and nanotube-based composites, and their applications. The chapters in this book will be helpful to many students, engineers and researchers working in the field of carbon nanotubes.",isbn:null,printIsbn:"978-953-51-1125-2",pdfIsbn:"978-953-51-4249-2",doi:"10.5772/3377",price:159,priceEur:175,priceUsd:205,slug:"syntheses-and-applications-of-carbon-nanotubes-and-their-composites",numberOfPages:550,isOpenForSubmission:!1,isInWos:1,isInBkci:!0,hash:"38dd4fb088a27b2552bf3d371e8c2872",bookSignature:"Satoru Suzuki",publishedDate:"May 9th 2013",coverURL:"https://cdn.intechopen.com/books/images_new/3077.jpg",numberOfDownloads:85777,numberOfWosCitations:194,numberOfCrossrefCitations:97,numberOfCrossrefCitationsByBook:12,numberOfDimensionsCitations:214,numberOfDimensionsCitationsByBook:21,hasAltmetrics:1,numberOfTotalCitations:505,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"March 1st 2012",dateEndSecondStepPublish:"March 22nd 2012",dateEndThirdStepPublish:"June 18th 2012",dateEndFourthStepPublish:"August 1st 2012",dateEndFifthStepPublish:"December 8th 2012",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6,7,8",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"30519",title:"Dr.",name:"Satoru",middleName:null,surname:"Suzuki",slug:"satoru-suzuki",fullName:"Satoru Suzuki",profilePictureURL:"https://mts.intechopen.com/storage/users/30519/images/system/30519.jpg",biography:"Dr. Satoru Suzuki earned an MS degree from Tohoku University, Sendai, Japan in 1992, and joined the Research and Development Center, NTT Corporation. Since 1998, he has worked for Basic Research Laboratories, NTT. He obtained a PhD degree in Science from Tohoku University in 1999. Dr. Suzuki has mainly studied the electronic structures of electrode materials for rechargeable lithium ion batteries, the electronic structures of pristine and doped carbon nanotubes, and low-energy irradiation damage specific to single-walled carbon nanotubes. He is currently also studying the synthesis and electric device applications of large-area graphene and hexagonal boron nitride.",institutionString:null,position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"1",totalChapterViews:"0",totalEditedBooks:"2",institution:null}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"1169",title:"Condensed Matter Physics",slug:"nanotechnology-and-nanomaterials-material-science-condensed-matter-physics"}],chapters:[{id:"38977",title:"Production of Carbon Nanotubes and Carbon Nanoclusters by the JxB Arc-Jet Discharge Method",doi:"10.5772/51964",slug:"production-of-carbon-nanotubes-and-carbon-nanoclusters-by-the-jxb-arc-jet-discharge-method",totalDownloads:5218,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:null,signatures:"Tetsu Mieno and Naoki Matsumoto",downloadPdfUrl:"/chapter/pdf-download/38977",previewPdfUrl:"/chapter/pdf-preview/38977",authors:[{id:"209593",title:"Dr.",name:"Tetsu",surname:"Mieno",slug:"tetsu-mieno",fullName:"Tetsu Mieno"}],corrections:null},{id:"43663",title:"Large Arrays and Networks of Carbon Nanotubes: Morphology Control by Process Parameters",doi:"10.5772/52674",slug:"large-arrays-and-networks-of-carbon-nanotubes-morphology-control-by-process-parameters",totalDownloads:3108,totalCrossrefCites:4,totalDimensionsCites:5,hasAltmetrics:0,abstract:null,signatures:"I. 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Furthermore, the nontoxic nature of chemicals in plants, positive healthy properties, consumer perception and acceptance of their use has been well demonstrated [3, 4].
\nThere are estimated 250,000–500,000 species of plants on Earth. A relatively small percentage (1–10%) of these is consumed as food by both humans and animal species. It is possible that a greater number are used for medicinal purposes. People on all continents have long applied poultices and imbibed infusions of hundreds, if not thousands, of indigenous plants. Currently, antimicrobial plant extracts are of especial interest to chemists and microbiologists due to growing public awareness of the negative effects of the over‐use of antibiotics and disinfectants [5].
\nPlants have the ability to synthesize an almost limitless array of substances. In many cases, these chemicals serve as plant‐defense mechanisms against predation by microorganisms, insects, and herbivores. Some, such as terpenoids, give plants their flavors; others—quinones and tannins are responsible for plant pigmentation. Any part of the plant may contain active components. For instance, roots of ginseng plants contain active saponins and essential oils, while eucalyptus leaves are harvested for their essential oils and tannins. Some trees contain useful substances in their bark, leaves, and shoots [6]. Some of the same herbs and spices used by humans to season food can yield useful medicinal compounds. Among different compounds derived from plants, saponins deserve a special mention. These chemicals may be considered as a part of plants’ defense systems. They have been included in a large group of protective molecules found in plants named ‘phytoanticipins’ or ‘phytoprotectants’ [7].
\nThe physiochemical and biological properties of saponins have led to a number of traditional and industrial applications. They have traditionally been used as natural detergents. The combination of a hydrophobic aglycone backbone and hydrophilic sugar molecules confers foaming and emulsifying properties of saponins [8]. The name ‘saponin’ is derived from the Latin word ‘sapo,’ meaning soap, as a soapy lather forms when plants containing saponins are agitated in water. They also exhibit a variety of biological activities. Plant‐derived triterpenoid and steroidal saponins have been used in the production of steroid hormones in the pharmaceutical industry, as food additives, fire extinguishers and in other industrial applications. Other interesting biological applications include their use in anti‐inflammatory, hypocholesterolemic and immune‐stimulating remedies [9, 10].
\nSaponins are a class of substances with a rigid skeleton of at least four hydrocarbon rings to which sugars in groups of one or two are attached (usually not more than 10 units). Traditionally, they are subdivided into triterpenoid and steroid glycosides. Steroidal saponins are mainly compounds containing 27 carbon atoms forming the core structures: spirostan (16β,22:22α,26‐diepoxy‐cholestan) and furostan (16β,22‐epoxycholestan) [11–13] (Figures 1 and 2).
\nStructures of (A) triterpenoid and (B) steroidal saponins [
Structures of (A) spirostanol and (B) furostanol saponins [
There are 11 main classes of saponins: dammaranes, tirucallanes, lupanes, hopanes, oleananes, taraxasteranes, ursanes, cycloartanes, lanostanes, cucurbitanes, and steroids. The oleanane skeleton is the most common, present in most orders of the Plant Kingdom [15, 16].
\nSaponins with the carbohydrate or oligosaccharide groups attached at the C‐3 position are monodesmosidic, while saponins with carbohydrates attached at both the C‐3 and C‐26 or C‐28 positions are bidesmosidic. The variety of a glycones, carbohydrates, and different attachment positions result in numerous types of saponins. The carbohydrate chains of saponins usually include: D‐glucose, D‐galactose, L‐rhamnose, L‐arabinose, D‐xylose, D‐apiose, D‐fucose, and D‐glucuronic acid. The steroidal saponins usually show furostanol or spirostanol form. Additionally, both steroidal and triterpene saponins may contain other functional groups: –OH, –COOH, –CH3 that give them additional diversity [17].
\nThe chemical structure of saponins may be transformed during storage or processing. The linkages between the sugar chain and the aglycones as well as between the sugar residues can undergo hydrolysis during acid or base treatment, hydrothermolysis or enzymatic/microbial transformations, resulting in the formation of aglycones, prosapogenins (partially hydrolyzed saponins), and sugar residues [17]. Therefore, the selection of methods appropriate to storage of plant material is a key part of each efficient technology [18–20].
\nThe presence of saponins has been reported in more than 100 families of plants and in a few marine sources such as star fish and sea cucumber. Triterpene saponins are present in many taxonomic plant groups. In particular, they can be found in parts of dicotyledonous plants (
The phylogenetic tree with plant subclasses [
Some studies have suggested that variations in saponin distribution and composition in plants may be a reflection of varying needs for plant protection. In some plants, for example,
The main sources of saponins in human diet are legumes, mainly broad beans, kidney beans and lentils. Saponins are also present in
Some of the better‐known botanicals rich in saponins are presented in Table 1.
\nPlant | \nSaponin content [%] | |
---|---|---|
Latin name | \nCommon name | |
Horse‐chestnut | \n3 | |
Oat | \n0.1–0.13 | |
Sugar beet (leaves) | \n5.8 | |
Quinoa | \n0.14–2.3 | |
Chickpea | \n0.23 | |
Saffron crocus | \n1.2–3.4 | |
Soybean | \n0.22–0.49 | |
Licorice (root) | \n22.2–32.3 | |
Ivy | \n5 | |
Alfalfa | \n0.14–1.71 | |
Chinese ginseng | \n2–3 | |
American ginseng | \n1.42–5.58 | |
Green pea | \n0.18–4.2 | |
Milkwort | \n8–10 | |
Primula | \n5–10 | |
Quillaja bark | \n9–10 | |
Soapwort | \n2–5 | |
Sarsaparilla | \n1.8–2.4 | |
Fenugreek | \n4–6 | |
Yucca | \n10 |
In Northern Europe, the main sources of saponins are:
In sugar beet leaves, saponins have been reported at level of 5%, and in roots 0.1–0.3%. However, during raw beet processing, these saponins are mostly concentrated in the waste products. For example, the concentration of saponins in sugar beet pulp water reaches 1.2% [23]. Similar concentrations of saponins have been detected in the filtration residues and molasses. In Polish research laboratories, several triterpene‐based saponin structures have been isolated and characterized [24]. Given the scale of worldwide sugar production from sugar beet, this plant can be considered as an industrial source of saponins [25]. Sugar beet as a high economic value crop will have a prosperous perspective of application in the food, bioenergy, and pharmacy industries [26].
\nIn Southern Europe, the region around the Mediterranean Sea is rich in grapes. Saponin glycosides in red wine are known as heart protective, due to their LDL cholesterol‐lowering and HDL cholesterol‐increasing effects. The saponins in red wine also help prevent clumping of red blood cells. Many of plant species rich in saponins are used traditionally in Greece for making herbal teas, as flavorings and seasonings and have been tested for various pharmacological activities [27]. Mediterranean thyme (
China is rich in various plant sources of saponins, which are often unknown in Europe.
The interesting plant in China is
The
The important source of natural medicines is
Plant saponins show region‐specific character. It was found that variety of soybean from China is richer in saponins than those from Japan, Canada or United States [42].
To obtain saponins from plant material different extraction methods may be used, using solvents as water, methanol, ethanol or hydroalcoholic mixtures in Soxhlet extractors or in orbital shakers. In addition, other solvents such as glycerol and aqueous or alcoholic surfactants solutions were also reported. Novel procedures use lower amounts of solvent but additional physical/chemical treatment: multi‐stage extraction, pressure, microwaves, ultrasounds or supercritical fluid extraction. These methods can led to an increase in the process efficiency. However, it should be considered that under harsher conditions (higher temperature and pressure), saponins can be hydrolyzed and degraded, so rather mild processes should be used [45–49].
\nSaponins, due to the presence of a lipid‐soluble aglycone and water‐soluble sugar chain, show amphiphilic nature. In this way, foam formation (with liquid‐gaseous phases), an emulgator effect (with liquid‐liquid phases) and dispersion abilities (with liquid‐solid phases) are achieved. Saponins with one sugar chain have the best foaming characteristics. The compounds with two or three sugar chains show decreasing of foaming ability. Some saponins without foaming character have also been observed [17].
\nIn aqueous solution, saponin molecules align themselves vertically on the surface with their hydrophobic ends oriented away from the water. This has the effect of reducing the surface tension of the water, causing it to foam. In aqueous solutions, surfactants form micelles above a critical concentration called critical micelle concentration (CMC). Below this concentration, molecules remain unassociated. Micelles have a lipophilic center, and this creation of a fat‐loving compartment explains why detergents can dissolve grease and oils (Figure 4).
\nMicelle formation [
The size and structure of micelles are dependent on the type of saponin. For example, saponins from
The presence of carboxylic acid in the saponin molecule may strongly influence the surface activity. Additionally, the location of this acid in the molecule is particularly important. For example,
Interactions between saponin and membrane‐bound cholesterol lead pore formation and increasing of membrane permeabilizing properties. This specific effect of saponins depends on the combination of various factors: the membrane composition, the type of saponin, and—especially—the nature of aglycone [52].
\nSaponins also affect the permeability of intestinal cells by forming complexes with sterols in mucosal cell membranes. This leads to increase in intestinal mucosal cells permeability. Thus, this facilitates the uptake of substances to which the gut would normally be impermeable, for example, milk alergen α‐lactoglobulin [17].
\nEmulsifiers play two key roles in the creation of successful emulsion‐based products. They: (i) facilitate the initial formation of fine lipid droplets during homogenization and (ii) enhance the stability of the lipid droplets once they have been formed. Oil‐in‐water emulsions may be formed using either high‐ or low‐energy approaches. High‐energy approaches utilize mechanical devices (homogenizers): high shear mixers, colloid mills, high‐pressure valve homogenizers, microfluidizers, and sonicators. Low‐energy homogenization relies on the spontaneous formation of emulsions when the composition or environment of certain emulsifier‐oil‐water mixtures is changed in a particular way.
Due to their amphiphilic nature, saponins show a wide range of biological activities. Various crude isolates, extracts, and saponin containing plants were utilized in the investigation of biological activity in the earlier studies; however, progress in the isolation/purification and characterization techniques has enabled the investigation of the bioactivity of well characterized [56, 57]. Saponins have been shown to swell and rupture erythrocytes causing a release of hemoglobin. The effect of saponin on erythrocyte death or hemolysis may limit the therapeutic use of the substances. On the other hand, saponins have been proposed for the treatment of a variety of diseases, including diabetes, obesity and osteoporosis [58]. Pharmacological effects of saponins include stimulation of immune responses. Their efficacy against cancer has been attributed to their ability to inhibit cell proliferation, to counteract angiogenesis and to stimulate apoptosis [59–61].
\nThe toxicity of saponins to insects (insecticidal activity), parasite worms (anthelmintic activity), molluscs (molluscicidal), and fish (piscidal activity), and their antifungal, antiviral, and antibacterial activity is well documented. Toxicity of saponins to warm blooded animals is dependent on the source, composition, and concentration of these compounds. The results of in vivo studies with rats, mice, and rabbits implied that saponins are not absorbed in the alimentary channel but hydrolyzed enzymatically to sapogenins [21].
\nThe action of saponins, by enhancing the immune response to antigens, has been documented since 1940s.
Several mechanisms have been proposed to explain the hypocholesterolaemic activity of saponins. Possible mechanisms may involve the capacity of saponins to: (i) form insoluble complexes with cholesterol, (ii) affect micelle formation, (iii) interfere with bile acid metabolism, (iv) inhibit lipase activity, or (v) regulate cholesterol homeostasis via monitoring the expression of the key regulatory genes of proteins or enzymes related to cholesterol metabolism [58, 64]. Cholesterol‐lowering activity of saponins has been demonstrated in both animal and human trials. Animal diet containing purified saponins or concentrated saponin extracts containing, for example, digitonin (saponin from
Anticancer activity has been reported for soya saponins, ginsenosides, saikosaponin, diosgenin and glycyrrhizic acid. In particular, the potential of soybean saponins as anticarcinogens has been studied in recent years. Anticancer activities of saponin containing plants such as ginseng and licorice were also investigated [65].
\nThe study of the relationship between chemical structure of aglycones and colon anticancer activity of soybean saponins revealed that the soya sapogenols were more bioactive than the glycosidic saponins. Other aglycones with anticancer activity include dammaranesapogenins from ginseng, betulinic acid, and oleanolic acid. These two last compounds were also reported to possess anti‐viral, anti‐inflammatory, hepatoprotective, anti‐ulcer, antibacterial, hypoglycaemic, anti‐fertility, and anticariogenic activities. However, the conversion of saponins to their aglycones may also result in the loss of activity. For example, the hydrolysis of saponins by ruminal bacteria results in the loss of antiprotozoal activity. Similarly, the deacylation of
The antimicrobial effects of saponins extracted from plants have been studied in
In the United States,
Tenon and co‐workers used HPLC/ELSD technique for
The second saponin source of commercial value is
A large amount of
The beneficial effects of extracts from
According to the Codex Alimentarius Commission, extracts from
Although
In the European Union,
The physiochemical properties of saponins can also be utilized in food processing applications, thus, while complex formation of saponins with cholesterol has been used for the removal of cholesterol from dairy products such as butter oil [89–91]. It was documented that the natural food‐grade surfactant isolated from the bark of the
As a natural surfactant,
Dried roots of licorice represent an important agricultural product. The name ‘glycyrrhiza’ originates from the Greek words ‘glykosrhiza,’ which mean ‘sweet root.’ Licorice is used as a sweetener and a flavor enhancer for foods in China and other countries. It is approved by Food and Drug Administration USA as a food additive, regarded with the ‘GRAS’ label and registered as CFR 184.1408 [33].
\nSaponins can be used to enhance both the effectiveness of cleaning/disinfection processes. They are considered natural detergents and are used as additives in washing powders, and additives for liquid/powder cleaning. The addition of a small amount of a saponin to an aqueous environment provides a product that is an effective water clarifier and solid surface cleanser. These compositions may be used to clean metals, metal‐plated surfaces, ceramics, wood, glass, etc. The use of natural plant products as detergents could provide cheaper, safer and more consumer‐acceptable alternatives to synthetic compounds.
\nSaponins are diverse compounds traditionally used as natural detergents. Their physicochemical and biological properties are wide exploited in food, cosmetics and pharmaceuticals. Information on the composition (qualitative and quantitative), properties of the saponins present in the raw material, and the effects of processing on their composition and properties are key elements of successful process design.
\nThis chapter investigates the relationship of varying pedagogical definitions alongside observations of teaching practice within different vocational areas. These pedagogical concepts include Technological Pedagogical Content Knowledge (TPCK), Signature Pedagogies and expansive vocational education. Originally Shulman [1] defined pedagogy in distinct ways that incorporated concepts such as Content Knowledge (CK) and Pedagogical Content Knowledge (PCK) and both relate to both academic and vocational pedagogy. However, for now the emphasis is on a consideration of signature pedagogies in vocational learning and its importance in professional learning.
According to Shulman [2] Content Knowledge arises from the knowledge of the discipline being taught and here he uses the example of Biology as the subject in question. In terms of teaching, he raises some interesting questions such as “How does the novice teacher (or even the seasoned veteran) draw on expertise in the subject matter in the process of teaching?” (p. 8). Ultimately this is about the amount and organisation of knowledge that the teacher has. Pedagogical Content Knowledge on the other hand refers to the way that the teacher organises specific topics and ranks them according to difficulty in learning. In this way he or she is able to build up a coherent scheme of work that builds knowledge and scaffolds it so that it becomes more accessible to learners. Here Shulman means the most frequently taught topics and the most accessible forms of representation and illustrations of that topic, again with the desire to make it more accessible to learners. In the past these would have been ‘cut and pasted’, photocopied and reproduced for the learners, nowadays the internet has allowed a different form of cut and paste. Hence in the light of technology Shulman’s original definitions of teacher knowledge have been revised and here a different dimension has been added to these concepts, that of Technological Pedagogical Content Knowledge (TPCK). Several authors (Koehler and Mishra [3] and Harris et al. [4]) discuss this concept and define the term as the effective use of technology in teaching and learning. Here it assumes that a teacher has some technical content knowledge, that is some knowledge of technology available to teaching as resources to illustrate and represent topics. Here the Content Knowledge, and PCK as advocated by Shulman come together as Technological Content Knowledge in other words, the knowledge of how technological aids can enhance these representations. However, this is all very well if the technology also aids pedagogically or if it is chosen just because it is there. Here the new concept of TPCK presents different challenges to teachers today.
TPCK can be viewed as the basis of good teaching with technology and requires an understanding of the way concepts can be represented through using emerging technologies and by using the correct pedagogical principles that use that technology in a constructive way to allow access to content. This is different for example than knowing that Padlet is an ‘app’ (application), it also involves cognition as to how this technology can help in pedagogical ways as well. Here Padlet can be used in collating student ideas and as collaboration in learning. It allows a more student-centred approach to construction of knowledge and hence application and analysis of that specific subject knowledge.
However more recently another concept of pedagogy has emerged in the literature, that of ‘signature pedagogies’ which is defined as “types of teaching that organise the fundamental ways in which future practitioners are educated for their new professions” Shulman [1]. This concept is of particular importance in a vocational context as here students are being prepared for specific professional careers such as Hairdressing, Engineering and Construction amongst others. Recent literature has revolved around the concept of vocational pedagogies and how students in vocational education and training are taught differently from more academic courses based on theory alone. As a concept signature pedagogy is an idea that Shulman [1] applied to vocational areas of learning and noted here that the learner is ‘trained’ in three areas of the professional work involved. These are:
Thinking as a professional
Performing as a professional
Acting as a professional
Shulman [1] goes onto note three dimensions to signature pedagogy, these being ‘surface structure’, ‘deep structure’ and an ‘implicit structure’. The surface structure he argues is the operational aspects of teaching and learning such as questioning students and demonstrating specific techniques important to those professions. In Hairdressing these would be demonstration of specific skills such as cutting hair and for example in Engineering, underpinning health and safety around the correct use of large lathes. The deep structure involved a set of assumptions about how to impart the specific knowledge within that profession and again in Engineering, this would be how to solve problems and find solutions. Finally, the implicit structure according to Shulman involves the moral aspects of that profession such as attitude, values and dispositions. Here he uses law as an example of legal reasoning and moral judgements.
Lucas and Hanson [5], as does Shulman, go one step further and refer to signature pedagogies as defining habits of hearts, mind and hands. Shulman [1] notes “One thing is clear: signature pedagogies make a difference. They form habits of the mind, habits of the heart, and habits of the hand”. For Lucas and Hanson these habits of mind can be described in Engineering as EHoM (Engineering Habits of Mind) and this involves as the following:
Systems thinking (seeing whole, systems and parts, and how they connect, pattern-sniffing, recognising interdependencies, synthesising)
Problem finding (clarifying needs, checking existing solutions, investigating, contexts, verifying)
Visualising (move from abstract to concrete, manipulating materials, mental rehearsal of physical space and of practical design solutions)
Improving (relentlessly trying to make things better by experimenting, designing, sketching, guessing, conjecturing, thought-experimenting, prototyping)
Creative problem solving (applying techniques from other traditions, generating, ideas and solutions with others, generous but rigorous critiquing, seeing engineering as a “team sport”)
Adapting (testing, analysing, reflecting, re-thinking)
Lucas and Hanson [5] conclude that those involved in engineering teaching and learning need to consider redesigning engineering education and start from the premise that they are trying to “cultivate learners who think like engineers, and we have suggested that a clearer articulation of the signature pedagogies of engineering may support this aim.” (p. 12).
Whilst not within an engineering context Claxton [6] too refers to Habits of mind as specific skills and attitudes to learning such as “resilience, creativity, communication, team working, leadership, flexibility, resourcefulness, reflection and metacognition” (p. 6). Lucas et al. [7] also use the term ‘expansive education’ as a means of redefining vocational or ‘real-world learning’ and here we see terms such as resourcefulness, self-belief and ‘wider dispositions for lifelong learning’ (p. 138). Lucas et al. [7] go onto unpick this concept further to look at the part that the teacher has on learning, through being ‘feedback-rich’ (p. 133). By this they mean ‘critical reflection on progress’ and how feedback provides learning with purpose and progression.
It is clear from the literature that signature pedagogies make a difference and as Shulman noted in 2005, they inform habits of the mind, heart, and hands. It follows therefore that teachers need to use these more in vocational learning to enable students to think like professionals with resilience and resourcefulness at the heart of what they do. The following section therefore looks to practice to see how vocational teachers do use signature pedagogies in practice.
In order to research the way that vocational teachers integrate the concepts of signature pedagogies into their day-to-day teaching, data was taken from a series of classroom observations within a vocational college in the Southeast of England. Staff here are routinely observed either within a theory classroom-based lesson or in a practical workshop involving skill-based learning. Observations are part of the quality assurance process and are recorded as a narrative report rather than a tick box approach. These are not graded but teachers are given specific targets for improvement based on what was observed in that session. Data was collected over two academic terms and here both practical and theory sessions were observed. There were 13 lessons observed in total, of these 11 were theory-based sessions with 2 practical ones. The vocational subjects seen were a Construction practical session, two Hairdressing sessions, one practical and one theory based. The other observations came from Engineering, two different theory lessons, Gas, two theory lessons, two Health and Social Care theory lessons, two Media theory sessions and two Plumbing theory sessions. All teachers seen were experienced in their vocational subject having been practitioners first and teachers later in life. In terms of demographics most were middle aged and had been teaching for several years. The Hairdressing and Health and Social Care teachers were female as was one of the Engineering teachers. The Media sessions was split between one male and one female and here the female teacher was a novice teacher in her first year of teaching having spent some years in broadcasting. All the Gas, Construction and Plumbing teachers were male. The observations were written up in full and comments were extracted from the observation feedback and analysed according to the following concepts relating to signature pedagogies in both practical and theory lessons. These were:
a surface structure – where there was a reference to teaching methods
a deep structure – where there was a reference to specific professional learning
an implicit structure – where there was a reference to the moral or value judgements of that profession
Using this data allowed an overall view of how signature pedagogy is incorporated in teaching of vocational learning. The following section outlines the findings of the observed sessions.
Table 1 shows the thirteen sessions observed with a breakdown of theory or practical. The comments in column two have been extracted from the full observation feedback as they show aspects of signature pedagogy. Column three shows the analysis of the comment in the light of Shulman’s [1] dimensions of signature pedagogy, these being surface/deep/implicit. All lessons observed showed deep or implicit dimensions of signature pedagogy in practice, these being references to specific professional learning or moral or value judgements.
Vocational subject | Observation comment that relates to the way that the teacher is demonstrating signature pedagogies | Dimension: surface/deep/implicit |
---|---|---|
Hairdressing theory lesson 1 | Wonderful, you talked about training as a hairdresser rather than just passing the exam. Good demonstrations seen that helped the learners to see a professional in practice. | Deep |
Hairdressing practical lesson 2 | Whole group is managed well and there is a brisk pace which is reinforced with reference to ‘hairdressing pace’, excellent standards required here | implicit |
Engineering theory lesson 1 | Reinforcement of key rules such as the need for the equation, excellent practice for their future as engineers. | deep |
Engineering theory lesson 2 | Here the project was linked to the real world of project management and the skills needed here (S). Linked to money and budgets as well. Well done. | Deep/implicit |
Health and Social Care theory lesson 1 | Made relevant to the real world of work and what they want to do in the future. | deep |
Health and Social Care theory lesson 2 | The topic was linked well to being a professional and the need for CPD, formative assessment via using whiteboards, here students write their ideas about how to complete CPD | deep |
Gas theory lesson 1 | The topic was gas decommissioning, and it began with consideration of the Duty of Care involved in any gas work undertaken. Excellent analogy provided which clearly highlighted the need to refer work that was not safe to the correct person/authority (S). This really showed the students the importance of never leaving work with a possible gas leak. This was reinforced with the legislation (RIDDOR) and the need to report any gas leaks immediately. The major strength seen here was the constant reference to the professional approach that needs to be taken when dealing with gas. This was done through the repeated reference to Duty of Care and the possibility of killing someone if gas explodes! | implicit |
Gas theory lesson 2 | Excellent use of own experiences and local knowledge with regard to the damage gas fires can do and you respond well to student questions here as well. You made it relevant to the exam that the students need to take and above all a strength here was the constant reference to the professional approach needed with regard to Duty of Care and the possibility of 7 years for manslaughter. This was reinforced several times as was the competence required for different equipment and ongoing need to continuous professional development as a gas engineer. | implicit |
Construction practical lesson 1 | Excellent use of humour and how to learn from mistakes and to move on. All this is good grounding for professional practice. Students rated this and it was then made clear to them as to the importance of this technique as practice for being a master craftsperson. Well done here, this showed the need for a professional approach to the trade. | implicit |
Plumbing theory lesson 1 | Discussion then moved to being a professional, although you did not mention this word. You did note the need for CPD and the regulations for renewal of the card at 5-year intervals. | Implicit/deep |
Plumbing theory lesson 2 | This was also well related to actual work as a plumber and you made good use of a past student to illustrate key points | deep |
Media theory lesson 1 | However, it was a useful exercise as it allowed you to evaluate the brief as well as being a chance to emphasize the need for some practical procedures that they would need in industry, this part was excellent as it really linked to the world of work | deep |
Media theory lesson 2 | This was also related to merit/distinction etc and again related to which area of the industry they might like to focus on in future. Logbooks were related to interview skills and you made it clear that even if they did not like doing them, they needed to! Linked to Btec rules of working with more than one person and again to real work ie getting a script and being creative. | deep |
To show the observation data analysed in terms of the way that vocational teachers use signature pedagogies in practice.
Interestingly the strongest lessons showing aspects of an implicit structure for a signature pedagogy came from the plumbing and construction teams. This was seen as implicit due to the references concerning health and safety and craftmanship. There were three lessons observed in this department, two theory-based lessons and one practical. Clearly the issue of dealing with a potential gas hazard can be considered as a moral judgement as did the comment made about being a master craftsman. In these instances, the teachers were drawing on their own experience as master craftsman to highlight the professional aspects of their trades. The comment regarding a ‘hairdressing pace’ was seen in a practical session in which the teacher was getting the learners to work at a pace appropriate to a real hairdressing salon even though they were still training. A point worth making here is that both gas and hairdressing involve working directly with customers and that in both health and safety is vital to a professional approach.
The lessons which were deemed to show deep structures rather than implicit ones were because they did not touch on the moral aspects of the craft but rather were aspects of specific knowledge relating to that subject. Here there were several references to the real world of work and being a professional. Here as well the teachers were modelling good practice as in for example, the hairdressing teacher who was demonstrating techniques in a professional way so as to enable students to observe a professional person in action. This resonates with Claxton’s [6] ideas of habits of mind where teamworking, creativity and communication are important skills required for that profession.
To some degree it can be argued that in Engineering there were elements of habits of mind as the reference to the need for ‘equation’ does highlight the need for students in this discipline to be able to visualise or ‘move from abstract to concrete’ as Lucas and Hanson [5] indicate as being an EHoM for this subject. Finally, it is clear from all the observations undertaken that there were deep structures of teachers using signature pedagogies as part of professional vocational learning.
To return to the literature, Shulman [1] applied the concept of signature pedagogy as one in which the learner is ‘trained’ to think, perform and act like a professional. The outcome he argued, would be that through the implicit structure of the pedagogical approach, learners would gain the valued dispositions for that profession. From this data it can be seen quite clearly that the vocational staff involved in teaching students today do use signature pedagogies in their day-to-day teaching, both in theory and practical sessions. The repeated reference to Health and Safety in working with gas was reinforcing the moral judgements that a professional must exercise at all times, the implicit structure that Shulman claims is part of signature pedagogy. Similarly, reference to the ‘pace of hairdressing’ shows how the trained professional must act and perform when working on real clients.
In terms of cultivating the habits of mind, heart and hand, there is evidence that the teachers were developing these by role modelling as seen in hairdressing, learning from mistakes as seen in the practical construction class and reinforcement of the ‘rules of equation’ seen in engineering. Unfortunately, the EHom that Lucas and Hanson [5] refer to was not really seen in the data, this is intended to be further research within this particular vocational area in the future.
The authors declare no conflict of interest.
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In-service vehicles equipped with sensors and GPS systems can act as probes to detect and analyse real-time vehicle vibration. Recently, a compact on-board sensing device has been developed. This chapter describes the track condition monitoring system that uses a compact on-board sensing device and diagnosis software. The diagnosis software provides the function of detecting track faults using the root mean square (RMS) of the car-body acceleration. It also allows analysis in the time-frequency domain using wavelet transform. A monitoring experiment in a local railway line showed that the system is effective for practical application.",book:{id:"4789",slug:"railway-research-selected-topics-on-development-safety-and-technology",title:"Railway Research",fullTitle:"Railway Research - Selected Topics on Development, Safety and Technology"},signatures:"Hitoshi Tsunashima, Hirotaka Mori, Masayuki Ogino and Akira\nAsano",authors:[{id:"49517",title:"Prof.",name:"Hitoshi",middleName:null,surname:"Tsunashima",slug:"hitoshi-tsunashima",fullName:"Hitoshi Tsunashima"}]},{id:"59302",doi:"10.5772/intechopen.74277",title:"Model-Based Fault Analysis for Railway Traction Systems",slug:"model-based-fault-analysis-for-railway-traction-systems",totalDownloads:1384,totalCrossrefCites:1,totalDimensionsCites:5,abstract:"Fault analysis in industrial equipment has been usually performed using classical techniques such as failure modes and effects analysis (FMEA) and fault tree analysis (FTA). Model-based fault analysis has been used during the last several years in order to overcome the limitations of classical methods when complex industrial equipment has to be analyzed. In railway and automotive sectors, the development and validation of new products are based on hardware-in-the-loop (HIL) platforms. In this chapter, a methodology to enhance classical FMEAs is presented. Based on HIL simulations, the objective is to improve the results of the fault analysis with quantitative information about the effects of each fault mode. 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In general, stress in steel elements may affect the energy state, phase changes, and corrosion. It may reduce fatigue strength and cause damage and cracks of the rails. It is one of the causes of accelerated development of standard railhead defects. Proper selection of, e.g., bending process parameters provides uniform distribution and acceptable level of residual stresses in the bent components. Residual stresses that develop during manufacturing process in the railway turnout steel components can change their strength properties. The first part of this chapter presents ultrasonic measurement method and computer simulation that allowed to develop a method to diagnose state and distribution of residual stresses in steel components of the railway turnout (wing rails and switch blades) in the production process. The second part of this chapter includes experimental and simulation studies of superstructure in operational conditions. 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A significant number of simulation calculations also allow to determine the duration of guaranteed functionality of a reinforced track substructure.",book:{id:"4789",slug:"railway-research-selected-topics-on-development-safety-and-technology",title:"Railway Research",fullTitle:"Railway Research - Selected Topics on Development, Safety and Technology"},signatures:"Jacek Kukulski",authors:[{id:"175842",title:"Ph.D.",name:"Jacek",middleName:null,surname:"Kukulski",slug:"jacek-kukulski",fullName:"Jacek Kukulski"}]},{id:"49716",doi:"10.5772/62080",title:"A Systems View of Railway Safety and Security",slug:"a-systems-view-of-railway-safety-and-security",totalDownloads:4110,totalCrossrefCites:2,totalDimensionsCites:3,abstract:"This chapter approaches the concerns over safety and security of modern mainline and light railways from a systems perspective. It addresses the two key concerns from the view point of systemic emergence arising from the interaction between all the principal constituents of the railway system, namely infrastructure, rolling stock, energy and human element comprising workers, passengers and the neighbours of the railways.",book:{id:"4789",slug:"railway-research-selected-topics-on-development-safety-and-technology",title:"Railway Research",fullTitle:"Railway Research - Selected Topics on Development, Safety and Technology"},signatures:"Ali G. Hessami",authors:[{id:"108303",title:"Prof.",name:"Ali G.",middleName:null,surname:"Hessami",slug:"ali-g.-hessami",fullName:"Ali G. Hessami"}]},{id:"57840",doi:"10.5772/intechopen.71768",title:"Advanced Train Positioning/Communication System",slug:"advanced-train-positioning-communication-system",totalDownloads:1660,totalCrossrefCites:3,totalDimensionsCites:3,abstract:"In the past, in order to ensure train positioning as well as ground-to-train information exchange, railways have adopted various technologies. Over time, each new generation of equipment enriched the global information exchange but, as a consequence, necessitated higher data rate transfers. For the positioning functionality, the existing localisation systems are still limited, since most of them require an infrastructure installation with constraints such as laying equipment between the rails or having high database maintenance requirements and computational costs. Moreover, some of them accumulate errors (odometers and inertial sensors) or offer limited coverage in shadowed areas (GNSS, etc.). Currently, in railway applications, a widely used localization system is based on proprioceptive sensors embarked in the train. This on-board system is coupled to the use of balises located at ground between the rails. These balises are kilometre markers. They are used to compensate for the drift of the localization information computed using the proprioceptive sensors alone, when the train moves. The balises provide absolute localization information whenever the train passes over them. They can also provide spot communication during the short period of time when trains are passing over them. In the first part of this chapter, techniques for achieving train positioning and data exchanges between trains and infrastructure are introduced. In the second part, a new balise is proposed. Particular attention is paid to the contribution of this new solution in terms of localization error and communication performances.",book:{id:"6065",slug:"modern-railway-engineering",title:"Modern Railway Engineering",fullTitle:"Modern Railway Engineering"},signatures:"Fouzia Elbahhar and Marc Heddebaut",authors:[{id:"140822",title:"Dr.",name:"Fouzia",middleName:null,surname:"Elbahhar",slug:"fouzia-elbahhar",fullName:"Fouzia Elbahhar"}]}],mostDownloadedChaptersLast30Days:[{id:"57056",title:"Transmission-Based Signaling Systems",slug:"transmission-based-signaling-systems",totalDownloads:3049,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"In this chapter, we describe the principal communication systems applied to the transmission-based signaling (TBS) systems for railways. Typical examples are communication-based train control (CBTC), European Rail Traffic Management System (ERTMS), and distance to go (DTG). Moreover, to properly address some of the challenges that need to face these systems, we will provide a deep insight on propagation issues related to all the environments (urban, suburban, rural, tunnel, etc.). We will highlight all the communication-related issues and the operational as well. Finally, a detailed survey on the directions of research on all these topics is provided, in order to properly cover this interesting subject. In this research, hot topics like virtual coupling are explained as well.",book:{id:"6065",slug:"modern-railway-engineering",title:"Modern Railway Engineering",fullTitle:"Modern Railway Engineering"},signatures:"Cesar Briso-Rodríguez, Juan Moreno García-Loygorri and Lei Zhang",authors:[{id:"171013",title:"Dr.",name:"Cesar",middleName:null,surname:"Briso",slug:"cesar-briso",fullName:"Cesar Briso"},{id:"216915",title:"Dr.",name:"Juan",middleName:null,surname:"Moreno Garcia-Loygorri",slug:"juan-moreno-garcia-loygorri",fullName:"Juan Moreno Garcia-Loygorri"},{id:"216916",title:"Dr.",name:"Lei",middleName:null,surname:"Zhang",slug:"lei-zhang",fullName:"Lei Zhang"}]},{id:"49375",title:"Experimental and Simulation Study of the Superstructure and Its Components",slug:"experimental-and-simulation-study-of-the-superstructure-and-its-components",totalDownloads:2553,totalCrossrefCites:2,totalDimensionsCites:3,abstract:"The issues discussed in this chapter are of interest of both the manufacturers and the experts responsible for condition of the track superstructure. In general, stress in steel elements may affect the energy state, phase changes, and corrosion. It may reduce fatigue strength and cause damage and cracks of the rails. It is one of the causes of accelerated development of standard railhead defects. Proper selection of, e.g., bending process parameters provides uniform distribution and acceptable level of residual stresses in the bent components. Residual stresses that develop during manufacturing process in the railway turnout steel components can change their strength properties. The first part of this chapter presents ultrasonic measurement method and computer simulation that allowed to develop a method to diagnose state and distribution of residual stresses in steel components of the railway turnout (wing rails and switch blades) in the production process. The second part of this chapter includes experimental and simulation studies of superstructure in operational conditions. A track substructure with a crashed stone composite is a solution of reinforced standard track substructure. The results are used to draw conclusions concerning further development and possible modifications of a proposed solution. A significant number of simulation calculations also allow to determine the duration of guaranteed functionality of a reinforced track substructure.",book:{id:"4789",slug:"railway-research-selected-topics-on-development-safety-and-technology",title:"Railway Research",fullTitle:"Railway Research - Selected Topics on Development, Safety and Technology"},signatures:"Jacek Kukulski",authors:[{id:"175842",title:"Ph.D.",name:"Jacek",middleName:null,surname:"Kukulski",slug:"jacek-kukulski",fullName:"Jacek Kukulski"}]},{id:"59304",title:"Improving Feasibility of High-Speed Train Project: Creating Added Value",slug:"improving-feasibility-of-high-speed-train-project-creating-added-value",totalDownloads:1471,totalCrossrefCites:1,totalDimensionsCites:2,abstract:"Infrastructure plays a significant role in increasing economic development by providing access of transportation and improving connectivity. High-speed train (HST), one of mega infrastructure projects, has a positive impact on economic development of a nation. However, the project feasibility requires the maximum value for money and an acceptable risk to attract private investors. This study aims to improve the feasibility of the project by producing a conceptual design of Jakarta-Surabaya high-speed train in Indonesia. Value engineering will be used to evaluate both technical and financial aspects of the project. The methodology uses both qualitative and quantitative approaches through a case study, in-depth interviews, and life-cycle cost analysis. The result shows an optimum route sketching for the project and potential added value to the project. It consists of the solar cell, fiber optic, tourism, and transit-oriented development. The output also generates the division of responsibility between the government and business entity during the project lifecycle regarding the project financing. The institutional scheme will regulate the position and roles for each related stakeholder that was involved in the HST project development.",book:{id:"6065",slug:"modern-railway-engineering",title:"Modern Railway Engineering",fullTitle:"Modern Railway Engineering"},signatures:"Mohammed Ali Berawi",authors:[{id:"207251",title:"Dr.",name:"Mohammed Ali",middleName:null,surname:"Berawi",slug:"mohammed-ali-berawi",fullName:"Mohammed Ali Berawi"}]},{id:"57840",title:"Advanced Train Positioning/Communication System",slug:"advanced-train-positioning-communication-system",totalDownloads:1660,totalCrossrefCites:3,totalDimensionsCites:3,abstract:"In the past, in order to ensure train positioning as well as ground-to-train information exchange, railways have adopted various technologies. Over time, each new generation of equipment enriched the global information exchange but, as a consequence, necessitated higher data rate transfers. For the positioning functionality, the existing localisation systems are still limited, since most of them require an infrastructure installation with constraints such as laying equipment between the rails or having high database maintenance requirements and computational costs. Moreover, some of them accumulate errors (odometers and inertial sensors) or offer limited coverage in shadowed areas (GNSS, etc.). Currently, in railway applications, a widely used localization system is based on proprioceptive sensors embarked in the train. This on-board system is coupled to the use of balises located at ground between the rails. These balises are kilometre markers. They are used to compensate for the drift of the localization information computed using the proprioceptive sensors alone, when the train moves. The balises provide absolute localization information whenever the train passes over them. They can also provide spot communication during the short period of time when trains are passing over them. In the first part of this chapter, techniques for achieving train positioning and data exchanges between trains and infrastructure are introduced. In the second part, a new balise is proposed. 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He is a vice-president of the Latin American Society for Travel Medicine (SLAMVI) and a Member of the Council of the International Society for Infectious Diseases (ISID). Since 2014, he has been recognized as a Senior Researcher, at the Ministry of Science of Colombia. He is a professor at the Faculty of Medicine of the Fundacion Universitaria Autonoma de las Americas, in Pereira, Risaralda, Colombia. He is an External Professor, Master in Research on Tropical Medicine and International Health, Universitat de Barcelona, Spain. He is also a professor at the Master in Clinical Epidemiology and Biostatistics, Universidad Científica del Sur, Lima, Peru. In 2021 he has been awarded the “Raul Isturiz Award” Medal of the API. Also, in 2021, he was awarded with the “Jose Felix Patiño” Asclepius Staff Medal of the Colombian Medical College, due to his scientific contributions to COVID-19 during the pandemic. 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