\r\n\tWithin this scenario, special attention needs to be devoted to financial implications, due to their pervasiveness. Nobody would question the key role that finance plays to complement the real sphere of the economy and that has increasingly attracted both academics and practitioners. As a result, traditional pillars – such as financial markets, products, and institutions – have evolved significantly, with financial innovation fueling further progress over time. The global side of the coin features – among others – financially connected markets, international financial exchanges, and financial conglomerates that provide valuable opportunities in terms of international corporate finance. On the other side, recent advances have involved a wider recourse to ESG factors, allowed forward steps towards a more inclusive financial system, and have made digital finance a must, rather than an option, even though much remains to be accomplished, for instance, to facilitate access to formal financial channels in many underdeveloped regions.
\r\n\r\n\t
\r\n\tThis book aims to examine emerging trends, new perspectives, and empirical applications that deal with globalization and sustainability. The goal is to provide a comprehensive overview of these important concepts as valuable support to successfully meet the challenges and take on the opportunities ahead. At the same time, drawing upon empirical evidence can contribute to bridging the gap between theory and practice, which also fits within the scope of this book.
It is a long time since Kohn and Sham pave the way to the self-consistent equation, based on the exchange and correlation effects in 1965, leading the Kohn–Sham (KS) Equation [1]. This has ignited the success of quantum physics and chemistry, specifically many-body problem, owing to the KS equation can be utilized for the ground state energy. Briefly stated, the KS equation formalism of density functional theory (DFT) described the motion of electron nuclei, which separated to be two part: the energy of electron
Regarding thermodynamic properties, the Gibbs free energy is considered for the static crystal energy of materials; however, the KS equation formalism of DFT carried out at a temperature of 0 K. The Gibbs free energy therefore reduced to the Enthalpy. This, appearing at first glance to be high potential for high-pressure physics, is actually demonstrated the importance of superconductivity. According to the aforementioned theoretical findings by the KS equation formalism of DFT, resulting the exchange and correlation effects
The extensive studies of electronic structure were initiated chiefly by the KS equation formalism of DFT. In principle, one should note the quasiparticle eigenvalues of occupied states is useful for achieving the electronic band structure, density of sates, phonon dispersion. It is also interesting to note the DFT used mainly strong sides for prediction the metallicity, leading to the prediction of superconducting transition temperature. For considered the superconductivity, the PBE formalism of GGA for exchange-correlation energy is suitable for interpret the metallicity. This implied that the reliable theoretical study has quite a predictive potential, moreover, the GGA-PBE for the exchange-correlation energy give an accurate description of dynamical stability of crystal structure. One of the well-known Bardeen-Cooper-Schrieffer (BCS) theory [5] were already discussed phonon mediated superconductivity, leading to the way to vast both experimental and theoretical studies on high-pressure research. At this stage, using the KS equation formalism of DFT with the GGA-PBE for the exchange-correlation energy were used to have unique features of phonon mediated superconductivity, showing towards the evidence of superconducting materials as well.
There is alternative way to use the KS equation formalism of DFT with the GGA-PBE. It is well known to
High pressure physics is important for structural phase transitions in materials [8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18]. Regarding a crystal structure of materials under high pressure, it can enhance electronic properties of materials [19, 20, 21]. Nowadays, superconductivity is one of the most charming in physical properties. Many materials were predicted to be a superconducting transition temperature (
As mentioned above, a structural prediction is a key factor for achieving a
A curious aspect of a
According to the aforementioned superconductor findings, the characteristic of electronic structure is often attributed to the
Regarding superconductivity in the metals [12, 14, 17, 41], a lattice dynamic is a key factor for consideration a stable structure. In practice, we can achieve the superconducting structure through electron–phonon coupling (EPC) [12, 14, 17, 41]. For example, recent work on LaH10 has shown that the quantum effect is important for the stabilization and destabilization [27]. In fact, both thermodynamically and dynamically structures have to consistent. Generally, the solution of dynamically structure is a harmonic phonon but the case of LaH10 shown that it displayed an anharmonic phonon. This because the EPC exhibited the destabilized structure. Hence, it is worth to note that Sr. is possible to be an anharmonic phonon in the Sr-III structure (the
In considered in the present work, we performed the first-principles calculations, based on the density functional theory, to examine the thermodynamic stability as a function of pressure. The static crystal energy of materials was considered at a temperature of 0 K. The calculation details of stable structure were determined by neglecting the entropy contributions. This is because the calculations were carried out at 0 K, indicating that the ground-state energy can confirm phase stability. Here, the KS equation formalism of DFT with the GGA-PBE for the exchange-correlation energy were used for Li, Sr., Sc, and As. For further details of the energy cutoff for plane waves and the Monkhorst–Pack k-point mesh as well as the DFT software have been described extensively in Refs. [10, 12, 13, 14]. Our works used the AIRSS technique, based on the density functional theory, to predict the novel structure. Following the AIRSS method, we calculated the enthalpies of the phases at any pressure using the simple linear approximation [7]. For each relaxed structure, the structures were simulated to be a non-symmetry and randomly placed in atomic position. During the calculations of the structures, it started to relax from bias until it reaches unbias. The shape is generating by shaking within a reasonable pressure range. It led to higher-symmetry space groups obtained in a search. The AIRSS technique is the approach in the local minima by giving the lowest enthalpy. We have studied the phonon mediated superconductivity by using isotropic Eliashberg theory, as implemented in the quantum espresso (QE) [54, 55]. Following the result of isotropic Eliashberg theory, the Allen-Dynes modify McMillan Equation [56] was used to estimated the superconducting transition temperature.
According to the aforementioned in the introduction, high pressure physics is useful in achieving a novel structure and superconductivity [12, 13, 14, 17, 33, 57, 58, 59]. Li is one of the challenging to find a novel structure [43, 60, 61, 62, 63]. Since it is interesting that there is complex structures were discovered in alkali metal, i.e. sodium (Na) [64], potassium (K) [65, 66, 67, 68], and rubidium (Rb) [69, 70]. Therefore, Li might be expected to possible to be a complex structure at high pressure. For the transitions sequence of Li, we found that the Im-3 m structure transformed into the Fm-3 m structure at pressure 8 GPa. Next, the Fm-3 m structure transformed into the R-3 m structure at pressure 39 GPa. With increasing pressure, the R-3 m structure transformed into the I-43d structure at pressure 44 GPa, then it transformed into C2mb at pressure 73 GPa. On further compression, the C2mb structure transformed into the C2cb structure at 80 GPa. Finally, it transformed into Cmca 120 GPa. It is interesting that there is no found the incommensurate host-guest structure at any pressure among such sequence [43, 60, 61, 62, 63, 71].
Li was observed by optical spectroscopic through diamond anvil cells (DAC) [72]. The solution of the experimental study revealed that there is unknown phase above 50 GPa. Moreover, the characteristic of the high frequency band, i.e. Li-Li vibration, can interpret to be an incommensurate host-guest structure. The commensurate host-guest structure is defined by the different the number of the guest atoms in channels in along the c axis of the host structure, referring to the commensurate value cH/cG, also known as
As mentioned above, the unknown structure can be identified by a random search techniques. The random search technique is the high performance for the prediction of the materials. For elemental Li, the
The relative enthalpy of Li as a function of pressure.
The existence of the incommensurate host-guest structure can be considered from the ELF calculation. As a possible cause of this, one might think of there is the s-p
The electron localization function (ELF) of the host-guest structure of Li is calculated in the (001) atomic plane.
Structural phase transitions in alkaline earth metal under high pressure is interested among the periodic table. Nowadays, there are several works reported a transition sequences [33, 37, 40, 47, 58]. It is interesting to consider that a transition sequences of Ca and Sr. are similar. Ca shown that it exhibited stable structure at high temperature and low pressure through compression [58, 73]. The experimental observations [74] and the theoretical study [58, 73] reported that the simple cubic (sc) structure is stable at room temperature. At this point, the solution of theoretical study revealed that the sc structure is stable by performing a molecular dynamics (MD) calculation [73]. This is because the MD calculation can include a temperature via
In 2009, Ca was reported a novel structure at high pressure that it is the
It is interesting to note that structural phase transitions in Sr. [33, 34, 35, 36, 37, 47]. The remarkable studies revealed that there are discrepancy between the experimental observations [34, 35, 36] and the theoretical studies [33, 37, 47]. The experimental observations were reported that the Fm-3 m structure transformed into the Im-3 m structure, then it transformed into the
In 2012, Sr. was predicted that there is a candidate structure [33]. The relative enthalpy of Sr. was reported that the Cmcm structure is thermodynamically favored over the Fm-3 m structure, the Im-3 m structure, and the
However, the discrepancy between the experimental observations and the theoretical studies were not solved yet. In 2015, the discrepancies in transition sequence between the experimental and theoretical works was explained by Tsuppayakorn-aek et al. [10]. Regarding transition sequence in Sr., it was investigated by the hybrid exchange-correlation functional, i.e. screened exchange local density approximation (sX-LDA) [78, 79, 80]. The stable structure of the
The energy level each electron configuration of isolate Sr.
The remarkable result of the Ref. [10] shown that the
The relative enthalpy of Sr. as a function of pressure by sX-LDA functional.
Regarding the superconductor in the
Structural prediction at high pressure is suitable for identifying unknown structure. Scandium (Sc) is one of d-transition metal, showing that there is an unknown structure (Sc-III) at high pressure [82]. The transition sequences is found that the hcp structure transformed into the host-guest structure [83, 84]. The host-guest structure is thermodynamically stable up to 70 GPa [85]. It is interesting to note that what is the unknown structure beyond the host-guest structure above 70 GPa. In 2018, Tsuppayakorn-aek et al. [14] was identified the unknown structure by
The relative enthalpy of Sc as a fucntion of pressure.
The phonon dispersion of the P41212 structure.
Regarding superconductor of the P41212 structure, it was found to be the metallicity by considering density of state (DOS), leading to investigate the
The
Tsuppayakorn-aek et al. [14] was revealed in that the
Sc is one of the group-IIIB element was shown that structural phase transformation displayed the complex to simple transition. Also, it promoted the superconducting temperature transition to be 8.36 K at 110 GPa, which it is in good agreement with the experimental observation.
The group-V element is one of central interest in superconductor. It is interesting to note that arsenic (As), antimony (Sb), and bismuth (Bi) share the remarkable similarity of structural and property [87, 88]. Structural of the group-V element was reported that As-III, Sb-IV, and Bi-III are the incommensurate host-guest structure [89, 90, 91, 92]. Also, it is worth to note that the Im-3 m structure is thermodynamically stable favored over the incommensurate structure [87, 88].
Tsuppayakorn-aek et al. [12] was explored the high-pressure phase in As. This because it is interesting to find the high-pressure phase, leading to go beyond the Im-3 m structure. The structural prediction was investigated up to 300 GPa. The predicted structure was shown that the body-centered tetragonal (bct) structure with space group I41/acd to be the stable structure at high pressure. The I41/acd structure is energetically and dynamically stable. Also, it is thermodynamically favored over the host-guest structure. The I41/acd structure displayed that it compete with the Im-3 m structure. Moreover, The I41/acd structure and the Im-3 m structure are very closed in enthalpy from 100 to 300 GPa. Also, the I41/acd structure is sub-spacegroup of the the Im-3 m structure. It is possible that the I41/acd structure is coexistence phase with the Im-3 m structure.
Here, the I41/acd structure was discovered to be the metallicity, indicating that it is superconducting phase. As already mentioned, the I41/acd structure and the Im-3 m structure are wonderfully closed in enthalpy. It is interesting to investigate the superconducting phase of both of them. An important and a fundamental of the spectral function led to consider superconductor. In fact, the spectral function is associated with the electron–phonon coupling (EPC). The I41/acd structure was regarded in superconductor, it was found that the estimated
The remarkable results of the
The spectral function of the I41/acd and Im-3 m structures at 150 GPa.
Now, it is worth to note that the I41/acd structure hold the metallic state at 300 GPa. Tsuppayakorn-aek et al. [12] suggested that the I41/acd structure is not favored superconductor above 300 GPa, indicating that it is likely to transform into a normal metallic state (Figure 9). As a possible cause of this, one might think of phase transformation [19]. Moreover, the EPC of the I41/acd structure is very poor characterized by compression. At this point, it is possible that a novel phase might occur above 300 GPa.
The
This project is funded by National Research Council of Thailand (NRCT): (NRCT5-RSA63001-04). This research is partially funded by Chulalongkorn University; Grant for Research. P.T. acknowledge support from the Second Century Fund (C2F), Chulalongkorn University.
The authors declare no conflict of interest.
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Although the horizontal axis wind turbine (HAWT) is the most popular wind turbine, the vertical axis wind turbine (VAWT) with the main advantages of smart design, novel structure, and wind direction independence receives more and more attention in small-scale wind power market. The straight-bladed VAWT (SB-VAWT) is one of the most researched and studied VAWTs. In this chapter, the historical development of the SB-VAWT will be briefly reviewed firstly. Then the aerodynamic models for the turbine design and performance analysis will be introduced. Finally, the types of traditional and new SB-VAWT and their characteristics and main utilizations will be introduced.",book:{id:"7766",slug:"rotating-machinery",title:"Rotating Machinery",fullTitle:"Rotating Machinery"},signatures:"Yan Li",authors:[{id:"277795",title:"Prof.",name:"Yan",middleName:null,surname:"Li",slug:"yan-li",fullName:"Yan Li"}]},{id:"67029",doi:"10.5772/intechopen.83794",title:"Methodology for Abrasive Wear Evaluation in Elevator Stage Centrifugal Pump Impellers",slug:"methodology-for-abrasive-wear-evaluation-in-elevator-stage-centrifugal-pump-impellers",totalDownloads:752,totalCrossrefCites:0,totalDimensionsCites:1,abstract:"The abrasion resistance of the impellers depends on the characteristics of the materials used in their manufacture. 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Though the measurement techniques are fundamentally the same as those used in other applications, the unique features associated with turbomachines place challenges in implementing these techniques. This chapter covers the fundamental working principles of individual measurement technique as well as the highlights of its application in turbomachines.",book:{id:"7766",slug:"rotating-machinery",title:"Rotating Machinery",fullTitle:"Rotating Machinery"},signatures:"Fangyuan Lou",authors:[{id:"275580",title:"Dr.",name:"Fangyuan",middleName:null,surname:"Lou",slug:"fangyuan-lou",fullName:"Fangyuan Lou"}]}],mostDownloadedChaptersLast30Days:[{id:"65843",title:"Straight-Bladed Vertical Axis Wind Turbines: History, Performance, and Applications",slug:"straight-bladed-vertical-axis-wind-turbines-history-performance-and-applications",totalDownloads:2743,totalCrossrefCites:4,totalDimensionsCites:6,abstract:"Wind turbine is a kind of rotating machinery. 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Finally, the types of traditional and new SB-VAWT and their characteristics and main utilizations will be introduced.",book:{id:"7766",slug:"rotating-machinery",title:"Rotating Machinery",fullTitle:"Rotating Machinery"},signatures:"Yan Li",authors:[{id:"277795",title:"Prof.",name:"Yan",middleName:null,surname:"Li",slug:"yan-li",fullName:"Yan Li"}]},{id:"67029",title:"Methodology for Abrasive Wear Evaluation in Elevator Stage Centrifugal Pump Impellers",slug:"methodology-for-abrasive-wear-evaluation-in-elevator-stage-centrifugal-pump-impellers",totalDownloads:752,totalCrossrefCites:0,totalDimensionsCites:1,abstract:"The abrasion resistance of the impellers depends on the characteristics of the materials used in their manufacture. In this work, a methodology is proposed for the evaluation of the abrasive wear of the plates of the centrifugal pump impellers, used in the gross water infrastructure station (GWIS) of sedimentary rivers, due to the sediment load variation and the river fluviometric dimension. In order to determine the wear mode and the relationship of the material-specific wear coefficient (K), due to the sediment concentration, a rotating ball abrasometer test was performed on SAE 8620, gray cast iron (GCI), and nodular cast iron (NCI), used in the manufacture of impellers. As an abrasive suspension, the concentrations of 1, 2, 3, 5, and 10 g L−1 of sediment were used in distilled water. The wear volume as a function of the relative velocity of the mixture in relation to the impeller blades was estimated mathematically. 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In the presented topology, the grid-side converter is replaced by a boost Current Source Inverter (CSI) therefore removing the need for the dc-bus electrolytic capacitors which results in increasing the system lifetime. In the developed topology, the synchronous inductance of the generator is utilized. This facilitates the elimination of the intrinsically required dc-link inductor in the CSI which further contributes to a reduction in the overall system weight and size. The boost CSI is capable of converting a low dc voltage to a higher line-to-line voltage. This results in the implementation of a low-voltage generator for DDWTs. The feasibility of the presented low-voltage generator is investigated through Finite Element (FE) computations. In this chapter, a modified 1.5 MW low-voltage generator for the proposed topology is compared with an existing 1.5 MW Permanent Magnet (PM) synchronous generator for DDWTs. The feasibility of the presented topology of generator-converter for DDWTs is verified through simulations and laboratory tests. Furthermore, the controls developed for the developed wind turbine topology is also presented in this chapter.",book:{id:"7766",slug:"rotating-machinery",title:"Rotating Machinery",fullTitle:"Rotating Machinery"},signatures:"Akanksha Singh",authors:[{id:"276799",title:"Dr.",name:"Akanksha",middleName:null,surname:"Singh",slug:"akanksha-singh",fullName:"Akanksha Singh"}]},{id:"66758",title:"Advance Measurement Techniques in Turbomachines",slug:"advance-measurement-techniques-in-turbomachines",totalDownloads:686,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"This chapter focuses on advanced measurement techniques that have been used in applications of turbomachines including temperature measurements, pressure measurements, velocity measurements, and strain/stress measurements. 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Other positions she has held at the university include Vice-Dean of Master Programs, Vice-Dean of the Degree in Biology and Vice-Dean for Mobility and Enterprise and Engagement at the Faculty of Science (University of Alicante). She received her Bachelor in Biology in 1998 (University of Alicante) and her PhD in 2003 (Biochemistry, University of Alicante). She undertook post-doctoral research at the University of East Anglia (Norwich, U.K. 2004-2005; 2007-2008).\nHer multidisciplinary research focuses on investigating archaea and their potential applications in biotechnology. She has an H-index of 21. She has authored one patent and has published more than 70 indexed papers and around 60 book chapters.\nShe has contributed to more than 150 national and international meetings during the last 15 years. Her research interests include archaea metabolism, enzymes purification and characterization, gene regulation, carotenoids and bioplastics production, antioxidant\ncompounds, waste water treatments, and brines bioremediation.\nRosa María’s other roles include editorial board member for several journals related\nto biochemistry, reviewer for more than 60 journals (biochemistry, molecular biology, biotechnology, chemistry and microbiology) and president of several organizing committees in international meetings related to the N-cycle or respiratory processes.",institutionString:null,institution:{name:"University of Alicante",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"79367",title:"Dr.",name:"Ana Isabel",middleName:null,surname:"Flores",slug:"ana-isabel-flores",fullName:"Ana Isabel Flores",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRpIOQA0/Profile_Picture_1632418099564",institutionString:null,institution:{name:"Hospital Universitario 12 De Octubre",institutionURL:null,country:{name:"Spain"}}},{id:"328234",title:"Ph.D.",name:"Christian",middleName:null,surname:"Palavecino",slug:"christian-palavecino",fullName:"Christian Palavecino",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000030DhEhQAK/Profile_Picture_1628835318625",institutionString:null,institution:{name:"Central University of Chile",institutionURL:null,country:{name:"Chile"}}},{id:"186585",title:"Dr.",name:"Francisco Javier",middleName:null,surname:"Martin-Romero",slug:"francisco-javier-martin-romero",fullName:"Francisco Javier Martin-Romero",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bSB3HQAW/Profile_Picture_1631258137641",institutionString:null,institution:{name:"University of Extremadura",institutionURL:null,country:{name:"Spain"}}}]},{id:"15",title:"Chemical Biology",coverUrl:"https://cdn.intechopen.com/series_topics/covers/15.jpg",editor:{id:"441442",title:"Dr.",name:"Şükrü",middleName:null,surname:"Beydemir",slug:"sukru-beydemir",fullName:"Şükrü Beydemir",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y00003GsUoIQAV/Profile_Picture_1634557147521",biography:"Dr. Şükrü Beydemir obtained a BSc in Chemistry in 1995 from Yüzüncü Yıl University, MSc in Biochemistry in 1998, and PhD in Biochemistry in 2002 from Atatürk University, Turkey. He performed post-doctoral studies at Max-Planck Institute, Germany, and University of Florence, Italy in addition to making several scientific visits abroad. He currently works as a Full Professor of Biochemistry in the Faculty of Pharmacy, Anadolu University, Turkey. Dr. Beydemir has published over a hundred scientific papers spanning protein biochemistry, enzymology and medicinal chemistry, reviews, book chapters and presented several conferences to scientists worldwide. He has received numerous publication awards from various international scientific councils. He serves in the Editorial Board of several international journals. 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He is a member of the Turkish Biochemical Society, American Chemical Society, and German Genetics society. Dr. Ekinci published around ninety scientific papers, reviews and book chapters, and presented several conferences to scientists. He has received numerous publication awards from several scientific councils. 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Novel computational algorithms for image analysis, scene understanding, biometrics, deep learning and their software or hardware implementations for natural and medical images, robotics, VR/AR, applications are some research directions relevant to this topic.",coverUrl:"https://cdn.intechopen.com/series_topics/covers/24.jpg",keywords:"Image Analysis, Scene Understanding, Biometrics, Deep Learning, Software Implementation, Hardware Implementation, Natural Images, Medical Images, Robotics, VR/AR"},{id:"25",title:"Evolutionary Computation",scope:"Evolutionary computing is a paradigm that has grown dramatically in recent years. This group of bio-inspired metaheuristics solves multiple optimization problems by applying the metaphor of natural selection. It so far has solved problems such as resource allocation, routing, schedule planning, and engineering design. Moreover, in the field of machine learning, evolutionary computation has carved out a significant niche both in the generation of learning models and in the automatic design and optimization of hyperparameters in deep learning models. This collection aims to include quality volumes on various topics related to evolutionary algorithms and, alternatively, other metaheuristics of interest inspired by nature. 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It has become a massive part of our daily lives, making predictions based on experience, making this a fascinating area that solves problems that otherwise would not be possible or easy to solve. This topic aims to encompass algorithms that learn from experience (supervised and unsupervised), improve their performance over time and enable machines to make data-driven decisions. It is not limited to any particular applications, but contributions are encouraged from all disciplines.",coverUrl:"https://cdn.intechopen.com/series_topics/covers/26.jpg",keywords:"Intelligent Systems, Machine Learning, Data Science, Data Mining, Artificial Intelligence"},{id:"27",title:"Multi-Agent Systems",scope:"Multi-agent systems are recognised as a state of the art field in Artificial Intelligence studies, which is popular due to the usefulness in facilitation capabilities to handle real-world problem-solving in a distributed fashion. 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The search for this knowledge grows in importance as rapid increases in population and economic development intensify humans’ stresses on ecosystems. Fortunately, rapid increases in multiple scientific areas are advancing our understanding of environmental sciences. Breakthroughs in computing, molecular biology, ecology, and sustainability science are enhancing our ability to utilize environmental sciences to address real-world problems.
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