Abstract
We discuss how various parts of a quantum many-body system exchange energies at thermal equilibrium. To show this, we assume a quantum system is coupled to a many-body environment (at thermal equilibrium with a bigger environment) consisting of a large number of independent and non-interacting quantum harmonic oscillators above a stable ground state. Once the coupling to a large environment is switched on, the system dissipates its energy continuously to the environment until it reaches equilibrium with the latter. We use the Quantum Langevin equation to show such energy exchange at equilibrium. We conclude that different parts of a physical system can exchange energies even at absolute zero temperature.
Keywords
- open systems
- quantum dissipation
- fluctuations
- instantaneous power
- the charged oscillator in a magnetic field
1. Introduction
Isolating a quantum system from its environment is not possible since the coupling energy plays a pivotal role in the low-temperature properties of the system. Moreover, a complete understanding or control of the huge environment is also not feasible. How one will study the properties of the quantum system? A working method is to partition the whole system into two different parts, viz., the
The well-known model of the system-plus-bath approach to open quantum systems stems from classical physics. The underlying phenomenon is the classical Brownian motion where a test system undergoes random motion due to the “kicks” received by the former from the surrounding particles when immersed in a suitable medium (Figure 1). In the classical setting, dissipation is introduced in the system “by hand” by inserting a time-dependent damping term into the equation of motion. However, this naive approach never works in the quantum domain where everything is governed by certain principles like Heisenberg’s uncertainty relation. Moreover, the physical quantities are operators in quantum mechanics and these operators must satisfy certain commutation relations. The damping term inserted in the equation of motion violates the uncertainty principle. The role of fluctuating/random forces is crucial in order to preserve the canonical structure. The knowledge of the details of the processes including dissipation in the system may not be explicitly known so sometimes the dissipation mechanism is globally described by friction, resistance, viscosity, etc. These parameters are introduced in order to compensate for the information loss due to dissipation. In this microscopic system-bath model,
The system plus reservoir (bath) approach to open quantum systems, was originally introduced by many authors [3, 4, 5, 6, 7, 8, 9] and popularized later in the literature by many others [10, 11, 12]. The idea here is to couple a system with a finite degree of freedom (system under study) with a reservoir consisting of an infinite number of independent and non-interacting harmonic oscillators. This model has been discussed in the literature both for harmonic systems [7, 8, 13, 14] and anharmonic systems [15]. Once the coupling is established the reservoir imparts fluctuations in the system coordinates which thereby causes the system under observation to lose energy rapidly (and is irrevocable) to the bath. Because of this fluctuating or random force, the system undergoes Brownian motion. The reservoir is commonly known as a heat bath because the system dissipates its energy continuously and the former distributes this dissipated energy it its various energy-infusing modes. The relevant variables of the heat bath are averaged out later from the larger Hilbert space of the full system-plus-bath setup, to obtain an effective description of the test system alone. The projected dynamics of the test quantum system belonging to the truncated Hilbert space appear dissipative due to the bath-induced decoherence effects. Usually, either a formal path integral approach in the Schrödinger picture [16] or the quantum Langevin equation in the Heisenberg picture [12] is used to eliminate the heat bath degrees of freedom.
2. Theoretical framework
The system-plus-bath model for dissipative quantum systems is described as follows. A quantum system of a finite degree of freedom is coupled to a heat bath consisting of independent and non-interacting harmonic excitations above a stable ground state. The interaction between the quantum system and an individual oscillator of the heat bath is inversely proportional to the total volume
We write the total Hamiltonian for the “full” system as
where the system Hamiltonian is given by
where
The possibility of revival of the initial state after a course of time, since one can pass on to the normal coordinates with the heat bath consisting of harmonic oscillators and
which is bilinear in the system and bath coordinates. The last term (which depends on the coupling constants
This becomes clear if we consider the minimum of the Hamiltonian with respect to the system and environment coordinates. From the requirement
we obtain
Using this result, we determine the minimum of the Hamiltonian with respect to the system coordinate and is given by
The second term in Eq. (4) thus ensures that this minimum is determined by the potential
2.1 Quantum mechanical derivation
We need to look at the reduced equation of motion for the system coordinate. In this section, we derive the quantum Langevin equation for our test system coordinate under the influence of the heat bath induced fluctuation effects. In the quantum domain, all the parameters are quantum variables and are operators. In the literature, Magalinski
From Eq. (9) we obtain the equations of motion for the bath degrees of freedom
and, similarly, the equations of motion for the system degree of freedom are given by
We treat the system coordinate
Inserting Eq. (15) into Eq. (13), we obtain an effective equation of motion for the system coordinate
This is further simplified by partially integrating the second term of the LHS and that yields
where the damping kernel is given by
It can also be expressed alternatively as
The operator-valued random force in Eq. (17) takes the form
The statistical average of this fluctuating force vanishes when the average is taken over the total density matrix of the bath degrees of freedom and the coupling. That is
where
where
This is the fluctuation-dissipation relation. For weak coupling, we seperate the transient term (or the initial slip)
Therefore the generalized Langevin equation takes the form
where
The integration in the forward direction of time in Eq. (25) ensures that it breaks the time reversal invariance explicitly thereby introducing irreversibility in the problem. When taken an average of the Eq. (26) with respect to the canonical classical equilibrium density operator of the unperturbed bath
we obtain
and the unequal time correlation
From Eq. (20), it is clear that the force operator depends explicitly on the initial conditions of the bath positions and momenta and also on an inhomogeneous slip term
Now, we calculate the correlation function of the random force. We may use either
At thermal equilibrium, the second moments of the position and momentum of the bath are calculated and yields
Incorporating Eqs. (31) and (32), the noise correlation in Eq. (30) can be expressed as
It is to be noted that the noise correlation contains an imaginary part. This is due to the fact that
so that the damping kernel takes a form
The most widely used form of the spectral density is of the following form
which is called the
But this is an ideal situation. In real physical situations, the spectral density falls off in the
where
We need
The “tilde” sign is used to denote the Fourier transform of a function throughout the chapter. One can still use the terminology “ohmic damping” even if the Eq. (38) does not hold above a critical frequency, provided all the typical frequencies appearing in the dynamics should be much lower than this critical frequency. In the strict ‘Ohmic’ limit the generalized Langevin equation becomes memoryless and corresponds to the classical Langevin equation.
3. The model and the calculation of instantaneous power
We discussed the theoretical descriptions to understand how a dissipative system behaves when connected to a heat bath at equilibrium. The quantum system was considered to be not in equilibrium prior to the coupling. Once the coupling is established the quantum system continuously transfers its energy to the equilibrium bath and eventually, the system reaches thermal equilibrium (asymptotically) with the heat bath. Thermal equilibrium is said to have reached when a quantum system explores its phase-space fully. From here onwards we discuss the various energy exchanges that happen in a many-body system at equilibrium. The thermal properties of the quantum system can be calculated by assuming that the entire system-plus-bath arrangement is embedded in an infinitely large environment which provides the working temperature. Therefore, from here onwards we denote the quantum system as a subsystem of the bigger bath. Of course, the heat bath with
To proceed further, we need a working model for the subsystem. We choose the charged oscillator in a magnetic field as our quantum subsystem. Hence our system of study is the dissipative charged oscillator in a magnetic field not the uncoupled charged oscillator in a magnetic field. A damped harmonic oscillator was used as a quantum subsystem in the literature [19, 20]. Magnetic field effects in the domain of dissipative quantum physics are of great interest in various phenomena including the quantum Hall effect [21] and superconductivity [22]. Studies on the dissipative charged oscillator in a magnetic field using the system-plus-reservoir approach were originally carried out by Li et al. [23, 24]. This model, later, was used by many others [25, 26, 27, 28, 29, 30] in different contexts (Figure 3).
where
Following the steps given in the previous section, we use the Heisenberg equations of motion from the total Hamiltonian, we obtain the equations of motion for the subsystem and the bath coordinates. Eliminating the bath variables yields the generalized equation for the system coordinate (which is an operator) and that is given by [30]:
This is an initial value equation and has an exact solution as well [30, 31]. Like we saw in the previous section, the spurious initial slip term is here as well. We may define an auxiliary random force
It is necessary to note that the damping
where
The anti-symmetric correlation can also be written as
where
The fluctuation dissipation theorem ensures that the symmetric combination and the commutator structure of the random force are (i) proportional to the friction constant
We now calculate the expectation value of the instantaneous power supplied by the random force. Since we work with operators, we use the symmetric form of the power. The power can be written as
with
where
where
The Laplace transform of the response function is written as
with the Fourier transform
where the dynamical susceptibility is given by
We have, here,
with the solution, which is a stationary process, is given by
We note from the expressions (Eqs. (53) and (57)) that, so long as
Upon comparing Eq. (61) with Eq. (60), we conclude that
Using Eqs. (52) and (62), we write the power as
Since the Langevin equation describes a stationary process the first term is zero because for a stationary process the expectation values of time dependent quantities must be time translational invariant or, in other words, they are constant. This becomes clear when we evaluate the expectation value of an arbitrary time dependent operator
where
We write [30].
where, using (47), we write [30].
After some algebra, we obtain [30].
where
Here
Similarly, the complex conjugate
with the
we obtain [30].
where
Taking the derivatives of Eq. (72) with respect to
Substituting the real part of the velocity autocorrelation into the equation for the power yields
Since the damping
It is possible to write
Since the bracketed term is just the Fourier transform
It is immediately observed that only the even part of the above integral contributes. We know that
This is the instantaneous power supplied by the random force for our particular model and the above expression is positive quantity always.
To check the result, we evaluate the power supplied by the random force at high temperatures (or in the classical case). After some tedious mathematical manipulations we obtain [32].
which in the large cutoff (strict ohmic) limit (
This clearly indicates to us that the rate of work done by the random force on the quantum subsystem is indeed proportional to the damping/dissipation strength
4. Discussion of the result
The full quantum many-body system has an infinite number of degrees of freedom each with its corresponding zero-point oscillations. The full system must be in the ground state at the absolute zero of temperature (
the mean square fluctuations of
In the new variable
Therefore
We need to compute the unequal time correlation functions
Using Eqs. (72) and (74), at
where
In the absence of the magnetic field (
which is nothing but the result for a two dimensional isotropic oscillator. Since
Even for a very weak damping, the mean of the subsystem energy is above its ground state energy and that the fluctuations in this energy do not vanish. This tells us that one part of a physical system in its ground state can and does exchange energy with another part. The formalism we have chosen to show the energy balance is an exact one. We use the Langevin equation to calculate the expectation values after taking the time derivative of the subsystem Hamiltonian.
The exact equation given above is obtained under the strict ohmic limit of the Langevin Equation in Eq. (62). The expectation values appearing above are equal time expectation values and are independent of time as the total physical system is invariant under the time translation. The first term in the above relation is zero. The rest of the equation then describe that the power (RHS) is actually proportional to the dissipation constant
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