Open access peer-reviewed chapter

Low Energy Excitations in Borate Glass

Written By

Seiji Kojima

Submitted: 03 July 2022 Reviewed: 19 July 2022 Published: 20 August 2022

DOI: 10.5772/intechopen.106650

From the Edited Volume

Characteristics and Applications of Boron

Edited by Chatchawal Wongchoosuk

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Abstract

The boson peak in the terahertz range is the low-energy excitations in glasses and disordered crystals. It is related to the excess part of the vibrational density of states. Borate glass is one of the typical network oxide glasses with covalent bonds and belongs to the strong type of glass formers. Alkali metal ions are well-known modifiers of the borate glass network and control various properties. The alkali metal effects are reviewed on basic physical properties such as elastic constants, density, and vibration modes in relation to the variation of structural units in a modified borate glass network. The alkali effect on a boson peak is discussed on the basis of experimental results of neutron inelastic scattering, neutron diffraction, Raman scattering, and heat capacity at low temperatures. The correlation is discussed between the boson peak frequency, the peak temperature of excess heat capacity, and shear modulus. The static and dynamical correlation lengths are also discussed.

Keywords

  • borate glass
  • boson peak
  • FSDP
  • medium range order
  • fragility
  • relaxation
  • excess heat capacity

1. Introduction

2022 is declared a United Nations International Year of Glass (IYOG), which celebrates the heritage and importance of this material in our lives [1]. Glass is technologically very important in industry, and it is clear that modern life would not be possible without glass. Glass is also very interesting in fundamental sciences related to random structure and non-equilibrium state. When a viscous liquid is cooled from a high temperature, it changes into a supercooled liquid state, and upon further cooling, it undergoes a liquid–glass transition into a nonequilibrium glassy state at a glass transition temperature Tg. However, a simple liquid is solidified into an equilibrium crystalline state at its melting temperature, Tm. The temperature dependence of enthalpy is shown in Figure 1 for a liquid (AB), supercooled liquid (BD), glassy (DE), and crystalline (CG) states. The enthalpy of a liquid crosses to that of a crystal at the point, F, which is the Kauzmann temperature, TK [1]. It is a static ideal glass transition temperature and close to the Vogel–Fulcher temperature, the dynamic ideal glass transition temperature, TVF [3, 4], which is lower than the calorimetric Tg. The temperature dependence of the relaxation time, τα, of α-structural relaxation process obeys the following Vogel-Fulcher law and the relaxation time diverges at TVF.

Figure 1.

Temperature dependence of the enthalpy for the liquid (AB), supercooled liquid (BD), glass (DE), and crystalline (CG) states, where Tm, Tg, and TK are the melting, glass transition, and Kauzmann temperatures, respectively [2].

τα=τ0expBTTVFforT>TVFE1

Here, τ0 and B are material-dependent constants, and Tg > TVF. The fragility index m is defined by Eq. (2) using the parameters of Eq. (1). When the intermolecular interactions are weak, m is large and materials are fragile. While the interactions are strong, Eq. (1) goes to the Arrhenius law and materials are strong.

m=dlogταdTgTT=Tg=BTgln101TVF/Tg2E2

In a liquid-glass transition, main three dynamical processes are the α-structural relaxation, fast β-relaxation, and boson peak. These three dynamics are interrelated with each other. According to the mode-coupling theory, the α-relaxation is related to the creation and annihiration of a molecular cage, the fast β-relaxation is related to a relaxation of molecules trapped in their cages. A boson peak is related to a damped librational motion of molecules trapped in their cages [5].

Glycerol (propane-1,2,3-triol, C3H8O3) undergoes a liquid–glass transition at about Tg = 187 K. Glycerol is intermediate with m = 53. The melting temperature is Tm = 291 K, while it does not crystalize even in very slow cooling. It is one of the typical glass-forming materials and well-known cryoprotectants due to its strong glass-forming tendency [6]. The dominant interaction among molecules is the intermolecular hydrogen bond, and the related O-H stretching band showed a remarkable temperature dependence in the vicinity of Tg [7]. By the broadband dielectric spectroscopy, the slowing down of the α- relaxation time towards Tg, which obeys the Vogel-Fulcher law of Eq. (1), was clearly observed in the milli hertz to gigahertz range [8]. For the dynamical properties in the terahertz range, the temperature dependence of low-frequency Raman scattering spectra is shown in Figure 2 [9]. The remarkable changes in Raman spectra were observed in the low-frequency range. In a liquid phase at 328 K, the broad Rayleigh wing appears, and the main contribution of this wing is the α-structural relaxation and fast β-relaxation. In supercooled liquid states at 271 and 228 K, the α-relaxation time becomes slow and the contribution to the Rayleigh wing becomes small. While the fast β-relaxation time does not depend on temperature, and its intensity gradually changes into a boson peak at about 40 cm−1 (=1.2 THz). In a glass state at 96 K, only a boson peak appears. The liquid-phase transition also occurs by the application of hydrostatic pressure at room temperature at Pg = 5 GPa. The boson peak was also observed in the pressure-induced glass state [10]. These dynamical properties on the boson peak, α- and fast β-relaxation processes in Figure 1 are common in liquid-glass transitions of organic and inorganic glass-forming materials.

Figure 2.

Temperature dependence of low-frequency Raman scattering spectra of a liquid-glass transition of glycerol [9].

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2. Borate glass and alkali metal modification

Borate glass is the most contemporary glass and optical material for technological and environmental applications. Pure borate glass undergoes a glass transition at Tg = 260°C. The melting temperature is Tm = 450°C [11]. The character of the temperature dependence of thermal expansibility, surface tension, and viscosity, in the range up to 1400°C, proves that, in the crystalline state and in the vitreous state below about 300°C, boron oxide consists of units held together by “weak” forces and that with increasing temperature this structure changes gradually toward a “strong” one [10]. The borate glass is strong with a fragility index of m = 30. Boron oxide glass has a random three-dimensional network of BO3-triangles with a comparatively high fraction of six-membered rings (boroxol rings). Krogh-Moe discussed structure models for boron oxide glass and molten boron oxide with reference to spectroscopic data, diffraction data, and other physical properties for boron oxide [12]. Borate glasses for scientific and industrial applications were reviewed by Bengisu [13].

Borate glass is modified by alkali metals and physical properties remarkably change by the appearance of various structural units and structural groups. In this chapter, we discuss the dynamical properties of binary alkali metal borate glasses, xM2O(1−x)B2O3 (M = Li, Na, K, Rb, Cs), i.e., lithium borate (LiB), sodium borate (NaB), potassium borate (KB), rubidium borate (RbB), and cesium borate (CsB) glasses. In alkali borate glasses, the physical properties are of special interest, because their alkali content dependences often show maxima and minima termed “borate anomaly” [14]. Their dependence also shows the difference among the kind of alkali metal ions. The dependences of density against the alkali content are classified to two groups. In LiB, NaB, and KB glasses, density shows a moderate increase as the alkali content increases, and they have the nature of covalent packing. While in RbB and CsB glasses, density remarkably increases against the alkali content increases, and they have the nature of ionic packing [15].

Since the physical properties are related to the structure, the variation has been discussed in terms of three kinds of structural units, BØ3, BØ4, and BOØ2, for the alkali content below x = 0.50 as shown in Figure 3 [15, 16]. Here, O and Ø denote the nonbridging and bridging oxygens, respectively. In pure borate glass, the coordination number of boron is three, and units BØ3 are dominant. When borate glass is modified by alkali ions, the units BØ4 and BOØ2 are formed by the chemical reactions of Eqs. (3) and (4). The two units coexist by the disproportion reactions of Eq. (5). As the ionic radius of alkali ions increases, the number of nonbridging oxygen increases and the average coordination number of boron decreases. Consequently, the number of BØ4 decreases, while that of BOØ2 increases.

Figure 3.

Structural units of alkali borate glasses.

M2O+2BØ32M++4E3
M2O+2BØ32M++BOØ2E4
4BOØ2E5

For the detailed discussion on the variation of structure, several kinds of superstructural units or structural groups such as boroxol ring, pentaborate, and diborate groups were considered [17].

For the analysis on the variation of physical properties, we introduce the quantity Vm(B) and Vm (O), which denote the volume of glass containing one a mole of boron and oxygen, respectively.

VmB=MxM2O1xB2O32ρ1xE6
VmO=MxM2O1xB2O3ρ32xE7

Where ρ is density, MxM2O1xB2O3 is the molar mass of the entity xM2O1xB2O3. Figure 4 shows alkali content dependences of volumes of glass containing one mole of (a) boron and (b) oxygen atoms [15].

Figure 4.

Alkali content dependences of volumes of glass containing one mole of (a) boron, and (b) oxygen atoms.

Both Vm(B) and Vm(O) increase with respect to alkali content in LiB, NaB, and KB glasses, while they decrease in RbB and CsB glasses. At a given alkali content, the packing of boron and oxygen in the glass structure becomes more compact as the ionic radius of alkali ion increases. The boron atoms are packed most compactly at x = 0.20 for LiB, x = 0.08 for NaB, x = 0.02 for KB, x = 0.01 for RbB, and none for CsB glasses.

The remarkable changes occur in the response to the stress such as their pressure derivatives. We discuss the derivatives of the molar volumes Vm(B) and Vm (O) with respect to pressure.

ddpVmB=1VdVdPVmB=κVmB,E8
ddpVmO=1VdVdPVmO=κVmO,E9

whereκ=1VdVdP, is the compressibility. The κVm(B) represents the effect of boron atoms on the elasticity, and the κVm(O) represents the effect of oxygen atoms on the elasticity. Figure 5 shows the alkali content dependences of κVm(B) and κVm(O) [15]. Both κVm(B) and κVm (O) at a given alkali content decrease as the ionic radius of alkali ions increases. In LiB and NaB glasses with covalent packing, κVm(B) and κVm(O) monotonically decrease. However, in KB, RbB, and CsB glasses with ionic packing, the concave and convex shapes appear. We discuss these dependences by the division into following three alkali content ranges.

  1. 0≤x≤0.07: The conversion of BØ3 → BØ4 in Eq. (3) is dominant and κVm(B) and κVm(O) decrease. The glass becomes incompressible with no alkali dependence.

  2. 0.07≤x≤0.2: The conversion of BØ3 → BØ4 continues. However, in RbB and CsB glasses, the formation of BØ3 → BOØ2 in Eq. (4) also occurs. The κVm(B) and κVm(O) increase by the presence of the small amount of M+ BOØ2 units. At a given alkali content, this conversion decreases as the ionic radius of alkali ion decreases.

  3. 0.2≤x≤0.3: The conversion of BØ3 → BØ4 does not occur. The volume of M+ BOØ2 unit is larger than that of M+4 unit and easily deformed by stress. Thus, the increase of small amount of M+ BOØ2 units causes the glass incompressible, and at x = 0.3 RbB and CsB glasses have the most compact structure.

  4. 0.3≤x≤0.4: By the formation of the large amount of M+ BOØ2 units, the glass becomes more compressible and elastically softer.

Figure 5.

Alkali content dependences of the derivatives of the molar volumes (a) κVm(B), and (b) κVm(O) of alkali borate glasses [15].

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3. Elastic properties of alkali borate glasses

Since the low-energy excitations in glass is closely related to the acoustic modes, the sound velocity was measured by the ultrasonic pulse-echo overlap method at a frequency of 10 MHz and at 298 K [15, 16]. The sound velocities of longitudinal acoustic (LA) and transverse acoustic (TA) modes of the binary alkali metal borate glasses, xM2O(1−x)B2O3 (M = Li, Na, K, Rb, Cs) are shown in Figure 6a and b, respectively [17].These dependences have a similarity with those of the reciprocal plots of κVm(B) and (b) κVm(O) in Figure 5a and b reflecting the variation of structural units by alkali ions.

Figure 6.

Alkali content dependences of velocity of (a) longitudinal, and (b) transverse acoustic modes.

Using the LA and TA velocities, the following elastic moduli were calculated.

Shear modulus:G=ρVT2E10
Longitudinal modulus:L=ρVL2E11
Poissonsratio:σ=12VL22VT2VL2VT2E12
Youngsmodulus:E=2G1+σE13
Bulk modulus:B=L43GE14
Compressibility:κ=1/BE15

Figure 7a shows the alkali content dependences of Young’s modulus. In the Young’s modulus of LiB and KB glasses, the monotonic increase was observed. However, In that of KB, RbB, and CsB glasses concave and convex shapes were observed. Such alkali dependence of Young’s modulus is similar to that of κVm(B) in Figure 5a.

Figure 7.

Alkali content dependences of (a) Young’s modulus, E, and (b) the ratio between bulk and shear moduli, B/G.

The plot of bulk versus shear moduli is helpful in distinguishing ductile from brittle behavior beyond the elastic limit. When B/G>>1 (σ=0.5), materials are extremely incompressible. For ceramics, B/G≈1. 7(σ≈0.25). For polymers, B/G≈2.7(σ≈0.33). When B/G<<1 (σ = −1), materials are extremely compressible. The B/G is also related to the boson peak intensity and the fragility index [18]. The ratio between bulk and shear modulus is plotted in Figure 7b. The B/G is between 1.8 and 2.9. The B /G shows the concave and convex shapes were observed in all the alkali borate glasses. These dependences are explained by the division of four alkali content ranges. (a) 0≤x≤0.07: The BØ3 changes into BØ4 only and does not change into BOØ2. (b) 0.07≤x≤0.20: The BØ3 changes into both BØ4 and BOØ2. The effect of BOØ2is predominant over that of BØ4. (c) 0.20≤x≤0.30: The BØ3 changes into both BØ4 and BOØ2. The effect of BØ4is predominant over that of BOØ2. (d) 0.30≤x≤0.40: The BØ3 changes only into BOØ2 without the further formation of BØ4.

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4. Boson peaks of alkali borate glasses

In glasses the universal features of their thermal properties at low temperatures have been observed. The heat capacity shows an excess part as the deviation from the Debye T3 law and the thermal conductivity has a plateau at around 10 K [19]. These universal behaviors are caused by the anomalous phonon dispersion in the terahertz frequency (THz) range. In the inelastic scattering spectra, the peak of g(E)/E2 has been observed, where g(E) and E= are the vibrational density of states (VDoS) and energy, respectively. The origin of a peak is the low-energy excess part of VDoS over the Debye model defined by g(E)/E2. This THz peak is called the boson peak [20]. In the measurement of heat capacity Cp at low temperatures, a bump in Cp/T3 at around 10 K is called a thermal boson peak. The plateau of the thermal conductivity indicates the strongly scattered of phonons above the boson peak frequency. It indicates that phonons meet the transverse Ioffe–Regel (IR) limit [21] around the boson peak.

The microscopic origin of a boson peak has been discussed by various theoretical models, such as (1) the structure and elastic constants heterogeneity [22, 23, 24]; (2) soft potential model [24, 25, 26]; (3) the resonant vibration of medium range order [27]; (4) mode-coupling theory on density fluctuations of arrested glass structures [28]; (5) broadening of the lowest van Hove singularity of the transverse phonon branch [29]; (6) the phonon-saddle transition in the energy landscape [30]; (7) the random first-order transition theory (RFOT) [31]; (8) anharmonic effects [32], and (9) recent numerical calculations reported that the boson peak originates from quasi-localized vibrations of string-like dynamical defects [33]. However, this situation has remained quite controversial because of a lack of distinct evidence.

The Stokes-component of Raman scattering intensity I(ν) is related to the imaginary part of Raman susceptibility χ″(ν).

Iν=I0χνnν+1,nν=1expkBT1E16

where nν is the Bose-Einstein factor and I0 is a constant which depends on the experimental condition. For the discussion of the boson peak in a Raman spectrum, the following quantity is plotted. Here, Cν=να (α=0∼2) is the light-vibration coupling constant and its frequency dependence shows a monotonic increase [20].

χνν=Iννnν+1Cνgνν2E17

Figure 8a shows the boson peak spectra of lithium borate glasses observed by Raman scattering using a triple-grating spectrometer with the additive dispersion. The boson peak frequency νBP = 26 cm−1 at x = 0.02 increases up to 72 cm−1 at x = 0.26 as the lithium content increases and the increase is related to the increase of transverse sound velocity shown in Figure 5b [34]. In LiB glasses, the fragility index m increases from 30 at x=0.00 to 62 at x=0.28. In strong glass, the boson peak intensity is high, while the intensity of the fast β-relaxation is weak. As the fragility index m increases, the boson peak intensity becomes weak and that of the fast β-relaxation increases. As shown in Figure 8a the boson peak intensity decreases as the Li content increases.

Figure 8.

(a) Reduced Raman spectra of boson peaks of lithium borate glasses observed by Raman scattering, and (b) Scaled boson peak spectra.

It is interesting to check that the boson peak spectra of inelastic neutron scattering, and Raman scattering are scaled by their peak positions and scattering intensity. In LiB glasses, it is found that the scaled boson peak spectra have a universal shape as shown in Figure 8b. The universal scaling of boson peaks indicates that the way of the distribution of VDoS basically remains the same, even though the glass structures drastically change by the alkali metal modification.

The alkali dependence of boson peak spectra at x=0.14 is shown in Figure 9. The origin of the boson peak in a pure borate glass was attributed to the coherent libration of several boroxol rings based on the study of the hyper-Raman scattering. As the alkali content increases, these boroxol rings change into other boron-oxygen structural units. As the ionic radius of alkali ions increases, the boson peak frequency decreases reflecting the difference in the modification of glass structure by alkali ions. Since the large Cs ions with the low charge density only slightly changes the boron-oxygen network structure. However, the small Li ions with the high charge density cause shrinking of the boron-oxygen network structure [35, 36]. By application of high pressure, it was reported that the boson peak frequency significantly increases up to 68 cm−1 at 4 GPa by shrinking of the boron-oxygen network structure [37]. The alkali content dependence of boson peaks of LiB glasses has the similarity with the densified borate glasses.

Figure 9.

Reduced Raman spectra of boson peaks of alkali borate glasses (x=0.14).

The boson peak frequency in a Raman spectrum includes the influence of the light-vibration coupling constant C(ν) as shown in Eq. (17). However, the boson peak in a neutron inelastic spectrum enables the direct observation of a boson peak frequency or energy even in the S/N ratio of scattering intensity is much lower than that of Raman scattering. Figure 10 shows the alkali dependence of boson peak spectra of alkali borate glasses at x=0.22 observed by cold neutron inelastic scattering. Neutron inelastic scattering measurements of all the alkali borate glasses were carried out at 25°C (far below the Tg) using a direct geometry chopper-type ToF spectrometer AGNES belonging to the Institute for Solid State Physics, University of Tokyo [38]. The neutron boson peak energy also decreases as the ionic radius of alkali ions increases. As the charge density decreases with the increase in ionic radius, the contraction of the boron–oxygen structural units become weaker and the boson peak energy may decrease.

Figure 10.

Boson peaks of alkali borate glasses at x=0.22 observed by cold neutron inelastic scattering [37].

If we assume that the boson peak is connected to the nano-heterogeneity of the shear modulus [27]. In this approach, a dynamic length scale, LBP, is given by

LBP=Vt/2πνBP,E18

where Vt is the transverse sound velocity, and νBP is the boson peak frequency. The LBP corresponds to a medium-range scale important for characterization of structure correlations in glasses. The good correlation between LBP and ionic radius of alkali ions is found as shown in Figure 11. It is found that LBP is proportional to the ionic radius of alkali ions. It indicates that the dynamic length of a boson peak may relate to the size of alkali ion in the void of boron-oxygen network structure.

Figure 11.

The correlation between LBP and ionic radius of alkali ions in alkali borate glasses.

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5. Excess heat capacity at low temperatures of alkali borate glasses

The excess heat capacity has been observed as the deviation from the Debye T3 law at low temperatures. The broad peak in a Cp/T3 vs. T plot is the thermal boson peak, where Cp is the heat capacity at a constant pressure. It is related to the non-Debye excess heat capacity. The alkali content dependence of Cp/T3 in lithium borate glasses is shown in Figure 12 [35]. In the pure borate glass, the peak of Cp/T3 was observed at the temperature, Tm = 5.8 K [39]. As the lithium content increases, the peak value decreases and the peak temperature increases. Such a behavior of the peak value and the peak temperature of thermal boson peaks is similar to the peak intensity and peak frequency of boson peaks observed by Raman scattering and neutron inelastic scattering, respectively.

Figure 12.

Temperature dependence of Cp/T3 of lithium borate glasses at low temperatures.

The temperature dependence of Cp/T3 of alkali borate glasses with x=0.22 below 50 K is shown in Figure 13 [35]. The peak temperature of CsB glass is close to that of pure borate glass. However, as the ionic radius of alkali metal ions decreases, the peak temperature markedly increases. The peak temperature of LiB glass is Tm=14.6 K, which is about three times of a pure borate glass.

Figure 13.

(a) Temperature dependence of Cp/T3 of alkali borate glasses normalized by Debye contribution at low temperatures, and (b) Scaled thermal boson peaks of alkali borate glasses.

For all the alkali borate glasses, the universal nature of the master plot in Cp/T3 vs. T is also observed as shown in Figure 13b. This universal nature is the same as that of boson peaks observed by Raman scattering and neutron inelastic scattering. This fact indicates that the distribution of the low-energy excess VDoS remains the same for all the alkali modification.

On the discussion on the origin of a boson peak, the correlation between the transverse acoustic mode and a boson peak is very interesting. According to the numerical simulation, the equality of the boson peak frequency to the Ioffe–Regel limit for “transverse” phonons was reported. The boson peak energy is proportional to the shear modulus [40]. Since the peak temperature of a thermal boson peak is proportional to the boson peak frequency, the correlation is examined between the peak temperature of Cp/T3, boson peak energy, and shear modulus. The good correlation is found between these quantities as shown in Figure 14. This fact indicates that the origin of a boson peak is closely related to the Ioffe-Regal limit for transverse acoustic waves.

Figure 14.

Correlation between the peak temperature of Cp/T3, boson peak frequency, and shear modulus.

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6. Medium range order of alkali borate glasses

In contrast to crystals with translational symmetry, glasses have disordered structure about local atomic arrangements. However, the structure of glasses has the medium range order (MRO) on a few nanometers’ length scale [41, 42]. The MRO in liquid and glassy states is characterized by the first sharp diffraction peak (FSDP). The FSDP is observed by neutron and X-ray diffraction experiments in the static structure factor S(Q), where Q is the modulus of the wave vector [43]. The peak position Q1 and the peak width ΔQ of a FSDP correspond to a periodic ordering with a periodicity of 2π/Q1 and a static structure correlation length Lfsdp given by

Lfsdp=/ΔQE19

respectively. It was reported that the FSDP intensity and peak position can be quantified using the characteristic void distribution function, defined in terms of average void size, void distance, and void density [44].

The static structure factor S(Q) of alkali borate glasses determined by the neutron scattering is shown in Figure 15 [38]. As the ionic radius of alkali ions decreases, the position Q1 of a FSDP increases. Using the peak width of a FSDP, the static structure correlation lengths Lfsdp are determined. The correlation between the static structure correlation length and ionic radius of alkali ions is plotted in Figure 16a. It is found that as the ionic radius increases, the correlation length also increases. The MRO may be related to the local structure in the vicinity of an alkali ion in voids.

Figure 15.

Static structure factor S(Q) of alkali borate glasses observed by neutron diffraction. Q1 is the position of a FSDP.

Figure 16.

(a) Correlation between the static structure correlation length of FSDP and the ionic radius of alkali ions of alkali borate glasses, and (b) Correlation between the static structure correlation lengths of a FSDP and the dynamic correlation length of a boson peak.

The correlation of various glasses between the boson peak frequency and the width of a FSDP was reported by Sokolov et al. [45]. Since the boson peak frequency is related to the dynamical correlation length LBP, the relation between the static structure correlation length and the dynamical correlation length is plotted in Figure 16b. The good correlation between the dynamical correlation length LBP and the static structure correlation length Lfsdp indicates that the boson peak is the vibration related to the MRO defined by the width of a FSDP.

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7. Conclusions

Borate glass is most contemporary glasses and optical materials for technological and environmental applications. Borate glass is one of the typical network oxide glasses with covalent bonds and belongs to the strong type of glass formers. Alkali metal ions are well known modifiers of the borate glass network and control various properties. Basic physical properties such as elastic constants, density, and vibration modes are reviewed in relation with the variation of structural units in modified borate glass network.

The boson peak in the terahertz range is the low-energy excitations in glasses and disordered crystals. It is related to the excess part of vibrational density of states. The alkali metal effects on the boson peak are discussed on the basis of experimental results of neutron inelastic scattering, neutron diffraction, Raman scattering, low-temperature heat capacity, and ultrasonic measurements. For all the alkali borate glasses, the universal nature of the master plots in boson peak spectra and Cp/T3 vs. T curve are observed. This fact indicates that the distribution of the low-energy excess VDoS remains the same for all the alkali modification.

The good correlation is found between the peak temperature of Cp/T3, boson peak frequency, and shear modulus. this fact indicates that the origin of a boson peak is closely related to the Ioffe-Regal limit for transverse acoustic waves. The static and dynamical correlation lengths show also the good correlation. As the ionic radius of alkali ions increase, both correlation lengths also increase. This fact suggests that the boson peak vibration is related to the medium range order in the boron-oxygen network near the voids filled by alkali ions.

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Acknowledgments

The author is thankful to Prof. M. Kodama, Prof. S. A. Feller, Prof. M. Affatigato, Prof. V. N. Novikov, Prof. M. Maczka, Prof. J.H. Ko, Prof. O. Yamamuro, Prof. H. Anwar, and Dr. Y. Matsuda for their collaboration and fruitful discussions. The author is also thankful to M. Kawashima, Y. Fukawa, K. Kaneda, S. Aramomi, and T. Sunaoshi for the experiments.

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Written By

Seiji Kojima

Submitted: 03 July 2022 Reviewed: 19 July 2022 Published: 20 August 2022