Open access peer-reviewed chapter

Mathematical Relationship Based on Experimental Data, for Corrosion Inhibition Mechanism of Phenolic Compounds Obtained from Echium italicum L.

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Boudiba Sameh, Hanini Karima, Boudiba Louiza, Saouane Izzeddine and Benahmed Merzoug

Submitted: June 29th, 2021 Reviewed: July 23rd, 2021 Published: August 18th, 2021

DOI: 10.5772/intechopen.99616

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Abstract

We highlight in this chapter the corrosion protection using phenolic extract. The building of mathematical models using experimental results obtained from the investigation of phenolic molecules or fractions extracted from Echium italicum L., used as corrosion inhibitors is one of the new trends in the study of steel protection. The evaluation of the corrosion inhibition of carbon steel (API 5 L-X60) in a solution 1 M of hydrochloric acid was performed using gravimetric method, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The predicted mathematical relationships between the corrosion rate and the inhibitory efficiency in the presence of the butanolic extract of Echium italicum L. (BEEI), when increasing temperature proved a good agreement between experimental and mathematical studies.

Keywords

  • mathematical
  • relationship
  • Echium italicum L.
  • phenolic compounds
  • corrosion inhibition

1. Introduction

Secondary metabolites, derived from natural plants, of which polyphenols constitute the grand part, have a wide range of activities [1]: biological (antibacterial, antioxidant [2, 3], anti-inflammatory [4], antidiabetic [5], anti-carcinogenic [6], etc.) and chemical (in connection with their chelating power with metals and their reducing properties generated by the hydroxyl functions of their aromatic rings). These molecules are used in several fields: as preservative food additives (constituting an alternative to the use of synthetic ones, such as buthylhydroxyanisol (BHA) and buthylhydroxytoluene (BHT), which have carcinogenic effects [7]; as flavoring in cosmetology [8]; as additives in electrolytic baths during the metals electrodeposition [9, 10, 11] and as corrosion inhibitors [12, 13, 14].

Even today, these molecules have not revealed all their secrets. Our research aims to understand the power of polyphenols in the field of metal protection against corrosion.

The Echium italicum L.is an annual herbaceous plant, available in most of Europe, Asia [15, 16, 17, 18], and Africa [19]. This plant widespread in Tebessa area (Algeria) [20], is used traditionally for several infections [15, 17, 18]. Furthermore, the Echium italicum L.contains different polyphenolic compounds, known as effective additives in electroplating baths [16, 17, 21].

We continue in this investigation to focus on the effectof plant extract obtained from the aerial parts of Echium italicum L.,on the corrosion inhibition of carbon steel (CS, API 5 L-X60) against 1 M hydrochloric acid solution, using weight loss, potentiodynamic polarization and electrochemical impedance measurements.

On the other hand, and in order to better understand the underlying reaction mechanisms of the corrosion phenomena to choose which inhibitors to use to combat it, the prediction of the implementation behavior of effective corrosion control measures is paramount. For this purpose, mathematical simulation was used as a powerful method [12, 22] to evaluate the kinetic parameters of both corrosion rate and inhibition efficiency.

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2. Corrosion

Corrosion, from the Latin “corrodere” (which means “to attack”) is one of the harmful global problems affecting several industrial fields such as maritime installations, petroleum, chemical, civil engineering, electrical, nuclear, sanitary, and other industries, without forgetting the environmental impact [23, 24, 25].

The corrosion of metals and their transformation into various compounds cause an alteration in their appearance, either on the surface or in-depth, thus reducing their effectiveness (parts breakage, the toxicity of the resulting metal oxides, etc.).

Several factors come into play in this phenomenon. They can be chemical (water, oxygen, salinity, acidity, etc.), physical (temperature, pressure, etc.), or biological (marine biological deposit of plants or animals, bacteria, etc.).

This phenomenon has Several definitions:

  • The ISO 8044 standard defines corrosion as a physicochemical process, which leads to the deterioration of a material (metal or alloy), or degrades its functional properties following its interaction with an aggressive environment, making it unsuitable for supposed application [26].

  • The National Association of Corrosion Engineers (NACE) outlines this phenomenon as the deterioration of a material, usually a metal, generated by its interaction with its environment [27].

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3. Corrosion protection

Corrosion control is the set of measures that can protect metallic materials from the harmful effects of the aggressive environment. Many of these methods were reported in the literature [28, 29]. The first protection is the choice of pure metal or alloys resistant to these attacks [30].

After designing the equipment using the appropriate material, it must be protected against corrosion should be considered to avoid many problems and ensure a certain service life. For this, the preferred outlet must comply with environmental protection requirements and allow the recycling or disposal of the various components at the end of their use by applying the following choices [31]:

  • Prevention by an adapted shape of the parts;

  • Protection by coatings;

  • Electrochemical protection;

  • Protection by corrosion inhibitors.

All these solutions have drawbacks of efficiency over time, cost and environmental pollution, which is why other alternatives are exploited in research for the benefit of sustainable development that respects the environment. To this end, there have recently been some new alternatives products both environmentally friendly and less expensive as the use of inhibitors from naturals origin [32].

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4. Corrosion inhibitors

Inhibitors have been successfully applied to prevent corrosion and damage in many and varied technical fields for a long time. These products have been frequently studied because they provide simple solutions to protect metals from corrosion in the aquatic environment. With the originality of being the only means of interference of the corrosive environment with steel, these compounds reduce the rate of corrosion of metals when added in appropriate amounts, without apparent change [9, 14].

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5. Materials and methods

5.1 Materials

The vegetable material was collected during May 2017 from the East-North of Tebessa (Algeria). The extraction and purification of the n-butanolic extract obtained from Echium italicumL. (BEEI) were performed as reported in litérature [10, 33, 34].

The tested aggressive medium was a chlorhydric acid solution (1 M), and the investigated inhibitors were freshly prepared solutions of BEEI with different concentrations (from 100 to 500 ppm).

Before each mesurements, the substrates were abraded using emery paper with different grades (from 200 to 2000), cleaned with distilled water and then acetone. The used substrates were carbon steels with the following composition: (by weight%): C (0.26%), Mn (1.35%), P (0.03%), S (0.03%) and Fe (98.33%). Weight loss measurements were performed with specimens with dimensions of 1 cm x 1 cm x 1 cm. For the electrochemical experiments, only an exposed surface of 1 cm2 was used. All measurements were conducted in an aerated area.

5.2 Methods

5.2.1 Electrochemical measurements

All electrochemical measurements were accomplished through a Voltalab (PGZ 301) potentiostat and controlled by software model (Voltamaster 4) under given conditions. The electrochemical characteristics of CS sample in uninhibited and inhibited solutions were realized in conventional three-electrode cell: CS as working electrode, platinum electrode as counter electrode and saturated calomel electrode (SCE) as a reference.

5.2.1.1 Potentiodynamic polarization

Potentiodynamic polarization curves were recorded after total immersion of the working electrode (CS) in 1 M HCl solution containing different concentrations of the tested inhibitor by changing the electrode potential from +250 to −250 mV vs. open circuit potential (OCP) with a scan rate of 1 mV/s. The linear Tafel segments of anodic and cathodic curves were extrapolated to corrosion potential Ecorrto get corrosion current densities icorr. The ηw%at different concentrations of BEEI were calculated using the formula (1) [35]:

ηp%=icorr0icorricorr0×100E1

where icorr0and icorrare the corrosion current density in the absence and presence of BEEI, respectively.

5.2.1.2 Electrochemical impedance spectroscopy

Electrochemical impedance spectroscopy (EIS) experiments were conducted in the frequency range of 100 kHz–10 mHz with a signal amplitude perturbation of 10 mV at open circuit potential (OCP) measured during 60 min of immersion in the tested solutions. The percentage of the inhibition efficiency ηw%was calculated using the polarization resistance by the following relationship [36]:

ηR=RpRp0Rp×100E2

where Rp0and Rpare polarization resistances without and with inhibitor addition, respectively.

5.2.2 Gravimetric method

For these measurements, the prepared and pre-weighed CS substrates were totally immersed in beakers containing 1 M HCl without and with the addition of diverse concentrations of BEEI. The substrates were taken out after two hours, washed with 20% NaOH solution containing 200 g/l of zinc dust with a brush, rinsed severally with bidistilled water, dried with acetone, washed again with bidistilled water, dried and reweighted [34]. From the weight loss data, the corrosion rate CRwas calculated according to Eq. (3) [37]:

CR=wA.tE3

where wis the average weight loss, Ais the total area of one CS sample, and tis the immersion time. The inhibition efficiency ηwcan be calculated by Eq. (4) [36]:

ηw%=CR0CRCR0×100E4

where CR0and CRare the values of corrosion rate in absence and presence of BEEI respectively.

5.2.3 Mathematical regression

A mathematical model is used to correlate variables by fitting an equation to experimental data. When using two variables, one of them is considered as explanatory, whereas the other is considered as a dependent. The linear regression of yis given as a function of xin the equation y=ax+bwhich minimize the value ab[38]:

ab=i=1i=Nyiaxi+b2E5

where aand bcan be calculated as follow:

a=i=1i=NxiX¯yiY¯i=1i=NxiX¯2E6

and

b=Y¯aX.¯E7
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6. Results and discussion

6.1 Electrochemical impedance spectroscopy

EIS was performed to estimate CS corrosion behavior in the presence of 500 ppm of BEEI at 298 K.

The inspection of Nyquist plots presented in Figure 1 shows only one depressed capacitive imperfect semicircle at the higher frequency range, indicating that the corrosion reaction is controlled by the charges transfer process on a heterogeneous and irregular steel surface electrode [39, 40, 41].

Figure 1.

Nyquist spectra for carbon steel in HCl solution in the absence and presence of 500 ppm of BEEI.

The electrical equivalent circuit model (EEC) adjusted by fitting from the resulting impedance diagrams for Nyquist plots is reported in literature [12].

From Table 1, a noticeable increase in Rct values and a decrease in Cdl at 500 ppm of BEEI due to the formation of protective diapers on the CS surface are observed. This phenomenon can be explained by the higher adsorption of phytochemical components above CS upon BEEI addition which ultimately reduces the charge transfer between the CS surface and the corrosion medium [42]. Consequently, we noticed that the ηRreached 74% at 500 mg.L−1.

C(mg/l)Rct(Ωcm2)Qx 105(Ω1Sncm−2)nCdl(μFcm−2)ηR(%)
Blank232.221.000.89142.5
500889.909.110.8047.8773.82

Table 1.

EIS parameters of CS in HCl solution in the absence and presence of 500 ppm of BEEI.

6.2 Potentiodynamic polarization measurement

To further evaluate the efficiency of the expected green inhibitor, the polarization technique was studied due to its excellent reliability. Figure 2 shows the parameters given in Table 2 and extracted from the CS electrode polarization curves for 500 ppm BEEI in the presence of 1 M HCl solution, at 293 K.

Figure 2.

Potentiodynamic polarization curves for carbon steel in HCl solution with and without inhibitor addition.

C (mg/l)EcorrmVicorr(mA cm−2)βa(mV dec−1)βc(mV dec−1)ηp%
Blank470.60.086172.6117.9
500483.90.021675.8134.274.91

Table 2.

Potentiodynamic polarizations parameters of CS in HCl solution in the absence and presence of 500 ppm of BEEI.

As can be seen in this figure, at 500 ppm of BEEI, the cathodic and anodic corrosion current densities will decrease. This comportment can be attributed to the adsorption of the inhibitor at the carbon steel interface [43] by reducing the dissolution of steel and delaying the hydrogen evolution reaction [44].

In our study, the maximum displacement in Ecorr value for the optimum concentration of BEEI was −13.3 mV (< 85 mV), which exhibits that the inhibitor acts as a mixed type [43, 45]. The highest inhibition efficiency was 75% at a concentration of 500 ppm.

6.3 Weight loss measurements

To study the behavior of the steel protection in the presence of an aggressive solution, the weight loss method was used. Based on this approach, the CR, the ηwand the degree of surface coverage θwere calculated and are very useful for discussing adsorption properties.

From Table 3, it can be observed that the CRvalues reduced progressively with increasing BEEI concentration, reaching 0.0334 g cm−2 h−1 for 500 ppm at 293 K. This result indicates that the addition of this inhibitor slows down the dissolution process of the CS. There was also a CRincrease with increasing temperature.

This behavior can be attributed to the removal of some adsorbed molecules contained in the BEEI, through thermal energy-induced mechanical vibration [46]. As the inhibition efficiency is derived from the weight-loss method, the highest inhibition efficiency was 72.88% for 500 ppm of BEEI at 293 K.

6.3.1 Thermodynamic parameters

The good fitting for experimental data of gravimetric measurements at all measured temperatures supports the applicability of Freundlich adsorption model expressed by the subsequent Equation [47, 48]:

logθ=logKads+αlogCE8

where,

Kadsis the adsorption constant which could be taken as a measure of the strength of the adsorption forces between the inhibitor molecules and the metal surface [49].

αis the parameter taking into account the heterogeneity of the intermolecular interactions in the adsorbed layer and the steel surface.

Kadsrepresent the values calculated from the intercept lines of logθversus Log C.

The standard adsorption free enthalpy Gads°can be calculated from the equation given below [50, 51]:

Gads°=RTlnCH2O×KadsE9

where

Ris the gas constant,

Tis the absolute temperature, CH2Ois the water concentration expressed in mg L−1 with an approximate value of 106. [52].

The standard adsorption enthalpy Hads°can be calculated by the relationship (10) [53]:

lnKads=Hads°RT+IE10

where

Iis the integration constant.

The Hads°values were calculated from the intercept lines of lnKadsversus 1/T.

The standard adsorption entropy Sads°was calculated using the equation below:

Sads°=Hads°Gads°TE11

The obtained results for Kads, Gads°, Hads°and Sads°are presented in Table 4.

From Table 4, we noticed the following:

  1. A decrease in Kads values with increasing temperatures, indicating that the adsorbent molecules contained in the BEEI adsorbed from the metal surface [54].

  2. Negative Gads°values point out the spontaneity of the adsorption process. Moreover, the results obtained for Gads°adsorption values below −40 kJmol−1 confirm the physisorption mechanism [55].

  3. The negative sign of Hads°indicates that the BEEI adsorption process on the steel surface is exothermic [56, 57].

  4. The positive sign of Sads°, indicates that the adsorption process is accompanied by increased disorder due to the substitution of water molecules during BEEI adsorption [58, 59, 60].

Temperature (K)C(ppm)CR(g cm−2 h−1)θηw%
293Blank0.1232
5000.03340.728872.88
303Blank0.1681
5000.05480.674067.40
313Blank0.1716
5000.06820.602560.25

Table 3.

Corrosion parameters obtained from weight loss measurements of CS in 1 M HCl with different concentrations of BEEI at different temperatures.

TKKads(L mg−1)Gads°KJmol1Hads°KJmol1Sads°Jmol1K1
2930.9809−25.44−22.2210.99
3030.9968−25.9912.44
3130.9968−25.6510.96

Table 4.

Thermodynamic parameters of the adsorption of BEEI on the CS in 1 M HCl at different temperatures.

6.3.2 Activation parameters of the corrosion process

The Arrhenius-type process was used to calculate the activation energies Eabetween the corrosion rate of CS in acidic solution, from the equation given below [61]:

lnCR=EaRT+lnDE12

Where

Eais the apparent activation energy of the CS dissolution.

Dis the Arrhenius pre-exponential factor.

The logarithm of the CRversus 1/Tcan be branded by straight lines. The activation energy values were calculated from Arrhenius plots lnCRversus 1/T and registered in Table 5.

C(ppm)Ea(kJ mol−1)Ha(kJ mol−1)Sa(J mol−1 K−1)
Blank12.7510.23−3.2822
50027.3224.80- 2.7202

Table 5.

Activation parametersfor carbon steel in HCl with 500 ppm of BEEI.

For the evaluation of the enthalpy Haas well as the standard adsorption entropy Saof the corrosion activation process, the alternative formulation of Arrhenius equation was employed [62, 63]:

lnCRT=lnRhNa+SaRHaRTE13

where

his the Planck’s constant,

Nais the Avogadro’s number.

The plot of lnCR/Tvs. 1/Tgave a straight line with a slope of Ha/Rand an intercept of ln(R/hNa+Sa/R), from which the values of Saand Hawere calculated and registered in Table 5.

The activation energy values were higher in the presence of 500 ppm of BEEI than in its absence, which proved the adsorption of BEEI molecules on the substrate by electrostatic bonds (physisorption) [62, 64]. The positive signs of Haindicate the endothermic nature of the dissolution process [65].

The BEEI adsorption process is accompanied by a decrease in its entropy. This can be explained that before the adsorption of the extract on the steel, the disorder degree of the inhibitor molecules is high, but when the molecules are adsorbed on the surface of the substrate, there is a decrease the in the disorder (i.e. a decrease in the entropy) [66].

6.4 Mathematical regression

This investigation focused on how could the used inhibitor (BEEI) decrease the corrosion rate CRand offer a good inhibition efficiency ηw.

For that, a mathematical method was employed to predict the influence of a variable xwhich is the BEEI concentration as a function of different variables yiwhich are CRand ηwfor 293 K, 303 K, and 313 K [51, 67]. The building of a mathematical model that can correlate between three variables (CR, ηw, and C) was also highlighted.

Based on experimental data of the CS behavior in the presence of BEEI at various temperatures, a linear regression relation between CRand ηw, was performed.

As reported by Khadom et al. [67], when the correlation coefficient of the correlation is < 0.30, the correlation is weak and when this coefficient is between 0.50 and 0.70, the correlation is important, while if it is >0.90, the correlation will be strong.

According to the plots shown in Figure 3, a decrease in the CR with a raise in the ηw, when adding BEEI with various concentrations at different temperatures was distinguished, and based on correlation coefficients rCR2and rηw2given in Table 6, the concordance between the experimental and the simulated results is very strong.

Figure 3.

Mathematical relationship between corrosion rate and inhibitory efficiency at different temperatures.

Temperature (K)rCR2rηw2
2930.97650.9625
3030.98860.9775
3130.99700.9890

Table 6.

Correlation coefficients evaluated from linear regression of CRand ηwfor CS with and without BEEI solution.

As we can see from the obtained results, the correlation coefficients were almost >0.90 for considered temperatures. However, as the temperature rises the correlation coefficients go up. The Eqs. (12)(14) construe the mathematical expression obtained for the relationship between the CRand the ηwat different temperatures.

This mathematical model exhibits a decrease in the corrosion rate when inhibition efficiency rises, with reducing in temperature. These results indicate the powerful concordance between experimental and predicted results.

T = 293 K

ηw=99.9849811.470.CRE14

T = 303 K

ηw=99.9977594.869.CRE15

T = 213 K

ηw=99.9910582.713.CRE16
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7. Conclusion

In order to estimate the multiple benefits of phenolic compounds, a phenolic Echium italicumL. extract was evaluated as an efficient corrosion inhibitor. The subsequent conclusions can be pointed out:

  • A concordance between the employed evaluating methods, suggesting that the phenolic extract could serve as an effective corrosion inhibitor for CS against corrosion.

  • Depending on the gravimetric measurements, the investigated phenolic extract was spontaneously adsorbed on the CS surface following a physical model according to Freundlich isotherm.

  • The prediction of the phenolic extract effect of as a corrosion inhibitor by the mathematical study was in good agreement with the experimental results, which confirms that the corrosion rate is affected by the temperature and the inhibitor concentration.

  • The generated mathematical model shows a decrease in the corrosion rate with the increase of inhibition efficiency. These results indicate a strong agreement between experimental and mathematical results.

  • The Echium italicumL. extract has prooved to be an effective corrosion inhibitor, and hence the phenolics can be useful on various existing industries to prevent losses caused by corrosion of steel without harming the environment.

For a more extensive valuation of phenolic products, many perspectives are envisaged, namely:

  • Evaluate the synergy between phenolic extracts extracted from different plants looking for a better efficiency.

  • The study can be extended to analyze the effect of these phenolic compounds in other corrosive media and on other types of steel.

  • Perform a theoretical simulation to highlight the active compound (s) responsible for this inhibition.

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Acknowledgments

The authors gratefully acknowledge the support of Tebessa University. We would like also to acknowledge the IntechOpen and the author service manager Dolores Kuzelj for their supports.

References

  1. 1. N. Miceliet al., "Comparative study of the phenolic profile, antioxidant and antimicrobial activities of leaf extracts of five Juniperus L.(Cupressaceae) taxa growing in Turkey," vol. 34, no. 11, pp. 1636-1641, 2020
  2. 2. A. N. Tamfu, O. Ceylan, G. C. Fru, M. Ozturk, M. E. Duru, and F. J. M. p. Shaheen, "Antibiofilm, antiquorum sensing and antioxidant activity of secondary metabolites from seeds ofAnnona senegalensis, Persoon," vol. 144, p. 104191, 2020
  3. 3. A. N. Tamfu, O. Ceylan, S. Kucukaydin, and M. E. J. L. Duru, "HPLC-DAD phenolic profiles, antibiofilm, anti-quorum sensing and enzyme inhibitory potentials ofCamellia sinensis(L.) O. Kuntze andCurcuma longaL," vol. 133, p. 110150, 2020
  4. 4. Y. Soltani, M. A. Bouzidi, F. Toumi, and A. J. P. Benyamina, "Activités anti-inflammatoire et analgésique de l’extrait hydroalcoolique des baies de Juniperus phoenicea L," vol. 17, no. 3, pp. 129-133, 2019
  5. 5. H. Keskes, K. Mnafgui, K. Hamden, M. Damak, A. El Feki, and N. J. A. P. j. o. t. b. Allouche, "In vitro anti-diabetic, anti-obesity and antioxidant proprieties ofJuniperus phoeniceaL. leaves from Tunisia," vol. 4, pp. S649-S655, 2014
  6. 6. S. Jennewein, R. J. A. m. Croteau, and biotechnology, "Taxol: biosynthesis, molecular genetics, and biotechnological applications," vol. 57, no. 1, pp. 13-19, 2001
  7. 7. R. Japón-Luján, P. Janeiro, M. a. D. J. J. o. A. Luque de Castro, and F. Chemistry, "Solid− Liquid Transfer of Biophenols from Olive Leaves for the Enrichment of Edible Oils by a Dynamic Ultrasound-Assisted Approach," vol. 56, no. 16, pp. 7231-7235, 2008
  8. 8. D. J. K. S. S. Atmanto, "Influence of the Addition of the Essential Oil of Cinnamon (Cinnamomum burmanii) in Soap Against Skin Care," pp. 587–595-587–595, 2019
  9. 9. K. Hanini, S. Boudiba, and M. Benahmed, "Reducing Emerging Contaminants Ensuing from Rusting of Marine Steel Installations," inEmerging Contaminants: IntechOpen, 2021
  10. 10. K. Hanini, M. Benahmed, S. Boudiba, I. Selatnia, H. Laouer, S. Akkal, "Influence of different polyphenol extracts of Taxus baccata on the corrosion process and their effect as additives in electrodeposition," vol. 14, p. 100189, 2019
  11. 11. B. Sameh, B. Baya, B. Louiza, H. Soraya, B. Hatem, and B. J. J. o. t. T. I. o. C. E. Merzoug, "Corrosion inhibition impact ofPyracantha coccineaM. Roem extracts and their use as additives in zinc electroplating: Coating morphology, electrochemical and weight loss investigations," vol. 121, pp. 337-348, 2021
  12. 12. S. Boudiba, K. Hanini, I. Selatnia, A. Saouane, S. Hioun, and Benahmed, "Experimental, theoretical and mathematical studies ofEchium italicumL. extract as a corrosion inhibitor for carbon steel in acidic medium,"Materials Research Expressvol. 6, no. 8, p. 086546, 2019
  13. 13. M. Benahmed, I. Selatnia, N. Djeddi, S. Akkal, and H. J. C. A. Laouer, "Adsorption and corrosion inhibition properties of butanolic extract of Elaeoselinum thapsioides and its synergistic effect with Reutera lutea (Desf.) Maires (Apiaceae) on A283 carbon steel in hydrochloric acid solution," vol. 3, no. 1, pp. 251-261, 2020
  14. 14. K. Haniniet al., "Experimental and Theoretical Studies of Taxus Baccata Alkaloid Extract as Eco-Friendly Anticorrosion for Carbon Steel in Acidic Solution," vol. 57, no. 1, pp. 222-233, 2021
  15. 15. A. De Natale and A. J. J. o. E. Pollio, "Plants species in the folk medicine of Montecorvino Rovella (inland Campania, Italy)," vol. 109, no. 2, pp. 295-303, 2007
  16. 16. K. Morteza-Semnani, M. Saeedi, and M. J. J. o. E. O. B. P. Akbarzadeh, "Chemical composition and antimicrobial activity of essential oil ofEchium italicumL," vol. 12, no. 5, pp. 557-561, 2009
  17. 17. A. E. J. I. J. o. P. Al-Snafi, "Medicinal plants possessed antioxidant and free radical scavenging effects (part 3)-A review," vol. 7, no. 4, pp. 48-62, 2017
  18. 18. N. Eruygur, G. Yilmaz, and O. J. F. J. o. P. S. Üstün, "Analgesic and antioxidant activity of some Echium species wild growing in Turkey," vol. 37, no. 3, p. 151, 2012
  19. 19. E. Retief and A. J. B. Van Wyk, "The genus Echium (Boraginaceae) in southern Africa," vol. 28, no. 2, pp. 167-177, 1998
  20. 20. P. Quezel and S. Santa, "Nouvelle flore de l'Algérie et des régions désertiques méridionales," 1963
  21. 21. I. Bošković, D. Đukić, P. Mašković, and L. J. B. C. C. Mandić, "Phytochemical composition and biological activity ofEchium italicumL. plant extracts," vol. 49, pp. 836-845, 2017
  22. 22. M. Merriman,A text book on the Method of Least Squares. Wiley, 1909
  23. 23. R. Idouhliet al., "Understanding the corrosion inhibition effectiveness usingSenecio anteuphorbiumL. fraction for steel in acidic media," vol. 1228, p. 129478, 2021
  24. 24. I. Bouali, "Étude d'inhibiteurs de corrosion métallique à base d'orthophosphates de zirconium lamellaires fonctionnalisés: synthèse, caractérisations et applications," Université de Lorraine; Université Caddi Ayyad, Marrakech (Maroc), 2018
  25. 25. D. Landolt,Corrosion and surface chemistry of metals. CRC press, 2007
  26. 26. P. DILLMANN and N. Delphine, "Corrosion des objets archéologiques ferreux," 2012
  27. 27. P. R. Roberge,Handbook of corrosion engineering. McGraw-Hill Education, 2019
  28. 28. B. Normand,Prévention et lutte contre la corrosion: Une approche scientifique et technique. PPUR presses polytechniques, 2004
  29. 29. M. J. M. Roche and Techniques, "Protection cathodique des ouvrages en milieu marin Normalisation et certification du personnel pour une protection cathodique plus efficace," vol. 101, no. 5-6, p. N18, 2013
  30. 30. Y.-P. Hsiehet al., "Complete corrosion inhibition through graphene defect passivation," vol. 8, no. 1, pp. 443-448, 2014
  31. 31. C. G. Dariva and A. F. J. D. i. c. p. Galio, "Corrosion inhibitors–principles, mechanisms and applications," vol. 16, pp. 365-378, 2014
  32. 32. C. Verma, E. E. Ebenso, I. Bahadur, and M. J. J. o. M. L. Quraishi, "An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media," vol. 266, pp. 577-590, 2018
  33. 33. S. Akkal, S. Louaar, M. Benahmed, H. Laouer, and H. Duddeck, "A new isoflavone glycoside from the aerial parts of Retama sphaerocarpa," Chemistry of natural compounds, vol. 46, no. 5, pp. 719-721, 2010
  34. 34. N. Obi-Egbedi, K. Essien, I. Obot, and E. Ebenso, "1, 2-Diaminoanthraquinone as corrosion inhibitor for mild steel in hydrochloric acid: weight loss and quantum chemical study," Int. J. Electrochem. Sci, vol. 6, pp. 913-930, 2011
  35. 35. M. Benahmed, I. Selatnia, A. Achouri, H. Laouer, N. Gherraf, and S. Akkal, "Steel corrosion inhibition by Bupleurum lancifolium (Apiaceae) extract in acid solution," Transactions of the Indian Institute of Metals, vol. 68, no. 3, pp. 393-401, 2015
  36. 36. A. Kalla, M. Benahmed, N. Djeddi, S. Akkal, and H. Laouer, "Corrosion inhibition of carbon steel in 1 MH 2 SO 4 solution by Thapsia villosa extracts," International Journal of Industrial Chemistry, vol. 7, no. 4, pp. 419-429, 2016
  37. 37. N. Djeddi, M. Benahmed, S. Akkal, H. Laouer, E. Makhloufi, and N. Gherraf, "Study on methylene dichloride and butanolic extracts of Reutera lutea (Desf.) Maire (Apiaceae) as effective corrosion inhibitions for carbon steel in HCl solution," Research on Chemical Intermediates, vol. 41, no. 7, pp. 4595-4616, 2015
  38. 38. M. Mansfield,Text Book on the Method of Least Squares. Hardpress Limited, 2013
  39. 39. M. H. Hussin, M. J. J. M. C. Kassim, and Physics, "The corrosion inhibition and adsorption behavior of Uncaria gambir extract on mild steel in 1 M HCl," vol. 125, no. 3, pp. 461-468, 2011
  40. 40. M. Behpour, S. Ghoreishi, M. Khayatkashani, N. J. M. C. Soltani, and Physics, "Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract ofPunica granatumpeel and main constituents," vol. 131, no. 3, pp. 621-633, 2012
  41. 41. S. Deng and X. J. C. S. Li, "Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions," vol. 55, pp. 407-415, 2012
  42. 42. S. Nofrizalet al., "Elucidation of the corrosion inhibition of mild steel in 1.0 M HCl by catechin monomers from commercial green tea extracts," vol. 43, no. 4, pp. 1382-1393, 2012
  43. 43. I. Ahamad, R. Prasad, and M. Quraishi, "Adsorption and inhibitive properties of some new Mannich bases of Isatin derivatives on corrosion of mild steel in acidic media," Corrosion Science, vol. 52, no. 4, pp. 1472-1481, 2010
  44. 44. V. V. Torreset al., "Inhibitory action of aqueous coffee ground extracts on the corrosion of carbon steel in HCl solution," Corrosion Science, vol. 53, no. 7, pp. 2385-2392, 2011
  45. 45. A. Satapathy, G. Gunasekaran, S. Sahoo, K. Amit, and P. Rodrigues, "Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution," Corrosion science, vol. 51, no. 12, pp. 2848-2856, 2009
  46. 46. N. Patel, S. Jauhariand, G. Mehta, S. Al-Deyab, I. Warad, and B. J. I. J. E. S. Hammouti, "Mild steel corrosion inhibition by various plant extracts in 0.5 M sulphuric acid," vol. 8, no. 2635, p. 2655, 2013
  47. 47. X. Li, S. Deng, and H. Fu, "Inhibition of the corrosion of steel in HCl, H2SO4 solutions by bamboo leaf extract," Corrosion Science, vol. 62, pp. 163-175, 2012
  48. 48. M. Bobina, A. Kellenberger, J.-P. Millet, C. Muntean, and N. Vaszilcsin, "Corrosion resistance of carbon steel in weak acid solutions in the presence of l-histidine as corrosion inhibitor," Corrosion Science, vol. 69, pp. 389-395, 2013
  49. 49. M. A. Amin, "Weight loss, polarization, electrochemical impedance spectroscopy, SEM and EDX studies of the corrosion inhibition of copper in aerated NaCl solutions," Journal of applied electrochemistry, vol. 36, no. 2, pp. 215-226, 2006
  50. 50. A. El Bribri, M. Tabyaoui, B. Tabyaoui, H. El Attari, and F. Bentiss, "The use of Euphorbia falcata extract as eco-friendly corrosion inhibitor of carbon steel in hydrochloric acid solution," Materials Chemistry and Physics, vol. 141, no. 1, pp. 240-247, 2013
  51. 51. A. S. Yaro, A. A. Khadom, and R. K. Wael, "Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid," Alexandria Engineering Journal, vol. 52, no. 1, pp. 129-135, 2013
  52. 52. S. Deng and X. Li, "Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions," Corrosion Science, vol. 55, pp. 407-415, 2012
  53. 53. L. Li, X. Zhang, J. Lei, J. He, S. Zhang, and F. Pan, "Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel," Corrosion Science, vol. 63, pp. 82-90, 2012
  54. 54. N. Djeddi, M. Benahmed, S. Akkal, H. Laouer, E. Makhloufi, and N. J. R. o. C. I. Gherraf, "Study on methylene dichloride and butanolic extracts of Reutera lutea (Desf.) Maire (Apiaceae) as effective corrosion inhibitions for carbon steel in HCl solution," vol. 41, no. 7, pp. 4595-4616, 2015
  55. 55. C. M. Goulart, A. Esteves-Souza, C. A. Martinez-Huitle, C. J. F. Rodrigues, M. A. M. Maciel, and A. J. C. S. Echevarria, "Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors," vol. 67, pp. 281-291, 2013
  56. 56. A. Ostovari, S. Hoseinieh, M. Peikari, S. Shadizadeh, and S. J. C. S. Hashemi, "Corrosion inhibition of mild steel in 1 M HCl solution by henna extract: A comparative study of the inhibition by henna and its constituents (Lawsone, Gallic acid, α-d-Glucose and Tannic acid)," vol. 51, no. 9, pp. 1935-1949, 2009
  57. 57. M. Deyab and S. J. J. o. t. T. I. o. C. E. Abd El-Rehim, "Effect of succinic acid on carbon steel corrosion in produced water of crude oil," vol. 45, no. 3, pp. 1065-1072, 2014
  58. 58. H. Zarrok, A. Zarrouk, B. Hammouti, R. Salghi, C. Jama, and F. J. C. S. Bentiss, "Corrosion control of carbon steel in phosphoric acid by purpald–weight loss, electrochemical and XPS studies," vol. 64, pp. 243-252, 2012
  59. 59. S. Pournazari, M. H. Moayed, and M. J. C. s. Rahimizadeh, "In situ inhibitor synthesis from admixture of benzaldehyde and benzene-1, 2-diamine along with FeCl3 catalyst as a new corrosion inhibitor for mild steel in 0.5 M sulphuric acid," vol. 71, pp. 20-31, 2013
  60. 60. M. Benahmed, N. Djeddi, S. Akkal, and H. J. I. J. o. I. C. Laouar, "Saccocalyx satureioides as corrosion inhibitor for carbon steel in acid solution," vol. 7, no. 2, pp. 109-120, 2016
  61. 61. M. Lebrini, F. Robert, A. Lecante, and C. Roos, "Corrosion inhibition of C38 steel in 1 M hydrochloric acid medium by alkaloids extract from Oxandra asbeckii plant," Corrosion Science, vol. 53, no. 2, pp. 687-695, 2011
  62. 62. K. Tebbji, N. Faska, A. Tounsi, H. Oudda, M. Benkaddour, and B. Hammouti, "The effect of some lactones as inhibitors for the corrosion of mild steel in 1 M hydrochloric acid," Materials Chemistry and Physics, vol. 106, no. 2-3, pp. 260-267, 2007
  63. 63. M. Behpour, S. Ghoreishi, M. Khayatkashani, and N. Soltani, "Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents," Materials Chemistry and Physics, vol. 131, no. 3, pp. 621-633, 2012
  64. 64. K. Tebbjiet al., "The effect of some lactones as inhibitors for the corrosion of mild steel in 1 M hydrochloric acid," vol. 106, no. 2-3, pp. 260-267, 2007
  65. 65. G. Hodaifa, J. Ochando-Pulido, S. B. D. Alami, S. Rodriguez-Vives, and A. Martinez-Ferez, "Kinetic and thermodynamic parameters of iron adsorption onto olive stones," Industrial crops and products, vol. 49, pp. 526-534, 2013
  66. 66. Z. Zhang, N. Tian, X. Huang, W. Shang, and L. J. R. a. Wu, "Synergistic inhibition of carbon steel corrosion in 0.5 M HCl solution by indigo carmine and some cationic organic compounds: experimental and theoretical studies," vol. 6, no. 27, pp. 22250-22268, 2016
  67. 67. A. A. Khadom, A. N. Abd, and N. A. Ahmed, "Xanthiumstrumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies,"south african journal of chemical engineering,vol. 25, pp. 13-21, 2018

Written By

Boudiba Sameh, Hanini Karima, Boudiba Louiza, Saouane Izzeddine and Benahmed Merzoug

Submitted: June 29th, 2021 Reviewed: July 23rd, 2021 Published: August 18th, 2021