Abstract
Swelling elastomers are a new breed of advanced polymers, and found increasing use in drilling of difficult oil and gas wells. It is important to know how an elastomer will behave under a given set of well conditions, especially after the initial quick-swell period. Good design depends on appropriate material selection. Results are presented in this chapter from experimental and numerical studies conducted to analyze how compressive and bulk behavior of actual oilfield elastomers changes due to swelling. Six key attributes of swelling elastomers needed for design improvement and performance analysis of elastomer seals are discussed: four mechanical properties (elastic modulus E, bulk modulus K, shear modulus G, and Poisson’s ratio ν), and two polymer structure characteristics (cross-link chain density NC, and average molecular weight MC). These parameters were experimentally determined before and after various stages of swelling for two different swelling elastomers being currently used by the regional petroleum industry, in low and high salinity brines. To strengthen the experimental results, and to be able to forecast for other elastomer materials and well conditions, tests were also simulated using the commercial FEM package ABAQUS, using the best available hyperelastic material models.
Keywords
- swelling elastomer
- compressive loading
- mechanical testing
- elastomer structure
1. Introduction
As discussed earlier, swelling elastomers are a new breed of advanced polymers [1]. Over the last two decades, they have found increasing use in drilling of difficult oil and gas wells, remediation of damaged wells, and renewal of production from abandoned wells [2, 3, 4, 5, 6, 7, 8]. It is important to know whether an elastomer type or a certain seal design will function properly and reliably under a given set of well conditions [9]. Investigation of the swelling and mechanical behavior of these elastomers is essential in resolving application and design issues. When an elastomer seal is positioned in the well, environmental conditions initiate the swelling. The material may continue to swell throughout its life, though very slowly after the initial quick-swell period [10, 11]. Swelling results in changes in its mechanical properties and sealing response. If elastomer seals are put into use without thoroughly studying these changes, seal failure can happen in certain cases, causing loss of time, money, and other resources. Rework is not only time consuming but at times not possible at all. Failures may even cause the production from the well to stop.
One critical aspect of good design is appropriate material selection. This cannot be done without reliable knowledge of how the material will behave when exposed to different loads, temperatures, and other environmental conditions. As swelling elastomers are basically used as sealing elements in petroleum applications, and as seals are mostly under compressive loading, investigation of the mechanical behavior of elastomers under compression is very important. Contemporary elastomer seal design is usually based on laboratory tests and trial-and-error method. Testing under all possible combinations of field parameters (elastomer material, water salinity, oil type, temperature, pressure, etc) in the laboratory is almost impossible, especially for extended swelling periods. Numerical modeling and simulation of seal design, validated by experimental results, may provide answers for possible scenarios, which cannot be attempted experimentally. Numerical simulations can shorten the lead time for development of robust sealing applications in difficult or new oil and gas wells, offering an accurate and cost effective alternative to extensive testing.
Results are presented in this chapter from experimental and numerical studies conducted to analyze how compressive and bulk behavior of actual oilfield elastomers changes due to swelling. Six key attributes of swelling elastomers needed for design improvement and performance analysis of elastomer seals are discussed: four mechanical properties (elastic modulus
2. Mathematical background
As stated above, this chapter describes the effect of swelling on mechanical properties (macro-level behavior) and polymer structure (micro-level characteristics) of two elastomers under compressive loading. Brief theoretical background and inter-relationships of these quantities are presented in this section.
2.1 Macroscopic behavior: isotropic relationships
The elastic behavior of any isotropic material is completely described by Hooke’s law [14]:
where
Figure 1 shows a body under a state of pure shear and its Mohr circle representation giving the principal stresses.
We can use Hooke’s law Eq. (1) to find the principal strains:
Shear strain
Comparing Eqs. (2) and (5), shear modulus becomes:
Bulk modulus (
For a body undergoing linear strains, it can be easily shown that [15].
Combining Eqs. (7) and (8), volume dilatation can be expressed as
Comparing this result with Eq. (1), and simplifying, we get
Recalling the definition of hydrostatic pressure
Once the values of
2.2 Structural behavior
Chemical and physical structure of a polymer is modified at different stages of swelling. The resulting changes in structural behavior affect the performance of swelling elastomer seals. It is important, therefore, to understand the factors that can affect swelling elastomer structure and, hence, its properties. Current section discusses the method of determining major structural properties.
2.2.1 Chain density
For any rubber-like material, network strands are formed both by cross-linking and by molecular entanglement. As the degree of cross-linking increases, the cross-link chain density increases, making the elastomer more rigid, thus giving higher values of stiffness and shear modulus
where
2.2.2 Number average chain molecular weight
Length of the network chain decreases due to an increase in the degree of cross-linking. In any polymer, chain density is closely related to the average molecular weight, and this property can also be used to explain the mechanics of swelling [17]. Multiplying and dividing Eq. (12) by Avogadro’s number
If
Combining the definition of chain density (
Comparing this result with Eq. (13), we can get the expression for the number average chain molecular weight
Once the value of shear modulus
3. Experimental work
Various researchers have investigated the behavior of rubber-like materials under compression [16], but not for swelling elastomers. The main objective of experiments described here is to obtain swelling behavior, stress–strain, and pressure-volumetric strain curves. Curve fitting on the linear portions of these graphs determines the values of elastic and bulk moduli. These curves are also used to extract material coefficients for the hyperelastic models used for numerical simulations.
Samples of two different water-swelling elastomers were allowed to swell for a one month period in saline water of 6,000 ppm (0.6%) and 120,000 ppm (12%) concentrations at 50°C; actual field conditions in regional oil-wells. Samples were placed in sealable glass jars containing the swelling medium and identified by mnemonic code names. Jars were placed inside servo-controlled ovens maintained at 50°C temperature throughout the thirty days test period. Compression and bulk tests were carried out on disc samples before swelling and after 1, 2, 4, 7, 10, 16, 23, and 30 days of swelling. To ensure repeatability and consistency, all reported values are average of readings from three samples.
3.1 Swelling tests
Cutting of disc samples and preparation of salt solutions has been described in detail in Chapter 3. Procedure for swelling tests is given below.
3.1.1 Test procedure
Samples were placed in sealable glass jars containing proper swelling medium and identified by mnemonic codenames. Jars were placed inside servo-controlled ovens maintained at 50°C temperature throughout the 30-day test period. Volume, thickness, mass, and hardness of each sample was measured before swelling and after different days of swelling. Test setup has been described in Chapter 3. Mass was measured using a digital balance. Volume measurements were done by a specially constructed (in-house) graduated beaker-cylinder arrangement based on the displacement method. Thickness measurements were carried out using digital Vernier calipers. Hardness readings were taken using a scale-A durometer.
3.2 Compression testing
Compression tests are performed in accordance with ASTM-D575 standard test method [18] as described in detail in Chapter 6.
3.3 Bulk testing
No standard is available for bulk testing of elastomers. A special test rig was therefore designed and fabricated in-house for bulk experiments; Figure 2. The rig was designed in such a way that under compressive loading the specimen is constrained to move only in the axial direction and radial expansion is not allowed. To match with compression testing, load is applied at the rate of 12 mm/min until the specimen fails. Force-deformation results are recorded and later converted into pressure-volumetric strain data.
4. Numerical investigation
Just as in experiments, simulations are run before swelling and after every swelling period. Using the commercial finite element package ABAQUS, swelling elastomer specimen is modeled using 8-noded linear brick element with reduced integration (C3D8R). As mentioned in Chapter 3, Ogden hyper-elastic material model with second strain energy potential [19] is used for all simulations since it gives the best results [20]. Coefficients for the Ogden model are extracted from the experimental stress–strain data.
4.1 Simulation of compression test
Simulations for compression experiments are discussed in detail in Chapter 3. Stress–strain curves from these simulations are used here to determine the values of Young’s modulus. Simulations are conducted before swelling and after each swelling period (total one month period) under both salinity conditions, and for both materials. Specimen geometry before and after deformations is shown in Figure 3.
4.2 Simulation of bulk test
For bulk testing, elastomer disc is still under compression but restricted from any transverse deformations. Only the top surface can move downward (z-axis) under the compressive load as shown in the test setup in Figure 2. Simulation results are used to plot graphs of pressure against volumetric strain, for determination of bulk modulus through curve fitting. Deformed and undeformed specimens from bulk test simulation are shown in Figure 4.
5. Results and discussion: experimental
Results of the experimental investigation (mechanical and structural response of the elastomer to swelling) are discussed in this section. Variations in properties (volume, thickness, hardness, and density) due to swelling are discussed first. Later, results from compression and bulk experiments are presented and analyzed.
5.1 Swelling behavior
Effect of swelling on volume, thickness, hardness, and density of the two types of elastomer samples under different salinities is discussed below.
5.1.1 Volume change
Figure 5 shows the change in volume against days of swelling in 6000 ppm (0.6%) and 120,000 ppm (12%) brine solutions at 50°C for materials
5.1.2 Thickness change
Figure 6 shows thickness change against swelling time for both materials. Fast swelling nature of the elastomer (materials
5.1.3 Hardness change
Hardness keeps on decreasing as the elastomer swells more. Figure 7 summarizes the change in hardness as samples for both materials swell in 0.6% and 12% salt solutions, at 50°C. It is interesting to observe that within the first week of swelling, hardness drastically drops down, and then remains almost constant. Material
In all of the above graphs, the overall trend is the same; very high swelling rate in the beginning, then a slow gradual change. This leads to a sharp initial drop in hardness, followed by almost no change for longer swelling periods. The slight fluctuating pattern may have roots in the nature of the swelling process [11, 21, 22]. Salt is one of the constituents of any swelling elastomer. When exposed to saline water, some salt can enter into the elastomer material (together with absorbed water), while some salt can break away from the elastomer and go into the salt solution. Rather than a consistent increase, this two-way salt transport cause slight fluctuations in the amount of swelling. Another important factor in swelling of such elastomers is the density of cross-link chains. Salt addition and breakaway can produce breaking and later re-forming of cross-link chains, causing increase or decrease of swelling at a particular time. As both these mechanisms are dependent on salt transport, fluctuation is more significant in higher concentration brine. After some time, a sort of equilibrium is reached, inflow and outflow of salt almost balancing out, and swelling starts to show a near steady-state behavior.
5.1.4 Density change
Density drops down considerably in the first few days for both materials and salinities, as can be seen in Figure 8. With more swelling, it increases a little before gradually dropping down to almost the same value as at the end of the first week. Due to the two-way water and salt transport during swelling of these elastomers, both volume and mass change at different rates; thus the slightly zigzag pattern of density variation.
5.2 Behavior under compressive loading
As an example, Figure 9 shows 3-sample compressive stress–strain graphs for materials
Three-sample pressure-volumetric strain graphs for both elastomer types under high salinity after 23 days of swelling are shown in Figure 10. Though the overall behavior is still nonlinear, as expected for rubbers and elastomers, there is a significant linear portion. Bulk modulus is determined by fitting a straight line to the linear portion of these pressure-volumetric strain curves.
5.2.1 Mechanical and structural properties
At small strains (up to 10%), elastomers exhibit almost a linear stress–strain relationship and behave like other elastic materials [23]. Hence, for the extraction of Young’s modulus, curve fitting is done on the initial 10% portion of the compressive stress–strain curve. For the determination of bulk modulus, some initial pressure-strain data is discarded before curve fitting. Elastomer disc does not touch the walls of the test cylinder at all points at the beginning of the test. As pressure is applied and the disc expands, it starts to fill this gap. Actual bulk test starts at the end of this gap-filling stage. Samples of linear curve fitting for extraction of elastic and bulk moduli (
5.2.2 Effect of swelling time
Compressive stress–strain behavior at different stages during the one month swelling period for materials
Pressure-volumetric strain curves for one month period for both materials in low salinity are shown in Figure 13. A trend similar to the compression curves can be seen in these pressure-strain graphs also; larger drop in bulk modulus during the first few days of swelling, then more gradual. Reasons are the same as discussed above.
5.2.3 Variation of elastic Modulus
Variation of Young’s modulus (
5.2.4 Variation of bulk Modulus
Variation of bulk modulus (
5.2.5 Variation of Poisson’s ratio
Variations of Poisson’s ratio (
5.2.6 Variation of shear Modulus
Variation of shear modulus (
5.2.7 Variation of chain density
Variation in cross-link chain density (
5.2.8 Variation of molecular weight
Figure 19 shows the variation in number-average chain molecular weight (
Slight fluctuations during the first week of swelling in the values of material and structural properties studied are due to this two-pronged variation in swelling amount. Compared to bulk tests, fluctuation is almost insignificant in compression tests due to the simple uniaxial nature of the load applied.
6. Results and discussion: numerical
Stress–strain curves under compressive loading, and pressure-strain curves for bulk testing are also produced through numerical simulation, using Ogden hyperelastic material model with second-degree strain energy function (N = 2). Graphs for variation of mechanical properties against swelling are generated from the numerical results. This work has been done for both materials under both salinities for the entire one-month swelling period. However, only a few representative graphs are presented below for comparison of experimental and numerical results.
6.1 Behavior under compressive loading
Stress–strain plots in the 10% strain region for experimental and numerical results of compression test for material
6.1.1 Mechanical properties
Variation of Young’s modulus, Poisson’s ratio, and shear modulus for the two materials under 0.6% and 12% salinity over the 30-day swelling period is shown in Figures 22–24. A reasonable match between experimental and simulation results can be observed. There are notable differences during days 2 to 7, especially in the case of higher salinity (12%), but the curves come close to each other upon further swelling.
Comparison between experimental and numerical results for bulk tests is given in Figures 25 and 26, for materials
6.1.2 Note
As discussed in detail in Chapter 6, Ogden model (N = 2) is the best one among the available hyperelastic models for representation of swelling elastomers. However, as most of the graphs in this section show, even the Ogden model does not yield results that follow experimental ones closely. In the absence of any other model, this may be the only choice for numerical simulation, but it is not good enough.
7. Conclusions
Experimental and numerical investigation of changes in compressive and bulk behavior of two water-swelling elastomers has been presented. Tests were carried out on standard compression and bulk samples (following ASTM standards) before swelling and after different swelling periods. Elastic modulus and bulk modulus were experimentally determined under different swelling conditions. Shear modulus and Poisson’s ratio were estimated using isotropic relations. Cross-link chain density and number average molecular weight were obtained using predictive equations of polymer structure. Mechanical testing was also modeled and simulated using the nonlinear finite element package ABAQUS, using Ogden hyperelastic model with second strain energy potential. Simulation results are somewhat close to experimental ones in most of the cases. However, there are significant differences in various other situations. This strengthens the need for a new material model to more effectively represent the behavior of swelling elastomers.
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