Tradeoff between utility and delay obtained from super-resolution performance measurement results (processing time have measured on
\r\n\tWithin this scenario, special attention needs to be devoted to financial implications, due to their pervasiveness. Nobody would question the key role that finance plays to complement the real sphere of the economy and that has increasingly attracted both academics and practitioners. As a result, traditional pillars – such as financial markets, products, and institutions – have evolved significantly, with financial innovation fueling further progress over time. The global side of the coin features – among others – financially connected markets, international financial exchanges, and financial conglomerates that provide valuable opportunities in terms of international corporate finance. On the other side, recent advances have involved a wider recourse to ESG factors, allowed forward steps towards a more inclusive financial system, and have made digital finance a must, rather than an option, even though much remains to be accomplished, for instance, to facilitate access to formal financial channels in many underdeveloped regions.
\r\n\r\n\t
\r\n\tThis book aims to examine emerging trends, new perspectives, and empirical applications that deal with globalization and sustainability. The goal is to provide a comprehensive overview of these important concepts as valuable support to successfully meet the challenges and take on the opportunities ahead. At the same time, drawing upon empirical evidence can contribute to bridging the gap between theory and practice, which also fits within the scope of this book.
Nowadays, many machine learning and deep learning algorithms have been developed in various applications such as computer vision, natural language processing, and so forth. Furthermore, the performances of the algorithms are getting better. Thus, the developments of machine learning and deep learning algorithms become mature. However, the research contributions which are focusing on the real-world implementation of the algorithms are relatively less than the developments of the algorithms themselves.
In order to operate the deep learning algorithms in real-world applications, it is essential to think about the real-time computation. Thus, the consideration of delay handling is desired because deep learning algorithm computation generally introduces large delays [1].
In communications and networks research literature, there exists a well-known stochastic optimization algorithm which is for utility function maximization while maintaining system stability. Here, the stability is modeled with queue, and then the algorithm aims at the optimization computation while stabilizing the queue dynamics. In order to formulate the stability, the queue is mathematically modeled with Lyapunov drift [2].
This algorithm is designed inspired by Lyapunov control theory, and thus, it is named to Lyapunov optimization theory [2]. In this chapter, the basic theory, examples, and discussions of the Lyapunov optimization theory are presented. Then, the use of Lyapunov optimization theory for real-time computer vision and deep learning platforms is discussed. Furthermore, the performance evaluation results with real-world deep learning framework computation (e.g., real-world image super-resolution computation results with various models) are presented in various aspects. Finally, the emerging applications will be introduced.
In this section, Lyapunov optimization theory which is for time-average optimization subject to stability is introduced at first (refer to Section 2.1), and then example-based explanation is presented (refer to Section 2.2). Finally, related discussions are organized (refer to Section 2.3).
In this section, we introduce the Lyapunov optimization theory which aims at time-average penalty function minimization subject to queue stability. Notice that the time-average penalty function minimization can be equivalently converted to time-average utility function maximization. The Lyapunov optimization theory can be used when the tradeoff exists between utility and stability. For example, it can be obviously seen that the tradeoff exists when current decision-making is optimal in terms of the minimization of penalty function, whereas the operation of the decision takes a lot of time, i.e., thus it introduces delays (i.e., queue-backlog increases in the system). Then, the optimal decision can be dynamically time-varying because focusing on utility maximization (i.e., penalty function minimization) is better when the delay in the current system is not serious (i.e., queueing delay is small or marginal). On the other hand, the optimal decision will be for the delay reduction when the delay in the current system is large. In this case, the decision should be for delay reduction while sacrificing certain amounts of utility maximization (or penalty function minimization).
Suppose that our time-average penalty function is denoted by
where
In this section, control action decision-making should be made in each unit time for time-average penalty function minimization subject to queue stability. Then, the mathematical program for minimizing time-average penalty function,
Subject to queue stability:
In (3),
As mentioned, the Lyapunov optimization theory can be used when tradeoff between utility maximization (or penalty function minimization) and delays exists. Based on this nature, drift-plus-penalty (DPP) algorithm [2, 3, 4] is designed for maximizing the time-average utility subject to queue stability. Here, the Lyapunov function is defined as
where
Therefore, the upper bound of the conditional Lyapunov drift can be derived as follows:
where
which supposes that the arrival and departure process rates are upper bounded. Due to the fact that
1:
2:
3: Decision Action:
4:
5: Observe
6:
7:
8:
9:
10:
11:
12:
13:
14:
Finally, the dynamic control action decision-making
where
In order to verify whether (11) works correctly or not, following two example cases can be considerable:
Then, (13) shows that control action decision-making should works as follows, i.e., (i) the arrival process should be minimized, and (ii) the departure process should be maximized. Both cases are for stabilizing the queue, i.e., it should be beneficial when
Then, (15) shows that control action decision-making should work for minimizing the given penalty function. This is semantically reasonable because focusing on our main objective is possible because stability does not need to be considered because
The pseudo-code of the proposed time-average penalty function minimization algorithm is presented in Algorithm 1. From line 1 to line 3, all variables and parameters are initialized. The algorithm works in each unit time as shown in line 4. In line 5, current queue-backlog
Up to now, the time-average penalty function minimization is considered. Based on the theory, the dynamic control action decision-making
where
In this section, the Lyapunov optimization-based stabilized time-average optimization algorithm is introduced with one simple toy model. In this example, dynamic core allocation decision-making algorithm is designed which is for time-average energy consumption minimization subject to queue stability.
As illustrated in Figure 1, mobile smartphone is with the processor which is equipped with multiple cores. For example, ARM big.LITTLE processors are with multiple little and big heterogeneous cores.
Mobile devices with multicore processors.
In this system, the task events will be generated when users generate events, which are denoted by
In order to design the dynamic core allocation decision-making,
where
In order to check whether the derived Eq. (18) is correct or not, two example cases can be considered, i.e., (i)
Thus, the departure process should be accelerated, i.e., more cores should be allocated. This is semantically true because the fast processing events from the queue is desired if overflow situations happen.
Thus, less cores should be allocated for energy consumption minimization which is our main objective. This is semantically true because the given main objective should be desired if the system is stable, i.e.,
As discussed with examples, the proposed Lyapunov optimization-based dynamic core allocation decision-making algorithm works as desired.
The proposed dynamic super-resolution model selection algorithm is beneficial in various aspects, as follows.
Suppose that this proposed algorithm is implemented in supercomputer-like high-performance computing machines. In this case, the processing should be fast; thus, the queue-backlog is always low. Therefore, the system has more chances to focus on our main objective, i.e., penalty function minimization or utility function maximization. On the other hand, if the hardware itself is performance/resource limited (e.g., mobile devices), then the processing speed is also limited due to the low specifications in processors. Thus, the queue-backlog can be frequently busy because it may not be able to process many data with the queue even though it utilizes the fastest model. Therefore, it can be finally observed that the proposed algorithm is self-adaptive which can adapt depending on the given hardware/system specifications. It automatically adapts the models based on the given hardware/system; thus, it does not require system engineer’s trial-and-error tuning. Furthermore, the proposed algorithm is reliable according to the fact that the self-adaptation is for maximizing its
As shown in Algorithm 1, the computation procedure is iterative for solving closed-form equation, i.e., (11) and (16). Thus, the computational complexity of the proposed algorithm is polynomial time, i.e.,
As explained, the Lyapunov optimization theory is a scalable, self-configurable, low-complexity algorithm which can be used in many applications. In this section, the use of Lyapunov optimization for deep learning and computer platforms is discussed in two different ways, i.e., departure process control (refer to Section 3.1) and arrival process control (refer to Section 3.2). Finally, its related performance evaluation results are presented (refer to Section 3.3).
As illustrated in Figure 2, stabilized real-time computer vision platforms should be equipped with queues in order to handle bursty traffics. If the queue is busy or near-overflow, the departure process should be accelerated. Thus, the simplest model should be used for reducing the corresponding computation. On the other hand, if the queue is empty, deep learning computation accuracy can be improved with more sophisticate models because we have enough time to conduct the computation. Thus, multiple models are desired in order to select one depending on queue backlog.
Lyapunov control over departure processes in real-time computer vision platforms for time-average learning accuracy maximization subject to queue stability.
In Figure 2, multiple models exist, and it can be seen that the simplest model (i.e., low-resolution model) is able to conduct fast computation, but it presents low learning accuracy. On the other hand, the most sophisticate model (i.e., high-resolution model) is good for accurate learning performance, but it introduces computation delays. Thus, the tradeoff exists between performance and delays, i.e., Lyapunov optimization theory-based dynamic model selection decision-making algorithm can be designed as follows:
and this can be reformulated as follows due to the fact that the arrival process is out of control:
where
The stabilized real-time computer vision platform in Section 3.1 is novel and scalable; however it has burden because multiple deep learning models should be implemented in a single platform.
Thus, a new dynamic control algorithm with a single deep learning model is also needed for resource-limited systems. As illustrated in Figure 3, our considering system has a single computer vision and deep learning model in computing platforms. In addition, the queue is in front of the system. Thus, the departure process is not controllable anymore. In this case, the arrival process should be controllable in order to control the queue dynamics for stability. Therefore, the arrival image/video streams should be controlled by handling sample rates. If high-frequency sampling is available, more signals will be generated, and then the results will be enqueued. Thus, the arrival process increases. This is beneficial because it increases computer vision performance due to the fact that more images/videos can be obtained especially in surveillance applications. On the other hand, i.e., if low-frequency sampling is conducted, the computer vision performance can be degraded, whereas the number of arrival process data decreases which is beneficial in terms of stability. Eventually, the tradeoff between computer vision performance and delays can be observed. Finally, Lyapunov optimization theory-based sampling rate selection decision-making algorithm can be designed as follows:
Lyapunov control over arrival processes in real-time computer vision platforms for time-average learning accuracy maximization subject to queue stability.
and this can be reformulated as follows due to the fact that the departure process is out of control:
where
In this section, the performance evaluation results of the proposed algorithm in Section 3.1 are presented. The data-intensive simulation-based evaluation is performed, and then the results are presented in Figure 4. In addition, Table 1 shows the performance of super-resolution depending on the number of hidden layers. If the number of hidden layers is maximum (i.e., 20 in this research), the PSNR and structural similarity (SSIM, one of the widely used performance metrics in super-resolution) values are maximum. However, the computation times (for CPU-only and CPU-GPU) become slow.
Performance evaluation: Queue-backlog (
Depth (# of hidden layers) | 0 | 4 | 6 | 8 | 11 | 14 | 17 | 20 |
---|---|---|---|---|---|---|---|---|
PSNR (dB) | 30.400 | 32.560 | 33.010 | 33.229 | 33.379 | 33.435 | 33.495 | 33.523 |
SSIM | 0.8682 | 0.9100 | 0.9160 | 0.9180 | 0.9200 | 0.9200 | 0.9210 | 0.9220 |
Processing time (CPU − only) | 0.0020 | 0.3210 | 0.5468 | 0.7725 | 0.9940 | 1.3170 | 1.6220 | 1.9600 |
Processing time (CPU + GPU) | 0.0010 | 0.0100 | 0.0120 | 0.0152 | 0.0189 | 0.0224 | 0.0262 | 0.0305 |
Tradeoff between utility and delay obtained from super-resolution performance measurement results (processing time have measured on
As illustrated in Figure 4, if the models are static (i.e.,
For the proposed self-adaptive stabilized algorithm, the evaluation with two processing capabilities (CPU-only platform vs. CPU-GPU platform), it can be observed that the CPU-GPU platform selects the maximum performance super-resolution model (i.e.,
In order to confirm the performance of super-resolution models, Figure 5 shows the super-resolution computation results with real-world images. As can be seen in the figures, the super-resolution models show better performances if they have more hidden layers, as shown in Figure 5b, Figure 5d, and Figure 5f. For the super-resolution computation without hidden layers, this paper uses bicubic interpolation, as shown in Figure 5a, Figure 5c, and Figure 5e. Finally, these results show that our considering Lyapunov control algorithms for adaptive deep learning platforms can make different super-resolution performance depending on queue-backlog size information.
Super-resolution computation results. Note that the model for low-resolution is bicubic which has no hidden layers. (a) Image #1 (low-resolution), (b) image #1 (high-resolution), (c) image #2 (low-resolution), (d) image #2 (high-resolution), (e) image #3 (low-resolution) and (f) image #3 (high-resolution).
As presented, the Lyapunov optimization framework is for time-average utility maximization while achieving queue stability; and this theory is scalable; thus it is widely applicable [2]. Therefore, there exist many applications based on this algorithm as follows.
Kim et al. [3, 5] design a dynamic control algorithm for time-average streaming quality (i.e., peak-signal-to-noise ratio (PSNR)) maximization subject to transmit buffer stability in wireless video networks. Koo et al. [6, 7] also propose a novel dynamic adaptive streaming over HTTP (DASH)-based mechanism for video streaming quality maximization under the consideration of battery status, LTE data quota, and stability in hybrid LTE and WiFi networks.
Neely et al. [8] proposed a novel dynamic multi-hop routing algorithm which is for energy-efficient data/packet forwarding in wireless ad hoc and sensor networks subject to queue stability.
Mo et al. [9] design a deep learning framework for CCTV-based distributed surveillance applications. In the system, multiple deep learning frameworks exist; and each deep learning model is with its own configurations. In this situation, there exists a tradeoff between complexity and performance. Therefore, the proposed CCTV-based surveillance algorithm adaptively selects a deep learning model depending on queue-backlog in the system for recognition performance maximization subject to CCTV queue stability. Kim et al. [10] also design a novel face identification deep learning frameworks for CCTV-based surveillance platforms. Instead of having multiple deep learning models, this system has one learning system (based on OpenFace open-source software library) and controls the sampling rates of the CCTV camera. Finally, the proposed decision-making algorithm dynamically selects CCTV sampling rates for recognition performance maximization subject to CCTV queue stability.
The application of Lyapunov optimization-based dynamic control algorithm for dynamic reinforcement learning policy design is illustrated in [11]. In addition, the adaptive control algorithms using the Lyapunov optimization framework in stock market pricing and smart grid are introduced in [12, 13].
This chapter introduces a dynamic control decision-making algorithm, inspired by Lyapunov optimization theory under the situation where the tradeoff between utility/performance and delays exists. Thus, the dynamic decision-making algorithms aim at time-average utility maximization (or penalty minimization) in real-time deep learning platforms. As discussed, the Lyapunov optimization-based algorithms are scalable, hardware/system-independent, self-configurable, and low-complexity. Thus, it can be used in various emerging applications such as video streaming, wireless networks, security applications, and smart grid applications.
This work is supported by the National Research Foundation of Korea (2019R1A2C4070663, 2019M3E4A1080391). J. Kim is a corresponding author (e-mail: joongheon@korea.ac.kr).
The authors declare no conflict of interest.
Hydrotalcite is a hydroxycarbonate of magnesium and aluminum which occur in nature as a layered double hydroxide (LDH). The LDHs are represented by the general formula [M2+(
Schematic representations of (a) Brucite and (b) Hydrotalcite.
The mineral hydrotalcite has the molecular formula Mg6Al2(OH)16CO3.4H2O, however, the synthetic hydrotalcite-like materials can have a wide compositional cation variability, different cationic ratios and varying anions in the interlayer region.
Undoubtedly the LDH most used in several applications is the MgAl-LDH system containing carbonate as interlayer ions. However, several other cations and anions are part of countless possible compositions. Co-precipitation is the main preparation method of LDHs, which consists of slowly adding an aqueous solution containing the metal ions in a proper ratio over an aqueous solution containing the hydroxyl ions (usually NaOH) and the anion to be intercalated under vigorous stirring during a certain time. The obtained precipitate is filtered, washed with deionized water, and dried. This is the least cost method for producing LDH. Mostly the production requires strict control of temperature, stirring, and pH to avoid the formation of impurities such as simple hydroxides. In the industrial case, the separation of impurities can raise the price of the final product.
These materials can be prepared by several methodologies other than co-precipitation. An alternative is the hydrothermal method, which permits obtaining high particle size and high product purity [3, 4]. This method is similar to the co-precipitation, meantime, after stirring the suspension is transferred to a Teflon autoclave for hydrothermal treatment. The temperature and aging time influences directly in the crystallinity and morphology uniformity of the material [3, 4, 5, 6, 7, 8]. Urea hydrolysis is a satisfactory example of hydrothermal synthesis in which urea is used as a source of carbonates and hydroxyls anions, providing better crystallinity due to very slow precipitation [9, 10, 11].
The ion exchange method is widely used; mainly for the intercalation of drugs [12, 13]. This method consists of inserting the precursor LDH in an aqueous solution containing the anion to be intercalated. The exchange of anions in the interlamellar space occurs after pH adjustment and constant stirring, generating a new LDH after the experimental procedures. The solid precipitate is then filtered, washed with deionized water, and dried in an oven. Increased interlayer distance may occur depending on the size of the intercalated ion, as exemplified in Figure 2.
Schematic representation of ion exchange method.
The LDHs reconstruction method is known as the memory effect, an intrinsic property of this type of material, which is characterized by the regeneration of the lamellar structure after thermal decomposition (Figure 3).
Schematic representation of memory effect.
The thermal decomposition of this type of material is a complex sequence of steps that involve dehydration, dehydroxylation (loss of hydroxyls), and loss of carbonate in the starting material [14]. The initial lamellar structure forms mixed metal oxides as the final products of thermal decomposition. When subjected to hydration, these oxides are capable of regenerating the initial lamellar structure. This method can also be used for ion exchange, since the solution used for rehydration may contain anions different from those contained in the initial LDH.
In addition to the aforementioned methodologies, the following deserve mention: sol–gel synthesis [15, 16], salt oxide method [17, 18], sonochemical assisted synthesis [19, 20, 21], and manual grinding method [22, 23]. The methodologies mentioned here do not exhaust the possibilities of synthesis of LDH. It should be noted that each method has its advantages and disadvantages and can be improved and applied according to the specifics of the desired product.
The great current interest in LDHs is due to the wide range of possible applications in different areas. This is reflected in a large number of recent reviews and papers published in high-impact journals from a variety of research fields. In the biomedical area, for example, Shirin
Jin
Still, in relation to the use of LDHs in the biomedical area, Meirelles and Raffin [26] published a technological and scientific prospection related to patents and articles involving composites employed in therapeutic devices. Despite the growing interest in the area, the authors considered the number of patents low (on average less than 10 documents per year in the last decade), and attributed this to the lack of regulation on nanomaterials used in the development of medications. Additionally, for further advances in nanomedicine applications are necessary: to improve the synthesis methodologies to enable uniform particle size distribution; understand how the number/density of surface modifiers affects biological performance; increase the molecular selectivity; study long-term side effects; to develop diverse imaging modalities for studies at molecular level providing comprehensive biological information; and to develop functional LDHs loading multiple antigens and biological adjuvants [27].
Another extremely relevant sector where LDHs are widely used is the removal of contaminants from water. Access to clean water and an efficient basic sanitation system are essential factors for socioeconomic development and the reduction of millions of deaths annually worldwide. Certainly, this situation is further aggravated by the pandemic caused by the new corona virus. Moreover, the need for decontamination of rivers and fountains is increasing, due to pollution caused by industrial and human waste. In this sense, LDHs have been extensively researched for use in water purification [28, 29, 30]. Its anion exchange property associated with high surface area, compositional versatility, and higher adsorption capacity are characteristics that differentiate them from other mineral adsorbents such as aluminum or iron oxy-hydroxides [28]. Nevertheless, scientists in this field agree that more knowledge is needed to be able to apply these materials on a large scale [28, 29, 30, 31]. Techniques of preparation, functionalization and thermal activation must be improved aiming to increase the understanding of their behavior on an atomic scale. In this way, it will be possible to correlate structure, chemical composition, morphology, and surface properties to maximize the adsorption capacity and, consequently, achieve better performances in removing pollutants from water.
Polymer nanocomposites (PNCs) containing LDHs are also considered as an important alternative for water purification systems. These materials have the interesting ability to combine the characteristics of the polymeric matrix and the LDH, forming nanocomposites with multifunctional properties. Pandey
The great interest in the application of LDHs and their composites with various substances is not limited only to the mentioned areas. A series of possible preparations, characterizations, and industrial applications were exemplified in some interesting reviews [35, 36]. The review of Yan
One of the areas in which LDHs find wide application is in catalysis. Particularly, in heterogeneous catalysis and photocatalysis, the LDHs are very used as a catalyst or, mainly, as a precursor of mixed oxides, which, in turn, can be used in various industrial catalytic processes [48, 49, 50, 51, 52, 53, 54]. Below will be highlighted some interesting catalytic reactions using hydrotalcite-like materials as catalyst or catalyst precursor. Examples of how Raman spectroscopy can be used to characterize these materials will also be discussed.
The use of hydrogen as an alternative to fossil fuels is an area of great interest to industries, governments, and researchers worldwide. In addition to its pollution-free characteristic, the high energy value and rich resources further enhance research on this subject. The catalytic steam reforming is the technology applied industrially for the hydrogen production. Light hydrocarbons are used in this process, especially methane. In this case, the reaction occurs in two steps: firstly, methane reacts with water vapor generating CO and H2; after, CO undergoes water gas shift (WGS) reaction generating CO2 and more H2Eqs. (1) and (2).
An alternative for the hydrogen production is the use of alcohols as source. Particularly, in relation to other alcohols, ethanol has some advantages from a socio-environmental point of view, such as ease of obtaining from renewable sources, large volume of production due to existing industrial facilities, ease of handling, and being non-toxic. The Eq. (3) summarizes the global ethanol steam reforming (ESR) reaction, but several other reactions such as WGS Eq. (2) and Boudouard reaction Eq. (4) occur concurrently [55].
Several systems are tested in the ESR reaction and the most relevant results are obtained for catalysts containing noble metals such as Pt, Pd, Ru or Rh [56, 57]. On the other hand, Ni, Co or Cu based catalysts can provide a better cost–benefit ratio. However, the greatest impediment to the industrial use of this process is to control the secondary reactions that occur and lead to the deactivation of the catalyst. The resolution for this involves the development of active, selective, and stable catalysts. Thus, mixed oxides formed from LDHs have been used for this purpose.
Passos
Raman and mass spectroscopies were used to monitoring the evolution of ethanol conversion and products obtained during the ESR reaction. Full conversion was achieved during the initial 30 min, however several byproducts were observed revealing the occurrence of parallel reactions. After 50 min a decrease in ethanol conversion is accompanied by a decrease in selectivities to CO2 and H2. The catalyst deactivation was monitored by increase of D and G bands observed respectively at 1336 and 1586 cm−1 in Raman spectra. These bands are respectively characteristics of large aromatic ring systems and ordered graphitic carbon species. Concomitantly, mass spectroscopy showed that these coke deposits originate from decomposition reactions of ethylene, acetaldehyde, and methane, in addition to the polymerization of ethylene and the Boudouard reaction. Besides filamentous and graphitic, amorphous coke species also were detected by Raman analysis, reaching 30% of coke deposits after 180 min on stream. The amorphous coke species were identified through vibrations at 1278 and 1500 cm−1, by deconvolution of Raman signals. These species come from acetaldehyde and ethylene reactions, and encapsulate the metallic sites accelerating the deactivation process. Oxidative regeneration was performed and ESR reaction was restarted. Then, metallic particles were recovered (100% of Cu0 and 85% of Ni0) due to the H2 formed in the ESR reaction, leading to a second reaction cycle with performance equivalent to the first one.
Sikander
During a photocatalytic process, a semiconductor surface is excited by ultraviolet–visible radiation. After absorbing energy equivalent to or greater than its band gap, an electron (
Schematic representation of a reaction catalyzed by a semiconductor.
As mentioned in Section 2, LDHs can be used for water purification. Major sources of environmental contamination are found in industrial waste, mainly from the dyeing industries, leading to problems such as low biodegradability, changes in color, smell and pH, in addition to low oxygen availability. The biological treatment is the most used for decontamination of water containing dyes, however it is considered slow and several poisonous molecules cannot be biologically treated. Other techniques are considered expensive and not all the usual techniques are capable of efficiently eliminating all toxic elements. In this regard, photocatalysis emerges as an alternative, enabling the development of more efficient and less environment harmful systems.
De Carvalho
In another work, De Carvalho
In order to improve the air quality, governments in various countries have announced new regulations to reduce the level of sulfur, nitrogen, and other contaminants which are present in transportation fuels [67]. Therefore, refiners need to decrease the concentration of contaminants, particularly in gasoline and middle distillates [68]. Gasoline from fluid catalytic cracking (FCC gasoline), which represents 30–50% of the total gasoline pool, is by far the most important sulfur contributor in gasoline, up to 90% [69]. Although, the olefins, which are important contributors to the octane rating in commercial petrol, are also present in FCC fraction. As a result, FCC gasoline is the focus for sulfur reduction.
The conditions used in the catalytic hydrodesulfurization (HDS) process such as high pressure, high temperature, and high hydrogen consumption make the process expensive. Several alternative methods, such as adsorption or alkylation have been developed in recent years. However, the key technical problem for the HDS of FCC gasoline is to perform a deep sulfur removal and, at the same time, to reduce the loss of the olefins occurring in the HDS process, by minimizing the hydrogenation (HYD) [70].
To preserve the olefins responsible for the octane number, it is necessary to improve the selectivity of the conventional catalysts (sulfide CoMo/γ-Al2O3) without loss of octane number. In this connection, one of the key parameters which determine the activity of the CoMo HDS catalysts is the type of support. Aiming to reduce the loss of octane number, Zhao
Presently, we characterize an MgAl-LDH and evaluate the use of their derived mixed oxide as support for HDS catalyst in comparison with γ-Al2O3. The powder X-ray diffraction (XRD), BET, Temperature Programmed Reduction of hydrogen (H2-TPR), and Fourier Transform Spectroscopies (FTIR and FT-Raman) were used to characterize the materials. FTIR spectra were recorded on a BOMEN MB-102 spectrometer using pressed KBr pellets and 4 cm−1 of spectral resolution to verify the vibrational modes present in the samples. Good signal-to-noise ratio was obtained from the accumulation of 128 scans. Raman spectra were acquired on a LabRAM HR-UV 800/Jobin-Yvon equipment, with He–Ne (633 nm) laser and CCD detector. The resolution was 2 cm−1 in the range between 1200 and 100 cm−1. Moreover, the hydrodesulfurization of thiophene and hydrogenation of cyclohexene were the reactions chosen to evaluate the activity and selectivity of CoMo sulfide catalysts.
The MgAl-LDH and Boehmite are commercial samples provided by Petrobras-Cenpes. These samples were calcined at 500°C for 3 h under air, to obtain the oxide supports (named as MgAl and γ-Al2O3, respectively). The supports were submitted to incipient wetness impregnation of solutions containing the Mo and Co salts using the appropriate amount of ammonium heptamolybdate and cobalt nitrate, to obtain catalysts with 10% of MoO3 and 3% of CoO on the surface. After calcination at 450°C for 1 h, the oxide catalysts were denominated CoMo/MgAl and CoMo/γ-Al2O3.
The spectroscopic data obtained for the MgAl-LDH are shown in Figure 5. In the FTIR spectrum, the strong and wide absorption band centered at 3464 cm−1 is due to the contribution of the asymmetric stretching modes of the lamellar hydroxyl groups (νOH) and of the interlamellar water molecules [74]. The shoulder at 3085 cm−1 is characteristic of the νOH symmetrical stretching of water molecules interacting by hydrogen bonding with interlamellar carbonate ions. The poor absorption at 1633 cm−1 is attributed to the deformation mode of water molecules (δOH). The band at 1354 cm−1 is assigned to the asymmetric stretch mode, ν3, of carbonate, and the small band at 1074 cm−1 is assigned to the symmetrical mode, ν1, of carbonates connected to OH groups, as suggested by absorption around 3000 cm−1. This absorption is expected due to the decrease in the symmetry of the carbonate groups (from D3h to C2v), caused by different types of interaction of these anions with interlamellar water molecules and hydroxyl groups present in brucite-like layers [75, 76]. The band at 775 cm−1 corresponds to the mode of deformation outside the plane of carbonate ions, and the mode of deformation in the plane is observed at 679 cm−1. Still in the region of low wavenumber, the absorption around 557 cm−1 is attributed to the vibration of the carbonate-water units [76], however this absorption can also be attributed to the M-O-M, O-M-O, and M-OH lattice vibration modes (where M is Mg or Al) [77]. Finally, the 451 cm−1 band is attributed to the contribution of the Mg-O and Al-O stretching modes.
FTIR (a), and FT-Raman (b) spectra of MgAl-LDH.
All data obtained through infrared analysis are in agreement with that observed in the FT-Raman spectrum. This spectrum features three typical LDH bands [76, 78]. The three weak absorptions at 1064 cm−1, 562 cm−1, and 354 cm−1 are attributed as symmetrical stretching of the carbonate ion, CO32− units linked by hydrogen interaction to interlamellar water molecules, and Mg-O stretching, respectively. Therefore, the vibrational study carried out using infrared and Raman spectroscopies suggests that carbonate ions are present in the crystalline network of the sample and are involved in hydrogen bonds.
In the infrared spectrum of the Boehmite sample, it is verified the presence of a band at 3315 cm−1 commonly attributed to the asymmetric stretching modes νOH from water molecules and hydroxides (Figure 6a). In addition, a band at 3094 cm−1 is observed due to the symmetric stretching νOH of hydroxyl groups interacting through hydrogen bonds. Around 1639 cm−1, absorption attributed to the δOH mode is noted. The δAl-OH mode is observed at 1074 cm−1. The νAl-O vibrational modes, with maximum absorption at 625 cm−1, appear as part of a wide and intense band in the region between 900 and 600 cm−1, which in turn still contains the contribution of lattice vibrational modes [79].
FTIR (a), and FT-Raman (b) spectra of Boehmite.
In the Raman spectrum (Figure 6b), the 680 and 500 cm−1 bands are assigned to the asymmetric and symmetric stretch modes νAl-OH, respectively. In addition, the intense band at 364 cm−1 stands out, due to the νAl-O stretching mode. Thus, these results corroborate with the infrared analysis, suggesting that the sample has a typical Boehmite spectrum.
All the peaks in the XRD patterns were indexed (Figure 7) [9, 80, 81, 82, 83, 84]. The cell parameters for the MgAl-LDH were refined using the Checkcell software [68] (Table 1). The input values were
X-ray diffraction patterns of (a) MgAl-LDH and MgAl, and (b) Boehmite and γ-Al2O3.
CS (nm) | d003 (Å) | Support | CS (nm) | |||
---|---|---|---|---|---|---|
56.8 | 3.026 (7) | 22.607 (5) | 7.49 | 11.4 | 4.149 (4) |
Crystallite size (CS) and lattice parameters for MgAl-LDH and its derived mixed oxide.
The diffraction patterns obtained for the supports are also show in Figure 7. The XRD profile of MgAl mixed oxide is typical of rock-salt phase [87, 88, 89]. The cell parameter
The XRD patterns obtained for both CoMo catalysts show no major differences relative to the respective supports, despite the decrease of the peak intensities, indicating a decrease in crystallinity after impregnation (Figure 8). This aspect indicates good dispersion of the impregnated phases in accordance with surface areas, which decreased slightly in relation to the supports (from 191 to 175 m2g−1 for CoMo/MgAl, and from 240 to 201 m2g−1 for alumina based catalyst). However, in this case, the XRD technique does not allow the identification of the crystalline phases present on the supports. For this, Raman spectroscopy is extremely useful.
X-ray diffraction patterns of the CoMo catalysts.
Typical Raman spectrum of the supported CoMo oxide catalysts is shown in Figure 9. The main bands around 995, 818, 665, 378, 337 and 291 cm−1 are characteristics of MoO3 [90, 91]. The most intense bands at 995 cm−1 and 818 cm−1 correspond to symmetric (νMo꞊O) and asymmetric stretching (νMo-O-Mo) vibrational modes, respectively [92]. Additionally, a low intense band assigned to CoMoO4 phase is observed at 950 cm−1 [93]. The CoMoO4 oxide is known as a good precursor for HDS catalysts, because it could lead to the formation of the active CoMoS Type II phases [94]. Thus, the Raman spectrum suggests that CoMoO4 and MoO3 species coexist on the surface of the supported CoMo oxide catalysts.
Raman spectrum of CoMo/γ-Al2O3 catalyst.
H2-TPR technique was used to verify the reduction behavior of impregnated species on the supports. Figure 10 shows the H2-TPR profiles of supported oxide catalysts. The CoMo/MgAl catalyst exhibit two peaks (375 and 556°C), while the CoMo/γ-Al2O3 catalyst display a peak at 460°C. In the literature, was reported that for catalysts containing only cobalt oxide dispersed on alumina (Co/γ-Al2O3) there is a peak around 340°C, assigned to the reduction of Co3O4, and peaks between 600 and 700°C, attributed to the reduction of Co2+ ions in different chemical environments [95]. When there is only molybdenum oxide on alumina (Mo/γ-Al2O3), the Mo6+ → Mo4+ reduction generally occurs at 500°C. This indicates that Mo6+ cations are easily reduced. Moreover, commonly above 800°C, are observed peaks related to different reduction steps (MoO3 → MoO2 → Mo0) [96, 97].
H2-TPR profiles of CoMo catalysts.
H2-TPR profiles obtained in the present work suggest an interaction between cobalt and molybdenum species, considering that the first peak is observed between 375 and 460°C (temperature higher than Co/γ-Al2O3 and lower than Mo/γ-Al2O3 reductions). Furthermore, for both samples the second reduction occurs above 800°C. The species reducing at slightly higher temperatures may have a somewhat stronger interaction with support surface. Thus, they cannot be reduced and they are therefore probably lead to inactive phases in the HDS reaction. Similar profile is observed in the work of Liu
For catalytic tests, the reactor was loaded with 300 mg of supported oxide catalyst and 900 mg of SiC (both 80–100 Tyler mesh) between quartz-wool plugs. The presulfiding of the supported oxide catalysts was carried out according to the following procedure: initially, the materials were dried at 150°C for 30 min under a 450 mL min−1 nitrogen flow. Then, the supported oxide catalysts were presulfided using a mixture of 1.66% CS2 in n-heptane (v/v). The liquid was fed to the reactor at 20 mL h−1 under hydrogen flow (450 mL min−1) and at atmospheric pressure. The sulfidation temperature was maintained at 280°C for 1 h, at 350°C for 30 min and, finally, at 400°C for 30 min. After sulfidation, the catalysts were tested at 280°C and 20 bar. The liquid feed consisting of 0.8% of thiophene and 17% of cyclohexene in n-heptane (v/v) was pumped to the reactor at 16.8 mL h−1 with a 450 mL min−1 hydrogen flow. The conversions were kept low in order to operate in differential regime.
The results show that the tested catalysts are active for both, HDS and HYD reactions, for which the main products were butenes and cyclohexane, respectively. Previous studies described calculations methods for the conversions of thiophene HDS and cyclohexene HYD, which were performed from the carbon balance for each of the reactants and the respective reaction products [73]. The results of catalytic performances are displayed in Figure 11. It is important to mention that the activity for HDS is practically the same for both catalysts, since thiophene conversions are around 14%. On the other hand, the catalyst supported on alumina has greater HYD activity than the catalyst supported on mixed oxide derived from LDH; in this case, the conversions of cyclohexene are 25 and 8.5%, respectively. Thus, the HDS/HYD ratios are 0.6 for sulfide CoMo/γ-Al2O3 and 1.7 for sulfide CoMo/MgAl. This result shows that the catalyst supported on mixed oxide derived from LDH is more selective for HDS reaction.
Conversions of thiophene (a) and cyclohexene (b) for CoMo catalysts.
As in the work of Trejo
In summary, supports based on mixed oxides derived from LDHs can be an alternative for use in HDS reactions. Raman spectroscopy is useful in the characterization of the support precursors and, associated with other characterization techniques, it is important in the identification of the active phases.
An overview of hydrotalcite-like materials was presented and the most used preparation methods were described. The possibility of varied compositions and their unique structural characteristics make it possible to obtain materials with specific properties and applications in several areas of industrial interest. In catalytic systems particularly these materials are widely studied and several processes need further characterization. In this sense, Raman spectroscopy proves to be an extremely useful and versatile tool, as it can be used for the structural characterization of LDHs, derived mixed oxides, composites, and other materials used. Furthermore, Raman spectroscopy is a very sensitive technique that makes it possible to determine the chemical nature of reaction products, being able to monitor the entire catalytic process. Thereby, the association of Raman with other techniques will allow the evolution in the understanding of different materials and processes.
The authors acknowledge the Petrobras for Financial support. Moreover, we would like to express our gratitude toward Prof. Arnaldo C. Faro Jr. (from UFRJ) for H2-TPR and HDS catalytic tests facilities, and Prof. Renato B. Guimarães and Jackson A.L.C. Resende (from LDRx/UFF) for providing the XRD facilities.
The authors declare no conflict of interest.
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He also obtained an MSc in Molecular and Genetic Medicine, and a Ph.D. in Clinical Immunology and Human Genetics from the University of Sheffield, UK. He also completed a short-term fellowship in Pediatric Clinical Immunology and Bone Marrow Transplantation at Newcastle General Hospital, England. Dr. Rezaei is a Full Professor of Immunology and Vice Dean of International Affairs and Research, at the School of Medicine, Tehran University of Medical Sciences, and the co-founder and head of the Research Center for Immunodeficiencies. He is also the founding president of the Universal Scientific Education and Research Network (USERN). Dr. Rezaei has directed more than 100 research projects and has designed and participated in several international collaborative projects. He is an editor, editorial assistant, or editorial board member of more than forty international journals. He has edited more than 50 international books, presented more than 500 lectures/posters in congresses/meetings, and published more than 1,100 scientific papers in international journals.",institutionString:"Tehran University of Medical Sciences",institution:{name:"Tehran University of Medical Sciences",country:{name:"Iran"}}},{id:"180733",title:"Dr.",name:"Jean",middleName:null,surname:"Engohang-Ndong",slug:"jean-engohang-ndong",fullName:"Jean Engohang-Ndong",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/180733/images/system/180733.png",biography:"Dr. Jean Engohang-Ndong was born and raised in Gabon. After obtaining his Associate Degree of Science at the University of Science and Technology of Masuku, Gabon, he continued his education in France where he obtained his BS, MS, and Ph.D. in Medical Microbiology. He worked as a post-doctoral fellow at the Public Health Research Institute (PHRI), Newark, NJ for four years before accepting a three-year faculty position at Brigham Young University-Hawaii. Dr. Engohang-Ndong is a tenured faculty member with the academic rank of Full Professor at Kent State University, Ohio, where he teaches a wide range of biological science courses and pursues his research in medical and environmental microbiology. Recently, he expanded his research interest to epidemiology and biostatistics of chronic diseases in Gabon.",institutionString:"Kent State University",institution:{name:"Kent State University",country:{name:"United States of America"}}},{id:"188773",title:"Prof.",name:"Emmanuel",middleName:null,surname:"Drouet",slug:"emmanuel-drouet",fullName:"Emmanuel Drouet",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/188773/images/system/188773.png",biography:"Emmanuel Drouet, PharmD, is a Professor of Virology at the Faculty of Pharmacy, the University Grenoble-Alpes, France. As a head scientist at the Institute of Structural Biology in Grenoble, Dr. Drouet’s research investigates persisting viruses in humans (RNA and DNA viruses) and the balance with our host immune system. He focuses on these viruses’ effects on humans (both their impact on pathology and their symbiotic relationships in humans). He has an excellent track record in the herpesvirus field, and his group is engaged in clinical research in the field of Epstein-Barr virus diseases. He is the editor of the online Encyclopedia of Environment and he coordinates the Universal Health Coverage education program for the BioHealth Computing Schools of the European Institute of Science.",institutionString:null,institution:{name:"Grenoble Alpes University",country:{name:"France"}}},{id:"131400",title:"Prof.",name:"Alfonso J.",middleName:null,surname:"Rodriguez-Morales",slug:"alfonso-j.-rodriguez-morales",fullName:"Alfonso J. Rodriguez-Morales",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/131400/images/system/131400.png",biography:"Dr. Rodriguez-Morales is an expert in tropical and emerging diseases, particularly zoonotic and vector-borne diseases (especially arboviral diseases). He is the president of the Travel Medicine Committee of the Pan-American Infectious Diseases Association (API), as well as the president of the Colombian Association of Infectious Diseases (ACIN). He is a member of the Committee on Tropical Medicine, Zoonoses, and Travel Medicine of ACIN. He is a vice-president of the Latin American Society for Travel Medicine (SLAMVI) and a Member of the Council of the International Society for Infectious Diseases (ISID). Since 2014, he has been recognized as a Senior Researcher, at the Ministry of Science of Colombia. He is a professor at the Faculty of Medicine of the Fundacion Universitaria Autonoma de las Americas, in Pereira, Risaralda, Colombia. He is an External Professor, Master in Research on Tropical Medicine and International Health, Universitat de Barcelona, Spain. He is also a professor at the Master in Clinical Epidemiology and Biostatistics, Universidad Científica del Sur, Lima, Peru. In 2021 he has been awarded the “Raul Isturiz Award” Medal of the API. Also, in 2021, he was awarded with the “Jose Felix Patiño” Asclepius Staff Medal of the Colombian Medical College, due to his scientific contributions to COVID-19 during the pandemic. He is currently the Editor in Chief of the journal Travel Medicine and Infectious Diseases. His Scopus H index is 47 (Google Scholar H index, 68).",institutionString:"Institución Universitaria Visión de las Américas, Colombia",institution:null},{id:"332819",title:"Dr.",name:"Chukwudi Michael",middleName:"Michael",surname:"Egbuche",slug:"chukwudi-michael-egbuche",fullName:"Chukwudi Michael Egbuche",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/332819/images/14624_n.jpg",biography:"I an Dr. Chukwudi Michael Egbuche. I am a Senior Lecturer in the Department of Parasitology and Entomology, Nnamdi Azikiwe University, Awka.",institutionString:null,institution:{name:"Nnamdi Azikiwe University",country:{name:"Nigeria"}}},{id:"284232",title:"Mr.",name:"Nikunj",middleName:"U",surname:"Tandel",slug:"nikunj-tandel",fullName:"Nikunj Tandel",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/284232/images/8275_n.jpg",biography:'Mr. Nikunj Tandel has completed his Master\'s degree in Biotechnology from VIT University, India in the year of 2012. He is having 8 years of research experience especially in the field of malaria epidemiology, immunology, and nanoparticle-based drug delivery system against the infectious diseases, autoimmune disorders and cancer. He has worked for the NIH funded-International Center of Excellence in Malaria Research project "Center for the study of complex malaria in India (CSCMi)" in collaboration with New York University. The preliminary objectives of the study are to understand and develop the evidence-based tools and interventions for the control and prevention of malaria in different sites of the INDIA. Alongside, with the help of next-generation genomics study, the team has studied the antimalarial drug resistance in India. Further, he has extended his research in the development of Humanized mice for the study of liver-stage malaria and identification of molecular marker(s) for the Artemisinin resistance. At present, his research focuses on understanding the role of B cells in the activation of CD8+ T cells in malaria. Received the CSIR-SRF (Senior Research Fellow) award-2018, FIMSA (Federation of Immunological Societies of Asia-Oceania) Travel Bursary award to attend the IUIS-IIS-FIMSA Immunology course-2019',institutionString:"Nirma University",institution:{name:"Nirma University",country:{name:"India"}}},{id:"334383",title:"Ph.D.",name:"Simone",middleName:"Ulrich",surname:"Ulrich Picoli",slug:"simone-ulrich-picoli",fullName:"Simone Ulrich Picoli",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/334383/images/15919_n.jpg",biography:"Graduated in Pharmacy from Universidade Luterana do Brasil (1999), Master in Agricultural and Environmental Microbiology from Federal University of Rio Grande do Sul (2002), Specialization in Clinical Microbiology from Universidade de São Paulo, USP (2007) and PhD in Sciences in Gastroenterology and Hepatology (2012). She is currently an Adjunct Professor at Feevale University in Medicine and Biomedicine courses and a permanent professor of the Academic Master\\'s Degree in Virology. She has experience in the field of Microbiology, with an emphasis on Bacteriology, working mainly on the following topics: bacteriophages, bacterial resistance, clinical microbiology and food microbiology.",institutionString:null,institution:{name:"Universidade Feevale",country:{name:"Brazil"}}},{id:"229220",title:"Dr.",name:"Amjad",middleName:"Islam",surname:"Aqib",slug:"amjad-aqib",fullName:"Amjad Aqib",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/229220/images/system/229220.png",biography:"Dr. Amjad Islam Aqib obtained a DVM and MSc (Hons) from University of Agriculture Faisalabad (UAF), Pakistan, and a PhD from the University of Veterinary and Animal Sciences Lahore, Pakistan. Dr. Aqib joined the Department of Clinical Medicine and Surgery at UAF for one year as an assistant professor where he developed a research laboratory designated for pathogenic bacteria. Since 2018, he has been Assistant Professor/Officer in-charge, Department of Medicine, Manager Research Operations and Development-ORIC, and President One Health Club at Cholistan University of Veterinary and Animal Sciences, Bahawalpur, Pakistan. He has nearly 100 publications to his credit. His research interests include epidemiological patterns and molecular analysis of antimicrobial resistance and modulation and vaccine development against animal pathogens of public health concern.",institutionString:"Cholistan University of Veterinary and Animal Sciences",institution:null},{id:"62900",title:"Prof.",name:"Fethi",middleName:null,surname:"Derbel",slug:"fethi-derbel",fullName:"Fethi Derbel",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/62900/images/system/62900.jpeg",biography:"Professor Fethi Derbel was born in 1960 in Tunisia. He received his medical degree from the Sousse Faculty of Medicine at Sousse, University of Sousse, Tunisia. He completed his surgical residency in General Surgery at the University Hospital Farhat Hached of Sousse and was a member of the Unit of Liver Transplantation in the University of Rennes, France. He then worked in the Department of Surgery at the Sahloul University Hospital in Sousse. Professor Derbel is presently working at the Clinique les Oliviers, Sousse, Tunisia. His hospital activities are mostly concerned with laparoscopic, colorectal, pancreatic, hepatobiliary, and gastric surgery. He is also very interested in hernia surgery and performs ventral hernia repairs and inguinal hernia repairs. He has been a member of the GREPA and Tunisian Hernia Society (THS). During his residency, he managed patients suffering from diabetic foot, and he was very interested in this pathology. For this reason, he decided to coordinate a book project dealing with the diabetic foot. Professor Derbel has published many articles in journals and collaborates intensively with IntechOpen Access Publisher as an editor.",institutionString:"Clinique les Oliviers",institution:null},{id:"300144",title:"Dr.",name:"Meriem",middleName:null,surname:"Braiki",slug:"meriem-braiki",fullName:"Meriem Braiki",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/300144/images/system/300144.jpg",biography:"Dr. Meriem Braiki is a specialist in pediatric surgeon from Tunisia. She was born in 1985. She received her medical degree from the University of Medicine at Sousse, Tunisia. She achieved her surgical residency training periods in Pediatric Surgery departments at University Hospitals in Monastir, Tunis and France.\r\nShe is currently working at the Pediatric surgery department, Sidi Bouzid Hospital, Tunisia. Her hospital activities are mostly concerned with laparoscopic, parietal, urological and digestive surgery. She has published several articles in diffrent journals.",institutionString:"Sidi Bouzid Regional Hospital",institution:null},{id:"229481",title:"Dr.",name:"Erika M.",middleName:"Martins",surname:"de Carvalho",slug:"erika-m.-de-carvalho",fullName:"Erika M. de Carvalho",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/229481/images/6397_n.jpg",biography:null,institutionString:null,institution:{name:"Oswaldo Cruz Foundation",country:{name:"Brazil"}}},{id:"186537",title:"Prof.",name:"Tonay",middleName:null,surname:"Inceboz",slug:"tonay-inceboz",fullName:"Tonay Inceboz",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/186537/images/system/186537.jfif",biography:"I was graduated from Ege University of Medical Faculty (Turkey) in 1988 and completed his Med. PhD degree in Medical Parasitology at the same university. I became an Associate Professor in 2008 and Professor in 2014. I am currently working as a Professor at the Department of Medical Parasitology at Dokuz Eylul University, Izmir, Turkey.\n\nI have given many lectures, presentations in different academic meetings. I have more than 60 articles in peer-reviewed journals, 18 book chapters, 1 book editorship.\n\nMy research interests are Echinococcus granulosus, Echinococcus multilocularis (diagnosis, life cycle, in vitro and in vivo cultivation), and Trichomonas vaginalis (diagnosis, PCR, and in vitro cultivation).",institutionString:"Dokuz Eylül University",institution:{name:"Dokuz Eylül University",country:{name:"Turkey"}}},{id:"71812",title:"Prof.",name:"Hanem Fathy",middleName:"Fathy",surname:"Khater",slug:"hanem-fathy-khater",fullName:"Hanem Fathy Khater",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/71812/images/1167_n.jpg",biography:"Prof. Khater is a Professor of Parasitology at Benha University, Egypt. She studied for her doctoral degree, at the Department of Entomology, College of Agriculture, Food and Natural Resources, University of Missouri, Columbia, USA. She has completed her Ph.D. degrees in Parasitology in Egypt, from where she got the award for “the best scientific Ph.D. dissertation”. She worked at the School of Biological Sciences, Bristol, England, the UK in controlling insects of medical and veterinary importance as a grant from Newton Mosharafa, the British Council. Her research is focused on searching of pesticides against mosquitoes, house flies, lice, green bottle fly, camel nasal botfly, soft and hard ticks, mites, and the diamondback moth as well as control of several parasites using safe and natural materials to avoid drug resistances and environmental contamination.",institutionString:null,institution:{name:"Banha University",country:{name:"Egypt"}}},{id:"99780",title:"Prof.",name:"Omolade",middleName:"Olayinka",surname:"Okwa",slug:"omolade-okwa",fullName:"Omolade Okwa",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/99780/images/system/99780.jpg",biography:"Omolade Olayinka Okwa is presently a Professor of Parasitology at Lagos State University, Nigeria. She has a PhD in Parasitology (1997), an MSc in Cellular Parasitology (1992), and a BSc (Hons) Zoology (1990) all from the University of Ibadan, Nigeria. She teaches parasitology at the undergraduate and postgraduate levels. She was a recipient of a Commonwealth fellowship supported by British Council tenable at the Centre for Entomology and Parasitology (CAEP), Keele University, United Kingdom between 2004 and 2005. She was awarded an Honorary Visiting Research Fellow at the same university from 2005 to 2007. \nShe has been an external examiner to the Department of Veterinary Microbiology and Parasitology, University of Ibadan, MSc programme between 2010 and 2012. She is a member of the Nigerian Society of Experimental Biology (NISEB), Parasitology and Public Health Society of Nigeria (PPSN), Science Association of Nigeria (SAN), Zoological Society of Nigeria (ZSN), and is Vice Chairperson of the Organisation of Women in Science (OWSG), LASU chapter. She served as Head of Department of Zoology and Environmental Biology, Lagos State University from 2007 to 2010 and 2014 to 2016. 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