Increase of carbon fiber composites for aircraft application.
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Barely three months into the new year and we are happy to announce a monumental milestone reached - 150 million downloads.
\n\nThis achievement solidifies IntechOpen’s place as a pioneer in Open Access publishing and the home to some of the most relevant scientific research available through Open Access.
\n\nWe are so proud to have worked with so many bright minds throughout the years who have helped us spread knowledge through the power of Open Access and we look forward to continuing to support some of the greatest thinkers of our day.
\n\nThank you for making IntechOpen your place of learning, sharing, and discovery, and here’s to 150 million more!
\n\n\n\n\n'}],latestNews:[{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"},{slug:"introducing-intechopen-book-series-a-new-publishing-format-for-oa-books-20210915",title:"Introducing IntechOpen Book Series - A New Publishing Format for OA Books"},{slug:"intechopen-identified-as-one-of-the-most-significant-contributor-to-oa-book-growth-in-doab-20210809",title:"IntechOpen Identified as One of the Most Significant Contributors to OA Book Growth in DOAB"}]},book:{item:{type:"book",id:"7173",leadTitle:null,fullTitle:"Multiple Pregnancy - New Challenges",title:"Multiple Pregnancy",subtitle:"New Challenges",reviewType:"peer-reviewed",abstract:"Multiple Pregnancy - New Challenges is a comprehensive book, written in an organized and concise format. The book offers an immersion into multiple pregnancy. Each chapter presents the reader with various important issues related to the subject matter. The book covers all spectrums of multiple pregnancy such as epidemiology, etiology, diagnosis, prenatal care, unique complications in monochorionic pregnancies, preterm birth and mode of delivery. Through its 10 chapters the book contemplates the most relevant aspects of multiple pregnancy. Authors from all over the world have contributed to this book, bringing the best from their research experiences. The book give the reader a state-of-the-art update of multiple pregnancy.",isbn:"978-1-78985-080-2",printIsbn:"978-1-78985-079-6",pdfIsbn:"978-1-83881-764-0",doi:"10.5772/intechopen.73973",price:119,priceEur:129,priceUsd:155,slug:"multiple-pregnancy-new-challenges",numberOfPages:232,isOpenForSubmission:!1,isInWos:1,isInBkci:!1,hash:"f599a465410812da5aee0b247d427e9b",bookSignature:"Julio Elito Jr.",publishedDate:"January 30th 2019",coverURL:"https://cdn.intechopen.com/books/images_new/7173.jpg",numberOfDownloads:11750,numberOfWosCitations:2,numberOfCrossrefCitations:5,numberOfCrossrefCitationsByBook:0,numberOfDimensionsCitations:9,numberOfDimensionsCitationsByBook:0,hasAltmetrics:0,numberOfTotalCitations:16,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"February 22nd 2018",dateEndSecondStepPublish:"March 15th 2018",dateEndThirdStepPublish:"May 14th 2018",dateEndFourthStepPublish:"August 2nd 2018",dateEndFifthStepPublish:"October 1st 2018",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"35132",title:"Prof.",name:"Julio",middleName:null,surname:"Elito Jr.",slug:"julio-elito-jr.",fullName:"Julio Elito Jr.",profilePictureURL:"https://mts.intechopen.com/storage/users/35132/images/system/35132.jpeg",biography:"Prof. Julio Elito Junior PhD graduated in Medicine from Federal University of São Paulo (UNIFESP) - Brazil in1989. He obtained his Master in 1995 and his Doctorate in 1997 both from UNIFESP. He is a specialist in laparoscopy (Cleveland Clinic Foundation, 2000) and has a PhD in reproductive medicine (2008). Due to the relevance of his research he obtained the title of Associate Professor of the Department of Obstetrics of UNIFESP (2006). He has experience in the field of Medicine, with emphasis in Gynecology and Obstetrics, acting mainly in the following subjects: ectopic pregnancy, methotrexate, ultrasonography, beta-hCG, polymorphisms, serological markers and multiple pregnancy. He has published a predictive score for medical treatment in ectopic pregnancy and reference charts for twins. He has published 68 articles in international and national journals, is a reviewer in several national and international journals, and a speaker at a number of national and international congresses. He wrote the book 'Ectopic Pregnancy' (2010), was an editor of the books 'Multiple Pregnancy - New Challenges' (2019) and 'Non-Tubal Ectopic Pregnancy' (2020), as well as an author of numerous chapters in national and international books. He has been nominated several times as an honored Professor by his students at the Medical School of Federal University of São Paulo (UNIFESP).",institutionString:"Federal University of Sao Paulo",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"3",totalChapterViews:"0",totalEditedBooks:"2",institution:{name:"Federal University of Sao Paulo",institutionURL:null,country:{name:"Brazil"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"1067",title:"Maternal-Fetal Medicine",slug:"maternal-fetal-medicine"}],chapters:[{id:"62717",title:"Historical Studies of Hellin’s Law",doi:"10.5772/intechopen.79583",slug:"historical-studies-of-hellin-s-law",totalDownloads:928,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Theorems, proofs, laws and rules are commonly named according to the presumed discoverer, but often earlier investigators have contributed substantially to the findings. One example of this is Hellin’s law, which was named after Hellin, although he was not the first to derive it. In research on twinning and higher multiple maternities, the law has played a central role because it is approximately correct, despite showing discrepancies that are difficult to explain or eliminate. However, most studies are based on empirical rates of multiple maternities. Such studies can only serve to identify errors too large to be characterized as random. It has been mathematically proven that Hellin’s law does not hold as a general rule. Consequently, improvements to this law have been proposed.",signatures:"Johan Fellman",downloadPdfUrl:"/chapter/pdf-download/62717",previewPdfUrl:"/chapter/pdf-preview/62717",authors:[{id:"249480",title:"Prof.",name:"Johan",surname:"Fellman",slug:"johan-fellman",fullName:"Johan Fellman"}],corrections:null},{id:"62902",title:"Twinning as an Evolved Age-Dependent Physiological Mechanism: Evidence from Large Brazilian Samples",doi:"10.5772/intechopen.79907",slug:"twinning-as-an-evolved-age-dependent-physiological-mechanism-evidence-from-large-brazilian-samples",totalDownloads:945,totalCrossrefCites:0,totalDimensionsCites:4,hasAltmetrics:0,abstract:"Multiple pregnancies occur in humans and other primates, which indicate that the twinning propensity is phylogenetically old. Factors such as decreased sexual dimorphism and size, rich and diverse nutrition and paternal care are related to multiple pregnancies in other animals. In human populations, despite its costs, twinning has a genetic basis and in Europe, Africa, and America, it was found that it increases mothers’ fitness. Here, we explore the hypothesis that twinning represents an evolved physiological mechanism, particularly in mothers of higher age, as an ‘all-or-nothing’ last chance strategy for reproduction just before menopause. We present decade-long, large-scale population data about maternities from the city of São Paulo and the entire country of Brazil that indicate a considerable main effect of advanced age in promoting twinning, particularly dizygotic (DZ) twinning, but also monozygotic (MZ) twinning and higher order maternities. We also show that socioeconomic status is an important contextual factor increasing twinning. Besides the theoretical implications, these datasets establish a Brazilian countrywide twinning rate of 9.39‰ and highlight an increasing historical trend. This chapter promotes the importance of integrating proximate patterns from human and nonhuman animals and evolutionary factors in order to reach a comprehensive view about twinning.",signatures:"Marco Varella, Eloisa Fernandes, Jonas Arantes, Tiziana Acquaviva,\nTania Lucci, Rafael Hsu, Vinicius David, Vera Bussab, Jaroslava\nValentova, Nancy Segal and Emma Otta",downloadPdfUrl:"/chapter/pdf-download/62902",previewPdfUrl:"/chapter/pdf-preview/62902",authors:[{id:"249634",title:"Ph.D.",name:"Marco",surname:"Varella",slug:"marco-varella",fullName:"Marco Varella"},{id:"249637",title:"Ms.",name:"Eloisa",surname:"Fernandes",slug:"eloisa-fernandes",fullName:"Eloisa Fernandes"},{id:"249640",title:"Mr.",name:"Jonas",surname:"Arantes",slug:"jonas-arantes",fullName:"Jonas Arantes"},{id:"249642",title:"BSc.",name:"Tiziana",surname:"Acquaviva",slug:"tiziana-acquaviva",fullName:"Tiziana Acquaviva"},{id:"249643",title:"MSc.",name:"Tania",surname:"Lucci",slug:"tania-lucci",fullName:"Tania Lucci"},{id:"249644",title:"MSc.",name:"Vinicius",surname:"David",slug:"vinicius-david",fullName:"Vinicius David"},{id:"249645",title:"Prof.",name:"Vera",surname:"Bussab",slug:"vera-bussab",fullName:"Vera Bussab"},{id:"249648",title:"Prof.",name:"Jaroslava",surname:"Valentova",slug:"jaroslava-valentova",fullName:"Jaroslava Valentova"},{id:"249650",title:"Prof.",name:"Nancy",surname:"Segal",slug:"nancy-segal",fullName:"Nancy Segal"},{id:"249651",title:"Prof.",name:"Emma",surname:"Otta",slug:"emma-otta",fullName:"Emma Otta"},{id:"260852",title:"BSc.",name:"Rafael",surname:"Hsu",slug:"rafael-hsu",fullName:"Rafael Hsu"}],corrections:null},{id:"62326",title:"Judicious Fertility Treatment to Minimise the Risk of Multiple Pregnancy",doi:"10.5772/intechopen.79288",slug:"judicious-fertility-treatment-to-minimise-the-risk-of-multiple-pregnancy",totalDownloads:983,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Pregnancies resulting from fertility treatment are associated with higher rates of multiple pregnancy and have higher rates of pregnancy complications than spontaneously conceived pregnancies. Methods exist to make fertility treatment safer and less likely to result in multiple pregnancy and practitioners should be practicing fertility treatment with the aim to produce a healthy, term, singleton pregnancy. Approaches to minimising the risk of multiple pregnancy include carefully monitoring ovulation induction (OI) cycles to produce mono-follicular ovulation. Identifying patients at risk of excessive response to ovulation induction and treating them with low dose therapies and close monitoring is a critical step in practicing safe OI treatment. Performing single embryo transfer in all but exceptional cases of in-vitro fertilisation (IVF), and never transferring more than two embryos, is the single, most successful way to reduce the multiple pregnancy rate with IVF. An appreciation of the increased risk of mono-chorionic twinning with IVF is also important. This chapter will explore ways to minimise the risk of multiple pregnancy with a variety of fertility treatments.",signatures:"Fiona Langdon and Roger Hart",downloadPdfUrl:"/chapter/pdf-download/62326",previewPdfUrl:"/chapter/pdf-preview/62326",authors:[{id:"187858",title:"Prof.",name:"Roger",surname:"Hart",slug:"roger-hart",fullName:"Roger Hart"},{id:"248046",title:"Dr.",name:"Fiona",surname:"Langdon",slug:"fiona-langdon",fullName:"Fiona Langdon"}],corrections:null},{id:"64141",title:"Early Pregnancy Ultrasound Assessment of Multiple Pregnancy",doi:"10.5772/intechopen.81498",slug:"early-pregnancy-ultrasound-assessment-of-multiple-pregnancy",totalDownloads:1715,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"As the frequency of multiple pregnancies is increasing, every obstetrician has to know that the correct, accurate, and timely determination of gestational age, chorionicity, and amnionicity has significant importance in the management of a multiple pregnancy. Surveillance, complications, outcome, morbidity, and mortality are totally different in a monochorionic and a dichorionic pregnancy. In this chapter, we will present the sonographic figures that are visualized in the first trimester in a multiple pregnancy and help us define the gestational age, chorionicity, and amnionicity. We will classify them into two periods: the early first trimester, including the 10 first weeks of gestation and the late first trimester including the period between the 10th and 14th week of gestation. Finally, we will review some interesting, although infrequent, cases from the literature, showing that pitfalls in the determination of both chorionicity and amnionicity exist and highlighting the importance of being aware of their subsistence.",signatures:"Panagiotis Antsaklis, Maria Papamichail, Marianna Theodora,\nMichael Syndos and George Daskalakis",downloadPdfUrl:"/chapter/pdf-download/64141",previewPdfUrl:"/chapter/pdf-preview/64141",authors:[{id:"64707",title:"Dr.",name:"George",surname:"Daskalakis",slug:"george-daskalakis",fullName:"George Daskalakis"},{id:"202113",title:"Dr.",name:"Panagiotis",surname:"Antsaklis",slug:"panagiotis-antsaklis",fullName:"Panagiotis Antsaklis"},{id:"253908",title:"Dr.",name:"Marianna",surname:"Theodora",slug:"marianna-theodora",fullName:"Marianna Theodora"},{id:"268350",title:"Dr.",name:"Maria",surname:"Papamichail",slug:"maria-papamichail",fullName:"Maria Papamichail"},{id:"268351",title:"Dr.",name:"Michael",surname:"Sindos",slug:"michael-sindos",fullName:"Michael Sindos"}],corrections:null},{id:"62365",title:"Prenatal Attachment in Twin Pregnancy",doi:"10.5772/intechopen.79365",slug:"prenatal-attachment-in-twin-pregnancy",totalDownloads:918,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:0,abstract:"Twin births are associated with several medical, healthcare, socio-emotional, psychological and developmental consequences for families. Parents generally describe twin pregnancies as physically and emotionally difficult. Moreover, compared to singleton pregnancies, twin pregnancies are reported to carry higher maternal as well as perinatal morbidity and mortality. The aim of this chapter is to review literature on twin pregnancy and to give a comprehensive framework about parents’ experience of expecting twins. An important issue related to the psychological adjustment during twin pregnancies is prenatal attachment. During pregnancy, mothers use to think about their child-to-be, and they start to create representation of themselves as mothers. Prenatal attachment in twin pregnancies may differ from that in singleton ones. During a twin pregnancy, the mother-to-be has to deal with an identification process with two children at the same time and have to create a mental space that allow her to make representation of both children. The monitoring of these pregnancies is important for the creation and the consolidation of these maternal representations: ultrasound examinations revealed the fetal gender that facilitates naming the unborn twins and thinking to them as individuals and this is particularly important in the case of complicated twin pregnancies.",signatures:"Chiara Ionio, Eleonora Mascheroni, Caterina Colombo and Gianluca\nLista",downloadPdfUrl:"/chapter/pdf-download/62365",previewPdfUrl:"/chapter/pdf-preview/62365",authors:[{id:"249605",title:"Ph.D.",name:"Chiara",surname:"Ionio",slug:"chiara-ionio",fullName:"Chiara Ionio"},{id:"250201",title:"Dr.",name:"Eleonora",surname:"Mascheroni",slug:"eleonora-mascheroni",fullName:"Eleonora Mascheroni"},{id:"250202",title:"Dr.",name:"Caterina",surname:"Colombo",slug:"caterina-colombo",fullName:"Caterina Colombo"},{id:"250203",title:"Dr.",name:"Gianluca",surname:"Lista",slug:"gianluca-lista",fullName:"Gianluca Lista"}],corrections:null},{id:"64174",title:"Multiple Pregnancy in Women of Advanced Reproductive Age",doi:"10.5772/intechopen.81096",slug:"multiple-pregnancy-in-women-of-advanced-reproductive-age",totalDownloads:1326,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Assisted reproduction techniques (ARTs) allow women of advanced reproductive age to become pregnant. One of the most frequent complications of ART is twin pregnancy. Cases where both factors are present represent a specially vulnerable population for obstetric complications and medical perinatal and post-partum consequences for both the mother and babies. Pre-existing medical conditions are more frequent at advanced age, and the pregnancy physiological changes and the high metabolic demand associated with a twin pregnancy may reveal or worsen any previous disease. A careful counselling process is very important in this population and certain obstetric interventions might be particularly addressed to it. Single embryo transfer should be strongly enforced in advanced age women to minimise risk for the mother and children.",signatures:"Laura Pérez Martín and Duna Trobo Marina",downloadPdfUrl:"/chapter/pdf-download/64174",previewPdfUrl:"/chapter/pdf-preview/64174",authors:[{id:"247905",title:"M.Sc.",name:"Laura",surname:"Pérez Martín",slug:"laura-perez-martin",fullName:"Laura Pérez Martín"},{id:"270035",title:"MSc.",name:"Duna",surname:"Trobo Marina",slug:"duna-trobo-marina",fullName:"Duna Trobo Marina"}],corrections:null},{id:"65160",title:"Complications in Monochorionic Pregnancies",doi:"10.5772/intechopen.83390",slug:"complications-in-monochorionic-pregnancies",totalDownloads:1135,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Monochorionic (MC) pregnancies have higher rates of fetal morbidity and mortality when compared to dichorionic (DC) ones. Therefore, the early diagnostic of chorionicity is of great importance. Monochorionic pregnancies have specific complications such as twin to twin transfusion syndrome (TTTS), selective fetal growth restriction (sFGR), twin anemia polycythemia sequence (TAPS), and twin reversed arterial perfusion sequence (TRAPS). MC pregnancies have several unique and serious complications that contribute to a perinatal mortality rate of 11%. The pathophysiology of most of these complications is related to the placental angio-architecture, and it results from an unbalanced perfusion between the fetuses. The screening of TTTS starts in 16 weeks with a sonographic follow-up every 2 weeks. In the last decade, there was an improvement in the treatment of TTTS. With the advent of the fetoscopic laser photocoagulation (FLPC), there was a drastic increase in the survival rate of the fetuses with TTTS when compared with serial amnioreduction. Besides that, in TRAPS, fetoscopic procedures such as cord occlusion improve the outcome of the normal fetus. We will also discuss sFGR and its classification and management. The aim of this chapter is to review the most important complications in MC pregnancies.",signatures:"Bruno Rodrigues Toneto",downloadPdfUrl:"/chapter/pdf-download/65160",previewPdfUrl:"/chapter/pdf-preview/65160",authors:[{id:"280542",title:"Dr.",name:"Bruno",surname:"Toneto",slug:"bruno-toneto",fullName:"Bruno Toneto"}],corrections:null},{id:"62984",title:"Quadruplets and Quintuplets",doi:"10.5772/intechopen.80338",slug:"quadruplets-and-quintuplets",totalDownloads:1105,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"A high-order pregnancy is always a challenge not only for the couple but also for the obstetrician, the pediatricians, the midwives, and the whole stuff of an obstetric clinic. The breakthroughs of infertility treatments have made more couples to postpone the birth of their children until they feel professionally and financially safe, many times after the age of 40. The advanced age of the mother puts extra pressure to the clinician for immediate success, leading to a rise of high-order pregnancies until the introduction of regulations and laws in many countries. The cost of a quadruplet and quintuplet pregnancy can be unbearable, not only financially but also psychologically. The management of such a pregnancy is also challenging since its beginning and to the end. Modern techniques and methods can also be difficult to be implemented on a quadruplet of quintuplet pregnancy because of the fear of losing four or five embryos at once. At the same time, the limited number of cases makes it almost impossible for studies to be made and guidelines to be established for most of the cases.",signatures:"Stelios Fiorentzis, Styliani Salta, Michail Pargianas, Artemis\nPontikaki, Dimitrios P. Koutsoulis, Christodoulos Akrivis, Dimitrios\nAkrivis and Ioannis Kosmas",downloadPdfUrl:"/chapter/pdf-download/62984",previewPdfUrl:"/chapter/pdf-preview/62984",authors:[{id:"40721",title:"Dr.",name:"Ioannis",surname:"Kosmas",slug:"ioannis-kosmas",fullName:"Ioannis Kosmas"},{id:"261850",title:"Dr.",name:"Stelios",surname:"Fiorentzis",slug:"stelios-fiorentzis",fullName:"Stelios Fiorentzis"},{id:"261851",title:"Dr.",name:"Styliani",surname:"Salta",slug:"styliani-salta",fullName:"Styliani Salta"},{id:"261860",title:"Ph.D. Student",name:"Michail",surname:"Pargianas",slug:"michail-pargianas",fullName:"Michail Pargianas"},{id:"261865",title:"Mrs.",name:"Artemis",surname:"Pontikaki",slug:"artemis-pontikaki",fullName:"Artemis Pontikaki"},{id:"261883",title:"Mr.",name:"Dimitrios",surname:"Koutsoulis",slug:"dimitrios-koutsoulis",fullName:"Dimitrios Koutsoulis"},{id:"261884",title:"Dr.",name:"Christodoulos",surname:"Akrivis",slug:"christodoulos-akrivis",fullName:"Christodoulos Akrivis"},{id:"261900",title:"Dr.",name:"Dimitrios",surname:"Akrivis",slug:"dimitrios-akrivis",fullName:"Dimitrios Akrivis"}],corrections:null},{id:"64795",title:"Preterm Birth in Twins",doi:"10.5772/intechopen.82447",slug:"preterm-birth-in-twins",totalDownloads:1097,totalCrossrefCites:2,totalDimensionsCites:2,hasAltmetrics:0,abstract:"Multiple pregnancy differs from singleton pregnancy in several aspects, including increased risk of preeclampsia, fetal malformation, maternal morbidity, and mortality. However, certainly, prematurity is a fundamental concern when twin gestation is approached, due to the frequency of this disease and also to the severity of preterm birth, which unfortunately can also occur near to the fetal viability limit. Labor in twin pregnancy generally occurs before singleton pregnancy. Nevertheless, another factor can contribute to raise even more preterm birth rates in this already high-risk gestation: the short cervix. Although only 1–2% of twin pregnancy present short cervix at transvaginal ultrasound, this association increases the chance of unfavorable outcome for the newborn, frequently causing death of one or both twins. So, many strategies were proposed to minimize this catastrophic situation: follow-up of cervical length to prevent preterm birth, pessary use, progesterone, tocolysis to postpone birth in 48 hours to 7 days in order to use corticosteroids in fetal pulmonary maturation, and magnesium sulfate use to neuroprotection.",signatures:"Marcelo Santucci Franca, Tatiana E. N. K. Hamamoto and Antônio\nFernandes Moron",downloadPdfUrl:"/chapter/pdf-download/64795",previewPdfUrl:"/chapter/pdf-preview/64795",authors:[{id:"35330",title:"Prof.",name:"Antonio",surname:"Moron",slug:"antonio-moron",fullName:"Antonio Moron"},{id:"278444",title:"Dr.",name:"Marcelo",surname:"Santucci Franca",slug:"marcelo-santucci-franca",fullName:"Marcelo Santucci Franca"},{id:"278446",title:"Dr.",name:"Tatiana Emy",surname:"Kawanami Hamamoto",slug:"tatiana-emy-kawanami-hamamoto",fullName:"Tatiana Emy Kawanami Hamamoto"}],corrections:null},{id:"63089",title:"Time and Mode of Delivery in Twin Pregnancies",doi:"10.5772/intechopen.80092",slug:"time-and-mode-of-delivery-in-twin-pregnancies",totalDownloads:1604,totalCrossrefCites:2,totalDimensionsCites:2,hasAltmetrics:0,abstract:"There are many suitable recommendations for twin gestation term in the literature. In many protocols, resolution is recommended for dichorionic pregnancies around 38 weeks, at 36 weeks for monochorionic (devoid of complications) and at 32–34 weeks in cases of single amniotic chamber. The main risk associated with vaginal delivery is connected to the possibility of anoxia of the second twin. However, a cesarean delivery performed by non-cephalic presentation of the second twin is associated with increased maternal morbidity without improved neonatal outcome. The most important factors in the decision of the delivery mode include the presentation of the fetus, gestational age, and weight or the weight difference between the fetuses.",signatures:"Eduardo Félix Martins Santana, Vivian Melo Corrêa, Isabela Bottura\nand José Pedro Parise Filho",downloadPdfUrl:"/chapter/pdf-download/63089",previewPdfUrl:"/chapter/pdf-preview/63089",authors:[{id:"171791",title:"Ph.D.",name:"Eduardo",surname:"Santana",slug:"eduardo-santana",fullName:"Eduardo Santana"},{id:"249917",title:"Dr.",name:"Vivian",surname:"Melo Correa",slug:"vivian-melo-correa",fullName:"Vivian Melo Correa"},{id:"251239",title:"Dr.",name:"Isabela",surname:"Bottura",slug:"isabela-bottura",fullName:"Isabela Bottura"},{id:"256945",title:"Dr.",name:"José Pedro",surname:"Parise Filho",slug:"jose-pedro-parise-filho",fullName:"José Pedro Parise Filho"}],corrections:null}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},subseries:null,tags:null},relatedBooks:[{type:"book",id:"8484",title:"Non-tubal Ectopic Pregnancy",subtitle:null,isOpenForSubmission:!1,hash:"f3168b3b6a134f1664b6dfa5e15368e2",slug:"non-tubal-ectopic-pregnancy",bookSignature:"Julio Elito Jr.",coverURL:"https://cdn.intechopen.com/books/images_new/8484.jpg",editedByType:"Edited by",editors:[{id:"35132",title:"Prof.",name:"Julio",surname:"Elito Jr.",slug:"julio-elito-jr.",fullName:"Julio Elito Jr."}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"776",title:"Preterm Birth",subtitle:"Mother and Child",isOpenForSubmission:!1,hash:"4e5369103770cdbf61058ad75e2e63bb",slug:"preterm-birth-mother-and-child",bookSignature:"John C. 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\r\n\tOver these last decades, ionic liquids were found suitable in the world of industry. Due to their specific properties such as very low volatility, high thermal stability, and their ability to dissolve a wide variety of compounds, this family of solvents appears to meet the rigorous criteria of industrial applications. Among others, ionic liquids appear to be efficient for gas capture, biomass pretreatment, separation problems, electrochemistry; they are also used in electrolytes, as lubricants, as catalysts, or as antistatic agents.
\r\n\r\n\tThis book welcomes topics related to biomass pretreatment, separation processes, analytical chemistry, energy applications, and biomedicine applications using ionic liquids. A short chapter will be devoted to the physicochemical properties of ionic liquids as well as to the predictive models for the estimation of thermodynamic properties useful in the industry. This book is recommended for researchers to whom ionic liquids are an area of interest.
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Figure 1 shows a Boeing 787 aircraft contains 50% by weight of its materials as composites, which is about 32,000 kg of carbon-fiber-reinforced polymer (CFRP) [1].
Boeing 787 aircraft contains 50% of composite materials.
The carbon fiber composites have a higher strength-to-weight ratio than traditional metal materials thus help making the aircraft lighter and to exceed the fuel efficiency target. Due to this important feature, the use of fiber reinforced composite laminates as primary structural components in these important large-scale and weight-critical applications has increased considerably (Table 1). Aircrafts with major composite parts including fuselage, wings, tail sections, doors and interior are presently being developed and gradually brought into service.
Year | 1982 | 1995 | 2006 | 2008 |
---|---|---|---|---|
Model | Boeing 767 | Boeing 777 | Airbus 380 | Boeing 787 |
Structures | Secondary | Primary/Secondary | Primary/Secondary | Primary/Secondary |
Amount of CFRP/aircraft | 1.5 tons | Approx. 10 tons | Approx. 35 tons | Approx. 35 tons |
Amount of CF/aircraft | 1 ton | Approx. 7 tons | Approx. 23 tons | Approx. 23 tons. |
Increase of carbon fiber composites for aircraft application.
For better efficiency in terms of strength and weight-optimization, aerospace structures are frequently appended with stiffener components. Figure 2 shows a 787’s disassembled composite fuselage section which is composed of hat-stiffened composite panels that represent the design methodology of meeting the high stiffness while keeping the minimal weight requirements. This laminated composite stiffened panel is a critical component and extensively used structure in aircrafts, and can operate when subjected to harsh environments such as severe dynamic loading.
Disassembled composite fuselage section of the Boeing 787.
Many work have been done on design and analysis of hat-stiffener structures. Recent advances in performing global and detailed analyses have made it possible to determine failure modes, strength, durability, and damage tolerance of composite structures with confidence. Bhar et al. [2] performed linearly elastic static and natural vibration analysis using an extended HSDT (higher-order shear deformation theory). Kim et al. [3] manufactured stiffened panels using co-curing, co-bonding and secondary bonding processes and evaluated them using 3D measurement and ultrasonic tester. Lauterbach et al. [4] built analysis tools including an approach for predicting interlaminar damage initiation and degradation models for capturing interlaminar damage growth as well as in plane damage mechanisms. Gangadhara et al. [5] analyzed stiffened panels using formulation based on the concept of equal displacements at the shell-stiffener interface. Kumar et al. studied the transient response of laminated stiffened plates using MSC/Patran and LS-DYNA3D [6] and Kristinsdottir et al. [7] presented an optimization formulation for the design of large panels when loads vary over the panel. Junhou et al. and Shenoi et al. [8, 9] examined the key aspects defining the performance characteristics of hat-stiffener joints in marine structures. Paul et al. [10] performed an integrated step-by-step design and analysis procedure for the hat-stiffened panels loaded in axial compression using the computer code BUSTCOP. Xiong and coworkers [11] has tested and analyzed the buckling and failure loads of hat-stiffened composite panels. Other research work have been focused on FEA modeling [12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22], manufacturing [23, 24, 25, 26, 27, 28, 29], evaluation of microstructures and damage evolution [30, 31, 32, 33], and the enhancement of the mechanical properties [34, 35, 36, 37] of composites at both materials- and structures-level.
Most commercial CAD/FEA software has included some form of parameterization of design variables. Basic research-level higher order structural elements are also developed. These tools allow quick, easy and accurate topology and geometry model creation with design constraints, implicit parameterization for easy model variation, integrated Finite Element generator, models and components storage in library for generation of knowledge database and reusability, shape and size optimization in a closed batch loop, on-the-fly definition of design variables and design space, and integration of specific applications like commercial optimization and design tools. In this work, we plan to utilize these aspects to create a Higher Order Abstract Structural Elements, later abbreviated as HOASE.
The goals and key feature of this work include analyzing the geometric parameter sensitivity of the hat stiffener, and developing and demonstrating a proof-of-concept theoretical model which is a parametric analytical solution that is theoretically equivalent to hat-stiffener stiffened panels in mechanical response. The analytical solution contains parametric information incorporating geometric, design allowables, and manufacturing information such as laminate stacking order. The constructions of these equivalent analytical models will be stored in a database from which they can be easily retrieved and parametrically modified.
Achieving the above requires specific technical objectives including:
Select composite ply materials and corresponding stochastic material properties for tracking them to parametric design allowables.
Explore the design space and using Finite Element Method (FEM) to analyze the parametrical sensitivity of the basic composite structural elements: hat stiffeners.
Develop an equivalent model using analytical solution and run case studies for various loading conditions to develop the empirical relationships between design parameters and allowables/performance. This takes into account the key geometric and material parameters and gives a higher and lower boundary of the relatively equivalent hat-stiffener stiffened panel.
Manufacture hat-stiffened composite panel and perform experimental investigation to compare its mechanical response with FEA models’ prediction and the mechanical response bounds resulting from the analytical models. Finally, this work would provide the aviation industry with a parametric databases of hat stiffener design and analysis.
In this work, hat stiffeners and plates were selected as basic elements for parametric analysis and for constructing an analytical solution. The plate element is an orthotropic laminated element with material, number of plies, stacking sequence, width, length, and thickness parameters. The hat stiffener element is also parametrically defined in terms of several geometric parameters as shown in Figure 3.
Hat stiffener basic element with geometric parameters.
FEM was utilized to produce sensitivity of structural behavior (deflection, stresses) to basic elements’ parameters and for comparing final experimental results with modeling. Laminated plate, hat-stiffener, hat-stiffener bonded to base plate were modeled in MSC NASTRAN for this purpose. Laminated plate modeling in FEM is routine and therefore not discussed for the sake of brevity. The hat stiffener (with and without plate to which it is bonded) are modeled as follows. Height of the stiffener web (h), width of the stiffener cap (W1), bottom width in between stiffener flanges (W2), width of the stiffener flange (due to symmetric, the left and right width are the both L1) are the geometric parameters considered in addition to thickness of a ply, ply orientation and the stacking sequence. The length of the hat stiffener is fixed at 508 mm (which is 20 inches).
Material properties are taken from Cytec information sheet CYCOM 5320 [12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37]. These unidirectional fiber tape tensile properties are:
E1 = 1.59E5 MPa;
E2 = 9.3E3 MPa;
Poisson’s Ratio v = 0.336;
Shear modulus G12 = G13 = 5.6E3 MPa.
QUAD4 MSC Nastran element and PCOMP material properties input was used for analysis. A uniform pressure of 6.89E-2 MPa is applied on each of the two bottom flange surfaces for the hat-stiffener simulation. For the second set of simulations, same magnitude of pressure, 6.89E-2 MPa is applied on the plate to which hat-stiffener is bonded. Longitudinal edges are free to rotate but not translate (Tx = Ty = Tz = 0). The transverse direction edges are free. These longitudinal edge boundary conditions represent fixed edges rather than simply supported, because edge cross sections are constrained from rotation. Same boundary conditions for flat plates will represent simply supported conditions.
Longitudinal edges (the two edges of the skin plate only, not including hat stiffener web and top cap) are simply supported as Tx = Ty = Tz = 0 for hat stiffener bonded to the plate. The transverse edges of the plate are subjected to the boundary conditions Tx = Ry = Rz = 0, corresponding to all four edges simply supported. These boundary conditions are chosen to demonstrate extreme sensitivity of structural response to boundary conditions.
To study the sensitivity of hat-stiffener’s geometric parameters, hat-stiffener models are created first. The hat-stiffener element is modeled and analyzed using MSC NASTRAN to construct parametric design space. As presented in the last section, design parameters were defined for hat-stiffeners. The parametric range and increments we defined here covered most of the practical design exploration space and are summarized in Table 2.
Hat-stiffener parametric design exploration space.
These parametric variations represent 1680 models and design points. A smaller set of parameter combinations are analyzed to get the design trends. We explored maximum specific bending rigidity contribution of hat-stiffeners to membrane skin which is designed to take torsional shear. Representative 10 psi uniform pressure loading and simply supported boundary conditions on a 508 mm (20 inches) long hat cross section beam are analyzed. The cross-sectional area of hat-stiffeners varies with design parameters. A baseline configuration with minimum cross-sectional area is chosen to illustrate effect of parameters on bending. This configuration represents 12.7 mm (0.5 inch) bottom flange length, 25.4 mm (1 inch) bottom hat width, 12.7 mm (0.5 inch) top hat width, 12.7 mm (0.5 inch) hat height, 1.016 mm (0.04 inch) thickness and [0/90/45/−45]s stacking order.
Figure 4 shows the mid-point transverse deflection and maximum flexural stress at mid-point on the beam as a percent change from the baseline configuration. Stacking sequence and therefore corresponding laminate thickness is kept constant. The ratio of top and bottom hat widths is kept constant at 0.5 for all parametric variations. Three curve-sets show variation of deflection and flexural longitudinal stress with hat height, width and bottom flange length, respectively. As expected, it is evident that bottom flange length contribution is minimal to the flexural behavior of the stiffener. The maximum change in bending rigidity is achieved by changing hat height up to three times the top flange width.
Hat stiffener basic element bending behavior.
A proof-of-concept analytical model consists of a rectangular plate stiffened by several hat stiffeners was established in MATLAB.
Figure 5 shows steps incorporated in constructing the analytical model. Composite ply properties, stacking sequence for hat and plate laminates, plate and hat stiffener geometric parameters, stiffener spacing, boundary conditions and loading are specified for the analytical model. Orthotropic plate properties are obtained by scaling, homogenizing and distributing stiffener properties over the space between the stiffeners.
Equivalent orthotropic plate for hat-stiffener stiffened skin.
Let
For bottom flange:
For top flange:
For webs, define:
And therefore, contribution from two web laminates is:
These equivalent
To better understand and predict the mechanical behavior of the structure, a demonstration FEA model of one panel with multiple hat stiffeners bonded onto it was built in MSC Nastran (Figure 6). A few composite ply material properties were selected from the Cytec Cycom 5320 prepreg data sheet for creating the model and database.
Midpoint deflection of the demonstration part FEA model.
For the geometric configuration of the model: this demonstrator model comprises a base panel of in-plane dimensions 304.8 mm (which is 12 inches) × 863.6 mm (which is 3 inches) with four hat stiffeners on it., each separated by approximately 85.725 mm (which is 3.37 inches). The bottom width of the hat stiffener is approximately 86.36 mm (which is 3.4 inches) with 60.96 mm (which is 2.4 inches) as the distance between the lower two corners of the hat stiffeners and 12.7 mm (which is 0.5 inch) overhang (i.e., flange) on the either side. The base panel has 8 plies of laminates with 5320 unidirectional prepreg properties and they are in a quasi-isotropic layup as follows: [90,−45,+45,0]S. Each of the four hats also consists of eight unidirectional fiber plies in the same quasi-isotropic layup.
Simulation of panel-level hat-stiffeners requires understanding of global and local effects of the parameters. One should consider local maximum deflection occurring in between the stiffeners on the panel, because that may become a dominant parameter for deformation constraints satisfaction.
To validate the modeling prediction of the center point deflection of the stiffened panel, a composite panel bonded with multiple hat-stiffeners was manufactured as a demonstrator part. During fabrication of the structural element and the final demonstration part, unidirectional Cytec Cycom 5320 prepreg material, out-of-autoclave curing, and secondary bonding technique were used.
The basic structural elements comprise of flat panels and hat cross section beams. The assembly of these basic structural elements forms the demonstrator part represented by a large panel stiffened by four equidistant hat beams, as shown in Figure 7. To accurately predict and compare with the FEA results, the demonstration part has identical set up with the MSC Nastran FEA model built and explained in the last section.
Manufacturing and assembly of basic structural elements into a demonstration part.
The demonstration part was tested under near-uniform 1 psi loading and the center point deflection was recorded so it can be compared with FEA results. Photographs of the testing setup are shown in Figure 8. The experimental testing of the demonstrator part involves simply supporting the edges and subjecting it to a uniform pressure loading condition by placing sandbags at the center. Experimentally measured panel displacements are then compared to predictions from both analytical constructs as well as FEA models.
Simply supported hat-stiffened composite panel under near-uniform pressure loading.
The demonstration plate midpoint deflections are experimentally obtained for 150, 225, 300, 375 and 400 lb. load are 0.022, 0.032, 0.039, 0.045 and 0.047 in, respectively. The first increment (150 lb) was using lead balls filled bags providing close to uniform loading. The remaining increments were obtained using iron discs that did not provide as uniform loading as lead balls filled bags would have. As the results are shown in Figure 9, the midpoint deflection is 1.52 mm (0.06 in) for 1 psi uniform loading while FEA simulation gave 1.83 mm (0.07 in).
Midpoint deflection of the demonstration part.
The analytical bounds for stiffened plates were also obtained. The midpoint deflection from the homogenized orthotropic plate gives the lower bound and simply supported idealized plate between the stiffeners gives upper bound. The lower bound provides better approximation for plates with closely spaced stiffeners. The real deformation starts to approach the upper bound as spacing between stiffeners increases. The lower bound for midpoint deflection under 1 psi is 0.133 mm (0.0052 in) and the upper bound is 2.85 mm (0.11 in).
The work performed establishes the basis for continuing future work to further develop a set of parametric models. The conceived process of designing advanced composite aircraft structural components from these parametric modeling constructs will be matured, implemented and validated to demonstrate the benefits of starting the design with validated parametric design elements.
This work has illustrated the process of developing an analytical model and the design and analysis of the parametric composite hat-stiffened panels. The amount of the work involved in designing to this level of abstraction is a significant part of the design of an aircraft. This work is needlessly repeated by designers again and again and can be standardized to abbreviate the design process, and has successfully shown most of the processes involved in creating parametric models with a hat-stiffener stiffened composite laminated plate model development.
Most commercial CAD/FEA software includes some form of parameterization of design variables. Basic research level higher order structural elements have also been developed. These tools allow quick, easy and accurate topology and geometry model creation with design constraints; implicit parameterization for easy model variation; integrated Finite Element generator; models and components storage in library for generation of knowledge database and reusability; shape and size optimization in a closed batch loop; on-the-fly definition of design variables and design space; and integration of specific applications like commercial optimization and design tools. Our future work includes integrating these models in similar design tools, such as a combination of MSC Nastran, ABAQUS, MATLAB and C++ platform.
Authors would like to appreciate Brian Casey, Senior Engineer of MSC NASTRAN Development, for his important suggestions and the time he has spent on proof-reading the manuscript.
The rapid growth of the world population and industrial activities has caused a significant increase in water consumption. These developments lead to a serious water shortage all around world especially in arid regions. Recently, the main problem affecting humane societies around the globe is the scarcity of water and increasing demand to it [1, 2]. As stated by United Nations’ reports, worldwide, about 1.2 billion people live in the region of physical scarcity. While another half a billion people are approaching this condition, about two billion people are facing economic water shortage. In addition to the treatment and reuse of wastewater, desalination is one of the technologies widely applied in the world. During recent decades, more than 100 countries have been using these processes [3, 4]. It is not possible to survive without clean water, unfortunately, based on international standards and various organizations, less than 1% of total water is clean. Rest of the water quantity is contaminated by various human-source pollutants such as agricultural activities, municipal wastewater, and industrial wastes [5, 6]. The major water pollutants can be specified as toxic heavy metals, pesticides, dyes, organic acids, halogenated compounds, fertilizers, and microorganisms [7, 8, 9, 10]. Because of non-biodegradability and toxicity, among these pollutants, heavy metals are the most hazardous materials for ecosystem and organism, because these toxic and dangerous metals tend to accumulate in ecosystem especially the food chain and the living organism. In addition, the polluted water intake leads to various health problems, such as organ damage, skin irritation, cancer, rupture of nasal septum, diarrhea, appetite loss, abdominal pain, and headache [11, 12, 13, 14]. For the reasons stated above, and especially in order to provide clean water to all living creatures to survive in a healthy life, these pollutants must be removed. Various membrane technologies have recently been used for removing these contaminants from water/wastewater. Among these technologies and applications, those of the greatest interest to researchers are listed below:
Microfiltration (
Ultrafiltration (
Nanofiltration (
Reverse osmosis (
Forward osmosis (
Membrane distillation,
Pressure retarded osmosis (
Membrane bioreactor (
Pervaporation (
Separation using liquid membranes [10].
In the last decade, various water/wastewater purification technologies such as NF, FO, and RO have been developed and effectively used [15]. It is inevitable that membrane-based processes will play an increasingly important role in water/wastewater treatment. These processes are expected to take a key role in solving many problems by developing further in a short period of time due to some advantages such as requiring less energy, ease of use, and making them easily modular [16]. Among the membrane technologies performed in the wastewater treatment, especially application of NF, FO, and NF processes will be increased in the near future [1]. Polymers are widely preferred materials in water/wastewater treatment, despite some disadvantages such as relatively high-energy consumption, permeability, short lifetime, relatively consumption of high energy, and low resistance to fouling. It is vital to develop low-energy, cost-effective, and functional membranes for contaminants removal from water/wastewater. In particular, the inclusion of nano-sized materials in the polymer matrix has made a significant progress in overcoming the challenges of water treatment of polymeric membranes developed and synthesized. Studies conducted in the last few years, especially nano-sized structures such as carbon nanotubes (CNTs), graphene, zeolites, silica, zinc, iron oxide, and other metal oxides, have been added to the polymer matrix and tested [17]. Supported by various nanostructures, NCMs have been used effectively in many applications including liquid-solid, liquid-liquid, and gas-gas separations. The PCMs have attracted great attention for water/wastewater cleaning because of overcoming trade-off between permeability and solute rejection along with fouling reduction property. Also, for water/wastewater treatment process, they are known as high-performance membrane [18]. As a result, it can be clearly stated that although there are some difficulties in industrial applications, nanomaterials offer outstanding benefits. For example, modification of the NCMs’ surface provides a great advantage in water treatment applications as it significantly changes its efficiency, such as pore size and hydrophilicity [18]. A brief schematic summary of NCM processes to treat water/wastewater is presented in Figure 1.
A schematic illustration of NCMs for heavy metals removal from wastewater.
In order for designing membranes for water/wastewater treatment, various natural and synthetic polymer types, including chitosan, cellulose acetate, polystyrene, polyamide, have been preferred [10, 19, 20]. Barriers including low contaminant removal, low chemical stability under pH change, biological fouling, loss of mechanical strength, and hydrophobicity prevent the widespread application of the polymeric membrane. The advantages and disadvantages of polymers used in NCMs are given in Table 1 [10].
Polymer | Advantages | Disadvantages |
---|---|---|
Chitosan |
|
|
Polyvinyl alcohol |
|
|
Cellulose acetate |
|
|
Polyamide |
|
|
Polystyrene polyethersulfone |
|
|
Advantages and disadvantages of some commonly used polymers in NCMs [10].
For water/wastewater treatment, nanotechnology has brought a great revolution. During the formation of polymeric nanocomposite membranes (PNCMs) process, when nanoscale entities such as nanoparticles and nanofibers add to PNCMs; it gives them unique properties. In the water/wastewater treatment processes, because of some outstanding properties such as permeability, mechanical and chemical stability, superior flexibility, less installation space requirement along with selectivity to chemical species, and high removal capability, PNCMs have become an ideal choice. The significance of PNCs for water/wastewater treatment can be tracked by the continuous rise in publications, also. Using PNCMs for treatment of water/wastewater is an energy-efficient eco-friendly and technology besides low-cost. Moreover, PNCMs technology can be feasibly combined with various processes [10, 21]. For example, the inclusion of metallic and metallic oxide nanoparticles in the polymer matrix has added antifouling properties to the membranes, as well as increased thermal and mechanical stability. Because of their low cost, they are often added in a small quantity of nanofibers into the polymer matrix. When the nanofibers are added to polymer matrix, in addition to the mechanical strength and thermal stability of polymer-based nanocomposites, its flexibility also increases [22, 23, 24, 25]. Nanoparticles composed of metal or metal oxides, which contain Ag, Cu, TiO2, and Fe2O3, are main examples of nanoparticles [26]. This nanoscale entity class of spherical shape demonstrates some superior properties such as increased lipophilicity and good dispersibility in organic solvent along with chemical stability. Another important class of nanoscales are carbon nanotubes (CNTs), nano-diamonds, and graphene oxides (GO). The GO is a 2D carbon-based nanomaterial, and they contain many oxygenated functionalities such as carbonyl or hydroxyl groups in their interconnected carbon layers. The CNTs with 1D carbon-based tubular layers have often been used in wastewater treatment process. Because of some vital properties including hydrophobic surfaces and low surface energy besides spherical nanoscale such as Cu, TiO2, ZnO entities are often used as disinfectants or antimicrobial agents [26]. Very small spherical nanoscale entities such as nanofibers, nanoplatelets, or polymers can be grown at the surface of the substrate to obtain functional nanoscale structures for applications such as catalysis. Various nanostructures obtained in this way are used for water purification as environmentally friendly, cost-effective, and quality products [10, 27]. A schematic illustration of pressure-driven NCMs for water/wastewater treatment is presented in Figure 2.
A schematic pressure-driven membrane nanocomposite illustration for wastewater treatment.
This study provides an overview of the applications of these current technologies in water/wastewater treatment for heavy metal removal, focusing on the latest technological developments in this field, as well as techniques for preparing NCMs. The properties and performance of PNCMs will be discussed considering different polymers and nanoscale entities. It is expected that this study would arouse curiosity and interesting for the development and application of functional NCMs to treatment water/wastewater. Moreover, preparation and application of the NCMs and future prospectives will be discussed.
Two main factors such as the nature of the polymer and the final required membrane structure play a key role in determining the type of membrane preparation method. Several different techniques may be used for fabricating of polymeric membranes. However, in general, some techniques are often preferred among them, and these are summarized below:
Interfacial polymerization technique
Phase inversion technique
Blending technique
Electrospinning technique [28].
Unfortunately, current membrane preparation techniques are not suitable for industrial-scale use. Therefore, efforts to develop and promote preparation techniques to overcome the limitations of existing strategies for membrane preparation should be strongly supported (Figure 3).
A schematic illustration of nanocomposite materials.
The technique called interfacial polymerization (IP) is often preferred for PNCMs production, and it is the most considerable technique for commercially fabricating various essential and important membranes including nanofiltration (NF) and thin-film composite (TFC) besides reverse osmosis (RO). For RO applications, the development and use of interfacial polymerized TFC membranes were an important milestone in the performance of the membranes [29]. Various types of TFC membrane have been fabricated using IP technique because of noticeably superior properties such as microporous substrate layer and independent optimization of the skin layer. In addition to TFC membranes, RO and NF membranes, which have many uses, were also produced using this useful technique. Barrier membrane layer composition and structural morphology are affected with many factors including monomer concentration, solvent type, reaction time, and subsequent treatment [30, 31]. In the highlighted technique, the interaction of two different monomers is as schematized in Figure 4. Before the polymerization process begins, nano-sized structures are incorporated and polymerization occurs at the interface between the two phases. The distinctive layer produced on the substrate in IP has very less thickness and due to these properties, possesses superior membrane flux. Also, for polymerization, suitable monomers selection can produce selective polymer layers, resistant to chemicals, good thermal stability, and better durability [10, 28].
A schematic illustration of interfacial polymerization technique for preparation of PNCMs.
For membrane preparation, the most usable method is phase inversion (PI) technique. For different applications, various kinds of morphologies can be obtained when using IP technique [32]. To design membranes, various polymers can be used effectively because the PI method is cost-effective, time-efficient, facile, flexible in use, and feasible to scale-up; therefore, PI technique is used for the manufacture of lab membranes and commercial [33]. All PI membranes are based on polymer precipitation in homogeneous casting solution. The polymer solution precipitation is governed by PI process kinetics and thermodynamics. Therefore, this process affects the prepared membranes final morphology. The precipitation takes place through a demixing process. In this mixing process, the polymer solution is converted from a liquid to a porous solid due to the exchange between solvent and non-solvent [34]. In other words, the PI process is a uniform polymer and a mixing process in which the solution of nanoscale structures is converted into a solid phase in a controlled manner. The PI technique is based on the change in solution stability of the dissolved polymer and nanoscale entity caused by temperature instability, mass change between coagulant bath/non-solvents, and solvent evaporation. The PI technique is frequently selected for preparation of asymmetric PNCMs with thin and dense layers. For membrane preparation (Figure 5), some parameters including solvent, non-solvent, choice of composition of polymer solutions, coagulation bath composition, and film casting conditions are the key parameters. As result, PI technique provides the advantage of large morphological differences by altering process parameters that are mentioned before [35, 36].
A schematic illustration of phase inversion technique.
Blending technique (BT) is based on the direct mixing of nanoscale entities such as metal oxide or metal nanoparticles and polymer. Also, to form PNCMs, the BT is the easiest technique. Such mixing/mixing can be accomplished in two ways, solution blending technique and melt blending technique.
In this technique, whole components such as polymer and nano-dimensional structures are disseminated in an appropriate common solvent. It is supported in the polymer matrix by adding nano-sized structures to the mentioned solvent. In this step, first the surface-modified nanoscale entities are dispersed in the solvent by means of ultrasonic waves. The mixture is then added to the polymer solution to obtain a homogeneous dispersion. The polymer chains remained intact and formed NCM upon solvent evaporation. Also, to select a convenient solvent for proper nanoscale entities and polymer mixing, it should not be forgotten that it is essential. For water-soluble polymers, the SBT is more useful. However, using organic solvents that are toxic and expensive is a main problem in application of SBT [37]. If NCM is to be obtained from polymers insoluble in low-boiling-point solvents, SBT is not preferred [38].
NCMs are formed from the polymer melt, after the nanoscale structures and polymers are injected into the extruder and melted at high temperature during intensive mixing. For providing polymer chains mobility, thermal energy is used. Generally, the MBTI is preferred because of its environment-friendly nature along with higher effectiveness. At a large scale, some parameters including use of high temperature and setup of processing may lead to limitations to their use [39]. During blending, the extruder configuration and screw affect the nanoscale entities dispersion quality, also [38, 40]. For preparation of NCMs, both SBT and MBT are simple and frequently used techniques. Generally, BTs are feasible to operate and appropriate for all nanoscale entities types.
Electrospinning technique (ET) that is simple and effective method is usable for producing fibrous membranes. Because of a number of uses including filtration and desalination, the ET is relatively new. It is a preferred technique for fabricating particularly porous membranes. The ET is often preferred for membrane preparation due to some superior features including excellent interconnectivity besides relatively homogeneous pores distribution. Also, because of nanofibers’ large surface area, these membranes functionalization are easier. The ET is a durable technique with very good control over the membrane structure. On the other hand, dense membranes are not produced using ET, because these membranes are required for a diffusion processes, for example, NF and RO [41]. In ET, an application of high potential using a voltage source is made between polymer solution droplet and grounded collector. When electrostatic potential is raised to an adequate level, it overcomes the droplet’s surface tension and forms a charged liquid jet. The solution of polymer contains the nanoscale entities and dissolved polymer. The fiber-containing membranes are perfect in that the fiber and morphology of the aspect ratios of the nano/microfibers can be controlled by variable parameters such as the applied electrical potential level, the flow rate of the membrane solution, and the membrane solution viscosity [10, 42, 43].
Finally, because of the forces present between them, jet leaves the tip. During thinning of the polymer jet, solvent phase evaporates and nanofibers are formed. Then, nanofibers are collected on the collector. Owing to rheological properties, jet instabilities arising of polymer melt are important in the shaping of fibrous membrane. By controlling the parameters and operating conditions, the fibrous membranes properties including morphology, porosity, aspect ratio, pore size distribution, and hydrophobicity can be regulated. Electrospun fibrous membranes are a preferable choice in applications filtration, because morphology, fiber shape, and size can be precisely controlled. It has been reported in many studies that nanostructured morphology and fiber diameter can be significantly affected by applied potential strength, solution feed rates, ionic salt addition, and polymer solution viscosity. Depending on the chosen polymer and its molecular weight, the minimum viscosity is decided [28, 42, 44].
In the processing and application of NCMs for the water/wastewater treatment, biofouling is one of the main drawbacks of membrane technology. Biologically sourced membrane contamination leads to clogging of the pores and thus to a serious decrease in performance. Moreover, biofouling increases the maintenance and operational cost of membranes. It decreases the membrane average lifetime, also. Microbial increase and biofilm formation are the main problems that increase the flow in the membranes and consequently require more energy. To overcome these problems, it is vital to prepare NCMS with antimicrobial activity. Preparation of NCMs with antimicrobial activity both increases the efficiency of the membranes and saves time by shortening the application time. Recently, many researchers have focused on using polymers with biocidal materials in designing NCMs with antibacterial properties. Metal oxides such as Ni2O3 [45], TiO2 [46], and ZnO Al2O3 [47] are frequently preferred because of their biocidal properties, that is, they directly target bacteria. For this reason, to reduce biofouling, metal oxides are commonly used to design the antibacterial NCMs. For example, owing to the outstanding biocidal properties of Ag, it is one of the most studied nanomaterials to create antimicrobial activity. Other nanostructures such as titanium, chromium, and copper are also metals that are highly preferred in antimicrobial NCMs production [18]. The optimal concentrations of most metal oxide nanoparticles used to destroy bacterial cells have no toxic effects on human health, which has also fueled interest in the use of these materials. The PNCM antimicrobial effectiveness is based on the electrostatic interaction between the membrane and bacteria. Commonly, the nanoscale structure found in PNCM contains a positive charge that attracts the negatively charged bacterial cell on their surface. This electrostatic interaction breaks the structural integrity of the bacteria and leads to the bacteria death [48].
The NCMs, during water/wastewater treatment, must possess good mechanical features including toughness, to endure the pressure. Because to define processability and stability besides end use of NCMs, enough mechanical strength is essential. The interaction between nanoscale entities and polymer components is vital in NCMs that impart mechanical properties. Nanoscale entity uniformity, size, and volume fraction affect mechanical properties. The good and homogeneous nanoparticle distribution in the polymer matrix restricts the chain movements and thus increases the mechanical strength. As a result, it can be clearly stated that anisotropy is an important property that is also responsible for its mechanical properties [11, 49, 50].
Several technologies are available for removing pollution including organic and inorganic from water/wastewater. The removal techniques such as chemical precipitation, coagulation/flocculation, membrane processes, reverse osmosis, ion-exchange/solvent extraction, biological operations, ultrafiltration, and adsorption have been used. Other techniques including precipitation and ion-exchange other than adsorption are not preferred because of the production of various secondary pollutants and their high operating efficiency. Apart from these techniques, the adsorption technique has come to the fore and has been accepted due to some advantages such as simple, efficient, and cost-effective. Adsorption that is most effective techniques is often preferred to remove heavy metals due to flexibility in design and operation. This technique contains a surface phenomenon where pollutants are deposited over the adsorbent surface. Ekstra energy, excess water, or additional chemicals are not used in adsorption process [26]. For the aforementioned reasons, the adsorption technique has become a unique phenomenon in removing contaminants from water/wastewater. Adsorbate and adsorbent surface interaction called physisorption or chemisorption occurs in adsorption process. The pollutants especially heavy metals may interact with the adsorbent surface with various forces including electrostatic interactions, van der Waals, or hydrogen bonding [26]. Functional groups included in PNCMs take part in pollutants and heavy metal ions removal by adsorption and can be regenerated by desorption process [51]. In recent years, various materials including nanoparticles [51] and beads [52] as adsorbent forms have been developed and used. In the last few years, many composite materials such as graphene oxide have widely used to remove heavy metal contaminants as novel adsorbents for the adsorption.
Detrimental heavy metals such as As and Ni are the biggest and most important pollutants for ecosystem. These toxic and carcinogenic pollutants can be discharged into the water sources in almost all walks of numerous industrial activities. They have damaged the environment and human health in many aspects. Since these metals, which are harmful and destructive, can enter the human body at more than the allowed concentration and accumulate in our tissues, they cause various harmful health problems. Since metals that are toxic effect are used in many fields of industry, without discharge of their release to the environment is also increasing. Toxic materials especially heavy metals, which spread to the environment and do not degrade, reach people especially through the food chain and water [53, 54, 55].
As practical and environmental approach for treating wastewater, separation technologies using membranes have been known as worldwide one of the best technology [56]. Membranes used for this purpose can be divided into two basic classes: inorganic membrane and polymeric membrane (Figure 6). There are four types of membranes, based on pore sizes, which are MF, UF, NF, and RO. It should not be forgotten that, during the water/wastewater treatment, heavy metals ions such as Ni2+, Cd2+, and Hg2+ were tiny, and sometimes they are soluble in which it is necessary to reverse the osmosis membrane’s size [57]. Therefore, recently, materials known as hybrid or specifically adsorptive membranes produced by the combination of adsorption and membrane separation processes have been the focus of many researchers [58, 59].
A schematic illustration of membrane type.
Because of sieving and surface charge effects, both NF and RO can effectively be used for heavy metal ions removal [58]. At the same time, for modification conventional UF and MF membranes to improve the membranes selectivity toward heavy metal ions, various studies have been made. Studies conducted in recent years for heavy metal ions removal from water/wastewater are summarized below.
For selective ion removal from water, Ag-doped multiwalled carbon nanotube (MWCNT)/polyphenylsulfone (PPSU) was prepared as NCM by Shukla et al. Silver-doped MWCNTs prepared and characterized based on specific surface area and distribution of particle size. For characterization, various properties such as porosity, topography, morphology, surface charge, and contact angles were investigated. To examine mentioned properties, several spectroscopic techniques besides transmission electron microscopy were used. It was stated that Ag-MWCNT/PPSU NCM achieves optimal performance and exhibits unique properties. When PPSU membrane is compared with NCMs, it was mentioned that NCMs exhibit significantly improved selective removal of several ions such as Na+, As5+, and Mg2+ ions from aqueous medium. Also, antibacterial activity of Ag-MWCNTs was evaluated using some bacteria such as
Delavar et al. reported the removal of Cd2+ and Cu2+ ions using mixed matrix membranes (MMMs) alumina nanoparticles fabricated as UF membranes and incorporated with alumina nanoparticles [60]. The characterization of structural morphology and hydrophilicity of synthesized MMMs was made by using field emission scanning electron microscope (FESEM), water contact angle, and Fourier transform infrared spectroscopy (FTIR) techniques. The alumina and hydrous manganese oxide (HMO) loading affected some properties such as pure water flux, mean pore size, porosity, and water contact angle of the membranes. In the light of this information, the performance of UF membranes for removal of Cd2+and Cu2+ ions was also investigated. Based on obtained data from UF experiments, when prepared MMM with a high HMO nanoparticles loaded, it was stated that they have had very fast kinetics and demonstrated the highest Cu2+ ions and Cd2+ ions removal efficiency (97% and 98%, respectively). This study results indicated that HMO nanoparticles can be a good candidate for preparation of MMMs. Also, to remove Cu2+ ions and Cd2+ ions from polluted water resources, it can be conveniently used [60].
In another study, to remove Cr(VI) ions using UF membranes that contain cellulose acetate, this is incorporated with TiO2 nanoparticles [61]. In addition, TiO2 nanoparticles were preferred to increase the affinity of heavy metal ions to the membrane and increase the removal efficiency. Moreover, TiO2 nanoparticles’ presence improved the membranes’ antifouling properties because of easily cleaned and regenerated. At pH 3.5, in the presence of aminated TiO2 nanoparticles, Cr(VI) removal efficiency was achieved as 99.8%. Present in the anions form such as Cr(VI) ions, the protonated amine group on the TiO2 nanoparticles established electrostatic interaction with the Cr(VI) species. Gebru and Das also reported, after four cycles of washing and regeneration processes, efficiency of removal was only slightly reduced to 96.6% [61].
In another study, for the treatment of water contaminants such as organic fouling agents and toxic heavy metal ions, a] thin film composite (TFC) NF membrane that contains poly(piperazineamide) [poly(PIP) was developed by Bera et al. It has been reported that the synthesized NCM has high performance in anti-organic fouling, anti-biofouling, and removal of multivalent cations. Also, they reported the thin film nanocomposite (TFNC) NF membranes preparation with improved rejection of heavy metals efficacy, anti-biofouling property, and anti-organic fouling properties compared with that of poly(PIP) TFC NF membrane. Using IP technique, FNC NF membranes were prepared and PEI-polyethylene glycol conjugate and then immobilization of Ag-NP. The IP was performed on a polyethersulfone/poly(methyl methacrylate)-co-poly(vinyl pyrollidone)/Ag-NP mixture UF membrane support. The synthesized TFNC membranes exhibited a good performance for several heavy metals as >99% for Pb2+, 91–97% for Cd2+, 90–96% for Co2+, and 95–99% for Cu2+ at applied 0.5 MPa pressure. It was mentioned that heavy metal ions rejection effect of the modified NF membranes is attributed to the positive surface charge development [62].
In the study carried out by Deng et al., a novel NCM containing improved physical properties and enhanced metal ions removal efficiency was prepared using ET technique. By reacting MWCNT-COOH with polyethylenimine (PEI), modified MWCNTs were fabricated, which was further embedded within polyacrylonitrile (PAN) nanofibers using ET technique. The MWCNT-PEI and NCM (MWCNT-PEI/PAN) properties such as physical properties, morphology, and structure were characterized using various techniques including TEM, SEM, FTIR besides mechanical test and contact angle measurements. When NCMs compare to plain PAN membrane because of hydrophilicity, higher mechanical strength, high permeation, and filtration efficiency, it is undisputed that the NCMs are clearly superior. Experiments studies revealed that synthesized NCMs such as MWCNT-PEI/PAN exhibited higher adsorption capacity for several heavy metals such as Cu2+ and Pb2+ ions compared with other NCMs. It was reported that Langmuir isotherm and dynamic adsorption results proved that the synthesized and designed NCMs exhibited improved rejection ability for heavy metal ions with a water flux at 145.8 L m−2 h−1 under 0.2 bar pressure. It is stated that these new and functional membranes synthesized have promising potential for contaminated water treatment due to their heavy metal removal properties [63]. In another study carried out, to functionalize graphene oxide (GO) nanoparticles using polyaniline (PANI), a polymerization technique was performed by Ghaemi et al. After NCMs were prepared by embedding PANI@GO nanoparticles into matrix of PES membrane, it was characterized by SEM and AFM for measuring various properties including porosity and permeability besides mean pore size. A response surface methodology compatible with central composite experimental design was carried out for membrane Pb2+ removal performance from water besides to optimize experimental conditions. Although the NPs addition to membrane matrix reduces the porosity, permeability, and hydrophilic properties, it has been reported that Pb2+ removal activity is significantly increased. It has been stated that increasing the pH and increasing the proportion of GO particles up to 25% by weight cause an increase in Pb2+ removal from the water and almost all Pb2+ ions are successfully removed by the NCMs. Ghaemi et al. examined adsorption mechanism, isotherm model, and the kinetic properties along with reusability performance of NCMs. They reported that Langmuir isotherm and pseudo-first order kinetic offered the most appropriate models for Pb2+ removal from water using synthesized NCMs [64].
Gohari et al. developed an UF mixed matrix membranes (MMMs) using polyethersulfone (PES)/hydrous manganese dioxide (HMO) for Pb2+ adsorption and removal by varying the weight ratio of PES:HMO in the membrane. The HMO loading effect on the membrane in terms of porosity, hydrophilicity, and pure water flux and adsorption capacity MMMs for Pb2+ studied, also. Moreover, prepared membranes properties such as structural morphology using and surface roughness were characterized by using SEM, AFM, and FTIR techniques. It was reported that in spite of pore size of membrane tended to decrease with increasing PES:HMO weight ratio, it has been stated that the water flux of the membrane is not affected. It was found that the Pb2+ removal capacity of the MMM prepared with the highest PES:HMO ratio was 204.1 mg g−1 and this adsorption capacity was quite promising, when compared with literature. It was observed that Pb2+ adsorbed on the membrane can be easily desorbed by using HCl solution. Studies conducted by repeating the adsorption-desorption process proved that this MMM can be used repeatedly [65].
In another study, the synthesis of polymeric membranes based PES and modified by the activated carbon addition and the removal potential of this developed membrane in removing Cu2+ ions from the aqueous medium were investigated. It has been reported that after modification of the PES membrane with the activated carbon addition, the retention capacity of Cu2+ ions are significantly increased [66]. Moreover, the synthesis of various membranes and their application to various samples for heavy metal removal are summarized in Table 2.
Used membrane | Removed metal | Reference |
---|---|---|
PAH and PSF/PAH blend membranes | Pb2+, Cd2+ | [67] |
Cellulose NCMs | Ag+, Cu2+, Fe3+, Fe2+ | [68] |
FO membranes | Co2+ | [69] |
CTA-ES membrane | Cs+ | [70] |
NCMs (PDA/GNPs/PEI) | Zn2+, Ba2+, Ni2+, Cd2+ | [71] |
Fe-Ag/f-MWCNT/PES | Cr(VI) | [72] |
Thin-film nanocomposite FO membrane | Pb2+, Cd2+, Cr6+ | [73] |
Ultra-thin NCMs (chitosan/GO NCM) | Mn2+ | [74] |
MWCNT/polysulfone composite membranes | Cr6+, Cd2+ | [75] |
Ag-doped MWCNT NCMs | As5+, Cr6+, Mg2+ | [59] |
NF membranes(quaternized polyelectrolyte complex membranes) | Na+, Mg2+, Ca2+, Cu+, Mg2+, Zn2+ | [76] |
Thin-film inorganic forward osmosis membrane | Cd2+, Pb2+, Cu2+ and Zn2+ | [77] |
Functionalized MWCNTs/PVA nanocomposite films | Zn2+, Ni2+, Mn2+, Cr2+, Cd2+, Pb2+ | [78] |
Heavy metal removal from water/wastewater by using various NCMs.
Recently, for water/wastewater treatment, PNCMs that have perfect antibacterial, mechanical, and adsorption properties and have become a globally known and usable method. Because of these outstanding performances, they managed to attract the attention of academia and industry. It is a variety of functional nanoscale materials and different architectures that allow PNCMs to have some outstanding properties. It has enabled an impressive improvement in the treatment of water/wastewater using PNCMs technology, which is open to this and similar developments. Over the past decade, to treat water/wastewater especially for removing toxic heavy metals, immense progress has been made in developing PNCMs. Membranes exhibit a unique useful behavior due to some of their physicochemical properties including charge density, porosity, hydrophilicity, mechanical and thermal stability, and nanoscale entities addition. Although two important parameters such as the polymer nature and the final required membrane structure determine the type of the method used in the preparation of the membrane, different methods such as IP and PI are the most frequently used methods for PNCMs preparation. The addition of nanomaterials such as nanofibers is of vital importance in improving the mechanical and, in particular, adsorption capability of membranes.
It can be clearly stated that spherical nanomaterials, for example, metal oxide nanoparticles, protect the membrane against biological contamination and provide antibacterial activity. However, it is clear that the methods for the synthesis, development, and distribution of nanoscale materials in the polymer matrix need more research. These research studies should focus especially on the following subjects:
The aggregates formation is a major problem for nanoscale entities dispersion into the polymer matrix as homogeneous.
The compatibility of polymer and nanoscale materials plays a key role in the formation of a successful membrane.
Focus should be placed on possible solutions for the stability of nanoscale entities in the polymer matrix that affect membrane performance.
Further studies are needed on the functionalization of the surface of nano-sized materials or optimization of the manufacturing process, the ability to increase the dispersion of nanoscale entities into polymer matrices. In the near future, it will be possible to optimize the distribution and hence the interaction between nanoscale entities and the polymer matrix.
While studies have shown that nanomaterials have unique properties that can contribute to the development of high-tech and new NCMs with advanced capabilities to treat water/wastewater, optimizing the durability of nanoscale assets and the loading concentration in NCMs is key to achieving the best performance. On the other hand, recently, for removing or reducing the heavy metals amount in water/wastewater bodies, extensive efforts have been made. Various methods have been applied, each of which has advantages and disadvantages. For removing of toxic metallic ions, membrane technology including UF, NF, RO, and FO membranes exhibits huge potential as it offers different separation mechanisms and a wide range of membrane properties. One of the best examples of this is that the adsorptive UF membrane shows a significant improvement in membrane morphology where the increase in water permeability is achieved. Even at low membrane pressure, mentioned membrane is convenient to treat low metal concentrations by enabling the complete filtration-adsorption metal ions removal. The NF, RO, and FO membranes have proven effective to remove metal ions from water/wastewater. In addition, the NF process has been reported to be efficient and effective even at an industrial level. Because it requires high energy consumption and is therefore costly, the RO method is preferred only to treat water resources that must meet drinking water standards. For these reasons, to reduce costs and expand usage, more research is still needed for RO. If the respective limitations can be overcome, it is highly likely that membrane technology will become a serious alternative method to remove heavy metal ions in the future. In summary, adsorptive membranes have a wide range of applications including wastewater treatment. Advances in the development and manufacture of adsorptive membranes are increasing day by day. Besides adsorptive removal of contaminants from the water/wastewater has also technologically advanced, it has played an important role with the development of adsorptive membrane technologies. Thus, multi-stage pollutant removal processes, which were previously applied, can now be carried out in a single-stage pollutant removal process. As a result, the contribution of properties such as pore size and surface hydrophilicity of the membrane has not yet been fully explained by researchers. Despite current developments in membrane technology, the practical wastewater applications of PNCMs do not yet have the potential to fully meet expectations. Most of the current investigations on applications of PNCMs are at laboratory scale and unfortunately there are limited studies for industrial production and application. For practical and safe applications, further studies are required to produce economic and industrial-scale membranes.
The authors declare no competing interest.
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Based on the assumption that informative and discriminative representation of the data lies on a low-dimensional smooth manifold which implicitly embedded in the original high-dimensional space, manifold learning aims to learn the low-dimensional representation following some geometrical protocols, such as preserving piecewise local structure of the original data. Manifold learning also plays an important role in the applications of computer vision, i.e., face image analysis. According to the observations that many face-related research is benefitted by the head pose estimation, and the continuous variation of head pose can be modelled and interpreted as a low-dimensional smooth manifold, we will focus on the head pose estimation via manifold learning in this chapter. Generally, head pose is hard to directly explore from the high-dimensional space interpreted as face images, which is, however, can be efficiently represented in low-dimensional manifold. Therefore, in this chapter, classical manifold learning algorithms are introduced and the corresponding application on head pose estimation are elaborated. Several extensions of manifold learning algorithms which are developed especially for head pose estimation are also discussed and compared.",book:{id:"5488",slug:"manifolds-current-research-areas",title:"Manifolds",fullTitle:"Manifolds - Current Research Areas"},signatures:"Chao Wang, Yuanhao Guo and Xubo Song",authors:[{id:"190308",title:"Dr.",name:"Chao",middleName:null,surname:"Wang",slug:"chao-wang",fullName:"Chao Wang"},{id:"190461",title:"Prof.",name:"Xubo",middleName:null,surname:"Song",slug:"xubo-song",fullName:"Xubo Song"},{id:"191562",title:"MSc.",name:"Yuanhao",middleName:null,surname:"Guo",slug:"yuanhao-guo",fullName:"Yuanhao Guo"}]},{id:"62804",doi:"10.5772/intechopen.79383",title:"Recent Advances of Manifold Regularization",slug:"recent-advances-of-manifold-regularization",totalDownloads:1070,totalCrossrefCites:0,totalDimensionsCites:3,abstract:"Semi-supervised learning (SSL) that can make use of a small number of labeled data with a large number of unlabeled data to produce significant improvement in learning performance has been received considerable attention. Manifold regularization is one of the most popular works that exploits the geometry of the probability distribution that generates the data and incorporates them as regularization terms. There are many representative works of manifold regularization including Laplacian regularization (LapR), Hessian regularization (HesR) and p-Laplacian regularization (pLapR). Based on the manifold regularization framework, many extensions and applications have been reported. In the chapter, we review the LapR and HesR, and we introduce an approximation algorithm of graph p-Laplacian. We study several extensions of this framework for pairwise constraint, p-Laplacian learning, hypergraph learning, etc.",book:{id:"7342",slug:"manifolds-ii-theory-and-applications",title:"Manifolds II",fullTitle:"Manifolds II - Theory and Applications"},signatures:"Xueqi Ma and Weifeng Liu",authors:null},{id:"53713",doi:"10.5772/67008",title:"An Intrinsic Characterization of Bonnet Surfaces Based on a Closed Differential Ideal",slug:"an-intrinsic-characterization-of-bonnet-surfaces-based-on-a-closed-differential-ideal",totalDownloads:1459,totalCrossrefCites:2,totalDimensionsCites:2,abstract:"The structure equations for a two‐dimensional manifold are introduced and two results based on the Codazzi equations pertinent to the study of isometric surfaces are obtained from them. Important theorems pertaining to isometric surfaces are stated and a theorem due to Bonnet is obtained. A transformation for the connection forms is developed. It is proved that the angle of deformation must be harmonic, and that the differentials of many of the important variables generate a closed differential ideal. This implies that a coordinate system exists in which many of the variables satisfy particular ordinary differential equations, and these results can be used to characterize Bonnet surfaces.",book:{id:"5488",slug:"manifolds-current-research-areas",title:"Manifolds",fullTitle:"Manifolds - Current Research Areas"},signatures:"Paul Bracken",authors:[{id:"92883",title:"Prof.",name:"Paul",middleName:null,surname:"Bracken",slug:"paul-bracken",fullName:"Paul Bracken"}]},{id:"72257",doi:"10.5772/intechopen.92441",title:"Quasiconformal Reflections across Polygonal Lines",slug:"quasiconformal-reflections-across-polygonal-lines",totalDownloads:419,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"An important open problem in geometric complex analysis is to establish algorithms for explicit determination of the basic curvelinear and analytic functionals intrinsically connected with conformal and quasiconformal maps, such as their Teichmüller and Grunsky norms, Fredholm eigenvalues and the quasireflection coefficient. This has not been solved even for convex polygons. This case has intrinsic interest in view of the connection of polygons with the geometry of the universal Teichmüller space and approximation theory. This survey extends our previous survey of 2005 and presents the new approaches and recent essential progress in this field of geometric complex analysis, having various important applications. Another new topic concerns quasireflections across finite collections of quasiintervals.",book:{id:"8760",slug:"structure-topology-and-symplectic-geometry",title:"Structure Topology and Symplectic Geometry",fullTitle:"Structure Topology and Symplectic Geometry"},signatures:"Samuel L. Krushkal",authors:[{id:"316576",title:"Prof.",name:"Samuel",middleName:null,surname:"Krushkal",slug:"samuel-krushkal",fullName:"Samuel Krushkal"}]}],mostDownloadedChaptersLast30Days:[{id:"73123",title:"Some Applications of Clifford Algebra in Geometry",slug:"some-applications-of-clifford-algebra-in-geometry",totalDownloads:784,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"In this chapter, we provide some enlightening examples of the application of Clifford algebra in geometry, which show the concise representation, simple calculation, and profound insight of this algebra. The definition of Clifford algebra implies geometric concepts such as vector, length, angle, area, and volume and unifies the calculus of scalar, spinor, vector, and tensor, so that it is able to naturally describe all variables and calculus in geometry and physics. Clifford algebra unifies and generalizes real number, complex, quaternion, and vector algebra and converts complicated relations and operations into intuitive matrix algebra independent of coordinate systems. By localizing the basis or frame of space-time and introducing differential and connection operators, Clifford algebra also contains Riemann geometry. Clifford algebra provides a unified, standard, elegant, and open language and tools for numerous complicated mathematical and physical theories. Clifford algebra calculus is an arithmetic-like operation that can be well understood by everyone. This feature is very useful for teaching purposes, and popularizing Clifford algebra in high schools and universities will greatly improve the efficiency of students to learn fundamental knowledge of mathematics and physics. So, Clifford algebra can be expected to complete a new big synthesis of scientific knowledge.",book:{id:"8760",slug:"structure-topology-and-symplectic-geometry",title:"Structure Topology and Symplectic Geometry",fullTitle:"Structure Topology and Symplectic Geometry"},signatures:"Ying-Qiu Gu",authors:[{id:"314607",title:"Dr.",name:"Ying-Qiu",middleName:null,surname:"Gu",slug:"ying-qiu-gu",fullName:"Ying-Qiu Gu"}]},{id:"52596",title:"Symplectic Manifolds: Gromov-Witten Invariants on Symplectic and Almost Contact Metric Manifolds",slug:"symplectic-manifolds-gromov-witten-invariants-on-symplectic-and-almost-contact-metric-manifolds",totalDownloads:1496,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"In this chapter, we introduce Gromov-Witten invariant, quantum cohomology, Gromov-Witten potential, and Floer cohomology on symplectic manifolds, and in connection with these, we describe Gromov-Witten type invariant, quantum type cohomology, Gromov-Witten type potential and Floer type cohomology on almost contact metric manifolds. On the product of a symplectic manifold and an almost contact metric manifold, we induce some relations between Gromov-Witten type invariant and quantum cohomology and quantum type invariant. We show that the quantum type cohomology is isomorphic to the Floer type cohomology.",book:{id:"5488",slug:"manifolds-current-research-areas",title:"Manifolds",fullTitle:"Manifolds - Current Research Areas"},signatures:"Yong Seung Cho",authors:[{id:"62522",title:"Prof.",name:"Yong Seung",middleName:null,surname:"Cho",slug:"yong-seung-cho",fullName:"Yong Seung Cho"}]},{id:"62804",title:"Recent Advances of Manifold Regularization",slug:"recent-advances-of-manifold-regularization",totalDownloads:1070,totalCrossrefCites:0,totalDimensionsCites:3,abstract:"Semi-supervised learning (SSL) that can make use of a small number of labeled data with a large number of unlabeled data to produce significant improvement in learning performance has been received considerable attention. Manifold regularization is one of the most popular works that exploits the geometry of the probability distribution that generates the data and incorporates them as regularization terms. There are many representative works of manifold regularization including Laplacian regularization (LapR), Hessian regularization (HesR) and p-Laplacian regularization (pLapR). Based on the manifold regularization framework, many extensions and applications have been reported. In the chapter, we review the LapR and HesR, and we introduce an approximation algorithm of graph p-Laplacian. We study several extensions of this framework for pairwise constraint, p-Laplacian learning, hypergraph learning, etc.",book:{id:"7342",slug:"manifolds-ii-theory-and-applications",title:"Manifolds II",fullTitle:"Manifolds II - Theory and Applications"},signatures:"Xueqi Ma and Weifeng Liu",authors:null},{id:"53552",title:"Sub-Manifolds of a Riemannian Manifold",slug:"sub-manifolds-of-a-riemannian-manifold",totalDownloads:1734,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"In this chapter, we introduce the theory of sub-manifolds of a Riemannian manifold. The fundamental notations are given. The theory of sub-manifolds of an almost Riemannian product manifold is one of the most interesting topics in differential geometry. According to the behaviour of the tangent bundle of a sub-manifold, with respect to the action of almost Riemannian product structure of the ambient manifolds, we have three typical classes of sub-manifolds such as invariant sub-manifolds, anti-invariant sub-manifolds and semi-invariant sub-manifolds. In addition, slant, semi-slant and pseudo-slant sub-manifolds are introduced by many geometers.",book:{id:"5488",slug:"manifolds-current-research-areas",title:"Manifolds",fullTitle:"Manifolds - Current Research Areas"},signatures:"Mehmet Atçeken, Ümit Yıldırım and Süleyman Dirik",authors:[{id:"191326",title:"Prof.",name:"Mehmet",middleName:null,surname:"Atceken",slug:"mehmet-atceken",fullName:"Mehmet Atceken"},{id:"196148",title:"Dr.",name:"Umit",middleName:null,surname:"Yildirim",slug:"umit-yildirim",fullName:"Umit Yildirim"}]},{id:"52886",title:"Head Pose Estimation via Manifold Learning",slug:"head-pose-estimation-via-manifold-learning",totalDownloads:1793,totalCrossrefCites:4,totalDimensionsCites:3,abstract:"For the last decades, manifold learning has shown its advantage of efficient non-linear dimensionality reduction in data analysis. Based on the assumption that informative and discriminative representation of the data lies on a low-dimensional smooth manifold which implicitly embedded in the original high-dimensional space, manifold learning aims to learn the low-dimensional representation following some geometrical protocols, such as preserving piecewise local structure of the original data. Manifold learning also plays an important role in the applications of computer vision, i.e., face image analysis. According to the observations that many face-related research is benefitted by the head pose estimation, and the continuous variation of head pose can be modelled and interpreted as a low-dimensional smooth manifold, we will focus on the head pose estimation via manifold learning in this chapter. Generally, head pose is hard to directly explore from the high-dimensional space interpreted as face images, which is, however, can be efficiently represented in low-dimensional manifold. Therefore, in this chapter, classical manifold learning algorithms are introduced and the corresponding application on head pose estimation are elaborated. Several extensions of manifold learning algorithms which are developed especially for head pose estimation are also discussed and compared.",book:{id:"5488",slug:"manifolds-current-research-areas",title:"Manifolds",fullTitle:"Manifolds - Current Research Areas"},signatures:"Chao Wang, Yuanhao Guo and Xubo Song",authors:[{id:"190308",title:"Dr.",name:"Chao",middleName:null,surname:"Wang",slug:"chao-wang",fullName:"Chao Wang"},{id:"190461",title:"Prof.",name:"Xubo",middleName:null,surname:"Song",slug:"xubo-song",fullName:"Xubo Song"},{id:"191562",title:"MSc.",name:"Yuanhao",middleName:null,surname:"Guo",slug:"yuanhao-guo",fullName:"Yuanhao Guo"}]}],onlineFirstChaptersFilter:{topicId:"165",limit:6,offset:0},onlineFirstChaptersCollection:[],onlineFirstChaptersTotal:0},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:8,numberOfPublishedChapters:87,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:98,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:27,numberOfPublishedChapters:286,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:9,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:11,numberOfPublishedChapters:139,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:8,numberOfPublishedChapters:129,numberOfOpenTopics:0,numberOfUpcomingTopics:2,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!1},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:105,numberOfOpenTopics:3,numberOfUpcomingTopics:1,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:9,numberOfPublishedChapters:101,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:11,numberOfOpenTopics:2,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:0,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!1},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:0,numberOfPublishedChapters:9,numberOfOpenTopics:4,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}},{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. 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