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Barely three months into the new year and we are happy to announce a monumental milestone reached - 150 million downloads.
\n\nThis achievement solidifies IntechOpen’s place as a pioneer in Open Access publishing and the home to some of the most relevant scientific research available through Open Access.
\n\nWe are so proud to have worked with so many bright minds throughout the years who have helped us spread knowledge through the power of Open Access and we look forward to continuing to support some of the greatest thinkers of our day.
\n\nThank you for making IntechOpen your place of learning, sharing, and discovery, and here’s to 150 million more!
\n\n\n\n\n'}],latestNews:[{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"},{slug:"introducing-intechopen-book-series-a-new-publishing-format-for-oa-books-20210915",title:"Introducing IntechOpen Book Series - A New Publishing Format for OA Books"}]},book:{item:{type:"book",id:"9444",leadTitle:null,fullTitle:"Ischemic Stroke",title:"Ischemic Stroke",subtitle:null,reviewType:"peer-reviewed",abstract:"Stroke continues to be a major public health issue. It is the third leading cause of death and disability across the globe. Its early identification and treatment along with prevention are major issues that confront a treating physician. We have understood the importance of early intervention and of the quote ‘time is brain’. Our endeavor now should be directed to the public at large and paramedics in particular. Although a stroke is a common condition, the availability of neurologists or stroke specialists is quite scarce. Today, management of a suspected case of stroke is done by a specialist team of medical and paramedical personnel. Advances in imaging, newer therapeutic agents, and endovascular management have revolutionized the management. Currently, we are witnessing a new era in the management of strokes and I am hopeful that continued research will get us to a satisfactory solution. This book along with another book from IntechOpen titled ‘Ischemic Stroke of Brain’ aims to improve the understanding of stroke medicine for postgraduate medical students in medicine and neurology who have an interest in stroke care.",isbn:"978-1-83962-395-0",printIsbn:"978-1-83962-394-3",pdfIsbn:"978-1-83962-396-7",doi:"10.5772/intechopen.86623",price:119,priceEur:129,priceUsd:155,slug:"ischemic-stroke",numberOfPages:130,isOpenForSubmission:!1,isInWos:null,isInBkci:!1,hash:"a24752137cbc5f228a3479e02a6a3d10",bookSignature:"Pratap Sanchetee",publishedDate:"March 24th 2021",coverURL:"https://cdn.intechopen.com/books/images_new/9444.jpg",numberOfDownloads:4209,numberOfWosCitations:0,numberOfCrossrefCitations:3,numberOfCrossrefCitationsByBook:0,numberOfDimensionsCitations:6,numberOfDimensionsCitationsByBook:0,hasAltmetrics:1,numberOfTotalCitations:9,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"September 26th 2019",dateEndSecondStepPublish:"March 3rd 2020",dateEndThirdStepPublish:"May 2nd 2020",dateEndFourthStepPublish:"July 21st 2020",dateEndFifthStepPublish:"September 19th 2020",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"206518",title:"Dr.",name:"Pratap",middleName:null,surname:"Sanchetee",slug:"pratap-sanchetee",fullName:"Pratap Sanchetee",profilePictureURL:"https://mts.intechopen.com/storage/users/206518/images/system/206518.jpg",biography:"Dr. Pratap Sanchetee is a first batch alumnus of Dr. SN Medical College, Jodhpur, and achieved his MBBS in 1970. Subsequently, he received his MD diploma (Medicine) from the University of Rajasthan in 1974, and DM (Neurology) from the Postgraduate Institute of Medical Education & Research (PGIMER), Chandigarh in 1985. He served in the Armed Forces India as a Physician and Neurologist for 24 years and retired as Lt Col in 1998. From 1994 to 1998, he also served as an Associate Professor, Armed Forces Medical College, Pune. He was awarded Chief of Army Staff’s Commendation in 1980. Since 1998, he has been pursuing clinical practice in neurology at various hospitals at Jodhpur and at Guwahati Assam. He has been a Visiting Professor, Ph.D. guide, and advisor to Jain Visva Bharti University (JVBI) and Bhagwan Mahaveer International Research Centre (BMIRC), Ladnun, Rajasthan since 2009. He is a Director of Research at the Spiritual Training Research Foundation (STRF), Mumbai, India. His areas of active interest are the mind as an interface between soul and body, meditation and the brain, and delivery of neurology care in society. Dr. Sanchetee has a life membership of 9 national associations. He is the editor of four books and has published 112 original papers, chapters, and review articles in national and international journals. He is currently the Chairperson of the 'Tropical Neurology Subsection' of the Indian Academy of Neurology. He regularly participates in national and international conferences and presents academic papers. He was an executive editor of the Medical Journal Armed Forces India and Journal of Indian Academy of Geriatrics.",institutionString:"Sanchetee Hospital & Research Institute",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"1",totalChapterViews:"0",totalEditedBooks:"2",institution:null}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"1056",title:"Neurology",slug:"neurology"}],chapters:[{id:"74822",title:"Current Trends in Stroke Rehabilitation",doi:"10.5772/intechopen.95576",slug:"current-trends-in-stroke-rehabilitation",totalDownloads:671,totalCrossrefCites:2,totalDimensionsCites:3,hasAltmetrics:0,abstract:"Stroke remains a leading cause of adult disability. The social, physical and psychological consequences of stroke are devastating. With better understanding of causation and breakthrough advances in management, we are witnessing a greater population of stroke survivors with varying neurological and functional deficits. Poststroke rehabilitation is a multi-disciplinary and multi-modal endeavor and not a ‘one size fits all’ intervention. A combination of interventions may be better suited to treat motor and sensory impairments, cognitive problems and psychological issues. There is great interest in exploring novel rehabilitation technologies to augment conventional therapies to reduce neurological disability and improve function. Yoga and spirituality, though ancient practices, are finding a bigger role in field of rehabilitation. In spite of good potentials for recovery, these rehabilitative measures are underutilized and major barriers are limited availability, geographical distance, high cost and lack of awareness about its benefits. While conventional measures are well engraved, this article review the recent concepts in stroke rehabilitation.",signatures:"Pratap Sanchetee",downloadPdfUrl:"/chapter/pdf-download/74822",previewPdfUrl:"/chapter/pdf-preview/74822",authors:[{id:"206518",title:"Dr.",name:"Pratap",surname:"Sanchetee",slug:"pratap-sanchetee",fullName:"Pratap Sanchetee"}],corrections:null},{id:"72380",title:"Ischemic Stroke in Young Adults: Practical Diagnosis Guide",doi:"10.5772/intechopen.92671",slug:"ischemic-stroke-in-young-adults-practical-diagnosis-guide",totalDownloads:980,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"With its increasing incidence in younger population and as a leading cause of disability, ischemic stroke represents a real public health problem. This chapter aims to evaluate the most common risk factors and causes for ischemic stroke in the young. Though some are identical to those found in older patients, most of them are specific to this population segment. Furthermore, another objective is to provide some guidance in approaching the case based on some important clinical clues. Due to the lack of universal management guidelines, it is up to the physician to judge the particularities of each case and to carry out the variety of investigations necessary for determining the cause.",signatures:"Diana Mihai, Florentina Cristina Plesa, Any Docu Axelerad, Alice Munteanu, Minerva Claudia Ghinescu and Carmen Adella Sirbu",downloadPdfUrl:"/chapter/pdf-download/72380",previewPdfUrl:"/chapter/pdf-preview/72380",authors:[{id:"318289",title:"Associate Prof.",name:"Carmen",surname:"Adella Sirbu",slug:"carmen-adella-sirbu",fullName:"Carmen Adella Sirbu"},{id:"318767",title:"Ms.",name:"Diana",surname:"Mihai",slug:"diana-mihai",fullName:"Diana Mihai"},{id:"320565",title:"Dr.",name:"Cristina Florentina",surname:"Plesa",slug:"cristina-florentina-plesa",fullName:"Cristina Florentina Plesa"},{id:"320566",title:"Dr.",name:"Any Docu",surname:"Axelerad",slug:"any-docu-axelerad",fullName:"Any Docu Axelerad"},{id:"320567",title:"Dr.",name:"Alice Elena",surname:"Munteanu",slug:"alice-elena-munteanu",fullName:"Alice Elena Munteanu"},{id:"320568",title:"Dr.",name:"Claudia Minerva",surname:"Ghinescu",slug:"claudia-minerva-ghinescu",fullName:"Claudia Minerva Ghinescu"}],corrections:null},{id:"72351",title:"Vascular Aphasias",doi:"10.5772/intechopen.92691",slug:"vascular-aphasias",totalDownloads:687,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:0,abstract:"Aphasia represents an acquired central disorder of language that impairs a person’s ability to understand and/or produce spoken and written language, caused by lesions situated usually in the dominant (left) cerebral hemisphere, in right-handed persons. Aphasia has a prevalence of 25–30% in acute ischemic stroke (vascular aphasia). It is considered as an important stroke severity marker, being associated with a higher risk of mortality, poor functional prognosis, and augmented risk of vascular dementia. The assessment of aphasias in clinical practice is based on classical analysis of oral production and comprehension. The language disturbances are frequently combined into aphasic syndromes which are components of different vascular syndromes that may evolve/involve rapidly at the acute stage of ischemic stroke. The main determinant of the type of vascular aphasia is the infarct location (especially left middle cerebral artery territory). Recent studies at the hyperacute stage of ischemic stroke have observed features of aphasia, have reanalyzed its neuroanatomy using new imaging techniques, and have shown that aphasias have a parallel course to that of cortico-subcortical hypoperfusion. Thus, the reversal of hypoperfusion, following recanalization (spontaneous or secondary to thrombolysis or thrombectomy), is associated with resolution of aphasia. Speech therapy is needed as soon as permitted by clinical condition.",signatures:"Dragoș Cătălin Jianu, Silviana Nina Jianu, Ligia Petrica, Traian Flavius Dan and Georgiana Munteanu",downloadPdfUrl:"/chapter/pdf-download/72351",previewPdfUrl:"/chapter/pdf-preview/72351",authors:[{id:"45925",title:"Prof.",name:"Dragoș",surname:"Cătălin Jianu",slug:"dragos-catalin-jianu",fullName:"Dragoș Cătălin Jianu"},{id:"55071",title:"Dr.",name:"Silviana Nina",surname:"Jianu",slug:"silviana-nina-jianu",fullName:"Silviana Nina Jianu"},{id:"241849",title:"Dr.",name:"Traian Flavius",surname:"Dan",slug:"traian-flavius-dan",fullName:"Traian Flavius Dan"},{id:"241852",title:"Dr.",name:"Georgiana",surname:"Munteanu",slug:"georgiana-munteanu",fullName:"Georgiana Munteanu"},{id:"318785",title:"Prof.",name:"Ligia",surname:"Petrica",slug:"ligia-petrica",fullName:"Ligia Petrica"}],corrections:null},{id:"72708",title:"Telestroke: A New Paradigm",doi:"10.5772/intechopen.92831",slug:"telestroke-a-new-paradigm",totalDownloads:623,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Stroke is one of the leading causes of death and disability across the world. With the development of new modalities of treatment, including the use of intravenous tissue plasminogen activator and mechanical thrombectomy, clinical outcomes have improved in patients with acute ischemic strokes. However, these interventions are time dependent, and there exists a great disparity between the rural and urban parts of the world in terms of the availability of neurologists and these lifesaving treatment options. Telestroke networks utilize digital technology for two-way, high-resolution video teleconferencing to help abate these disparities by bringing safe, efficient, and cost-effective care to underserved communities in the United States and around the world.",signatures:"Rohan Sharma, Krishna Nalleballe, Nidhi Kapoor, Vasuki Dandu, Karthika Veerapaneni, Sisira Yadala, Madhu Jasti, Suman Siddamreddy, Sanjeeva Onteddu and Aliza Brown",downloadPdfUrl:"/chapter/pdf-download/72708",previewPdfUrl:"/chapter/pdf-preview/72708",authors:[{id:"319857",title:"Ph.D.",name:"Aliza",surname:"Brown",slug:"aliza-brown",fullName:"Aliza Brown"},{id:"319923",title:"Dr.",name:"Krishna",surname:"Nalleballe",slug:"krishna-nalleballe",fullName:"Krishna Nalleballe"},{id:"320987",title:"Dr.",name:"Rohan",surname:"Sharma",slug:"rohan-sharma",fullName:"Rohan Sharma"},{id:"320988",title:"Dr.",name:"Nidhi",surname:"Kapoor",slug:"nidhi-kapoor",fullName:"Nidhi Kapoor"},{id:"320989",title:"Dr.",name:"Karthika",surname:"Veerapaneni",slug:"karthika-veerapaneni",fullName:"Karthika Veerapaneni"},{id:"320990",title:"Dr.",name:"Sisira",surname:"Yadala",slug:"sisira-yadala",fullName:"Sisira Yadala"},{id:"320991",title:"Dr.",name:"Sanjeeva",surname:"Onteddu",slug:"sanjeeva-onteddu",fullName:"Sanjeeva Onteddu"},{id:"320992",title:"Dr.",name:"Vasuki",surname:"Dandu",slug:"vasuki-dandu",fullName:"Vasuki Dandu"},{id:"320994",title:"Dr.",name:"Madhu",surname:"Jasti",slug:"madhu-jasti",fullName:"Madhu Jasti"},{id:"320995",title:"Dr.",name:"Suman",surname:"Siddamreddy",slug:"suman-siddamreddy",fullName:"Suman Siddamreddy"}],corrections:null},{id:"72501",title:"The Treatment of Acute Stroke",doi:"10.5772/intechopen.92763",slug:"the-treatment-of-acute-stroke",totalDownloads:655,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Stroke is a major public health issue, because of its high incidence rate, high case fatality rate, risk of residual physical and neuropsychological disabilities, and direct and indirect costs. Many strokes are preventable and treatable in the acute stage, provided that patients are admitted soon enough. The term stroke covers a wide range of heterogeneous disorders, depending on the severity of the clinical presentation, from transient deficits to severe cases with coma and early death; the underlying mechanism, i.e., cerebral ischemia, parenchymal hemorrhage, subdural hemorrhage, or subarachnoid hemorrhage (SAH); and the cause, i.e., atherosclerosis, cardioembolism, small-vessel occlusion, rare vasculopathies and undetermined causes in cerebral ischemia, or vascular malformations, cerebral amyloid angiopathies, small-vessel diseases, rare vasculopathies and undetermined causes in parenchymal hemorrhages. This chapter will focus only on acute cerebral ischemia and parenchymal hemorrhage. We will cover the general assessment of stroke patients, the complications that can occur in the acute stage, the treatment of acute stroke, and finally a few situations that require specific managements and where evidence-based data are scarce.",signatures:"Irina Alexandrovna Savvina and Anna Olegovna Petrova",downloadPdfUrl:"/chapter/pdf-download/72501",previewPdfUrl:"/chapter/pdf-preview/72501",authors:[{id:"318757",title:"Associate Prof.",name:"Irina Alexandrovna",surname:"Savvina",slug:"irina-alexandrovna-savvina",fullName:"Irina Alexandrovna Savvina"},{id:"319118",title:"Dr.",name:"Anna Olegovna",surname:"Petrova",slug:"anna-olegovna-petrova",fullName:"Anna Olegovna Petrova"}],corrections:null},{id:"70917",title:"Vinpocetine and Ischemic Stroke",doi:"10.5772/intechopen.90551",slug:"vinpocetine-and-ischemic-stroke",totalDownloads:596,totalCrossrefCites:0,totalDimensionsCites:2,hasAltmetrics:1,abstract:"Vinpocetine (VPN) is a synthetic ethyl-ester derivative of the alkaloid apovincamine from Vinca minor leaves. VPN is a selective inhibitor of phosphodiesterase type 1 (PDE1) has potential neurological effects through inhibition of voltage gated sodium channel and reduction of neuronal calcium influx. VPN have noteworthy antioxidant, anti-inflammatory and anti-apoptotic effects with inhibitory effect on glial and astrocyte cells during and following ischemic stroke (IS). VPN is effective as an adjuvant therapy in the management of epilepsy; it reduces seizure frequency by 50% in a dose of 2 mg/kg/day. VPN improves psychomotor performances through modulation of brain monoamine pathway mainly on dopamine and serotonin, which play an integral role in attenuation of depressive symptoms. VPN recover cognitive functions and spatial memory through inhibition of hippocampal and cortical PDE-1with augmentation of cAMP/cGMP ratio, enhancement of cholinergic neurotransmission and inhibition of neuronal inflammatory mediators. Therefore, VPN is an effective agent in the management of ischemic stroke and plays an integral role in the prevention and attenuation of post-stroke epilepsy, depression and cognitive deficit through direct cAMP/cGMP-dependent pathway or indirectly through anti-inflammatory and anti-oxidant effects.",signatures:"Hayder M. Al-kuraishy and Ali I. Al-Gareeb",downloadPdfUrl:"/chapter/pdf-download/70917",previewPdfUrl:"/chapter/pdf-preview/70917",authors:[{id:"306350",title:"Prof.",name:"Hayder M.",surname:"Al-kuraishy",slug:"hayder-m.-al-kuraishy",fullName:"Hayder M. Al-kuraishy"}],corrections:null}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},subseries:null,tags:null},relatedBooks:[{type:"book",id:"6789",title:"Ischemic Stroke of Brain",subtitle:null,isOpenForSubmission:!1,hash:"c63002a8b0e07111f925c3e8b313d721",slug:"ischemic-stroke-of-brain",bookSignature:"Pratap Sanchetee",coverURL:"https://cdn.intechopen.com/books/images_new/6789.jpg",editedByType:"Edited by",editors:[{id:"206518",title:"Dr.",name:"Pratap",surname:"Sanchetee",slug:"pratap-sanchetee",fullName:"Pratap Sanchetee"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1191",title:"Neuromuscular Disorders",subtitle:null,isOpenForSubmission:!1,hash:"6f634511340dcd5fe321e13e83a62531",slug:"neuromuscular-disorders",bookSignature:"Ashraf Zaher",coverURL:"https://cdn.intechopen.com/books/images_new/1191.jpg",editedByType:"Edited by",editors:[{id:"66392",title:"Prof.",name:"Ashraf",surname:"Zaher",slug:"ashraf-zaher",fullName:"Ashraf Zaher"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"745",title:"Neurodegenerative Diseases",subtitle:"Processes, Prevention, Protection and Monitoring",isOpenForSubmission:!1,hash:"3d5795dad33257368f0b7848c22d5dd4",slug:"neurodegenerative-diseases-processes-prevention-protection-and-monitoring",bookSignature:"Raymond Chuen-Chung Chang",coverURL:"https://cdn.intechopen.com/books/images_new/745.jpg",editedByType:"Edited by",editors:[{id:"33396",title:"Dr.",name:"Raymond Chuen-Chung",surname:"Chang",slug:"raymond-chuen-chung-chang",fullName:"Raymond Chuen-Chung Chang"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3278",title:"Neurodegenerative Diseases",subtitle:null,isOpenForSubmission:!1,hash:"aa717c2801cf98db641d48414cef8ced",slug:"neurodegenerative-diseases",bookSignature:"Uday Kishore",coverURL:"https://cdn.intechopen.com/books/images_new/3278.jpg",editedByType:"Edited by",editors:[{id:"155691",title:"Dr.",name:"Uday",surname:"Kishore",slug:"uday-kishore",fullName:"Uday Kishore"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"434",title:"Alzheimer's Disease Pathogenesis",subtitle:"Core Concepts, Shifting Paradigms and Therapeutic Targets",isOpenForSubmission:!1,hash:"49f4c7dbf69e8a9eaf780e37f4aae1ab",slug:"alzheimer-s-disease-pathogenesis-core-concepts-shifting-paradigms-and-therapeutic-targets",bookSignature:"Suzanne De La Monte",coverURL:"https://cdn.intechopen.com/books/images_new/434.jpg",editedByType:"Edited by",editors:[{id:"29111",title:"Dr.",name:"Suzanne",surname:"De La Monte",slug:"suzanne-de-la-monte",fullName:"Suzanne De La Monte"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3296",title:"Understanding Alzheimer's Disease",subtitle:null,isOpenForSubmission:!1,hash:"b040d696d429a2a6dc90cd236f160778",slug:"understanding-alzheimer-s-disease",bookSignature:"Inga Zerr",coverURL:"https://cdn.intechopen.com/books/images_new/3296.jpg",editedByType:"Edited by",editors:[{id:"26013",title:"Prof.",name:"Inga",surname:"Zerr",slug:"inga-zerr",fullName:"Inga Zerr"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3437",title:"Mood Disorders",subtitle:null,isOpenForSubmission:!1,hash:"62c54b70da87ce48e712c07601105311",slug:"mood-disorders",bookSignature:"Nese Kocabasoglu",coverURL:"https://cdn.intechopen.com/books/images_new/3437.jpg",editedByType:"Edited by",editors:[{id:"91417",title:"Prof.",name:"Nese",surname:"Kocabasoglu",slug:"nese-kocabasoglu",fullName:"Nese Kocabasoglu"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1062",title:"Dystonia",subtitle:"The Many Facets",isOpenForSubmission:!1,hash:"81069e5ab5b7c4bb52cf7bd16d0c4cb2",slug:"dystonia-the-many-facets",bookSignature:"Raymond L. 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This introductory chapter gives a general view of global energy state, demand, and some of the historical events which have led to the current global energy situation. A brief review of the trends in energy research, the motivation, and direction are then presented.
\nThe world demand for energy is projected to continue due to increased population and associated economic activities in addition to technological developments and changes. Environmental concerns related to traditional energy sources such as fossil fuels and recognition, that this is a diminishing resources globally, has given impetus in the development and search for a number of alternative energy sources. To date, new methods and techniques that allow energy to be harvested mechanically, electronically, magnetically, thermally, biochemically, or through some other means for different purposes and applications have been developed. However, some of the methods and techniques still require refinement and perfection in order to realize their full potentials. For example, despite solar cell technology having matured over the years, its full utilization of photovoltaic (PV) systems has been hampered by high costs related to processing technologies of silicon as well as limited conversion efficiency. In this respect, new materials are being tested to solve the high-cost problem.
\nPrior to the development of coal in the mid-nineteenth century, nearly all energy used was renewable. Energy that can be collected and naturally replenished on human timescale such as sunlight, wind, rain, tides, waves, and geothermal heat are termed renewable energy [1]. Four important areas—electricity generation, air and water heating/cooling, transportation, and rural (off-grid) energy—are the areas in which renewable energy provides services [2]. There is no doubt that traditional biomass used for fuel fires is one of the oldest forms of renewable energy. The use of biomass has been traced back to about 790,000 years ago. According to much literature, biomass for fire did not become commonplace until many hundreds of thousands of years later, sometime between 200,000 and 400,000 years ago. Many authors put the second oldest usage of renewable energy as harnessing the wind in order to drive ships over water. The practice can be traced to ships in the Persian Gulf and on the Nile some 7000 years ago. However, historical records show that the primary sources of traditional renewable energy were human labor, animal power, water power, wind, in grain crushing windmills, and firewood, a traditional biomass.
\nFears that civilization would run out of fossil fuels started to emerge in the 1860s and 1870s and the need was felt for a better source of energy.
\nThe start of a major global energy crisis of the twentieth century began to unfold as petroleum production in the United States and some other parts of the world peaked in the late 1960s and early 1970s. World oil production in different oil producing countries began a long-term decline after 1979. The problems brought about by these events created a crisis which came to be known as the 1970s energy crisis. Major industrial countries of the world, particularly the United States, Canada, Western Europe, Japan, Australia, and New Zealand, faced substantial petroleum shortages, real and perceived, as well as elevated prices. The year 1973 saw the first worst oil crisis period. This was followed by another energy crisis in 1979, when the Yom Kippur War and the Iranian Revolution triggered interruptions in Middle Eastern oil exports [3, 4, 5, 6]. The major industrial centers of the world were forced to contend with escalating issues related to petroleum supply. Western countries started creating reliance on the resources of potentially unfriendly countries in the Middle East and other parts of the world.
\nWhat followed after the 1970 oil crisis led to stagnant economic growth in many countries as oil prices rose sharply. Although there were genuine concerns with supply, part of the run-up in prices resulted from the perception of a crisis. The combination of stagnant growth and price inflation during this era led to the coinage of the term
Both the recessions of the 1970s and adjustments in local economies saw many nations and countries finding ways to use petroleum in a more efficient manner. Strategies were developed and put in place which saw the petroleum prices worldwide return to more sustainable levels in the 1980s [7].
\nThe 1970 oil crisis period was not uniformly negative for all economies. Petroleum-rich countries in the Middle East benefited from increased prices and the slowing production in other areas of the world. Some other countries, such as Norway, Mexico, and Venezuela, benefited as well. Major economic booms were experienced in the United States in places such as Texas and Alaska and some other oil-producing areas due to high oil prices even though most of the rest of the country struggled with poor and stagnant economy. Many of the economic gains, however, did not continue as oil prices stabilized and dropped in the 1980s [8, 9, 10].
\nWhile all these events were taking place, researchers worldwide intensified their efforts toward the search and development of energy that is collected from renewable resources, which are naturally replenished on a human timescale, such as sunlight, wind, rain, tides, waves, and geothermal heat for industrial and domestic uses. The sources called renewable energy sources often provide energy in four important areas: electricity generation, air and water heating/cooling, transportation, and rural (off-grid) energy services.
\nWith the emergence of new technologies employing semiconductors requiring low current and the realization that fossil fuels cause climate change and global warming coupled with high oil prices, the search for new and renewable energy and energy sources intensified. There has been increasing different world government support in terms of driving renewable energy legislation, incentives, and commercialization. New government spending, regulations, and policies that were implemented helped the energy industry weather the global financial crisis better than many other sectors. In a report of 2011 by the International Energy Agency, it is projected that solar power generators may produce most of the world’s electricity within 50 years, reducing the emissions of greenhouse gases that harm the environment [11]. These sentiments have been echoed by the United Nations Secretary Ban Ki-moon.
\nAs of 2011, small solar PV systems provided electricity to a few million households, and micro-hydro configured into mini-grids served many more. Though rural folks in least developed countries have no electricity, many households now rely on renewable energy such as biogas made in household-scale digesters for lighting and/or cooking. Others rely on new generations of more efficient biomass cook stoves. These efforts are, however, doing very little to address the bigger problem of global warming. On the other hand, the United Nations is highly in support of the renewable energy initiatives and believes that renewable energy has the ability to lift the poorest nations to new levels of prosperity [12].
\nApart from the mainstream technologies using large amounts of energy, new gadgets in many households globally presently rely on continuous supply of small amounts of energy. Different forms of renewable energy sources are now in abundant supply for their operations. Mobile phones, portable Compact Disc players, and sport lights have evolved so much that most of them use rechargeable batteries. Though some of these gadgets are working quite well, researchers are still pushing the limits to perfect their energy supplies.
\nEnergy has a fundamental importance in the human civilization. Conventional methods are used for the production of energy use oil, gas, and coal. The reservoirs of oil and gas in the world are decreasing, and the burning of oil and gas causes a threat to the environment; therefore, people are searching for cheap methods for the production of clean energy. These renewable energy production methods include photovoltaic, nuclear energy, biogas, wind energy, and thermoelectricity. All these methods have their advantages and disadvantages. For example, solar cells can produce energy during the daylight and also need high technology for the fabrication of solar cells. Nuclear energy production needs nuclear power plants which not only require high cost but also a high risk for the community. Similarly, wind energy can only be produced in the strong windy areas. On the other hand, thermoelectricity is very cheap and an easy method for the clean energy production. Thermoelectricity is based on the very famous Seebeck effect which was invented by Seebeck in 1821 and is stated as.
\nAn emf is induced when a temperature difference is created between two metal junctions. Thermoelectricity needs only temperature difference between two metals; therefore, it is supposed to be the cheapest form of clean energy. It is reported that that 60% of heat produced during cooking process, in industry and in running vehicles, is wasted, but we are able to convert this wasted heat into electricity using thermoelectric power generators; we can save huge amount of money. Furthermore, thermoelectricity has other advantages over other sources of energy such as it has no moving parts, it is environment friendly, no specialized technology is required, and it is less maintenance.
\nThe thermoelectric devices convert thermal energy into electrical energy, and the principle is based on the Seebeck effect invented by Seebeck in 1821. It states that a voltage is induced between two points of metal/semiconductor having a difference of temperature as shown in Figure 1. The charge carriers on the hot side can have more energy than the cold side; therefore, they form a potential difference. Suppose dT is the temperature between hot and cold side of sample, therefore according to Seebeck effect.
\nSchematic diagram of the Seebeck effect.
where S is the Seebeck coefficient.
\nAnother term frequently used in thermoelectric is the power factor which is defined as.
\nwhere α is electrical conductivity.
\nThe performance of thermoelectric material strongly depends upon a unit less quantity called figure of merit:
\nThis equation shows that for a good thermoelectric material, high Seebeck coefficient, high electrical conductivity, and low thermal conductivity are essential.
\nThe thermoelectric conversion efficiency depends upon a quantity called figure of merit and can be written as [1].
\nwhere S is the Seebeck coefficient, α is the electrical conductivity, and σ is the thermal conductivity.
\nThe figure of merit for a material to be used for practical power generation system should be in the range of 2–3 [2]. But the best reported value of figure of merit for oxide semiconductor is not more than 0.1. Figure 2 indicates the history of efforts to increase the figure of merit.
\nA brief history of materials used for thermoelectric applications.
Different strategies have been employed to tune and alter the thermoelectric properties. The general techniques are as follows [3]:
Optimization using doping techniques
Substructuring
Nanostructuring
Compositing
But for the semiconductors the governing parameters includes the following:
\nBand structure is a very important parameter to tune the thermoelectric properties of oxide semiconductors. One of the most important methods of band gap control is varying the carrier concentration by doping [4]. But the doping process itself required a high technology that increased the cost of thermoelectric devices very high. So if we tune the carrier concentration by controlling the density of intrinsic defects, this will cut short the cost of the final device. Interestingly, oxide semiconductors have rich the chemistry of intrinsic defects. Oxygen vacancy and zinc interstitials act as intrinsic shallow donors and form electronic states near the conduction band [5].
\nThe mobility of carriers in thermoelectric materials has played a vital role in the tuning of Seebeck coefficient and power factor. The power factor is strongly dependent on the conductivity which has strong dependence on mobility. Therefore, the modulation of mobility to achieve highest value of power factor is necessary. The mobility of the carrier can be controlled by the scattering mechanisms. Two scattering mechanisms, that is, lattice scattering and impurity scattering mechanisms, are very important in oxide semiconductors [6].
\nDiffusion is a process of movement of particles from hot junction to cold junction in thermoelectric material. The diffusion of charge carriers has fundamental importance to tune the thermoelectric properties of oxide semiconductors. The diffusion in compound semiconductors is more complex than in elemental semiconductors because of the larger number of possible native point defects that can, in principle, mediate self-diffusion [7, 8]. Oxide semiconductors have high density of intrinsic defects, which in principal affect the diffusion of charge carriers. Therefore, for the effective use of oxide semiconductors for thermoelectric properties, the control of intrinsic defects has fundamental importance and should be studied further. Again, we propose that annealing will be a very effective method of studying the diffusion properties of carriers in oxide semiconductors.
\nThermal expansion is critical, as the devices for high-temperature applications will be subjected to extreme temperature fluctuations. The CTE of TE materials is of critical importance because the shear stress is proportional to the temperature gradient, and the larger the heterogeneity in the thermal expansion coefficient of a material is, the larger is the shear stress that will result [9]. It is also reported that thermal expansion coefficient of semiconductor for low- and high-temperature region is almost the same but different for medium temperature. Therefore, a comprehensive study on the thermal expansion coefficient is still needed to completely understand the mechanism [10].
\nIn this study, experiment is held under thermal vapor deposition technique using single-stage horizontal glass tube furnace. In this experiment, 99.9% pure magnesium, Zinc, and Copper powders along with Ge, In, and Al powders are used under the ratio 1:1 as source material. This source material is being kept in the center of a glass tube in ceramic boat. The silicon substrate is placed at substrate holder, and the distance between source and the substrate is about 15 cm. The temperature of the furnace is tuned at 950°C for 30 min, whereas the oxygen flow is kept constant at 100 sccm. After the growth of thin film, the substrate of silicon is divided into different pieces for annealing purpose at different temperatures from 600 to 800°C for 30 min.
\nX-ray diffraction has been performed for the structural analysis of grown thin film. Raman spectroscopy has been also performed to study the rotational and vibrational modes of thin film. Surface morphology is being assessed by the scanning electron microscope (SEM). The most important characterization to calculate Seebeck coefficient has been performed on the homemade Seebeck system which is based on the four-probe system. And the thickness of the thin film has been measured by the filmtronics technique and it is about.
\n\nFigure 3(a–c) represents the XRD patterns of Cu2InO4, CuAlO2, and Zn2GeO4 thin films annealed at different temperature from 600 to 800°C, respectively. The XRD graph of Cu2InO4 thin films in Figure 3(a) demonstrated that unannealed and low temperature (600°C) would not be able to make the grown material crystalline due to low thermal energy for bonding. But as we increased the temperature above 600°C, the sample is converted into crystalline structure with preferred orientation (006) at 2θ = 33.086° [11, 12]. It is also observed that the intensity of this plane is increased as we further increase the annealing temperature, which suggested that carriers now get enough energy to sit down at a particular position in planes of the crystal. Figure 3(b) shows the XRD graph of CuAlO2. The unannealed sample consists of one major phase at 2θ = 32.05 which belongs to CuAlO2 (0 0 6) plane [13]. Annealing resulted in the development of new phases at 2θ = 35.4, 42.4, and 48.4 related to CuO (1 1 1) and CuAlO2 (1 0 4) and (0 0 9) orientations, respectively. We have observed that (0 0 6) plane has the strongest intensity which is oxygen sensitive; therefore, enhancement of intensity of this plane with annealing temperature is understandable.
\n(a–c) XRD patterns of Cu2InO4, CuAlO2, and Zn2GeO4, respectively.
\nFigure 3(c) shows the XRD pattern of grown and annealed samples of Zn2GeO4 thin films at various temperatures. The unannealed and annealed samples consist of eight diffraction peaks which are related to Zn2GeO4, Si, Au, and ZnO, respectively. The diffraction peak at 25.8, 42.9, 44.7, 58.4, 58.9, and 65° are belonging to Zn2GeO4which are indexed as (2 2 0), (6 0 0), (0 0 6), (6 3 0), and (7 1 3), respectively [14]. The peak which appears at 28.6° and 38.4° is belonging to (1 1 1) plane of Si and Au [15, 16], respectively, along with peak of ZnO at 34.6° having (0 0 2) plane [17]. It is observed that substrate and pre-deposited gold shows maximum intensity in all the samples which is attributed to the thin porous layer deposited over the substrate. The XRD data also demonstrated that the sample annealed at 900oC has three additional peaks at 45.7° and 65° which are related to the secondary phases of Zn2GeO4.
\n\nFigure 4(a–c) demonstrated the effect of annealing temperature on the Seebeck coefficient of Cu2InO4, CuAlO2, and Zn2GeO4 thin films grown by thermal evaporation technique, respectively. All graphs showed that the value of Seebeck coefficient increases as the annealing temperature increased. It is also observed that the value of Seebeck coefficient also increases as the measurement temperature increases from 25 to 100°C. Zn2GeO4 has the highest value of the Seebeck coefficient (1470 μV/K) as compared to Cu2InO4 and CuAlO2. The observed result can be explained as post-growth annealing enhances the density of oxygen atoms and also provides more thermal energy to Ge atoms which resulted in the creation of GeO-based secondary phases. These newly developed secondary phases act as barrier for charge carriers at the interface of secondary phases. Due to this barrier, the low-energy carriers are filtered out at the interface and caused the enhancement in the Seebeck coefficient. As other two samples have no secondary, therefore have lower value of the Seebeck coefficient as evident by XRD data (Figure 5
(a–c) Effect of annealing temperature on the Seebeck coefficient of Cu2InO4, CuAlO2, and Zn2GeO4, respectively.
(a–c) Effect of annealing temperature on the power factor of CuInO, CuAlO, and ZnGeO thin films grown by thermal evaporation, respectively.
To further probe the effect of annealing temperature on the thermoelectric properties of grown oxide semiconductors, we have calculated the power factor using the following formula:
\nwhere S is Seebeck coefficient and α is electrical conductivity. The power factor is enhanced significantly with increasing annealing and measurement temperature because both Seebeck coefficient and electrical conductivity increases.
\nThis chapter described the effect of annealing temperature on the thermoelectric properties of oxide semiconductors. All samples were grown by thermal evaporation technique using tube furnace under vacuum using similar growth conditions. After growth, oxide semiconductors were annealed in oxygen environment at various temperatures. The reported results have suggested that Zn2GeO4 has good potential to be used as thermoelectric material because it has the highest value of Seebeck coefficient and power factor.
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All published Book Chapters are licensed under a Creative Commons Attribution 3.0 Unported License. Monographs are licensed under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) license granted to all others. Our Copyright Policy aims to guarantee that original material is published while at the same time giving significant freedom to our Authors. IntechOpen upholds a flexible Copyright Policy meaning that there is no copyright transfer to the publisher and Authors hold exclusive copyright to their work.
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