The most applicable in-situ and ex-situ bioremediation techniques for hydrocarbon removal.
\r\n\tReservoir characterization is defined as the model that characterises the reservoirs based on their ability to store and produce hydrocarbons. They are used to indicate the reservoir fluids' behaviour under different circumstances and to find the optimal production techniques that can maximise production. Reservoir modeling is the process of creating a three-dimensional representation of a given reservoir based on its petrophysical, geological, and geophysical properties. These properties are defined during reservoir characterization where geoscientists and engineers gather all physical and chemical data to extrapolate those values throughout the reservoir. They can then create a three-dimensional model to be used for reservoir simulation. From a practical point of view, the integrated reservoir modeling represents now the most valuable technical approach for estimating the oil/gas reserves and computing the future production profiles, reducing the uncertainties always associated with the static and dynamic reservoir descriptions. Reservoir engineering is the formulation of development and production plans that will result in maximum recovery for a given set of economic, environmental, and technical constraints which is not a one-time activity but needs continual updating throughout the production life of a reservoir. Reservoir management is often defined as the allocation of resources to optimize hydrocarbon recovery from a reservoir while minimizing capital investments and operating expenses.
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Later, people measured their fields, they measured and counted the pieces of wood and stones when they built their houses and temples and manufactured things of daily use. When currency was invented, calculations were necessary for how much, for what remains and for how much is owed.
This primitive pre-mathematics—the useful, practical tool—is the basis for “scientific” mathematics, as we understand it today. According to Proclus, it was Pythagoras who stripped mathematics from the servant position in crafts and trade and elevated it to the “liberal arts”. Mathematics shifted to the ideal, intelligible world, the world visible only to our inner sight, the world where everything is absolutely accurate. Mathematics has remained in this “Pythagorean paradise” to this day. More precisely, it stands between our daily, temporal, physical world (which supplies it with practical problems) and the higher, eternal, metaphysical world—the “Pythagorean paradise”. In the original Pythagorean view, this “higher” world also has a “supernatural nature”. Numbers not only expressed quantities but also bore deeper, metaphysical meaning. There is, however, a close mutual interaction between these two realms: the “higher” metaphysical world helps mathematics solve practical problems, and the physical world serves as a window through which flesh sparks from the “higher” world. This higher world, however, also carries problems of its own, to be discussed in a later section.
It was Plato who expanded and absolutised this Pythagorean paradise and created the realm of forms-ideas. This realm concerns not only mathematics but also spans above the entire mundane world. This conception of mathematics is called mathematical Platonism, though it should preferably be called Pythagoreanism—but history isn’t usually fair. (Especially astounding in this connection is the fact that, in Plato’s system, mathematical forms had a slightly lower degree of reality than other forms. See Plato’s Republic.)
It bears mentioning that many candidates for entry to that mathematical paradise were and still are of suspicious nature and their adoption is regarded with hesitation. Allow them inside, or rather not? During the time of the Pythagoreans, the most provocative question concerned irrational numbers. Such queer numbers were called ALOGION—“illogical”—or “ALOGION KAI ANEIDON”—“inexpressible and unthinkable”. More precisely, the Pythagoreans refused to even consider such peculiarities as numbers; they refused to attribute existence to them and didn’t allow them into their “mathematical paradise”. An even bigger problem presented itself with APEIRON, that is, infinity. The concept of infinity holds a place in ancient history but, as with all other old concepts, that of infinity was still very vague. The Pythagoreans then tried to clarify the meaning of APEIRON and integrate it into their mathematics. Their attempt, however, was unsuccessful. Infinity was also “ALOGION KAI ANEIDON”, that is, in contradiction to reason and non-restrictive.
Since rationality verbally and consequently also conceptually coincided with the numerical ratio—with the existence of rational numbers (in mathematics it still coincides, at least on a verbal level), the Pythagoreans concluded that rational numbers can express all quantities. A rational number can truly approximate any value with arbitrarily high accuracy. A physicist or an engineer would manage them easily. However, this “reasonable assumption” led Pythagoreans to the dispute, which was not only perceived as the first mathematics crisis but mainly as a crisis of reason-LOGOS.
Admission of such suspect concepts like infinity or irrational numbers would subvert their mathematical paradise. Since everything is a number and a defining limit, our world would have collapsed along with the fall of the mathematical world—at least according to the Pythagoreans—however, this thesis is repeated even by some mathematicians today [1].
The issues of irrational numbers and infinity have the same denominator, as irrational numbers contain an “inner infinity”. Their writing as a fraction (LOGOS) would have to consist of an infinite numerator as well as denominator—if that were possible. Even their decimal notation would be infinite—if that were possible… (The Pythagoreans were obviously unaware of that at the time.)
According to the legend, the Pythagoreans tried to keep the existence of incommensurability (irrational numbers) a secret. It contradicted their basic idea that the world is rationally tangible. It is also said that the life of Hippasus, the (alleged) discoverer of incommensurability, ended in the depths of the sea. Apparently, he was drowned by the gods because he revealed the Pythagorean secret. Perhaps he was drowned by the Pythagoreans themselves. The story is even alive today as it is witnessed by another variant of the legend, authored by the contemporary mathematician, Rudy Rucker [2]. He suggests that Pythagoras himself was behind the death of Hippasus. Rucker, however, neglected to mention that Hippasus lived a hundred years after Pythagoras. Be that as it may, the story is more important than the facts insomuch as “poetry is more philosophical than history”, as stated by Aristotle [3]. The aforementioned legends can be understood symbolically: poor Hippasus drowned in the very APEIRON that is hidden in the concept of irrational numbers. Just as the body can drown in the boundless vastness of the ocean, the soul can be drowned in the immense APEIRON. APEIRON is a metaphor for the ocean, and the ocean is a metaphor for APEIRON-infinity.1
According to Aristotle view, we should consider two types of infinity: the actual one which is present here and now, and the potential one which is present only in a possibility. In his Physics [4], he says that infinity could be understood similarly as a finite number, that is, the quantity of some units or some size. This would correspond to actual infinity. Although in nature, we don’t encounter such limitless quantities and we apparently don’t need it in mathematics either. For example, we can imagine dividing a segment into an infinite number of parts, but no one can carry out such a task. Therefore, it is necessary to reject the existence of actual infinity. In essence, only the potential infinity (DYNAMIKOI) remains. (For details see Refs. [5, 6].)
The concepts of actuality and potentiality (ENTELECHEIA and DYNAMIS) were introduced by Aristotle already in his Metaphysics [5, 7]. He illustrated them in the example of marble or bronze. These materials are a statue in their potentiality–possibility. All that is necessary is to cut away the superfluous stone, cast the metal in the mould. The possibility will be fulfilled, realised. However, in the case of infinity, Aristotle’s analogy of the statue is clearly lacking. Unlike the “actual statue” in which the “potential statue” (i.e. a piece of stone) can be remodelled, potential infinity can’t be “remodelled”–as actual infinity does not exist! Aristotle himself was aware of this issue:
Despite these problems, Aristotle accepted the existence of potential infinity as did all other ancient mathematicians. (Actual infinity, as we will see, was not afforded the same acceptance for quite a long time.) For example, Aristotle considered the number of points on a line as potentially infinite. In Aristotle’s view, a line doesn’t “consist” of an infinite number of points nor can it be divided into an infinite number of points. (This view was already pointed out by Zeno of Elea in his APORIA on a bisection of a line.) We can, however, create points on the line without limitation–by cutting it in half over and over, for example. We will always reach only a finite number of points, in this case. Aristotle’s opinion actually defines what the concept of existence means in the case of points on a line (as well as other geometric shapes, of course). In this manner, Aristotle introduced the category of potentiality into mathematics.
However, using the concept of “potentiality” regarding infinity is problematic. Potential infinity isn’t something that can be achieved or something that we can approach. “Approaching infinity” is just receding from finite limits–from certain finite numbers and values. Potential infinity can’t be defined by actual infinity as it is only the negation of the finite. It is not defined positively nor is it “something” I can “have in front of me” in some sense; it is not an object. Potential infinity is a mere designation of a process which is altogether impossible to be finished in principle. Its reality is, in essence, only “borrowed”.
So-called potential infinity is but an ongoing process of enlargement,2 a movement in a general sense. Although movement isn’t actual nor potential, according to Aristotle! Wouldn’t it be, therefore, more accurate to speak of processual infinity?
As we have seen, the Pythagorean God (perhaps there was only one God in the Pythagorean religion) protected people against paradoxes and confusions. The role of the Christian God was different, however. Although not a mathematician, it was St. Augustine who first summoned God to the realm of mathematics. Augustine attempted to combine Platonism and Christian theology on the philosophical plane. In his “Theo-Platonism”, he placed Plato’s realm of forms (ideas) in the mind of God. The existence of infinity Augustine justified on the grounds of God’s omniscience. Since God is all-knowing, He must know all numbers; hence, He must also be cognizant of infinity [9]. In this manner of thinking, actual infinity exists–at the very least in the mind of God. Variations of this theological “proof of infinity” have survived to the present day, though this “proof” is open to question even in terms of theology:
It was Thomas Aquinas who, in his attempts to rationalize theology, demonstrated that not even God can know concepts that are intrinsically contradictory, that is, nonsense. So if actual infinity were a dubious concept, not even God could help it [10].
The second objection: If (actual) infinity exists in front of God’s eyes, does it mean it should exist also for us mortals? How does this relate to the story of the forbidden fruit of knowledge?
And perhaps the most serious objection: is it appropriate to suppose mathematics could be dependent on theological arguments?
The concept of infinity was addressed by many philosophers and mathematicians. Most of them surrendered before it due to its paradoxical and contradictory nature. (Descartes, Galileo…)
But what is meant by “paradoxical nature”? This is simply a contradiction to our presentiment of how things should be. It is a contradiction to our subconscious philosophy of mathematics and in conflict with our prejudices. But what about “real, that is, inner contradiction”? This means mutual conflict of accepted assumptions. However, in the case that we have two contradictory assumptions, does it mean therefore that just the assumption of the existence of infinity should be avoided?
One of those who were not afraid of accepting infinity was Spanish Jesuit Rodrigo de Arriaga (1592–1667).3 He worked in the first half of the seventeenth century as a professor in Clementinum College in Prague.4 (As a curiosity, it bears mentioning that Arriaga illustrated the existence of actual infinity by way of the number of angels.) Arriaga accepted the existence of actual infinity and divided it into five types: four secular (infinity in number, extension, intensity and perfection-quality) and one divine which is related to God only [11, 12]. He formulated many interesting and farsighted approaches to infinity; however, he did not create a consistent mathematical theory of infinity.
One of the most interesting thinkers to undertake the problem of infinity was Bohemian scholar Bernard Bolzano (1781–1848).
Bolzano studied at Clementinum College, where the spirit of Rodrigo de Arriaga lived on. Upon completion of his studies of philosophy and mathematics, he was still concerned with matters of theology. He was a lengthy hesitation. He was influenced by the ideas of the Enlightenment and approached all of the supernatural with scepticism. Wasn’t it all only myth and delusion? Wasn’t it in contradiction with history? Eventually, Bolzano acquiesced to the ethos of the moral and practical implications of religion–that faith in God brings good to people and he aimed to take part in the dissemination of good help. On 7th April, 1805, he was ordained a priest, and ten days later, he graduated as a doctor of philosophy. Bolzano preached at the Church of the Holy Saviour (a part of Clementinum College) and taught at the newly established department of religious studies. His position was rather complicated, however, as there was a strong anticlerical sentiment among the students, and Bolzano was booed. Eventually, Bolzano gained control of the situation and became a popular teacher. Nevertheless, he soon faced resistance from the opposite side. Bolzano’s idiosyncratic views and his approach to religion were met with contempt at the Vienna suzerain. A professor of religious science paid by the Austrian State was thoroughly expected to teach only what he had been instructed. He should not independently invent, even if it were to be new evidence of God’s existence. This trend of inventing new theory originated solely, according to the commission, in philosophers’ vain delusions of grandeur.5 The affair led to a ban on Bolzano’s teaching and publishing. Subpoenas were delivered to Bolzano on Christmas Day, 1819 [13–15].
Bolzano wrote a number of treatises in the field of philosophy, sociology, mathematics and logic. In his Wissenschaftslehre (Theory of Science), Bolzano defined the concept of the set (die Menge), a concept that would become central to future mathematics [16]. Bolzano’s final work was Paradoxes of Infinity (published 1851, three years after the author’s death) [17]. On the basis of theological considerations, he acknowledged actual infinity and formulated some original approaches to it.
Bolzano justified the existence of infinity roughly as follows: It is certain that there is at least one true sentence, one truth. Therefore, it is also true that there is one truth. Furthermore, it is true that there is truth concerning the existence of truth etc. An omniscient God must know all these truths; therefore, He must also know infinity. (The question remains: why doesn’t Bolzano say that God knows all the numbers? It could be proposed that He knows them all, but not necessarily. He must, however, know all truths, etc.) The argument is perplexing, especially when we consider how sceptical Bolzano had been regarding the supernatural. Perhaps he concluded that belief in God also brings about “mathematical good”?
In Bolzano’s approach, there existed many sizes of infinity: the infinity of points on a longer line is greater than that of the shorter line; the infinite number of points in a square is bigger by order than the number of points on a line, etc. He failed, however, to give complete mathematical form to his approach (the possibility of which is still uncertain). And he also did not realise the crucial role of infinity in mathematics.
Bolzano had the misfortune of working in isolation, without contact with mathematical society. Subsequently, his provocative ideas nearly fell into oblivion. It took more than a hundred years for new approaches to set theory to emerge in the middle of the twentieth century, whereby some of Bolzano’s notions found new life (or were, perhaps, reinvented).
There is no doubt that the genuine father of the set theory was the German mathematician Georg Cantor (1842–1918). His theory of sets constituted a revolution in mathematics. To this day, most mathematicians regard his set theory as the undisputed “gospel” truth, the image of objective reality.
Cantor’s criterion of equivalence of sets is one-to-one correspondence (bijection). This criterion represents the basic difference from Bolzano’s approach. (According to Bolzano, a one-to-one correspondence exists even between infinite sets of various sizes. This peculiarity represented one of Bolzano’s paradoxes of infinity.)
Cantor also assumed that there are different sizes of infinite sets but he defined their size differently than Bolzano. (Different sizes of infinity in Bolzano’s concept are equally large in Cantor’s theory.) He marked the size of infinities with the so-called cardinal numbers, cardinalities or briefly, cardinals. The cardinal number of the “smallest infinity” was marked as aleph-zero. This infinity denotes the quantity of natural numbers. According to Cantor, it also corresponds to the quantity of rational numbers. (Cantor found a one-to-one correspondence between the sets of natural and rational numbers.) On the other hand, the size of the set of real numbers is greater, the cardinality of real numbers being aleph one. Cantor proved that the one-to-one correspondence between real and natural numbers didn’t exist. Soon, Cantor discovered how to construct larger and larger infinite sets. In Cantor’s view, there were an infinite number of cardinalities. The infinities grow ever skyward to an infinite infinity–the Absolute. This greatest infinity is impossible to capture by human means; by mathematics, this infinity belongs only to God [18, 19].
The fundamentals of set theory were created in their entirety in one mind–the mind of Georg Cantor. Cantor’s original intention was, however, not so ambitious, i.e. the study of the so-called fundamental series.6 He was surprised by the world he had opened (invented or discovered?) to mathematicians–the world which David Hilbert called “Cantor’s mathematical paradise”.
To understand the important role religion played in the development of set theory, let’s stop for a moment to examine Cantor’s life course. Born in St. Petersburg, he with his parents moved in 1856 to Germany. His mother was a Catholic and his father a Lutheran. Deep religious faith was reflected in all of Cantor’s life as well as in his work. Georg was gifted not only in mathematics but also in music and art and went to study mathematics in Zurich. After his father’s death, he moved to Berlin and then to Göttingen to study. In 1867, he defended his doctorate, and at 34 years of age, he became a full professor of mathematics at the University of Halle.
However, Cantor’s life also had a downside. Shortly after his 39th birthday, his mental illness developed. He never freed himself of the manic and depressive attacks and was repeatedly hospitalized at the neurology clinic. The trigger for the first seizure was a conflict with his former teacher, Leopold Kronecker, who considered Cantor’s infinities insane and a source of many contradictions. Cantor couldn’t find understanding even from Henri Poincaré who, at first, enthusiastically accepted his theory. He turned away from Cantor’s work, however, when contradictions appeared. Regarding Cantor’s theory, Poincaré said that it represented a “lethal infection for mathematics”. Even Cantor’s close friend Mittag-Leffler discouraged him from publishing the results, stating that they wouldn’t be understood as they were too ahead of their time. Cantor surmised that his focus on mathematics was too narrow and didn’t lead to a proper valuation. He began looking for new interests that would help him overcome his deep depression. In 1899, he was again in crisis. Within a short period, his mother, brother and his talented, thirteen-year-old only son all died. Cantor reassessed his life and regretted that he hadn’t dedicated himself to music instead of mathematics. He wished to leave teaching and requested the job of librarian. He attached a curious remark to his application: he stated that he had some important findings regarding the early English kings, knowledge that would certainly shock the British Government. If his request stood without response, he would join the service of Czar Nicholas II as a native Russian. After further hospitalization in 1905, he announced that he received the inspiration from above to re-study the Bible without prejudices and with open eyes. “Enlightened from above”, he wrote down the interesting moments from the history of Christianity. His final admittance to the clinic began in May 1917. He didn’t live to be released from the clinic or to see the end of the war. His earthly journey ended on the feast of the Epiphany, 6th January, 1918.
Cantor had many opponents among mathematicians. Conversely, he found kinship among Catholic theologians. God’s mind is infinite, and therefore, it must also contain infinite sets. Actually, St. Augustine argued similarly, and, in the nineteenth century, Bolzano, Dedekind, and neo-Thomist, Constantin Gutberlet also formulated similar “proofs of infinity”.7 Cantor himself believed that the existence of infinities is warranted by God–after all, it wouldn’t be worthy of the Almighty to create only finite sets. This calls to mind the “heretical argument” of Giordano Bruno, who used nearly the same words to justify the infinity of the universe! In the case of Cantor, however, theologians also started to worry: Will Cantor’s theory perhaps lead to the identification of God with the infinite? What would be the consequences? Fortunately, it was no longer the sixteenth century and heretics didn’t end in flames. Cantor’s eloquence dispelled these doubts. Prominent theologian Johannes Baptiste Cardinal Franzelin commented that the concept of transfinite infinity–as he understood it–didn’t hold any danger for religious truths. Ironically, set theory was then recognized sooner by theologians than by mathematicians.
Paradoxically, Cantor himself couldn’t explain his success rationally. He stated that the theory of transfinite numbers was told to him by a “powerful energy”–who other than God? He claimed that he was merely a messenger chosen to proclaim that truth to humanity. How these events mirror those in the life of St. Augustine! He also couldn’t explain the reason for his sudden life turn–leaving a debauched life for an inclination to Christianity–and so also attributed it to a divine intervention! Cantor gradually sought God’s intervention in his entire life. Eventually, he began to understand his set theory as a “theory of everything”, as it concerned not only mathematics but also the world of the Divine and physics.
Cantor constantly sought a career at the prestigious University of Göttingen or Berlin. Backroom scheming by his enemies, however, obstructed his plans. Cantor fell under the impression that he was being persecuted, that someone wanted to silence him because he had revealed uncomfortable secrets. In the end, he came to the conclusion that God was the reason his career ambitions weren’t fulfilled:
Cantor died in January 1918. His arch-rival Leopold Kronecker (+1891) was also dead and so were other of Cantor’s opponents. The dispute of finitism and transfinitism was slowly fading. The onset generation of mathematicians accepted and further developed Cantor’s mathematical results.8 Together with these results, they also subconsciously accepted God hidden in Cantor’s presumptions.
Contradictions soon emerged in Cantor’s original (so-called naïve) theory, which obliged mathematicians to underpin it by systems of axioms. Problematical sets were excluded. However, it soon became apparent that the complete axiomatisation of the theory was not possible (as was demonstrated by Kurt Gödel). Even the “corrected” axiomatic theories gave rise to a number of paradoxes, that is, contradictions with an intuitive opinion, with our “unconscious philosophy”. They may be viewed positively as remarkable discoveries from the higher, “divine world of mathematics”, or negatively as a sign of the theory’s detachment from reality.
However, after some initial hesitation, the majority of mathematicians accepted Cantor’s theory. “Cantor’s paradise” represented a fragment of a much spacious paradise which had been opened by ancient Pythagoreans. To this day, most mathematicians do not hesitate to recognize the verity of Cantor’s approach, and their vision is to base the whole of mathematics on the set theory. That endeavour culminated in the works published under the name of Nicolas Bourbaki, which surfaced during the period between the thirties and the eighties of the twentieth century.
Cantor’s mathematical Platonism admits the existence of many mathematical objects for which there is no example or equivalent in the real world. Despite this, many significant mathematicians spent the most prolific years of their lives in Cantor’s paradise. The myth was so seductive that mathematicians liked to believe that the question of infinity was definitively settled. If not indeed settled, then at least it had been caught with the right end.
However, physicists were aware that Cantor’s paradise has very little or even nothing to do with the world around us, nothing in common with physics [21]. Additionally, also some mathematicians gradually started to realise the need to abandon that beautiful myth in order to create a set theory (and thus a theoretical basis for the whole of mathematics) in a simpler, more worldly, more secular fashion.
Most of Cantor’s “supernatural” concepts, however, are unusable not only in the physical world but are also problematic in terms of mathematics itself. As an illustration, we can mention the concept of the set of real numbers. According to Cantor, real numbers form a set of cardinality aleph one, and therefore, there are many more of them than natural (and rational) numbers. However, the vast majority of these real numbers are “random”—numbers that can’t be expressed by any (finite) decimal notation, or by any other mathematical means. They are the so-called incalculable numbers.9 By title alone, “an incalculable number” appears to be an oxymoron or even nonsense. Isn’t it just a “maths joke”, as declared in 1927 by Émile Borel? [22] Or is it referring to the unlimited mathematical God? Borel wasn’t alone in questioning the meaningful existence of these “incalculable numbers” and was joined by Charles Peirce and Kurt Gödel. At first, Cantor himself also hesitated. Finally, he decided to accept them and reached the uncountable, innumerable infinity. In a relatively simple way, Cantor later reached even greater infinities. All he needed to do was to create powers set, that is, sets of all subsets of the given set. This power set has a greater cardinality than the original set. In the creation of power sets, it is possible to continue without end. This is guaranteed by the so-called Cantor theorem, which is de facto an axiom-definition10 assigning existence to these sets.11 The existence ensured by this “mathematical aid”, however, is quite doubtful. It is just a proof of existence, unconstructive definition because we have to our disposal no real construction. “It’s possible to do it, but no one can do it” (perhaps God).12 This is a typical situation with many mathematical theorems, axioms, and proofs. However, is it legitimate to refer to God? What then is the reality of those infinities which create the “Tower of Babel”?13
Another flaw in Cantor’s theory was that, on its basis, it wasn’t possible to build a theory of infinitesimals.14 These infinitely small quantities already introduced in the seventeenth century by Newton and Leibniz were based solely on intuition. Mathematicians, however, failed to establish this concept exactly. So, they resorted to the definition using limits, that is, the proven potential-processual infinity. However, physicists, as well as some mathematicians, continued to use the non-exact, intuitive definition, and they successfully worked with it [23]. What does this mean for the importance of the foundations of mathematics?
Despite these reservations which remained only in the subconscious of mathematicians, the higher infinities were eventually adopted. Some mathematicians, however, didn’t accept them, and their world didn’t collapse. In a certain way, their world simplified.15 These mathematicians and physicists felt the need to get rid of a mythical Divine Implementer who (more or less manifestly) guaranteed the veracity of axioms and so also the existence of (actual) infinities. This idea was advanced by the Dutch mathematician Luzien Brouwer (1881–1966), the founder of the doctrine of mathematical intuitionism (close to constructivism) [24]. He rejected the concept of actual infinity as non-evident and non-intuitive and, by human means, non-constructible.16 With the refusal of Cantor’s approach, Brouwer also eliminated many paradoxes. For example, for Brouwer, the mathematical continuum (line) isn’t anything completed; it’s “a media of free emergence”.17 He also considered the dividing sphere as described by the paradox of Banach and Tarski as nonsense.18
However, as it happens in a revolution, a new totalitarianism often takes hold in the name of freedom. Brouwer replaced the obsolete “bent” facts with new facts, intuitionistic facts which he understood equally dogmatically. He didn’t avoid such oddities as the previously discussed concept of objectively existing random, that is, non-quantifiable numbers.19 The old myth is replaced by a new one and age-old prejudices with those new and unused. Brouwer condemned Platonism so he could quietly go back to it through the back door. However, before the return, he had swept out a lot of old junk from “Plato’s world”. Being revolutionary on the one hand and inconsistent on the other became fatal for Brouwer. The intuitionists’ approach to mathematics was so idiosyncratic that most mathematicians rejected intuitionism as a “Bolshevist menace”, as British mathematician Frank Ramsey (1903–1930) claimed. Mathematicians returned to their proven “rigid mathematical truths”, to their traditionally sanctified myths and prejudices, to their mathematical God and to the “supernatural” axioms. They also returned to their “tower of infinities”.
Brouwer also met with incomprehension in David Hilbert. In 1928, Hilbert withdrew him from the editorial board of the prestigious Mathematische Annalen. Brouwer then loudly doubted Hilbert’s mental health. Albert Einstein was also in the dispute. From the perspective of philosopher and physicist, he labelled the dispute a farce and trifling.
We have demonstrated the crucial role God played in the epistemology of higher mathematics. Mathematics was perhaps the last scientific discipline dependent on divine inspiration. In the 1970s, a prominent role in systematic attempts to strip away theological motivations was played by Czech mathematician Petr Vopěnka [25, 26, 27]. He created quite a different set theory based on different assumptions. In his approach, Alternative Set Theory, Vopěnka demonstrated that set theory could be founded in quite a different way without Cantor’s paradise, without the “Tower of Babel of infinities”, even without an omniscient God. Vopěnka’s new approach was not a manifestation of atheism, however, but only a demonstration of the fact that God (whether He exists or not) should play no role in human mathematics.20 God’s knowledge is for us inaccessible and mathematics isn’t part of theology. Cantor’s “higher” infinities are but a projection of our unabridged fantasy and divine inspiration.
Vopěnka did not ascribe reality to infinities of higher cardinals and formulated the concept of so-called general collapse, according to which it is possible to find a one-to-one correspondence between all infinities. (So, all infinite sets must be equivalent.) This step is in accordance with Bolzano’s view, but in strong contradiction with Cantor’s approach. However, the contradiction disappears when we reject ascribing reality to these incalculable, innumerable “real” numbers–to these “mathematical jokes”.
And in his Alternative set theory, Vopěnka demonstrated that parallel concepts of infinite ensembles can be constructed. And also, that exact construction of infinitesimals is possible. On these ideas, he started to formulate new foundations of mathematical analysis [28–36]. He also derived philosophical consequences of his approach.
Does Vopěnka’s approach means that the Platonic realm of mathematical forms does not exist? That this realm (Cantor’s or even the Pythagorean paradise) is only our fantasy, a non-obligatory notion? Does it mean that we can build up different mathematical realms and also different foundations of maths? Does it mean that we might accept the Aristotelean viewpoint (i.e. nominalism), in which Plato’s ideas-forms are but our common names? Or does it mean that we should accept “postmodern” approach according to which “everything goes”?
However, Vopěnka’s answer to these questions was emphatic no! He did not accept these courageous views. The reason was perhaps psychological. While young, he flirted with phenomenological philosophy and empiricism. When mature, he abandoned such ideas and returned to the “certainties of Platonism” or, more precisely, to certainties of “his own mathematical Platonism”. He relied on the existence of “a single eternal mathematical realm”, albeit no longer with the enticing recesses of that “ornamental neo-Baroque superstructure”–Cantor’s paradise of sets. Shortly before Vopěnka left this world, he even stopped considering his Alternative Theory (with a capital “A”) to being an alternative (with a lower case “a”) and regarded it as the only possible one. He completely rejected classical Cantorian set theory and renamed his own the “New set theory” because “there exists no alternative”. He replaced the old “religion of mathematics” with a new one, which was less divine and less metaphysical, but again, the only true one.
Vopěnka’s intellectual development reminds us of Nicolas Copernicus. Copernicus moved the centre of the universe from the Earth to the Sun and by this step (perhaps unconsciously) raised the question as to whether there actually is any centre at all. However, Copernicus himself was afraid of this overly revolutionary idea and he did not leave the bounded, final universe closed to the sphere of fixed stars. Vopěnka later cancelled Cantor’s theory as the sole basis of mathematics. By this step, he evoked the idea of whether mathematics should have a single, metaphysical (metamathematical) basis or whether it can be established with various alternative (better said, parallel) ways. Even the name of his theory directly points to alternativity. However, like Copernicus, Vopěnka also backed and marked his own theory as the only acceptable and therefore renamed it “The New” because “there is no alternative”, as Vopěnka proclaimed [37].
What about other mathematicians? We must admit that the impact of Vopěnka’s ideas was very limited.21 Tradition is firmly rooted in our collective unconsciousness and tends to be stronger than reason. Thanks to tradition, the old mathematical “religion” still survives, and the new approaches have only a negligible impact. Time will tell for how long.
Within the framework of mathematics, physics and what we call “reality”, the nature of infinity is non-apparent and metaphysical, much like the nature of God. It is left to us to admit its existence or not. And the one we choose, the one we create is the one we are stuck with. Our choice cannot be entirely arbitrary, of course. It depends on the overall concept of mathematics, and possibly also on that of physics. So, it depends on the philosophy of mathematics and physics, that is, metaphysics. The choice of a metaphysical system is dependent not only on our rational considerations but also on our subconscious beliefs, on our faith, on our “religion” (or religion without quotation marks). However, it should first and foremost take into consideration its utility in real mathematics and physics, that is, how it can be used in practice. Infinity is primarily our tool to understand the world which is finite. This does not imply short-sighted pragmatism, of course. The usefulness of our tools might only be apparent after some period of time, and there is no way to determine it in advance. Reliance on intuition is the only possibility.
Let us recall the hesitant approach of young Bolzano towards religion. Under the influence of the Enlightenment and rationalism, he doubted the supernatural origin and content of the Biblical message as likely a myth, a fallacy. It seemed that Bolzano doubted the very basis of faith. However, he overcame his doubts and eventually became a preacher of that faith. He realised that the supposed divine origin isn’t what was the most important. More fundamental is the good that religion brings to mankind. What seems to be the real foundation is only a formal basis, while the true foundation lies elsewhere. Therefore, “not true but useful” or even “truth = usefulness”. This exact sentiment is echoed in the philosophy of pragmatism.
Imagine: If it is proved that no miracles happened and that everything is just a myth, then the church wouldn’t collapse.22 However, if religion has nothing to say to people, it cannot dispense the “good”, the cathedrals will become dead monuments over time and the church itself will die. The strength and weakness of faith lie in the practice of human life. A practice which elevates people, which is beneficial to them, which leads them to good and successful ends, such practice is also the right foundation and the right argument for faith and religion.
Similarly, I believe that it is advisable to use the Bolzano pragmatic way to approach science, including mathematics. The formal “ontological under-building” of mathematics–the set theory–is a monumental work on which mathematicians practiced their art. Yet it is only a formal basis. What is important is what mathematics brings to mankind and what it could bring even if it were built on a different basis. If mathematicians discovered (or rather accepted) that the set theory is just a myth or fallacy and that there are no infinities, the mathematics wouldn’t collapse. If, however, mathematics couldn’t be used in the earthly world, if it weren’t beneficial for practice (therefore not providing “Bolzano’s good”), it would become a purposeless game, such as chess, checkers and go. The strength of mathematics lies in the practice of life and it is this practice–that is real, applied mathematics–that is the most real justification and foundation for the entire of mathematics.
The above-mentioned conclusions can be illustrated by two examples. First, we can examine the pragmatic approach of Abraham Robinson, the founder of non-standard analysis. In 1964, he concluded that actual infinity doesn’t exist–neither in a real nor in an ideal sense. However, Robinson reassures us: the absence of actual infinity means nothing for practice and for mathematics! We are supposed to ignore this fact and pretend that nothing is happening! [40]
The second example brings us back to Petr Vopěnka. He approached the expected absence of actual infinity (represented by infinite sets) quite differently. He deemed it necessary to redo all the foundations of mathematics. And he undertook this ambitious task himself. The effect, however, wasn’t as significant as he probably expected. Those new foundations did not provide much that couldn’t be obtained from the disputed traditional foundations.
What do these cases demonstrate regarding the importance of the foundations of mathematics? What does that say about the conception of infinity?
Throughout history, we are aware of many examples wherein theology hampered the development of philosophy and science. This applies especially to the fundamentalistically understood religions which were doing a disservice to astronomy and to all natural science, in fact. As we have seen, the situation was different in mathematics. Monotheistic religion served with an inspiring vision of an all-knowing God who was transformed into “the god of mathematicians”.
Mathematicians relied on God; He was the guarantor of the metaphysical world of mathematics. Throughout the advent of modern times, mathematicians slowly began to realise that mathematics isn’t a part of or an extension of theology. They gradually left the theological “proofs of infinity”; more specifically, they stopped talking about God. However, God survived in the depths of their collective unconsciousness. Most mathematicians never got rid of this hidden God or “supernatural concepts”–axioms guaranteeing the existence of large, highly “unnatural” infinities, the continuum hypotheses, the axiom of choice, etc. By declaring these “holy truths” through their mouths, they only provided God with a disguise.
In the mid-twentieth century, some mathematicians (or rather philosophers of mathematics) timidly began to realise the limitation of this Theo-Platonic approach. They emboldened themselves and tried to formulate the “God-free” foundations of mathematics. Nevertheless, on a deeper philosophical layer, Platonism still was hidden there (Brouwer, Vopěnka…). One “mathematical religion” was exchanged for another. One that was less theological and less metaphysical, perhaps “more scientific”, but again it was the only real and true. Despite this effort towards new foundations of mathematics, the practical effect was negligible. Mathematicians are conservative people; like most of us, they don’t like to abandon their prejudices. However, there is a more rational argument: their mathematics “works”. However, this is not an argument against different foundations of mathematic, because “working mathematics” can also be based completely differently. The reason is that the factual foundation of mathematics is the real mathematics, that is, applied maths.
But, were the substantial effort of Georg Cantor and other mathematicians all for naught? Was it all leading to a dead end? I am not of this view. Even if Cantor’s paradise vanished for good, even if it became a mere myth or simply a beautiful dream, the metaphysical excursions of nineteenth and twentieth century mathematics would not have been in vain. Neither would the pilgrimage to “God’s mind”, and to “divine infinities”. This journey provided a great deal of experience and inspiring insights. Mathematics returns from these voyages changed, much richer, more experienced and much stronger.
Although I accept the practice as the ultimate criterion, I am aware that the first-pragmatism isn’t sufficient for the foundation of science. Neither mathematics nor science can do without a metaphysical overlap, without “myth” or “religion”. We as people can’t do without it either. Only metaphysics, the “irradiation of a spiritual light”, provides an understanding of things and incorporate them to science and to our life. Only metaphysics creates sense and provides a story.
One of the major environmental problems facing industrialized nations in recent times is hydrocarbon contamination resulting from oil and gas exploration and exploitation activities. As the demand for liquid petroleum increases, the release of this essential energy source into the environment becomes inevitable and has caused devastating consequences to marine/coastal waters, shorelines and land as well. Human activities such as accidental release of petroleum products, uncontrolled landfills, sabotage, leaking of underground storage or improper storage of crude oil are of particular concern in the environment. Hydrocarbon components have been known to belong to the family of carcinogens and neurotoxic organic pollutants which constitutes a major health challenge globally. Oil spill on land, penetrates to a depth of about 10–30 cm and sometimes beyond, results in the loss of soil fertility and also initiates environmental degradation [1]. This consequently alters the physicochemical properties of the soil making it impossible for the soil to produce at its optimal capacity.
The application of biotechnology today as a tool for environmental clean-up has been widely studied. Biotechnological tools in eco-restoration of crude oil impacted sites involves the use of biological agents to decontaminate/detoxify, mineralize, transform or degrade toxic/harmful substances into innocuous forms. The process known as bioremediation is genetically-driven, whereby microbes with inherent enzymes harboring catabolic genes utilize these xenobiotics as a source of carbon and energy thereby decontaminating the environment. The biological agents in bioremediation; microbes (microbial bioremediation), plants (phytoremediation) or plant-microbe interaction and their mode of operation will be extensively discussed in this chapter. Nigeria and some other nations in Africa have experienced devastating consequences of pollution in all environmental compartments which till date is still a major challenge [2].
With the advances of biotechnology, bioremediation has become one of the most rapidly developing fields of environmental restoration, utilizing microorganisms to reduce the concentration and toxicity of various chemical pollutants, such as petroleum hydrocarbons, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, phthalate esters, nitroaromatic compounds, industrial solvents and the very recalcitrant substances [3]. This has been made possible through a very important, emerging and next generation approach, called genetic engineering which involves the modification of the genetic structure of an organism to increase/enhance their activity. This approach is one potential key to a very successful, and swift bioremediation, whereby the catabolic potentials of an organism is enhanced by the introduction of hydrocarbon catabolic genes into the microbe. This paper highlights the various biotechnological tools that can be practically adopted especially in Nigeria and Africa at large to encourage environmental sustainability and eco-restoration of crude oil polluted environments.
The intensification and rapid increase of manufacturing industries and the intensive use of fuels has led to an increased release of a wide range of xenobiotic compounds to the environment. Overtime, continuous loading of excess hazardous waste and xenobiotic compounds into the water bodies and soil has led to the destruction of soil structure, component and biodiversity, scarcity of clean water thereby limiting crop production [4, 5]. One of the major types of pollution that have caused so much harm/damage to the ecosystem generally is crude oil pollution. Crude oil contains so many toxic compounds such as hydrocarbons which can be easily converted to activated metabolites or free radicals during their oxidation [6]. The high toxicity of crude oil is usually attributed to its low molecular weight hydrophobic petroleum hydrocarbons. Other larger constituents of crude oil include alkyl PAHs with three or more rings which are less soluble in water [7]. In the past, several incidents have occurred which caused devastating damage to the ecosystem and have revealed the importance of preventing the escape of effluents into the environment, one of such incidents is the Exxon Valdez oil spill [8]. The Exxon valdez, a cargo ship carrying crude oil was grounded on the 24th march, 1989 along the Bligh Reef in Alaska, northeastern Prince William Sound. This resulted in the release of about 20% of the entire cargo (about 36,000 metric tons) [9]. Another significant oil spill that occurred in the Gulf of Mexico in 2010 is the BP Deepwater Horizon spill. Approximately 4 million barrels of crude oil spilled from the Macondo Wellhead (MW) making it the largest accidental marine oil spill in history. The biological impacts of the oil spill were severe, including in the deep sea, a habitat typically characterized by high biodiversity and generally economic and ecological impact [10].
In Nigeria, crude oil and gas production contributes to 25% of the nation’s gross domestic product (GDP) and about 90% of the foreign exchange. The exploration and production of crude oil has caused devasting impact to all environmental compartments within the country, especially in the Niger Delta Region [11, 12]. A constant reoccurring phenomenon is the leaks from oil tankers and petrol leakage into the soil and these slicks formed contribute to reduction of dissolved oxygen and co-marine environment which causes oil slick. Polycyclic aromatic hydrocarbons (PAHs) which are one of the major components of crude oil have been found in water ways as a result of pollution caused by the effluents from petrochemical industries. Some of the major activities that cause petroleum hydrocarbon pollution of the environment are oil well drilling production operations, refining, storage, transportation, marketing in the upstream and downstream industry, anthropogenic sources [13]. Some of the causes of oil pollution may also occur in form of spillages due to corrosion of pipelines, oil well blowout, vandalization of pipelines or accidental discharges.
Crude oil pollution has been reported to cause devastating environmental consequences. Its effects range from the destruction of the soil structure and biodiversity, to limitations in plant growths which may further affect the farmer’s source of income, and health hazards in man. It has also been reported that plants that grow in oil polluted soils show signs of chlorosis on their leaves and are also retarded due to the water deficiency. These have led to a complete halt in some farming activities like fishing or even death in some cases when contaminated water or food crop is consumed [14, 15].
There are countless literatures on the study of the causes and effects of petroleum hydrocarbon contamination on human health, soil, plant growth and the environment in general [16, 17, 18]. Ojimba [19] conducted a research to determine the effects of crude oil pollution on crop production. He analyzed data from 17 out of the 23 Local governments in Rivers state, Nigeria. His results showed there has been a significant reduction in the size of available farmlands due to crude oil pollution, this further reduced the physical farm products by 1.09016 tons. His results also indicated that 78% of farm lands had less than 80% efficiency due to crude oil contamination. The study concluded that crude oil pollution on farmlands and crops has negative effects on the output of crops. Abii and Nwosu [20] reported that Crude oil pollution causes reduction in the fertility of the soil such that the major essential nutrients necessary for the plants to grow are almost completely lost. Other effects of crude oil pollution on plants may range necrosis, chlorosis, yield reduction, bleaching, spotting of leaves, malformations to mesophyll cells and epidermal layers [21].
Al-Qahtani [16] investigated the effects of sludge from oil refineries on soil properties and the rate of plant growth. He carried out the experiment by applying the refinery sludge in a plant
Sun et al. [18] conducted an experiment to study ability of the eggs and larvae of a marine medaka (
Obire and Anyanwu. [24] also conducted an experiment to investigate the Fungal population at different concentrations of crude oil pollution in a soil sample. Their analysis showed high significant difference between the control and the oil treated soils, the total fungal counts of petroleum-utilizing fungi were relatively higher. Some of the fungi species isolated from the soil were
Biotechnology is defined as the set of scientific techniques that makes use of biological systems or living organisms to make, modify or improve products which may be products mays be plants or animals [25]. It has also been defined as a process which involves developing organisms for specific purposes and it includes the use cell fusion, recombinant DNA and other novel bioprocess technologies [26]. Biotechnological tools in eco-recovery of crude oil polluted sites are those biotechnological processes that involves the use of bio-products and also microbes for production of environmentally friendly products, reduces pollution and its effect, and all general restoration and maintenance of the environment to its pristine (natural) state for the benefit of man and the environment [2]. Biotechnological tools in eco recovery are also concerned with prevention of processes capable of causing an unsustainable environment for man and eco-components. There are no known number of bio tools used in prevention or restoration of a polluted environment, however the most successfully applied, eco-friendly and cost effective tool in environmental decontamination is bioremediation. The different types of bioremediation (biosurfactant-enhanced bioremediation, microbial bioremediation, plant bioremediation, genetically modified microorganisms in bioremediation), mechanism of action and factors influencing the process will be discussed in this chapter.
Before now, remediation of contaminated/polluted environments have been carried out using conventional methods such as to cap and contain the contaminated areas of a site or digging up contaminated site and removing it to a landfill. These methods have however had some drawbacks. The first method is however just a temporary solution as the contaminants may still linger on the site and may further require monitoring and maintenance in the future, this leads to increased cost. In the landfill method, the contaminated soil is excavated moved to a different site and the excavation and transporting of the contaminants may pose a serious environmental risk, it might also prove expensive to find new sites for the disposal of the contaminated soil [27]). These drawbacks have led to the search for a better approach which would include transforming the pollutants to a harmless substance or a complete destruction of the pollutants if possible [28].
The use of biotechnology which entails the application of genetic modifications to improve the ratio of work done and reduce cost associated with remediation and eco restoration process have become a major factor for the increased exploitation of biological systems in waste reduction and eco restoration. Due to the urgency in the need for an effective and efficient biotechnological process and the need for a process that completely destroys the pollutants, researchers have come up with a technique for rehabilitating either contaminated sites or sites that have been degraded due to anthropogenic activities and the mismanagement of the eco system. This process is called bioremediation and it involves the application of living microorganisms to degrade environmental pollutants or to prevent pollution. The different strategies/tools used in bioremediation of oil spills include bio-stimulation, bio-augmentation, use of genetically engineered microbes, nutrient application, seeding with competent or adapted hydrocarbonoclastic bacteria or their consortium. Some of these Environmental biotechnological tools for the clean-up of crude oil contaminated sites are highlighted here.
Bioremediation has been defined as the process of removing toxic waste from the environment using biological agents. According to Kumar et al. [27] It was defined as the most effective tool to manage waste polluted environment and recovery of contaminated soil. Bioremediation have been carried out both in situ and ex situ in several sites around the world with very successful outcomes. This method is considered a non-invasive, cost effective and sometimes logistically favorable clean-up technology which attempts to accelerate the naturally occurring biodegradation of contaminants through the optimization of the prevailing conditions [29, 30]. Bioremediation alongside natural attenuation have provided solution for emerging contaminant problems using actions such as biological carbon sequestration, landfill stabilization, endocrine disrupters and mixed waste biotreatment. Plants and microorganisms play roles in the remediation of contaminated environment; thus, the purpose of bioremediation is to reduce the potential toxicity of chemical contaminants in the environment via degradation, transformation, and immobilization of the undesirable compounds through the introduction of biosystems such as higher organisms like plants (phytoremediation), microbes, and animals. Some of the microbes involved in bioremediation process may include aerobes, anaerobic bacteria, fungi and other microbes with degradative potentials. Several microorganisms including
Several bioremediation strategies have been explored for treating different sites but most have been designed for land oil spill control. These strategies attempts to increase the efficiency of natural attenuation process and they include: landfarming, composting, use of bioreactors, bioventing/biosparging, pump and treat, bioslurping, biostimulation, and bioaugmentation [36]. A description of the in-situ and ex-situ bioremediation techniques is presented in Table 1.
Technique/definition | Potential success | Limitations | Applicability | Reference |
---|---|---|---|---|
Landfarming: this involves periodic mixing of the hydrocarbon polluted soil for aerobic microbial degradation to occur | This process has been useful in degrading a number of hydrocarbon compounds. Suitable for treating large volumes of contaminated soil | Large amount of land is required Unsuccessful in degrading high molar mass PAHs It is a very slow .biodegradation process | Volatile organic compounds and light weight PAHs. It can be applied in-situ and ex-situ. | [37] |
Bioventing/Biosparging: it is designed for the decontamination of hydrocarbons at the saturated and unsaturated zones with the supply of nutrients (if required) and oxygen. | Little disturbance to site operations, treatment time from 6 months to 2 years. Hydrocarbons can be degraded in both saturated and non-saturated zones | Too slow in degrading heavy fractions of PAHs. Can only be used where bio- sparging/bioventing is suitable. Absence of other natural processes involved in degradation | Saturated and unsaturated zone. Mid-weight and low weight petroleum hydrocarbons. In-situ bioremediation system. | [36, 38] |
Composting: It utilizes biological agents in organic amendments to aerobically degrade spilled pollutants. | High oleophilic microbial population derived from the organic amendment and elevated temperature optimal for degradation of the pollutant. Produces an end product of mature compost suitable for agricultural purposes. Suitable for treating large volumes of soil. | Longer treatment time compared to other ex-situ techniques. | Stimulates hydrocarbon degradation and enhances availability of hydrocarbon pollutant. | [39] |
Use of bioreactor: it comprises a bioreactor system that controls the environmental /nutritional factors that influence biodegradation. | Rapid degradation kinetics. Optimized environmental parameters. Enhances mass transfer. Effective use of biostimulants. | Excavation of polluted soils or pumping of contaminated groundwater to the treatment site that is cost-ineffective. Production of toxic sludge as a by-product of the bioreactor. Increased operational cost. | Containment of volatile organic compounds (VOCs) or polluted air emissions. Highly efficient in diesel and PAH degradation. | [40, 41] |
Pump and treat: this system is specially designed to treat groundwater pollution by pumping the polluted water to this for treatment before re-injection | Encourages biodegradation of contaminants in the unsaturated zone. Effective groundwater clean-up technique. Cost intensive. | Location of the groundwater contaminant plume, designing a capture mechanism and installing extraction and injection wells | [42] |
The most applicable in-situ and ex-situ bioremediation techniques for hydrocarbon removal.
Many microorganisms involved in bioremediation produce potent surface-active compounds that can emulsify oil in water called biosurfactants and unlike chemical surfactants, the microbial emulsifier is biodegradable and non-toxic thereby facilitating the removal of hydrocarbon pollutants especially in the marine environment [43]. Biosurfactants can improve hydrocarbon bioremediation by two methods; the first incorporates the increment of substrate bioavailability for microorganisms, while the other method includes interaction with the cell surface which builds up the hydrophobicity of the surface allowing hydrophobic substrates to relate more effectively with bacterial cells [44]. By bringing down surface and interfacial tension, biosurfactants causes an increment to the surface areas of insoluble compounds prompting expanded portability and bioavailability of hydrocarbons. In outcome, biosurfactants upgrade biodegradation and removal of hydrocarbons. Biosurfactants are known to increase biodegaradation of highly hydrophobic compounds such as aromatics, alkanes, resins, cycloalkanes [45] by increasing bioavailability of the hydrophobic compound through facilitated transport of the pollutants from the solid phase (such as communication between surfactants and hydrocarbons, communication between contaminants and single biosurfactant molecules), improvement on the apparent solubility of the contaminants (improve the apparent solubility of the hydrophobic organic compound), and emulsification of non-aqueous phase liquid contaminants (in this process biosurfactants can lower the surface tension between non-aqueous and aqueous phases, this then leads to an increase in improving mass transport, the contact area, and mobilization liquid-phase contaminants).
Biosurfactants may be secreted outside the cells (extra-cellular) or located inside the cells (intracellular) [46] Based on myriads of documented reports available on bacterial bio-surfactants, it has been established that the spectrum of activity depends on the chemical composition of the pollutant. A strain of
Bacteria produce biosurfactants in the form of biofilm which interacts with an interface and alters the surface properties such as wettability and other properties. Biosurfactant producing bacteria have been to be isolated from different environmental compartments including the marine environment. A marine bacterium,
Microbial-assisted bioremediation explores the potentials of naturally occurring hydrocarbon degrading microbes (oleophilic microbes) or plants in the detoxification/degradation/mineralization of hazardous substances to human health and the environment. These microbes can either be native to the contaminated area or could be introduced from a similar site into the contaminated soil, a process called bioaugmentation [54]. Bioremediation occurs most frequently by the action of microbial-mediated degradation. This process is often achieved by the action of consortia of organisms and for bioremediation to be effective, there must be complete mineralization of the hydrocarbon which occurs through a series of enzymes harboring catabolic genes to produce harmless products such as CO2 and H2O [55].
Biodegradation of petroleum hydrocarbons is a complex process that depends on the nature and on the amount of the hydrocarbon present. Petroleum hydrocarbons are divided into four broad categories: Saturates (branched, unbranched and cyclic alkanes), aromatics-ringed hydrocarbon molecules such as monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs), resins (Polar oil-surface structures dissolved in saturates and aromatics) and asphaltenes (dark-brown amorphous solids colloidally dispersed in saturates and aromatics). These various categories respond differently to biodegradation as a result of their chemical structures and molecular weight. For example, PAHs, asphaltenes and resins are considered highly recalcitrant because of their high molecular weight [56].
Microbial degradation is a major route and ultimate natural mechanism by which one can clean up petroleum hydrocarbon pollutants from soil environment [57]. Typically, an individual microorganism will biodegrade a limited number of hydrocarbons whereas a microbial consortium can biodegrade an impressive array of hydrocarbons collectively [58, 59]. Onuoha et al. [60] reported that Nigerian soil especially in the Niger Delta region, may harbor a significant population of hydrocarbon degraders as a result of the increased multifarious activities of the oil industry within the region. The result of the investigation revealed that an appreciable number of bacterial isolates showed different degrees of degradation in mineral salt medium using spent oil as sole source of carbon. In a similar study, Chikere and Ekwuabu [61] conducted an investigation in Bodo community, Ogoniland, Nigeria to characterize the active culturable indigenous hydrocarbon utilizing microbial population. A significant population of hydrocarbon utilizing bacteria and fungi corresponding to the long-term impact of crude oil in the study area was observed. The hydrocarbon degrading microbes have an inherent genetic capacity to assimilate hydrocarbons and/or its products [62]. The process is therefore regarded as a complex biological oxidation process involving mostly aerobic organisms which may be enhanced by supplementation with fixed nitrogen, phosphate and other rate-limiting nutrients. Microorganisms have enzyme systems that can degrade and utilize different hydrocarbons as source of carbon and energy [63, 64]. The driving force for petroleum biodegradation is the ability of microbes to utilize hydrocarbons, to satisfy cell growth and energy.
Biodegradation may occur spontaneously and the process is called natural attenuation. In most cases however, this might take a longer time and this could be as a result of inability of the natural circumstances of the contaminated site to favor the natural attenuation process [65]. Also, it may be due to inadequate number or diversity of microorganisms with specific enzyme system required to break down the contaminant and lack of favorable environmental conditions to support the process. Such situations can be improved by supplying one or more of the missing/inadequate microbes, developing oil eating bugs through genetic engineering/recombination, introducing rate-limiting nutrients or enhancing environmental factors to favor the active degraders. It was reported that extra nutrients were added to accelerate the breakdown of oil spill caused by the super tanker Exxon Valdez on the Alaskan shoreline [66]. Since numerous types of pollutants are to be encountered in a contaminated site, diverse species of microorganisms are likely to be required for effective mediation [67].
Microbial bioremediation strictly involves the use of microbes or their derivates (Enzymes, biomass) to degrade or transform xenobiotics for the detoxification of crude oil polluted environments. Microorganisms are ubiquitous, therefore pollutants in the different environments come in contact with these oleophilic microbes. Specifically, the hydrocarbon degrading microorganisms (bacteria, fungi, algae) are able to breakdown these pollutants because of their inherent genetic capabilities to mineralize these hydrocarbons through metabolic pathways. Microbial bioremediation technology in the long run promotes the growth of specific microflora or the microbial consortia, indigenous to the contaminated sites that are able to perform the desired activities. In the process, microorganisms use the contaminants as source of energy or nutrient. The microbial consortia can perform this role optimally by either adding terminal electron acceptor or promoting microbial growth by adding nutrients [27]. In oil contaminated sites as it relates to this review, oil spills can be broken down using multiple techniques which includes the microbes feeding on the crude oil or addition of fertilizers/nutrients to the contaminated site to accelerate the decomposition of crude oil by the microorganism present in the soil or by introducing hydrocarbon degrading bacteria from exogenous sources to augment the indigenous population. As regards to crude oil contaminated environment, bioremediation process exploits the catabolic ability of microorganism to feed on oil. Research frontiers globally have described various application of microorganisms in the bioremediation of oil pollution under controlled conditions, field scale and in different environmental conditions, with very encouraging results [13, 15, 55]. The natural existence of a large diversity of microbial species expands the variety of chemical pollutants that are degraded or detoxified [68].
So many microorganisms have been reported with hydrocarbon remediation potentials which are
Microbial bioremediation technique has some advantages over other clean-up methods such as: public acceptance, a naturally occurring process, low cost technology, it can be done in situ and ex situ, instead of contaminants being transferred from one form to another or one medium to another, complete destruction of target organic pollutants is possible to produce non-toxic substance and it can lead to eco-restoration of the polluted medium [40, 68]. Some oleophilic microbes and their hydrocarbon specificity are presented in Table 2.
There are a few factors that contribute to the success of microbial bioremediation, some of these factors may include the growth and survival of microbial populations, the ability of these organisms to come into contact with the substances that need to be degraded into less toxic compounds, cation exchange capacity, relevant nutrient availability, acidity (soil pH), aeration or oxygen (electron acceptor level), water solubility, temperature, enzyme activity, hydraulic properties, [31] water content, site condition, microbial communities, sufficiency of the numbers of microorganisms and the habitability of the microbial environment for the microbes to thrive [89]. Sometimes the environment might be too toxic for the microorganisms to survive, in this case, the microbes should be engineered to be able to survive the high toxicity. Also, bioremediation works best in soils that are relatively sandy because sandy soils allow mobility and greater likelihood of contact between the microbes and the contaminant [90]. Therefore, for any bioremediation process to be successful, the environmental factors that play major roles in the process must first be understood.
The process of bioremediation may not always result in the complete mineralization of organic compounds, some of the organic compounds are transformed naturally to other metabolites and the toxicity and persistence of these new metabolites are mostly unknown [91]. Compliance analysis requires examination of the contaminated site in the light of the governing regulation and the action plan. For a successful bioremediation, the site must first be examined and characterized and this is a very challenging and difficult aspect of a bioremediation efforts. Some factors that influence microbial degradation of hydrocarbons in the environment is present are presented in Table 3.
Oleophilic micro-organisms | Type of microorganism | Hydrocarbon-specificity | Habitat | Reference |
---|---|---|---|---|
Bacterium | Bezene, toluene, ethylbenzene, xylene, naphthalene, phenanthrene, kerosene and diesel | Soil, river and marine | [73, 74] | |
Bacterium | Alkanes | Soil, river and marine | [75] | |
Bacterium | Anthracene, benzene, tolune, ethylbenzene, xylene and Benzo (a) pyrene | Soil, river and marine | [76] | |
Bacterium | Benzo (a) pyrene and pyrene | Soil | [77] | |
Bacterium | Benzene, toluene, ethylbenzene and xylene | Soil, river and marine | [78] | |
Bacterium | Phenanthrene and pyrene | Soil, river and marine | [79] | |
Bacterium | Most PAH (not specific) | Soil | [80] | |
Bacterium | Toluene and diesel | Soil | [74] | |
Bacterium | Phenanthrene and pyrene | Marine | [79] | |
Bacterium | Most PAH (not specific) | Soil | [80] | |
Bacterium | Xylene and diesel | Soil | [74] | |
Bacterium | Anaerobic breakdown of benzene | Groundwater, deep soil and oceans sediments | [81] | |
Bacterium | Light Arabian oil | Soil | [82] | |
Bacterium | PAH (not specific) | soil | [83] | |
Bacterium | Alkanes (not specific) | soil river and marine | [84] | |
Bacterium | Low molecular weight PAH | Soil/sludge | [85] | |
Bacterium | Low molecular weight PAH | Soil/sludge | [85] | |
Bacterium | Low molecular weight PAH | Soil/sludge | [85] | |
Bacterium | A wide spectrum of petroleum hydrocarbon | Soil | [65] | |
Bacterium | PAH (not specific) | Soil | [86] | |
Fungus | PAH (not specific) | Soil | [87] | |
Fungus | PAHs (not specific) | Soil | [88] |
Oleophilic microorganism and hydrocarbon specificity.
Physical factors | Optimal conditions |
---|---|
Temperature | Affects the chemistry of the pollutants as well as physiology and diversity of pollutants. Optimal at 30-40°C in soil |
Nutrient | Stimulates the growth of indigenous oleophilic microbes in the environment. C:N:P ratio – 100:10:1 |
pH | Soil pH affects availability of nutrients and it’s important in the survival of microbes within a certain pH range. Optimal at pH 7 Acceptable range: 6–8 |
Moisture | Soil microorganisms require moisture for cell growth and function. Optimal moisture content for petroleum hydrocarbon degradation ranges between 45 and 85% of the water holding capacity. |
Oxygen | Major degradation pathways for petroleum hydrocarbons involves oxygenates and molecular oxygen since most degradation process is aerobic |
Factors that influence microbial degradation of petroleum hydrocarbon in the environment.
This is one of the biotechnological approach/tools in which plants are used in the clean-up of contaminated environments. It is an emerging technology and it promises a cost friendly, less-intrusive and effective clean up and restoration of crude oil contaminated soils [65]. It can also simply be defined as a process of using plants and plant-associated microorganisms such as Arburscular Mycorrhizal fungi (AMF) or plant growth promoting rhizobacteria (PGPR) to clean up contaminated soils. It is an inexpensive, non-invasive alternative for other remediation methods such as the chemical/engineering-based methods [31]. Green plants are solar-driven, and are an effective filtering system endowed with fouling and degradative abilities [92]. It has been reported that salt marsh plants such as
In an experiment by Olusola and Anslem. [96] A plant (
Plants and plant-associated microorganisms are both involved in phytoremediation process. The plants used must first be tolerant to the pollutants, encourage the growth of rhizospheric microorganisms and in turn these microorganisms can secrete oil degrading enzymes and thereby generate energy in a process called rhizodegradation. However, there is a major setback with this process in that plants tend to compete with the hydrocarbon degrading microorganisms for the available nutrients like fixed nitrogen and phosphorus.
Phytoremediation offers potential for restoring large areas of contaminated environments requires certain mechanisms for a successful remediation process. Plants are able to remove pollutants through processes such as biodegradation, phytovolatilization, accumulation, and metabolic transformation. Several factors determine the most effective phytoremediation mechanism to adopt, such as the bioavailability of the contaminant, type of contaminant, soil properties and other environmental factors that support plant growth and activities. There are several routes through which plants decontaminate polluted sites, however, the primary channel for plant uptake of contaminants is through the root systems (rhizosphere) which harbors the essential components required for decontaminating toxic substances. The rhizosphere of plants has a large surface area responsible for the absorption and accumulation of essential nutrients and water required for growth. A large diversity of microorganisms are usually found in this region because of the exudates and enzymes released which stimulates the activities of microorganisms capable of degrading hydrocarbons present in the soil, direct biochemical transformation of petroleum hydrocarbons, and have also shown resistance to crude oil toxicity [97]. Rhizospheric interactions between host plants and the microorganisms that are resident in the rhizosphere are critical to the phytoremediation process. Host plants enrich the rhizosphere by releasing root exudates that help in recruiting the beneficial pollutant degrading bacteria and other microorganisms to the rhizosphere. In a report, a plant growth promoting rhizobacteria
There are several other phytoremediation mechanisms which include; phytoextraction, phytostabilization, phytofiltration, phytodegradation, phytovolatilization rhizodegradation and phytostimulation (Figure 1).
Mechanism of phytoremediation of crude oil.
Generally speaking, microbial degradation of xenobiotics involves the utilization of microbes with specific enzyme systems responsible for the degradation, mineralization, transformation or detoxification of pollutants [100]. Nevertheless, under certain growth conditions, composition, type and concentration of the pollutant, effective degradation is not expected even with the availability of microbes with degradation potentials. Compounds like Polychlorinated biphenyls (PCBs), synthetic group of chlorinated aromatic hydrocarbons and other Organic compounds, due to their complex organic structure, is posing persistent and deleterious threats to the ecology and human health even for decades [101, 102, 103, 104, 105, 106, 107]. Therefore, it has become imperative to design and develop alternative hydrocarbon degradation arrangement with specific degradation genes to the available pollutants in the environment by cultivating microbes with engineered catalytic capabilities [108].
Genetically Engineered Microorganisms (GEMs) can be obtained by recombinant DNA technology/genetic engineering of microbes or by natural exchange of genes by bacteria in the environment through horizontal gene transfer of plasmid-borne genes. The application of GEMs in bioremediation of xenobiotics have shown great potentials in soil [103], groundwater [102] and other environmental components exhibiting improved mineralization abilities over a broad-range of contaminants.
The use of GEMs represent a research frontier with wide application which extends to phytoremediation. Jain and Bajpai [108] reported a number of applications available in enhancing the degradative performance of oleophilic microbes using genetic engineering approaches. A very significant example is the genetic modification of rate-limiting steps in the metabolic pathway of hydrocarbon degrading microbes to yield increase in mineralization rates or the development of completely new metabolic pathways incorporated into the bacterial strains for the degradation of highly persistent compounds.
The first GEM,
Additionally, since oil is a mixture of various hydrocarbons (n-alkanes, aromatic hydrocarbons, polycyclic aromatic hydrocarbons), the construction of engineered bacteria capable of degrading various petroleum hydrocarbons by genetic engineering technology is a development direction to control crude oil pollution. The degradation of some petroleum components by microorganisms is controlled by an extrachromosomal plasmid; therefore, superbugs (product of genetic engineering: oil eating bug) can be constructed by introducing plasmids with capabilities for degrading different components in a single cell.
A recombinant
Genetically modified microorganisms such as bacteria including
Microbe-assisted contaminant reduction and in-depth analysis of the organisms’ metabolisms have over time accelerated the overall bioremediation process. However, in the next decade, molecular manipulations and the decryption of the cellular mechanisms using an integrated OMIC tool approach will play major roles in bioremediation processes [115].
Recently, a key area of modern-day scientific advancement in the removal of pollutants from the environment (either in soil or groundwater) is the nanoparticles empowered remediation. Green nanoremediation as a nature-based technology offers numerous promises for the cleanup and restoration of polluted soils such as crude oil polluted soils with reference to the efficiency of the process, energy consumed and the global need for eco-friendly processes [116]. Wang et al. [117] reported the use of silica nanoparticles capped with lipid bilayers of
Some of the all-round benefits of the use of green nanotechnology as a biotechnological tool for remediation of crude oil polluted sites may include the rapid removal of pollutants, reduced usage of hazardous substances and the cost effectiveness. Nanobioremediation might contribute immensely to the sustainability of the environment because of these benefits when compared to other methods of remediation. The copulation of biological entities with nanomaterials have furthermore demonstrated enhanced effectiveness in the degradation of contaminants in soil and water. This can be seen as a future possibility in facing environmental challenges. Dave and Das [118] reported that nanoparticles can potentially bind with xenobiotic compounds and can either transform them into less harmful byproducts or completely degrade them, this process can help in the clean-up of contaminated environment. The requirement for any ideal bioremediation process relies on the use of an environmentally friendly and efficient approach. These above-described technologies are complete for the effective bioremediation process. Also, as part of Nanotechnological tools in bioremediation, nanobiosurfactants provides unique properties which makes them potentially strong candidates for ecofriendly nanobioremediation in the future [119].
Some inorganic sensors have also been developed and applied in nanotechnology [120] to trace and identify contaminants/pollutants in the environment which will inform the most suitable/appropriate biotechnological tool to be applied for clean-up process. In another study, it was reported that the use of oxygen-sensitive proteins to develop oxygen biosensors is an emerging field which can be adopted for the preparation of nanomaterials that are able to respond to oxygen levels and other specific components of pollutants [121]. Ryu et al. [122] extensively reviewed the field of Transmembrane proteins which were incorporated into membranes coupled to several trandusctors and observed that this approach can be successfully applied in pesticide detection, monitoring of gases, microarray etc. Based on this, [123] recommended that in the future, hydrocarbon catabolic enzymes may also be incorporated to monitor more complex pollutants such as Polycyclic aromatic hydrocarbons (PAHs). These concepts, explored with proteins will open a wide area of sensing and detoxification opportunities in bioremediation. Techniques such as biofilm formation and whole-cell immobilization for the removal and recovery of soils containing pollutants such as heavy metals and PAHs have also gained attention [124].
The various biotechnological tools in ecorestoration of crude oil polluted environment outlined in this review has been confirmed to be eco-friendly and effective in the mineralization of the pollutants. Biosurfactant-producing microbes contribute significantly to enhancing microbial bioremediation by increasing bioavailability. Microorganisms produce a wide range of surfactants with hydrocarbon specificity. Microbial bioremediation and phytoremediation have both yielded positive results in environmental studies under favorable conditions and growth conditions, respectively. The genetic engineered microbes in bioremediation favor the degradation of recalcitrant hydrocarbons and increase the rate of degradation. Although this method is still under investigation based on environmental and ecological risk. This review has highlighted known eco-friendly approaches of bioremediation of polluted sites using several biotechnological tools.
"Open access contributes to scientific excellence and integrity. It opens up research results to wider analysis. It allows research results to be reused for new discoveries. And it enables the multi-disciplinary research that is needed to solve global 21st century problems. Open access connects science with society. It allows the public to engage with research. To go behind the headlines. And look at the scientific evidence. And it enables policy makers to draw on innovative solutions to societal challenges".
\n\nCarlos Moedas, the European Commissioner for Research Science and Innovation at the STM Annual Frankfurt Conference, October 2016.
",metaTitle:"About Open Access",metaDescription:"Open access contributes to scientific excellence and integrity. It opens up research results to wider analysis. It allows research results to be reused for new discoveries. And it enables the multi-disciplinary research that is needed to solve global 21st century problems. Open access connects science with society. It allows the public to engage with research. To go behind the headlines. And look at the scientific evidence. And it enables policy makers to draw on innovative solutions to societal challenges.\n\nCarlos Moedas, the European Commissioner for Research Science and Innovation at the STM Annual Frankfurt Conference, October 2016.",metaKeywords:null,canonicalURL:"about-open-access",contentRaw:'[{"type":"htmlEditorComponent","content":"The Open Access publishing movement started in the early 2000s when academic leaders from around the world participated in the formation of the Budapest Initiative. They developed recommendations for an Open Access publishing process, “which has worked for the past decade to provide the public with unrestricted, free access to scholarly research—much of which is publicly funded. Making the research publicly available to everyone—free of charge and without most copyright and licensing restrictions—will accelerate scientific research efforts and allow authors to reach a larger number of readers” (reference: http://www.budapestopenaccessinitiative.org)
\\n\\nIntechOpen’s co-founders, both scientists themselves, created the company while undertaking research in robotics at Vienna University. Their goal was to spread research freely “for scientists, by scientists’ to the rest of the world via the Open Access publishing model. The company soon became a signatory of the Budapest Initiative, which currently has more than 1000 supporting organizations worldwide, ranging from universities to funders.
\\n\\nAt IntechOpen today, we are still as committed to working with organizations and people who care about scientific discovery, to putting the academic needs of the scientific community first, and to providing an Open Access environment where scientists can maximize their contribution to scientific advancement. By opening up access to the world’s scientific research articles and book chapters, we aim to facilitate greater opportunity for collaboration, scientific discovery and progress. We subscribe wholeheartedly to the Open Access definition:
\\n\\n“By “open access” to [peer-reviewed research literature], we mean its free availability on the public internet, permitting any users to read, download, copy, distribute, print, search, or link to the full texts of these articles, crawl them for indexing, pass them as data to software, or use them for any other lawful purpose, without financial, legal, or technical barriers other than those inseparable from gaining access to the internet itself. The only constraint on reproduction and distribution, and the only role for copyright in this domain, should be to give authors control over the integrity of their work and the right to be properly acknowledged and cited” (reference: http://www.budapestopenaccessinitiative.org)
\\n\\nOAI-PMH
\\n\\nAs a firm believer in the wider dissemination of knowledge, IntechOpen supports the Open Access Initiative Protocol for Metadata Harvesting (OAI-PMH Version 2.0). Read more
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\\n\\nBook chapters published in edited volumes are distributed under the Creative Commons Attribution 3.0 Unported License (CC BY 3.0). IntechOpen upholds a very flexible Copyright Policy. There is no copyright transfer to the publisher and Authors retain exclusive copyright to their work. All Monographs/Compacts are distributed under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0). Read more
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\\n\\nThe Open Access publishing model employed by IntechOpen eliminates subscription charges and pay-per-view fees, enabling readers to access research at no cost. In order to sustain operations and keep our publications freely accessible we levy an Open Access Publishing Fee for manuscripts, which helps us cover the costs of editorial work and the production of books. Read more
\\n\\nDigital Archiving Policy
\\n\\nIntechOpen is committed to ensuring the long-term preservation and the availability of all scholarly research we publish. We employ a variety of means to enable us to deliver on our commitments to the scientific community. Apart from preservation by the Croatian National Library (for publications prior to April 18, 2018) and the British Library (for publications after April 18, 2018), our entire catalogue is preserved in the CLOCKSS archive.
\\n\\nOpen Science is transparent and accessible knowledge that is shared and developed through collaborative networks.
\\n\\nOpen Science is about increased rigour, accountability, and reproducibility for research. It is based on the principles of inclusion, fairness, equity, and sharing, and ultimately seeks to change the way research is done, who is involved and how it is valued. It aims to make research more open to participation, review/refutation, improvement and (re)use for the world to benefit.
\\n\\nOpen Science refers to doing traditional science with more transparency involved at various stages, for example by openly sharing code and data. It implies a growing set of practices - within different disciplines - aiming at:
\\n\\nWe aim at improving the quality and availability of scholarly communication by promoting and practicing:
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The Open Access publishing movement started in the early 2000s when academic leaders from around the world participated in the formation of the Budapest Initiative. They developed recommendations for an Open Access publishing process, “which has worked for the past decade to provide the public with unrestricted, free access to scholarly research—much of which is publicly funded. Making the research publicly available to everyone—free of charge and without most copyright and licensing restrictions—will accelerate scientific research efforts and allow authors to reach a larger number of readers” (reference: http://www.budapestopenaccessinitiative.org)
\n\nIntechOpen’s co-founders, both scientists themselves, created the company while undertaking research in robotics at Vienna University. Their goal was to spread research freely “for scientists, by scientists’ to the rest of the world via the Open Access publishing model. The company soon became a signatory of the Budapest Initiative, which currently has more than 1000 supporting organizations worldwide, ranging from universities to funders.
\n\nAt IntechOpen today, we are still as committed to working with organizations and people who care about scientific discovery, to putting the academic needs of the scientific community first, and to providing an Open Access environment where scientists can maximize their contribution to scientific advancement. By opening up access to the world’s scientific research articles and book chapters, we aim to facilitate greater opportunity for collaboration, scientific discovery and progress. We subscribe wholeheartedly to the Open Access definition:
\n\n“By “open access” to [peer-reviewed research literature], we mean its free availability on the public internet, permitting any users to read, download, copy, distribute, print, search, or link to the full texts of these articles, crawl them for indexing, pass them as data to software, or use them for any other lawful purpose, without financial, legal, or technical barriers other than those inseparable from gaining access to the internet itself. The only constraint on reproduction and distribution, and the only role for copyright in this domain, should be to give authors control over the integrity of their work and the right to be properly acknowledged and cited” (reference: http://www.budapestopenaccessinitiative.org)
\n\nOAI-PMH
\n\nAs a firm believer in the wider dissemination of knowledge, IntechOpen supports the Open Access Initiative Protocol for Metadata Harvesting (OAI-PMH Version 2.0). Read more
\n\nLicense
\n\nBook chapters published in edited volumes are distributed under the Creative Commons Attribution 3.0 Unported License (CC BY 3.0). IntechOpen upholds a very flexible Copyright Policy. There is no copyright transfer to the publisher and Authors retain exclusive copyright to their work. All Monographs/Compacts are distributed under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0). Read more
\n\nPeer Review Policies
\n\nAll scientific works are Peer Reviewed prior to publishing. Read more
\n\nOA Publishing Fees
\n\nThe Open Access publishing model employed by IntechOpen eliminates subscription charges and pay-per-view fees, enabling readers to access research at no cost. In order to sustain operations and keep our publications freely accessible we levy an Open Access Publishing Fee for manuscripts, which helps us cover the costs of editorial work and the production of books. Read more
\n\nDigital Archiving Policy
\n\nIntechOpen is committed to ensuring the long-term preservation and the availability of all scholarly research we publish. We employ a variety of means to enable us to deliver on our commitments to the scientific community. Apart from preservation by the Croatian National Library (for publications prior to April 18, 2018) and the British Library (for publications after April 18, 2018), our entire catalogue is preserved in the CLOCKSS archive.
\n\nOpen Science is transparent and accessible knowledge that is shared and developed through collaborative networks.
\n\nOpen Science is about increased rigour, accountability, and reproducibility for research. It is based on the principles of inclusion, fairness, equity, and sharing, and ultimately seeks to change the way research is done, who is involved and how it is valued. It aims to make research more open to participation, review/refutation, improvement and (re)use for the world to benefit.
\n\nOpen Science refers to doing traditional science with more transparency involved at various stages, for example by openly sharing code and data. It implies a growing set of practices - within different disciplines - aiming at:
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De",surname:"Nazaré",slug:"fabio-nazare",fullName:"Fábio Nazaré"}]},{id:"15098",doi:"10.5772/15736",title:"Silicon Carbide: Synthesis and Properties",slug:"silicon-carbide-synthesis-and-properties",totalDownloads:23037,totalCrossrefCites:26,totalDimensionsCites:65,abstract:null,book:{id:"83",slug:"properties-and-applications-of-silicon-carbide",title:"Properties and Applications of Silicon Carbide",fullTitle:"Properties and Applications of Silicon Carbide"},signatures:"Houyem Abderrazak and Emna Selmane Bel Hadj Hmida",authors:[{id:"18643",title:"Dr.",name:"Houyem",middleName:null,surname:"Abderrazak",slug:"houyem-abderrazak",fullName:"Houyem Abderrazak"},{id:"23082",title:"Dr.",name:"Emna Selmane",middleName:null,surname:"Bel Hadj Hmida",slug:"emna-selmane-bel-hadj-hmida",fullName:"Emna Selmane Bel Hadj Hmida"}]},{id:"61428",doi:"10.5772/intechopen.76161",title:"Printing Technologies on Flexible Substrates for Printed Electronics",slug:"printing-technologies-on-flexible-substrates-for-printed-electronics",totalDownloads:3186,totalCrossrefCites:38,totalDimensionsCites:61,abstract:"Printing technologies have been demonstrated to be highly efficient and compatible with polymeric materials (both inks and substrates) enabling a new generation of flexible electronics applications. Conductive flexible polymers are a new class of materials that are prepared for a wide range of applications, such as photovoltaic solar cells, transistors molecular devices, and sensors and actuators. There are many possible printing techniques. This chapter provides an opportunity to review the most common printing techniques used at the industrial level, the most commonly used substrates and electronic materials, giving an overall vision for a better understanding and evaluation of their different features. Several technological solutions (contact/noncontact) and its critical challenges are also presented. Inkjet Printing Technology (IPT) has been receiving a great attention and therefore higher focus is given to this technology. An overview of IPT is presented to evidence its importance and potential as a key-technology on the research field for printed electronics development, as well as on large scale industrial manufacturing. A background and a review on prior work are presented along with used materials, developed applications and potential of IPT technology. The main features of the different printing technologies, advantages and main challenges are also compared.",book:{id:"6765",slug:"flexible-electronics",title:"Flexible Electronics",fullTitle:"Flexible Electronics"},signatures:"Sílvia Manuela Ferreira Cruz, Luís A. Rocha and Júlio C. Viana",authors:[{id:"15565",title:"Prof.",name:"Julio",middleName:null,surname:"Viana",slug:"julio-viana",fullName:"Julio Viana"},{id:"238389",title:"Ph.D.",name:"Sílvia",middleName:null,surname:"Cruz",slug:"silvia-cruz",fullName:"Sílvia Cruz"},{id:"247716",title:"Prof.",name:"Luís",middleName:null,surname:"Rocha",slug:"luis-rocha",fullName:"Luís Rocha"}]}],mostDownloadedChaptersLast30Days:[{id:"70315",title:"Some Basic and Key Issues of Switched-Reluctance Machine Systems",slug:"some-basic-and-key-issues-of-switched-reluctance-machine-systems",totalDownloads:1216,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"Although switched-reluctance machine (SRM) possesses many structural advantages and application potential, it is rather difficult to successfully control with high performance being comparable to other machines. Many critical affairs must be properly treated to obtain the improved operating characteristics. This chapter presents the basic and key technologies of switched-reluctance machine in motor and generator operations. The contents in this chapter include: (1) structures and governing equations of SRM; (2) some commonly used SRM converters; (3) estimation of key parameters and performance evaluation of SRM drive; (4) commutation scheme, current control scheme, and speed control scheme of SRM drive; (5) some commonly used front-end converters and their operation controls for SRM drive; (6) reversible and regenerative braking operation controls for SRM drive; (7) some tuning issues for SRM drive; (8) operation control and some tuning issues of switched-reluctance generators; and (9) experimental application exploration for SRM systems—(a) wind generator and microgrid and (b) EV SRM drive.",book:{id:"8899",slug:"modelling-and-control-of-switched-reluctance-machines",title:"Modelling and Control of Switched Reluctance Machines",fullTitle:"Modelling and Control of Switched Reluctance Machines"},signatures:"Chang-Ming Liaw, Min-Ze Lu, Ping-Hong Jhou and Kuan-Yu Chou",authors:[{id:"37616",title:"Prof.",name:"Chang-Ming",middleName:null,surname:"Liaw",slug:"chang-ming-liaw",fullName:"Chang-Ming Liaw"},{id:"306461",title:"Mr.",name:"Min-Ze",middleName:null,surname:"Lu",slug:"min-ze-lu",fullName:"Min-Ze Lu"},{id:"306463",title:"Mr.",name:"Ping-Hong",middleName:null,surname:"Jhou",slug:"ping-hong-jhou",fullName:"Ping-Hong Jhou"},{id:"306464",title:"Mr.",name:"Kuan-Yu",middleName:null,surname:"Chou",slug:"kuan-yu-chou",fullName:"Kuan-Yu Chou"}]},{id:"52822",title:"Non-Orthogonal Multiple Access (NOMA) for 5G Networks",slug:"non-orthogonal-multiple-access-noma-for-5g-networks",totalDownloads:14704,totalCrossrefCites:25,totalDimensionsCites:35,abstract:"In this chapter, we explore the concept of non-orthogonal multiple access (NOMA) scheme for the future radio access for 5G. We first provide the fundamentals of the technique for both downlink and uplink channels and then discuss optimizing the network capacity under fairness constraints. We further discuss the impacts of imperfect receivers on the performance of NOMA networks. Finally, we discuss the spectral efficiency (SE) of the networks that employ NOMA with its relations with energy efficiency (EE). We demonstrate that the networks with NOMA outperform other multiple access schemes in terms of sum capacity, EE and SE.",book:{id:"5480",slug:"towards-5g-wireless-networks-a-physical-layer-perspective",title:"Towards 5G Wireless Networks",fullTitle:"Towards 5G Wireless Networks - A Physical Layer Perspective"},signatures:"Refik Caglar Kizilirmak",authors:[{id:"188668",title:"Dr.",name:"Refik Caglar",middleName:null,surname:"Kizilirmak",slug:"refik-caglar-kizilirmak",fullName:"Refik Caglar Kizilirmak"}]},{id:"77871",title:"Protection of Microgrids",slug:"protection-of-microgrids",totalDownloads:261,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"The concept of microgrids goes back to the early years of the electricity industry although the systems then were not formally called microgrids. Today, two types of microgrids can be seen: independent and grid connected. The protection requirement of these two types differs as the protection needs of an independent microgrid are intended for protecting components and systems within the microgrid, whereas a grid connected microgrid demands both internal and external protection. The first part of this chapter is dedicated to independent microgrids. How protection devices such as residual current circuit breakers, miniature and moulded case circuit breakers, and surge protective devices should be selected for an example microgrid is discussed while referring to the relevant standards. In the next section, the protection of a grid connected microgrid is discussed. Particularly, micro-source protection, microgrid protection, loss of mains protection and fault ride-through requirements are discussed while referring to two commonly used distributed generator connection codes. An example with simulations carried out in the IPSA simulation platform was used to explain different protection requirements and calculation procedures. Finally, grounding requirements are discussed while referring to different interfacing transformer connections and voltage source inverter connections.",book:{id:"10176",slug:"microgrids-and-local-energy-systems",title:"Microgrids and Local Energy Systems",fullTitle:"Microgrids and Local Energy Systems"},signatures:"Janaka Ekanayake",authors:[{id:"328170",title:"Prof.",name:"Janake",middleName:null,surname:"Ekanayake",slug:"janake-ekanayake",fullName:"Janake Ekanayake"}]},{id:"47585",title:"Free Space Optical Communications — Theory and Practices",slug:"free-space-optical-communications-theory-and-practices",totalDownloads:8970,totalCrossrefCites:41,totalDimensionsCites:53,abstract:null,book:{id:"4473",slug:"contemporary-issues-in-wireless-communications",title:"Contemporary Issues in Wireless Communications",fullTitle:"Contemporary Issues in Wireless Communications"},signatures:"Abdulsalam Ghalib Alkholidi and Khaleel Saeed Altowij",authors:[{id:"100466",title:"Dr.",name:"Abdulsalam",middleName:null,surname:"Alkholidi",slug:"abdulsalam-alkholidi",fullName:"Abdulsalam Alkholidi"},{id:"131091",title:"MSc.",name:"Khalil",middleName:null,surname:"Altowij",slug:"khalil-altowij",fullName:"Khalil Altowij"}]},{id:"41657",title:"Algorithms for Efficient Computation of Convolution",slug:"algorithms-for-efficient-computation-of-convolution",totalDownloads:9887,totalCrossrefCites:15,totalDimensionsCites:20,abstract:null,book:{id:"3158",slug:"design-and-architectures-for-digital-signal-processing",title:"Design and Architectures for Digital Signal Processing",fullTitle:"Design and Architectures for Digital Signal Processing"},signatures:"Karas Pavel and Svoboda David",authors:[{id:"154795",title:"Ph.D. Student",name:"Pavel",middleName:null,surname:"Karas",slug:"pavel-karas",fullName:"Pavel Karas"},{id:"155141",title:"Dr.",name:"David",middleName:null,surname:"Svoboda",slug:"david-svoboda",fullName:"David Svoboda"}]}],onlineFirstChaptersFilter:{topicId:"116",limit:6,offset:0},onlineFirstChaptersCollection:[{id:"81158",title:"SOA Model and Design Guidelines in Lossless Photonic Subsystem",slug:"soa-model-and-design-guidelines-in-lossless-photonic-subsystem",totalDownloads:18,totalDimensionsCites:0,doi:"10.5772/intechopen.103048",abstract:"We propose a new practical analytical model to calculate the performance of amplitude-modulated systems, including semiconductor optical amplifiers (SOA). Lower and upper-performance bounds are given in terms of signal quality factor (Q) concerning the input signal pattern. The target is to provide a design tool for gain elements included in photonic integrated circuits (PIC) to compensate for their insertion loss. This subject is a critical issue, for example, in the arrays of optical transmitters with silicon photonics modulators used for interconnection applications. Due to implementation limitations, the design of an SOA embedded in a PIC is considerably different with respect to the use of SOAs as line amplifiers in optical networks. SOA amplified spontaneous emission (ASE) and gain saturation effects have been included in the model, together with the input signal extinction ratio and the receiver electrical filter. Each degradation effect provides its own contribution to the signal integrity in terms of signal-to-noise ratio (SNR) or inter-symbol interference (ISI). The model shows that the SOA operation at low extinction ratios, typical in optical interconnect applications, is substantially different from the operation at higher extinction ratios used in transport networks. The model is validated through numerical simulations and experiments. Finally, two examples are provided for dimensioning a PIC system and optimizing the SOA parameters.",book:{id:"11158",title:"New Advances in Semiconductors",coverURL:"https://cdn.intechopen.com/books/images_new/11158.jpg"},signatures:"Pantea Nadimi Goki, Antonio Tufano, Fabio Cavaliere and Luca Potì"},{id:"81339",title:"Radiation Response of Group-IV and III-V Semiconductors Subjected to D–D and D–T Fusion Neutrons",slug:"radiation-response-of-group-iv-and-iii-v-semiconductors-subjected-to-d-d-and-d-t-fusion-neutrons",totalDownloads:16,totalDimensionsCites:0,doi:"10.5772/intechopen.103047",abstract:"This work focuses on the radiation response of Group IV (Si, Ge, SiC, diamond) and III-V (GaAs, GaN, GaP, GaSb, InAs, InP, InSb, AlAs) semiconductors subjected to D–D (2.45 MeV) and D–T (14 MeV) neutrons. The response of each material has been systematically investigated through a direct calculation using nuclear cross-section libraries, MCNP6, and Geant4 numerical simulations. For the semiconductor materials considered, we have investigated in detail the reaction rates per type of reaction (elastic, inelastic, and nonelastic) and proposed an exhaustive classification and counting of all the neutron-induced events and secondary products as a function of their nature and energy. Several metrics for quantifying the susceptibility of the related semiconductor-based electronics to neutron fusions have been finally considered and discussed.",book:{id:"11158",title:"New Advances in Semiconductors",coverURL:"https://cdn.intechopen.com/books/images_new/11158.jpg"},signatures:"Jean-Luc Autran Daniela Munteanu"},{id:"81346",title:"Power Reduction Using Efficient Way of Tri-State Buffer Connection",slug:"power-reduction-using-efficient-way-of-tri-state-buffer-connection",totalDownloads:9,totalDimensionsCites:0,doi:"10.5772/intechopen.102643",abstract:"Clock gating is a very important technique for decreasing wasted power in digital design. One of the approaches to obtain dissipated power is an intention by the way of masking the clock pulse that is going to the unused part of the design. In this research, a comparative evaluation of current clock gating techniques on synchronous digital design changed into provided. In the new suggested design, the gated clock technology circuit is a use of tri-state buffer and gated clock. The new submodule was created by the connection of two tri-state logic used as switched to control to the design. The new suggested technique was saving more power and area. The suggested sub-module was achieved by using ASIC design methodologies. In order to implement Huffman modules, the architecture of the proposed module has been generated using Verilog HDL language. In addition, it is proved using Modalism-Altera 10.3c (Quartus II 14.1) tools. By using the tri-state technique, dynamic power and total power are decreased. The suggested technique will decrease the hardware complexity.",book:{id:"11158",title:"New Advances in Semiconductors",coverURL:"https://cdn.intechopen.com/books/images_new/11158.jpg"},signatures:"Maan Hameed"},{id:"81253",title:"Many-Electron Problem in an Atomic Lattice Reduced Exactly to Two-Particle Pseudo-Electron Excitations: Key to Alternative First-Principles Methods",slug:"many-electron-problem-in-an-atomic-lattice-reduced-exactly-to-two-particle-pseudo-electron-excitatio",totalDownloads:7,totalDimensionsCites:0,doi:"10.5772/intechopen.103045",abstract:"Prediction of properties of solids (semiconductors) is based almost entirely on the first-principles methods. The first principles theories are far from being perfect and new schemes are developing. In this study, we do not follow the traditional one-particle-in-effective-field concept. Instead, all Coulomb interactions between particles are treated in their original form, i.e., particle-particle discrete interactions. Two-particles Coulomb excitations theory in a crystal lattice is proposed, along with a method for calculations of physical measurables. Most important, the relevant particles are not electrons but pseudo-electrons with both the Coulomb interaction mode and the effective mass different from those of electrons. The unitary transformation represents the many-body system as an ensemble of two-pseudo-electron excitations without neglection of the terms in a Hamiltonian. The many-particle wave function, being derived in a non-trivial two-particle form, ensures a full description of exchange-correlation and screening effects, for both ground and excited states. As an example, the energy of a many-electron system and the quasiparticle energies are expressed in an elegant integral closed-form and compared with the Density Functional Theory. The proposed scheme possibly opens a new route toward the numerical evaluation of properties of many-particle systems.",book:{id:"11158",title:"New Advances in Semiconductors",coverURL:"https://cdn.intechopen.com/books/images_new/11158.jpg"},signatures:"Adil-Gerai Kussow"},{id:"80904",title:"Temperature Dependence of Electrical Resistivity of (III, Mn)V Diluted Magnetic Semiconductors",slug:"temperature-dependence-of-electrical-resistivity-of-iii-mn-v-diluted-magnetic-semiconductors",totalDownloads:12,totalDimensionsCites:0,doi:"10.5772/intechopen.103046",abstract:"In this work, a theory of temperature dependence of electrical resistivity is developed, with a particular emphasis on dilute magnetic semiconductors (DMSs). The approach is based on the equation of motion of the Ruderman-Kittel-Kasuya-Yosida (RKKY) exchange interaction and considers both spin and charge disorder. The formalism is applied to the specific case of Ga1−xMnxAs.Using the RKKY exchange interaction, the relaxation time τand the exchange interaction J are calculated. Then using spin-dependent relaxation time, electrical resistivity of the material is calculated. The electrical resistivity of Mn-doped III—V DMS is decreased with increasing temperature and magnetic impurity concentration.",book:{id:"11158",title:"New Advances in Semiconductors",coverURL:"https://cdn.intechopen.com/books/images_new/11158.jpg"},signatures:"Edosa Tasisa Jira"},{id:"80827",title:"Theory of Charge Transport in the Illuminated Semiconductor/Liquid Junctions",slug:"theory-of-charge-transport-in-the-illuminated-semiconductor-liquid-junctions",totalDownloads:54,totalDimensionsCites:0,doi:"10.5772/intechopen.103049",abstract:"The field of photoelectrochemical (PEC) cells for solar water splitting or CO2 reduction has attracted intense attention of many research groups in last 15 years. Nevertheless, a cost-effective and efficient PEC cell for hydrogen production in the large scale was not yet discovered. The core functionality of the PEC cell is provided by the semiconductor/liquid junction, creating the electrostatic field to separate the photogenerated charges. This work aims to be a starting point for a newcomer in the field providing a compact knowledge about the charge transport and electrochemistry fundamentals in semiconductor/liquid junctions in the steady state. We describe charge transport within the semiconductor and electron transfer between the semiconductor and electrolyte, followed by the effect of illumination and charge recombination on charge transport. Finally, we discuss the effects due to surface trap states and the relation of the theoretical expressions and experimental results.",book:{id:"11158",title:"New Advances in Semiconductors",coverURL:"https://cdn.intechopen.com/books/images_new/11158.jpg"},signatures:"Peter Cendula"}],onlineFirstChaptersTotal:6},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:87,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:98,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:27,numberOfPublishedChapters:287,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:9,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:11,numberOfPublishedChapters:139,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:8,numberOfPublishedChapters:129,numberOfOpenTopics:0,numberOfUpcomingTopics:2,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!1},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:107,numberOfOpenTopics:3,numberOfUpcomingTopics:1,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:10,numberOfPublishedChapters:103,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:12,numberOfOpenTopics:2,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:0,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!1},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:0,numberOfPublishedChapters:10,numberOfOpenTopics:4,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}},{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. 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\r\n\tThis series will provide a comprehensive overview of recent research trends in business and management, economics, and marketing. Topics will include asset liability management, financial consequences of the financial crisis and covid-19, financial accounting, mergers and acquisitions, management accounting, SMEs, financial markets, corporate finance and governance, managerial technology and innovation, resource management and sustainable development, social entrepreneurship, corporate responsibility, ethics and accountability, microeconomics, labour economics, macroeconomics, public economics, financial economics, econometrics, direct marketing, creative marketing, internet marketing, market planning and forecasting, brand management, market segmentation and targeting and other topics under business and management. This book series will focus on various aspects of business and management whose in-depth understanding is critical for business and company management to function effectively during this uncertain time of financial crisis, Covid-19 pandemic, and military activity in Europe.
",coverUrl:"https://cdn.intechopen.com/series/covers/22.jpg",latestPublicationDate:"May 18th, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:1,editor:{id:"356540",title:"Prof.",name:"Taufiq",middleName:null,surname:"Choudhry",slug:"taufiq-choudhry",fullName:"Taufiq Choudhry",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000036X2hvQAC/Profile_Picture_2022-03-14T08:58:03.jpg",biography:"Prof. Choudhry holds a BSc degree in Economics from the University of Iowa, as well as a Masters and Ph.D. in Applied Economics from Clemson University, USA. In January 2006, he became a Professor of Finance at the University of Southampton Business School. He was previously a Professor of Finance at the University of Bradford Management School. He has over 80 articles published in international finance and economics journals. His research interests and specialties include financial econometrics, financial economics, international economics and finance, housing markets, financial markets, among others.",institutionString:null,institution:{name:"University of Southampton",institutionURL:null,country:{name:"United Kingdom"}}},editorTwo:null,editorThree:null},subseries:{paginationCount:3,paginationItems:[{id:"86",title:"Business and Management",coverUrl:"https://cdn.intechopen.com/series_topics/covers/86.jpg",isOpenForSubmission:!0,editor:{id:"128342",title:"Prof.",name:"Vito",middleName:null,surname:"Bobek",slug:"vito-bobek",fullName:"Vito Bobek",profilePictureURL:"https://mts.intechopen.com/storage/users/128342/images/system/128342.jpg",biography:"Dr. Vito Bobek works as an international management professor at the University of Applied Sciences FH Joanneum, Graz, Austria. He has published more than 400 works in his academic career and visited twenty-two universities worldwide as a visiting professor. Dr. Bobek is a member of the editorial boards of six international journals and a member of the Strategic Council of the Minister of Foreign Affairs of the Republic of Slovenia. He has a long history in academia, consulting, and entrepreneurship. His own consulting firm, Palemid, has managed twenty significant projects, such as Cooperation Program Interreg V-A (Slovenia-Austria) and Capacity Building for the Serbian Chamber of Enforcement Agents. He has also participated in many international projects in Italy, Germany, Great Britain, the United States, Spain, Turkey, France, Romania, Croatia, Montenegro, Malaysia, and China. Dr. Bobek is also a co-founder of the Academy of Regional Management in Slovenia.",institutionString:"Universities of Applied Sciences FH Joanneum, Austria",institution:null},editorTwo:{id:"293992",title:"Dr.",name:"Tatjana",middleName:null,surname:"Horvat",slug:"tatjana-horvat",fullName:"Tatjana Horvat",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002hXb0hQAC/Profile_Picture_1642419002203",biography:"Tatjana Horvat works as a professor for accountant and auditing at the University of Primorska, Slovenia. She is a Certified State Internal Auditor (licensed by Ministry of Finance RS) and Certified Internal Auditor for Business Sector and Certified accountant (licensed by Slovenian Institute of Auditors). At the Ministry of Justice of Slovenia, she is a member of examination boards for court expert candidates and judicial appraisers in the following areas: economy/finance, valuation of companies, banking, and forensic investigation of economic operations/accounting. 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