The quantity of silver (ppm) and antimicrobial efficiency expressed as a bacterial reduction (%) of untreated and plasma-treated cotton samples functionalized with powdered silver nanoparticles
The textile industry in developed countries is confronting the world’s marketing conditions and competitive challenges which are driving towards the development of advanced, highly functional textiles and textiles with higher added value. The conventional textile finishing techniques are wet chemical modifications where water and rather hazardous chemicals are used in large quantities and wastewaters need to be processed before discharging effluent, whereas the most problematic factor are ecological impacts to the environment and effects to human health. The increasing environmental concerns and demands for an environmentally friendly processing of textiles leads to the development of new technologies, the use of plasma being one of the suitable methods . Plasma technology is an environmentally friendly technology and a step towards creating solid surfaces with new and improved properties that cannot be achieved by conventional processes . Plasma is the fourth state of matter. It is a gas with a certain portion of ionized as well as other reactive particles, e.g. ions, electrons, photons, radicals and metastable excited particles. Several types of plasma are known; however, only non-equilibrium or cold plasma is used for the modification of physical and chemical properties of solid materials such as textiles. Chemically reactive particles produced at a low gas temperature are a unique property of cold plasma; hence, there is minimal thermal degradation of a textile substrate during the plasma processing . Cold plasma is a partially ionized gas with the main characteristic of a very high temperature of free electrons (typically of the order of 10,000 K, often about 50,000 K) and a low kinetic temperature of all other species. The average energy of the excited molecules is usually far from the values calculated from the thermal equilibrium at room temperature. The rotational temperature, for instance, is often close to 1000 K, while the vibrational temperature can be as high as 10,000 K, although the kinetic (translation) temperature is close to room temperature. Furthermore, the dissociation fraction is often several percent, which is orders of magnitude larger than that calculated from thermal equilibrium at room temperature. This also applies to the ionization fraction; although this is often much lower than the dissociation fraction. Plasma with such characteristics readily interacts with solid surfaces, causing reactions that would otherwise occur only at elevated temperature of the solid material. For this reason, non-equilibrium plasma represents an extremely powerful medium for modification of the surface properties of solid materials. A medium of particular interest is weakly ionized highly dissociated oxidative plasma that can be sustained in high frequency discharges in oxygen, air, carbon dioxide, water vapor, and mixtures of these gases with a noble gas. Such plasma has been successfully utilized in an extremely wide range of applications from nanoscience to fusion reactors. Plasma is used for synthesis of nanostructures with interesting properties, removal of thin films of organic impurities, selective etching of composites, sterilization, passivation of metal, ashing of biological materials, etching of photoresists, functionalization of polymers, and conditioning of tokamaks with carbon walls [4-9].
The choice of discharge parameters is determined by the requirements of each particular application. For selective plasma etching, for instance, extremely aggressive plasma is needed; thus, it is created with powerful generators at a moderate pressure (where the O density is the highest) in pure oxygen or in a mixture of oxygen and argon. For treatment of delicate organic materials, on the other hand, weak plasma performs better, since aggressive plasma would destroy organic material in a fraction of a second. Therefore, extremely delicate organic materials are rather treated in an afterglow or in plasma created at low pressure and with a low-power generator. Water vapor is sometimes used instead of oxygen. The advantages of using plasma are ecological and economical. Moreover, the textiles subjected to the treatment are modified without an alteration of the bulk properties. Unlike wet chemical processes, which penetrate deep into the fibers, plasma produces no more than a surface reaction, the properties given to the material being limited to the surface layer of a few nanometers . The modification of textile substrates using plasma enables different effects on the textile surfaces from the surface activation to a thin film deposition via plasma polymerization. In the first stage of the treatment, plasma reacts with the substrate surface where active species and new functional groups are created, which can completely change the reactivity of the substrate . The changes in the surface morphology of fibers can be induced by plasma etching process where the nano- or micro-roughness of fibers is formed . The nanostructured textile surfaces have a higher specific surface area, which leads to new or improved properties of the treated surface, i.e. increased surface activity, hydrophilic or hydrophobic properties, and increased absorption capacity towards different materials, i.e. nanoparticles and nano-composites [13- 18].
When researching the deposition of nanoparticles onto different substrates, it is important to understand the adhesion of particles, which is dependent on the interaction mechanism with a material. The mechanism of nanoparticle adhesion has not been completely explained yet, since there are many different opinions among the theorists on the subject. Thus, it is generally considered that attractive forces and chemical bonds play an important role in the adhesion of particles . The physical or mechanical adhesion of nanoparticles mostly occurs due to van der Walls or electrostatic forces, while the chemical adhesion of particles is a consequence of ionic, covalent, metallic and hydrogen bonds . Moreover, the nanoparticles can penetrate into certain parts of the substrate, such as pores, holes and crevices, and they lock mechanically to the substrate. This adhesion mechanism, which is called mechanical interlocking, has been solved from the perspective of surface roughness effects . Since plasma causes etching of the fibers and leads to an increase of the surface roughness higher adhesion properties towards metal or ceramic particles onto substrates can be achieved [22-30]. The adhesion of TiN (titanium nitride) onto PP (polypropylene) and PC (polycarbonate) was increased after a modification of substrates with argon low-pressure plasma . The roughness after plasma treatment increased from 15 nm to 17 nm for PP and from 12 nm to 30 nm for PC. Consequently, contact angles decreased from 95° to 59° for PC and from 87° to 35° for PP. The surface modification of polyethylene terephthalate (PET) polymer was created by oxygen and nitrogen plasma at different treatment times . The surface of PET polymer was modified in order to achieve improved attachment of fucoidan, which is a bioactive coating with antithrombogenic properties. The attachment of fucoidan was improved by oxygen plasma treatment, especially due to the surface roughening. The adhesion work, the surface energy and the surface polarity of PA6 (polyamide-6) fibers were improved by dielectric barrier discharge (DBD) treatment in helium at atmospheric pressure. Furthermore, a new structure was observed at the nanoscale, with an increased roughness and a larger surface area, favoring the adsorption . The self-cleaning and UV protective properties of PET fibers were drastically improved after a modification of PET fibers with oxygen plasma and loading of TiO2 prepared by an aqueous sol-gel process . Cotton also showed self-cleaning properties after RF plasma and TiO2 treatment . TiO2 on textile substrates is also used for a biomedical application to improve antimicrobial effectiveness of the fabric . By using oxygen radiofrequency plasma at a higher power input, the roughness of fibers increased and likewise the adhesion of TiO2 onto treated fabric. Treatment of PA and PET with corona plasma increased the adhesion of colloidal silver which affected the antifungal protection of the fabrics . The quantity of silver on plasma-treated fabric was three times higher than on untreated fabric.
Preparation of metal nanoparticles also enables the development of new biocides. Due to their large surface area and ability to detain moisture, the textile materials are an excellent environment for a microorganism growth. Microorganisms can cause milder, aesthetic unpleasantness to serious health related problems. Textile materials with an antimicrobial effectiveness are used for medical, military and technical textiles, textiles for sports and leisure and bedding. At nanotechnology researches in textiles, different forms of silver were used, such as metal silver nanoparticles, silver chloride (AgCl) and composite particles of silver and titanium dioxide (Ag-TiO2) [3, 24, 25, 27, 38-47]. In the case of antimicrobial efficiency, the surface coating of nanosilver on titanium dioxide maximizes the number of particles per unit area in comparison with the use of an equal mass fraction of pure silver [48,49]. Different methods have been used for the deposition and loading of silver nanoparticles onto synthetic and natural textiles, i.e. sonochemical coating, sol-gel process, dip-coating, pad-batch and exhaustion method, the use of nanoporous structure of cellulose fibers as a nanoreactor for
When dealing with modification of textiles by silver it is important to know how the functionalization will affect the color change of fabric. A reflectance (UV/VIS) spectrophotometry is one of the methods to be used when detecting or controlling the presence of silver nanoparticles in a solution or on a textile substrate. It is a direct measure that the abundance of silver is in the topmost layer of the textile fabric . The instrument analyzes the light being reflected from the sample and produces an absorption spectrum. Some of the electrons in the nanoparticles are not bound to the selected atom of silver, but are forming an electronic cloud. Light falling on these electrons excite the collective oscillations, called surface plasmons. The resonance condition is established when the frequency of light photons matches the natural frequency of surface electrons oscillating against the restoring force of positive nuclei. Surface plasmon resonance is the basis of many standard tools for measuring adsorption of material onto planar metal (typically gold and silver) surfaces or onto the surface of metal nanoparticles. It is the fundamental principle behind many color-based biosensor applications. As a result of the particles growth, an intense absorption band at 400 nm to 415 nm caused by collective excitation of all free electrons in the particles was observed . Increase in diameters of the nanoparticles from 1 to 100 nm induces a shift of the surface plasmon absorption band to higher wavelength [50, 57-59]. That means that the size of nanoparticles is defined by their optical response, therefore by that the color that can be seen [50, 60]. Loading of colloidal silver nanoparticles onto bleached cotton fabric caused yellowish coloring of fabric with absorption maximum at 370 nm [24, 30]. The evaluation of color changes of textiles modified by silver nanoparticles was also determined in CIELAB color space . Loading of colloidal silver nanoparticles in concentration of 10 ppm induced very small, eye insensitive, color change (∆E* < 1) to the fabric. When colloidal silver nanoparticles in concentration of 50 ppm were loaded, the color change of fabric was obvious (∆E* = 15.09). Loading of silver onto textiles before or after dyeing also causes color changes; however the changes are not as extensive as with the white fabric. When colloidal silver was loaded before dyeing, the color change was ∆E* = 1.44 and when loaded after dyeing, the color change was ∆E* = 2.73. Color changes of textiles can be also induced by plasma treatment. When plasma is used for a modification of cotton to improve its hydrophilicity, then cotton has a better dyeability and consequently deeper coloration . Also, a raw cotton fabric can be bleached by using ozone plasma . The whiteness index (CIE WI) of fabric was even higher after plasma treatment than after peroxide bleaching (CIE WI O3 = 95.3; CIE WI H2O2 = 94.5).
Since the modification of substrates by plasma improves the adhesion of metal nanoparticles onto substrates than it is no surprise that plasma modification of textiles has a special significance when applying silver nanoparticles. The chapter presents the influence of plasma treatment on loading capacity of cotton toward different forms of nanosilver. Exhaust dyeing process was used for loading of nanosilver onto plasma-treated cotton, which represents a new approach to textile finishing in achieving multifunctional textile properties.
2. Experimental setup and methodology
Low-pressure plasma of different working gases and air atmospheric corona plasma were used for a modification of textiles. Untreated and plasma-treated textile substrates were additionally modified by loading of silver nanoparticles during dyeing process. Morphological, chemical and physical properties of plasma-treated textile substrates were studied using microscopy (SEM), spectroscopy (XPS) and measuring of the breaking strength and elongation of textiles. The quantity of adsorbed silver was determined using mass spectrometry (ICP-MS), while the antibacterial efficiency of functionalized textiles was determined using microbiological tests.
2.1. Plasma modification of textiles
Cotton substrates were modified using different plasma systems, i.e. atmospheric air corona plasma [63-65] and low-pressure inductively coupled radiofrequency (ICRF) discharge plasma of different working gases, water vapor [3, 26, 66, 67] and tetrafluoromethane , respectively. ICRF plasma is particularly suitable for treatment of delicate materials with a large surface for the following reasons: the neutral gas kinetic temperature remains close to the room temperature; the plasma-to-floating potential difference is small; the density of neutral reactive particles is large; and extremely high treatment uniformity is achieved. The use of low-pressure plasma is a contemporary technological process, not yet fully applied in textile industry due to its discontinuous process. For a continuous, on-line processing interfaced to a conventional production line the use of corona atmospheric pressure plasma is recommended. Furthermore, the corona plasma treatment also introduces new functional groups onto fibers surfaces, produces surface cleaning and etching effect of treated textiles. The comparative research of corona plasma treatment of polyester was presented as well .
2.1.1. Low-pressure plasma treatment
A RF generator with a nominal power of 5 kW and a frequency of 27.12 MHz was applied. The power absorbed by plasma, however, was much smaller due to poor matching and was estimated to about 500 W. The discharge chamber was a cylindrical Pyrex tube with a diameter of 27 cm and a length of 30 cm. Cotton fabric was put onto a glass holder mounted in the center of the discharge chamber. After closing the chamber the desired pressure of 0.4 mbar was achieved by a two-stage rotary pump with a nominal pumping speed of 65 m3/h. The pressure was fairly stable during the experiment. Although the ultimate pressure of the rotary pump was below 1 Pa, the pressure remained much higher at 40 Pa. The source of water vapor was the cotton fabric itself. When tetrafluoromethane was used as a working gas, it was leaked into the chamber in order to obtain a pressure of about 100 Pa, the pressure where plasma is most reactive. By switching on the RF generator, the gas in the discharge chamber was partially ionized and dissociated, starting the plasma treatment of the fabric. The plasma treatment time was 10 s in both cases. The schematic diagram of low-pressure RF plasma reactor is presented in Fig. 1.
2.1.2. Atmospheric plasma treatment
Textile samples were treated in a commercial device, Corona-Plus CP-Lab MKII (Vetaphone, Denmark) (Fig. 2). Samples (270 × 500 mm2) were placed on a backing roller (the electrode roll covered with silicon coating), rotating at a working speed of 4 m/min. The distance between electrodes was adjusted with air gap adjusters at both sides of the electrode to 2 mm. Corona discharge was generated within the air gap between the electrode and backing roller. The power was 900 W and the number of passages was set to 30.
2.2. Morphological, chemical and physical properties of untreated and plasma-treated textiles
2.2.1. X-ray photoelectron (XPS) analysis
Information on the chemical composition and chemical bonds of surface atoms of untreated and plasma-treated textile samples was obtained with XPS analysis. During the XPS analysis, a sample is illuminated with monochromatic X-ray light in an XPS spectrometer and the energy of emitted photoelectrons from the sample surface is analyzed. In the photoelectron spectrum, which represents the distribution of emitted photoelectrons as a function of their binding energy, peaks can be observed that may correspond to the elements present on the sample surface up to about 6 nm in depth. From the shape and binding energy of the peaks within XPS spectra, the chemical bonding of surface elements was inferred with the help of data from the literature.
2.2.2. Scanning Electron Microscopy (SEM)
The morphological surface properties of fibers and their changes after plasma treatment were studied using scanning electron microscopy (JEOL SEM type JSM-6060LV). All samples were coated with carbon and a 90% Au/10% Pd alloy layer.
2.2.3. Dynamometer tensile testing
Breaking strength and elongation of untreated and plasma-treated fabrics were analyzed according to the ISO 2062:1997 standard. Instron 6022 was used for this purpose. 100 mm samples of cotton yarn were analyzed using a pre-loading of 0.5 cN/tex and a speed of 250 mm/min. Samples were conditioned according to the ISO 139 standard. Tensile stress (cN/dtex) and elongation ε (%) are the mean values of the measured tensile strength and the elongation of 10 specimens, respectively, in the warp and in the weft directions.
2.3. Modification by dyeing and nanoparticles
For a research three different types of silver nanoparticles were used: silver nanoparticles of known dimensions (Ames Goldsmith Inc.), commercial form RucoBac AGP (Rudolph Chemie) and laboratory synthesized colloidal silver nanoparticles. Silver nanoparticles of known dimensions was medium density mono-dispersed 30 nm silver powder (Silver Nano Powder NP-30) and high density mono-dispersed 80 nm silver powder (Silver Nano Powder NP-80) . The powdered silver nanoparticles are namely intended for a fine line printing (Ink-jet printing) and for electronics use. Because of their purity and known size they are very suitable and important for studies of adhesion to textile materials . The initial concentration of silver powders in the dyeing baths was 20 mg/l. Commercial form of silver nanoparticles RucoBac AGP is a hygienic finish for all fiber types. It is a highly concentrated hygiene and freshness system complying with the Oeko-Tex® standard 100. RucoBac AGP is a nano-dispersion of titanium dioxide (TiO2) as the carrier of the active component silver chloride (AgCl) . The recommended concentration of RucoBac AGP is 0.2–0.5%. Laboratory synthesized colloidal silver nanoparticles were made by a reduction of silver salt in an aqueous solution at room temperature. An amount of 25.5 mg of AgNO3 was dissolved in 750 ml of bi-distilled water, and argon gas was introduced into the solution for 30 min. The reduction was performed with 375 mg of NaBH4 under constant stirring. The solution was kept under an argon atmosphere for another hour .
2.3.2. Dyeing of cotton samples
188.8.131.52. Dyeing with reactive dyes.
Exhaust dyeing with or without the addition of silver nanoparticles [3, 27, 72] was performed on untreated and plasma-treated cotton samples. The dye solutions were separately prepared using two different dyeing concentrations: blank (dyeing without dyestuff) and 0.05% on weight of fabric (owf) of Cibacron Deep Red S-B in liquor ratio 20 : 1. Dyeing baths contained 30 g/l of salt (Na2SO4 anhydrous) and 8 g/l of sodium carbonate (Na2CO3 anhydrous). After the dyeing process, rinsing with distilled water was performed and neutralization with 1 ml/l of 30% acetic acid (CH3COOH). As a soaping agent 1 g/l of CIBAPON R was used.
184.108.40.206. Vat dyeing procedure
Vat dyeing was performed on untreated and plasma-treated cotton samples. The dyed cotton fabrics were post-treated in a colloidal silver solution . A dyeing bath was prepared with 4% owf Bezathren Blau BCE, 15 ml/l NaOH 38°Bé and 3.5 g/l Na2S2O4. The liquor ratio was 83.3 : 1. The dyeing of cotton fabrics was performed at 60°C for 60 min. The dyed samples were rinsed twice in deionised water for 5 min, post-treated in 2 ml/l HCOOH 85% for 5 min and rinsed in deionised water for 5 min.
2.4. Color measurements
Color measurements of differently modified samples were performed after conditioning them according to the ISO 139 standard. CIE standard illuminant D65/10 was used on a Datacolor Spectraflash SF 600-CT reflection spectrophotometer. The aperture diameter of the measuring port of the spectrophotometer was 9 mm.
2.5. Elemental and antimicrobial analysis
The quantity of adsorbed silver was determined using ICP-MS. This technique combines a high-temperature inductively coupled plasma (ICP) source with a mass spectrometer (MS). The antibacterial efficiency of functionalized textiles was determined using microbiological tests according to the ASTM Designation: E 2149–01 method. Antibacterial activity of the cotton fabrics was tested by a certified laboratory against
3. Results and discussion
The influence of different plasma systems on the adhesion of nanoparticles is discussed. The emphasis of the study is to use minimal concentrations, initially, of nanoparticles for loading onto textiles and to achieve maximum quantity on the material. Exhaust dyeing process was used for loading of silver nanoparticles onto textiles. Before applying nanoparticles to any material, its surface needs to be adequately prepared and chemically and morphologically well analyzed. Only good conditions on the substrate surface can provide a qualitative deposition of particles . In literature one can find quotations of XPS analysis of plasma modified cotton substrates which were pre-prepared with various procedures prior to plasma modification (i.e. alkaline boiling, scouring, laundering). But to study plasma modification of cotton it is important to know about the surface changes of substrates that were not cleaned or otherwise pre-prepared. Therefore, the chemical surface changes were evaluated for raw, bleached and bleached/mercerized cotton before and after plasma treatment.
The surface of raw untreated cotton fabric contains a high concentration of carbon and a low concentration of oxygen. This is not characteristic for native cellulose . XPS spectrum C 1s of cellulose also does not include C-C/C-H bonds (Figure 3). The surface of raw cotton is rich in C atoms (C-C/C-H bonds), what could indicate the presence of C-C/ C-H bond rich substances, such as waxes, pectin and proteins. The surfaces of bleached and bleached/mercerized cotton fabrics are alike but very different from raw cotton. Bleached and bleached/mercerized cotton samples are pre-oxidized due to the scouring, bleaching and mercerizing process, and therefore more similar to native cellulose. After modifications with atmospheric air corona plasma and water vapor low-pressure plasma cotton samples contain a higher O/C ratio (the samples contain more of the oxygen and less of the carbon atoms) (Figure 4).
The increase of O/C ratio is expected since plasma interaction with cotton causes the surface oxidation. Changes of C-atom bonds on raw cotton samples after corona and low-pressure plasma treatment are visible in Figure 3 as the ratio of C-O and C=O bonds increased. The results show that increase of relative concentration of C-O bonds is distinctive after corona plasma treatment (41 %) than after low-pressure plasma treatment (23.9 %). It is similar for C=O bonds. The relative concentration of C=O bonds on the surface of raw cotton increases to 16.6 % after corona plasma treatment and to 8.2 % after low-pressure plasma treatment. Both plasma treatments result in a formation of O-C=O bonds. C 1s spectrum of plasma-treated samples resembles to the spectra of native cellulose, which could indicate that plasma selectively removed the noncellulosic parts present on a surface of a raw untreated cotton fabric. After plasma treatment the oxygen content on surface of bleached and bleached/mercerized cotton samples increases. After a treatment with corona plasma the content of oxygen on bleached cotton sample increases from 34.3 at% to 44.5 at%, while the treatment with low-pressure plasma increases oxygen to 36.8 at%. After both plasma treatments the content of C-O remains the same (~55 %), the content of C=O bonds increases and appearance of O-C=O bonds is noticeable. Increase of bonds is distinctive after corona plasma treatment than after low-pressure plasma treatment. Content of C-C/C-H bonds decreases after both plasma treatments. Increase of O/C ratio on plasma-treated bleached/mercerized cotton samples is distinctive after corona plasma treatment, where the oxygen concentration increases to 45.3 at%, while increases to 37.5 at% after low-pressure plasma treatment. Due to oxidation process in plasma, the content of C-C/C-H bonds deceases and the change is more noticeable for bleached/mercerized cotton than for a bleached cotton fabric. For bleached/mercerized cotton sample concentration of C-O bonds is increased in the case of corona plasma treatment, from 47.6 % to 69.3 %, while it remains almost equal after low-pressure plasma treatment (47.8 %). After both plasma treatments the content of C=O bonds increases and appearance of O-C=O bonds is noticeable. These changes are more distinct after low-pressure plasma treatment (20.7 % and 6.8 %) than after corona plasma treatment (15.5 % and 3.9 %). The results summarized in Figure 4 show higher concentration of oxygen on atmospheric air corona and water vapor low-pressure plasma-treated raw cotton than on untreated bleached or bleached/mercerized cotton. From these results it can be concluded that by using plasma technology some of the technological processes of pretreatment of cotton fabrics before dyeing can be avoided. Plasma-treated raw cotton fabric absorbs the same or more of dyestuff as untreated bleached or bleached/mercerized cotton fabric [3, 65, 65, 76]. Reactive dyes are typical anionic dyes containing reactive systems which in alkaline media make bonds with –OH groups of cotton fibers. Increase of dyeability of cotton treated with atmospheric air corona plasma or water vapor low-pressure plasma is correlated to an increase of the number of hydrophilic groups on the surface of the fibers. In Figure 5 the correlation between color differences (expressed as ΔE*) of reactive dyed cotton and differences in O/C ratio (expressed as ΔO/C) of untreated and plasma-treated cotton is presented. The most perceptible changes in color differences (ΔE*) are noticeable when differences in O/C ratio (ΔO/C) are higher. Visible color differences between untreated and water vapor plasma-treated cotton were noticeable for raw (ΔE* = 2.20) and bleached/mercerized cotton (ΔE* = 1.07).
The samples modified in tetrafluoromethane low-pressure plasma (CF4 plasma) gave different results. There was no visible color difference between untreated and CF4 plasma-treated bleached/mercerized cotton samples (ΔE* = 0.62). Both samples were practically equally colored. Treating cotton fabrics for 10 sec with CF4 plasma does not influence their dyeing properties. The results of XPS study show a small increase in the concentration of oxygen after CF4 plasma treatment, but the result is hardly remarkable (Figure 6 and 7).
It is interesting, however, that no fluorine was observed in the XPS spectra, but that the additional ISE analysis indicated the presence of <5 ppm of total fluoride on CF4 plasma-treated samples. Here, it is worth mentioning that we are not the first group to observe little or no fluorine on organic materials treated with CF4 plasma [76, 77]. Although XPS analysis did not show specific chemical surface differences between untreated and CF4 plasma-treated cotton samples, the SEM analysis showed strongly modified surface morphology of plasma-treated cotton (Figure 8), while smaller changes of the surface morphology of cotton samples treated with atmospheric air corona plasma and water vapor low-pressure plasma are noticed.
SEM image of untreated cotton (Figure 8 a) shows a typical grooved surface morphology with macrofibrils oriented predominantly in the direction of the fiber axis. The outlines of the macrofibrils are still visible, and they are smooth and distinct due to the presence of an amorphous layer covering the fiber. The surface of corona plasma-treated cotton has striped, cleaned and more distinct macrofibrilar structure (Figure 8 b). The same effect can be noticeable on the surface of cotton fibers treated with water vapor low-pressure plasma (Figure 8 c). The plasma-treated fiber surface remains grooved and the macrofibrile structure has gained a much sharper outline. The individual macrofibrils (0.2–1 nm) and their transversal connections are visible in the primary cell wall. Between them, narrow voids thinner than 10 nm are noticeable. The surface morphology of CF4 plasma-treated cotton (Figure 8 d) is very different comparing to those treated with water vapor low-pressure or corona plasma. CF4 plasma-treated cotton has an extremely rough and nanostructured surface with dimensions of the grains roughly between 150 and 500 nm. Dissociation energies of plasma molecules are the reason for such rich etched surface. Both CF4 and H2O molecules get dissociated in our plasma . The dissociation energy of CF4 is 12.6 eV  while the ionization energy of CF4 is about 16 eV, which is much higher than the dissociation energy of water vapor or OH molecules, which is at about 5 and 4 eV, respectively. The electrons with energy of few eV are therefore likely to dissociate water and OH molecules rather than dissociate the CF4 molecules. The result is an extremely high dissociation fraction of water molecules and a moderate dissociation fraction of CF4 molecules. Since the partial pressures of water and CF4 are comparable, it can be concluded that the density of O and OH radicals in our plasma is at least as high as the density of CFx radicals if not more so. The textile sample exposed to plasma is therefore subjected to interact with CFx, O, OH, F and H radicals. The density of H is probably as high as that of F so extensive recombination to HF is expected. CFx radicals tend to graft onto the textile, but the grafting probability on cellulose is low compared to the interaction probability with O and OH radicals. O and OH radicals are extremely reactive and cause etching of cellulose. Fluorine atoms are efficient at abstracting hydrogen in the first step of the oxidation reaction. In addition, the presence of fluorine atoms in the plasma enhances the dissociation of the oxygen, further increasing the ashing rates . CF4 is the gas most commonly added to oxygen to enhance the generation of atomic oxygen in plasma and to increase polymer etch rates .
While the surface of plasma-treated cotton was changed, the mechanical properties of cotton fabrics did not alter after plasma modification. The breaking strength and elongation of textiles practically do not change (Figure 9 and 10) [3, 27]. These results are in accordance with the results obtained by other authors [82-85]. Plasma modification of textiles does not impair their mechanical properties.
A textile surface with such extremely rich surface morphology (as seen from SEM) is likely to influence higher adsorption of silver nanoparticles, which is in accordance with our ICP-MS results in Table 1, where the quantity of adsorbed silver onto cotton samples is presented.
From the results summarized in Table 1, it is clear that 30 nm silver nanoparticles are more adhesive to the cotton fabric than 80 nm silver nanoparticles. Regarding their volume, nanoparticles have a high specific surface area. By decreasing the size of a particle, its surface distribution rate increases . The quantity of adsorbed silver on untreated bleached/mercerized cotton was 32 ppm when 30 nm silver nanoparticles were used and 13 ppm when 80 nm silver nanoparticles were used. Similar trend can be observed when cotton was modified with plasma. When cotton was treated with water vapor low-pressure plasma the quantity of adsorbed 30 nm silver nanoparticles was 50 ppm and the quantity of adsorbed 80 nm silver nanoparticles was 17 ppm, which means that adsorption of 80 nm silver nanoparticles was three times lower than the adsorption of 30 nm silver nanoparticles. The results show that plasma heavily modifies the morphology and surface chemical properties of cotton and by that has a great impact on the adsorption of silver nanoparticles onto fabrics. Atmospheric air corona treatment of cotton fabrics enhanced the quantity of silver onto raw cotton up to 4 times and onto bleached/mercerized cotton up to 2 times . The adsorption of 80 nm silver nanoparticles onto CF4 plasma-treated cotton was 2 times higher and onto water vapor plasma-treated cotton was 1.3 times higher than on untreated cotton. These fabrics had a sufficient antimicrobial effectiveness against
|Plasma modification of cotton||Functionalization with silver nanoparticles||Ag quantity (ppm) on cotton||Bacterial reduction (%)|
|Corona air||80 nm||39||–a|
|ICRF water vapor||30 nm||50||52 (
|ICRF CF4||30 nm||54||68 (
Although the purpose of our research was to study the efficiency and appropriateness of plasma modification of textiles in order to achieve a higher adsorption of nanoparticles onto their surfaces, the wash fastness of functionalized textiles was examined as well. Wash fastness test was carried out in a laboratory apparatus Launder-O-Meter [3, 27]. The samples were washed repetitively ten times at 95°C in a solution of 5 g/l of SDC standard detergent and 2 g/l of Na2CO3 (where 10 globules were added). The duration of the washing cycles was 30 min. After every wash cycle, the samples were rinsed twice in distilled water and then for 10 minutes under a tap water, which was followed by squeezing and air drying. In Table 2 the results of silver quantity on washed cotton samples are presented. From the results it can be seen that after ten times washing at 95°C the quantity of silver on the cotton samples decreased (Table 2).
|ICRF water vapor||30 nm||50||26|
|ICRF CF4||30 nm||54||36|
When cotton was modified by water vapor plasma the quantity of 30 nm silver nanoparticles decreased by 48%, and when modified by CF4 plasma the quantity of silver nanoparticles decreased by 34%. The drop in the concentration of silver on the cotton after ten wash cycles is also observed with the 80 nm silver nanoparticles. Cotton that is treated with water vapor plasma loses 41%; however, cotton treated with CF4 plasma loses 15% of the silver nanoparticles. After a 10-second treatment with CF4 plasma, the surface of the bleached/mercerized cotton is more liable to the adsorption of silver nanoparticles than the surface that was modified by the water vapor plasma. The particle adhesion is a complex phenomenon depending on the interaction mechanism between particles and the surface of a material. Adsorption of silver nanoparticles onto cotton from a dyeing bath is much higher for smaller particles than for larger ones. When particles are already on the surface of cotton fibers the attractive interactions and forces are stronger for 80 nm silver nanoparticles than for 30 nm silver nanoparticles. That is the reason for a better wash durability of 80 nm silver particles. From the results presented in Table 1 and 2, it is evident that the quantity of silver on untreated and unwashed cotton is almost the same as on the samples that were modified by plasma and washed 10 times at 95°C.
The further experiments in functionalization of cotton with other forms of silver nanoparticles (i.e. commercial form RucoBac AGP and laboratory synthesized colloidal silver nanoparticles) were based on the obtained adhesion results of silver nanoparticles of known dimensions. The application of RucoBac AGP and synthesized colloidal silver nanoparticles was carried on a bleached/mercerized cotton fabric modified by atmospheric air corona plasma and water vapor low-pressure plasma.
The exhaustion method was used for the deposition of RucoBac AGP onto blank dyed, dyed, plasma-treated blank dyed and plasma-treated dyed cotton samples. 0.1 % of RucoBac AGP was used, which represents a half of the lowest concentration recommended by the agent producer. The reason for such a decision was to verify the possibility in achieving good antibacterial efficiency of a cotton fabric with the use of a very low concentration of silver composite. The liquor ratio was 10 : 1, and the treatment time 30 min at 50 ºC. Afterwards, the samples were dried at 130 ºC for 4 min. The results of the ICP-MS and antimicrobial analysis of samples are presented in Table 3.
0.1 % RucoBac AGP
|ICRF water vapor||11||58 (
|Dyeing with reactive dye and functionalization with
0.1 % RucoBac AGP
|Corona air||8,4||100 (
|ICRF water vapor||13||80 (
The results summarized in Table 3 show low adsorption of silver onto untreated blank dyed cotton. The adsorption of silver onto corona modified cotton did not significantly increase. Both samples do not exhibit the antimicrobial effectiveness. However, treating cotton with water vapor low-pressure plasma increased the adsorption of silver onto cotton up to 7 times, which resulted in an excellent antimicrobial effectiveness against
The objectives for textile industry have been continuous on-line treatments of fabrics. Low-pressure plasma reactors, such as radio frequency powered plasma, provide greater stability and uniformity but generally require more handling of textile materials through the vacuum system than corona discharges at atmospheric pressures. In this respect, the use of corona plasma is more appropriate for the industry. In our following research when laboratory colloidal silver was used, we focused on treating cotton fabric with atmospheric corona plasma. The synthesis of colloidal silver was performed by reducing silver salt in an aqueous solution at room temperature under argon atmosphere. The procedure was described previously, in section 3.2.1. A synthesis of colloidal silver and loading of silver onto cotton fabric was performed as the second phase after dyeing cotton fabrics with a blue vat dye. To verify whether vat-dyeing influences the adsorption of colloidal silver onto cotton fabric, a blank vat-dyeing procedure (dyeing with all chemicals and no dye) was also performed . Apart from indigo, the vat dyes used in dyeing applications are mainly derivatives of anthraquinone and of higher condensed aromatic ring systems with a closed system of conjugated double bonds. They generally contain two, four or six reducible carbonyl groups .
The vat dyes are insoluble in the keto form (Figure 11a). For dyeing they must be transformed to a water soluble enolate (leuko) form (Figure 11c) by a reduction. This form of the dye is appropriate for cellulose dyeing, but the addition of electrolyte is also required. After the dyeing, the dye in amorphous regions is transformed through leuko acid (Figure 11b) into its original water insoluble form by rinsing and oxidation . The vat dyeing of bleached/mercerized cotton fabric before colloidal silver treatment significantly influences the adsorption of silver onto cotton fabrics . Also the adsorption of silver is influenced by an immersion time of cotton into colloidal silver solution. Although it was proven that modification of cotton by corona plasma strongly influences the adsorption of powdered silver nanoparticles by increasing their quantity on the modified cotton, the experiment using synthetized colloidal silver on corona treated cotton had to be conducted. The Table 4 presents the results of ICP-MS and antimicrobial analysis of untreated, corona and vat dyed colloidal silver loaded cotton.
|Dyed and functionalized with colloidal silver||24||100 (
|Corona plasma-treated, dyed and functionalized with colloidal silver||43||100 (
|Corona plasma-treated and functionalized with a half of concentration of colloidal silver||1.6||—a|
|Corona plasma-treated, dyed and functionalized with a half of concentration of colloidal silver||4.6||100 (
The results summarized in Table 4 show that atmospheric air corona treatment enhanced the quantity of silver onto dyed cotton up to 1.8 times comparing to the untreated dyed cotton. In addition to the morphological changes induced by plasma (seen by SEM), XPS analysis showed the increase of C-O and C=O bonds and formation of O-C=O bonds on the surface of treated cotton. The increased concentration of oxygen and newly formed bonds contributed to a better adhesion of Ag+ ions from the colloidal solution onto cellulosic fibers. In addition to the increased number of functional groups containing oxygen, the dyed cotton fabric contains additional anionic sites due to the partial ionization of the molecules of insoluble vat dye. Colloidal silver is produced in a water solution using AgNO3 reduced by NaBH4. NaBH4 also slightly reduces the water insoluble vat dye on the dyed fabric into a slightly soluble form. Although NaBH4 is not a sufficiently strong reducing agent for dyeing cotton with a vat dye , it is nevertheless strong enough to enhance the negative charge of the dye on the fabric  such that silver ions (Ag+) from a silver colloidal solution can be electrostatically attracted to the dyed cotton surface. It was reported that while Ag+ ions from a colloidal silver solution are exhausted to the anionic cotton fibers to a high degree because of the attractive electrostatic interactions, the high increase of the adsorption ability of silver nanoparticles caused by the van der Walls forces resulted from the high surface area to volume ratio of these particles .
The important goal of our research was to use minimal concentrations, initially, of silver nanoparticles for loading onto textiles and to achieve a maximum quantity on the material, and thus to achieve functionalized cotton textile with an excellent antimicrobial efficiency. Since the cotton fabrics already had an excellent antimicrobial efficiency when functionalized with rather low concentration of silver, the decision was made to verify the possibility in achieving good antibacterial efficiency of a cotton fabric with the use of half of the initial concentration of AgNO3 and NaBH4. In this case, the corona plasma modified and undyed cotton contained 1.6 ppm of silver. The quantity of silver was so low that the fabric did not have an antimicrobial efficiency. However, when cotton fabric was modified by corona plasma and then vat dyed the quantity of silver was 4.6 ppm, which gave the fabric an excellent antimicrobial efficiency against
Our research shows that plasma treatment is an effective method to be used in achieving surface changes on the textile material by changing the functional groups on the textile surface and by changing the morphology of the fibers. The results of adsorption of different forms of silver nanoparticles on untreated and plasma-treated surfaces of fabrics confirm the fact that, for nanotechnological processes, the surface of the material has to be properly prepared. The adsorption of metal nanoparticles on textile materials depends on specific chemical and morphological properties of fibers. Plasma modification of cotton had a positive influence on the increased adsorption of silver nanoparticles loaded during exhaust dyeing process. From the bath, which contained a low concentration of silver nanoparticles, we have successfully applied a greater quantity of silver onto plasma modified cotton (up to four times). In some cases using plasma the dyeability of cotton was also improved. We succeeded to create a cotton fabric containing minimal quantity of silver with an excellent antimicrobial efficiency. This is very interesting from the technological point of view since by this method the quantity of silver in wastewater can be dramatically reduced. Another important result of the research was that plasma modification did not impair the mechanical properties of textiles. By using plasma technology new and improved properties of materials can be created that cannot be achieved by standard procedures, where nanostructuring of natural and synthetic fibers is emphasized. The use of plasma for modification of textiles brings to the textile industry many novelties, since plasma technology can be used as a substitute or as a support to the existing technologies, and by that positively influences the economy and ecology of the industrial processes. The knowledge of using plasma technology enables an introduction of contemporary (state-of-the-art) and ecological process of a textile modification into the textile industry and a development of highly technological products with improved or new properties.
This work was financially supported by Slovenian Research Agency (Programme P2-0213 Textile and Ecology), and Eureka Nanovision project.
Kang J.Y., Sarmadi M. Textile Plasma Treatment Review – Natural Polymer-Based Textiles. AATCC Review 2004; 4(10) 28-32.
Gorjanc M., Recelj P., Gorenšek M. Plasma Technology for Textile Purposes. Tekstilec 2007; 50(10-12) 262-266.
Gorjanc M., Bukosek V., Gorensek M., Vesel A. The Influence of Water Vapor Plasma Treatment on Specific Properties of Bleached and Mercerized Cotton Fabric. Textile Research Journal 2010; 80(6) 557-567.
Mozetic M., Cvelbar U., Sunkara M.K., Vaddiraju S. A Method for the Rapid Synthesis of Large Quantities of Metal Oxide Nanowires at Low Temperatures. Advanced Materials 2005; 17(17) 2138-2142.
Levchenko I., Rider A. E., Ostrikov K. Control of Core-shell Structure and Elemental Composition of Binary Quantum Dots. Applied Physics Letters 2007; 90(19) 193110.
Drenik A., Vesel A., Mozetič M. Controlled Carbon Deposit Removal by Oxygen Radicals. Journal of Nuclear Materials 2009; 386-88, 893-895.
Huang S.Y., Arulsamy A.D., Xu M., Xu S., Cvelbar U., Mozetič M. Customizing Electron Confinement in Plasma-Assembled Si/AlN Nanodots for Solar Cell Applications. Physics of Plasmas 2009; 16(12) 123504-1-123504-5.
Mozetic M. Reactive Plasma Technologies in Electronic Industry, Informacije MIDEM 2003; 33(4) 222-227.
Ferreira J.A., Tabares F.L., Tafalla D. Removal of Carbon Deposits in Narrow Gaps by Oxygen Plasmas at Low Pressure. Journal of Vacuum Science and Technology A 2007; 25(4) 746-750.
Shishoo R. Plasma Conquering the Textile Industry. Magazine for European Research 1999; 24, 22-23.
Fridman, A. Plasma chemistry. New York : Cambridge University Press. 2008.
Morent R., De Geyter N., Verschuren J., De Clerck K., Kiekens P., Leys C. Non-thermal Plasma Treatment of Textiles. Surface and Coatings Technology 2008; 202, 3427-3449.
Franceschini D.F., Achete C.A., Freire F.L., Beyer W., Mariotto G. Structural Modifications in a-c-h Films Doped and Implanted With Nitrogen. Diamond and Related Materials 1994; 3(1-2) 88-93.
Chen P., Wang J., Wang B., Li W., Zhang C., Li H., Sun B. Improvement of Interfacial Adhesion for Plasma-Treated Aramid Fiber-Reinforced Poly(Phthalazinone Ether Sulfone Ketone) Composite and Fiber Surface Aging Effects. Surface and Interface Analysis 2009; 41(1) 38-43.
Guo F., Zhang Z.-Z., Liu W.-M., Su F.-H., Zhang H.-J. Effect of Plasma Treatment of Kevlar Fabric on the Tribological Behavior of Kevlar Fabric/Phenolic Composites. Tribology International 2009; 42(2) 243-249.
Jia C., Chen P., Li B., Wang Q., Lu C., Yu Q. Effects of Twaron Fiber Surface Treatment by Air Dielectric Barrier Discharge Plasma on the Interfacial Adhesion in Fiber Reinforced Composites. Surface and Coatings Technology 2010; 204(21-22) 3668-3675.
Liu L., Jiang Q., Zhu T., Guo X., Sun Y., Guan Y., Qiu Y. Influence of Moisture Regain of Aramid Fibers on Effects of Atmospheric Pressure Plasma Treatment on Improving Adhesion with Epoxy. Journal of Applied Polymer Science 2006; 102(1) 242-247.
Bhoj A.N., Kushner M.J. Repetitively Pulsed Atmospheric Pressure Discharge Treatment of Rough Polymer Surfaces: I. Humid Air Discharges. Plasma Sources Science and Technology 2008; 17(3), art. no. 035024.
KinlocH A.J. The Science of Adhesion: Part 1: Surface and Interfacial Aspects. Journal of Materials Science 1980; 15, 2141-2166.
Wu S. Polymer Interface and Adhesion. New York : Marcel Dekker. 1982.
Marsh D.H., Riley D.J., York D., Graydon A. Sorption of Inorganic Nanoparticles in Woven Cellulose Fabrics. Particuology 2009; 7(2) 121-128.
Bozzi A., Yuranova T., Guasaquillo I., Laub D., Kiwi J. X Self-cleaning of Modified Cotton Textiles by TiO2 at Low Temperatures under Daylight Irradiation. Journal of Photochemistry and Photobiology A: Chemistry 2009; 174, 156-164.
Cunko R., Varga K. Application of Ceramics for the Production of High-Performance Textiles. Tekstil 2006; 55(6) 267-278.
Gorensek M., Gorjanc M., Bukosek V., Kovac J., Jovancic P., Mihailovic D. Functionalization of PET Fabrics by Corona and Nano Silver. Textile Research Journal 2010; 80(3) 253-262.
Gorenšek M., Gorjanc M., Bukošek V., Kovač J., Petrović Z., Puač N. Functionalization of Polyester Fabric by Ar/N2 Plasma and Silver. Textile Research Journal 2010; 80(16) 1633-1642.
Gorjanc M., Mozetič M., Gorenšek M. Low-temperature plasma for pretreatment of cotton fabric for better adhesion on nano silver. In: Simončič, B., Gorjanc, M. (eds.). Conference proceedings 19. June 2009. Ljubljana; 2009.
Gorjanc M., Bukošek V., Gorenšek M., Mozetič M. CF4 Plasma and Silver Functionalized Cotton. Textile Research Journal 2010; 80(20) 2204-2213.
Mihailovic D, Saponjic Z., Molina R., Puac N., Jovancic P., Nedeljkovic J., Radetic M. Improved Properties of Oxygen and Argon RF Plasma-Activated Polyester Fabrics Loaded with TiO2 Nanoparticles. ACS Applied Materials and Interfaces 2010; 2(6) 1700-1706.
Tao D., Feng Q., Gao D., Pan L., Wei Q., Wang D. Surface Functionalization of Polypropylene Nonwovens by Metallic Deposition. Journal of Applied Polymer Science 2010; 117(3) 1624-1630.
Yuranova T., Rincon A.G., Bozzi A., Parra S., Pulgarin C., Albers P., Kiwi J. Antibacterial Textiles Prepared by RF-Plasma and Vacuum-UV Mediated Deposition of Silver. Journal of Photochemistry and Photobiology A-Chemistry 2003; 161 (1) 27-34.
Pedrosa P., Chappe J.-M., Fonseca C., Machado A. V., Nobrega J.M., Vaz F. Plasma Surface Modification of Polycarbonate and Poly(propylene) Substrates for Biomedical Electrodes. Plasma Processes and Polymers 2010; 7(8) 676-686.
Junkar I., Vesel A., Cvelbar U., Mozetič M., Strnad S. Influence of Oxygen and Nitrogen Plasma Treatment on Polyethylene Terephthalate (PET) Polymers. Vacuum 2009; 84 (1) 83-85.
Borcia C., Dumitrascu N. Adhesion Properties of Polyamide-6 Fibres Treated by Dielectric Barrier Discharge. Surface and Coatings Technology 2006; 201, 1117-1123.
Qi K., Xin J.H., Daoud W.A., Mak C.L. Functionalizing Polyester Fiber with a Self-cleaning Property using Anatase TiO2 and Low-Temperature Plasma Treatment. International Journal of Applied Ceramic Technology 2007; 4(6) 554-563.
Mejia M.I., Marin J.M., Restrepo G., Pulgarin C., Mielczarski E., Mielczarski J., Arroyo Y., Lavanchy J.-C., Kiwi J. Self-cleaning Modified TiO2-cotton Pretreated by UVC-light (185 nm) and RF-plasma in Vacuum and also under Atmospheric Pressure. Applied Catalysis B-environmental 2009; 91(1-2) 481-488.
Szymanowski H., Sobczyk A., Gazicki-Lipman M., Jakubowski W., Klimek L. Plasma enhanced CVD deposition of titanium oxide for biomedical applications. Surface and coatings technology, 2005; 200(1-4) 1036-1040.
Ilic V., Saponjic Z., Vodnik V., Molina R., Dimitrijevic S., Jovancic P., Nedeljkovic J., Radetic M. Antifungal Efficiency of Corona Pretreated Polyester and Polyamide Fabrics Loaded with Ag Nanoparticles. Journal of Materials Science 2009; 44(15) 3983-3990.
Gorenšek M., Recelj P. Reactive Dyes and Nano-silver on PA6 Micro Knitted Goods. Textile Research Journal 2009; 79(2) 138-146.
Kvitek L., Panacek A., Soukupova J., Kolar M., Vecerova R., Prucek R., Holecova M., Zboril R. Effect of Surfactants and Polymers on Stability and Antibacterial Activity of Silver Nanoparticles (NPs). Journal of Physical Chemistry C 2008; 112(15) 5825-5834.
Tomšič B., Simončič B., Cvijn D., Orel B., Zorko M., Simončič A. Elementary Nano Sized Silver as Antibacterial Agent. Tekstilec 2008; 51(7-9) 199–215.
Vertelov G., Krutyakov Y., Efremenkova O., Olenin A., Lisichkin G. A Versatile Synthesis of Highly Bactericidal Myramistin Stabilized Silver Nanoparticles. Nanotechnology 2008; 19(35) art.no. 355707.
Choi O., Deng K., Kim N., Ross L., Surampalli R., Hu Z. The Inhibitory Effects of Silver Nanoparticles, Silver Ions and Silver Chloride Colloids on Microbial Growth. Water Research 2008; 42(12) 3066-3074.
Klemenčič D., Simončič B., Tomšič B., Orel B. Biodegradation of Silver Functionalised Cellulose Fibers. Carbohydrate Polymers 2010; 80, 426-435.
Tomšič B., Simončič B., Žerjav M., Simončič A. A Low Nutrition Medium Improves the Determination of Fungicidal Activity of AgCl on Cellulose Fibres. Tekstilec 2008; 51(7-9) 231-241.
Tomšič B., Simončič B., Orel B., Žerjav M., Schroers H.-J., Simončič A., Samardžija Z. Antimicrobial Activity of AgCl Embedded in a Silica Matrix on Cotton Fabric. Carbohydrate Polymers 2009; 75(4) 618-626.
Gavriliu S., Lungu M., Enescu E., Gavriliu L. Composite Nanopowder for Antibacterial Textiles. Industria Textila 2010; 61(2) 86-90.
Yuranova T., Rincon A. G., Pulgarin C., Laub D., Xantopoulos N., Mathieu H.-J., Kiwi J. Performance and Characterization of Ag-cotton and Ag/TiO2 Loaded Textiles during the Abatement of E. coli. Journal of Photochemistry and Photobiology A-chemistry 2006; 181(2-3) 363-369.
Rimai D.S., Quesnel D.J., Busnaina A.A. The Adhesion of Dry Particles in the Nanometer to Micrometer-size Range. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2000; 165(1-3), 3-10.
Dastjerdi R., Mojtahedi M.R.M., Shoshtari A.M. Investigating the Effect of Various Blend Ratios of Prepared Masterbatch Containing Ag/TiO2 Nanocomposite on the Properties of Bioactive Continuous Filament Yarns. Fibers and Polymers 2008; 9(6) 727-734.
Dubas, S.T., Kumlangdudsana, P., Potiyaraj, P. Layer-by-layer Deposition of Antimicrobial Silver Nanoparticles on Textile Fibers. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2006; 289(1-3) 105-109.
Hadad L., Perkas N., Gofer Y., Calderon-Moreno J., Ghule A., Gedanken A. Sonochemical Deposition of Silver Nanoparticles on Wool Fibers. Journal of Applied Polymer Science 2007; 104(3) 1732-1737.
He J.H., Kunitake T., Nakao A. Facile in situ Synthesis of Noble Metal Nanoparticles in Porous Cellulose Fibers. Chemistry of Materials 2003; 15(23) 4401-4406.
Hegemann D., Hossain M.M., Balazs D.J. Nanostructured Plasma Coatings to Obtain Multifunctional Textile Surfaces. Progress in Organic Coatings 2007; 58(2-3) 237-240.
Moazami A., Montazer M., Rashidi A., Rahimi M.K. Antibacterial Properties of Raw and Degummed Silk with Nanosilver in Various Conditions. Journal of Applied Polymer Science 2010; 118(1) 253-258.
Gorensek M., Recelj P. Nanosilver Functionalized Cotton Fabric. Textile Research Journal 2007; 77(3) 138-141.
Jiang S.X., Qin W.F., Zhang L. Surface Functionalization of Nanostructured Silver-Coated Polyester Fabric by Magnetron Sputtering. Surface and Coatings Technology 2010; 204(21-22) 3662-3667.
Malinsky M.D., Kelly K.L., Schatz G.C., Van Duyne R.P. Chain length dependence and sensing capabilities of the localized surface plasmon resonance of silver nanoparticles chemically modified with alkanethiol self-assembled monolayers, J. Am. Chem. Soc., 123 (2001), pp. 1471–1482.
Bosbach J., Hendrich C., Stietz F., Vartanyan T., Trager F. Ultrafast Dephasing of Surface Plasmon Excitation in Silver Nanoparticles: Influence of Particle Size, Shape, and Chemical Surrounding. Physical Review Letters 2002; 89(25) art.no. 257404.
Mock J.J., Barbic M., Smith D.R., Schultz D.A., Schultz S. Shape Effects in Plasmon Resonance of Individual Colloidal Silver Nanoparticles. Journal of Chemical Physics 2002; 116(15) 6755-6759.
Ilic V., Saponjic Z., Vodnik V., Potkonjak B., Jovancic P., Nedeljkovic J., Radetic M. The Influence of Silver Content on Antimicrobial Activity and Color of Cotton Fabrics Functionalized with Ag Nanoparticles. Carbohydrate Polymers 2009; 78 (3) 564-569.
Carneiro N., Souto A.P., Silva E., Marimba A., Tena A., Ferreira H., Magalhaes V. Dyeability of Corona-Treated Fabrics. Coloration Technology 2001; 117, 298-302.
Navarro, A., Bautista, L. Surface modification and characterization in cotton fabric bleaching. Proceedings of 5th world textile conference AUTEX 2005. Maribor; 2005.
Gorjanc M., Jovančić P., Bukošek V., Gorenšek M. Study of adsorption of nano silver on cotton pretreated with plasma. Proceedings of the 9th Autex, Izmir, Turkey; 2009.
Gorjanc M., Jovančić P., Gorenšek M. Nano silver on cotton. In: Mihailović D., Kobe S., Remškar M., Jamnik J., Čopič M., Drobne D. (eds.). Hot nano topics 2008 : incorporating SLONANO 2008, 3 overlapping workshops on current hot subjects in nanoscience, 23-30 May, Portorož, Slovenia : abstract book. Ljubljana; 2008.
Gorjanc M., Jovančić P., Kovač J., Bukošek V., Gorenšek M. Plasma treatment of cotton: correlation between dyeability of cotton with reactive dye and chemical composition of surfaces. In: XXII IFATCC International congress (International Federation of the Association of Textile Chemists and colorists), Lago Magiore (Italy), May 5-7th, 2010. From textile chemistry to fashion : multifunctionality, sustainability, competitivity : proceedings of the XXII IFATCC International congress, Stresa, Lago Magiore. Milano: Associazione Italiana di Chimica Tessile e Coloristica: = AICTC Italia; 2010.
Gorjanc M., Mozetič M., Bukošek V., Gorenšek M. Impact of low-pressure plasma on dyeability of cotton. In: Dragčević Z. (ed.) 4th International Textile, Clothing & Design Conference [also] ITC&DC, October 5th to October 8th, 2008, Dubrovnik, Croatia. Magic world of textiles : book of proceedings. Zagreb: Faculty of Textile Technology, University of Zagreb; 2008.
Gorjanc M., Mozetič M., Gorenšek M. Low-pressure plasma for pretreatment of cotton fabric for better adhesion of nanosilver. Tekstilec 2009; 52(10-12) 263-269.
Ames Goldsmith - Silver nano powders. Data sheet, 2005. http://www.amesgoldsmith.com/products/silver-nano-powders.asp/ (accessed 25 February 2011).
Gorjanc M. Plasma Modification of Cotton Surfaces for a Deposition of Nanosilver. PhD thesis. University of Ljubljana, Faculty of Natural Sciences and Engineering; 2011.
The ultimate hygenic finish for textiles. Rudolph Chemie, Rudolph Info 5/07; 2007.
Gorjanc M., Kovač F., Gorenšek M. The Influence of Vat Dyeing on the Adsorption of Synthesized Colloidal Silver onto Cotton Fabrics. Textile Research Journal 2012; 82(1) 62-69.
Gorjanc M., Gorenšek M. Influence of Dyeing Cotton with Reactive Dye on Adsorption of Silver. Tekstilec 2011; 54(10-12) 228-237.
Doering R., Nishi Y. Handbook of Semiconductor Manufacturing Technology. Boca Raton : CRC Press; 2000.
Johansson L.S., Campbell J.M., Stenius P., Pere J., Buchert T. Surface Characterization of Cellulosic Materials with XPS. Abstracts of Papers of the American Chemical Society 2001; 221 (Part I) U180-U180.
Gorjanc M., Mozetič M., Jazbec K., Gorenšek M. Influence of ICRF water vapour plasma on dyeability and UPF of cotton fabrics. In: Simončič B., Hladnik A., Pavko-Čuden A., Ahtik J., Luštek Preskar B., Demšar A., Urbas R. (eds.). 41st International Symposium on Novelties in Textiles and 5th International Symposium on Novelties in Graphics and 45th International Congress IFKT, Ljubljana, Slovenia, 27-29 May 2010. Symposium proceedings. Ljubljana: Faculty of Natural Sciences and Engineering, Department of Textiles; 2010.
Tsafack M.J., Levalois-Grutzmacher J. Towards Multifunctional Surfaces using the Plasma-Induced Graftpolymerization (PIGP) Process: Flame and Waterproof Cotton Textiles. Surface and Coatings Technology 2007; 201(12): 5789-5795.
McCord M.G., Hwang Y.J., Qui Y., Hughes L.K. Bourham M.A. Surface Analysis of Cotton Fabrics Fluorinated in Radio-Frequency Plasma. Journal of Applied Polymer Science 2003; 88(8), 2038-2047.
Cvelbar U., Krstulovic N., Milosevic S., Mozetic M. Inductively Coupled RF Oxygen Plasma Characterization by Optical Emission Spectroscopy. Vacuum 2007; 82(2) 224-227.
Kurihara M., Petrovic Z., Makabe T. Transport Coefficients and Scattering Cross-Sections for Plasma Modelling in CF4-Ar Mixtures: a Swarm Analysis. Journal of Physics D-Applied Physics 2000; 33(17); 2146-2153.
Flamm D.L. Mechanisms of Radical Production in CF3Cl, CF3Br, and Related Plasma Etching Gases: The role of Added Oxidants. Plasma Chemistry and Plasma Processing 1981; 1(1) 37-52.
d’Agosiono R. Plasma Deposition, Treatment, and Etching of Polymers. San Diego: Academic Press Inc; 1990.
Poll, H.U., Schladitz, U., Schreiter, S. Penetration of Plasma Effects into Textile Structures. Surface and Coatings Technology 2001; 142, 489-493.
Hwang Y.J., McCord M.G., An J.S., Kang B.C., Park S.W. Effects of Helium Atmospheric Pressure Plasma Treatment on Low-Stress Mechanical Properties of Polypropylene Nonwoven Fabrics. Textile Research Journal 2005; 78(11) 771-778.
Yip J., Chan K., Sin K.M., Lau K.S. Study of Physico-Chemical Surface Treatments on Dyeing Properties of Polyamides. Part 1: Effect of Tetrafluoromethane Low Temperature Plasma. Coloration Technology 2002; 118(1) 26-30.
Sun D., Stylios G.K. Investigating the Plasma Modification of Natural Fiber Fabrics - the Effect on Fabric Surface and Mechanical Properties. Textile Research Journal 2005; 75(9) 639-644.
Owens F.J., Poole Jr., C.P., editors. The physics and chemistry of nanosolids. New Jersey: Wiley & Sons, Inc.; 2008.
Kawabata A., Taylor J.A. Effect of Reactive Dyes upon the Uptake and Antibacterial Action of Poly(Hexamethylene Biguanide) on Cotton. Part 1: Effect of Bis(Monochlorotriazinyl) Dyes. Coloration Technology 2004; 120(5) 213-219.
Preston C., editor. The Dyeing of Cellulosic Fibers. London: Dyers’ Company Publications Trust; 1986.
Gorenšek M. Dyes and textile colour. In: Jeler S. (ed.) Textile and colour. Firenze: Edizioni Tassinari; 2004. P5-19.
Shore J. Cellulosics Dyeing. Bradford : Society of Dyers and Colourists; 1995.
Nair, G.P., Shah, R.C. Sodium Borohydride in Vat Dyeing. Textile Research Journal 1970; 40(4) 303-312.
Klemenčič D., Simončič B., Tomšič B., Orel B. Biodegradation of Silver Functionalized Cellulose Fibres. Carbohydrate Polymers 2010; 80, 426-435.