The methane gas adsorption capacity of various MOFs under different pressures conditions [38, 43, 44].
\r\n\tThere will be a chapter on secondary causes of sexual dysfunction disorders related to diabetes, cardiovascular disease, and obesity. A chapter on remedial measures to enhance sexual activity and maintain human relationships will be discussed. As there is a growing number of cancer survivors a chapter on cancer-related sexual dysfunction will be welcomed for including it.
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Dr. Sheriff has authored five books including a textbook on medical biochemistry with additional interest in human sexology. He had editorials written in the British Journal of Sexology, Journal of Royal Society of Medicine, Postgraduate Medicine, and Scientist. 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So far, the Least Mean Square (LMS) and its normalized version (NLMS) adaptive algorithms have been the most commonly adopted approaches owing to the clarity of the mean-square-error cost function in terms of statistical concept and the simplicity for computation. It is known that the NLMS algorithm gives better convergence characteristics than the LMS because it uses a variable step-size parameter in which the variation is achieved due to the division, at each iteration, of the fixed step size by the input power. However, a critical issue associated with both algorithms is the choice of the step-size parameter that is the trade-off between the steady-state misadjustment and the speed of adaptation. Recent studies have thus presented the idea of variable step-size NLMS algorithm to remedy this issue [4-7]. Also, many other adaptive algorithms [8, 9] have been defined and studied to improve the adaptation performance. In this work, the proposed approach of randomizing the NLMS algorithm’s step-size has been introduced in the adaptation process of bothchannel equalisation and system identification, and tested over a defined communication channels. The proposed random step-size approach yields an algorithm with good convergence rate and steady state stability.
The objective of this chapter is analyzing and comparing the proposed random step-size NLMS and the standard NLMS algorithms that were implemented in the adaptation process of two fundamental applications of adaptive filters, namely adaptive channel equalization and adaptive system identification. In particular, we focus our attention on the behavior of Mean Square Error (MSE) of the proposed and the standard NLMS algorithms in the two mentioned applications. From the MSE performances we can determine the speed of convergence and the steady state noise floor level. The key idea in this chapter is that a new and simple approach to adjust the step-size () of the standard NLMS adaptive algorithm has been implemented and tested. The value of is totally controlled by the use of a Pseudorandom Noise (PRN) uniform distribution that is defined by values from 0 to 1. Randomizing the step-size eliminates much of the trade-off between residual error and convergence speed compared with the fixed step-size. In this case, the adaptive filter will change its coefficients according to the NLMS algorithm in which its step-size is controlled by the PRN to pseudo randomize the step size. Also this chaptercovers the most popular advances in adaptive filtering which include adaptive algorithms, adaptive channel equalization, and adaptive system identification.
In this chapter, the concept of using random step-size approach in the adaptation process of the NLMS adaptive algorithm will be introduced and investigated. The investigation includescalculating and plotting the MSE performance of the proposed algorithm in system identification and channel equalization and compares the computer simulation results with that of the standard NLMS algorithm.
The organization of this chapter is as follows: In Section 2 an overview of adaptive filters and their applications is demonstrated. Section 3 describes the standard NLMS and the proposed random step size NLMS algorithms. In Sections 4 the performance analysis of adaptive channel equalization and adaptive system identification are given. Finally the conclusion and the list of references are given in Sections 5 and 6, respectively.
An adaptive filter generally consists of two distinct parts: a filter, whose structure is designed to perform a desired processing function, and an adaptive algorithm for adjusting the coefficients of that filter. The ability of an adaptive filter to operate satisfactory in an unknown environment and track time variations of input statistics make the adaptive filter a powerful device for signal processing and control applications [1].
Adaptive filters are self learn. As the signal into the filter continues, the adaptive filter coefficients adjust themselves to achieve the desired result, such as identifying an unknown filter or cancelling noise in the input signal. Figure 1 represents the adaptive filter, comprising the adaptive filter and the adaptive weight control mechanism. An adaptive Finite Impulse Response (FIR) filter or Infinite Impulse Response (IIR) filter designs itself based on the characteristics of the input signal to the filter and a signal which represent the desired behavior of the filter on its input. Designing the filter does not require any other frequency response information or specification. To define the self learning process the filter uses, you select the adaptive algorithm used to reduce the error between the output signal
The ability of an adaptive filter to operate satisfactorily in an unknown environment and track time variations of input statistics make the adaptive filter a powerful device for signal processing and control applications [12]. In fact, adaptive filters have been successfully applied in such diverse fields as communications, radar, sonar, seismology, and biomedical engineering. Although these applications are quite different in nature, however, they have one basic common aspect: an input vector and a desired response are used to compute an estimation error, which is in turn used to control the values of a set of adjustable filter coefficients. The fundamental difference between the various applications of adaptive filtering arises in the way in which the desired response is extract.
In many applications requiring filtering, the necessary frequency response may not be known beforehand, or it may vary with time. (for example; suppression of engine harmonics in a car stereo). In such applications, an adaptive filter which can automatically design itself and which can track system variations in time is extremely useful. Adaptive filters are used extensively in a wide variety of applications, particularly in telecommunications. Despite that adaptive filters have been successfully applied in many communications and signal processing fields including adaptive system identification, adaptive channel equalization, adaptive interference (Noise) cancellation, and adaptive echo cancellation, the focus here is on their applications in adaptive channel equalisation and adaptive system identification.
Adaptive filter algorithms have been used in many signal processing applications [1]. One of the adaptive filter algorithms is the normalized least mean square (NLMS), which is the most popular one because it is very simple but robust. NLMS is better than LMS because the weight vector of NLMS can change automatically, while that of LMS cannot [2]. A critical issue associated with all algorithms is the choice of the step-size parameter that is the trade-off between the steady-state misadjustment and the speed of adaptation. A recent study has presented the idea of variable step-size LMS algorithm to remedy this issue [4].Nevertheless, many other adaptive algorithms based upon non-mean-square cost function can also be defined to improve the adaptation performance. For example, the use of the error to the power Four has been investigated [8] and the Least-Mean-Fourth adaptive algorithm (LMF) results.Also, the use of the switching algorithm in adaptive channel equalization has also been studied [9].
General targets of an adaptive filter are rate of convergenceand misadjustment. The fast rate of convergence allows the algorithm to adapt rapidly to a stationary environment of unknown statistics, but quantitative measure by which the final value of mean-square error (MSE) is averaged over an ensemble of adaptive filters, deviates from the minimum MSE more severely as the rate of convergence becomes faster, which means that their trade-off problem exists.
The least mean square (LMS) algorithm has been widely used for adaptive filters due to its simplicity and numerical robustness. On the other hand, NLMS algorithmis known that it gives better convergence characteristics than the LMS, because the NLMS uses a variable step-size parameter in which, in each iteration, a step-size fixed parameter is divided by the input power. Depending on the value of the fixed step-size parameter, however, the LMS and NLMS algorithms result in a trade-off between the convergence speed and the mean square error (MSE) after convergence [5].
A general form of the adaptive filter is shown in Figure 1, where an input signal
Block diagram of adaptive transversal filter
The weight vector of an adaptive filter should be changed in a minimal manner, subject to a constraint imposed on the updated filter’s output. The NLMS adaptive filter is a manifestation of the principal of minimal disturbance from one iteration to the next [10]. To describe the meaning of NLMS as an equation, let
Subject to the constraint
The method of the lagrange multiplier is used to solve this problem as:
The unknown multiplier, λ, can be obtained by substituting (3) into (2):
Where
Then, combining (3) and (4) to formulate the optimal value of the incremental change,
Equation (6) can be written as:
Where the constant
The stability of the NLMS algorithm depends on the value of its step-size, and thus its optimization criterion should be found [12]. The desired response has been set as follows:
Where
Substituting (9) into (7) yields:
To study the stability performance of adaptive filters, the mean-square deviation may be identified [11].
Where
where
The bounded range of the normalized step-size parameter can be found from (12) as:
For the case of real-valued data, the following equation can be used:
Substituting (15) into (14) yields:
where
Using the proposed idea of randomizing the step size, the step-size for the NLMS algorithm is changed into a variable one, where the fixed step size is multiplied by PN (pseudo random number generator) being a selection from random numbers of uniform distribution [01] at each iteration time. Formulating the Pseudo-random NLMS algorithm results:
Where
The step-size
Adaptive channel equalizationin digital communication systems is perhaps the most heavily exploited area of application for adaptive filtering algorithms. Adaptive filtering algorithms have been widely applied to solve the problem of channel equalization in digitalcommunication systems. This is because, firstly, the adaptation of tap weights of an equalizer is necessary to perform channel equalization tasks successfully and secondly, the development of an adaptive algorithm that allows fast weight modification, while improving the estimation performance of the equalizer, will enhance the capability of suchequalization systems in real applications.
The block diagram of the considered system is shown in Figure 2 below:
The block diagram of the considered system
The input signal is Binary phase shift keying which has two phases (0 and ) so the signal is limited between 1 and -1. The general equation for a sum of weighted time delayed Telephone channel impulse responses can be written as
Two types of channels are considered here, the minimum phase (CH-1) and the non-minimum phase (CH-2) channels, which are given, respectively, below:
The discrete time model for the adaptive channel equalization considered in this paper is depicted in Figure 3.
The block diagram of the adaptive channel equalization
In a transversal adaptive filter, the input vector Un and the weight vector Wn at the time of nth iteration are defined as follows:
Where un is the filter input and wi, (i=0, 1, …, M-1) is the weight vector which corresponds to the filter length.The filter output is obtained as follows:
The error signal e(k), involved in the adaptive process, is defined by
Where w(k) is the tap-weight vector of the adaptive filter assumed to have a transversal structure.
This section introduces adaptive filters through the application of system identification using the NLMS and the random step-size NLMS algorithms. The adaptive filter adjusts its coefficients to minimize the mean-square error between its output and that of an unknown system.The objective is to change (adapt) the coefficients of an FIR filterto match as closely as possible the response of an unknown system.
Consider the system identification problem illustrated in Figure 4. The Figure shows the discrete time model for the FIR system identification. One common application is to use adaptive filters to identify an unknown system, such as the response of an unknown communications channel. An unknown FIR system with N-point impulse response vector w(n) has an input sequence {u(n)} and an output sequence {d(n)}. The input signal is binary phase shift keying (BPSK) which has two phases (0 and) so the signal is limited between 1 and -1. The general formula for a sum of weighted time delayed channel impulse response can be written as:
The desired response d(n), providing a frame of reference for the adaptive filter, is defined by:
Where U(n) is the input vector, which is common to both the unknown system and the adaptive filter and v(n) is the Additive White Gaussian Noise (AWGN) with zero mean and variance 2. First the error signal, e (n), is computed which measures the difference between the output of the adaptive filter and the output of the unknown system. On the basis of this measure, the adaptive filter will change its coefficients in an attempt to reduce the error.
Hence the error signal,e(n), involved in the adaptive process, is defined by:
where W^(n) is the tap-weight vector of the adaptive filter assumed to have a transversal structure.
System identification model using linear transversal adaptive filter
Clearly, when e(n) is very small, the adaptive filter response is close to the response of the unknown system. Application of the Wiener filter to this problem involves constructing an estimate y(n) of the observed output d(n) by passing the observed input sequence u(n) through a system modeling filter with impulse response vector w(n). The impulse response of the system model is chosen to minimize the MSE. It is assumed that the adaptive filter has the same number of taps as the unknown system represented by w(n).
This section presents the computer simulations results of the performance of the non-linear transversal equalizer adapted by NLMS algorithm and the proposed pseudo-randomized NLMS algorithm [13]. The system was tested over both minimum phase and non-minimum phase channels, which are defined, respectively, as follows:
The digital signal transmitted through the channel was bipolar BPSK with values of 1 and the channel was corrupted by AWGN with SNR = 30dB. The order of the filter was set to 12 for both minimum phase, H1(z), and non-minimum phase, H2(z), channels. The step size for the NLMS algorithm was chosen from (0.01) to (0.1) and the number of transmitted bits equals to 2500 bits. The comparison between the two algorithms, the standard NLMS and the pseudo random step size NLMS, is done by first choosing the best step size that gives fast convergence and then uses this step size for the comparison.
Figure 5, shown below, shows that the step size with a value of 0.05 gives the fast convergence rate over the minimum phase channel (CH-1) while over the non-minimum phase channel (CH-2) the step size with a value of 0.01 gives the fast convergence rate. The comparison also looks at the effects of decreasing the SNR from 25 dB to 5 dB.While Figures 6 – 8, shown below, show the performances of the mean square error against the number of iterations for various values of signal-to-noise ratios using non-linear transversal equalizer over the minimum phase channel. From these figures it is clear that the speed of convergence has approximately the same convergence rate for both algorithms but the ground noise floor level decreases when the SNR decreases in the case of using the random step-size NLMS algorithm. The same conclusion has been noticed in the case of using the non-minimum phase channel that defined in (32) above. This is due to that the step-size parameter of the proposed random NLMS algorithm is designed based on utilizing the random distribution which made the error sequence accelerates the level of the noise floor to a much lower value compared to that of the standard NLMS algorithm with a fixed step-size value.Results for CH-2 are not included here due to space limitation.
MSE performances of the NLMS for various step-sizes over CH-1
MSE performances of the two algorithms for SNR=15dB over CH-1
MSE performances of the two algorithms for SNR=10 dB over CH-1
MSE performances of the two algorithms for SNR=5 dB over CH-1
This section presents the computer simulations results of the performance of fixed and random step-size NLMS algorithms used in system identification [14]. The following two equations represent the coefficient vector of the unknown system (to be identified by the adaptive filter) and its transfer function, respectively.
The unknown system output is disturbed by an uncorrelated zero-mean white Gaussian noise. The digital message applied to the channel is in random bipolar with the values of 1. The channel output is corrupted by a white Gaussian noise with zero mean and a variance of 0.01. The performance is determined by taking an average of 100 independent experimental simulations to demonstrate the mean-square error (MSE) performance of the proposed algorithm. The signal to noise ratio is set to 20 dB. Finally, the simulated systems have been implemented using Matlab codes. Figs. 9 & 10 show the MSE performances of the NLMS algorithm for various fixed step-sizes.
On the other hand Figs. 11-13, compare the MSE performances of the NLMS algorithm in the cases of fixed step-sizes of 0.5, 0.9, and 1.3 against the random step-size NLMS algorithm. It is clearly shown that the MSE performance of the NLMS algorithm using random step-size approach outperforms the fixed step-size algorithm’s performance, especially with large step-sizes.
MSE performance of the NLMS algorithm for various step-sizes (mu)
MSE performance of the NLMS algorithm for various step-sizes (mu)
MSE performances of fixed and randomstep-size NLMS algorithms
MSE performances for fixed and randomstep-size NLMS algorithms
MSE performances for fixed and randomstep-size NLMS algorithms
The proposed idea of using random step-size approach in the adaptation of the NLMS algorithm has been implemented and tested in the adaptation process of both channel equalization and system identification. The tests measure the MSE performance of using both the standard NLMS and the random step-size NLMS algorithms in the above mentioned applications. An extensive investigation, to determine the NLMS algorithm’s best fixed step size, has been carried out over the defined channels. And a comparison between the performances of using the NLMS with a fixed step-size and a pseudo random step-size approaches has been carried out which shows the trade off between the convergence speed and the noise floor level.
It can be concluded, in the case of adaptive channel equalization, that the performance of using the random step-size outperforms the performance of the fixed step-size by achieving much lower ground noise floor, especially at low signal-to-noise ratios while maintaining a similar convergence rate.
In the case of adaptive system identification, the performance of using the random step-size outperforms the performance of that of fixed step-size NLMS adaptive algorithm and achieved lower ground noise floor, especially at larger step-sizes.
The values of the step-size parameter of the proposed random NLMS algorithm are based on utilizing the random uniform distribution which made the error sequence accelerates the MSE’s level of the noise floor to a much lower value compared to that of the standard NLMS algorithm with a fixed step-size value.
The author would like to acknowledge the contributions of Mr. N. Al-Saeedi [13] towards getting some results related to the channel equalization and Dr. T. Shimamura [14] for his contribution towards discussing the idea of using the random step-size approach in system identification.
The well-known alternative fuels for crude oil-based liquid products are natural gas and hydrogen. Nevertheless, these gaseous fuels require a special storage technique for effective utilization due to their lower volumetric energy density values. Natural gas with wide availability and improved production technology is considered to be an important energy source for the future and a cleaner form of energy compared to that of the higher hydrocarbon-based fuels such as gasoline and diesel due to its low C/H ratio. This consists of mainly methane (55–98 vol%) as the primary component along with other gases such as ethane (2–4 vol%), propane (0.5–2 vol%), and butane (0.25–0.5 vol%) in minor amounts along with few acid gases in trace amounts [1]. An estimate has shown that natural gas produces 55.9 kg CO2/GJ of energy, which is lower than that of anthracite coal (91.3 CO2/GJ), gasoline (78.5 CO2/GJ), and diesel (73.3 CO2/GJ) [2]. Therefore, among the several areas of attention for further technological advances in the natural gas domain, storage, utilization, and supply chain are prominent in the downstream sector. The concept of natural gas storage is old and typically produced and, in some cases, the processed gas is stored in an underground facility in the vicinity of the supply center. The stored gas is regularly monitored for potential loss and emission reliability of the supply chain to meet the customer demand is an important parameter for this form of energy [3]. The current issues related to the environment has led to adopting effective measures to handle major pollution sources and the transportation sector is considered as one of the important one among these. The use of natural gas owing to wide availability and its lower carbon emission compared to that of the higher hydrocarbons as fuel for vehicular application is projected to control the pollution level to a certain extent. Natural gas in two forms are utilized as vehicle fuel, i.e. compressed natural gas (CNG) and liquefied natural gas (LNG). The CNG is especially important for light vehicle transport such as cars and other cargo transporting vehicles, whereas the LNG form is utilized in industries and manufacturing along with domestic applications. However, these systems suffer from the limitations of high cost, low storage efficiency, and safety issues.
To improve the efficiency of the process, the concept of adsorbed natural gas (ANG) originated, in which the natural gas was stored in a comparatively high amount in a porous adsorbent system under ambient temperature conditions. In this process, the methane is believed to be adsorbed in molecular form in the nanosized pores of the adsorbent network and the density in the adsorbed form exceeds the bulk density. The adsorption process being exothermic typically depended on the thermodynamic conditions. The amount of adsorption increased with a decrease in temperature and an increase in pressure. The ANG is considered to be a cost-effective alternative compared to that of liquefaction and energy-intensive compression. The storage pressure in this scenario can be decreased to ~35 bar compared to that of the utilized in CNG technology (200 bar) [4]. The target set by the Department of Energy (DOE) is 263 cm3/cm3 working capacity under standard conditions for the adsorbent material to be commercially viable. The value is gravimetrically equivalent to 0.5 g/g of adsorbent and amount of CNG at 200 bar and 25°C pressure and temperature respectively. Furthermore, the low energy density value of the natural gas also requires improvement which may be achieved by high-density packing so that it mimics the energy density value of LNG, i.e. ~22.2 MJ/L. Therefore, efficient adsorbents with high adsorption and desorption efficiency are desirable to utilize this ANG technology in an affordable manner for commercial implementation.
The selection of a suitable adsorbent is one of the most important criteria for the utilization of the technology for successful commercial application. An adsorbent with high surface area, large pore volume, narrow micropore distribution, the pore size of 1–1.2 nm, and high density is required to achieve the ambitious ANG storage target for vehicular application set by the US DOE. The porous materials studied in recent literature for adsorption based natural gas storage at relatively low pressure compared to that of the CNG and ambient temperature conditions are resins, zeolites [5], xerogels [6], aerogels, carbon-based materials [7] such as carbon nanotubes and fibers, metal organic frameworks (MOF) and covalent organic frameworks (COF). The methane adsorption efficiency is known to be linearly dependent on the surface area of the adsorbent (Figure 1) [8]. Earlier studies have revealed that Zeolites exhibiting adsorption capacity up to 100 V/V storage capacity are not suitable to reach the target set by the DOE and the interest has shifted to the carbon-based materials and 3D frameworks [4].
Schematics showing the effect of the surface of the carbon-based adsorbents on the methane uptake capacity, the red squares represent the carbon in granular powder form and the green circles represent the coal samples.
The volumetric storage capacity of the adsorbed natural gas may be calculated in a simple manner by following the equation given below;
where, nstg is the volumetric storage capacity, nexc is the excess amount of adsorbate per volume of adsorbent, ρgas, ρpack, and ρHe is the gas, packing and helium density respectively.
Porous carbon materials are one of the widely studied systems for said application. In general carbon-based materials have exhibited higher adsorption capacity compared to that of the other studied porous materials possessing similar surface area due to their slit-shaped pore structure [9]. The packing density of activated carbon-based materials is also known to exhibit a linear dependence on the applied pressure and the value reaches up to 0.8 g/cm3 on applying pressure till 980 MPa [10]. Furthermore, the activated carbon-based materials can be easily synthesized from readily available low-cost starting materials such as wooden materials, corns, different fossil fuels, and polymer and are cost-effective. These materials can be easily physically activated using steam or CO2 and chemically activated in an industrial scale using acids and bases under high-temperature conditions [11]. Earlier studies on carbon-based adsorbent for the natural gas storage application was based on the single-walled carbon nanotubes (SWCNT). The Monte Carlo simulation-based theoretical studies predicted that the SWCNT bundles may be suitable for methane storage under moderate pressure conditions [12]. However, experimental studies afterward suggested that the adsorption capacity is limited to 0.11 g/g in these systems at 60 bar and 30°C [13]. The activated carbon-based materials have been successful in achieving excess gravimetric methane uptake till 0.2 g/g at 35 bar and ambient temperature conditions and in this case the delivery capacity was 170 V/V at 65 bar pressure [14]. Further increase in pressure to 100 bar improved the adsorption capacity to 263 V/V, which surpassed the target set by DOE. However, the deliverable capacity of carbon-based materials is reported to be inferior, which limits the utilization of these materials for storage applications. The carbon nanotube (CNT) though has shown promise to achieve high adsorption capacity, the experimental value is limited to 160 V/V at 35 bar and 25°C [15].
One of the advantages of these carbon-based materials is that these can be synthesized from renewable, polymeric, and cost-effective sources and activated via multiple routes. For example, olive stones were utilized to prepare carbon-based materials, which on carbonization at 500°C under inert atmosphere produced the carbon material. The sample was activated using KOH at a high temperature of 800°C [16]. The sample exhibited 3551 m2/g BET surface area and 215 V/V methane uptake capacity at 100 bar with a working capacity of 135 V/V. In another instance, polyacrylonitrile beads were pyrolyzed at 600°C to synthesize carbon flowers. The carbon flowers were then activated with KOH by heating the mixture at 800°C. The flowers were also activated by heating these under CO2 flow at 850°C. The resulting carbon materials exhibited a BET surface area of 1077 m2/g and methane adsorption capacity of 196 V/V at 65 bar [17]. Other biomass precursors for the synthesis of porous carbon materials include coconut shells [18], corn straws [19], banana peels [20], and soya [21]. Xiao and coworkers published a summary on the use of various biomass for the synthesis of porous carbon materials and the surface area of the resulting materials [22]. The review also summarized the different activation methods utilized to activate the carbon materials such as strong inorganic bases [23], lewis acid [24], and H3PO4 [25] based procedures to optimize the pore structure further and enhance their adsorption performance. Templating is another useful technique utilized in literature to achieve highly ordered and large surface area carbon materials. Both soft and hard templating can be used for this purpose. Hard templates could be a various nanoparticles, silica, and molecular sieves. For example, mesoporous silica sieve hard templates in presence of 1,10-phenanthroline ligand were utilized to synthesize Co immobilized nitrogen-doped porous carbon materials for catalytic applications. The calcination for the material synthesis was carried out at 800°C [26]. Typically, in the case of the soft templating method, the polymers or surfactant self-assemble into a particular ordered shape, which is then immobilized into the mesoporous material to be synthesized. Subsequently, the templates are removed to expose the pores and obtain the porous material. Ionic liquid and self-assembled block polymers have been utilized as the soft templates for this purpose [27, 28]. Direct carbonization of ordered nanostructures is also becoming another attractive option to generate porous carbon materials. For example, the MOF can be utilized as precursors to directly synthesize porous carbon materials via pyrolysis under an inert environment [29]. The presence of various organic ligands may also serve as the carbon source for the above synthesis, whereas the metal nodes often help to control the pore structure and control the physical properties of the carbon material. For example, Yamaguchi and coworkers utilized a Zn and Co-based bimetallic MOF to synthesize nanoporous carbon by pyrolyzing the precursor under an inert atmosphere at 900°C [30]. The shape of the precursor was replicated in the carbon material produced as can be shown in Figure 2 below. Metal such as Zn evaporates at a high temperature allowing the formation of pores in the resulting carbon product. In some cases, the metal ions convert to the corresponding nanoparticles and serve as a catalytic site for further applications. The type of metal, the metal content, and ligand type play important role in developing nanoporous carbon structures.
(a) The crystal structure of Zn and Co-based bimetallic MOF, (b) the photographs of solutions possessing different molar ratios of Co2+ to Zn2+, (c and d) the TEM and (e) SEM images of the MOF and produced nanoporous carbon., Reproduced with permission from
In this regard, the MOFs have gained strong interest in their ability to reversibly store natural gas for vehicular application. MOFs are a wide family of reticular and highly porous coordination polymers formed by the coordination self-assembly of the metal center with multidentate organic building blocks [32, 33]. The MOFs are reported to exhibit ultra-high surface area up to 10,000 m2/g, and tunable pore sizes with the possibility to functionalize them [34]. A number of MOF materials such as MIL-74, CAU-8, Zn6(H2O)3(BTP)4, Zn-MOF-74, 3W-ROD-1, and Ni-MOF-74 are studied towards their ability to store natural gas (Figure 3) [31]. Similarly, Pore size optimization is one of the important targets in the field of MOF materials. The effective way to address the same is by gradually changing the length of the organic linker and introducing functionality into the linker. For example, the introduction of sulfone and carbonyl groups notably improved the CO2 absorption capacity compared to that of the un-functionalized one (Figure 4) [35].
Structure of some of the rod MOFs synthesized in recent literature. Reproduced with permission from [
Effect of ligand size on the pore structure of the resulting MOFs. Reproduced with permission from [
For an adsorbent to exhibit adequate adsorption ability, the system should maintain a balance between gravimetric (SAG) and volumetric surface area (SAV) along with high porosity. Often the normalized value of the product of SAG and SAV is utilized to suggest the above. It is known that the helium void fraction displays a volcano relationship with the largest pore diameter. The NU-1500; Al and PET-based MOF systems exhibit void fraction and largest pore diameter values of 0.76 and 12.7 Å respectively and display high CH4 storage capacity. A similar system with Fe at the coordinating center, the NU-1501 series displayed increased VF values of 0.87 and an LPD value of 18.8 Å [36]. The MOF series based on extended PET system and Al metal displayed SAG and SAV of 7310 m2/g and 2060 m2/cm3 respectively. The corresponding Fe-based system showed a somewhat lower SAG value (7140 m2/g) and comparable SAV value (2130 m2/cm3). The study showed that the SAG and SAV values can be controlled further to significantly improve the gravimetric uptake capacity while retaining the volumetric storage capacity.
The gas adsorption capacity and separation performance of the MOFs may be optimized further by suitably modifying the organic building blocks with functional groups using simple organic transformation. The presence of polar functional groups in the mainframe of MOFs effectively improves the CO2 capture and separation abilities. For example, MOF is based on flexible hexadentate ligands containing amide groups, N-tris-isophthalic acid-1,3,5-benzenetricarboxamide (TPBTM) such as [Cu24(TPBTM6−)8(H2O)24](Cu-TPBTM) with high surface area [37]. The pore structure of the resulting MOFs depended on the size, structure, and functionality of the organic building blocks as shown inFigure 5 for representative purposes.
The Cu-TPNTM MOFs and their pore structure is depicted above. Reproduced with permission from [
These class of materials are reported to exhibit adsorption capacity up to 180 V/V. For example, the HKUST-1 based on Cu metal and 1,3,5-benzenetricarboxylate organic linker exhibits surface area up to 1800 m2/g with adequate stability [37]. Similarly, a MOF system based on Cu and a hexadentate linker 3,3′,3″,5,5′,5″-benzene-1,3,5-triyl-hexabenzoic acid exhibited BET surface area up to 6240 m2/g [39]. The open metal site in these MOFs serves as the site to bind to the methane molecule. At 100 bar pressure and 25°C, these MOFs display storage capacity up to 330 V/V. The issue with this MOF system towards practical applications is that higher hydrocarbons, such as ethane and propane adsorb more strongly compared to that of the methane and tend to block the pore site [40]. Seki reported a MOF system, based on copper and triethylenediamine (TED), [Cu-(O2CRCO2)·1/2TED}n] [R = 4,4′-C6H4C6H4 (1)] which recorded a volumetric storage capacity for methane up to 225 V/V [41]. For the synthesis of MOFs for said application, key factors such as the number of coordinating sites, size, shape, and geometric configuration of organic linkers require careful attention, which determines the self-assembled structure and gas adsorption performance of MOFs. Typically, the coordinating sites of the organic building blocks consist of electron-donating elements such as O, S, and N. Among the corresponding coordinating functionalities, the carboxylic acid groups tend to form stable MOFs. A set of crystalline MOFs based on 4,4′,4″-[benzene-1,3,5-triyl-tris(ethyne-2,1-diyl)]tribenzoate organic linker and Zn4O(CO2)6 was synthesized that exhibited non-interpenetrating 3D crystal structures with pores of ~48 Å sizes [42]. The MOF displayed an extremely high BET surface area of 6240 m2/g. A table summarizing the adsorption capacity under given temperature and pressure conditions for various MOFs is included for reference (Table 1) [43].
MOFs | BET | Pressure | Capacity (cm3/g) | Reference |
---|---|---|---|---|
(m2/g) | (bar) | |||
NU-1500-Al | 3650 | 100 | 549.1 | [43] |
MOF-177 | 4500 | 65 | 475 | [38] |
NU-1501-Al | 7310 | 100 | 929.7 | [43] |
PCN-46 | 2500 | 65 | 310.7 | [43] |
PCN-61 | 3000 | 65 | 366.8 | [43] |
PCN-66 | 4000 | 65 | 397.9 | [43] |
PCN-68 | 5109 | 65 | 465.2 | [43] |
UTSA-61 | 2171 | 65 | 337 | [43] |
UTSA-20 | 1620 | 65 | 252.7 | [43] |
NOTT-119 | 4118 | 65 | 426.6 | [43] |
NU-111 | 4930 | 65 | 503 | [43] |
NU-125 | 3286 | 65 | 395 | [43] |
NU-140 | 4300 | 65 | 451.5 | [43] |
NOTT-100 | 1661 | 35 | 210 | [43] |
NOTT-102 | 3342 | 35 | 308 | [38] |
UTSA-110 | 3241 | 65 | 402 | [44] |
UTSA-76 | 2820 | 65 | 363 | [44] |
NJU-Bai-43 | 3090 | 65 | 396 | [44] |
LIFM-82 | 1624 | 65 | 267 | [44] |
MFM-38 | 2022 | 65 | 346 | [44] |
MFM-115a | 3394 | 65 | 389 | [44] |
MIL-53 (Cr) | 1500 (Langmuir) | 35 | 159 | [38] |
SNU-77 | 3670 | 35 | 250 | [38] |
PCN-68 | 5109 | 35 | 332 | [38] |
IRMOF | 1102 | 35 | 163 | [38] |
DUT-4 | 1308 | 35 | 158 | [38] |
FJI-1 | 4043 | 35 | 273 | [38] |
DUT-13 | 5570 (Langmuir) | 35 | 250 | [38] |
MOF-210 | 6240 | 35 | 331 | [38] |
DUT-8 (Co) | 1400 | 35 | 78 | [38] |
Considering the gas density in the pores of the adsorbent to be considerably higher compared to that of the bulk density, the optimization of void space becomes important to maximize the adsorption capacity. Therefore, monoliths of MOFs are prepared using compression, binder, and polymeric additives [45]. However, the use of additives though known to improve the mechanical strength has their drawback as these tend to block the pore space and decrease the uptake capacity [46]. Therefore, preparation of pure monolith of MOF using compression has been pursued in literature. Even mechanical compression notably decreased the uptake capacity possibly due to the collapse of the pore structure. For example, the uptake capacity of Ni2(1,4-dioxido-2,5-benzenedicarboxylate) based MOF decreased from 230 to 100 V/V at 34 bar and 30°C after palletization [47]. Another way to handle the issue is to use a sol-gel technology in which gradual evaporation of solvent from the monoliths without destroying the pore structure. Recently, HKUST-1 monolith prepared using sol-gel technique exhibited uptake capacity of 259 V/V at 65 bar and 25°C [48].
The methane binding sites were studied in the literature on Zn-based MOF samples using low-temperature synchrotron analysis. The data revealed two primary adsorption sites and one secondary adsorption site. The primary adsorption sites were located near the Zn complex paddlewheel and the center of the small windows was recognized as the second primary adsorption site. At these sites, the methane interacted with the phenyl units and paddlewheel units. The secondary adsorption site was recognized as the center of the cavity [49]. However, still, the interaction of functional groups with methane is not very clear. More studies with support from spectroscopic tools may be necessary for future to completely ascertain the mechanism of methane storage. Using flexible MOFs is attractive to improve desorption capacity and minimize the loss during desorption. Considering the desorption pressure of the working engine is fixed at 4.8 bar by DoE, the reported flexible MOFs are known to absorb ANG at between 35 and 65 bar and release most of the gas at ~5 bar pressure [50, 51]. The type of metal center in the MOF also controls the uptake capacity and thermal management of the system. For example, Co(bdp) and Fe(bdp) based MOFs through exhibit comparable methane uptake capacity, Fe-based system has desorption steps at higher pressures of 10 bar compared to that of the Co-based system [52]. Similarly, in terms of intrinsic thermal management, the amount of heat released by Fe(bdp) based system (64.3 kJ/L) is 12% compared to that of the Co(bdp) (73.4 kJ/L) based system. Overall, the challenge with these systems lies with the fact that the 3D structure to be produced in such a way that the aromatic rings are exposed for the CH4 interaction. However, expansion of the organic linkers leads to fragile materials and allows for the self-interpenetration of lattices. Furthermore, the thermal stability of the coordination linkage, low heat of adsorption, and high packing density are also important from the perspective of commercial viability. Keeping in view of the above, suitable MOFs with high surface area and porosity may be designed and synthesized for the ANG storage application.
Another exciting avenue for reversible storage of CH4 is the covalent organic frameworks (COFs). The COFs are nanoporous materials formed by the covalent crosslinking of organic functional groups. These are lightweight materials with large pore volume, low density, and presence of hydrocarbon frames that enhances the interaction towards CH4 and improve the uptake capacity. Importantly, these possess high thermal stability and low molecular weight. For example, the COFs based on boronic acid linkage exhibited high thermal stability till 500°C and surface area up to 1590 cm2/g [53]. The surface area of boronic acid-based COFs increased further by restructuring the pore structure through the incorporation of two nodes, i.e. triangular (ctn) and tetrahedral (bor). The surface area of the COFs was measured to be 4210 cm2/g [54]. Earlier studies have proposed to minimize the methane COF interaction and increase the heat of adsorption to enhance the delivery efficiency of methane. These studies have further proposed that substitution on the phenyl ring does not alter the binding ability in the samples [55].
A study based on aromatic imine networks revealed that sub-stoichiometric construction of COFs hexagonal building blocks with four connecting sites, where the two unreacted sites can be used to enhance the selectivity of hydrocarbon adsorption [56]. The COF displayed a high BET surface area up to 3478 m2/g and methane adsorption capacity of 11.2 cm3/g. Similarly, another sub-stoichiometric COFs based on imines displaying bex net topology synthesized using tri- and tetratopic linkers are reported in the literature [57]. Topology control in COF is another important aspect to control the uptake capacity. For example, recently an N,N-dimethyl acetamide and 1,3,5-trimethylbenzene based imine-COF was synthesized that displayed two different types of triangular micropores of different pore dimensions. The diameter of the pores was 11.3 and 15.2 Å respectively [58]. The COFs with tbo topology have been reported in the literature by using planar porphyrin with four coordinating sites and 3 coordinating trigonal aldehydes of a triphenylamine. The COFs are arranged into a
COFs possessing pcu topology have been synthesized using distorted aromatic compounds serving as triangular antiprismatic nodes [60]. Imine-based COFs possessing fjh topology was synthesized by coupling a triangular linker with a square building block [61]. Triptycene-based COFs displaying a non-interpenetrated ceq or acs topology was synthesized using a combination of a triangular prism and planar triangle nodes [44]. The sample displayed methane adsorption capacity up to 48 cm3/g at 0°C and 1 bar. The COF exhibited a BET surface area value of 2650 m2/g. Overall, studies have shown that the organic building block structure and functionality can be utilized as a control to develop COFs with controlled pore size, pore structure, and topology. The functionality in the COF system may be introduced to enhance the selectivity of such systems towards methane adsorption compared to that of the polar gases. The stoichiometry also serves as one of the handles to control the topology of the COFs. Several studies have shown that these materials possessing adequate thermal stability and binding ability towards methane may be a useful option for methane storage applications.
To summarize, ANG holds strong promise in the area of fuel for transportation and other consumer sectors. The affordability depends on the availability of cost-effective adsorbents with high storage capacity with optimized deliverability. Though porous carbon, metal-organic framework, and covalent organic framework have shown promise, the target set by the DOE is yet to be complied with optimum deliverability. Selective compositions have been successful in achieving the storage capacity limits, the cost-effective and large scale production of such materials is under ways to materialize a commercializable product. These porous nanostructures are predicted to reach a high surface area up to 4000 m2/g and beyond. A greater understanding of the pore structure, synthetic process, and mechanism of formation, pore controlling factors during synthesis and factors contributing towards the pore uniformity and stability would notably help towards the development of nonporous materials with high surface area and controlled pore structure. Therefore, the development of new cost-effective, thermally stable adsorbents with high uptake capacity and material strength is still desirable to further fulfill the commercial viability aspect of the technology.
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His studies in robotics lead him not only to a PhD degree but also inspired him to co-found and build the International Journal of Advanced Robotic Systems - world's first Open Access journal in the field of robotics.",institutionString:null,institution:{name:"TU Wien",country:{name:"Austria"}}},{id:"441",title:"Ph.D.",name:"Jaekyu",middleName:null,surname:"Park",slug:"jaekyu-park",fullName:"Jaekyu Park",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/441/images/1881_n.jpg",biography:null,institutionString:null,institution:{name:"LG Corporation (South Korea)",country:{name:"Korea, South"}}},{id:"465",title:"Dr.",name:"Christian",middleName:null,surname:"Martens",slug:"christian-martens",fullName:"Christian Martens",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"Rheinmetall (Germany)",country:{name:"Germany"}}},{id:"479",title:"Dr.",name:"Valentina",middleName:null,surname:"Colla",slug:"valentina-colla",fullName:"Valentina Colla",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/479/images/358_n.jpg",biography:null,institutionString:null,institution:{name:"Sant'Anna School of Advanced Studies",country:{name:"Italy"}}},{id:"494",title:"PhD",name:"Loris",middleName:null,surname:"Nanni",slug:"loris-nanni",fullName:"Loris Nanni",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/494/images/system/494.jpg",biography:"Loris Nanni received his Master Degree cum laude on June-2002 from the University of Bologna, and the April 26th 2006 he received his Ph.D. in Computer Engineering at DEIS, University of Bologna. On September, 29th 2006 he has won a post PhD fellowship from the university of Bologna (from October 2006 to October 2008), at the competitive examination he was ranked first in the industrial engineering area. He extensively served as referee for several international journals. He is author/coauthor of more than 100 research papers. He has been involved in some projects supported by MURST and European Community. His research interests include pattern recognition, bioinformatics, and biometric systems (fingerprint classification and recognition, signature verification, face recognition).",institutionString:null,institution:null},{id:"496",title:"Dr.",name:"Carlos",middleName:null,surname:"Leon",slug:"carlos-leon",fullName:"Carlos Leon",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"University of Seville",country:{name:"Spain"}}},{id:"512",title:"Dr.",name:"Dayang",middleName:null,surname:"Jawawi",slug:"dayang-jawawi",fullName:"Dayang Jawawi",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"University of Technology Malaysia",country:{name:"Malaysia"}}},{id:"528",title:"Dr.",name:"Kresimir",middleName:null,surname:"Delac",slug:"kresimir-delac",fullName:"Kresimir Delac",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/528/images/system/528.jpg",biography:"K. 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Manjur",middleName:null,surname:"Shah",slug:"mohammad-manjur-shah",fullName:"Mohammad Manjur Shah"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}],booksByTopicTotal:2,seriesByTopicCollection:[],seriesByTopicTotal:0,mostCitedChapters:[{id:"55521",doi:"10.5772/intechopen.68958",title:"The Impact of Plant-Parasitic Nematodes on Agriculture and Methods of Control",slug:"the-impact-of-plant-parasitic-nematodes-on-agriculture-and-methods-of-control",totalDownloads:6217,totalCrossrefCites:39,totalDimensionsCites:81,abstract:"Plant-parasitic nematodes are costly burdens of crop production. Ubiquitous in nature, phytoparasitic nematodes are associated with nearly every important agricultural crop and represent a significant constraint on global food security. Root-knot nematodes (Meloidogyne spp.) cyst nematodes (Heterodera and Globodera spp.) and lesion nematodes (Pratylenchus spp.) rank at the top of list of the most economically and scientifically important species due to their intricate relationship with the host plants, wide host range, and the level of damage ensued by infection. Limitations on the use of chemical pesticides have brought increasing interest in studies on alternative methods of nematode control. Among these strategies of nonchemical nematode management is the identification and implementation of host resistance. In addition, nematode genes involved in parasitism represent key targets for the development of control through gene silencing methods such as RNA interference. Recently, transcriptome profiling analyses has been used to distinguish nematode resistant and susceptible genotypes and identify the specific molecular components and pathways triggered during the plant immune response to nematode invasion. This summary highlights the importance of plant-parasitic nematodes in agriculture and the molecular events involved in plant-nematode interactions.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Gregory C. Bernard, Marceline Egnin and Conrad Bonsi",authors:[{id:"203575",title:"Dr.",name:"Gregory",middleName:null,surname:"Bernard",slug:"gregory-bernard",fullName:"Gregory Bernard"}]},{id:"55770",doi:"10.5772/intechopen.69164",title:"Harnessing Useful Rhizosphere Microorganisms for Nematode Control",slug:"harnessing-useful-rhizosphere-microorganisms-for-nematode-control",totalDownloads:2215,totalCrossrefCites:7,totalDimensionsCites:12,abstract:"Nematodes are very diverse and parasitize various plants including vegetables, and their management is of concern. Biological control of nematodes provides an environmentally friendly management option and there are various micro‐soil‐borne organisms which can be considered for this purpose. The primary goal of this chapter is to provide a review on the progress made so far, in application of biological control agents in nematode management in vegetables, cereals, and root and tuber crops. This chapter will be divided into five (5) sections: (1) herbivore‐induced plant volatiles, (2) root exudates and nematode control, (3) inhibitory metabolites in bacteria for nematode management, (4) fungi and symbiotic reprogramming in host cells, and (5) fungi antagonists of nematodes.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Seloame Tatu Nyaku, Antoine Affokpon, Agyemang Danquah and\nFrancis Collison Brentu",authors:[{id:"182528",title:"Dr.",name:"Seloame Tatu",middleName:null,surname:"Nyaku",slug:"seloame-tatu-nyaku",fullName:"Seloame Tatu Nyaku"},{id:"204222",title:"Dr.",name:"Antoine",middleName:null,surname:"Affokpon",slug:"antoine-affokpon",fullName:"Antoine Affokpon"},{id:"204223",title:"Dr.",name:"Agyemang",middleName:null,surname:"Danquah",slug:"agyemang-danquah",fullName:"Agyemang Danquah"},{id:"204224",title:"Dr.",name:"Collison",middleName:null,surname:"Brentu",slug:"collison-brentu",fullName:"Collison Brentu"}]},{id:"55761",doi:"10.5772/intechopen.69403",title:"Methods and Tools Currently Used for the Identification of Plant Parasitic Nematodes",slug:"methods-and-tools-currently-used-for-the-identification-of-plant-parasitic-nematodes",totalDownloads:3829,totalCrossrefCites:10,totalDimensionsCites:11,abstract:"Plant parasitic nematodes are one of the limiting factors for production of major crops worldwide. Overall, they cause an estimated annual crop loss of $78 billion worldwide and an average 10–15% crop yield losses. This imposes a challenge to sustainable production of food worldwide. Unsustainable cropping production with monocultures, intensive planting, and expansion of crops to newly opened areas has increased problems associated with nematodes. Thus, finding sustainable methods to control these pathogens is in current need. The correct diagnosis of nematode species is essential for choosing proper control methods and meaningful research. Morphology-based nematode taxonomy has been challenging due to intraspecific variation in characters. Alternatively, tools and methods based on biochemical and molecular markers have allowed successful diagnosis for a wide number of nematode species. Although these new methods have been useful due to their practical, fast, accuracy, and cost effective, the use of integrative diagnose, combining morphology, biochemical and molecular data is more appropriate when necessary to strength diagnose, define species boundaries, and to have a more suitable molecular database for nematode species. Here, we report a review on current methods and tools used to identify plant parasitic nematodes.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Regina Maria Dechechi Gomes Carneiro, Fábia Silva de Oliveira\nLima and Valdir Ribeiro Correia",authors:[{id:"191564",title:"Dr.",name:"Fábia",middleName:null,surname:"Lima",slug:"fabia-lima",fullName:"Fábia Lima"},{id:"191758",title:"Dr.",name:"Valdir",middleName:null,surname:"Correa",slug:"valdir-correa",fullName:"Valdir Correa"}]},{id:"55809",doi:"10.5772/intechopen.69512",title:"Assessing the Viability and Degeneration of the Medically Important Filarial Nematodes",slug:"assessing-the-viability-and-degeneration-of-the-medically-important-filarial-nematodes",totalDownloads:1432,totalCrossrefCites:3,totalDimensionsCites:4,abstract:"The assessment of nematodes as they generate and die is not a simple thing to do due in part to the complexity of the organism, and the fact that still relatively little is known about their physiology and internal biology. Indeed, the pathological changes in the internal organs of the worms are still only recognized in general terms. Obviously dead worms are easily recognized (when fractured, or calcified, etc.) but the lesser obvious changes can be difficult to detect and interpret. The point at which a worm can be defined as dead is not a simple matter; cessation of motility is currently the most commonly used parameter for this but it is not always a robust indicator and better indicators are needed. Various methods can be used to assess the presence, viability, and functionality of nematodes but these must be used with an understanding of the situation at hand and the specific questions being addressed. Careful use of appropriate statistics is essential given the complex nature of the target organism and the variability in the changes that can be seen within even one anatomical component of these worms. Histological assessment of the parasites present in both parasitized host tissues and isolated worms used in in vitro experiments can provide information that gives a more detailed understanding of the changes in nematodes as they degenerate and die. Understanding of the pathways nematodes follows as they degenerate naturally or under various external pressures, such as chemotherapy, remains a fascinating and potentially productive goal for investigation. Likewise, a complete understanding and definition of specific indicators that reflect parasite load, parasite viability, and damage, or reduced fecundity, will greatly help the fight against those nematode infections that currently cause significant burdens of disease in humans and animals.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Charles D. Mackenzie, Ashley Behan‐Braman, Joe Hauptman and\nTimothy Geary",authors:[{id:"201692",title:"Dr.",name:"Charles",middleName:null,surname:"Mackenzie",slug:"charles-mackenzie",fullName:"Charles Mackenzie"},{id:"204538",title:"MSc.",name:"Ashley",middleName:null,surname:"Braman",slug:"ashley-braman",fullName:"Ashley Braman"},{id:"204539",title:"Dr.",name:"Roger",middleName:null,surname:"Hauptman",slug:"roger-hauptman",fullName:"Roger Hauptman"},{id:"204540",title:"Prof.",name:"Timothy",middleName:null,surname:"Geary",slug:"timothy-geary",fullName:"Timothy Geary"}]},{id:"56369",doi:"10.5772/intechopen.69861",title:"Searching for Better Methodologies for Successful Control of Termites Using Entomopathogenic Nematodes",slug:"searching-for-better-methodologies-for-successful-control-of-termites-using-entomopathogenic-nematod",totalDownloads:2184,totalCrossrefCites:2,totalDimensionsCites:4,abstract:"Termites are social insects reported from many countries of the world. Some species of them are known to be beneficial to man, whereas some others cause substantial losses (billions of US dollars annually) of properties and amenities. Various preventive and remedial methods are used to control undesirable termite species. The current review paper gives an overview of beneficial and detrimental activities of termites. Methods of control of undesirable species of termites are given and their advantages and disadvantages are discussed. We emphasized on the use of entomopathogenic nematodes (EPNs) as effective, environmentally safe and sustainable biological control method against termites. Species of EPNs recovered in Africa are documented. Some techniques used to collect termites and to maintain them for experiments and also to propagate, to formulate, to store, and to check for the quality of EPNs for application in the laboratory and in the field are also discussed. The environmental factors affecting the potential of EPNs to control termites are discussed. The information provided in this chapter will help researchers to enhance their skills of the use of EPNs against termites by selecting from the methodologies described here the best ones to adapt to particular experimental conditions, especially in African soil conditions.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Hugues Baïmey, Lionel Zadji, Léonard Afouda, André Fanou, Régina\nKotchofa and Wilfrieda Decraemer",authors:[{id:"201690",title:"Dr.",name:"Hugues",middleName:null,surname:"Kossi Baimey",slug:"hugues-kossi-baimey",fullName:"Hugues Kossi Baimey"}]}],mostDownloadedChaptersLast30Days:[{id:"55521",title:"The Impact of Plant-Parasitic Nematodes on Agriculture and Methods of Control",slug:"the-impact-of-plant-parasitic-nematodes-on-agriculture-and-methods-of-control",totalDownloads:6217,totalCrossrefCites:39,totalDimensionsCites:81,abstract:"Plant-parasitic nematodes are costly burdens of crop production. Ubiquitous in nature, phytoparasitic nematodes are associated with nearly every important agricultural crop and represent a significant constraint on global food security. Root-knot nematodes (Meloidogyne spp.) cyst nematodes (Heterodera and Globodera spp.) and lesion nematodes (Pratylenchus spp.) rank at the top of list of the most economically and scientifically important species due to their intricate relationship with the host plants, wide host range, and the level of damage ensued by infection. Limitations on the use of chemical pesticides have brought increasing interest in studies on alternative methods of nematode control. Among these strategies of nonchemical nematode management is the identification and implementation of host resistance. In addition, nematode genes involved in parasitism represent key targets for the development of control through gene silencing methods such as RNA interference. Recently, transcriptome profiling analyses has been used to distinguish nematode resistant and susceptible genotypes and identify the specific molecular components and pathways triggered during the plant immune response to nematode invasion. This summary highlights the importance of plant-parasitic nematodes in agriculture and the molecular events involved in plant-nematode interactions.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Gregory C. Bernard, Marceline Egnin and Conrad Bonsi",authors:[{id:"203575",title:"Dr.",name:"Gregory",middleName:null,surname:"Bernard",slug:"gregory-bernard",fullName:"Gregory Bernard"}]},{id:"55032",title:"Introductory Chapter: Nematodes - A Lesser Known Group of Organisms",slug:"introductory-chapter-nematodes-a-lesser-known-group-of-organisms",totalDownloads:2707,totalCrossrefCites:0,totalDimensionsCites:1,abstract:null,book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Mohammad Manjur Shah and Mohammad Mahamood",authors:[{id:"94128",title:"Dr.",name:"Mohammad Manjur",middleName:null,surname:"Shah",slug:"mohammad-manjur-shah",fullName:"Mohammad Manjur Shah"},{id:"202894",title:"Dr.",name:"Mohammad",middleName:null,surname:"Mahamood",slug:"mohammad-mahamood",fullName:"Mohammad Mahamood"}]},{id:"77474",title:"Nematodes Diseases of Fruits and Vegetables Crops in India",slug:"nematodes-diseases-of-fruits-and-vegetables-crops-in-india",totalDownloads:361,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"Nematodes are the most plentiful animals on earth, commonly found in soil or water, including oceans. Some species of nematodes are parasites of plants and animals. Plant-parasitic nematodes are non-segmented microscopic, eel-like round worms, obligate parasite possess stylets that live in soil causing damage to plants by feeding on roots or plant tissues. Plant-parasitic nematodes feed on roots, either within the root, some nematodes feed leaves. These nematodes cause breakdown of resistance to fungal diseases in fruit crops. Plant-parasitic nematodes living host tissue to feed on to grow and reproduce. Nematode life cycle consists of an egg, 4 pre-adult stages (juveniles) and an adult, life cycle depending on the species and the temperature. Nematodes do not move long distances (less than 6 inches per year). They are usually transported over long distances on machinery, in nursery stock, transplants, seeds, or by animals, moves soil, water and wind. They acquire nutrients from plant tissues by needle-like feeding structure (stylet/spear). Nematodes can be classified into three groups depending on feed on the plants such as ectoparasitic nematodes are always remaining outside the plant root tissues. Migratory endoparasitic nematodes move through root tissues sedentary endoparasitic nematodes penetrate young roots at or near the growing tip. They steal nutrients, disrupt water and mineral transport, and provide excellent sites for secondary pathogens (fungus and bactria) to invade the roots and decay. Several nematode species that cause problems in fruit orchards that are major limiting factors in fruit crop production cause extensive root necrosis resulting in serious economic losses. The root-knot nematode (Meloidogyne spp.), burrowing nematode (Radopholus similis) and citrus nematode (Tylenchulus semipentrans) are the major nematode pests that infect fruit crops. Parasitic nematodes that can damage tree fruit roots. Many kinds of nematodes have been reported in and around the roots of various fruit crops, only few are cause serious damage, including Root-knot nematodes (Meloidogyne spp.), Lesion nematodes (Pratylenchus species), Ring nematodes (Mesocriconema spp) are cigar-shaped that are strictly ectoparasitic, Dagger nematodes (Xiphinema spp) are relatively large ectoparasites that feed near root tips, Sting nematodes (Belonolaimus species) are ectoparasitic, Citrus nematodes (Tylenchulus semipenetrans) are sedentary semi-endoparasites. Nematodes reduce yield without the production of any noticeable above ground symptoms. Typical above ground symptoms of nematode infections stunting, yellowing and wilting. Major nematodes associated in large number of vegetables crops in India such as root-knot nematodes (Meloidogyne spp.), cyst nematodes (Heterodera spp.), lesion nematodes (Pratylenchus sp.), reniform nematodes (Rotylenchulus sp.) lance nematodes (Hoplolaimus spp.), stem and bulb nematode (Ditylenchus spp.) etc. Root-knot nematodes are important pests of vegetables belonging to solanaceous (brinjal, tomato, chili), cucurbitaceous (biter ground, cucumber, pumpkin, bottle gourd) leguminous (cowpea, bean, pea), cruciferous cauliflower, cabbage, broccoli, brussels, sprout), okra and several other root and bulb crops (onion, garlic, lettuce, celery, carrot, radish). Four species (M. incognita, M. javanica, M. arenaria and M. hapla) are more than 95% of the root-knot nematode population worldwide distribution. Stem and Bulb nematode (Ditylenchus spp.) commonly attacks onion, garlic, potato, pea and carrot etc. The nematodes spread from one area to another mainly through infested planting materials, water drains from infested areas into irrigation system, soil that adheres to implements, tyres of motor vehicles and shoes of plantation workers. Management recommendation through bio-pesticides, cultural practices, enrichment of FYM, Neem cake and other organic amendments.",book:{id:"10745",slug:"nematodes-recent-advances-management-and-new-perspectives",title:"Nematodes",fullTitle:"Nematodes - Recent Advances, Management and New Perspectives"},signatures:"Amar Bahadur",authors:[{id:"353289",title:"Assistant Prof.",name:"Amar",middleName:null,surname:"Bahadur",slug:"amar-bahadur",fullName:"Amar Bahadur"}]},{id:"55761",title:"Methods and Tools Currently Used for the Identification of Plant Parasitic Nematodes",slug:"methods-and-tools-currently-used-for-the-identification-of-plant-parasitic-nematodes",totalDownloads:3829,totalCrossrefCites:10,totalDimensionsCites:11,abstract:"Plant parasitic nematodes are one of the limiting factors for production of major crops worldwide. Overall, they cause an estimated annual crop loss of $78 billion worldwide and an average 10–15% crop yield losses. This imposes a challenge to sustainable production of food worldwide. Unsustainable cropping production with monocultures, intensive planting, and expansion of crops to newly opened areas has increased problems associated with nematodes. Thus, finding sustainable methods to control these pathogens is in current need. The correct diagnosis of nematode species is essential for choosing proper control methods and meaningful research. Morphology-based nematode taxonomy has been challenging due to intraspecific variation in characters. Alternatively, tools and methods based on biochemical and molecular markers have allowed successful diagnosis for a wide number of nematode species. Although these new methods have been useful due to their practical, fast, accuracy, and cost effective, the use of integrative diagnose, combining morphology, biochemical and molecular data is more appropriate when necessary to strength diagnose, define species boundaries, and to have a more suitable molecular database for nematode species. Here, we report a review on current methods and tools used to identify plant parasitic nematodes.",book:{id:"6019",slug:"nematology-concepts-diagnosis-and-control",title:"Nematology",fullTitle:"Nematology - Concepts, Diagnosis and Control"},signatures:"Regina Maria Dechechi Gomes Carneiro, Fábia Silva de Oliveira\nLima and Valdir Ribeiro Correia",authors:[{id:"191564",title:"Dr.",name:"Fábia",middleName:null,surname:"Lima",slug:"fabia-lima",fullName:"Fábia Lima"},{id:"191758",title:"Dr.",name:"Valdir",middleName:null,surname:"Correa",slug:"valdir-correa",fullName:"Valdir Correa"}]},{id:"80094",title:"Plant Parasitic Nematodes: A Major Constraint in Fruit Production",slug:"plant-parasitic-nematodes-a-major-constraint-in-fruit-production",totalDownloads:151,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"The plant parasitic nematodes are one of the major limiting factors in fruit trees specially in citrus, banana, papaya, jackfruit, guava etc. The root knot nematodes are the major problem amongst all those nematodes infecting on these trees. Besides, directly causing a huge losses, they are also inviting the secondary plant pathogens, like fungi, bacteria, viruses etc. amongst which, the wilt fungus, Fusarium species increase the severity of the diseases. This complex disease is becoming much severe in banana and guava recent years. In citrus also, the citrus nematodes, Tylenchulus semipenetrans, is causing havoc by slow decline disease and it is becoming a major problem in horticultural nurseries because these nurseries are a hot spot of citrus nematodes. So, unknowingly these nematodes get spread to different places. The management of these nematodes by simple, cheap and eco friendly methods, is very important as it will decrease the monetary pressure on cultivators as well as it helps in improving environmental pollution.",book:{id:"10745",slug:"nematodes-recent-advances-management-and-new-perspectives",title:"Nematodes",fullTitle:"Nematodes - Recent Advances, Management and New Perspectives"},signatures:"Nishi Keshari and Gurram Mallikarjun",authors:[{id:"357008",title:"Dr.",name:"Nishi",middleName:null,surname:"Keshari",slug:"nishi-keshari",fullName:"Nishi Keshari"},{id:"439770",title:"Mr.",name:"Gurram",middleName:null,surname:"Mallikarjun",slug:"gurram-mallikarjun",fullName:"Gurram Mallikarjun"}]}],onlineFirstChaptersFilter:{topicId:"422",limit:6,offset:0},onlineFirstChaptersCollection:[],onlineFirstChaptersTotal:0},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:90,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:107,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:33,numberOfPublishedChapters:330,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:18,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:14,numberOfPublishedChapters:145,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:9,numberOfPublishedChapters:139,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:122,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:112,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:21,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:10,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:"2753-6580",doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"25",title:"Environmental Sciences",doi:"10.5772/intechopen.100362",issn:"2754-6713",scope:"\r\n\tScientists have long researched to understand the environment and man’s place in it. The search for this knowledge grows in importance as rapid increases in population and economic development intensify humans’ stresses on ecosystems. Fortunately, rapid increases in multiple scientific areas are advancing our understanding of environmental sciences. Breakthroughs in computing, molecular biology, ecology, and sustainability science are enhancing our ability to utilize environmental sciences to address real-world problems.
\r\n\tThe four topics of this book series - Pollution; Environmental Resilience and Management; Ecosystems and Biodiversity; and Water Science - will address important areas of advancement in the environmental sciences. They will represent an excellent initial grouping of published works on these critical topics.
\r\n\tThe environment is subject to severe anthropic effects. Among them are those associated with pollution, resource extraction and overexploitation, loss of biodiversity, soil degradation, disorderly land occupation and planning, and many others. These anthropic effects could potentially be caused by any inadequate management of the environment. However, ecosystems have a resilience that makes them react to disturbances which mitigate the negative effects. It is critical to understand how ecosystems, natural and anthropized, including urban environments, respond to actions that have a negative influence and how they are managed. It is also important to establish when the limits marked by the resilience and the breaking point are achieved and when no return is possible. The main focus for the chapters is to cover the subjects such as understanding how the environment resilience works, the mechanisms involved, and how to manage them in order to improve our interactions with the environment and promote the use of adequate management practices such as those outlined in the United Nations’ Sustainable Development Goals.
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His work is reflected in more than 230 communications presented in national and international conferences and congresses, 29 invited lectures from universities, associations and government agencies. Prof. Navarro-Pedreño is also a director of the Ph.D. Program Environment and Sustainability (2012-present) and a member of several societies among which are the Spanish Society of Soil Science, International Union of Soil Sciences, European Society for Soil Conservation, DessertNet and the Spanish Royal Society of Chemistry.",institutionString:"Miguel Hernández University of Elche, Spain",institution:{name:"Miguel Hernandez University",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null,series:{id:"25",title:"Environmental Sciences",doi:"10.5772/intechopen.100362",issn:"2754-6713"},editorialBoard:[{id:"177015",title:"Prof.",name:"Elke Jurandy",middleName:null,surname:"Bran Nogueira Cardoso",slug:"elke-jurandy-bran-nogueira-cardoso",fullName:"Elke Jurandy Bran Nogueira Cardoso",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRGxzQAG/Profile_Picture_2022-03-25T08:32:33.jpg",institutionString:"Universidade de São Paulo, Brazil",institution:null},{id:"147289",title:"Prof.",name:"Francisco",middleName:null,surname:"Guevara-Hernández",slug:"francisco-guevara-hernandez",fullName:"Francisco Guevara-Hernández",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRCgVQAW/Profile_Picture_2022-06-27T11:25:21.png",institutionString:null,institution:{name:"Autonomous University of Chiapas",institutionURL:null,country:{name:"Mexico"}}},{id:"246299",title:"Dr.",name:"Maria Belén",middleName:null,surname:"Almendro-Candel",slug:"maria-belen-almendro-candel",fullName:"Maria Belén Almendro-Candel",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRUGxQAO/Profile_Picture_2022-07-26T14:57:26.jpg",institutionString:null,institution:{name:"Miguel Hernandez University",institutionURL:null,country:{name:"Spain"}}},{id:"211260",title:"Dr.",name:"Sandra",middleName:null,surname:"Ricart",slug:"sandra-ricart",fullName:"Sandra Ricart",profilePictureURL:"https://mts.intechopen.com/storage/users/211260/images/system/211260.jpeg",institutionString:null,institution:{name:"University of Alicante",institutionURL:null,country:{name:"Spain"}}}]},onlineFirstChapters:{paginationCount:3,paginationItems:[{id:"82956",title:"Potential Substitutes of Antibiotics for Swine and Poultry Production",doi:"10.5772/intechopen.106081",signatures:"Ho Trung Thong, Le Nu Anh Thu and Ho Viet Duc",slug:"potential-substitutes-of-antibiotics-for-swine-and-poultry-production",totalDownloads:0,totalCrossrefCites:0,totalDimensionsCites:0,authors:null,book:{title:"Antibiotics and Probiotics in Animal Food - Impact and Regulation",coverURL:"https://cdn.intechopen.com/books/images_new/11578.jpg",subseries:{id:"20",title:"Animal Nutrition"}}},{id:"82905",title:"A Review of Application Strategies and Efficacy of Probiotics in Pet Food",doi:"10.5772/intechopen.105829",signatures:"Heather Acuff and Charles G. Aldrich",slug:"a-review-of-application-strategies-and-efficacy-of-probiotics-in-pet-food",totalDownloads:8,totalCrossrefCites:0,totalDimensionsCites:0,authors:null,book:{title:"Antibiotics and Probiotics in Animal Food - Impact and Regulation",coverURL:"https://cdn.intechopen.com/books/images_new/11578.jpg",subseries:{id:"20",title:"Animal Nutrition"}}},{id:"78849",title:"Application of Vermicompost Fertilizer in Aquaculture Nutrition: Review",doi:"10.5772/intechopen.100326",signatures:"Sonnia Nzilani Musyoka and Rita Nairuti",slug:"application-of-vermicompost-fertilizer-in-aquaculture-nutrition-review",totalDownloads:75,totalCrossrefCites:0,totalDimensionsCites:0,authors:null,book:{title:"Animal Nutrition - Annual Volume 2022",coverURL:"https://cdn.intechopen.com/books/images_new/11416.jpg",subseries:{id:"20",title:"Animal Nutrition"}}}]},publishedBooks:{paginationCount:5,paginationItems:[{type:"book",id:"8737",title:"Rabies Virus at the Beginning of 21st 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