Constants for transfer coefficients

## 1. Introduction

Re-circulating cooling water systems are generally used to remove waste heat from hot process streams in conditions above the ambient temperature in many types of industries such as chemical and petrochemical, electric power generating stations, refrigeration and air conditioning plants, pulp and paper mills, and steel mills. Typical re-circulating cooling water systems are constituted by a mechanical draft wet-cooling tower that provides the cooling water that is used in a set of heat exchangers operated in parallel as can be seen in Figure 1. The economic optimization of re-circulating cooling water systems includes the simultaneous selection of the optimal design variables of the cooling tower and each heat exchanger in the cooling network, as well as the optimal structure of the cooling water network. The question is then how to reach this goal. Earlier work on cooling water systems has concentrated on the optimization of stand-alone components, with special attention given on the individual heat exchangers of the cooling water network. Other publications have dealt with the problem of designing minimum-cost cooling towers for a given heat load that must be dissipated (see Söylemez 2001, 2004; Serna-González et al., 2010). Most of the methodologies previously reported have concentrated their attention in the optimal synthesis of cooling water networks (see Kim and Smith, 2001; Feng et al., 2005; Ponce-Ortega et al., 2007). All previous formulations simplified the network configurations because they consider the installation of only one cooling tower; however, the industrial practice shows that sometimes it is preferable to use a set of cooling towers connected in series, parallel, and series-parallel arrangements to improve the performance of the cooling towers reducing the operational cost and, hence, to decrease the overall total annual cost for the cooling water system. In addition, previous methodologies do not have considered several arrangements for the cooling water that can improve the performance in the coolers and reduce their capital costs. Another limitation for the previously reported methodologies is that they are based on the use of simplified formulations for the design of cooling towers.

This chapter presents an optimization model for the simultaneous synthesis and detailed design of re-circulating cooling water systems based on the superstructure of Figure 2. The model considers all the potential configuration of practical interest and the results show the significant savings that can be obtained when it is applied.

## 2. Model formulation

This section presents the relationships for the proposed model, which is based in the superstructure of Figure 2. In the next equations, the set NEF represents the cooling medium streams leaving the cooler network* , ST*the stages of the cooling network,

*the hot process streams and*HP

*represents the cooling towers. The subscripts*NCT

*,*av

*,*b

*,*cu

*,*d

*,*dis

*,*ev

*,*f

*,*fi

*,*fr

*,*i

*,*j

*,*k

*,*e

*,*l

*,*m

*,*in

*,*n

*,*out

*,*p

*,*pl

*,*r

*,*s

*and*t

*are used to denote average, blowdown, cooling medium, drift, end of the cooling tower network, evaporation, fan, fill, cross-sectional, hot process stream, cold process stream, stage in the cooling network, type of packing, constants to calculate the heat and mass transfer characteristics for a particular type of packing, constants for the loss coefficient correlation for a particular type of packing, inlet, temperature increment index, cooling tower, outlet, pump, parallel arrangement, makeup, series arrangement, total and wet-bulb, respectively. The superscript*WB

*is an upper limit and*max

*is a lower limit. In addition, the scalars*min

*is the total number of stages in the cooling network, NCP is the total number of cooling medium streams at the hot end of the cooling network and*NOK

*is the last cooling tower in the cooling tower network.*LCT

The heat of each hot process stream (_{i}) is calculated by the multiplication between the heat capacity flowrate of each hot process stream (_{i}) and the difference of the inlet and outlet temperatures of each stream (_{i}, _{i}), All terms of the above equation

are parameters with known values. The heat absorbed by the cooling medium in the matches is equal to the transferred heat by the hot process streams, where _{i,k}is the heat exchanged in each match. In addition to the above balance, the model includes balances for the splitters and mixers on each stage for the cooling medium.

A heat balance for each match of the superstructure is required to determine the intermediate temperatures of the hot process stream and the cooling medium as well as the cooling medium flowrate at each match. For problems with * NH*hot process stream, the number of stages in the superstructure

*must be equal to*NOK

*, to allow arrangements completely in series. In this case, there are*NH

*+1 temperatures for each hot process stream, because the outlet temperature at one stage is equal to the inlet temperature in the next stage. It is required to identify the inlet and outlet temperatures at each stage for the cooling medium. Stage*NOK

*=1 represents the lowest level of temperature. The heat balance for each match is given as follows:*k

where _{i,k}is the flowrate for the cooling medium in each match. In addition, _{i,k}is the temperature of each hot stream in each match, _{k}is the inlet temperature for the cooling medium in each stage, _{i,k}is the outlet temperature for the cooling medium in each match and _{cu}is the heat capacity for the cooling medium. In previous equations, _{cu}is a parameter known prior to the optimization process.

Mass and energy balances are required to calculate the inlet flow rate and temperature for the cooling water to each stage. For the * kth*stage of the cooler network, the mass balance in the mixer is given by the sum of the water flow rates that are required by the matches in that stage (

*+1 (*k

FF

_{k+1}) minus the sum of the bypass water flow rate (

FO

_{k}) running from the splitter of that stage to the cooler network outlet and the flow rates of cooling water streams that are required by the matches of the hotter adjacent stage

*+1 (*k

To calculate the temperature of the bypass cooling-water stream of each stage (TOk), the following heat balance in the splitters is required,

Note that using the heat balance given in equation (4) is possible to know the inlet cooling medium temperature (* k*= 1). And for the first stage, the cooling medium temperature is given by the cooling tower,

The above set of equations is necessary for * NOK*-1 stages.

The following mass balance must be included for the first stage to determine the flowrate of the cold water provided by the cooling tower network to the cooler network, considering that only cold water is used in the first stage.

The inlet temperatures of the hot process streams define the last location for the superstructure. In other words, the inlet temperature of the hot process stream * i*is the temperature of such stream in the hot end of the cooling network (

Th

_{i,NOK+1}),

The outlet temperatures of hot process streams give the first location for the superstructure. Therefore, the outlet temperature of the hot process stream * i*is the temperature of such stream in the cold end of the cooling network (

Th

_{i,1}),

In addition, the inlet temperature for the cooling medium (* TCUIN*) represents the inlet temperature at the first stage (

Tcin

_{1}), considering that the outlet temperature in each match is restricted by an upper limit (

To ensure a monotonically decrement for the temperatures through the stages of the superstructure, the next constraints are included. It is necessary to specify that the temperature of each hot process stream in the stage * k*must be lower or equal than the temperature of each hot process stream in the stage

*+1,*k

The inlet cooling medium temperature to stage * k*must be lower or equal than the outlet cooling medium temperature in the match

*,*i

*,*k

The temperature inlet cooling medium to the cooling network must be less or equal than the inlet cooling medium temperature in the stage * k*,

Finally, the outlet cooling medium temperature in the match * i*,

*should be lower or equal than the outlet cooling medium temperature in the match*k

*,*i

*,*k+1

Logic constraints and binary variables are used to determine the existence of the heat exchangers between the hot process stream * i*in the stage

*with the cooling medium. These constraints are stated as follow,*k

Here * i*and

Because the area requirements for each match (_{i,k}) are included in the objective function, the temperature differences should be calculated. The model uses a pair of variables for the temperature difference in the cold side (_{i,k}) and the hot side (_{i,k}) of each match. In addition, binary variables are used to ensure positive temperature differences and greater than a given value of

where * i*. The value of

Equations (18) and (19) are written as inequalities because the heat exchanger costs decrease when the temperature differences increase. Note that the use of binary variables allows the feasibility because if the match does not exist, the parameter * i*exists at the stage

*, the binary variable*k

The flowrates (Fw_{j}) and temperatures (Tw_{j}) of the cooling water streams that are directed to the splitters at the inlet of the cooling tower network are determined in the last stage of the cooler network. It is important to note that a problem with * NH*hot process streams will have

*cooling water streams leaving the cooler network, because in addition to the flowrates of the cooling water for each match in the last stage it is generated an overall cooling water stream that results from combining the bypass cooling-water streams of the previous stages. Therefore, the value for the set of cooling water streams directed to the cooling tower network is*NH+1

*=*NEF

*+1.*NH

The outlet cooling water stream flowrate from the cooling network can be sent to each tower of the cooling tower network (_{1,j,net}) and/or directed to the end of the cooling tower network (_{2,j}),

the inlet water flowrate (_{in,net}) and temperature (_{in,net}) to the cooling towers are generated by the mix of the portions of cooling medium streams sent to the cooling towers and the flowrate from the cooling tower (_{net-1,net}),

There is a loss of water in the cooling towers by evaporation (_{ev,net}) and the drift of water by the air flowrate (_{d,net}). The water evaporated is obtained from the following relationship:

while the drift loss of water is 0.2 percent of the inlet water flowrate to the cooling tower (Kemmer, 1988):

Thus, for each cooling tower, the outlet water flowrate is given by the following expression:

and the outlet cooling tower flowrate (_{out,net}) can be split and sent to the next cooling tower and/or to the end of the cooling tower network (_{net}),

The flowrate (_{dis}) and temperature (_{dis}) for the end of the cooling tower network are the sum of the bypassed flowrates of the cooling medium streams and the outlet cooling tower flowrates,

To avoid salts deposition, usually a little blowdown flowrate (_{b}) is applied over the water flowrate treated in the cooling tower network, which can be determined by,

Note that the last term is the total drift loss of water by the air in the cooling tower network. Also, _{r}is the makeup flowrate and _{CYCLES} is the number of concentration cycles. Then, the outlet flowrate of the cooling tower network (* Fwctn*) is equal to the flowrate at the end of cooling network minus the blowdown,

but the cooling medium temperature in the outlet of cooling network (_{wctn}) is,

To maintain the cooling medium flowrate constant in the cooling system, it is necessary a makeup flowrate to replace the lost water by evaporation, drift and blowdown,

Note that the total water evaporated and drift loss of water in the cooling tower network are considered. The flowrate required by the cooling network (_{in}) is determined as follow:

and the inlet cooling medium temperature to the cooling network is obtained from,

To avoid mathematical problems, the recycle between cooling towers is not considered; therefore, it is necessary to specify that the recycle in the same cooling tower and from a cooling tower of the stage * nct*to the cooling tower of stage

*is zero,*nct-1

The following relationships are used to model the design equations for the cooling towers to satisfy the cooling requirements for the cooling network. First, the following disjunction is used to determine the existence of a cooling tower and to apply the corresponding design equations,

Here

where _{nct}, is calculated using the four-point Chebyshev integration technique (Mohiudding and Kant, 1996),

where * n*is the temperature-increment index. For each temperature increment, the local enthalpy difference (

and the algebraic equations to calculate the enthalpy of bulk air-water vapor mixture and the water temperature corresponding to each Chebyshev point are given by,

where _{n}is a constant that represents the Chebyshev points (_{1}=0.1, _{2}=0.4, _{3}=0.6 and _{4}=0.9). The heat and mass transfer characteristics for a particular type of packing are given by the available Merkel number correlation developed by Kloppers and Kröger (2005):

To calculate the available Merkel number, the following disjunction is used through the Boolean variable

Notice that only when the cooling tower * ntc*exists, its design variables are calculated and only one fill type must be selected; therefore, the sum of the binary variables referred to the different fill types must be equal to the binary variable that determines the existence of the cooling towers. Then, this disjunction can be described with the convex hull reformulation (Vicchietti et al., 2003) by the following set of algebraic equations:

Values for the coefficients

The corresponding disjunction is given by,

Using the convex hull reformulation (Vicchietti et al., 2003), previous disjunction is modeled as follows:

e=1 (splash fill) | e=2 (trickle fill) | e=3 (film fill) | |

0.249013 | 1.930306 | 1.019766 | |

2 | -0.464089 | -0.568230 | -0.432896 |

3 | 0.653578 | 0.641400 | 0.782744 |

4 | 0 | -0.352377 | -0.292870 |

5 | 0 | -0.178670 | 0 |

Values for the coefficients

where _{m,nct}is the arithmetic mean air-vapor flowrate through the fill in each cooling tower,

e=1 (splash fill) | e=2 (trickle fill) | e=3 (film fill) | |

1 | 3.179688 | 7.047319 | 3.897830 |

2 | 1.083916 | 0.812454 | 0.777271 |

3 | -1.965418 | -1.143846 | -2.114727 |

4 | 0.639088 | 2.677231 | 15.327472 |

5 | 0.684936 | 0.294827 | 0.215975 |

6 | 0.642767 | 1.018498 | 0.079696 |

The air-vapor flow at the fill inlet and outlet _{in,nct}and _{out,nct}are calculated as follows:

where _{in,nct}is the humidity (mass fraction) of the inlet air, and _{out,nct}is the humidity of the outlet air. The required power for the cooling tower fan is given by:

where

where _{fi,t}), which depends on the arrangement of the cooling tower network (i.e., parallel (_{fi,t,pl}) or series (_{fi,t,s}));

If the arrangement is in parallel, the total fill height is equal to the fill height of the tallest cooling tower, but if the arrangement is in series, the total fill height is the sum of the cooling towers used in the cooling tower network. This decision can be represented by the next disjunction,

This last disjunction determines the existence of flowrates between cooling towers. Following disjunction is used to activate the arrangement in series,

here

If a series arrangement does not exist, then a parallel arrangement is used. In this case, the total fill height is calculated using the next disjunction based on the Boolean variable

The reformulation for the disjunction is:

Notice that when

Finally, an additional equation is necessary to specify the fill height of each cooling tower depending of the type of arrangement,

According to the thermodynamic, the outlet water temperature in the cooling tower must be lower than the lowest outlet process stream of the cooling network and greater than the inlet wet bulb temperature; and the inlet water temperature in the cooling tower must be lower than the hottest inlet process stream in the cooling network. Additionally, to avoid the fouling of the pipes, 50º C usually are specified as the maximum limit for the inlet water temperature to the cooling tower (Serna-González et al., 2010),

here * TMPO*is the inlet temperature of the coldest hot process streams,

*is the inlet temperature of the hottest hot process stream. The final set of temperature feasibility constraints arises from the fact that the water stream must be cooled and the air stream heated in the cooling towers,*TMPI

The local driving force (_{nct}-_{nct}) must satisfy the following condition at any point in the cooling tower (Serna-González et al., 2010),

The maximum and minimum water and air loads in the cooling tower are determined by the range of test data used to develop the correlations for the loss and overall mass transfer coefficients for the fills. The constraints are (Kloppers and Kröger, 2003, 2005),

Although a cooling tower can be designed to operate at any feasible _{in,nct}_{nct}ratio, Singham (1983) suggests the following limits:

The flowrates of the streams leaving the splitters and the water flowrate to the cooling tower have the following limits:

The objective function is to minimize the total annual cost of cooling systems (* TACS*) that consists in the total annual cost of cooling network (

*), the total annual cost of cooling towers (*TACNC

*) and the pumping cost (*TACTC

*),*PWC

where _{Y}is the yearly operating time and * ce*is the unitary cost of electricity. The total annual cost for the cooling network is formed by the annualized capital cost of heat exchangers (

*) and the cooling medium cost (*CAPCNC

*).*OPCNC

where the capital cooling network cost is obtained from the following expression,

Here _{i}is the fixed cost for the heat exchanger * i*,

CAHE

_{i}is the cost coefficient for the area of heat exchanger

*,*i

K

_{F}is the annualization factor, and

where _{i}is the overall heat-transfer coefficient, _{i}and _{cu}are the film heat transfer coefficients for hot process streams and cooling medium, respectively.

In addition, the operational cost for the cooling network is generated by the makeup flowrate used to replace the lost of water in the cooling towers network,

where * CUw*is the unitary cost for the cooling medium. The total annual cost of cooling towers network involves the investment cost for the cooling towers (

*) as well as the operational cost (*CAPTNC

*) by the air fan power of the cooling towers. The investment cost for the cooling towers is represented by a nonlinear fixed charge expression of the form (Kintner-Meyer and Emery, 1995):*OPTNC

where _{CTF}is the fixed charge associated with the cooling towers, _{net}is the incremental cooling towers cost based on the tower fill volume, and _{CTMA}is the incremental cooling towers cost based on air mass flowrate. The cost coefficient _{net}depends on the type of packing. To implement the discrete choice for the type of packing, the Boolean variable

This disjunction is algebraically reformulated as:

where the parameters ^{e}are 2,006.6, 1,812.25 and 1,606.15 for the splash, trickle, and film types of fill, respectively. Note that the investment cost expression properly reflects the influence of the type of packing, the air mass flowrate (_{net}) and basic geometric parameters, such as height (_{fi,nct}) and area (_{fi,nct}) for each tower packing. The electricity cost needed to operate the air fan and the water pump of the cooling tower is calculated using the following expression:

This section shows the physical properties that appear in the proposed model, and the property correlations used are the following. For the enthalpy of the air entering the tower (Serna-González et al., 2010):

For the enthalpy of saturated air-water vapor mixtures (Serna-González et al., 2010):

For the mass-fraction humidity of the air stream at the tower inlet (Kröger, 2004):

where _{WB,in}is calculated from Equation (115) and evaluated at _{in}. For the mass-fraction humidity of the saturated air stream at the cooling tower exit (Kröger, 2004):

where _{out}is the vapor pressure estimated with Equation (115) evaluated at _{out}* ,*and

P

_{t}is the total pressure in Pa. Equation (115) was proposed by Hyland and Wexler (1983) and is valid in the range of temperature of 273.15 K to 473.15 K,

* PV*is the vapor pressure in Pa,

*is the absolute temperature in Kelvin, and the constants have the following values:*T

c

_{-1}= 5.8002206 x 10

^{3},

c

_{0}= 1.3914993,

c

_{1}= -4.8640239 x 10

^{-3},

c

_{2}= 4.1764768 x 10

^{-5}and

c

_{3}= -1.4452093 x 10

^{-7}. For the outlet air temperature, Serna-González et al. (2010) proposed:

For the density of the air-water mixture (Serna-González et al., 2010):

where _{t}and * T*are expressed in Pa and K, respectively. The density of the inlet and outlet air are calculated from the last equation evaluated in

T = TA

_{in}and

T = TA

_{out}for

w = w

_{in}and

w = w

_{out}, respectively.

## 3. Results

Two examples are used to show the application of the proposed model. The first example involves three hot process streams and the second example involves five hot process streams. The data of these examples are presented in Table 3. In addition, the value of parameters * ce*,

H

_{Y},

K

_{F},

N

_{CYCLES}

, η

_{f},

η

_{p},

P

_{t}, C

_{CTF},

C

_{CTMA},

CU

_{w},

CP

_{cu},

*,*β

*,*CFHE

*are 0.076 $US/kWh, 8000 hr/year, 0.2983 year*CAHE

^{-1}, 4, 0.75, 0.6, 101325 Pa, 31185 $US, 1097.5 $US/(kg dry air/s), 1.5449x10

^{-5}$US/kg water, 4.193 kJ/kg°C, 1, 1000$US, 700$US/m

^{2}, respectively. For the Example 1, fresh water at 10 °C is available, while the fresh water is at 15º C for the Example 2.

For the Example 1, the optimal configuration given in Figure 3 shows a parallel arrangement for the cooling water network. Notice that one exchanger for each hot process stream is required. In addition, only one cooling tower was selected; consequently, the cooling tower network has a centralized system for cooling the hot process streams. The selected packing is the film type, and the lost water is 13.35 kg/s due to the evaporation lost (75%), and the drift and blowdown water (4.89% and 20.11%), while a 70.35% of the total power consumption is used by the fan and the rest is used by the pump (29.64%). The two above terms represent the total operation cost of the cooling system; therefore, both the evaporated water and the power fan are the main components for the cost in this example. Notice that the water flowrate in the cooling network is 326.508 kg/s, but the reposition water only is 13.25 kg/s, which represents a save of freshwater of 95.94% respect to the case when is not used a cooling tower for thermal treatment of the cooling medium. The total annual cost is 468,719.906$US/year. The contribution to total annual cost for the cost of cooling network is 66%, while for cooling tower network and the pump are 31% and 2.96%, respectively. These results are given in the Table 4.

Respect to the Example 2, Figure 4 presents the optimal configuration, which shows a parallel arrangement to the cooling water network, while the cooling towers network is formed by a distributed system composed by two cooling towers to treat the effluents from the cooling network and to meet the cooling requirements. The selected fill is the film type, and the lost water by evaporation, drift and blowdown represent a 74.99%, 3.94% and 21.07% of the total water lost, respectively. Respect the total power consumption in the cooling system, the fan demands a 65.37% and the pump use a 34.62% of the total cost. The economical results are given in the Table 4. The optimal cooling system shows costs for the cooling network, cooling tower and water pump equal to 61.21%, 36.34% and 2.44%, respectively, of the total annual cost. In addition, for the case that only one cooling tower is selected, the total annual cost is 143,4326.66$US/year, which is 7% more expensive than the optimal configuration. The savings obtained are because the distributed system is able to find a better relationship between the capital cost and the operation cost, which depends of the range, inlet water flowrate and inlet air flowrate to the cooling tower network; therefore,

in the distributed systems there are more options. In this case, the use of freshwater by the cooling network is reduced by 94.92% with the use of the cooling towers. Other advantage of use a distributed system is that depending of the problem data just one cooling tower could not meet with the operational and/or thermodynamic constraints and could be necessary to use more than one cooling tower.

THIN (ºC) | THOUT (ºC) | FCP (kW/ºC) | Q (kW) | h (kW/m^{2}ºC) | |

40 | 76.6 | 100 | 3660 | 1.089 | |

60 | 82 | 60 | 1320 | 0.845 | |

45 | 108.5 | 400 | 25540 | 0.903 | |

THIN (ºC) | THOUT (ºC) | FCP (kW/ºC) | Q (kW) | h (kW/m^{2}ºC) | |

80 | 60 | 500 | 10000 | 1.089 | |

75 | 28 | 100 | 4700 | 0.845 | |

120 | 40 | 450 | 36000 | 0.903 | |

90 | 45 | 300 | 13500 | 1.025 | |

110 | 40 | 250 | 17500 | 0.75 |

468,719.906 | 1,334,977.470 | |

309,507.229 | 817,192.890 | |

145,336.898 | 485,196.940 | |

6,131.013 | 16,588.250 | |

32,958.635 | 61,598.140 | |

13,875.780 | 32,587.640 | |

303,376.216 | 800,604.640 | |

112,378.262 | 181,000.330 |

## 4. Conclusion

This chapter presents a new model for the detailed optimal design of re-circulating cooling water systems. The proposed formulation gives the system configuration with the minimum total annual cost. The model is based on a superstructure that considers simultaneously series and parallel arrangements for the cooling water network and cooling tower network, in which the cooling medium can be thermally treated using a distributed system. Significant savings were obtained with the distributed cooling systems for the interconnection between cooling water network and cooling towers. Evaporation represents the main component for the lost of water (70-75%); while the drift and blowdown represent the 3-5% and 20-25%, respectively. The fan power consumption usually represents the 65-70% of the total power consumption in the cooling system; and the pump represents around the 30-35%. For re-circulating cooling water systems the costs of cooling network, cooling tower network and the water pump represent the 60-70%, 30-40% and 2-5% of the total cooling system cost, respectively. When re-circulating cooling water systems are used, the use of freshwater in the cooling network is significantly reduced (i.e., 95%).