Examples of bioactive compounds from plant- and animal-derived by-products and the applied extraction techniques.
\r\n\t- Breeding and Molecular Breeding
\r\n\t- Tissue Culture and Somatic Hybrids
\r\n\t- Diseases and their Management
\r\n\t- Value Addition
\r\n\t- Genomics, Genetics, and Biotechnology
\r\n\t- Whole-Genome Sequencing and QTL mapping
\r\n\t- Genetic transformation and trait development, etc
\r\n\t
Food represents as one of the most basic human needs, providing our physical integrity. The entire planet is facing an alarming issue, regarding the amount of edible food and by-products, which are wasted in an increasingly manner. Moreover, food manufacturing requires resources such as soil and water and involves various processes, which generate huge amounts of food waste. As the production of food is resource-intensive, food losses and wastes are strongly correlated with a broad range of environmental problems, such as water and air pollution, soil erosion, and greenhouse gas emissions; all of these undesirable effects occur in all stages of production, storage, and transportation as well as in the case of adopting a deficient management system [1].
The generation of food waste is inevitable, especially during the pre-consumption stage. It is estimated that up to 42% of food waste is generated from household activities, 39% occur from the food manufacturing industry, and 14% occur from the food service sector (catering and restaurants), while 5% is lost during storage and distribution. This problem is intensified by the global population growth leading consequently to an increasing demand for natural resources like food and energy [2, 3].
Nowadays, the biggest challenge of the scientific world is to provide viable alternative models that combine food production with an efficient valorization strategy of waste and by-product, minimization of energy consumption, and environmental protection. In this context, the exploitation of food waste or by-products for the recovery of valuable functional compounds can be considered as being one of the most feasible approaches [4].
In order to implement a circular economy in any industrial sector, two main strategies are needed: reducing waste levels and finding the most sustainable solution to manage the remaining waste. In particular, the waste management of new strategies focus on the following actions: waste prevention, reuse, recycling, energy recovery, and, lastly, disposal [5].
Until a few decades ago, food waste was considered neither a cost nor a benefit being usually discarded to landfills, sent for composting, or used as animal feed. The negative perception on these by-products and implicitly the application of a deficient management lead to environmental degradation and especially to significant loss of valuable material that could otherwise be exploited as food, fuels, and a great variety of additives [6].
At present, the attitude has changed radically, the researches being intensely oriented toward the identification and extraction of valuable compounds from residues and their reintegration in the food industry but also in other fields such as cosmetics, pharmaceuticals, or agriculture (Figure 1).
The main applications of bioactive compounds extracted from agri-food waste.
Using the recovered bioactive molecules as functional ingredients represents a sustainable alternative of food waste exploitation as an inexpensive source of valuable compounds while developing innovative food and nonfood products with health-promoting benefits and at the same time contributing to an efficient waste reduction management.
Most of the wastes generated by the agri-food industries are difficult to store, transport, and process because of the biological instability, pathogenic potential, high levels of nutrients or enzyme activity, high water content, and the potential for self-oxidation.
The new aspects concerning the use of agri-food wastes as by-products for further exploitation in the production of various functional products must be environmentally friendly and sustainable from the economic point of view [7, 8, 9]. Therefore, it is imperative to identify the most feasible and optimized stabilization methods in order to ensure a flow of biomass with a constant composition and reduced storage and transport costs.
For this purpose, technological innovation has favored the development of many effective exploitation methods, with cogeneration of electricity and thermal biogas, also called green energy. In addition, the implementation of a biorefinery concept offers remarkable opportunities to valorize biomass by converting it to a wide range of chemicals with many applications in food, cosmetic, and pharmaceutical industries [10, 11].
The innovative approach of converting food waste in new generation of useful products involves the application of unconventional methods and advanced techniques in order to model the most appropriate and sustainable recovery system (Figure 2).
A schematic representation of the most used conventional and novel techniques suitable for extracting biomolecules.
Nevertheless, the extraction protocols cannot be used indiscriminately, and their choice depends on the type of bioactive compounds and matrix structure, the processing scale (pilot or industrial level), the balance between processing costs and economic income of the recovered component, and their new assigned destinations [6].
In the last years, the researches focused on the development and optimization of the methods for the recovery and purifications of the functional compounds; some of them are based on new emerging techniques, but some are effective by applying and modeling the existing conventional method. In both situations, the extraction of the high-value components must be environmentally friendly and economically feasible to perform.
The applied parameters have a major impact on the release of the bioactive compounds from the matrix but also on their structure and functionality. Therefore, selecting the most suitable extraction protocol is a decisive step for the recovery of the valuable component [6, 9, 12].
Several examples of bioactive compounds recovered from food processing by-products and the selected extraction methods are presented in Table 1.
Recovered compounds | Waste source | Extraction method | Ref. |
---|---|---|---|
Polysaccharide/dietary fibers | Fruits pomace, sugar beet, sunflower heads | Solid-liquid extraction | [13] |
Citrus peel and apple pomace | Subcritical water extraction | [14] | |
Cereal by-products | Enzymatic treatment and sequential extraction | [15] | |
Apple pomace | Hot-compressed water | [16] | |
Organic acids | [17] | ||
Olive mill wastewaters | Ultrafiltration and nanofiltration | [18] | |
Rice bran | Microwave treatment and microbial fermentation | [19] | |
Phenolic compounds | Apple pomace | Microwave-assisted extraction | [20] |
Electric field-assisted extraction | [21] | ||
Tomato pomace and skin | Enzymatic-assisted extraction/solvent extraction | [22] | |
Potato peels | Microwave-assisted extraction | [23] | |
Olive cake | Ultrasound-assisted extraction | [24] | |
Avocado peel and seeds | Solvent extraction | [25] | |
Wheat beans | Ultrasound-assisted extraction | [26] | |
Tea by-products | Supercritical fluid extraction; microwave-assisted extraction/solvent extraction | [27, 28] | |
Bran and germs | Ultrasound-assisted extraction | [29] | |
Grape by-products | Ultrafiltration | [30] | |
High-voltage electrical discharges and ultrafiltration | [31] | ||
Supercritical fluid extraction | [32] | ||
Solvent extraction/microwave-assisted extraction/ultrasound-assisted extraction | [33] | ||
Blueberry residue | Supercritical fluid extraction and pressurized liquids | [34] | |
Flax seeds | Solid-liquid extraction | [35] | |
Caffeine | Tea waste | Microwave-assisted extraction/solvent extraction | [28] |
Oils | Rice bran | Supercritical carbon dioxide extraction and compressed liquefied petroleum gas/solid-liquid extraction | [36, 37] |
Essential oils | Citrus peel | Solvent extraction/hydrodistillation | [38] |
Steam explosion at high temperature and pressure | [39] | ||
Microwave-assisted hydro-diffusion | [40] | ||
Proteins | Brewers’ spent grain | Sequential extraction of proteins and arabinoxylans; enzymatic-assisted extraction | [15, 41] |
Rice by-products | Enzymatic hydrolysis and membrane filtration technique | [42] | |
Hazelnut meal | Solvent extraction (water, acetone) | [43] | |
Rapeseed by-products | Ultrasound-assisted aqueous extraction | [44] | |
Carotenoids | Tomato pomace and skin | Enzymatic-assisted extraction | [45] |
Supercritical fluid extraction/solvent extraction | [46] | ||
Supercritical fluid extraction | [47] | ||
Citrus peel | Ultrasound-assisted extraction | [48] | |
Sea buckthorn seeds | Supercritical carbon dioxide fluid extraction | [49] | |
Proteins and bioactive peptides | Whey wastewater | Membrane separation/ultrafiltration/microfiltration/nanofiltration/reverse osmoses | [50] |
Mild enzymatic hydrolysis | [51] | ||
Cheese whey | Ultrafiltration/nanofiltration | [52] | |
Fish and chicken | Isoelectric solubilization and precipitation | [53] | |
Sardine solid waste | Enzymatic hydrolysis and ultrafiltration | [54] | |
Shellfish | Enzymatic hydrolysis and micro-, ultra-, and nanofiltration/ion exchange chromatography | [55] | |
Sugars | Whey wastewater | Membrane separation and spray drying | [50] |
Cheese whey | Ultrafiltration/nanofiltration | [52] |
Examples of bioactive compounds from plant- and animal-derived by-products and the applied extraction techniques.
Beside the possibilities mentioned before for the proper management of food waste and its valorization through the recovery of the bioactive compounds, we also need to consider the role of food preservation to reduce food waste. Following harvest, slaughter, or manufacture, all foods start to lose quality. The rate at which food quality is lost is dependent on food type, composition, the way it was processed, packed and storage conditions. On the other hand, the lost of quality and safety attributes of the foods may occur at any stage in the food chain generating food waste: raw material storage; product formulation; processing; packaging; storage in the factory; distribution to depots and storage; distribution to retail outlets; display in stores; sale to the consumer and further storage; preparation for consumption. Nonetheless, by applying conventional, highly advanced or hurdle preservation techniques (Figure 3), one can impede the chemical or microbiological deteriorations, thus preventing outbreaks of foodborne illness and at the same time limiting the food waste. As it is illustrated in Figure 3, in the food industry, beside the commonly used preservation techniques, a number of new ones are being developed to satisfy the current demands of economic preservation and consumer satisfaction in safety, nutritional and sensory aspects. Also, as the preservation of foods is often a multicomponent issue, the “hurdle” concept was introduced, highlighting the complex interaction between the factors that are significant for food safety and stability [56, 57, 58].
A schematic representation of the most used conventional and novel techniques for foods preservation.
The idea of converting the agri-food waste into functional ingredients is an area of research with huge potential and opportunities. Many researches in biotechnology have already shown that agri-food by-products are no longer regarded as a waste but rather a valuable substrate for producing a new range of useful compounds. Based on this, it is an undeniable fact that, through compatible biotechnological processes, every food processing by-product possesses a relevant potential for a sustainable reuse.
The recent findings, presented in the chapters of this book, highlighted the potential reuse of food industry by-products and led to the idea that multidisciplinary approaches should be implemented in order to achieve the most effective exploitation protocol or to develop integrated biorefineries
This work was supported by three grants of Ministry of Research and Innovation, CNCS - UEFISCDI, project number PN-III-P1-1.1-PD-2016-0869, CNCS - UEFISCDI, project number PN-III-P1-1.1-TE-2016-0973 and CNCS-UEFISCDI Projects for Financing the Excellence in CDI, Contract no. 37PFE/06.11.2018.
Polyimide (PI) is used as insulating material for resist surface discharge because of its excellent electrical, thermal, and mechanical characteristics [1, 2]. PI films are usually expected to withstand surface discharge caused by repetitive impulse voltages. For example, surface partial discharge occurs during lifetime of turn-to-turn insulation of inverter-fed traction motors due to the driven pulse width modulation (PWM) converters, which has become one of the most important factors for surface degradation and final premature failures of the insulation of inverter-fed traction motors. Therefore, the PD-dependent lifetime of PI films under repetitive impulse voltages needs to be improved to meet the requirement for rapid development of industry applications [3, 4].
To provide a comprehensive understanding to lifetime of PI under repetitive impulse voltages and to clarify the emerging problems, we review the recent progress in partial discharge characteristics, degradation, and charge storage effect under repetitive impulse voltages. Particular attention is paid on lifetime improvement approaches, such as using nanocomposites and surface modification.
Figure 1 shows the system for testing lifetime and partial discharge characteristics of polyimide under repetitive impulse voltages. Bipolar continuous square impulse voltage was conducted. The amplitude, risetime, duty cycle, and frequency of applied voltage were 1 kV, 40 ns, 50%, and 10 kHz, respectively. The electrodes used in the test were designed according to the standard of ASTM 2275 01, including a rod electrode, a plate electrode, and an insulating board [5]. By this configuration, we can obtain the voltage endurance of solid electrical insulating materials subjected to surface partial discharges. The PD signal was measured by an UHF antenna.
Schematic diagram of the PD aging test system.
Figure 2 shows the lifetime of PI under repetitive impulse voltages, which decreases sharply with increasing temperature. The lifetime values are much shorter than that under AC voltages [6].
Lifetime of PI under repetitive impulse voltages [6].
Figure 3 shows the PD characteristics, including the PDIV, PD amplitude, and PD number, of PI films under repetitive impulse voltages as a function of temperature. PDIV decreases with increasing temperature; on the contrary, PD amplitude and PD number increase with increasing temperature. All these parameters are higher than that under AC voltages [6].
PD characteristics of PI films with increasing temperature. (a) PDIV, (b) PD amplitude, (c) PD number.
Due to the electrode structure as shown in Figure 2, surface discharge would occur in the air gap between the sample and the upper rod electrode during lifetime testing. Certain region on the film surface, as shown in Figure 4, would be corroded by surface discharge generating high-energy electrons, ultraviolet rays, and high-activity chemical groups [7, 8]. The microtopography of PI films after 3-h aging and breakdown (lifetime: 6 h and 10 min) under repetitive impulse voltages is shown in Figure 5. An obvious circle can be seen on the surface of aged PI film, which is eroded as the consequence of surface discharge, resulting in surface roughness and morphology changing. From the microscopic view of the breakdown point as shown in Figure 5(b), the mesh structure and voids can be observed on the surface microtopography around the breakdown point obviously, indicating degradation of PI occurred during discharge.
Sample discharge area and eroded area of sample [6].
Microtopography of PI films after 3-h aging and breakdown. (a) 3-h aging and (b) breakdown.
Under repetitive impulse voltages, partial discharge-induced degradation would be intensified because of charge storage effect. We discuss the electrical field distribution on discharge region of the sample surface, as shown in Figure 6, where Ei is the electric field in the air gap between the sample and the edge of the upper electrode. When external electric field reverses, accumulated charges on the film surface will enhance the electric field in the air gap between the rod and the sample, as shown in Figure 6. Assuming the external electric field is negative, the charge-induced electric field in the air gap Eq is proportional to the difference between the charges on the rod electrode Qup and that on the film surface Qdown, namely, Eq (Qup − Qdown). Thus, the effective electric field in the air gap can be obtained, Ei = Et + Eq, where Et is the external electric field. Since the charges on the film surface are unable to dissipate in such short rising time, the Qdown can be considered as a constant. When the external electric field reverses and becomes positive, the Eq is proportional to the sum of the charges on the rod electrode Qup and that on the film surface Qdown, namely, Eq (Qup + Qdown). As the charge continues accumulating, the value of Ei can increase to a critical value, and then PD would take place.
The electric field change in air gap when external electric field inverses from negative to positive side [9].
PD characteristics and lifetime repetitive impulse voltages would be improved by using polyimide nanocomposites. Figure 7(a) shows the PDIV of PI and PI/Al2O3 nanocomposites. PDIV increases with increasing nano-alumina content. The PDIV of PI/Al2O3 (8 wt.%) increases from 693 to 782 V (12.8% increase) compared with that of PI. This means the discharge threshold is much higher for PI/Al2O3 nanocomposites. Figure 7(b) gives the PD amplitude and number recorded in 1 min, which both decrease with increasing nano-alumina content, revealing that the decrease in PD intensity is attributed to the effect of nano-alumina.
PD characteristics of PI and PI/Al2O3 nanocomposites. (a) PDIV and (b) PD amplitude [9].
As shown in Figure 8, the PD resistance is enhanced significantly as the content of nano-alumina increases. The lifetime values of PI/Al2O3 with nano-alumina content of 0, 2, 5, and 8 wt.% are 37.8, 52.1, and 61.9 min, increasing by 92.8, 165.8, and 215.8% respectively, compared with that of PI. This demonstrates that the nano-alumina helps to prolong the lifetime of PI.
Lifetime of PI and PI/Al2O3 nanocomposites under PD aging [9].
In polyimide nanocomposites, the melting point of nano-alumina particles is higher than that of polyimide. Under the effect of surface discharge, nanoparticles float on the film surface, forming a protective layer to prevent the polyimide matrix from further erosion. This layer, therefore, is able to mitigate the PD effects on films and block the erosion path, which can help avoid the same local point being eroded continuously. In contrast, without nanoparticles, the erosion will follow a specific path and lead to breakdown much faster. This is why there are a number of micro-cavity groups in PI/Al2O3 nanocomposites but only a few big cavities in the PI films, as shown in Figure 6c and d. Thus, the incorporation of nanoparticles improves the physical characteristics of PI/Al2O3 nanocomposites, because nanoparticles can act as obstacles in the erosion path, and then the degradation of polymer can be reduced, and prolonged lifetime of PI/Al2O3 nanocomposites can be obtained subsequently.
In addition, some acid compounds (e.g., the amic acid and the nitric acid) are generated during PD aging. Meanwhile, new bonds in PI/Al2O3 nanocomposites are the weakest, subsequently the ether linkage, imide ring, and then aromatic ring. Those weakest bonds in interfacial regions would be destroyed at the first stage of aging, so the dissociations of polyimide molecules would be reduced. Because of the chemical bonding between nanoparticles and PI molecules, the degradation of polymer can be reduced, and prolonged lifetime of PI/Al2O3 nanocomposites can be obtained consequently.
Moreover, higher surface conductivity facilitates surface charge dissipation and leads to low PD intensity. Lower trap density is responsible for the low possibility of charge recombination and the corresponding released energy. All these factors improve the electrical characteristics of PI/Al2O3 nanocomposites resulting in reduced degradation of polymer and longer lifetime.
Lifetime of PI under repetitive impulse voltages would be further improved by surface modification. Figure 9 shows the lifetime of PI and PI/Al2O3nanocomposites under repetitive impulse voltages, after being treated by nonthermal plasma in atmospheric air with different treating times. For both PI and PI/Al2O3 nanocomposites, lifetime can be prolonged by plasma treatment. Apparent improvement of lifetime can be seen in the first 20 s of treating time. However, the lifetime decreases with increasing treating time, when the treating time is longer than 20 s. When the treating time exceeds 30 s, the lifetime decreases sharply, by reaching the values even shorter than that of the untreated samples. For plasma-treated samples, with shallower trap energy level, less charge accumulation facilitates charge dissipation and local electric field mitigation, leading to suppressed PD intensity and longer lifetime. Active groups containing oxygen and nitrogen, which are introduced during plasma treatment, are responsible for trap energy distribution modification of PI films. An appropriate treating time is the key factor to introduce reactive groups on film surface and prolong the lifetime.
Lifetime of PI and PI/Al2O3 nanocomposites with different plasma treating times under repetitive impulse voltage.
Structure design is another effective approach to improve lifetime of PI under repetitive impulse voltages. Figure 10 shows the lifetime of PI, PI/Al2O3nanocomposites, and PI/Al2O3-PI-PI/Al2O3 films under repetitive impulse voltages as a function of applied voltage. For all samples, lifetime decreases with increasing applied voltage. As the thickness of these three types of samples is all 60 mm, the lifetime of PI/Al2O3 nanocomposites are the longest. However, the results shown in Figure 10 were tested at room temperature. Considering the effect of temperature, lifetime of PI/Al2O3-PI-PI/Al2O3 films is longest when the temperature is higher than 90°C, as shown in Figure 11. For applications such as inverter-fed motors, the operating temperature of PI is usually higher than 90°C; thus layered structure is an important approach to improve lifetime for industry applications.
Lifetime of PI, PI/Al2O3 nanocomposites, and PI/Al2O3-PI-PI/Al2O3 films under repetitive impulse voltages as a function of applied voltage (room temperature) [10].
Lifetime of PI, PI/Al2O3 nanocomposites, and PI/Al2O3-PI-PI/Al2O3 films under repetitive impulse voltages as a function of temperature (1 kV) [10].
PD-dependent lifetime of PI under repetitive impulse voltages is a key parameter for its industry applications. Due to charge storage effect under repetitive impulse voltages, partial discharge-induced degradation would be intensified, resulting in a shorter lifetime. By using nanocomposites, surface modification, and structure design, the lifetime would be prolonged.
This work was financially supported by National Natural Science Foundation of China (NSFC) (under Grant 51837009 and 51907167) and State Key Laboratory of Electrical Insulation and Power Equipment (EIPE18212).
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