Comparison of the separation techniques.
\r\n\tAnimal food additives are products used in animal nutrition for purposes of improving the quality of feed or to improve the animal’s performance and health. Other additives can be used to enhance digestibility or even flavour of feed materials. In addition, feed additives are known which improve the quality of compound feed production; consequently e.g. they improve the quality of the granulated mixed diet.
\r\n\r\n\tGenerally feed additives could be divided into five groups:
\r\n\t1.Technological additives which influence the technological aspects of the diet to improve its handling or hygiene characteristics.
\r\n\t2. Sensory additives which improve the palatability of a diet by stimulating appetite, usually through the effect these products have on the flavour or colour.
\r\n\t3. Nutritional additives, such additives are specific nutrient(s) required by the animal for optimal production.
\r\n\t4.Zootechnical additives which improve the nutrient status of the animal, not by providing specific nutrients, but by enabling more efficient use of the nutrients present in the diet, in other words, it increases the efficiency of production.
\r\n\t5. In poultry nutrition: Coccidiostats and Histomonostats which widely used to control intestinal health of poultry through direct effects on the parasitic organism concerned.
\r\n\tThe aim of the book is to present the impact of the most important feed additives on the animal production, to demonstrate their mode of action, to show their effect on intermediate metabolism and heath status of livestock and to suggest how to use the different feed additives in animal nutrition to produce high quality and safety animal origin foodstuffs for human consumer.
",isbn:"978-1-83969-404-2",printIsbn:"978-1-83969-403-5",pdfIsbn:"978-1-83969-405-9",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!1,hash:"8ffe43a82ac48b309abc3632bbf3efd0",bookSignature:"Prof. László Babinszky",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/10496.jpg",keywords:"Technological Feed Additives, Feed Industry, Quality of Compound Feed, Non-Antibiotic Growth Promoter, Product Quality, Additive Enzymes, Digestibility of Nutrients, NSP Enzymes, Farm Animals, Livestock, Immunity, Microbiome",numberOfDownloads:null,numberOfWosCitations:0,numberOfCrossrefCitations:null,numberOfDimensionsCitations:null,numberOfTotalCitations:null,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"November 24th 2020",dateEndSecondStepPublish:"December 22nd 2020",dateEndThirdStepPublish:"February 20th 2021",dateEndFourthStepPublish:"May 11th 2021",dateEndFifthStepPublish:"July 10th 2021",remainingDaysToSecondStep:"2 months",secondStepPassed:!0,currentStepOfPublishingProcess:4,editedByType:null,kuFlag:!1,biosketch:"Professor Emeritus from the University of Debrecen, Hungary who authored 297 publications (papers, book chapters) and edited 3 books. Member of various committees and chairman of the World Conference of Innovative Animal Nutrition and Feeding (WIANF).",coeditorOneBiosketch:null,coeditorTwoBiosketch:null,coeditorThreeBiosketch:null,coeditorFourBiosketch:null,coeditorFiveBiosketch:null,editors:[{id:"53998",title:"Prof.",name:"László",middleName:null,surname:"Babinszky",slug:"laszlo-babinszky",fullName:"László Babinszky",profilePictureURL:"https://mts.intechopen.com/storage/users/53998/images/system/53998.jpg",biography:"László Babinszky is Professor Emeritus of animal nutrition at the University of Debrecen, Hungary. From 1984 to 1985 he worked at the Agricultural University in Wageningen and in the Institute for Livestock Feeding and Nutrition in Lelystad (the Netherlands). He also worked at the Agricultural University of Vienna in the Institute for Animal Breeding and Nutrition (Austria) and in the Oscar Kellner Research Institute in Rostock (Germany). From 1988 to 1992, he worked in the Department of Animal Nutrition (Agricultural University in Wageningen). In 1992 he obtained a PhD degree in animal nutrition from the University of Wageningen.He has authored 297 publications (papers, book chapters). He edited 3 books and 14 international conference proceedings. His total number of citation is 407. \r\nHe is member of various committees e.g.: American Society of Animal Science (ASAS, USA); the editorial board of the Acta Agriculturae Scandinavica, Section A- Animal Science (Norway); KRMIVA, Journal of Animal Nutrition (Croatia), Austin Food Sciences (NJ, USA), E-Cronicon Nutrition (UK), SciTz Nutrition and Food Science (DE, USA), Journal of Medical Chemistry and Toxicology (NJ, USA), Current Research in Food Technology and Nutritional Sciences (USA). From 2015 he has been appointed chairman of World Conference of Innovative Animal Nutrition and Feeding (WIANF).\r\nHis main research areas are related to pig and poultry nutrition: elimination of harmful effects of heat stress by nutrition tools, energy- amino acid metabolism in livestock, relationship between animal nutrition and quality of animal food products (meat).",institutionString:"University of Debrecen",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"1",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"University of Debrecen",institutionURL:null,country:{name:"Hungary"}}}],coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"25",title:"Veterinary Medicine and Science",slug:"veterinary-medicine-and-science"}],chapters:null,productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},personalPublishingAssistant:{id:"185543",firstName:"Maja",lastName:"Bozicevic",middleName:null,title:"Ms.",imageUrl:"https://mts.intechopen.com/storage/users/185543/images/4748_n.jpeg",email:"maja.b@intechopen.com",biography:"As an Author Service Manager my responsibilities include monitoring and facilitating all publishing activities for authors and editors. From chapter submission and review, to approval and revision, copyediting and design, until final publication, I work closely with authors and editors to ensure a simple and easy publishing process. I maintain constant and effective communication with authors, editors and reviewers, which allows for a level of personal support that enables contributors to fully commit and concentrate on the chapters they are writing, editing, or reviewing. I assist authors in the preparation of their full chapter submissions and track important deadlines and ensure they are met. I help to coordinate internal processes such as linguistic review, and monitor the technical aspects of the process. As an ASM I am also involved in the acquisition of editors. Whether that be identifying an exceptional author and proposing an editorship collaboration, or contacting researchers who would like the opportunity to work with IntechOpen, I establish and help manage author and editor acquisition and contact."}},relatedBooks:[{type:"book",id:"7144",title:"Veterinary Anatomy and Physiology",subtitle:null,isOpenForSubmission:!1,hash:"75cdacb570e0e6d15a5f6e69640d87c9",slug:"veterinary-anatomy-and-physiology",bookSignature:"Catrin Sian Rutland and Valentina Kubale",coverURL:"https://cdn.intechopen.com/books/images_new/7144.jpg",editedByType:"Edited by",editors:[{id:"202192",title:"Dr.",name:"Catrin",surname:"Rutland",slug:"catrin-rutland",fullName:"Catrin Rutland"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1591",title:"Infrared Spectroscopy",subtitle:"Materials Science, Engineering and Technology",isOpenForSubmission:!1,hash:"99b4b7b71a8caeb693ed762b40b017f4",slug:"infrared-spectroscopy-materials-science-engineering-and-technology",bookSignature:"Theophile Theophanides",coverURL:"https://cdn.intechopen.com/books/images_new/1591.jpg",editedByType:"Edited by",editors:[{id:"37194",title:"Dr.",name:"Theophanides",surname:"Theophile",slug:"theophanides-theophile",fullName:"Theophanides Theophile"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3092",title:"Anopheles mosquitoes",subtitle:"New insights into malaria vectors",isOpenForSubmission:!1,hash:"c9e622485316d5e296288bf24d2b0d64",slug:"anopheles-mosquitoes-new-insights-into-malaria-vectors",bookSignature:"Sylvie Manguin",coverURL:"https://cdn.intechopen.com/books/images_new/3092.jpg",editedByType:"Edited by",editors:[{id:"50017",title:"Prof.",name:"Sylvie",surname:"Manguin",slug:"sylvie-manguin",fullName:"Sylvie Manguin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3161",title:"Frontiers in Guided Wave Optics and Optoelectronics",subtitle:null,isOpenForSubmission:!1,hash:"deb44e9c99f82bbce1083abea743146c",slug:"frontiers-in-guided-wave-optics-and-optoelectronics",bookSignature:"Bishnu Pal",coverURL:"https://cdn.intechopen.com/books/images_new/3161.jpg",editedByType:"Edited by",editors:[{id:"4782",title:"Prof.",name:"Bishnu",surname:"Pal",slug:"bishnu-pal",fullName:"Bishnu Pal"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"72",title:"Ionic Liquids",subtitle:"Theory, Properties, New Approaches",isOpenForSubmission:!1,hash:"d94ffa3cfa10505e3b1d676d46fcd3f5",slug:"ionic-liquids-theory-properties-new-approaches",bookSignature:"Alexander Kokorin",coverURL:"https://cdn.intechopen.com/books/images_new/72.jpg",editedByType:"Edited by",editors:[{id:"19816",title:"Prof.",name:"Alexander",surname:"Kokorin",slug:"alexander-kokorin",fullName:"Alexander Kokorin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1373",title:"Ionic Liquids",subtitle:"Applications and Perspectives",isOpenForSubmission:!1,hash:"5e9ae5ae9167cde4b344e499a792c41c",slug:"ionic-liquids-applications-and-perspectives",bookSignature:"Alexander Kokorin",coverURL:"https://cdn.intechopen.com/books/images_new/1373.jpg",editedByType:"Edited by",editors:[{id:"19816",title:"Prof.",name:"Alexander",surname:"Kokorin",slug:"alexander-kokorin",fullName:"Alexander Kokorin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"57",title:"Physics and Applications of Graphene",subtitle:"Experiments",isOpenForSubmission:!1,hash:"0e6622a71cf4f02f45bfdd5691e1189a",slug:"physics-and-applications-of-graphene-experiments",bookSignature:"Sergey Mikhailov",coverURL:"https://cdn.intechopen.com/books/images_new/57.jpg",editedByType:"Edited by",editors:[{id:"16042",title:"Dr.",name:"Sergey",surname:"Mikhailov",slug:"sergey-mikhailov",fullName:"Sergey Mikhailov"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"371",title:"Abiotic Stress in Plants",subtitle:"Mechanisms and Adaptations",isOpenForSubmission:!1,hash:"588466f487e307619849d72389178a74",slug:"abiotic-stress-in-plants-mechanisms-and-adaptations",bookSignature:"Arun Shanker and B. Venkateswarlu",coverURL:"https://cdn.intechopen.com/books/images_new/371.jpg",editedByType:"Edited by",editors:[{id:"58592",title:"Dr.",name:"Arun",surname:"Shanker",slug:"arun-shanker",fullName:"Arun Shanker"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"878",title:"Phytochemicals",subtitle:"A Global Perspective of Their Role in Nutrition and Health",isOpenForSubmission:!1,hash:"ec77671f63975ef2d16192897deb6835",slug:"phytochemicals-a-global-perspective-of-their-role-in-nutrition-and-health",bookSignature:"Venketeshwer Rao",coverURL:"https://cdn.intechopen.com/books/images_new/878.jpg",editedByType:"Edited by",editors:[{id:"82663",title:"Dr.",name:"Venketeshwer",surname:"Rao",slug:"venketeshwer-rao",fullName:"Venketeshwer Rao"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"4816",title:"Face Recognition",subtitle:null,isOpenForSubmission:!1,hash:"146063b5359146b7718ea86bad47c8eb",slug:"face_recognition",bookSignature:"Kresimir Delac and Mislav Grgic",coverURL:"https://cdn.intechopen.com/books/images_new/4816.jpg",editedByType:"Edited by",editors:[{id:"528",title:"Dr.",name:"Kresimir",surname:"Delac",slug:"kresimir-delac",fullName:"Kresimir Delac"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}]},chapter:{item:{type:"chapter",id:"38977",title:"Production of Carbon Nanotubes and Carbon Nanoclusters by the JxB Arc-Jet Discharge Method",doi:"10.5772/51964",slug:"production-of-carbon-nanotubes-and-carbon-nanoclusters-by-the-jxb-arc-jet-discharge-method",body:'\nSince the discovery of methods for the mass production of single-walled carbon nanotubes (SWNTs) [1, 2], applications of SWNTs such as transistor devices, biosensing devices, double-layer-type capacitors, transparent electrode films, radio wave absorbents and material hardeners have been studied [3-5]. Large-scale production and improvement of purity of SWNTs by the electric-arc techniques have been developed [6, 7]. However, the efficient production of high-quality and defect-free SWNTs, and metal/semiconductor selected or diameter-controlled production of SWNTs have not yet been achieved. Therefore, basic study of the various methods of producing SWNTs is still important, by which new high-performance routes to producing desired SWNTs are expected to be found.
\nHere, the production of SWNTs and carbon nanoclusters by the arc discharge method utilizing a magnetic field, known as the JxB arc-jet discharge method, has been studied [8-10]. Although the application of a steady-state magnetic field to arc discharge is not such a popular method, electromagnetic force can change the flow of hot gas in the arc region and thus control the production process of carbon clusters. To realize the large-scale production of carbon clusters by the arc discharge method, a revolver-injection-type JxB arc-jet producer was successfully developed by our group, by which the continuous mass production of SWNTs and other carbon clusters can be carried out.
\nAs a result, the more efficient production of SWNTs and other carbon clusters compared with conventional arc discharge methods has been achieved. Here, the development of the JxB arc-jet discharge method and results obtained using the method are described.
\nBy applying a steady-state weak magnetic field (B\n \n 0\n\n = 1 – 5 mT) perpendicular to the discharge current in the arc discharge, the Lorentz force (JxB force) causes the ejection of the arc plasma and surrounding gas in the JxB direction as shown in Fig. 1 [8, 11]. In the 1960s, this force in a pulsed discharge was actively studied in relation to the electric propulsion engine of rockets [12].
\nSchematic diagram of the JxB arc-jet discharge.
Here, this effect is used to eject sublimated carbon atoms in a selected direction. By controlling the magnetic field, control of the hot gas including the carbon material is possible, and suitable conditions to do hot gas reactions for the production of SWNTs and other carbon clusters can be selected. This method can also reduce the influence of the electrode direction and chamber configuration.
\nWhen the discharge current density and applied magnetic field are 50 A/cm2 and 5 mT, respectively, the Lorentz force causing acceleration of electrons and ions is 0.25 N/cm3. When the gas pressure and the gas temperature around the arc are 30 kPa and 5000 K, respectively, the mean free path and collision frequency of electrons are about 0.01 mm and 10 GHz, respectively. Because of this high collision frequency, electrons frequently collide with neutral gas atoms and accelerate them in the JxB direction, resulting in the ejection of hot gas from the arc region. The acceleration time is related to the electron lifetime in the plasma.
\nTo investigate the JxB arc-jet discharge reaction, several types of arc reactors are used. Figure 2 shows a schematic of the reactor used to measure the heat flux of the arc plasma [11]. The reactor is made of stainless steel (18 cm diameter, 20 cm height) and has a carbon anode (8.0 mm), a carbon cathode (15 mm), a viewing port and a movable calorimetric probe. The reactor is evacuated by a rotary pump to a pressure of less than 10 Pa and then closed. After introducing He gas with p(He) = 10 – 80 kPa, discharge starts, where the discharge current is I\n \n d\n = 20 – 80 A and voltage between the electrodes is V\n \n rod\n = 20 - 35 V. At the front and back of the reactor, solenoid coils (20 cm inner diameter) are installed to produce a steady state magnetic field of B\n \n 0\n = 0 - 5 mT.
\nWhen a magnetic field is applied during the discharge, the shape of the arc flame dramatically changes, and a strong plasma flow in the JxB direction can be observed. Figures 3(a) and (b) respectively show side views of the arc flames for B\n \n 0\n = 0 and B\n \n 0\n = 2.0 mT, where p(He)= 40 kPa and I\n \n d\n\n = 80 A. The upper direction is the JxB direction. By applying a magnetic field, the plasma and the hot gas are ejected in the vertically upward direction. The upward flow of carbon particles can sometimes be clearly observed. By developing a calorimeter [11] in which flowing water absorbs the heat flux, the local heat flux is measured and the results are shown in Figs. 4 (a) and (b) [11]. By increasing the magnetic field, the heat flux is localized in the upper part of the arc plasma (FWHM value of about 50 mm). Above the arc plasma, the heat flux monotonically increases.
\nSchematic side view of the arc reactor with a calorimetric probe installed.
Arc flames for B\n \n 0\n = 0 (a) and B\n \n 0\n = 2.0 mT (b) (side views), where p(He)= 40 kPa and I\n \n d\n = 80 A.
Radial profiles (a) and vertical profiles (b) of heat flux above the arc plasma for B\n \n 0\n = 0, 1.0, 2.0 and 3.0 mT. p(He)= 40 kPa and I\n \n d\n = 60 A.
The heat flux above the arc plasma as a function of He gas pressure is measured and shown in Fig. 5(a), where I\n \n d\n = 60 A, d\n \n G\n = 5 mm, and the distance from the arc center is 40 mm. The heat flux increases monotonically with the pressure, which is particularly in the case of B\n \n 0\n = 2.0 mT. Figure 5(b) shows the heat flux above the arc plasma as a function of the gap distance between the two electrodes d\n \n G\n , where p= 40 kPa, I\n \n d\n = 60 A and z= 40 mm. By changing d\n \n G\n , the effect of the arc jet changes, which can be observed from the viewing port. The heat flux gradually increases with the gap distance, and this effect is greatly enhanced when B\n \n 0\n = 2.0 mT.
\nTo summarize these results, that the JxB arc jet is enhanced by increasing the applied magnetic field (B\n \n 0\n = 0 - 3.0 mT), the He pressure and the gap distance. However, under a stronger magnetic field of B\n \n 0\n > 4 mT, the discharge tends to be extinguished easily by fluctuation in the discharge.
\n(a) He pressure dependence of the heat flux, where I\n \n d\n = 60 A, d\n \n G\n = 5 mm and z= 40 mm from the arc center. (b) Gap distance dependence of the heat flux, where p= 40 kPa, I\n \n d\n = 60 A and z= 40 mm.
In the case of gas arc discharge, gravity induces strong heat convection. Therefore, by changing the current direction relative to that of gravity, different production characteristics of carbon can be expected [13]. Direction of the \n JxB\n\n force compared with that of gravity should also be an important parameter. To examine the relations among the directions of the discharge current, magnetic field and gravity for the production of fullerenes, five experimental configurations are prepared and a discharge experiment is carried out. The 5 configurations are shown in Fig. 6. Here, the carbon anode is 6.5 mm in diameter and the carbon cathode is 15 mm in diameter.
\nSchematic of five experimental configurations. The directions of the discharge current J and magnetic field B relative to that of gravity G\n \n 0\n are changed.
The production rates of carbon soot W\n \n soot\n (g/h) as a function of B\n \n 0\n\n for configurations (types A – E) are obtained and the results are shown in Fig. 7, where p(He) = 40 kPa, I\n \n d\n = 70 A and d\n \n G\n ~ 5 mm [13]. Generally, the soot production rate increases steadily with the magnetic field. However, for type A, W\n \n soot\n is very low for B\n \n 0\n =0 and it rapidly increases with increasing magnetic field. When B\n \n 0\n = 4.0 mT, the differences in W\n \n soot\n are very small among the five configurations.
\nProduction rate of carbon soot versus B\n \n 0\n for the five configurations. p= 40 kPa, I\n \n d\n = 70 A and discharge time T\n \n d\n = 60 min
Production rate of C60 versus B\n \n 0\n for the five configurations. p= 40 kPa, I\n \n d\n = 70 A and discharge time T\n \n d\n = 60 min.
The production rate of C60 as a function of B\n \n 0\n\n for configurations (types A – E) is obtained and the results are shown in Fig. 8, where the conditions are the same us those of Fig. 7. Similarly to in Fig. 7, the C60 production rate generally increases with B\n \n 0\n , except for type A. C60 production rate of type A is very low at B\n \n 0\n = 0. Moreover, for type E, the C60 production rate does not increase monotonically with B\n \n 0\n and the magnetic field does not have a positive effect on the production rate.
\nFrom these results, it can be concluded that the directions of the discharge current and magnetic field compared with that of gravity affect the production of carbon soot and fullerenes. The JxB force tends to reduce the effect of gravity when B\n \n 0\n is sufficiently large. The type A and the Type E are less suitable for the production of fullerenes.
\nThe production of high-quality SWNTs is one of the most important targets in advancing nanomaterial development. The growth model of SWNTs in the arc-discharge reactors has not been confirmed. Several models show importance of catalyst particles in the hot gas, carbon density and catalyst temperature. [14, 15] Here, the production of SWNTs is examined using the JxB arc-jet method, which could modify the growth reactions in the hot gas. In this case, a Ni/Y catalyst is included in the carbon material rods (6.0 x 6.0 mm, rectangular type, 4.2 W% of Ni and 0.9 W% of Y included), and p(He)= 60 kPa and I\n \n d\n\n = 50 A. The soot production rate as a function of applied magnetic field is shown in Fig. 9(a) [16, 17]. By increasing the magnetic field, the production rate monotonically increases. However, further increasing B\n \n 0\n\n to above 3.5 mT makes the discharge unstable. Figure 9(b) shows the pressure dependence of the soot production rate for B\n \n 0\n = 0 and B\n \n 0\n = 2.2 mT. As the pressure increases and the collisional effect of He gas increases, the JxB force clearly affects soot production.
\nUsing this JxB arc-jet method, a large amount of SWNTs is produced from carbon rods including a Ni/Y catalyst. Figure 10 shows a typical TEM image of the produced soot, in which many bundles of SWNTs are included. There are also carbon nanoparticles and catalyst nanoparticles in the soot, which should be removed during the purification of the SWNT products. The quality of the products is measured by a Raman spectrometer (Jasco Co., NR-1800. An Ar ion laser of λ= 488.0 nm is used.), and the results are shown in Figs. 11 (a) and 11(b) for B\n \n 0\n = 0 and B\n \n 0\n = 3.2 mT. In both cases, there are very small D(disorder) band peaks and large G (graphite) band peaks, from which we can estimate the content and quality of SWNTs in the produced carbon soot. These figures show that the JxB arc discharge does not degrade the quality of the SWNTs. From the signals of the radial breathing mode in Fig. 11(a), we can evaluate the SWNT diameters [18]. The major diameter is 1.40 nm, and SWNTs with a diameter of 1.26 nm also exist in the case of B\n \n 0\n = 3.2 mT. SWNTs with diameters of 1.70 nm, 1.16 nm and 1.0 nm also exist in the case of B\n \n 0\n = 0.
\nProduction rate of soot including SWNTs versus B\n \n 0\n (a), where p(He)= 60 kPa and I\n \n d\n = 50 A, and pressure dependence (b), where I\n \n d\n = 50 A.
Typical TEM image of SWNTs produced by the JxB arc-jet discharge method.
Raman spectra of the produced samples for magnetic fields of B\n \n 0\n = 3.2 mT and 0 T. p(He)= 60 kPa and I\n \n d\n = 50 A. λ = 488.0 nm.
Photograph of SWNTs dispersed in pure water.
In the arc production of SWNTs, effect of gas species is examined. Ar, Ne or N2 gas is used instead of He gas, all of which degrade production of SWNTs. When amount of H2 gas is included in He gas, the SWNT production rate considerably decreases, which is not consistent with the previous report [19]. It is conjectured that He atom has high ionization potential, and it causes almost no chemical reactions and less emission loss. When Co or Fe particles are used as catalyst material instead of Ni/Y particles, the SWNT production rate considerably decreases. However, in case of of Co catalyst, a little amount of very long bundles of SWNTs is obtained, which is about 5 cm long. Improvement of the long-SWNT yield by this method is one of our study targets.
\nUsually SWNTs have poor dispersibility in water, which limits their potential applications. Therefore, the development of water-dispersible SWNTs is very important. Here we attempt to dissolve a SWNT sample in pure water. First, a small amount of SWNTs is placed in 20 mL of pure water, which is then mixed using a supersonic homogenizer (Sonics Co., VC-130, 25 W) for about 40 min. Then, a small amount of surfactant is added, which is one of bio-polymers [20, 21]. And it is mixed by sonication again for about 40 min. As a result, the SWNTs are well dispersed in water, and the dispersion remains very stable for more than 1 month. Figure 12 shows a photograph of SWNTs dispersed in water after 50 times dilution. The study of SWNTs dispersed in water is continuing with the aim of realizing biological applications.
\nUsing the above arc-jet discharge methods, endohedral metallofullerenes (such as Gd@C82 and La@C82) [22] and carbon nanocapsules are efficiently produced. Applications of these materials are expected.
\nBy performing arc discharge using a Gd2O3-containing carbon rod (6.0 x 6.0 mm, rectangular), metallofullerenes are produced, where p(He)= 50 kPa and I\n \n d\n\n = 58 A. The production rate of soot is about 2.5 g/h. Figure 13(a) shows a typical TEM image of the sample obtained, in which gadolinium nanoparticles with a diameter on the order of 10 nm are covered with carbon atoms, resulting in the formation of carbon capsules with a size of 10 – 50 nm, which are very stable in air. By refluxing the sample with toluene, fullerenes can be extracted from the soot. After 4 h of reflux, the liquid is filtered and a reddish liquid is obtained. A mass spectrum of this sample obtained using a laser-desorption time-of-flight mass spectrometer (LD-TOF-MS) (Bruker Co., Autoflex, + ion mode, 50 shots averaged) is shown in Fig. 13(b). We can confirm the existence of not only C60 and higher fullerenes but also endohedral metallofullerenes Gd@C82. Although the peak intensities are not quantitative, the relative yield of Gd@C82 compared with that of C60 is several mol%. The Gd@C82 is expected to be used as a contrast agent in MRI [23].
\n(a) TEM image of gadolinium-continuing carbon nanoparticles produced by the arc-jet discharge method. (b) LD-TOF-MS spectrum of a carbon sample extracted from soot using toluene.
Using the JxB arc-jet discharge method, many types of metal-particle-encapsulated carbon nanoparticles [24, 25] can be easily produced. As examples, iron-encapsulated carbon nanoparticles and cobalt-encapsulated carbon nanoparticles have been produced. Both are ferromagnetic nanoparticles with a size of 10 - 100 nm, and are very stable.
\nUsing iron-containing carbon rods (6.0 x 6.0 mm, rectangular), iron-encapsulated carbon nanoparticles are produced, where p(He)= 50 kPa and I\n \n d\n\n = 50 A. The soot production rate is about 0.43 g/h. Figure 14 (a) shows a photograph of the produced soot suspended by a magnet, demonstrating the good ferromagnetic property. A typical TEM image of the sample is shown in Fig. 14 (b). Iron particles with a size of 1 nm to 20 nm are covered with carbon atoms, resulting in the formation of carbon particles with a size of 10 – 100 nm. These particles are very stable in air and inactive in hydrochloric acid.
\n(a) Photograph of iron-containing carbon nanoparticles suspended by a magnet. (b) TEM image of iron-containing carbon nanoparticles.
Photograph of iron-containing carbon nanoparticles dispersed in water.
Cobalt-encapsulated carbon nanoparticles, which also have ferromagnetic properties, are produced by the arc-jet discharge method. They are dispersed in pure water with a small amount of surfactant (gelatin etc.) and mixed using a supersonic homogenizer (Sonic Co., VX-130) for 1 h. Finally, a black inklike liquid is obtained. The dispersion is homogeneous and stable, and most of the particles do not precipitate even after one month. These water-soluble magnetic nanoparticles potentially have many applications in the fields of liquid sealing, medical diagnostics and medical treatment [26]. Figure 15 shows a photograph of the stable iron-containing carbon nanoparticles dispersed in water.
\nTo produce SWNTs and carbon nanoclusters at a commercial scale by the JxB arc-jet discharge method, a revolver-injection-type arc jet producer (RIT-AJP) has been developed by collaboration with Daiavac Ltd. (Japan) [9].
\nA schematic and photograph of RIT-AJP are shown in Fig. 16. The left side of the machine is an arc discharge chamber, which consists of a vacuum vessel made of stainless steel 25 cm in diameter and 70 cm high that is uniformly cooled by water jackets. About 5 L of water is stored in the jackets and cooling water is slowly supplied to the jackets. In the central part of the chamber, a cathode electrode (30 mm in diameter), an anode electrode, an exhaust port, a viewing port and an electrode-cleaning hand are mounted. The top and bottom parts of the chamber are soot collectors, with an inner diameter of about 25 cm and a height of 24 cm, in which produced soot is deposited. Using these collectors, as much as 25 L of soot can be easily collected after a single operation.
\nThe right side of the apparatus is a revolver-type carbon rod magazine. In the cylindrical metal vacuum vessel, which is 34 cm in diameter and 49 cm long, there is a rotatable cylindrical magazine, in which as many as 50 carbon rods of 6 - 10 mm diameter and 300 mm length can be loaded. A schematic figure of the material-feeding mechanism of the magazine is shown in Fig. 17(a), and a photograph of a rotatable carbon rod magazine (for 50 carbon rods) is shown in Fig. 17(b). Under the vacuum chamber, there is a vacuum pump, an electrical controller and a microcomputer. Discharge power is supplied by an inverter-type DC power supply (Daihen Co., ARGO-300P).
\nSchematic (a) and photograph (b) of the revolver-injection-type JxB arc-jet producer (RIT-AJP).
Feeding mechanism (a) and photograph (b) of the rotatable carbon rod magazine in the revolver-type carbon rod magazine.
The production sequence is as follows. First, up to 50 carbon rods are loaded in the magazine, and the chamber is evacuated by the vacuum pump. After evacuation to a pressure of less than 10 Pa, pure helium gas is introduced and the chamber is closed. Upon turning on the electrical controller, a metal striker pushes one of the carbon rods towards the cathode, and the discharge starts upon electrical contact. As the discharge conditions are determined by the discharge voltage and discharge current, the carbon rod is automatically moved until both parameters match the set values. Once the carbon rod is consumed, the cylindrical carbon magazine rotates 1/50 of a turn and the next carbon rod is inserted by the striker. A magnetic field can be applied by a block-type ferrite magnet located outside the chamber, by which a magnetic field of about 2 mT is applied horizontally to the discharge space. Carbon deposited on the cathode is removed by a cathode-cleaning hand. After the discharge, produced soot that has been deposited is carefully collected.
\nAs an example of the continuous production of carbon clusters, fullerenes are produced. Using 134 carbon rods of 8 mm diameter, continuous JxB arc-jet discharge is carried out, where p(He)= 40 kPa, the discharge current is I\n \n d\n = 120 A, the voltage between electrodes is V\n \n rod\n ~ 33 V and the gap distance is d\n \n G\n ~ 5 mm. The insertion speed of the carbon rods is about 30 cm/h. After the discharge, carbon soot from three parts (the top collector, central chamber and bottom collector) is collected separately and their masses are measured. The amount of soot deposited on the top wall is considerably increased by applying the magnetic field, because the carbon molecules are blown upward onto the top wall. After sufficient mixing, the C60 content in the soot is measured by a UV/visible spectrometer (Shimadzu Co. UV-1200). At the top collector, the C60 content is the highest and about 14 W% of C60 is present, whereas, 4.2 W% is present on the center wall and 2.9 W% is present on the bottom wall. In total, about 105 g of soot containing about 7 g of C60 is produced in 12 h.
\nThe contents of higher fullerenes in the soot are measured using a high-pressure liquid chromatograph (HPLC) (Jasco Co., Gulliver Series, PU980) [27]. The collection rates of C60, C70, C76, C78 and C84 for two different magnetic fields are shown in Fig. 18. White rectangules in the graphs show the measurement errors. By applying a magnetic field, the collection rates of these fullerenes considerably increase.
\nCollection rates of C60 and C70 (a), and C76, C78 and C84 (b) for two different magnetic fields.
By applying a steady state magnetic field perpendicular to the discharge current, JxB arc-jet discharge is successfully produced. The flow of hot gas and the heat flux are concentrated in the JxB direction.
Carbon atoms sublimated from the anode are continuously ejected from the arc plasma in the JxB direction. As a result of the JxB force, the effect of gravity (heat convection) can be reduced.
By increasing the magnetic field, the production rate of carbon soot including SWNTs considerably increases, in which the quality of the SWNTs remains high. Water-soluble SWNTs can be obtained by additional processing.
Using the JxB arc-jet discharge, endohedral metallofullerenes, Gd@C82 and magnetic nano-particles (iron-encapsulateted carbon nanoparticles and cobalt-encapsulated carbon nano-particles) are sucessfully produced.
For the continuous and large-scale production of carbon clusters, a revolver-injection-type arc-jet producer (RIT-AJP) has been developed. Using this machine, the automatic mass production of SWNTs and carbon clusters is realized. We are currently attempting to fabricate many new types of carbon clusters using this machine.
Shipping has a vital role in developing human society over the years, at which the shipping activities have linked the widely separated parts of the world through commercial relationships. In fact, the shipping industry is still developing from time to time with rapid industrial and digital economy growth. In Canada, the shipping industry has been established since 1840 and now undergone significant technological advances, where the size of ships that carry containers for international use continues to increase [1]. Even in Malaysia, the government has launched an initiative, namely, Malaysia Shipping Master Plan, that ensures the shipping industry is focused on developing itself and has a guide for future development. This initiative takes place from 2017 until 2022 with a “Revitalizing Shipping for a Stronger Economy” theme [2].
\nGenerally, there are three main classifications for the global cargo shipping industry, which are:
Wet bulk: Transportation of crude oil and other petroleum products
Dry bulk: Shipment of bulk goods
Liners: Small shipments of general commercial goods
Each of wet bulk, dry bulk, and liner shipping needs their specialized vessels, which are tankers, bulkers, and container ships, respectively [3].
\nFirstly, for wet bulk shipping, approximately a quarter of the goods transported by sea is dominated by crude oil [4]. The oils are transported from its production point to the purchasers by the wet bulk shipping or known as tankers. Majority of the crude oil is moved from the most significant oil-producing region, which is the Middle East, to the dominant importers like the European Union, Japan and the United States of America. Other than that, North America imports oil from the Caribbean and West America meanwhile West and North Africa export their oils to Europe [4].
\nNext, the largest group out of these three classifications is dry bulk shipping, where more than 50% of all loaded goods are handled by the bulkers, while 30 and 16% are for tankers and containers, respectively [5]. There is a vast range of solid cargoes transported by containers. Generally, there are five primary crucial bulk goods, which are coal, grain, iron ore, bauxite, and phosphates, in which iron ore and coal are the two goods that are transported the most [4]. Meanwhile, chemical packages and steel products are the example of the shipped minor bulk goods [6]. The main routes for iron ore transportation are from Australia and Brazil to Japan as well as from Brazil to Western Europe. While for coal, which is commonly used as steam coal in power stations to generate electricity, the leading exporters are from South Africa, Australia, Colombia, the East and West Coast of the United States, as well as Indonesia. Moreover, Australia, South Africa, Colombia, and the East Coast of the United States export their coal to Western Europe, whereas Japan receives the coal from the West Coast of the United States, Australia, and South Africa [4].
\nLiner shipping, also known as container shipping, provides services by transporting goods in containers with scheduled sailings. The variety of goods transported by liner shipping are packed in a smaller unit. One of the contributors to the continuation and development of liner shipping is the increment of the digital economy. According to Ref. [7], companies that produce and process raw materials, commodities, and manufacturing goods are the previous world’s fastest-growing and biggest corporations. However, currently, Internet-related service and technology-based manufacturers, such as Alibaba, Amazon, Apple, and Microsoft, have become the world’s most valuable and most prominent companies, where e-commerce, online communication and cashless Business to Business (B2B) and Business to Consumer (B2C) transactions are practiced [7]. This development has contributed more to the growth of the shipping industry, where it is considered as a catalyst for economic development by facilitating world trade, due to the cheaper mode of transportation.
\nHowever, aside from on-the-ground activities such as lubricants, refineries, and petrochemical industries, it is undeniable that shipping activities have contributed to marine pollution, especially in this twentieth century where carriage of the cargoes by the ships is increasing. According to [8], millions of tons of oily wastes and waste oils are generated as the by-products of the ships, every year. One of the contributors to water pollution by the operating marine vessels is the discharging of oily bilge water. Typically for marine vessels, the oily wastes and waste oil that come from various sources accumulate in the bilge space, which is the lowest part of the vessel.
\nRoutinely, the accumulated oily bilge water must be discharged out of the bilge spaces to maintain the stability of the vessel, hence eliminating the possibility of the ship to be in the conditions that can cause a hazard to it [9]. The wastes discharged can eventually cause water pollution, which leads to many negative impacts on the human, environment, and marine populations. Oily bilge water may poison marine organisms because it might cover plants and tiny animals when it floated on the surface of the water and is carried into the shoreline, causing life cycles of the plant and the respiration of the animals be interfered [10].
\nHence, many governments and international industries are working on the marine pollution issue, mainly originated from the shipping industry, such as the Marine Environmental Protection Committee (MEPC), the International Convention for the Prevention of Marine Pollution from Ships (MARPOL), and the Department of Environment (DOE), Malaysia. In order to solve the problem, oily wastewater separator is essential and needs to be installed and operated effectively to prevent the pollution as well as to ensure that the water discharged overboard is within legal limits.
\nThe lowest compartment of the vessels and directly above the keel is known as bilge, where water that drains off from various sources is captured. The water might be originated from rain, interior spillage, rough seas, or minor leakage in other main parts of the vessel. Depending on a few factors such as ship size, design of engine room, and components’ age, the amount of accumulated bilge water onboard varies from one to another. In order to maintain the stability of the vessel and to avoid conditions that can cause hazard (such as vessel’s propulsion systems and ancillary machinery damage and fire hazard) due to too much of bilge waste accumulation, it is crucial to remove the bilge water into a holding tank, periodically [9]. There are two options to manage the bilge water, which are whether installing bilge separator to treat it onboard or holding it in a tank on the vessel before discharging it to the shore’s treatment facility. Somehow, treating it onboard has an advantage where a smaller volume of oily bilge water has to be stored in the vessel. Meanwhile, the treated wastewater can be removed according to the related regulations and standards.
\nThe composition of bilge water depends on the design and function of the ship. The wastewater is commonly comprised of water, oily fluids, cleaning fluids, lubricant, and grease as well as other wastes that originated from piping, engines, and other operational and mechanical sources in the vessel’s machinery spaces [9] as well as urine and chemicals. Other than that, extra waste streams in massive vessels contain sludge, waste oil, and oily water mixtures. Sludge is formed from the continuous fuel purification to remove contaminants in order to enhance low-quality fuels as well as to avoid ship’s engines and highly machined components from being damaged.
\nThe regulation stipulated by the International Maritime Organization (IMO) highlighted on the oil content of the bilge water discharged to the sea. The International Convention for the Prevention of Pollution from Ships (MARPOL 73/78) has set the maximum limit of 15 mg/L for the oil content in the wastewater to be discharged to the sea. According to the US EPA (2008), passenger ships produce the highest amount of bilge water with huge difference as compared to the other types of ships. This is due to their more complex constructions and support for crowds of passengers [9].
\nTypically, the small volumes of treated bilge water are released above the water line and instantly diluted in the sea water. Hence, the obvious effects of oil spill is most likely not going to occur. However, a long-term effect might happen to the marine living organisms around the shipping lanes. The negative consequences that will take place may be due to the excessive concentration of biodegradable compounds, including oil, as well as continuous increment of nondegradable compound concentration such as metals [11].
\nOther than that, surfactant is one of the significant chemicals contained in the bilge water. The mixtures of oil and surfactants may cause higher toxicity since the oil and surfactants alone are toxic themselves. This may be due to the synergistic effects or the crude oil that has been dissolved, causing it to be consumable for the exposed organisms [12, 13, 14, 15].
\nTypically, OWS is made up of three segments, which are separator unit, filter unit, and oil content monitor and control unit. The separator and filter units are included as treatment units, where many designs and different principles are applied. The gravity and centrifugal separators are commonly used as the first stage of the treatment, followed by other separation techniques, which is called as polishing treatment. The examples of the polishing unit are flotation, coagulation and flocculation, filtration, biological treatment, as well as absorption and adsorption [16]. Normal techniques, such as gravitational and centrifugation, are used for oily wastewater that has two distinct phases; meanwhile, addition of chemical or biological de-emulsification is required for separation of emulsified oily bilge water [17].
\nTypically, oily bilge water treatment onboard starts with a gravitational method in order to remove heavy fractions and lighter fractions based on density difference. In this method, coalescing materials made of oleophilic polymer in the form of loose-packed media or parallel plate are used to attract the oil droplets to adhere to the plate [16]. Examples of oleophilic polymer used as the coalescing plate separators are polyethylene, fiberglass, and nylon [18].
\nThe free-moving dispersed oil droplets continue to adhere to the plate or media until it can break from the coalescing material and float up to the surface of the tank. The presence of the oil detected by the sensors then automatically triggers the OWS to remove the collected oil to a waste oil tank. However, this method can only be effective when the phase of the oil and water is separated distinctively [19]. In other words, in some instances, the gravitational method is not suitable since the bilge water typically consists of emulsified oil formed due to the chemical emulsifiers (solvents and cleaning agents) as well as mechanical means such as ship’s motion and transfer system pump [16]. Figure 1 shows the gravitational separator process.
\nGravitational separator [20].
As can be seen from the figure above, as the oily bilge water flows through the parallel plate, oil globules are formed and float up to the surface to form oil layer. Oil skimmer is used to skim off the oil layer. Then, oil discharge valve and purge water valve are opened, where the oil is removed from the unit by the purge water.
\nCentrifugal separators are the alternative option for the gravity separators. The same principle is applied, in which the oil is separated based on the different density of oil and water as well as coalescence of the oil droplets. Somehow, the centrifugal acceleration causes the gravity to increase more, and the coagulation and flocculation processes are enhanced in order to separate the emulsified oil. This type of separator has many advantages as compared to gravity OWS. Since it can separate more oil from the bilge water, including emulsified oil, less oil content is loaded to the next treatment step, which is usually called a polishing unit. Thus, the polisher’s service life might last long, reducing the cost of maintenance and repair. Centrifugal separators are also more compact and require smaller bilge water holding tanks [16]. However, high capital cost is needed for the centrifuges, and regular maintenance must be done since large horsepower motors are used during the process.
\n\nFigure 2 shows an example of manufactured separator (PureBilge by Alfa Laval).
\nPatented Alfa Laval XLrator [21].
In the inlet stream of the unit, the bilge water is accelerated by the XLrator with less shearing and foaming in order to prevent the oil drops from separating and further emulsion formation. Then, it flows into the separator, in which coalescence occurs due to high centrifugal force. Flocculation of small oil drops takes place and flocculants is added to promote bigger flocs for easier separation [21].
\nSeparation of oil by flotation occurs due to the difference in density of oil and water, where water is denser than oil, forming a scum layer on top of the water. Floatation technique can be divided into many different techniques, including electroflotation, froth flotation [22], and dissolved air flotation (DAF). Electroflotation separates oil from water through electrochemical reactions by electrolysis, where tiny bubbles produced from electrolysis will cause the pollutants to float to the water body surface [23]. In froth flotation, the separation takes place when the oil adheres onto the fine bubbles generated when air is introduced into the system. Surfactant is added to adsorb the air or water interface of the bubbles of air with the head groups (hydrophilic) in the water and the tail groups (hydrophobic) in the air. Hence, when the bubbles rise through the solution, the oil will concentrate on the bubble surfaces and foam is formed [24].
\nMeanwhile, dissolved air flotation (DAF) introduces micro gas bubbles into the flotation chamber that has been formed when water is saturated with gas under pressure [25]. The oil droplet will spread around the gas, and conglomerate will continue to rise to the surface of the solution. The advantages of flotation treatment are the following: less investment needed, low energy consumption, and easy to maintain [26]. However, the statement contradicts with Yu et al. [27] who stated that flotation requires high energy consumption and has repairing and maintenance problem as well as issue in manufacturing of the device.
\nAccording to Yu et al. [27], coagulation process is a robust oil–water separation technology because it is able to separate dissolved and emulsified oil; hence, it is vastly applied in the latest oily wastewater treatment method [28]. In the coagulation process, coagulant, a chemical substance, is added to the wastewater to destabilize the charge of colloidal particles in the solution [29] which is too tiny for gravitational settling. When the particles are destabilized, larger flocs are formed making it easier to settle and then are skimmed off to the clarifier or sludge thickener.
\nAnyhow, many experiments might be needed if the coagulation method is going to be used in treating oily wastewater. This is because of the complexity of oily wastewater, making it hard to choose the most suitable coagulants for effective separation of oil and water to take place [27]. In a study done by Zeng et al. [30], oil removal efficiency is improved up to 99% when aggregation of poly-zinc silicate (PZSS) with anionic polyacrylamide (A-PAM) is used as the coagulating and flocculating chemicals. Somehow, higher costs are needed, and it could cause water bodies’ secondary pollution and difficulties to the next process [27].
\nSome bilge water treatment units include biological treatment, which is called as a bioreactor. In this method, microorganisms are used to eliminate or reduce the organic and inorganic compounds before the treated wastewater being discharged to the sea or to a collection system [29]. The microorganisms convert the dissolved and particulate carbonaceous organic matter, including oil, in the bilge water into simple end products through the oxidation process. The equation below is representing the aerobic biological oxidation of organic matter [29].
\nAs can be seen from Eq. 1 above, the oxidation process needs oxygen (O2) and nutrients, which are nitrate (NH3) and phosphate (PO4\n3−), in order to convert the organic matter to carbon dioxide (CO2) and water (H2O). Other than that, the new cells generated are referring to the biomass produced after the oxidation of organic matter takes place.
\nThere are two principals of biological processes used to treat wastewater, which are suspended growth and attached growth, or also known as biofilm, processes. Suspended growth process maintains the microorganisms in liquid suspension by proper mixing methods. Meanwhile, attached growth attach the microorganisms to an inert packing material, where the wastewater will flow past the biofilm to remove the organic materials [29]. For OWS onboard, biofilm is used, in which the bacteria are attached to a synthetic support media. In this bioreactor, aerators are installed under the media to supply oxygen to the bacteria for bacterial growth as well as for oxidation of the organic contaminants to take place. Other than that, a clarifier is needed in order to remove the biomass formed at the end of the processes [16].
\nBiological treatment, with flexible operation, simple maintenance and management, as well as stable effluent quality [26], is indeed a suitable method since no waste oil is produced by the process [16]. Small oil droplets of emulsified oil, which are hardly removed by physical and chemical treatment, can be degraded easily by the bacteria [31]. However, CO2 will be produced from the process, resulting in increment in greenhouse gases. Even though the operating cost is low, the capital cost needed is high and skillful personnel to be in charge is required to ensure the treatment functioned well.
\nBasically, there are three stages involved in the process [32]. The first stage is heavy phase separation, where separated oils and solids are removed. In the second stage, the bacteria are used to convert the emulsified oil into non-harmful end products. This stage is known as emulsified oil degradation stage. Then, the third stage contains clarifier in order to remove the remaining solids and water.
\nPhysicochemical sorption involved in absorption and adsorption processes can eventually separate the oil from the bilge water. Absorption occurs when two discrete physical states of substances are fused together. Meanwhile, in adsorption, molecules adhere onto the surface of different phase [16]. Both absorption and adsorption involved absorbent sorption media and adsorbent, respectively. The oil is separated by pumping the bilge water through these media until their maximum sorption capacity is achieved, which then the oil is removed. Certain used media are possible to be regenerated onboard; meanwhile, some are regenerated or disposed of onshore. Somehow, the regenerated media is replaced once it is exhausted, where it can no longer absorb or adsorb the oil molecules. Having a few advantages which include low capital and operating cost as well as compact treatment unit, these two sorption techniques are suitable for vessels with less than 400 gross tonnages [16]. Table 1 summarizes the comparison of the oil–water separation techniques.
\nTechniques | \nAdvantages | \nDisadvantages | \nReferences | \n
---|---|---|---|
Gravitational | \nEffective for discrete phases of oil and water | \nNot effective to separate emulsified oils from water | \n[16, 19] | \n
Centrifugation | \n\n
| \n\n
| \n[16] | \n
Flotation | \n\n
| \n\n
| \n[26, 27] | \n
Coagulation and flocculation | \n\n
| \n\n
| \n[16, 27, 28, 33] | \n
Biological | \n\n
| \n\n
| \n[16, 27] | \n
Absorption and adsorption | \n\n
| \n\n
| \n[16] | \n
Comparison of the separation techniques.
Currently, many types of OWS for bilge from different manufacturers are available in the market. The separators consist of a number of separator units that use different separation techniques. Table 2 shows examples of companies that produced commercially available bilge water separators.
\nNo. | \nManufacturers | \nName of the products | \nSeparation techniques applied | \n
---|---|---|---|
1 | \nAlfa Laval | \nPureBilge | \nCentrifugation | \n
2 | \nEnSolve Biosystems, Inc. | \nPetroLiminator OWS | \nBiological | \n
3 | \nVillage Marine Tec. | \nVillage Marine Tec. Oily Water Separator (VMT OWS) | \nAdsorption | \n
4 | \nSeparator Spares & Equipment, LLC. | \nULTRA-SEP Bilge Water Separator | \nUltrafiltration (membrane) | \n
5 | \nCompass Water Solutions | \nCRP-SEP | \n\n
| \n
ULTRA-SEP | \n\n
| \n||
VG-SEP | \n\n
| \n||
6 | \nRecovery Energy, Inc. | \nBOSS Oily Water Separators | \n\n
| \n
Examples of commercially available bilge water separator.
Different techniques are available and being used in the oil–water separation techniques for bilge water treatment. Typically, more than one unit of separators is needed to meet the minimum allowable discharge limit value set by the regulatory bodies. Gravitational and centrifugal methods are said to be the first technique before undergoing further polishing separation. Polishing treatment unit caters smaller droplet of oil, or emulsified oil, which cannot be treated by gravitational and centrifugal methods. To conclude, oily bilge water can be treated with proper separation techniques so that the treated bilge water discharged to the sea comply with the limit and marine pollution can be minimized and prevented. Any other treatment techniques can as well be tested and introduced to enhance the oil–water separation process in treating bilge water.
\nThe authors would like to acknowledge the Centre for Biofuel and Biochemical Research (CBBR) and Chemical Engineering Department, Universiti Teknologi PETRONAS for the support.
\nThe authors declare no conflict of interest.
The Internet has irrevocably changed the dynamics of scholarly communication and publishing. Consequently, we find it necessary to indicate, unambiguously, our definition of what we consider to be a published scientific work.
",metaTitle:"Prior Publication Policy",metaDescription:"Prior Publication Policy",metaKeywords:null,canonicalURL:"/page/prior-publication-policy",contentRaw:'[{"type":"htmlEditorComponent","content":"A significant number of working papers, early drafts, and similar work in progress are openly shared online between members of the scientific community. It has become common to announce one’s own research on a personal website or a blog to gather comments and suggestions from other researchers. Such works and online postings are, indeed, published in the sense that they are made publicly available. However, this does not mean that if submitted for publication by IntechOpen they are not original works. We differentiate between reviewed and non-reviewed works when determining whether a work is original and has been published in a scholarly sense or not.
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\\n"}]'},components:[{type:"htmlEditorComponent",content:'A significant number of working papers, early drafts, and similar work in progress are openly shared online between members of the scientific community. It has become common to announce one’s own research on a personal website or a blog to gather comments and suggestions from other researchers. Such works and online postings are, indeed, published in the sense that they are made publicly available. However, this does not mean that if submitted for publication by IntechOpen they are not original works. We differentiate between reviewed and non-reviewed works when determining whether a work is original and has been published in a scholarly sense or not.
\n\nThe significance of Peer Review cannot be overstated when it comes to defining, in our terms, what constitutes a published scientific work. Peer Review is widely considered to be the cornerstone of modern publishing processes and the key value-adding contribution to a scholarly manuscript that a publisher can make.
\n\nOther than the issue of originality, research misconduct is another major issue that all publishers have to address. IntechOpen’s Retraction & Correction Policy and various publication ethics guidelines identify both redundant publication and (self)plagiarism to fall within the definition of research misconduct, thus constituting grounds for rejection or the issue of a Retraction if the work has already been published.
\n\nIn order to facilitate the tracking of a manuscript’s publishing history and its development from its earliest draft to the manuscript submitted, we encourage Authors to disclose any instances of a manuscript’s prior publication, whether it be through a conference presentation, a newspaper article, a working paper publicly available in a repository or a blog post.
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\n\nSome basic information about the editorial treatment of different varieties of prior publication is laid out below:
\n\n1. CONFERENCE PAPERS & PRESENTATIONS
\n\nGiven that conference papers and presentations generally pass through some sort of peer or editorial review, we consider them to be published in the accepted scholarly sense, particularly if they are published as a part of conference proceedings.
\n\nAll submitted manuscripts originating from a previously published conference paper must contain at least 50% of new original content to be accepted for review and considered for publication.
\n\nAuthors are required to report any links their manuscript might have with their earlier conference papers and presentations in a note to the Academic Editor, as well as in the manuscript itself. Additionally, Authors should obtain any necessary permissions from the publisher of their conference paper if copyright transfer occurred during the publishing process. Failure to do so may prevent Us from publishing an otherwise worthy work.
\n\n2. NEWSPAPER & MAGAZINE ARTICLES
\n\nNewspaper and magazine articles usually do not pass through any extensive peer or editorial review and we do not consider them to be published in the scholarly sense. Articles appearing in newspapers and magazines rarely possess the depth and structure characteristic of scholarly articles.
\n\nSubmitted manuscripts stemming from a previous newspaper or magazine article will be accepted for review and considered for publication. However, Authors are strongly advised to report any such publication in an accompanying note to the External Editor.
\n\nAs with the conference papers and presentations, Authors should obtain any necessary permissions from the newspaper or magazine that published the work, and indicate that they have done so in a note to the External Editor.
\n\n3. GREY LITERATURE
\n\nWhite papers, working papers, technical reports and all other forms of papers which fall within the scope of the ‘Luxembourg definition’ of grey literature do not pass through any extensive peer or editorial review and we do not consider them to be published in the scholarly sense.
\n\nAlthough such papers are regularly made publicly available via personal websites and institutional repositories, their general purpose is to gather comments and feedback from Authors’ colleagues in order to further improve a manuscript intended for future publication.
\n\nWhen submitting their work, Authors are required to disclose the existence of any publicly available earlier drafts in a note to the Academic Editor. In cases where earlier drafts of the submitted version of the manuscript are publicly available, any overlap between the versions will generally not be considered an instance of self-plagiarism.
\n\n4. SOCIAL MEDIA, BLOG & MESSAGE BOARD POSTINGS
\n\nWe feel that social media, blogs and message boards are generally used with the same intention as grey literature, to formulate ideas for a manuscript and gather early feedback from like-minded researchers in order to improve a particular piece of work before submitting it for publication. Therefore, we do not consider such internet postings to be publication in the scholarly sense.
\n\nNevertheless, Authors are encouraged to disclose the existence of any internet postings in which they outline and describe their research or posted passages of their manuscripts in a note to the Academic Editor. Please note that we will not strictly enforce this request in the same way that we would instructions we consider to be part of our conditions of acceptance for publication. We understand that it may be difficult to keep track of all one’s internet postings in which the researcher´s current work might be mentioned.
\n\nIn cases where there is any overlap between the Author´s submitted manuscript and related internet postings, we will generally not consider it to be an instance of self-plagiarism. This also holds true for any co-Author as well.
\n\nFor more information on this policy please contact permissions@intechopen.com.
\n\nPolicy last updated: 2017-03-20
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