Chapters authored
Conducting Polymers Films Deposited on Carbon Steel and Their Interaction with Crude Oil
The formation of scale/solids deposits inside the pipelines is a frequent problem in the petrochemical industry. These scales can be organic as the asphaltenes and inorganic as the accumulations of salts, which apart from blocking the inside of the pipes can also cause a change in the integrity of the steel. Therefore, it is necessary to avoid the conditions where deposition occurs, together with chemical and mechanical methods of remediation to mitigate the deposition. In this work we intend to use conductive polymers in order to inhibit the deposition of asphaltenes on carbon steel surfaces, by using polypyrrole (PPy) as material capable of conducting electrical current. The electrodeposition of PPy on carbon steel were performed by cyclic voltammetry (CV) and chronoamperometry (CA). The results showed that under certain experimental conditions it is possible to make a PPy film with adequate characteristics. Important factors were the grip and electrochemical stability of the formed film on steel, which depends on the electrosynthesis technique and in some cases favoured by a pre-treatment with a 10% HNO3 solution applied to the steel prior to electropolymerization. The PPy films deposited with pre-treatment completely covered the steel surface and showed better stability, adherence and generated a hydrophobic material.
Part of the book: Recent Insights in Petroleum Science and Engineering