Summary of product yield of pyrolysis processes [36].
\\n\\n
These books synthesize perspectives of renowned scientists from the world’s most prestigious institutions - from Fukushima Renewable Energy Institute in Japan to Stanford University in the United States, including Columbia University (US), University of Sidney (AU), University of Miami (USA), Cardiff University (UK), and many others.
\\n\\nThis collaboration embodied the true essence of Open Access by simplifying the approach to OA publishing for Academic editors and authors who contributed their research and allowed the new research to be made available free and open to anyone anywhere in the world.
\\n\\nTo celebrate the 50 books published, we have gathered them at one location - just one click away, so that you can easily browse the subjects of your interest, download the content directly, share it or read online.
\\n\\n\\n\\n\\n"}]',published:!0,mainMedia:null},components:[{type:"htmlEditorComponent",content:'
IntechOpen and Knowledge Unlatched formed a partnership to support researchers working in engineering sciences by enabling an easier approach to publishing Open Access content. Using the Knowledge Unlatched crowdfunding model to raise the publishing costs through libraries around the world, Open Access Publishing Fee (OAPF) was not required from the authors.
\n\nInitially, the partnership supported engineering research, but it soon grew to include physical and life sciences, attracting more researchers to the advantages of Open Access publishing.
\n\n\n\nThese books synthesize perspectives of renowned scientists from the world’s most prestigious institutions - from Fukushima Renewable Energy Institute in Japan to Stanford University in the United States, including Columbia University (US), University of Sidney (AU), University of Miami (USA), Cardiff University (UK), and many others.
\n\nThis collaboration embodied the true essence of Open Access by simplifying the approach to OA publishing for Academic editors and authors who contributed their research and allowed the new research to be made available free and open to anyone anywhere in the world.
\n\nTo celebrate the 50 books published, we have gathered them at one location - just one click away, so that you can easily browse the subjects of your interest, download the content directly, share it or read online.
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In 1977, he served as a research assistant at the Institute of Structural Engineering, University of Tsukuba, Japan. He became a full professor at the same university in 1995. In 2012 he earned the title of Professor Emeritus and he is still active at the University of Tsukuba. Dr. Matsuuchi was a visiting professor at Khon Kaen University, Thailand, and a specially appointed professor at the Oguz Khan Engineering and Technology University of Turkmenistan.",institutionString:"University of Tsukuba",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"3",totalChapterViews:"0",totalEditedBooks:"1",institution:{name:"University of Tsukuba",institutionURL:null,country:{name:"Japan"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:{id:"321873",title:"Dr.",name:"Hiroaki",middleName:null,surname:"Hasegawa",slug:"hiroaki-hasegawa",fullName:"Hiroaki Hasegawa",profilePictureURL:"https://mts.intechopen.com/storage/users/321873/images/system/321873.png",biography:"In 1989, Dr. Hiroaki Hasegawa started as a research engineer working on research and development of ramjet and jet engines at the Japan Defense Agency. In 1998, he earned the title of senior research engineer at the same agency. He obtained a Ph.D. in Engineering from the University of Tsukuba, Japan, in 1999. Dr. Hasegawa was appointed a lecturer in the Department of Mechanical Engineering, Akita University, Japan, in 2002. He is currently a professor in the Department of Mechanical and Intelligent Engineering, Utsunomiya University, Japan.",institutionString:"Utsunomiya University",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"0",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"Utsunomiya University",institutionURL:null,country:{name:"Japan"}}},coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"124",title:"Vehicle Engineering",slug:"vehicle-engineering"}],chapters:[{id:"79180",title:"Introductory Chapter: Propulsion and Movement",doi:"10.5772/intechopen.101071",slug:"introductory-chapter-propulsion-and-movement",totalDownloads:95,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:null,signatures:"Kazuo Matsuuchi",downloadPdfUrl:"/chapter/pdf-download/79180",previewPdfUrl:"/chapter/pdf-preview/79180",authors:[{id:"42387",title:"Prof.",name:"Kazuo",surname:"Matsuuchi",slug:"kazuo-matsuuchi",fullName:"Kazuo Matsuuchi"}],corrections:null},{id:"76789",title:"Hybrid Propulsion System: Novel Propellant Design for Mars Ascent Vehicles",doi:"10.5772/intechopen.96686",slug:"hybrid-propulsion-system-novel-propellant-design-for-mars-ascent-vehicles",totalDownloads:240,totalCrossrefCites:0,totalDimensionsCites:1,hasAltmetrics:1,abstract:"This chapter briefly introduces hybrid rocket propulsion for general audience. Advantageous of hybrid rockets over solids and liquids are presented. This chapter also explains how to design a test setup for hybrid motor firings. Hybrid propulsion provides sustainable, safe and low cost systems for space missions. Therefore, this chapter proposes hybrid propulsion system for Mars Ascent Vehicles. Paraffin wax is the fuel of the rocket. Propulsion system uses CO2/N2O mixture as the oxidizer. The goal is to understand the ignition capability of the CO2 as an in-situ oxidizer on Mars. CO2 is known as major combustion product in the nature. However, it can only burn with metallic powders. Thus, metallic additives are added in the fuel grain. Results show that CO2 increase slows down the chemical kinetics thus reduces the adiabatic flame temperature. Maximum flammability limit is achieved at 75% CO2 by mass in the oxidizer mixture. Flame temperature is 1700 K at 75% CO2. Ignition quenches below the 1700 K.",signatures:"Ozan Kara and Arif Karabeyoglu",downloadPdfUrl:"/chapter/pdf-download/76789",previewPdfUrl:"/chapter/pdf-preview/76789",authors:[{id:"332637",title:"Dr.",name:"Ozan",surname:"Kara",slug:"ozan-kara",fullName:"Ozan Kara"}],corrections:null},{id:"74791",title:"Keeping the Dream Alive: Is Propellant-less Propulsion Possible?",doi:"10.5772/intechopen.95603",slug:"keeping-the-dream-alive-is-propellant-less-propulsion-possible-",totalDownloads:419,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:1,abstract:"“Breakthrough” advanced propulsion can only take place with a correct understanding of the role of inertia in general relativity. Einstein was convinced that inertia and gravitation were the obverse and reverse of the coin. The most general statement of the principle of relativity, captured in his Equivalence Principle and the gravitational induction of inertia. His ideas and how they have fared are reprised. A rest mass fluctuation that is expected when inertia is gravitationally induced is then mentioned that can be used for propulsion. Recent work supported by National Innovative Advanced Concepts Phase 1 and 2 NASA grants to determine whether thrusters based on gravitationally induced inertia can actually be made to work is presented. A recent design innovation has dramatically increased the thrust produced by these Mach Effect Gravity Assist (MEGA) impulse engines.",signatures:"James F. Woodward",downloadPdfUrl:"/chapter/pdf-download/74791",previewPdfUrl:"/chapter/pdf-preview/74791",authors:[{id:"335130",title:"Emeritus Prof.",name:"James F.",surname:"Woodward",slug:"james-f.-woodward",fullName:"James F. Woodward"}],corrections:null},{id:"75849",title:"Introduction to Plasma Based Propulsion System: Hall Thrusters",doi:"10.5772/intechopen.96916",slug:"introduction-to-plasma-based-propulsion-system-hall-thrusters",totalDownloads:322,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:0,abstract:"Technically, there are two types of propulsion systems namely chemical and electric depending on the sources of the fuel. Electrostatic thrusters are used for launching small satellites in low earth orbit which are capable to provide thrust for long time intervals. These thrusters consume less fuel compared to chemical propulsion systems. Therefore for the cost reduction interests, space scientists are interested to develop thrusters based on electric propulsion technology. This chapter is intended to serve as a general overview of the technology of electric propulsion (EP) and its applications. Plasma based electric propulsion technology used for space missions with regard to the spacecraft station keeping, rephrasing and orbit topping applications. Typical thrusters have a lifespan of 10,000 h and produce thrust of 0.1–1 N. These devices have E→×B→ configurations which is used to confine electrons, increasing the electron residence time and allowing more ionization in the channel. Almost 2500 satellites have been launched into orbit till 2020. For example, the ESA SMART-1 mission (Small Mission for Advanced Research in Technology) used a Hall thruster to escape Earth orbit and reach the moon with a small satellite that weighed 367 kg. These satellites carrying small Hall thrusters for orbital corrections in space as thrust is needed to compensate for various ambient forces including atmospheric drag and radiation pressure. The chapter outlines the electric propulsion thruster systems and technologies and their shortcomings. 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Parenthood is known for its importance in the development of children in different parts of the world. Parental relationships consist of routine actions of care that are necessary for the survival and well-being of the young, including beliefs, values, and expectations in a given culture [1- 6].
Through the journey of daily care, parents and caretakers gradually prepare children with education that is considered important to be inserted into various social contexts, in addition to taking care of the physical and emotional needs of children [4]. Therefore, parenthood involves social practices performed by those who take care of or are responsible for the education of children, serving as examples of values and beliefs. Culture and history also participate in this process [5,6].
What is considered adequate, as well as practices that promote what is considered appropriate in the development of children vary from culture to culture, even within the same country over time history [4]. According to the authors [6] this understanding reflects the contextualist paradigm that challenges the neo-positivist view of the data collected in a given society may be relevant in another, as well as data collected in a particular historical moment are necessarily significant in a period later [6]. In this sense, it is necessary to examine parenting in many social groups.
According to reference [7], the differences observed in beliefs and care practices in different cultures can be described by cultural models that express different methods of parenthood. Parents with high levels of education who live in a city have socialization techniques that are different from those of families with low levels of education who live in the country [7,6].
In this perspective, the author [3] that made extensive transcultural research, tell us about the differences between the parental practices in terms of cultural prototypes, as being those which can valorize the autonomy within the caring practices, such as situation of the American families, and others that reforce the obedience and the sense of belonging to the group, such as the case of the rural communities. The same way, significant differences are found between the practices of the Minority World (typically represented by the white middle class from North America and Western Europe) and Majority (countries with low human development index) [8]. Such differences take in consideration aspects of the point of view economic and cultural and are evidenced from points such as: the attachment mother-baby, the shared responsibility, the probability of mortality, the size of the family, the roles played by the members of the family and the surrounding community [8, 3].
Noteworthy is the fact that studies that compared educational practices between the Minoritary World and poor rural communities in the Majoritary World led to a consensus that parental practices in those countries are a shortcoming [8,3,4].Therefore, parental practices in countries of the Minoritary World are considered more adequate, and such a trend is emphasized by the use of measurement scales and tools for psychological investigation that advocate universal practices [5].
An important topic to evidence is the fact that the studies interested in comparing the educational practices observed between the Minority World and the impoverished rural communities of the Majority World have conducted in a mistaken way to the consensus that the parental practices in those countries are presented as deficient [8, 3, 4]. In this sense, the parental practices present in the countries of the Minority World are taken as more adequate which trend is to reinforce by the use of measure scales and psychological investigation instruments that profess them as universal practices [5].
According to the author [5], more important than the use of such tools is the observation of daily activities and interactions in a given cultural context, which are full of meaning and express the concepts of parental care and how families are connected with the surrounding community [3, 9, 10]. In this sense, the studies by [1,2,5,3,7] are notable. In the case of Brazil, [11, 12, 13] contribute to the understanding of parenthood in different social groups.
The main interest in studying different cultural communities would, however, focus on the involvement of people in their communities, examining the nature and dynamics of generating individual lives and social practices of the community [3]. In other words, recognize what cultural practices familiar to every social group that permits examining and recognizing the organization, values, visions and social practices that are common and persistent in a given place, at a given social class or social group [3,4]
Considering that the roles performed by families are distinct in different cultural communities and in daily care practices, the objective of the present study was to describe the routines of two families who lived in Amazon river regions in the state of Pará, Brazil. These communities are inserted in the Amazonia forest, in which living activities are linked to nature with different degrees of isolation from urban centers.The figure 1 demonstrates this rich and distinctive ecological context.
The Amazonian context: the florest and housing typically riverine Amazon (collection of Laboratory Ecology of Human Development)
The Amazon river region consists of a forest rich in biodiversity, possessing 20% of the freshwater on the planet. Additionally, it represents 50% of the Brazilian territory and has approximately 11 million people, in which 62.4% live in the cities and 37.6% live in the country [14].The riverine area still has energetic resources and wealth and is rich with lush flora and fauna, but it is still considered an economically poor region compared with its natural richness because of its historical lack of infrastructure investment [15].
The riverine communities arranged in the Amazon forest are considered traditional, with occupations associated with waterways, cultures with riverine roots, and small-scale agriculture [16]. Although sharing a way of life and traditional cultures, significant differences are found among these communities in terms of access to public policies and economic development. Thus, riverine communities that live in geographic isolation have more financial stringency and depend more on forest resources and less on commercial interchange. However, in riverine communities near urban centers, people have more accessibility to foreign goods and knowledge, thus incorporating values found in urban areas [17].
With regard to the way of life on the Amazon river, [18] indicated that these populations have an intense relationship with the cycles and dynamics of nature. Residents build their day-to-day activities and identities based on the river and forest surroundings, with a depth of knowledge about natural dynamics that reflects elaborate strategies for the use and management of natural resources.
Knowledge is orally transferred from generation to generation. From a practical perspective, this is characteristic of such populations, who use symbols and rituals linked to hunting, fishing, and extractive activities. In addition to the practical sense, living with cyclical and repetitive periods and guided by the dynamics of nature, distinct senses and meanings are generated in these populations, in which their routine tasks and social relationships develop more slowly [18].
Based on interest in recognizing parenthood within the context such different development, the objective of the present study was to understand parental practices based on the descriptions of the routines of two riverine families and provide evidence of the relationships between cultural activities and the Amazonian context. We highlight the social activities during weekdays and weekends, with parenthood considered based on the daily activities that reflect these families’ beliefs.
This study comprised two periods of data collection, between 2006 and 2010, when visits and interviews were performed in two Amazonia riverine communities that have different geographies and social dynamics. The Araraiana community is located in Ponta de Pedras city in the Marajó archipelago, and the Piriquitaquara community is on Combu Island and belongs to the insular area of Belém. The data form the database of the Laboratory of Ecology of Human Development, which has been conducting scientific studies on the development of Amazonia riverine families.
The first phase of research was performed in the Araraiana community that belongs to the county of Ponta de Pedras, Marajó Island, PA. The county area is approximately 3,365.30 km², with a population of 20,067 inhabitants. Araraiana is a community geographically isolated from urban centers, with an absence of medical and social assistance see [19].
The Araraiana community, during data collection, consisted of 22 families with 125 inhabitants who lived in stilt houses on the margins of the river. Overall, the houses had three rooms (e.g., living room, bedroom, and kitchen) and were made of wood and straw collected from the forest adjacent to the houses. The houses were distributed along the river with an approximate minimum distance of 300 m from each other. The houses had no furniture, such as sofas, chairs, wardrobes, or beds. In several houses, it was common to sit and have guests sit on the floor made of wood boards or on benches made of wood close to the walls, typically in the living room and kitchen. The few appliances were wood-burning stoves, radios, and televisions. Because of the absence of local electricity, televisions and radios functioned with batteries for limited periods of time, mainly at night. The houses were essentially occupied by the family, in which the number varied as a function of family type (i.e., nuclear families with one to six residents or extended families with six to 10 residents), whereas multigenerational families were characterized by a higher density (i.e., eight to 12 residents).
The principal occupation of the men was extraction activities, followed by fishing. Women were housewives or artisans. The river and forest provided food and products for local extraction activities, such as fish, shrimp, game animals, and açaí.
With regard to the availability of health services, no assistance was provided by the state, in addition to the lack of treated water, trash and sewer services, and complex health problems of the population (e.g., stomach and intestinal problems and malnutrition). Similar to the lack of health services, no investments were made in education. The only school in the community was located in the house of a local resident who provided only first-year elementary school education.
This community belongs to Combu Island, Belém county, Pará state. It has an approximate territorial size of 15 km² and is approximately 1.5 km from the capital Belém via waterway. It is characterized by floodplain forest with diversified flower composition in addition to enormous tourist and commercial attractions.
Considered the fourth largest island of Belém county, Combu Island is located at the margins of Guamá River. In this area, approximately 375 families or 1,700 residents live in and are clustered in four communities: Igarapé of the Combu, Igarapé of the Piriquitaquara, “Furo da Paciência,” and the margin of Guamá River. The houses are predominantly made of wood and distributed along the margins of the waterways. The social and production structure is organized as a function of local natural resources, such as açaí and cacau harvesting, palm heart extraction, shrimping, fishing, and raising chickens, ducks, and pigs, which constituted the principal local activities.
Access to Combu Island is via waterway on boats that leave daily from different Belém harbors. Such waterways play a strategic role in the transportation of goods and people. Work is performed with activities in the riverine area. Other services, including the marketing of plant and gathering products, health services, schools, shops, and amenities, occur in the urban context.
The houses were made of wood and covered with clay tiles or asbestos. They were built on stilts and located approximately 30 m from each other. Electricity was not available during data collection, but it became available in July 2011. Treated water was not yet available. Drinking water was obtained from a public tap in Belém and carried in bulk or plastic bottles to the community.
With regard to infrastructure, the community had a health center that was having difficulty with functioning because it was closed for some months due to a lack of physicians, equipment, and medicine. Aside from this health center, a municipal school was located in the igarapé itself, characterized by a typical Amazonia riverine style and made of wood on stilts. The school had two classrooms, a courtyard, a pantry, restrooms, a coordination room, and an external area available for recreation when the river level was low. In this community, almost all of the residents received benefits from the federal program “Bolsa Família” (family grant), a program that directly provides income to families depending on health conditions and school attendance.
In the present study, we used two representative families, one from each context (focal families), and the choice was made by considering accessibility and availability.
We used an inventory prepared by the research group LEDH that presents the following items: identification (name, age, gender, parenthood, and marital status), family income, and house characterization (whether the house was owned, construction type, number of rooms, appliances and furniture, electricity, availability of treated water, and sewage and trash services).
The QFR [20] was used to ascertain the family routine. The QFR consisted of a sheet on which the periods of the day (i.e., dawn, morning, afternoon, and night) were listed in rows and referred to developed activities. The location where the activities took place and the people who were present at the time of the activity were entered in columns, with additional space for other observations. This tool was applied for all participating family members by asking them to describe the activities they performed in a normal day before the interview. Subsequently, we asked the participants to describe their routine on the last Sunday, which was a typical weekend day. The QFR was adapted to the riverine context, which allowed better compatibility with local characteristics [20].
The process of insertion of the research team on the islands first involved systematic access to the spaces shared by the family. During the approach of the places frequented by the residents, such as the school, residents’ association, and houses themselves, we took care to become part of the population day-by-day by sharing time and activities.
After familiarization with the families, we were able to access their homes with the help of local boaters because of a lack of an address system similar to the ones used in cities given that igarapés are constituted by rivers that intersect, which can cause confusion for those who do not live in the region. After mapping the participants’ houses, we began visiting the houses. The observations, talks, and activities were reported in a field diary immediately after the visits.
A statement of consent warranted the rights of the participants, and the ethical committee of the Federal University of Pará approved the study (CAEE – 0016.0.073.000-09).
The inventories were applied with the parents on previously scheduled days. During the interviews, we asked questions, and the participants were free to respond. The responses were recorded and transcribed. The tabulation of responses into categories of activities was based on discussions and agreement of two of the three researchers who collected the data. In case of discordance, we consulted the project mentors.
We divided the activities into eight categorical clusters: Economic Subsistence (ES; which refers to all activities that are aimed at obtaining financial resources), Food subsistence (FS; which includes all activities involved in food acquisition and preparation), Domestic tasks (DT; which refers to tasks performed in the house, excluding the kitchen; e.g., sweeping, dish washing, gathering firewood, and fixing the house), Physical care (PC; which refers to tasks related to other people, typically the children; e.g., feeding, bathing, and putting them to sleep), Leisure (L; which refers to activities performed in their free time, including activities for having fun, entertainment, or distraction; e.g., social interaction/talking, watching television, and playing soccer), Play (which represents playful activities with children), and Study (which comprises learning activities in addition to formal teaching).
To facilitate data visualization, we made Diagrams of Family Activities (DFAs) that consisted of forms that allowed descriptions of intrafamilial subsystems in activity performance. The DFAs were composed of a genealogy tree of the groups who shared a house, and the activity subsystems in which the family members were inserted were delineated with lines of different thicknesses, which allowed distinguishing activity categories. Such categories were identified by complementary descriptions around the figure. The DFA allowed knowledge of the tasks and who performed them, the time of the meeting, whether there was close interaction or isolation, and useful reflections on the nature and characteristics of family gatherings [20].
The contexts investigated here had similarities and differences that represented peculiar lifestyles in the Amazon river region. Both presented forest vegetation and delimitations from regional rivers, contextual aspects that characterize the disposition of the houses where lands are flooded and promote isolation although they are close to each other.
The authors [21, 22, 23]indicated that this disposition of geographic isolation, marked by the presence of rivers, reveals an important contextual characteristic that is necessary to understand the composition of relationships established in the Amazon river communities. To reach out to neighbors, one must go through natural barriers that restrict exiting from the domestic environment. Therefore, the groups of river families turn to themselves, intensely sharing moments of interaction and developing strong affective bonds. Another important aspect is the fact that the families live together in the same community for generations; therefore, relatives mostly comprise the neighborhood. This composition is indicated in figures 2 and 3.
Neighboring houses in the Amazon river context (collection of Laboratory Ecology of Human Development)
Canoe used to transport families around the house (collection of Laboratory Ecology of Human Development)
With regard to contextual differences, the Araraiana community presented higher isolation and exclusion compared with populations with the same profile. The isolation can be justified based on the following factors: lack of systematic transportation in the region, difficulty contacting river residents, and difficulty accessing media [20]. However, in the Piriquitaquara community, the residents had more access to goods and services, healthcare, and public policies, such as the “Bolsa Família,” aspects that softened extreme local poverty.
The contexts also presented similarities in terms of housing characteristics. They were made of wood gathered from the forest, covered with clay tiles or asbestos, and built on stilts. Electricity was nonexistent in the Araraiana community, whereas electricity became available in July 2011 on Combu Island. Therefore, at the time of the study, both communities had no electricity. With regard to basic sanitation, in both contexts, 90% of the houses had their bathroom in the backyard in a small wooden cubicle with an open bottom where waste was directly dumped on the muddy substrate. During high tide, the river carried the waste away.
In the Araraiana community, only one house had a water well; all of the other residents consumed water directly from the river. Water treatment basically consisted of straining the water with a cloth; thus, the incidence of stomach ailments was epidemic in the locale. On Combu Island, drinking water was obtained from a public tap. In Belém, it was carried in buckets and plastic bottles to the community. Therefore, we observed from the daily field records that the community of Combu worried more about water quality compared with the Araraiana community.
With regard to the families’ routine, the following examples describe representative families in the riverine contexts studied to help understand parenthood in the context of the Amazon river.
This is an extended family composed of the couple and their nine children, with the oldest child living in Ponta de Pedras, Ilha do Marajó, PA, with the maternal grandmother. Hence, in the house lived Beto (30), Márcia (age unknown), and the children Paulo (15), Raissa (13), Tamiris (12), Célia (10), Geisa (6), Inaiara (5), Nanci (3), and Ana Paula (1). These are fictitious names, and the ages refer to the time of data collection. The family’s living came from gathering açaí, fishing, and extracting other products from the forest.
Eduardo, the father, would wake up early, leave with his boat just after breakfast, and work by hauling and transporting goods. He would return at the end of the morning and afternoon. Overall, except in leisure times, which mainly involved playing soccer with his friends, his daily activities were spent alone. Márcia spent her day engaged in domestic tasks and physical care of the eight children with the help of her older daughters. Her routine was restricted to the house and surroundings.
The daughters, Raissa, Célia, Tamiris, Geisa, and Inaiara, went to school early, which was located in the house of one resident of the community (with only one room where all of the children from the community studied). In addition to studying in the same place, the people ate meals and shared several activities together. In the afternoon, they played in the surroundings of their uncle’s house, which was next to the school. In addition to helping the mother with DT and FS, the oldest daughters were in charge of taking care of the youngest. At the end of the afternoon, it was common to see them bathe in the river in front of their house.
The oldest son, Paulo, performed activities isolated from his siblings. In the morning, he engaged in ES and SF activities. In the afternoon, he went to school and on his way back he either played soccer with his friends or performed FS activities.
Family gatherings occurred at night when they had dinner together and shared leisure activities. The sleeping place depicted the organization of the family subgroups. The girls slept with the mother in the bedroom. The father slept in the living room, and Paulo, the oldest son, slept in the kitchen. Fig. 4 illustrates the family’s routine.
Activities/tasks performed and subsystems involved in the B/M family during weekdays.
The collected data revealed little sharing of activities between the couple because the division of activities was done by gender. The brothers formed different subsystems (Fig. 1). The oldest brother performed his food subsistence, economic, school, and leisure activities basically alone. Because of similarities in the school schedule with the five sisters (Raissa, Tamiris, Célia, Geisa, and Inaiara), this constituted a subsystem in the school and play time. Because of her important role in activities with her mother, Raissa was isolated from the group of sisters. Geisa, Inaiara, Nanci, and Ana Paula formed an affinity and playing activity subgroup, with Geisa, the oldest sister, playing the role of caretaker. On the weekends, the dynamics of the family changed, with the exception of Márcia who maintained her routine of domestic tasks. The father and son would visit friends in the community, the activities of which often involved eating lunch and having Sunday occupied by leisure activities. The girls played and bathed in the river but did not stop performing the DT, FS, and PC activities to support their mother.
The routine or care practices in this family were strongly linked by gender. The division of tasks and roles between men and women consisted of distinct status occupied by the spouses. The mother’s role was to maintain the family through domestic tasks, such as taking care of the children and the family environment, cooking, plant cultivation, and raising animals. The father had the role of provider, taking care of economic activities and food subsistence. Thus, we did not see a time when the father performed activities that were directed at taking care of the children or living with his daughters. The division by gender allowed and encouraged the closeness of the father with the older son and almost totally restricted a closer relationship with the daughters.
Another important aspect related to parenthood concerns the fact that this community presented high incidences of extended families, which is consistent with a survival strategy of families in the rural context that has been present in Amazonia for centuries [16]. This occurs when the source of income is linked to extractive work. It is expected that several children would help with ES activities.
Consistent with this contextual characteristic, in the traditional model adopted, the oldest daughters were encouraged to learn, beginning at early ages, to perform FS and DT activities, stay with their mother all the time, and restrict their relationship networks to the domestic environment. Therefore, they precociously developed roles in which they were allowed to take care of the young and guide them in education and insertion to the surrounding community. This type of brotherly relation, marked by the care common in this community, differs from urban contexts where brotherly relations are more often conflicting, given that the cultural prototypes emphasize individuality and low obedience [3,5,6].
Being prepared since childhood for domestic tasks, the traditional riverine women get married during adolescence, as opposed to the current urban perspective. Academic education does not appear to be important. Instead, education that ensures marriage and family maintenance is viewed as more important. In fact, in traditional societies, marriage is necessary for survival, and the woman’s social role is to be mother and wife, such as in some communities in Oriental Africa [9,3].
In addition to the gender patterns that structure social organization and parental practices, the isolation status of the riverine families is also taken into consideration. The distance and poor access to services impose relationship barriers that make bond formation with other parts of the community difficult; thus, the daily routine has been maintained in a traditional way for centuries.
For comparison purposes, below we present data on the family who resided on Combu Island, an Amazon river region that is close to the capital Belém and not considered a typically traditional community, although it maintains characteristics of the Amazon river region.
This remarried family was composed of João, the father (41), Vânia, the mother (32), the adolescents Maura (14) and Alexandre (17), and the children Laís (8) and Amanda (3). These are fictitious names, and the ages refer to the time of data collection. The couple has lived together for 9 years. Laís and Amanda are the biological children of the couple, the latter of whom has Down syndrome. The others are Vânia’s children.
The family lived with a fix income composed of João’s salary. He worked as a boater hired by Belém city to transport students and teachers of the school located a few meters from his house and from “Benefício Assistencial de Prestação Continuada BPC – LOAS” because of the daughter with a deficiency. Additionally, the children relied on the benefits of “Bolsa Família” (i.e., a program that involves the direct transfer of income to benefit poor families) because they met the health and education requirements that are necessary for this federal program.
All of them would wake up early. João, Vânia, and Alexandre left to gather açaí (ES). Upon returning from the forest, João went to his boating job. Maura prepared breakfast (FS), along with the younger sisters. Alexandre went to “Porto da Palha” to negotiate the selling of açaí. Maura remained at home to help with DTs, and Laís went to the school located next to their house. However, because of the terrain flooded by the river, the shortest route was by boat.
Vânia typically was found at home with the youngest daughter performing DT and PC activities. However, twice per week, the husband took her by boat to the capital to go to the hospital for therapeutic care of her deficiency, which was sometimes done with the help of Maura. Thus, the family organization was adequate for the routine to address the needs of the daughter with Down syndrome.
Vânia concomitantly performed the SF, DT, and PC activities of Amanda. Around noon, the other family members returned home for lunch. Before eating, Maura took a bath in the river with Amanda during moments of PC and L. After lunch, Alexandre and Maura went by boat to the capital to study in a state school. At the beginning of the afternoon, João transported the students of the afternoon period. Vânia took care of the PC activities of Amanda and Laís, the principal partner of the youngest daughter. At night, everybody performed activities linked to L.
The distribution of the members during sleep followed a similar distribution as the family of the Araraiana community, in which all of the daughters slept in the only bedroom, and the parents and oldest son slept in the living room.
Activities/task performed and subsystems involved in the J/V family during weekdays.
During the weekends, the family went on a boat trip to Vânia’s mother’s house, a place in the metropolitan region of Belém where most of the relatives lived.
In this community, the participating family presented a way of life with some characteristics common to traditionally isolated families, such as a strong familial bond, which is considered a survival strategy among families who live in the forest [16]. However, because they were directly influenced by the urban environment, we found different characteristics compared with traditional families, which is reflected by the speech of the matriarch (Vânia) who, although she is responsible for the house organization and care of the children, presented herself as the family leader who was responsible for day-to-day decisions. Thus, the father, despite being the provider, was not considered the family leader. This posture highlights the flexibility of gender division in traditional communities.
Another important aspect to be emphasized is the fact that the children were able to finish their education in the capital because only up to the fifth year of elementary school (Cycle II) is provided on the island. Thus, we observed from the collected data that significant changes were introduced with regard to the children’s beliefs about work, the future, and family. The daughters were allowed to study in the capital. Although they continued to perform routine domestic tasks, they spent more time in school and were encouraged to study and be prepared for paid work in the cities. Thus, marriage was no longer the main goal of the teenagers.
Another important point concerns the detachment of the father from the domestic environment. [3] indicated that the occupational roles marked by gender specify that men be engaged in activities that require physical strength and detachment from the home. In the case of riverine families, separating activities and social relationships between boys and girls is common. A boy’s job is to help gather açaí (an Amazonian fruit base of their diet), process it, prepare it, and sell it, in addition to hunting and fishing. The girls should stay around home, and their learning is directed to domestic tasks that do not require high physical effort and do not put them in situations of risk, such as falling and snake bites.
With regard to fraternal subgroups, we observed the same pattern as in traditional Amazonian river families. Siblings of the same sex spent most the time together. The oldest, the majority of which were girls, were responsible for taking care of the young. The oldest, when not at school, helped the adults with domestic tasks, açaí gathering, and fishing. They were also seen at different times playing or bathing in the river.
Thus, the Piriquitaquara community consists of intermediate characteristics between two well-defined contexts: urban and traditional Amazonia riverine. The incorporated family inherited the traditional way of life, combined with influences from the capital. They even relied on a set of services made available by the state and city, such as education, healthcare, and work.
However, although Combu Island is considered a peculiar region from a cultural standpoint, it was composed of a peripheral scenario of strong local economic impoverishment, a common characteristic of all Amazonia riverine communities. Thus, the families studied herein were representative of hundreds of Amazonia riverine communities that survive by gathering forest products within the context of poverty.
The present study found that the participating families were similar because they shared the same culture, based on knowledge and familiarity with the Amazon forest, and could be distinguished based on gender social roles. Both the father and mother had their roles previously defined in the familial environment and surrounding community. Thus, the parental practices were different from those in urban centers and were more similar to rural communities because they were based on cultural prototypes aimed at the division of daily activities between parents and children and obedience in fulfilling domestic tasks, see [3].
The children spent most of their time engaged in activities performed with siblings, and the presence of the parents was not common during these times. The time shared between the father, mother, and children only occurred through daily activities that were directed at the learning necessary to fulfill domestic tasks (e.g., SF, ES, and DT). The parents did not stay busy with the children. The mothers, despite always being present in the domestic environment, kept away from the children, and this trend increased as the children aged. The older children, normally girls, delegated the responsibilities of taking care of the young (i.e., CT).
The fact that the parents did not directly take care of the children does not mean that they were not concerned about the children’s well-being or development. However, the concerns were more linked to obtaining food from the river and forest to ensure family survival. The paper of [6] indicated that what the parents do or do not do only makes sense if the specificity of the context where they are inserted is understood.
Living in the middle of the Amazon forest requires that the Amazonia riverine parents’ actions are linked to subsistence and the practical direction of daily activities that certainly are unknown in urban contexts. Thus, although parental behavior is considered a task of universal development, the nature of this development is cultural [3,7]. Therefore, any kind of judgment about the best practices for children’s’ development can only be made by considering the values and beliefs of each specific group [6]. No parental practice should be evaluated in isolation, and there is no cultural standard that is better or worse for human development [5,6].
With the central objective of providing visibility of riverine communities, the present study sought to understand parenthood in such contexts, challenging assumptions that are considered universal with regard to parental care. Moreover, our goal was to compare families in transition communities. According to [3], this helps to better understand how communities are transformed over time based on contextual changes and parental needs to provide essential care for children in an ever-transforming world.
The Piriquitaquara community on Combu Island can be considered a community in transition [3]. For many years, it stopped living exclusively in a traditional way. The closeness with urban centers located on the other side of the river influences the way of life of its residents who participate in social institutions that are present in the cities, sharing commercial exchanges and absorbing typically urban values and beliefs.
The parental practices also adapted to these changes, but this does not mean that they became practices toward autonomy, which is common for parents in urban contexts. However, they no longer reflect the totally prototypical interdependence of rural communities. Something is changing. Some indicators of this transformation have arisen from the flexibility of the maternal role because the mother in the family studied herein was the leader who made the family’s decisions. Even the children, including the girls, were encouraged to continue their education in the urban context.
We conclude that the status of social exclusion in riverine people and the difficulties of their routine are related to the fact that they have stayed in the Amazon forest for such a long period of time. Their routine expresses a way of thinking about parenthood in a specific way, which can cause a series of difficulties linked to health, education, and development, which can and should be remedied by federal and local public policies. Therefore, the present study also sought to make Amazonia riverine communities more visible. The lack of public policies directed toward riverine citizens impedes the quality of life in their particular environment.
Notable is the relevance of the present study and several other previous studies developed by the Laboratory of Ecology of Human Development, which provided information about Amazon riverine communities that are separated by rivers from the urban centers of the cities to which they belong. Therefore, we seek to contribute to the development of public policies that are compatible with the social organization and symbols of their social groups to improve the quality of life of these populations that are isolated and impoverished.
We thank CNPq National Council for Technological and Scientific Development for the provided funding. In addition, we thank to all the members of Laboratory of Ecology Development (LED) that collaborated at different moments, but intensely collecting the data presented here. Our thanks go to Leila Assef Mendes, Daniela Castro Reis, Sara Danielle Baia da Silva, Lorena Santos, Daiane Gasparetto, Eline Monteiro, Katia Carvalho, Viviam Rafaela Barbosa Pinheiro Freire, Júlia de Almeida Roffé Borges, Leandro Cavalcante Lima, Maria Elizabeth Costa Araújo, Suzane Santana Lima dos Santos and external collaborators Julia Bucher-Maluschke and Silvia Helena Koller.
With energy shortages and pollution escalating worldwide, renewable feedstocks are crucial for human long-term development. There are many natural sources of animal fats, including lignocellulosic biomass, crops, aquatic culture, biowaste generated by waste management, and domestic and urban waste recycling [1]. Utilizing thermochemical decomposition processes like gasification or pyrolysis, biofuels (bio-oil and syngas) can be produced from biomass and a carbon-based solid residue called biochar [2].
As a porous solid with high carbon content, biochar is formed during the thermal decomposition of biomass at moderate temperatures (e.g., 350–700°C) and under oxygen-limited conditions [3, 4, 5, 6, 7]. Despite its chemical and physical properties, biochar’s thermochemical process and the intrinsic properties of biomass feedstock are two of the factors that influence its properties [4]. Due to its porosity and large surface area, biochar is classified as activated carbon (AC), yet it also contains numerous surface functional groups (carbon monoxide, hydroxyl, carbonyl, carboxylic acid, among others) that can be easily tuned and used to make various functionalized carbon materials. As well as being used for AC production and soil amendment, biochar serves as an adsorbent for pollutants in water and air [5].
Recent research has revealed that biochar is widely utilized as support for metals in catalysis, due to its feedstock availability, large surface area (for good metal phase dispersion and stability), low cost, and stability in basic and acidic media [6]. In addition to catalysis, biochar’s excellent performance in supporting and catalyzing a wide range of reactions has been demonstrated: electrochemical reactions, hydrolysis, gasification/pyrolysis, catalytic reforming/cracking, esterification/transesterification, peroxide/peroxynmonosulfate oxidation, and many more.
Biochar-based catalysts have been utilized for a variety of applications, including water and soil remediation. On the other hand, current perspectives tend to concentrate on applications designed to remediate soils, revegetate, and restore them, convert energy, and remove contaminants from water and wastewater. Despite this, there is still a lack of understanding regarding the synthesis, development, and novel applications of biochar-based catalysts. This chapter provides a comprehensive overview of recent developments in the production, application, and limitations of biochar-based catalysts. Various emerging catalytic applications of biochar-based catalysts are also addressed in this chapter. Further, the benefits of using biochar as catalysts and catalyst supports, as well as the correlations between structural and physical properties of biochar, which provide insights into the development of effective and promising biochar-based catalysts will be highlighted. The challenges and future advancements of using biochar-based catalyst materials are further discussed.
Biochar is a form of organic material that is mostly rich in carbon and other elements such as nitrogen (N), oxygen (O), and hydrogen (H). Biochar has a carbon (C) content ranging from 380 to 800g kg−1 and has both alkyl and aromatic structures [7]. Biochar is also composed of inorganic elements including phosphorus (P), calcium (Ca), aluminum (Al), potassium (K), and silicon (Si), whose quantities vary according to the feedstock used [8]. It has been reported that acidic pH can occur during pyrolysis, depending on conditions of production and the raw materials [9]. Other factors can affect the biochar pH, ranging from neutral to alkaline [10]. In general, biochar has a pH between 5 and 12, and its pH tends to increase in response to increased pyrolysis temperature as bionic acid decomposes, and mineral alkali elements increase [11]. Also, the high pH of biochar can be attributed to the functional organic groups present in it, namely hydroxyl-, aldehyde, and ketone- [12]. As a buffer between acid and bases, these functional organic groups influence biochar’s hydrophobicity and hydrophilicity as well as its adsorption properties [8]. The functional organic groups have the effect of lowering the negative charge on biochar, and therefore, enhancing its cation exchange capacity (CEC) [13].
Due to its high carbon content, biochar has a complex microstructure with numerous pores, which maximizes its surface area [14]. Biochar’s surface area and total pore volume typically range from 8 to 132 m2/g and 0.016–0.083 cm3/g, respectively. Using the right precursor and pyrolysis parameters, biochar can have surface areas and pore volumes as high as 490.8 m2/g [15] and 0.25 cm3/g [16]. Following effective post-treatments, such as potassium hydroxide (KOH) activation, the surface area and total pore volume of biochar can be enhanced to 3263 m2/g and 1.772 cm3/g, respectively [17], which is comparable to or even greater than commercial activated carbon. Biochar’s surface area and porosity are greatly affected by the pyrolysis temperature [16]. Biochar with a higher pyrolysis temperature within a certain temperature range has a greater surface area [12]. As temperature rises in biochar pyrolysis, volatile substances are forced out of the char, causing pores to form a larger surface area [17]. Due to its high porosity/high amount of residual pores and large surface area, biochar can retain a large quantity of water [14, 18, 19, 20]. In contrast, a high pyrolysis temperature diminishes the polar functional groups found in biochar, thereby increasing its hydrophobicity [18]. According to the above characteristics, biochar can influence the, pH, soil water-holding capacity, as well as base saturation, and CEC [14]. It is generally possible to modify the properties of biochar by modifying its conditions of preparation [19], as outlined in the next section.
To produce biochar from different feedstocks, several approaches have been developed. Torrefaction, pyrolysis, gasification, hydrothermal carbonization (HTC), and flash carbonization are the most prominent thermochemical conversion technologies (Figure 1).
Overview of biochar-based system production and applications.
Torrefaction is a mild pre-treatment consisting of slow heating at 200–300°C, followed by a short retention time before gasification or pyrolysis [20]. Often, the resultant solid product is porous, low density, and carbon-enriched, with low moisture content and O/C ratio, an increase in energy density, and improved grindability, making it easier to store and deliver [21]. Its carbon yield can be affected by temperature, retention times, raw material types, and furnace atmosphere [22]. At 200°C, for example, beech lignin began to degrade, the majority of biomass developed at 230°C and cellulose only degraded over 270°C [22]. Using a pilot process, hardwood and switchgrass pellets produced solid yields above 77 wt% [23]. Oil palm fiber pellets were torrefied in an inert atmosphere for 30 min and in an oxidizing atmosphere for 30 min at 275–350°C to yield 43 and 65 wt% biochar, respectively [24].
Pyrogenic carbons are produced by the decomposition of biomass at 300–1200°C without oxygen (or with limited oxygen). During pyrolysis, biochar is produced at temperatures ranging from 300 to 700°C. A pyrolysis process can be classified into slow, fast, intermediate, flash, and vacuum modes [25].
In slow pyrolysis, the process temperature is lower (400–600°C), the heating rate is slower (~10°C min−1), the vapor residence time is much longer (5–30 minutes), and the holding time is long (hours to days) [25]. Biochar typically yields 20–40 wt%, with yields decreasing with increasing pyrolysis temperature and heating rate [26], however, biochar characteristics are also affected by the procedure and feedstock used [27]. Comparing biochars derived from the wood stem and bagasse with palm kernel shell, paddy straw, and cocopeat, biochar derived from the wood stem and bagasse exhibited a wide range of pores and a high surface area. Biochar develops a significant surface area structure and pore structure at around 500°C [28] with a wide range of mineral compositions and high thermal stability [29].
Fast pyrolysis refers to the treatment of biomass at high temperatures without oxygen [30]. It is usually necessary to dry and grind the feedstock to facilitate effective heat exchange and conversion. This technique produces high liquid yields (bio-oil) rather than solid char (15–25 wt%) [31]. In contrast to the slow pyrolysis of wheat straw, fast pyrolysis generated biochar with a labile un-pyrolyzed carbohydrate fraction (8.8%) rather than carbonized completely [32]. There was a significant difference in the pH, particle size, and specific surface area for biochars produced using these two methods at 400°C, as well as a significant increase in surface area at 500°C (175.4 m2 g−1), in comparison to 300°C (2.9 m2 g−1) and 400°C (4.8 m2 g−1) [21, 33].
Intermediate pyrolysis produces 15–35 wt% dry and brittle biochar at temperatures between slow and fast pyrolysis, i.e., solid residence durations of 0.5–25 min, vapor residence times of 2–4 s, and moderate temperatures up to 500°C [34]. Utilizing barley straw and wood pellets, a pilot-scale production yielded 30 wt% char with a carbon content of 75 wt% [25]. The process produces 51.7 wt% char from the organic fraction of municipal solid waste as a result of inert fractions in the biomass [35]. Table 1 illustrates the product yield of pyrolysis processes.
Process | Bio-oil (liquid) | Biochar [37] | Syngas (gas) |
---|---|---|---|
Fast pyrolysis Short hot residence time (<2 s) Moderate temperature (~500°C) | 75% (25% water) | 15–25% | 10–25% |
Intermediate pyrolysis Moderate hot vapor residence time Low-moderate temperature (300–400°C) | 50% (50% water) | 25% | 20–30% |
Slow pyrolysis Long residence time Low-moderate temperature (200–300°C) | 50% (50% water) | 35% | 35% |
Gasification Long vapor residence time High temperature (>700°C) | 5% tar (5% water) | 10% | 85% |
Summary of product yield of pyrolysis processes [36].
Carbonaceous materials are turned into char, tars, and syngas through gasification at high temperatures (~800°C) in the presence of a gaseous active medium (e.g., carbon dioxide, air, nitrogen, oxygen, steam, or gas mixtures) [37, 38]. During this process, the material is dried, pyrolyzed, partially oxidized, and reduced. Generally, char only makes up 5–10 wt% of the mass of the feedstock [39]. As a by-product of large-scale processes, biochar is produced in large quantities every day. Biochar produced through gasification usually has smaller particles than biochar produced by pyrolysis, lower surface area, and a lower total pore volume [40]. Since the aromatic rings are condensed, gasification chars contain little carbon (20–60 wt%) but are highly stable, preventing microbial mineralization and chemical oxidation; however, their surface chemistry is constrained by their absence of functional groups [34]. Biodiesel generation, catalytic tar decomposition, soil amendment, anode materials for direct carbon fuel cells, and anaerobic digestion additives are just a few of the uses for gasification char [41].
Biomass can be processed using a thermochemical process called hydrothermal carbonization (HTC). In closed vessels with liquid water and autogenous pressure of 2–10 MPa, the feedstock is heated from 200 to 300°C and hydrochar is produced [42]. The thermal stability of hydrochar is improved by high temperatures (300°C). Wet torrefaction or wet pyrolysis are other terms for HTC [43, 44]. In comparison with biochar, hydrochar contains less carbon, ash, surface area, and a smaller pore volume [39].
Through flash carbonization, biomass can be transformed into biocarbon (i.e., charcoal) rapidly and efficiently, typically by starting and controlling a flash fire at a high temperature within a packed bed (~1 MPa) [45]. The biomass is transformed into gas and charcoal in less than 30 min when the combustion flame flows in the opposite direction of the airflow. Charcoal yields are typically approximately 40 wt% [45].
Biochar can serve as catalyst support. Besides stabilizing and dispersing nanoparticles, biochar can also provide more active sites for catalytic degradation reactions [46]. Biochar’s mesoporous structure enhances the proper dispersion of immobilized metal particles while also preventing particle aggregation owing to intra-particle interaction [47]. The incorporation or fixing of metal elements, for example, magnesium (Mn), copper (Cu), cobalt (Co), and iron (Fe) into biochar pores result in no or minimal metal escape into the aqueous phase [48].
As a heterogeneous catalyst or support, biochar offers many advantages including large surface area, lower cost, functional group tailoring, etc., which makes it highly beneficial for many catalytic applications. There are several intrinsic properties of biochar that contribute to its effectiveness as a catalyst [49]. It has a good thermal, stable structure, mechanical stability, and a chemically hierarchical structure that originates from biomass. Biochar-based catalysts have the following distinctive characteristics: (i) heterogeneity, i.e., the reaction mixture can be easily isolated from other reactants; (ii) bifunctionality, i.e., transesterification and esterification are involved; (iii) recyclable; (iv) porous; (v) non-graphițable, i.e., it does not form crystal at high temperatures [50]. Comparing biochar-based catalysts with other solid-based catalysts, biochar has the advantages of being cost-effective, eco-friendly, easy to produce, reusable, and biodegradable.
Furthermore, biochar as a catalyst can be used in many different fields, including agriculture, environment, and energy, for biodiesel production, tar removal, waste management, production of syngas, production of chemicals, and removal of contaminants, etc. [45, 51]. Biochar is an excellent catalyst with several beneficial properties. Biochar, for instance, is catalytically active in cracking tar because of its presence of inorganic elements including Fe and K [47]. A biochar-supported metal catalyst can be synthesized by adsorbing metal precursors on its surface functional groups [52]. Despite this, biochar has some properties that preclude it from functioning as a catalyst, such as poor porosity and low surface area. Considering that biochar contains more functional groups, it must have a large surface area for catalysis. A functional group, such as OH, adsorbs norfloxacin. Adsorption of ammonium is possible through C〓O and ▬OH groups. To endow biochar with specific properties, it is necessary to develop a variety of modification strategies. Furthermore, several processes can be used to activate feedstocks, control synthesis conditions, functionalize materials on the surfaces, form composites with other materials [53], etc.
In addition to its properties, biochar’s potential for specific applications is dependent on both the biomass source and the conditions of preparation. Biochar, for instance, is suitable as an electrode material because it is electrically conductive and porous [54]. It has been proven that structurally bound nitrogen groups and high porosity biochar make superior supercapacitor electrode materials [55]. However, the intrinsic inorganics, matrix nature, and surface functionality of biochar have a significant influence on its catalytic performance.
The carbon content of activated carbon from coal is approximately 80–95%; however, that content is lower for biochar (45–60 wt%) than carbon black (98%) [5]. Biochar also contains substantial amounts of hydrogen and oxygen. Another characteristic of biochar is that it contains small amounts of inorganic elements like potassium, sodium, calcium, magnesium, sodium, iron, and calcium. The nature of raw biomass greatly affects the amount and composition of inorganics. Woody biomass, as well as herbaceous and hydrophyte biomass, usually have a much lower inorganic content than biochar made from these sources [56, 57].
The inorganic components of biochar are crucial to many of the biochar’s catalytic applications [47], including tar cracking [58], methane decomposition, and bio-oil upgrading [59].
Amorphous crystalline sheets of high-conjugated aromatics make up most of the biochar matrix. As shown in Figure 2, these aromatic sheets are crosslinked randomly. In response to rising processing temperatures, biochar crystallites increase in size, and order is created throughout the entire structure [62]. The aromatic structure of biochar may also contain heteroatoms, including N, P, and S. These heteroatoms have a different electronegativity from the aromatic C, which results in biochar’s chemical heterogeneity. This plays a key role in catalytic applications [58].
Chemical structures of (a) pyrochar and (b) hydrochar (adapted from Shi & Lee) [
Comparing biochar to other carbon materials including (activated carbon and carbon black), Figure 3 shows that it typically contains large numbers of surface functional groups. Biochar can be functionalized using its surface functional groups. Moreover, biochar has been shown to facilitate the loading of metal precursors onto metal catalysts as part of the synthesis of a metal catalyst supported by biochar [52]. Biochar-based catalysts can also work better for certain reactions if they contain some surface functional groups. Biochar-based solid-acid catalysts are typical examples. Kitano, Yamaguchi [63] demonstrated that sulfonated carbon is more effective at hydrolyzing cellohexaose, than sulfonic acid (SO3H)—bearing resins. Adsorption sites, in this case, were found in the carboxylic acid (COOH) and hydroxyl (OH) groups of phenolic groups in the carbon material. Researchers found that the combination of functional groups on biochar-based solid acids was efficient for hydrolyzing cellulose and 1,4-glucan.
A porous biochar model with multiple functional groups (adapted from Yang et al [
Biochar has been activated and functionalized in various ways to adjust its physicochemical properties, leading to enhanced reactivity in a range of processes and applications [48]. Impregnation and physical or chemical activation are the most popular methods.
Feedstock | Production method (biochar) | Production method (catalyst) | Type of catalyst | Ref. |
---|---|---|---|---|
Banana | Carbonization | Wet impregnation | Solid alkali | [49] |
Vegetable oil asphalt, coconut shell, oat hull, glucose, peanut shell | Carbonization | Sulfonation | Solid acid | [50] |
Rice husk | Carbonization | Chemical activation | Solid acid | [51] |
Peat | Carbonization | Wet impregnation | Solid alkali | [52] |
Irul wood saw dust | Slow pyrolysis | Sulfonation | Solid acid | [53] |
Pamelo peel, shelled palm kernel | Carbonization | Wet impregnation Calcination | Solid alkali | [54] |
Production methods and feedstocks for biochars and biochar-based catalysts.
This technique involves mixing feedstock and metallic precursors (in-situ) into biochar structures to incorporate active metallic species into them [64]. With the use of biochar, lignin magnetite pellets were synthesized into zero-valent iron at 900°C [64]. It was possible to remove trichloroethylene by both adsorptive and degradative mechanisms due to the macro-porosity developed. Rice straw biochar was impregnated with cobalt nitrate (Co(NO3)2), then hydrothermally treated and calcined to produce the composite [65]. In comparison to pure biochar (43.0 m2 g−1, 0.081 cm3 g−1) and cobalt (II, III) oxide (CO3O4 (37.0 m2 g−1, 0.184 cm3 g−1), the composite showed greater SBET (62.7 m2 g−1) and total pore volume (0.207 cm3 g−1). The catalyst was shown to be effective for oxidatively degrading ofloxacin (over 90% removal in 10 min) using peroxymonosulfate (PMS). An X-ray photoelectron spectrometer (XPS) study revealed that the rich mesoporous support contains many CO▬OH groups, which are important for activation. The obtained pristine biochar may also contain metal species varying in amounts and characteristics, depending on the biomass source. Despite this, impregnation typically produces composites rather than carbonaceous biochar, so one could compare biochar with impregnated composites and exhausted catalysts.
A physical activation process involves exposing the pyrolyzed biochar materials to a streamflow control or carbon dioxide or a mixture of both when temperatures exceed 700°C. Gaseous activation agents, depending on the degree of C▬H2O and/or C▬CO2 gasification that occurs at such high temperatures, are capable of partially eroding carbon atoms in the as-prepared biochar matrix [66]. By physically activating the carbonized material, most of the reactive carbon parts can be eliminated and the enclosed pores in the biochar matrix can be opened and interconnected [67]. Consequently, the surface area of biochar increases significantly, resulting in an improved micropore structure and a lower mesopore content [68]. Figure 4 illustrates the process for producing biochar-based catalysts.
Method involved in producing biochar-based catalyst.
Activated biochars differ significantly from one another in terms of a specific area, pore size distribution, and porosity based on the type of biomass, reaction parameters, and activating gas [66]. Lima et al. [62] for example, evaluated the effects of steam activation on the surface areas and porosities of different biochars, as well as their metal ion adsorptive capabilities. They found that steam-activating biochars at 800°C for 45 minutes dramatically increased the surface area and micropore volume from less than (5 m2 g−1) to (136–793) m2 g−1. In addition, due to the increased porosity and surface area, these biochars were able to improve their metal ion adsorption performance to varying degrees after activation [69]. In addition, Kołtowski et al. [60] utilized steam and CO2 to activate biochar produced from the slow pyrolysis of willow. Their findings revealed that both steam and carbon dioxide activation considerably increased the porosity and surface area of biochar. Additionally, steam-activated biochar (840.6 m2 g−1) and CO2-activated biochar (512.0 m2 g−1) showed significantly larger surface areas than those of unactivated biochar (11.4 m2 g−1). In contrast with the CO2-activated biochar, steam-activated biochar was found to have higher specific surface areas and pores [60].
Chemical activation involves mixing freshly prepared biochar with activation agents (e.g., KOH, ZnCl2, K2CO3, H2SO4, H3PO4, etc.). The biochar is subsequently heated at high temperatures in an inert gas flow [70]. While the mechanism for chemical activation is still unclear, chemical activation is more corrosive than physical activation [71]. However, high temperatures can significantly enhance the corrosion properties of chemical activation substances. Aside from removing some carbon atoms from the biochar matrix, these chemicals might suppress tar formation and/or facilitate the formation of volatile compounds [67]. It was reported by Liu et al. [59], that chemical erosion and physical activation lead to large surfaces and high porosities in KOH-activated biochar, and metallic K intercalation. Chemical activation generally results in a higher activation efficiency than physical activation, and chemical activation may be performed at a relatively lower temperature, resulting in a more porous and higher surface area biochar [43]. Although chemical activation leaves biochar with improved surface area and porosity, it is usually necessary to wash it to remove impregnating agents and salts [50]. The use of chemical activation is, therefore, affected to some extent by several factors, including corrosion of equipment, chemical recycling, secondary pollution, etc. [43].
Several factors affecting the chemically activated biochar, including the temperature of activation, feedstock type, the type, and concentration of the activating agent, etc., are significant [66]. Biochar impregnated with KOH solution has been investigated by Dehkhoda et al. [65] to determine how activation temperature (685–700°C) influenced the electrosorption performance, porosity, and surface area. In their study, there was an increase in the surface area of the biochar from (1.66 m2 g−1) to (614–990 m2 g−1), as well as its porosity, which increased from negligible to 0.6–0.9 m3 g−1. Additionally, as the temperature rises, a decrease in biochar surface area is observed, by collapsing and burning off the micropore walls or causing the formation of graphite-like structures in the matrix. Since biochar activated at 675°C contains more micropores and oxygen-containing functional groups, its overall electrosorption capacitance was more than twice as high as that of activated biochar at 1000°C [68].
The growing discovery of biochar as a diverse material for catalytic activities has prompted preliminary study into the catalytic potential of biochar as well as applications in different processes.
It has been demonstrated that biodiesel can be used as a renewable alternative to traditional petrochemical-derived diesel [67, 72]. The application of traditional catalysts in the synthesis of biodiesel from biomass (vegetable oils) has been extensively explored. However, the manufacture of such catalysts necessitates the use of costly metal precursors. Because of their low cost and versatility, sulfonated biochars have been utilized to produce biodiesel. It has been demonstrated that sulfonated biochar can produce the maximum productivity (88%) of biodiesel products from vegetable oil in the esterification of FFAs (free fatty acids) and transesterification of TGs (triglycerides) carried out simultaneously at 100°C for 15 h [72, 73, 74]. It was observed that after five recycles of the catalyst, the output of methyl esters reduced from 88% to 80%, due to the leaching of ▬SO3H functional groups [74]. Using a biochar catalyst made from palm kernel shells to transesterify sunflower oil, Kostić et al. [69] investigated the catalytic activity. With the deposition of 3 wt% catalysts into a reaction, the production of methyl esters was 99% at 65°C [75]. The solid acid/base biochar catalysts mentioned above resulted in a significant synthesis of biodiesel from a variety of edible oils. In contrast, both catalysts exhibited signs of deactivation after many re-uses in the laboratory. While transesterification was taking place, the base catalyst was contaminated by undesired secondary products formed by CaO and the feed oil interactions [75]. The ester output (from TGs and FFAs) is comparable to that obtained from non-biochar catalysts. However, to make biochar catalysts for biodiesel generation more realistic, the stability of biochar catalysts must be increased to prevent the need for post-treatment processes to remove S or Ca from the catalyst [75]. The biodiesel production efficiency of different biochar and non-biochar-based catalysts is shown in Table 3.
Biochar-based catalyst | Feedstock | Temp. | Biodiesel yield | Ref. |
---|---|---|---|---|
Wood biochar-mixture | Canola oil | 423 K | 44% | [76] |
Peanut hull-biochar | Palmitic + stearic acid + soybean oil | 333 K | 70% | [77] |
Husk of rice | Oleic acid + canola oil | 423 K | 48% | [78] |
Rice husk-biochar | Cooking oil waste | 383 K | 88% | [79] |
Biochar-palm kernel shell | Sunflower oil | 333 K | 99% | [80] |
Al(HSO4)3 | Vegetable oil waste | 493 K | 81% | [81] |
Zeolite beta | Cooking oil waste | 353 K | 25% | [82] |
SO42−/ZrO2 | Cooking oil waste | 353 k | 44% | [83] |
A comparison of biochar and non-biochar-based catalysts for biodiesel production.
Biochar catalysis has been applied in biomass hydrolysis. The fact that most biochar-based catalysts are more effective than commercially available and traditional catalysts has long been recognized. According to Ormsby et al. [75], pinewood chips and peanut hulls that were sulfonated with H2SO4 were used as the raw materials for biochar. When used to hydrolyze xylan, the sulfonated pine chip-biochar catalyst demonstrated an 85% transformation rate in 2 h at 393 K. On the other hand, while having a greater surface area (1391 m2g−1) than the biochar catalyst (365 m2g−1), industrial activated carbon only achieved a 57% transformation in 24 hours [84]. Furthermore, biochar catalysts showed greater starting process rates for the hydrolysis of cellobiose and xylan when compared to other catalysts (activated carbon and Amberlyst-15) [84], indicating that they were more efficient than the other two catalysts. Moreover, the hydrolysis of maize stover, switchgrass, and prairie cordgrass biomass was accomplished using a corn stover-biochar mixture [85]. Compared to a traditional homogeneous H2SO4 catalyst, the catalyst exhibited a stronger preference for glucose and xylose, confirming its superior efficiency in biomass hydrolysis. The existence of sulfonated corn stover-based biochar increased the production of glucose and xylose from lignocellulosic biomass [48]. The glucose output was 8–10% and the xylose yield was 23–41% when compared to the equivalent polysaccharide [85]. The findings were equivalent to those obtained from the hydrolysis of model substances using a similar catalyst: cellulose yielded 3% glucose and xylan yielded 40% xylose. This indicated that the biochar was able to sustain good efficiency even when exposed to contaminants and a complex matrix of biomass materials. The performance of different biochar based catalysts for hydrolysis is shown in Table 4.
Feedstock | Condition of catalyst preparation | Feedstocks | Condition of reaction | Catalyst performance | Ref. |
---|---|---|---|---|---|
Forestry wood waste | Slow pyrolysis at 700°C for 15 h; sulfonated with 30 w/v% H2SO4. | Fructose or maltose | Ccata = 25 w/v%, T = 1 h (maltose: 160°C and fructose: 180°C), CF = 5 w/v% | Selectivity = 60.4%; HMF yield = 42.3%; selectivity = 88.2%. Glucose yield = 85.4% | [86] |
Palm kernel shells | Carbonized at 550°C for 4 h; sulfonated at 120°C for 6 h with concentrated sulfuric acid | Cellobiose | Ccata = 50 g/L, T = 24 h, Temp. = 110°C CF = 100 g/L | Glucose yield ≈ 100% | [87] |
Bamboo | Carbonates of alkali molten molten at 450°C; pyrolyzed at 450°C; sulfonated at 150°C for 6 h | Cellulose | Ccata ≈ 16.67 g/L, T = 12 h, Temp. = 150°C CF ≈ 16.67 g/L | RSs yield = 52.8%, Glucose yield = 43.5% | [88] |
Bamboo | 80% sulfuric acid treatment; immersion in oleum and heating with N2; ultrasonic vibration treatment with NaCl saturated aqueous solution; treatment with an excess of IL-Cu in anhydrous MeCN | Bamboo and cellulose | Bamboo: CF ≈ 133.33 g/L, Ccata ≈ 66.67 g/L, T = 2 h, Temp. = 110°C, Microwave radiation = 750 W. Cellulose: CF ≈ 133.33 g/L, Ccata ≈ 66.67 g/L, T = 2 h, Temp. = 90°C, Microwave radiation = 350 W | TON: 3.54 (cellulose), 2.42 (bamboo), RSs yield = 35.6% (cellulose), 22.5% (bamboo) | [89] |
Biochar catalyst for hydrolysis.
Hydroxymethyl furfural = HMF, reducing sugars = RSs, TON = turnover number, temperature = Temp, time = T, catalyst amount = Ccata, feedstocks concentration = CF, imidazolium chloride = IL-Cu; anhydrous MeCN = anhydrous acetonitrile.Source: Adapted from Shan et al. [90].
Tar reforming is the process of converting the hydrocarbon combination that is inevitably generated following the gasification and pyrolysis of biomass into useful syngas (combination of CO and H2). Syngas is a multipurpose intermediate and/or beginning raw material for the synthesis of fuels and chemicals. As a result of this fact, several studies have investigated the potential involvement of biochar catalysts in the generation of syngas in recent years [58]. Biochar comprises catalytic centers that are similar to those found in traditional catalysts, such as dolomites (MgCO3·CaCO3), olivine ((Mg2+, Fe2+)2SiO4), and Ni- and alkali metal-based catalysts, could be efficient for tar reforming [78]. The switchgrass biochar that had been activated by KOH demonstrated the highest efficacy, with around 90% elimination of toluene. This was likely owing to the increased surface area of the switchgrass biochar. Iron calcined biochar [79] and nickel nanoparticle-embedded biochar [80] have also been shown to be efficient. Ren et al. [58] noted that the application of a biochar catalyst improved the quantity of syngas produced during biomass pyrolysis. At 480°C, it was discovered that the syngas output increased from 15 wt% to 46 wt% in the absence and presence of biochar catalyst respectively. According to Ren et al. [58, 81], the hydrogen content in syngas rose significantly with the addition of the biochar catalyst (27 vol%), in contrast to when the catalyst was not employed. A current investigation shows that biochar can be applied in the dry reforming process [82]. The dry reforming of CH4 was carried out on a tungsten carbide [83] Based on a biochar (WC-biochar) catalyst. As the CH4/CO2 ratio rose, the CH4 transformation reduced, while the CO2 transformation improved. Increases in the CH4/CO2 ratio and temperature resulted in greater H2 production, and the WC-biochar catalyst remained stable for 500 hours after being introduced into the system [82].
The gasification of biomass is a viable sustainable energy pathway since it has the potential to enhance the generation of large quantities of syngas. A consequence of its synthesis, however, is the formation of condensable hydrocarbons (tar). Tars can accumulate in pipelines throughout a system, causing them to become clogged and potentially inhibiting downstream operations [84]. To commercialize biomass gasification for syngas generation, the elimination and/or mitigation of tar is a vital first stage in the procedure [85, 90]. In reality, catalytic tar cracking was carried out at 823–1173 K, with dolomite, olivine, and base metals including nickel [78], serving as catalysts. These conventional tar cracking catalysts, on the other hand, were susceptible to deactivation as a result of coking and contamination [91]. It has been attempted numerous times to degrade tars using a secondary reactor containing noble metal catalysts (e.g., platinum, palladium, and rhodium) [92], but the restoration of the catalyst has remained a difficult process. The introduction of an affordable catalyst for tar breakdown is therefore preferable in this situation. In this regard, biochar was found to be superior to traditional catalysts when used as a catalyst to remove tar [93]. The tar removal efficiency of biochar catalysts is summarized in Figure 5. The majority of investigations have relied on model processes of tar disintegration with toluene, naphthalene, and phenol. Moreover, the biochar-based metal catalysts (e.g., Nickel and Iron) outperformed the typical mineral catalysts in terms of tar removal efficiency. For example, a catalyst constituted of a combination of NiO and wood-biochar eliminated 97% of the genuine tars formed during sawdust gasification, resulting in an improvement in syngas synthesis attributed to the catalytic reformation of the tars [94]. According to Shen et al. [79], bimetallic catalysts based on rice husk-biochar generated seven times fewer tars in the biomass combustion process than monometallic catalysts and raw biochars during the pyrolysis of biomass. The NiO-biochar catalyst combination remained stable for an 8-h time in the stream (TOS). One of the limitations linked to biochar and metal-biochar catalysts for tar reduction is the process temperature, as tar elimination occurs at >973 K. At reduced temperatures (i.e., 843 K) with the typical nickel catalyst, tar removal can be commenced [92], however, biochar is not yet efficient at these lower temperatures [95]. To overcome these restrictions and broaden the scope of biochar’s application as a catalyst, future work must concentrate on overcoming these constraints.
Evaluation of tar elimination using biochar-based catalysts at 973–1173 K (adapted from Lee et al. [
Due to its ability to remedy environmental pollutants, biochars are becoming highly significant for enhancing environmental quality in the world today [96]. Wastewater, which is a result of household, commercial, and agricultural operations, has long been a global concern since it affects everyone. Biochars offer a significant deal of promise for use in wastewater remediation applications. Biochar’s applications in the cleanup of different wastewaters are the primary focus of this section.
Industrial wastewater originates from a variety of sources. In addition, heavy metals and organic contaminants are the most prevalent contaminants in industrial wastewater. It has been demonstrated that biochars can be used in the treatment of industrial effluent. It is possible to cast membranes, beads, and solutions from a biochar-chitosan combination that has been cross-linked. It has the potential to be used efficiently as an adsorbent for the adsorption of heavy metals in industrial wastewater. The amount of chitosan and biochar used in the adsorption of Cu, Pb, As, Cd and other heavy metals in industrial wastewater would depend on the ratio of the two materials [97]. Gliricidia biochar has shown promise in the elimination of crystal violet (CV) from aquatic environments in dye-based industries. A biochar’s pH value, surface area, and pore volume are all important factors to consider throughout the CV sorption process [98]. Biochar made from bagasse was employed to absorb lead from the effluent of the battery production sector. The maximal adsorption ability can attain 13 mg/g, and the adsorptive activity is dependent on the moderate pH value, contact time, and concentration [99]. So far, the majority of the trials on the utilization of biochar in the clean-up of contaminants from industrial wastewater have been carried out in a laboratory environment; however, additional study and deployment in the actual situation are required.
Biochar can be employed alone or in combination with other techniques for municipal wastewater treatment, resulting in the retrieval of labile nitrogen and phosphorus [100]. Engineered biochar containing aluminum oxyhydroxides (AlOOH) was used to recover and restore phosphorus from tertiary remediated wastewater [101]. The adsorption strategy of phosphorus is mostly based on electrostatic interaction. Phosphorus adsorbed on manufactured biochar has the potential to be used as a slow-release fertilizer for agricultural activities. Biochar generated from digested sludge was employed as an adsorbent for the elimination of NH4 from municipal wastewater. Biochar produced at 723 K has the maximum NH4 reduction capability due to its increased functional group density and surface area, and the procedure is governed by chemisorption [102]. This shows that biochar derived from waste sludge can be utilized to ozonate refinery effluent and achieve a significant reduction rate of total organic carbon (TOC) [103].
Because of the rapid development of the agriculture sector, agricultural pollution is getting extremely serious. As a result, pesticides and toxic heavy metals are released into croplands in large quantities, the situation is becoming increasingly worrisome [104, 105]. The use of biochar and its modified forms in the remediation of agricultural wastewater pollution has been investigated. Pesticides such as atrazine and pentachlorophenol are two of the most often used in agriculture. Adsorption of atrazine and imidacloprid from agricultural wastewater by rice straw biochar and phosphoric acid-modified rice straw biochars is much higher than that of adjusted rice straw biochar [106]. Corn straw and soybean biochars both exhibit strong atrazine reduction potentials, with the adsorption efficiency owing mostly to the pH value and pore volume of the biochars [107]. Steam-activated biochar is efficient at eliminating sulfamethazine, and the rate at which it absorbs the substance is reliant on the pH value [108]. The presence of hazardous heavy metals in agricultural wastewater is yet another widespread issue.
Recent advancements in the use of biochar for processes other than agriculture have been linked to biochar’s various properties. Among other characteristics that are suitable for electrode materials, biochar has high porosity and high electrical conductivity [54]. It is preferred to use biochar with structurally bound nitrogen groups and high porosity as electrode materials for supercapacitors [55]. During catalysis, surface functionality, matrix nature, and intrinsic inorganic components are all important factors [49]. Unlike activated carbon derived from coal, biochar has a considerable amount of other organics present in it based on the biomass feedstock. These organics aid its compatibility, utilization, and effectiveness for varying applications than activated carbon.
There are several advantages to using biochar as a catalyst or catalyst support. Firstly, since biomass resources are sustainable and synthesis techniques have been developed, the process for producing biochar is simple and inexpensive. Secondly, the physicochemical properties of biochar can be easily tuned through a variety of methods. As a third consideration, biochar may be of interest in catalytic applications because of its surface functional groups, a hierarchical structure derived from the biomass matrix, and the presence of inorganic species [48]. Additionally, active metals and biochar support may, in some cases, have synergistic effects on catalysis [49].
Due to excess energy generation, energy storage is becoming more popular in some developed countries, and stored energy can also be used as a backup in the event of an emergency. The increased use of electric vehicles necessitates the continuous development of batteries with greater energy storage capacity. Despite continuous battery development, there are times when an unplanned situation may occur in electric vehicles. To alleviate such a situation, supercapacitors, which are energy storage devices primarily made of carbon materials, have been applied as continuous power sources in digital communications systems and electric vehicles. Because of its wide availability and low environmental impact, carbon materials with a high surface area and a rich porous structure are the primary raw materials for making super-capacitors [98]. It is crucial to the development of the supercapacitor industry to produce attractive, high-quality carbon materials at a reasonable price [99].
The utilization of biochar as material for supercapacitors has been tested by researchers with incredible results obtained. Biochar is made from paper cardboard and woody biomass. Based on the pyrolysis of woody biomass, the biochar supercapacitor electrodes exhibited a potential window of about 1.3 V, and fast charging-discharging behaviors with about 14 F/g gravimetric capacitance [100]. The authors also enhanced the performance of woody biochar by activating it with nitric acid. According to the researchers, the nitric acid treatment helped increased the capacitance from 14 to 115 F/g with 5000 usage cycles [100]. Likewise, Liu et al. [98] also created a high-performance supercapacitor out of biochar-derived carbon monolith, which was created by pyrolyzing poplar wood at 900°C for 6 h and then surface-modifying with nitric acid. The supercapacitor was discovered to have a highly consistent structure as well as a high porosity. The maximum specific capacitance was high (234 F/g) and cyclic stability was excellent [98, 99].
With the recent development of direct carbon fuel cell (DCFC) which converts carbonaceous material directly into electricity. The DCFC directly oxidizes solid carbon to produce electricity by using the chemical energy contained therein. Fuel utilization can reach nearly 100% if fuel feed and product gases are separated easily. The use of biochar as an energy source for this fuel cell has shown tremendous results. In a study by Kacprzak et al. [101], nine different carbonaceous fuels were tested, including commercial graphite, a carbon black, two commercial types of hard coal, and four biochars made by the authors, and one commercial biochar. At 0.5 V, commercial biochar had the second-highest current density (64.22 mA/cm2) and the third-highest power density (32.8 mW/cm2). Biochar produced in the laboratory had a high current density (36–44.6 mA/cm2) and power density (18–22.4 mW/cm2) [102].
The use of biochar just as any other material has some limitations in its application for energy storage, conversion, and electrocatalyst. In terms of energy storage, the performance efficiency of tested biochar is still low when compared to its counterparts, though the biochar is easy to access and economical. Likewise, in the use of biochar in DCFC, it has been reported that upon consumption of the carbon content, the ash content present in biochar blocks the active surface area thereby impeding the effectiveness of the whole process [102]. In terms of reusability as a catalyst, further work still needs to be done as biochar from some feedstocks is reusable after the second attempt. For electrochemical oxidation of fuel, an ideal anode should have a large surface area, high porosity, and a continuous frame to ensure mechanical strength. Boosting the DCFC’s power output and durability is therefore possible by improving its anode material [99].
Along with biochar’s widespread use in wastewater remediation, scientists should consider its possible adverse impact on the ecosystem. To effectively employ biochar, one of the most significant features that must be considered is its capacity to maintain its stability throughout time. The aromaticity and extent of aromatic condensation of biochar are two factors that influence the stability of biochar [103]. When biochar is employed for wastewater detoxification, the possible emission of carbon from the biochar can cause the carbon concentration of the solution to be treated to rise. Moreover, the discharge of heavy metals from biochar formed from sludge is a possibility, particularly for biochar generated from sludge. Huang et al. [105] demonstrated that the dissolution of organic materials from biochar into an aqueous solution is caused by the biochar’s instabilities. In addition, it was discovered that the stability of the biochar deteriorated after multiple cycles when it was employed as a support for a catalyst. This can be attributed to variations in the carbon framework of the biochar. It is usually acknowledged that the stability of biochar relies on the type of the starting feedstock as well as the experimental settings utilized during its thermal transformation. As a result, it is required to establish a relationship between these two factors and the stability of the biochar. Another significant element to consider is the renewal and restoration of biochar after it has been utilized. The adsorption procedure is characterized by the transition of pollution from the liquid stage to the solid material/adsorbent phase in most cases. As a result, it is critical to transforming the hazardous pollutants that are bonded to biochar into non-toxic conditions to control them effectively [101].
The use of biochar-based catalysts can be beneficial in several catalytic processes, including biodiesel production, bio-oil up-gradation, reforming, and various organic reactions involving specialty or functional chemicals. These are currently in their infancy and must be scaled up. Biochar production systems must be set up on an industrial scale to enable the scaling up of these processes. The biggest barriers to scaling up biochar production are multiple competing end-users, as well as the collection and transportation of raw materials to the facilities that manufacture biochar. Homagain [107] studied the sensitivity of transportation distance and distinct carbon offset values and found that the system is financially viable at 200 km with good biomass availability. Furthermore, the seasonal biomass production cycle makes it difficult to maintain a steady supply of sustainable and reliable fuel.
The moisture content and particle size are other critical parameters in the synthesis of biochar. The biochar production method requires a lot of energy to process feedstocks with a high moisture content or large particle size. During biochar production, it is necessary to pre-process feedstock by drying and reducing its size. The heat resistance of feedstocks, on the other hand, limits heat transfer during biochar formation. Due to temperature differences, this phenomenon causes unconverted feedstock to accumulate on the inner walls of reactors, posing a significant barrier to the widespread production of uniform biochar [103].
Biochar’s properties can also be difficult to fine-tune once it has been produced to achieve the required transformation. Following the proper design of biochar-based catalysts, the resulting materials will have real-world applications and will be able to replace catalysts that are expensive, non-renewable, and harmful to the environment. These conditions can be met by conducting mechanistic investigations during the char activation/synthesis/loading of necessary metals and catalytic processes. It is critical to comprehend two key factors in the catalytic process. The first is the interaction between biochar’s physicochemical properties and its catalytic activity. The second step is to tune physicochemical parameters during the char production and activation process based on catalytic activity. Regarding this, the investigation of high surface area, active sites, and optimal pores is critical to managing the combined impacts of important production process variables (e.g., reagent gas, duration, heating rate, and temperature) and activation process variables (e.g., chemical, and physical). Just a few experiments have been conducted to control the physicochemical parameters of biochar for catalytic applications. However, the biorefinery of the future will require a single-step method for producing biochar with effective porous structure and functionality that is closely related to the production of biochemicals, biogas, and biofuels.
Although biochar has many applications, biochar-based catalysts are still in the very early stages of development. Therefore, it is imperative to develop a method that can maximize catalytic activity. Researchers are currently exploring the modifications that can be carried out on biochar-based catalysts to apply them in future fields such as catalysis, environmental pollution, energy storage and conservation, and even chromatography.
Laboratory research is still underway for biochar-based catalysts. A purpose-driven synthesis and modification will be necessary for the future of an industrial application. Mechanistic studies may help to achieve this. A first step would be to investigate how biochar’s catalytic properties relate to its physicochemical properties. To accomplish this, advanced characterization techniques of catalytic materials can be combined with theoretical modeling of the mechanisms involved. Second, it is critical to determine how biochar’s properties are affected by synthesis conditions and feedstock. It is extremely difficult to work with biomass because of its complex composition and complex formation mechanism. The application of advanced characterization techniques, such as pyrolysis/gas chromatography/mass spectrometry (Py/GC/MS), and thermogravimetric analysis/Fourier-transform infrared spectroscopy/mass spectrometry (TGA/FTIR/MS), is potentially vital for the future.
In terms of process optimization, the role of catalysts in biochar synthesis must be given much more thought. The presence of some inorganic species in biomass feedstock can catalyze pyrolysis. However, their autocatalysis is not enough to ignite the process. A catalyst must achieve at least one of the following goals: (1) to reduce reaction temperature or residence time so that biochar can be produced more efficiently; (2) to make biochar with desirable properties in a single step instead of having modification and synthesis done separately. In the future, we may be able to produce biochar-supported catalysts directly from biomass using catalysts that can produce effective functional groups and porous structures in a single step. A biomass refinery would also be able to produce biofuels and biochemicals in close coordination with manufacturing biochar-based catalysts, allowing for a more integrated and environmentally sustainable process for using biomass.
Biochars intended for use as catalysts require a functionalization and/or activation process because of their limited porosity, surface area, and surface functional groups. According to the activation technique, biochar can have varying physicochemical properties, such as surface area or porosity. Activated biochar can be endowed with specialized properties via the addition of functional groups or substances, such as selectivity, catalysis, and selective adsorption. Although biochars vary significantly according to the type of biomass they are produced from, as well as their production conditions and functionalization or activation. Future research should focus on the production of biochar with stable properties on an industrial scale.
The use of biochar-based catalysts in environmental applications has excellent catalytic properties. Recent achievements of biochar catalyst preparation procedures, as well as their performance, were examined from a range of applications. Additionally, the catalytic properties of biochar were examined further by its production and activation methods. Through various chemical and/or physical treatments, biochar can be modified in terms of morphology and surface functionality. Therefore, biochar has a strong potential for replacing costly and non-renewable conventional catalysts.
It has been demonstrated that biochar-derived catalysts are effective in a variety of reactions, including the production of biodiesel from biomass, removal of tars from bio-oil and syngas, and production of syngas. However, biochar catalyst properties (including surface functionality, surface area, porosity, and acidity) vary widely with biomass origin, biochar synthesis conditions, and pre/post-treatment. Yet, there is limited information about how biochar’s properties can be controlled to enable its catalytic applications. Therefore, further research is needed to develop the catalytic properties of biochar to design active, stable, and selective biochar catalysts. Also, if biochar is to be considered as an industrial heterogeneous catalyst, the development of a method that allows for the manufacture of biochar on an industrial scale is extremely desirable. For large-scale production, it is also challenging to secure stable sources of raw biochar materials. To meet these challenges, biochar catalysts must be stimulated and facilitated to be used in real-world applications to replace costly, non-environmentally benign catalysts, which have been used for a wide range of applications until now.
Authors are listed below with their open access chapters linked via author name:
",metaTitle:"IntechOpen authors on the Global Highly Cited Researchers 2018 list",metaDescription:null,metaKeywords:null,canonicalURL:null,contentRaw:'[{"type":"htmlEditorComponent","content":"New for 2018 (alphabetically by surname).
\\n\\n\\n\\n\\n\\n\\n\\n\\n\\nJocelyn Chanussot (chapter to be published soon...)
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\\n\\nJaakko Kangasjärvi 2015-18
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\\n\\nAlberto Mantovani 2014-18
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\\n\\nUlrike Ravens-Sieberer 2016-18
\\n\\nYexiang Tong 2017, 2018
\\n\\nJim Van Os 2015-18
\\n\\nLong Wang 2017, 2018
\\n\\nFei Wei 2016-18
\\n\\nIoannis Xenarios 2017, 2018
\\n\\nQi Xie 2016-18
\\n\\nXin-She Yang 2017, 2018
\\n\\nYulong Yin 2015, 2017, 2018
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\n\n\n\n\n\n\n\n\n\nJocelyn Chanussot (chapter to be published soon...)
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\n\nEwan Birney 2015-18
\n\nFrede Blaabjerg 2015-18
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\n\nJunhong Chen 2017, 2018
\n\nZhigang Chen 2016, 2018
\n\nMyung-Haing Cho 2016, 2018
\n\nMark Connors 2015-18
\n\nCyrus Cooper 2017, 2018
\n\nLiming Dai 2015-18
\n\nWeihua Deng 2017, 2018
\n\nVincenzo Fogliano 2017, 2018
\n\nRon de Graaf 2014-18
\n\nHarald Haas 2017, 2018
\n\nFrancisco Herrera 2017, 2018
\n\nJaakko Kangasjärvi 2015-18
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\n\nJunji Kido 2014-18
\n\nJose Luiszamorano 2015-18
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\n\nMohamed Oukka 2016-18
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\n\nUlrike Ravens-Sieberer 2016-18
\n\nYexiang Tong 2017, 2018
\n\nJim Van Os 2015-18
\n\nLong Wang 2017, 2018
\n\nFei Wei 2016-18
\n\nIoannis Xenarios 2017, 2018
\n\nQi Xie 2016-18
\n\nXin-She Yang 2017, 2018
\n\nYulong Yin 2015, 2017, 2018
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His studies in robotics lead him not only to a PhD degree but also inspired him to co-found and build the International Journal of Advanced Robotic Systems - world's first Open Access journal in the field of robotics.",institutionString:null,institution:{name:"TU Wien",country:{name:"Austria"}}},{id:"441",title:"Ph.D.",name:"Jaekyu",middleName:null,surname:"Park",slug:"jaekyu-park",fullName:"Jaekyu Park",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/441/images/1881_n.jpg",biography:null,institutionString:null,institution:{name:"LG Corporation (South Korea)",country:{name:"Korea, South"}}},{id:"465",title:"Dr",name:"Christian",middleName:null,surname:"Martens",slug:"christian-martens",fullName:"Christian Martens",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:null},{id:"479",title:"Dr.",name:"Valentina",middleName:null,surname:"Colla",slug:"valentina-colla",fullName:"Valentina Colla",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/479/images/358_n.jpg",biography:null,institutionString:null,institution:{name:"Sant'Anna School of Advanced Studies",country:{name:"Italy"}}},{id:"494",title:"PhD",name:"Loris",middleName:null,surname:"Nanni",slug:"loris-nanni",fullName:"Loris Nanni",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/494/images/system/494.jpg",biography:"Loris Nanni received his Master Degree cum laude on June-2002 from the University of Bologna, and the April 26th 2006 he received his Ph.D. in Computer Engineering at DEIS, University of Bologna. 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Almost all the parts of this plant, that are, fruit, leaves, flower bud, trunk, and pseudo-stem, can be utilized. This chapter deals with the fiber extracted from the pseudo-stem of the banana plant. It discusses the production of banana pseudo-stem fiber, which includes plantation and harvesting; extraction of banana pseudo-stem fiber; retting; and degumming of the fiber. It also deals with the characteristics of the banana pseudo-stem fiber, such as morphological, physical and mechanical, durability, degradability, thermal, chemical, and antibacterial properties. Several potential applications of this fiber are also mentioned, such as the use of this fiber to fabricate rope, place mats, paper cardboard, string thread, tea bags, high-quality textile materials, absorbent, polymer/fiber composites, etc.",book:{id:"7544",slug:"banana-nutrition-function-and-processing-kinetics",title:"Banana Nutrition",fullTitle:"Banana Nutrition - Function and Processing Kinetics"},signatures:"Asmanto Subagyo and Achmad Chafidz",authors:[{id:"257742",title:"M.Sc.",name:"Achmad",middleName:null,surname:"Chafidz",slug:"achmad-chafidz",fullName:"Achmad Chafidz"},{id:"268400",title:"Mr.",name:"Asmanto",middleName:null,surname:"Subagyo",slug:"asmanto-subagyo",fullName:"Asmanto Subagyo"}]},{id:"40180",title:"Plant Tissue Culture: Current Status and Opportunities",slug:"plant-tissue-culture-current-status-and-opportunities",totalDownloads:66452,totalCrossrefCites:43,totalDimensionsCites:89,abstract:null,book:{id:"3568",slug:"recent-advances-in-plant-in-vitro-culture",title:"Recent Advances in Plant in vitro Culture",fullTitle:"Recent Advances in Plant in vitro Culture"},signatures:"Altaf Hussain, Iqbal Ahmed Qarshi, Hummera Nazir and Ikram Ullah",authors:[{id:"147617",title:"Dr.",name:"Altaf",middleName:null,surname:"Hussain",slug:"altaf-hussain",fullName:"Altaf Hussain"}]},{id:"66996",title:"Ethiopian Common Medicinal Plants: Their Parts and Uses in Traditional Medicine - Ecology and Quality Control",slug:"ethiopian-common-medicinal-plants-their-parts-and-uses-in-traditional-medicine-ecology-and-quality-c",totalDownloads:4059,totalCrossrefCites:6,totalDimensionsCites:10,abstract:"The main purpose of this review is to document medicinal plants used for traditional treatments with their parts, use, ecology, and quality control. Accordingly, 80 medicinal plant species were reviewed; leaves and roots are the main parts of the plants used for preparation of traditional medicines. The local practitioners provided various traditional medications to their patients’ diseases such as stomachaches, asthma, dysentery, malaria, evil eyes, cancer, skin diseases, and headaches. The uses of medicinal plants for human and animal treatments are practiced from time immemorial. Stream/riverbanks, cultivated lands, disturbed sites, bushlands, forested areas and their margins, woodlands, grasslands, and home gardens are major habitats of medicinal plants. Generally, medicinal plants used for traditional medicine play a significant role in the healthcare of the majority of the people in Ethiopia. The major threats to medicinal plants are habitat destruction, urbanization, agricultural expansion, investment, road construction, and deforestation. Because of these, medicinal plants are being declined and lost with their habitats. Community- and research-based conservation mechanisms could be an appropriate approach for mitigating the problems pertinent to the loss of medicinal plants and their habitats and for documenting medicinal plants. Chromatography; electrophoretic, macroscopic, and microscopic techniques; and pharmaceutical practice are mainly used for quality control of herbal medicines.",book:{id:"8502",slug:"plant-science-structure-anatomy-and-physiology-in-plants-cultured-in-vivo-and-in-vitro",title:"Plant Science",fullTitle:"Plant Science - Structure, Anatomy and Physiology in Plants Cultured in Vivo and in Vitro"},signatures:"Admasu Moges and Yohannes Moges",authors:[{id:"249746",title:"Ph.D.",name:"Admasu",middleName:null,surname:"Moges",slug:"admasu-moges",fullName:"Admasu Moges"},{id:"297761",title:"MSc.",name:"Yohannes",middleName:null,surname:"Moges",slug:"yohannes-moges",fullName:"Yohannes Moges"}]},{id:"70658",title:"Factors Affecting Yield of Crops",slug:"factors-affecting-yield-of-crops",totalDownloads:4044,totalCrossrefCites:25,totalDimensionsCites:40,abstract:"A good understanding of dynamics involved in food production is critical for the improvement of food security. It has been demonstrated that an increase in crop yields significantly reduces poverty. Yield, the mass of harvest crop product in a specific area, is influenced by several factors. These factors are grouped in three basic categories known as technological (agricultural practices, managerial decision, etc.), biological (diseases, insects, pests, weeds) and environmental (climatic condition, soil fertility, topography, water quality, etc.). These factors account for yield differences from one region to another worldwide. The current chapter will discuss each of these three basic factors as well as providing some recommendations for overcoming them. In addition, it will provide the importance of climate-smart agriculture in the increase of crop yields while facilitating the achievement of crop production in safe environment. This goes in line with the second goal of 2030 Agenda for Sustainable Development of United Nations in transforming our world formulated as end hunger, achieve food security, improve nutrition and promote sustainable agriculture.",book:{id:"8153",slug:"agronomy-climate-change-food-security",title:"Agronomy",fullTitle:"Agronomy - Climate Change & Food Security"},signatures:"Tandzi Ngoune Liliane and Mutengwa Shelton Charles",authors:[{id:"313819",title:"Dr.",name:"Liliane",middleName:null,surname:"Tandzi",slug:"liliane-tandzi",fullName:"Liliane Tandzi"},{id:"314316",title:"Prof.",name:"Charles Shelton",middleName:null,surname:"Mutengwa",slug:"charles-shelton-mutengwa",fullName:"Charles Shelton Mutengwa"}]},{id:"59402",title:"Robotic Harvesting of Fruiting Vegetables: A Simulation Approach in V-REP, ROS and MATLAB",slug:"robotic-harvesting-of-fruiting-vegetables-a-simulation-approach-in-v-rep-ros-and-matlab",totalDownloads:2797,totalCrossrefCites:7,totalDimensionsCites:8,abstract:"In modern agriculture, there is a high demand to move from tedious manual harvesting to a continuously automated operation. This chapter reports on designing a simulation and control platform in V-REP, ROS, and MATLAB for experimenting with sensors and manipulators in robotic harvesting of sweet pepper. The objective was to provide a completely simulated environment for improvement of visual servoing task through easy testing and debugging of control algorithms with zero damage risk to the real robot and to the actual equipment. A simulated workspace, including an exact replica of different robot manipulators, sensing mechanisms, and sweet pepper plant, and fruit system was created in V-REP. Image moment method visual servoing with eye-in-hand configuration was implemented in MATLAB, and was tested on four robotic platforms including Fanuc LR Mate 200iD, NOVABOT, multiple linear actuators, and multiple SCARA arms. Data from simulation experiments were used as inputs of the control algorithm in MATLAB, whose outputs were sent back to the simulated workspace and to the actual robots. ROS was used for exchanging data between the simulated environment and the real workspace via its publish-and-subscribe architecture. Results provided a framework for experimenting with different sensing and acting scenarios, and verified the performance functionality of the simulator.",book:{id:"6265",slug:"automation-in-agriculture-securing-food-supplies-for-future-generations",title:"Automation in Agriculture",fullTitle:"Automation in Agriculture - Securing Food Supplies for Future Generations"},signatures:"Redmond R. Shamshiri, Ibrahim A. Hameed, Manoj Karkee and\nCornelia Weltzien",authors:[{id:"182449",title:"Prof.",name:"Ibrahim",middleName:"A.",surname:"Hameed",slug:"ibrahim-hameed",fullName:"Ibrahim Hameed"},{id:"203413",title:"Dr.",name:"Redmond R.",middleName:null,surname:"Shamshiri",slug:"redmond-r.-shamshiri",fullName:"Redmond R. Shamshiri"},{id:"241193",title:"Dr.",name:"Manoj",middleName:null,surname:"Karkee",slug:"manoj-karkee",fullName:"Manoj Karkee"},{id:"241194",title:"Dr.",name:"Cornelia",middleName:null,surname:"Weltzien",slug:"cornelia-weltzien",fullName:"Cornelia Weltzien"}]}],onlineFirstChaptersFilter:{topicId:"5",limit:6,offset:0},onlineFirstChaptersCollection:[{id:"82508",title:"Introductory Chapter: Global Cotton Research Development Trends for the Past Five Years - Key Directions",slug:"introductory-chapter-global-cotton-research-development-trends-for-the-past-five-years-key-direction",totalDownloads:0,totalDimensionsCites:0,doi:"10.5772/intechopen.105748",abstract:null,book:{id:"11362",title:"Cotton",coverURL:"https://cdn.intechopen.com/books/images_new/11362.jpg"},signatures:"Ibrokhim Y. Abdurakhmonov"},{id:"82512",title:"Antimicrobial Residues in Meat and Meat Products",slug:"antimicrobial-residues-in-meat-and-meat-products",totalDownloads:0,totalDimensionsCites:null,doi:"10.5772/intechopen.105784",abstract:"The presence of antimicrobial residues (AMRs) in meat is considered a serious threat to public health in the twenty-first century. This work aims at addressing the problem of AMRs in meat regarding their sources, negative effects, detection tests, and prevention and control practices. The health risks associated with such residues include direct toxicity, drug allergy, hypersensitive reactions, and the development of antibiotic-resistant bacteria. Moreover, disturbance of gut microbiota and bone marrow disorders are also direct consequences of continuous exposure to small quantities of antimicrobial residues (AMRs). Due to long-term exposure to antibiotic residues during gestation, various congenital anomalies were also seen in newborn children. Carcinogenic impacts and mutagenic effects are other negative impacts of antibiotic residues on the food. Different practices are known to introduce AMRs into meat and meat products, such as misuse of chemotherapeutic medications, violating withdrawal periods, even with the proper administration of anti-infective agents, and usage of antibiotics as growth promoters and feed additives. The prevention of this problem requires multi-sector cooperation to restrict the improper use of antimicrobial drugs, standardize the rationale usage, and development of alternative chemicals or biologics for the purposes of preservation of meat products and as growth promoters for food-producing animals.",book:{id:"11638",title:"Meat Science and Nutrition - Recent Advances and Innovative Processing Technologies",coverURL:"https://cdn.intechopen.com/books/images_new/11638.jpg"},signatures:"Dhary Alewy Almashhadany, Hero I. Mohammed, Thaera Abdulwahid M. Muslat, Rzgar F. Rashid, Rawaz R. Hassan and Abdullah O. Hassan"},{id:"81769",title:"Biological Control of Agricultural Insect Pests",slug:"biological-control-of-agricultural-insect-pests",totalDownloads:2,totalDimensionsCites:0,doi:"10.5772/intechopen.104464",abstract:"Pests are highly responsible for heavy crop losses and reduced food supplies, poorer quality of agricultural products, economic hardship for growers and processor. Generally, chemical control methods are practiced for their control which is neither always economical nor effective and may have associated unwanted health, safety and environmental risks. However, to meet the challenge of feeding to the ever increasing human population, an efficient, economical and environment friendly disease control methods are requisites. In this regard, biological control may be an effective means of reducing or mitigating the pests and pest effects through the use of natural enemies. Biological control is an environmentally sound which involves the use of beneficial microorganism to control plant pathogens and diseases they cause. Therefore, in this chapter we will provide a comprehensive account of this environmental friendly approach for effectively management of plant diseases. This chapter will also accentuate the development of biological control agents for practical applications and the underlying mechanism. The contents in the chapter will be beneficial and advantageous to all those working in academia or industry related to crop protection.",book:{id:"11015",title:"Insecticides",coverURL:"https://cdn.intechopen.com/books/images_new/11015.jpg"},signatures:"Mrinalini Kumari, Atul Srivastava, Shyam Babu Sah and Subhashini Sini"},{id:"82474",title:"Vitamin D Deficiency in Childhood Obesity: Behavioral Factors or Altered Metabolism?",slug:"vitamin-d-deficiency-in-childhood-obesity-behavioral-factors-or-altered-metabolism",totalDownloads:3,totalDimensionsCites:0,doi:"10.5772/intechopen.105819",abstract:"Obesity childhood is related to vitamin D deficiency, but the mechanisms for this association still remain questionable. We hypothesized that behavioral factors would be decisive in reducing the body content of vitamin D in patients with obesity. A cross-sectional clinical and analytical study (calcium, phosphorus, calcidiol, and parathyroid hormone) was carried out in a group of 377 patients with obesity (BMI-DS >2.0), 348 patients with severe obesity (BMI-DS >3.0), and 411 healthy children. The place of residence was categorized as urban or rural. Vitamin D status was defined according to the US Endocrine Society criteria. The prevalence of vitamin D deficiency was significantly higher (p < 0.001) in severe obesity (48.6%) and obesity groups (36.1%) than in the control group (12.5%). Vitamin D deficiency was more frequent in severe obesity and obesity groups living in urban areas than in those living in rural areas (not in the control group). The patients with obesity living in urban residence did not present significant seasonal variations in vitamin D deficiency throughout the year in contrast to those patients with obesity living in rural residence. These findings suggest that the most probable mechanism for vitamin D deficiency in children and adolescents with obesity, rather than altered metabolic, is the behavioral factors (sedentary lifestyle and lack of adequate sunlight exposure).",book:{id:"11639",title:"Vitamin D Deficiency - New Insights",coverURL:"https://cdn.intechopen.com/books/images_new/11639.jpg"},signatures:"Teodoro Durá-Travé and Fidel Gallinas-Victoriano"},{id:"82475",title:"Pharmacological Efficacy and Mechanism of Vitamin D in the Treatment of “Kidney-Brain” Disorders",slug:"pharmacological-efficacy-and-mechanism-of-vitamin-d-in-the-treatment-of-kidney-brain-disorders",totalDownloads:2,totalDimensionsCites:0,doi:"10.5772/intechopen.105820",abstract:"Accumulating evidences have shown that serum 25-hydroxyvitamin D concentrations were inversely correlated with the incidence or severity of coronavirus disease 2019 (COVID-19), caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), and that vitamin D deficiency might be associated with an increased susceptibility to many of the complications accompanied by COVID-19, such as disorders in kidney and brain. Our previous experimental studies demonstrated that vitamin D and its analogs could protect from kidney diseases, neuroinflammation, and musculoskeletal disorders such as osteoporosis and muscle atrophy, through the suppressive effects on overactivation of the renin-angiotensin system (RAS) in tissues. Moreover, we published a review describing the therapeutic effects of traditional Chinese medicine (TCM) for organ injuries associated with COVID-19 by interfering with RAS. In the TCM principle “Kidney dredges brain,” this chapter will emphasize the potential preventive and therapeutic effects of vitamin D on both renal injuries and central nervous system disorders in COVID-19 patients and further elucidate the pharmacological effects with underlying mechanisms of vitamin D in “Kidney-Brain” disorders.",book:{id:"11639",title:"Vitamin D Deficiency - New Insights",coverURL:"https://cdn.intechopen.com/books/images_new/11639.jpg"},signatures:"Jia-Li Zhang, Yong-Jun Wang and Yan Zhang"},{id:"82217",title:"Sustainable Management Plans in Fisheries and Genetic Tools: An Overview of the Challenge in Invertebrates’ Fisheries at the Central Area of the Southern Bay of Biscay, Spain",slug:"sustainable-management-plans-in-fisheries-and-genetic-tools-an-overview-of-the-challenge-in-inverteb",totalDownloads:4,totalDimensionsCites:0,doi:"10.5772/intechopen.105353",abstract:"The fishing and aquaculture sectors are an important source of development around the globe. In Asturias (Spain), the diversity and richness of the fishing grounds of the Cantabrian Sea favored the historical settlement of a large number of communities closely linked to the marine environment and fishing resources, forming an integral part of the region’s cultural and natural heritage. However, aquatic ecosystems are facing, nowadays, important threats from anthropogenic activities. To address these problems and avoid their impact on fishing activities, it is essential to know the ecological and genetic status of the species. Despite this, the application of genetic tools is still incipient in many species of commercial interest; however, its use can help to generate data that allow better regulation and fisheries planning. Here, the use of genetic markers and educational strategies in the management of some shellfish species of great commercial and cultural value in Asturias are reviewed. Moving toward sustainable fisheries management is a priority that can only be achieved through R + D + i, educational strategies, and the development and implementation of a regional strategy oriented toward the sustainable management and exploitation.",book:{id:"10748",title:"Fishery",coverURL:"https://cdn.intechopen.com/books/images_new/10748.jpg"},signatures:"Marina Parrondo, Lucía García-Florez, Eduardo Dopico and Yaisel J. Borrell"}],onlineFirstChaptersTotal:354},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:89,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:104,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:32,numberOfPublishedChapters:318,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:12,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:11,numberOfPublishedChapters:141,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:8,numberOfPublishedChapters:129,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:113,numberOfOpenTopics:3,numberOfUpcomingTopics:1,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:106,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:5,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:0,numberOfPublishedChapters:15,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:null,doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"14",title:"Artificial Intelligence",doi:"10.5772/intechopen.79920",issn:"2633-1403",scope:"Artificial Intelligence (AI) is a rapidly developing multidisciplinary research area that aims to solve increasingly complex problems. In today's highly integrated world, AI promises to become a robust and powerful means for obtaining solutions to previously unsolvable problems. This Series is intended for researchers and students alike interested in this fascinating field and its many applications.",coverUrl:"https://cdn.intechopen.com/series/covers/14.jpg",latestPublicationDate:"June 11th, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:9,editor:{id:"218714",title:"Prof.",name:"Andries",middleName:null,surname:"Engelbrecht",slug:"andries-engelbrecht",fullName:"Andries Engelbrecht",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRNR8QAO/Profile_Picture_1622640468300",biography:"Andries Engelbrecht received the Masters and PhD degrees in Computer Science from the University of Stellenbosch, South Africa, in 1994 and 1999 respectively. He is currently appointed as the Voigt Chair in Data Science in the Department of Industrial Engineering, with a joint appointment as Professor in the Computer Science Division, Stellenbosch University. Prior to his appointment at Stellenbosch University, he has been at the University of Pretoria, Department of Computer Science (1998-2018), where he was appointed as South Africa Research Chair in Artifical Intelligence (2007-2018), the head of the Department of Computer Science (2008-2017), and Director of the Institute for Big Data and Data Science (2017-2018). In addition to a number of research articles, he has written two books, Computational Intelligence: An Introduction and Fundamentals of Computational Swarm Intelligence.",institutionString:null,institution:{name:"Stellenbosch University",institutionURL:null,country:{name:"South Africa"}}},editorTwo:null,editorThree:null},subseries:{paginationCount:6,paginationItems:[{id:"22",title:"Applied Intelligence",coverUrl:"https://cdn.intechopen.com/series_topics/covers/22.jpg",isOpenForSubmission:!0,editor:{id:"27170",title:"Prof.",name:"Carlos",middleName:"M.",surname:"Travieso-Gonzalez",slug:"carlos-travieso-gonzalez",fullName:"Carlos Travieso-Gonzalez",profilePictureURL:"https://mts.intechopen.com/storage/users/27170/images/system/27170.jpeg",biography:"Carlos M. Travieso-González received his MSc degree in Telecommunication Engineering at Polytechnic University of Catalonia (UPC), Spain in 1997, and his Ph.D. degree in 2002 at the University of Las Palmas de Gran Canaria (ULPGC-Spain). He is a full professor of signal processing and pattern recognition and is head of the Signals and Communications Department at ULPGC, teaching from 2001 on subjects on signal processing and learning theory. His research lines are biometrics, biomedical signals and images, data mining, classification system, signal and image processing, machine learning, and environmental intelligence. He has researched in 52 international and Spanish research projects, some of them as head researcher. He is co-author of 4 books, co-editor of 27 proceedings books, guest editor for 8 JCR-ISI international journals, and up to 24 book chapters. He has over 450 papers published in international journals and conferences (81 of them indexed on JCR – ISI - Web of Science). He has published seven patents in the Spanish Patent and Trademark Office. He has been a supervisor on 8 Ph.D. theses (11 more are under supervision), and 130 master theses. He is the founder of The IEEE IWOBI conference series and the president of its Steering Committee, as well as the founder of both the InnoEducaTIC and APPIS conference series. He is an evaluator of project proposals for the European Union (H2020), Medical Research Council (MRC, UK), Spanish Government (ANECA, Spain), Research National Agency (ANR, France), DAAD (Germany), Argentinian Government, and the Colombian Institutions. He has been a reviewer in different indexed international journals (<70) and conferences (<250) since 2001. He has been a member of the IASTED Technical Committee on Image Processing from 2007 and a member of the IASTED Technical Committee on Artificial Intelligence and Expert Systems from 2011. \n\nHe has held the general chair position for the following: ACM-APPIS (2020, 2021), IEEE-IWOBI (2019, 2020 and 2020), A PPIS (2018, 2019), IEEE-IWOBI (2014, 2015, 2017, 2018), InnoEducaTIC (2014, 2017), IEEE-INES (2013), NoLISP (2011), JRBP (2012), and IEEE-ICCST (2005)\n\nHe is an associate editor of the Computational Intelligence and Neuroscience Journal (Hindawi – Q2 JCR-ISI). He was vice dean from 2004 to 2010 in the Higher Technical School of Telecommunication Engineers at ULPGC and the vice dean of Graduate and Postgraduate Studies from March 2013 to November 2017. He won the “Catedra Telefonica” Awards in Modality of Knowledge Transfer, 2017, 2018, and 2019 editions, and awards in Modality of COVID Research in 2020.\n\nPublic References:\nResearcher ID http://www.researcherid.com/rid/N-5967-2014\nORCID https://orcid.org/0000-0002-4621-2768 \nScopus Author ID https://www.scopus.com/authid/detail.uri?authorId=6602376272\nScholar Google https://scholar.google.es/citations?user=G1ks9nIAAAAJ&hl=en \nResearchGate https://www.researchgate.net/profile/Carlos_Travieso",institutionString:null,institution:{name:"University of Las Palmas de Gran Canaria",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null},{id:"23",title:"Computational Neuroscience",coverUrl:"https://cdn.intechopen.com/series_topics/covers/23.jpg",isOpenForSubmission:!0,editor:{id:"14004",title:"Dr.",name:"Magnus",middleName:null,surname:"Johnsson",slug:"magnus-johnsson",fullName:"Magnus Johnsson",profilePictureURL:"https://mts.intechopen.com/storage/users/14004/images/system/14004.png",biography:"Dr Magnus Johnsson is a cross-disciplinary scientist, lecturer, scientific editor and AI/machine learning consultant from Sweden. \n\nHe is currently at Malmö University in Sweden, but also held positions at Lund University in Sweden and at Moscow Engineering Physics Institute. \nHe holds editorial positions at several international scientific journals and has served as a scientific editor for books and special journal issues. \nHis research interests are wide and include, but are not limited to, autonomous systems, computer modeling, artificial neural networks, artificial intelligence, cognitive neuroscience, cognitive robotics, cognitive architectures, cognitive aids and the philosophy of mind. \n\nDr. Johnsson has experience from working in the industry and he has a keen interest in the application of neural networks and artificial intelligence to fields like industry, finance, and medicine. \n\nWeb page: www.magnusjohnsson.se",institutionString:null,institution:{name:"Malmö University",institutionURL:null,country:{name:"Sweden"}}},editorTwo:null,editorThree:null},{id:"24",title:"Computer Vision",coverUrl:"https://cdn.intechopen.com/series_topics/covers/24.jpg",isOpenForSubmission:!0,editor:{id:"294154",title:"Prof.",name:"George",middleName:null,surname:"Papakostas",slug:"george-papakostas",fullName:"George Papakostas",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002hYaGbQAK/Profile_Picture_1624519712088",biography:"George A. Papakostas has received a diploma in Electrical and Computer Engineering in 1999 and the M.Sc. and Ph.D. degrees in Electrical and Computer Engineering in 2002 and 2007, respectively, from the Democritus University of Thrace (DUTH), Greece. Dr. Papakostas serves as a Tenured Full Professor at the Department of Computer Science, International Hellenic University, Greece. Dr. Papakostas has 10 years of experience in large-scale systems design as a senior software engineer and technical manager, and 20 years of research experience in the field of Artificial Intelligence. Currently, he is the Head of the “Visual Computing” division of HUman-MAchines INteraction Laboratory (HUMAIN-Lab) and the Director of the MPhil program “Advanced Technologies in Informatics and Computers” hosted by the Department of Computer Science, International Hellenic University. He has (co)authored more than 150 publications in indexed journals, international conferences and book chapters, 1 book (in Greek), 3 edited books, and 5 journal special issues. His publications have more than 2100 citations with h-index 27 (GoogleScholar). His research interests include computer/machine vision, machine learning, pattern recognition, computational intelligence. \nDr. Papakostas served as a reviewer in numerous journals, as a program\ncommittee member in international conferences and he is a member of the IAENG, MIR Labs, EUCogIII, INSTICC and the Technical Chamber of Greece (TEE).",institutionString:null,institution:{name:"International Hellenic University",institutionURL:null,country:{name:"Greece"}}},editorTwo:null,editorThree:null},{id:"25",title:"Evolutionary Computation",coverUrl:"https://cdn.intechopen.com/series_topics/covers/25.jpg",isOpenForSubmission:!0,editor:{id:"136112",title:"Dr.",name:"Sebastian",middleName:null,surname:"Ventura Soto",slug:"sebastian-ventura-soto",fullName:"Sebastian Ventura Soto",profilePictureURL:"https://mts.intechopen.com/storage/users/136112/images/system/136112.png",biography:"Sebastian Ventura is a Spanish researcher, a full professor with the Department of Computer Science and Numerical Analysis, University of Córdoba. 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In the last five years, he has published more than 60 papers in international journals indexed in the JCR (around 70% of them belonging to first quartile journals) and he has edited some Springer books “Supervised Descriptive Pattern Mining” (2018), “Multiple Instance Learning - Foundations and Algorithms” (2016), and “Pattern Mining with Evolutionary Algorithms” (2016). He has also been involved in more than 20 research projects supported by the Spanish and Andalusian governments and the European Union. He currently belongs to the editorial board of PeerJ Computer Science, Information Fusion and Engineering Applications of Artificial Intelligence journals, being also associate editor of Applied Computational Intelligence and Soft Computing and IEEE Transactions on Cybernetics. Finally, he is editor-in-chief of Progress in Artificial Intelligence. He is a Senior Member of the IEEE Computer, the IEEE Computational Intelligence, and the IEEE Systems, Man, and Cybernetics Societies, and the Association of Computing Machinery (ACM). Finally, his main research interests include data science, computational intelligence, and their applications.",institutionString:null,institution:{name:"University of Córdoba",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null},{id:"26",title:"Machine Learning and Data Mining",coverUrl:"https://cdn.intechopen.com/series_topics/covers/26.jpg",isOpenForSubmission:!0,editor:{id:"24555",title:"Dr.",name:"Marco Antonio",middleName:null,surname:"Aceves Fernandez",slug:"marco-antonio-aceves-fernandez",fullName:"Marco Antonio Aceves Fernandez",profilePictureURL:"https://mts.intechopen.com/storage/users/24555/images/system/24555.jpg",biography:"Dr. Marco Antonio Aceves Fernandez obtained his B.Sc. (Eng.) in Telematics from the Universidad de Colima, Mexico. 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settings. She is now a lecturer at the University of Witwatersrand, South Africa, and a principal researcher at the Health Economics and Epidemiology Research Office (HE2RO), South Africa. Dr. Moolla holds a Ph.D. in Psychology with her research being focused on mental health and resilience. In her professional work capacity, her research has further expanded into the fields of early childhood development, mental health, the HIV and TB care cascades, as well as COVID. She is also a UNESCO-trained International Bioethics Facilitator.",institutionString:"University of the Witwatersrand",institution:{name:"University of the Witwatersrand",country:{name:"South Africa"}}},{id:"419588",title:"Ph.D.",name:"Sergio",middleName:"Alexandre",surname:"Gehrke",slug:"sergio-gehrke",fullName:"Sergio Gehrke",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000038WgMKQA0/Profile_Picture_2022-06-02T11:44:20.jpg",biography:"Dr. Sergio Alexandre Gehrke is a doctorate holder in two fields. The first is a Ph.D. in Cellular and Molecular Biology from the Pontificia Catholic University, Porto Alegre, Brazil, in 2010 and the other is an International Ph.D. in Bioengineering from the Universidad Miguel Hernandez, Elche/Alicante, Spain, obtained in 2020. In 2018, he completed a postdoctoral fellowship in Materials Engineering in the NUCLEMAT of the Pontificia Catholic University, Porto Alegre, Brazil. He is currently the Director of the Postgraduate Program in Implantology of the Bioface/UCAM/PgO (Montevideo, Uruguay), Director of the Cathedra of Biotechnology of the Catholic University of Murcia (Murcia, Spain), an Extraordinary Full Professor of the Catholic University of Murcia (Murcia, Spain) as well as the Director of the private center of research Biotecnos – Technology and Science (Montevideo, Uruguay). Applied biomaterials, cellular and molecular biology, and dental implants are among his research interests. He has published several original papers in renowned journals. In addition, he is also a Collaborating Professor in several Postgraduate programs at different universities all over the world.",institutionString:null,institution:{name:"Universidad Católica San Antonio de Murcia",country:{name:"Spain"}}},{id:"342152",title:"Dr.",name:"Santo",middleName:null,surname:"Grace Umesh",slug:"santo-grace-umesh",fullName:"Santo Grace Umesh",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/342152/images/16311_n.jpg",biography:null,institutionString:null,institution:{name:"SRM Dental College",country:{name:"India"}}},{id:"333647",title:"Dr.",name:"Shreya",middleName:null,surname:"Kishore",slug:"shreya-kishore",fullName:"Shreya Kishore",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/333647/images/14701_n.jpg",biography:"Dr. Shreya Kishore completed her Bachelor in Dental Surgery in Chettinad Dental College and Research Institute, Chennai, and her Master of Dental Surgery (Orthodontics) in Saveetha Dental College, Chennai. She is also Invisalign certified. She’s working as a Senior Lecturer in the Department of Orthodontics, SRM Dental College since November 2019. She is actively involved in teaching orthodontics to the undergraduates and the postgraduates. Her clinical research topics include new orthodontic brackets, fixed appliances and TADs. She’s published 4 articles in well renowned indexed journals and has a published patency of her own. Her private practice is currently limited to orthodontics and works as a consultant in various clinics.",institutionString:null,institution:{name:"SRM Dental College",country:{name:"India"}}},{id:"323731",title:"Prof.",name:"Deepak M.",middleName:"Macchindra",surname:"Vikhe",slug:"deepak-m.-vikhe",fullName:"Deepak M. Vikhe",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/323731/images/13613_n.jpg",biography:"Dr Deepak M.Vikhe .\n\n\t\n\tDr Deepak M.Vikhe , completed his Masters & PhD in Prosthodontics from Rural Dental College, Loni securing third rank in the Pravara Institute of Medical Sciences Deemed University. He was awarded Dr.G.C.DAS Memorial Award for Research on Implants at 39th IPS conference Dubai (U A E).He has two patents under his name. He has received Dr.Saraswati medal award for best research for implant study in 2017.He has received Fully funded scholarship to Spain ,university of Santiago de Compostela. He has completed fellowship in Implantlogy from Noble Biocare. \nHe has attended various conferences and CDE programmes and has national publications to his credit. His field of interest is in Implant supported prosthesis. Presently he is working as a associate professor in the Dept of Prosthodontics, Rural Dental College, Loni and maintains a successful private practice specialising in Implantology at Rahata.\n\nEmail: drdeepak_mvikhe@yahoo.com..................",institutionString:null,institution:{name:"Pravara Institute of Medical Sciences",country:{name:"India"}}},{id:"204110",title:"Dr.",name:"Ahmed A.",middleName:null,surname:"Madfa",slug:"ahmed-a.-madfa",fullName:"Ahmed A. Madfa",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/204110/images/system/204110.jpg",biography:"Dr. Madfa is currently Associate Professor of Endodontics at Thamar University and a visiting lecturer at Sana'a University and University of Sciences and Technology. He has more than 6 years of experience in teaching. His research interests include root canal morphology, functionally graded concept, dental biomaterials, epidemiology and dental education, biomimetic restoration, finite element analysis and endodontic regeneration. Dr. Madfa has numerous international publications, full articles, two patents, a book and a book chapter. Furthermore, he won 14 international scientific awards. Furthermore, he is involved in many academic activities ranging from editorial board member, reviewer for many international journals and postgraduate students' supervisor. Besides, I deliver many courses and training workshops at various scientific events. Dr. Madfa also regularly attends international conferences and holds administrative positions (Deputy Dean of the Faculty for Students’ & Academic Affairs and Deputy Head of Research Unit).",institutionString:"Thamar University",institution:null},{id:"210472",title:"Dr.",name:"Nermin",middleName:"Mohammed Ahmed",surname:"Yussif",slug:"nermin-yussif",fullName:"Nermin Yussif",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/210472/images/system/210472.jpg",biography:"Dr. Nermin Mohammed Ahmed Yussif is working at the Faculty of dentistry, University for October university for modern sciences and arts (MSA). Her areas of expertise include: periodontology, dental laserology, oral implantology, periodontal plastic surgeries, oral mesotherapy, nutrition, dental pharmacology. She is an editor and reviewer in numerous international journals.",institutionString:"MSA University",institution:null},{id:"204606",title:"Dr.",name:"Serdar",middleName:null,surname:"Gözler",slug:"serdar-gozler",fullName:"Serdar Gözler",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/204606/images/system/204606.jpeg",biography:"Dr. Serdar Gözler has completed his undergraduate studies at the Marmara University Faculty of Dentistry in 1978, followed by an assistantship in the Prosthesis Department of Dicle University Faculty of Dentistry. Starting his PhD work on non-resilient overdentures with Assoc. Prof. Hüsnü Yavuzyılmaz, he continued his studies with Prof. Dr. Gürbüz Öztürk of Istanbul University Faculty of Dentistry Department of Prosthodontics, this time on Gnatology. He attended training programs on occlusion, neurology, neurophysiology, EMG, radiology and biostatistics. In 1982, he presented his PhD thesis \\Gerber and Lauritzen Occlusion Analysis Techniques: Diagnosis Values,\\ at Istanbul University School of Dentistry, Department of Prosthodontics. As he was also working with Prof. Senih Çalıkkocaoğlu on The Physiology of Chewing at the same time, Gözler has written a chapter in Çalıkkocaoğlu\\'s book \\Complete Prostheses\\ entitled \\The Place of Neuromuscular Mechanism in Prosthetic Dentistry.\\ The book was published five times since by the Istanbul University Publications. Having presented in various conferences about occlusion analysis until 1998, Dr. Gözler has also decided to use the T-Scan II occlusion analysis method. Having been personally trained by Dr. Robert Kerstein on this method, Dr. Gözler has been lecturing on the T-Scan Occlusion Analysis Method in conferences both in Turkey and abroad. Dr. Gözler has various articles and presentations on Digital Occlusion Analysis methods. He is now Head of the TMD Clinic at Prosthodontic Department of Faculty of Dentistry , Istanbul Aydın University , Turkey.",institutionString:"Istanbul Aydin University",institution:{name:"Istanbul Aydın University",country:{name:"Turkey"}}},{id:"240870",title:"Ph.D.",name:"Alaa Eddin Omar",middleName:null,surname:"Al Ostwani",slug:"alaa-eddin-omar-al-ostwani",fullName:"Alaa Eddin Omar Al Ostwani",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/240870/images/system/240870.jpeg",biography:"Dr. Al Ostwani Alaa Eddin Omar received his Master in dentistry from Damascus University in 2010, and his Ph.D. in Pediatric Dentistry from Damascus University in 2014. Dr. Al Ostwani is an assistant professor and faculty member at IUST University since 2014. \nDuring his academic experience, he has received several awards including the scientific research award from the Union of Arab Universities, the Syrian gold medal and the international gold medal for invention and creativity. Dr. Al Ostwani is a Member of the International Association of Dental Traumatology and the Syrian Society for Research and Preventive Dentistry since 2017. He is also a Member of the Reviewer Board of International Journal of Dental Medicine (IJDM), and the Indian Journal of Conservative and Endodontics since 2016.",institutionString:"International University for Science and Technology.",institution:{name:"Islamic University of Science and Technology",country:{name:"India"}}},{id:"42847",title:"Dr.",name:"Belma",middleName:null,surname:"Işik Aslan",slug:"belma-isik-aslan",fullName:"Belma Işik Aslan",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/42847/images/system/42847.jpg",biography:"Dr. Belma IşIk Aslan was born in 1976 in Ankara-TURKEY. After graduating from TED Ankara College in 1994, she attended to Gazi University, Faculty of Dentistry in Ankara. She completed her PhD in orthodontic education at Gazi University between 1999-2005. Dr. Işık Aslan stayed at the Providence Hospital Craniofacial Institude and Reconstructive Surgery in Michigan, USA for three months as an observer. She worked as a specialist doctor at Gazi University, Dentistry Faculty, Department of Orthodontics between 2005-2014. She was appointed as associate professor in January, 2014 and as professor in 2021. Dr. Işık Aslan still works as an instructor at the same faculty. She has published a total of 35 articles, 10 book chapters, 39 conference proceedings both internationally and nationally. Also she was the academic editor of the international book 'Current Advances in Orthodontics'. She is a member of the Turkish Orthodontic Society and Turkish Cleft Lip and Palate Society. She is married and has 2 children. Her knowledge of English is at an advanced level.",institutionString:"Gazi University Dentistry Faculty Department of Orthodontics",institution:null},{id:"178412",title:"Associate Prof.",name:"Guhan",middleName:null,surname:"Dergin",slug:"guhan-dergin",fullName:"Guhan Dergin",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/178412/images/6954_n.jpg",biography:"Assoc. Prof. Dr. Gühan Dergin was born in 1973 in Izmit. He graduated from Marmara University Faculty of Dentistry in 1999. He completed his specialty of OMFS surgery in Marmara University Faculty of Dentistry and obtained his PhD degree in 2006. In 2005, he was invited as a visiting doctor in the Oral and Maxillofacial Surgery Department of the University of North Carolina, USA, where he went on a scholarship. Dr. Dergin still continues his academic career as an associate professor in Marmara University Faculty of Dentistry. He has many articles in international and national scientific journals and chapters in books.",institutionString:null,institution:{name:"Marmara University",country:{name:"Turkey"}}},{id:"178414",title:"Prof.",name:"Yusuf",middleName:null,surname:"Emes",slug:"yusuf-emes",fullName:"Yusuf Emes",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/178414/images/6953_n.jpg",biography:"Born in Istanbul in 1974, Dr. Emes graduated from Istanbul University Faculty of Dentistry in 1997 and completed his PhD degree in Istanbul University faculty of Dentistry Department of Oral and Maxillofacial Surgery in 2005. He has papers published in international and national scientific journals, including research articles on implantology, oroantral fistulas, odontogenic cysts, and temporomandibular disorders. Dr. Emes is currently working as a full-time academic staff in Istanbul University faculty of Dentistry Department of Oral and Maxillofacial Surgery.",institutionString:null,institution:{name:"Istanbul University",country:{name:"Turkey"}}},{id:"192229",title:"Ph.D.",name:"Ana Luiza",middleName:null,surname:"De Carvalho Felippini",slug:"ana-luiza-de-carvalho-felippini",fullName:"Ana Luiza De Carvalho Felippini",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/192229/images/system/192229.jpg",biography:null,institutionString:"University of São Paulo",institution:{name:"University of Sao Paulo",country:{name:"Brazil"}}},{id:"256851",title:"Prof.",name:"Ayşe",middleName:null,surname:"Gülşen",slug:"ayse-gulsen",fullName:"Ayşe Gülşen",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/256851/images/9696_n.jpg",biography:"Dr. Ayşe Gülşen graduated in 1990 from Faculty of Dentistry, University of Ankara and did a postgraduate program at University of Gazi. \nShe worked as an observer and research assistant in Craniofacial Surgery Departments in New York, Providence Hospital in Michigan and Chang Gung Memorial Hospital in Taiwan. \nShe works as Craniofacial Orthodontist in Department of Aesthetic, Plastic and Reconstructive Surgery, Faculty of Medicine, University of Gazi, Ankara Turkey since 2004.",institutionString:"Univeristy of Gazi",institution:null},{id:"255366",title:"Prof.",name:"Tosun",middleName:null,surname:"Tosun",slug:"tosun-tosun",fullName:"Tosun Tosun",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/255366/images/7347_n.jpg",biography:"Graduated at the Faculty of Dentistry, University of Istanbul, Turkey in 1989;\nVisitor Assistant at the University of Padua, Italy and Branemark Osseointegration Center of Treviso, Italy between 1993-94;\nPhD thesis on oral implantology in University of Istanbul and was awarded the academic title “Dr.med.dent.”, 1997;\nHe was awarded the academic title “Doç.Dr.” (Associated Professor) in 2003;\nProficiency in Botulinum Toxin Applications, Reading-UK in 2009;\nMastership, RWTH Certificate in Laser Therapy in Dentistry, AALZ-Aachen University, Germany 2009-11;\nMaster of Science (MSc) in Laser Dentistry, University of Genoa, Italy 2013-14.\n\nDr.Tosun worked as Research Assistant in the Department of Oral Implantology, Faculty of Dentistry, University of Istanbul between 1990-2002. \nHe worked part-time as Consultant surgeon in Harvard Medical International Hospitals and John Hopkins Medicine, Istanbul between years 2007-09.\u2028He was contract Professor in the Department of Surgical and Diagnostic Sciences (DI.S.C.), Medical School, University of Genova, Italy between years 2011-16. \nSince 2015 he is visiting Professor at Medical School, University of Plovdiv, Bulgaria. \nCurrently he is Associated Prof.Dr. at the Dental School, Oral Surgery Dept., Istanbul Aydin University and since 2003 he works in his own private clinic in Istanbul, Turkey.\u2028\nDr.Tosun is reviewer in journal ‘Laser in Medical Sciences’, reviewer in journal ‘Folia Medica\\', a Fellow of the International Team for Implantology, Clinical Lecturer of DGZI German Association of Oral Implantology, Expert Lecturer of Laser&Health Academy, Country Representative of World Federation for Laser Dentistry, member of European Federation of Periodontology, member of Academy of Laser Dentistry. Dr.Tosun presents papers in international and national congresses and has scientific publications in international and national journals. He speaks english, spanish, italian and french.",institutionString:null,institution:{name:"Istanbul Aydın University",country:{name:"Turkey"}}},{id:"171887",title:"Prof.",name:"Zühre",middleName:null,surname:"Akarslan",slug:"zuhre-akarslan",fullName:"Zühre Akarslan",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/171887/images/system/171887.jpg",biography:"Zühre Akarslan was born in 1977 in Cyprus. She graduated from Gazi University Faculty of Dentistry, Ankara, Turkey in 2000. \r\nLater she received her Ph.D. degree from the Oral Diagnosis and Radiology Department; which was recently renamed as Oral and Dentomaxillofacial Radiology, from the same university. \r\nShe is working as a full-time Associate Professor and is a lecturer and an academic researcher. \r\nHer expertise areas are dental caries, cancer, dental fear and anxiety, gag reflex in dentistry, oral medicine, and dentomaxillofacial radiology.",institutionString:"Gazi University",institution:{name:"Gazi University",country:{name:"Turkey"}}},{id:"256417",title:"Associate Prof.",name:"Sanaz",middleName:null,surname:"Sadry",slug:"sanaz-sadry",fullName:"Sanaz Sadry",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/256417/images/8106_n.jpg",biography:null,institutionString:null,institution:null},{id:"272237",title:"Dr.",name:"Pinar",middleName:"Kiymet",surname:"Karataban",slug:"pinar-karataban",fullName:"Pinar Karataban",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/272237/images/8911_n.png",biography:"Assist.Prof.Dr.Pınar Kıymet Karataban, DDS PhD \n\nDr.Pınar Kıymet Karataban was born in Istanbul in 1975. After her graduation from Marmara University Faculty of Dentistry in 1998 she started her PhD in Paediatric Dentistry focused on children with special needs; mainly children with Cerebral Palsy. She finished her pHD thesis entitled \\'Investigation of occlusion via cast analysis and evaluation of dental caries prevalance, periodontal status and muscle dysfunctions in children with cerebral palsy” in 2008. She got her Assist. Proffessor degree in Istanbul Aydın University Paediatric Dentistry Department in 2015-2018. ın 2019 she started her new career in Bahcesehir University, Istanbul as Head of Department of Pediatric Dentistry. In 2020 she was accepted to BAU International University, Batumi as Professor of Pediatric Dentistry. She’s a lecturer in the same university meanwhile working part-time in private practice in Ege Dental Studio (https://www.egedisklinigi.com/) a multidisciplinary dental clinic in Istanbul. Her main interests are paleodontology, ancient and contemporary dentistry, oral microbiology, cerebral palsy and special care dentistry. She has national and international publications, scientific reports and is a member of IAPO (International Association for Paleodontology), IADH (International Association of Disability and Oral Health) and EAPD (European Association of Pediatric Dentistry).",institutionString:null,institution:null},{id:"202198",title:"Dr.",name:"Buket",middleName:null,surname:"Aybar",slug:"buket-aybar",fullName:"Buket Aybar",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/202198/images/6955_n.jpg",biography:"Buket Aybar, DDS, PhD, was born in 1971. She graduated from Istanbul University, Faculty of Dentistry, in 1992 and completed her PhD degree on Oral and Maxillofacial Surgery in Istanbul University in 1997.\nDr. Aybar is currently a full-time professor in Istanbul University, Faculty of Dentistry Department of Oral and Maxillofacial Surgery. She has teaching responsibilities in graduate and postgraduate programs. Her clinical practice includes mainly dentoalveolar surgery.\nHer topics of interest are biomaterials science and cell culture studies. She has many articles in international and national scientific journals and chapters in books; she also has participated in several scientific projects supported by Istanbul University Research fund.",institutionString:null,institution:null},{id:"260116",title:"Dr.",name:"Mehmet",middleName:null,surname:"Yaltirik",slug:"mehmet-yaltirik",fullName:"Mehmet Yaltirik",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/260116/images/7413_n.jpg",biography:"Birth Date 25.09.1965\r\nBirth Place Adana- Turkey\r\nSex Male\r\nMarrial Status Bachelor\r\nDriving License Acquired\r\nMother Tongue Turkish\r\n\r\nAddress:\r\nWork:University of Istanbul,Faculty of Dentistry, Department of Oral Surgery and Oral Medicine 34093 Capa,Istanbul- TURKIYE",institutionString:null,institution:null},{id:"172009",title:"Dr.",name:"Fatma Deniz",middleName:null,surname:"Uzuner",slug:"fatma-deniz-uzuner",fullName:"Fatma Deniz Uzuner",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/172009/images/7122_n.jpg",biography:"Dr. Deniz Uzuner was born in 1969 in Kocaeli-TURKEY. After graduating from TED Ankara College in 1986, she attended the Hacettepe University, Faculty of Dentistry in Ankara. \nIn 1993 she attended the Gazi University, Faculty of Dentistry, Department of Orthodontics for her PhD education. After finishing the PhD education, she worked as orthodontist in Ankara Dental Hospital under the Turkish Government, Ministry of Health and in a special Orthodontic Clinic till 2011. Between 2011 and 2016, Dr. Deniz Uzuner worked as a specialist in the Department of Orthodontics, Faculty of Dentistry, Gazi University in Ankara/Turkey. In 2016, she was appointed associate professor. Dr. Deniz Uzuner has authored 23 Journal Papers, 3 Book Chapters and has had 39 oral/poster presentations. She is a member of the Turkish Orthodontic Society. Her knowledge of English is at an advanced level.",institutionString:null,institution:null},{id:"332914",title:"Dr.",name:"Muhammad Saad",middleName:null,surname:"Shaikh",slug:"muhammad-saad-shaikh",fullName:"Muhammad Saad Shaikh",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"Jinnah Sindh Medical University",country:{name:"Pakistan"}}},{id:"315775",title:"Dr.",name:"Feng",middleName:null,surname:"Luo",slug:"feng-luo",fullName:"Feng Luo",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"Sichuan University",country:{name:"China"}}},{id:"423519",title:"Dr.",name:"Sizakele",middleName:null,surname:"Ngwenya",slug:"sizakele-ngwenya",fullName:"Sizakele Ngwenya",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"University of the Witwatersrand",country:{name:"South Africa"}}},{id:"419270",title:"Dr.",name:"Ann",middleName:null,surname:"Chianchitlert",slug:"ann-chianchitlert",fullName:"Ann Chianchitlert",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"Walailak University",country:{name:"Thailand"}}},{id:"419271",title:"Dr.",name:"Diane",middleName:null,surname:"Selvido",slug:"diane-selvido",fullName:"Diane Selvido",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"Walailak University",country:{name:"Thailand"}}},{id:"419272",title:"Dr.",name:"Irin",middleName:null,surname:"Sirisoontorn",slug:"irin-sirisoontorn",fullName:"Irin Sirisoontorn",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"Walailak University",country:{name:"Thailand"}}},{id:"355660",title:"Dr.",name:"Anitha",middleName:null,surname:"Mani",slug:"anitha-mani",fullName:"Anitha Mani",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"SRM Dental College",country:{name:"India"}}},{id:"355612",title:"Dr.",name:"Janani",middleName:null,surname:"Karthikeyan",slug:"janani-karthikeyan",fullName:"Janani Karthikeyan",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"SRM Dental College",country:{name:"India"}}},{id:"334400",title:"Dr.",name:"Suvetha",middleName:null,surname:"Siva",slug:"suvetha-siva",fullName:"Suvetha Siva",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"SRM Dental College",country:{name:"India"}}}]}},subseries:{item:{id:"38",type:"subseries",title:"Pollution",keywords:"Human activity, Pollutants, Reduced risks, Population growth, Waste disposal, Remediation, Clean environment",scope:"\r\n\tPollution is caused by a wide variety of human activities and occurs in diverse forms, for example biological, chemical, et cetera. In recent years, significant efforts have been made to ensure that the environment is clean, that rigorous rules are implemented, and old laws are updated to reduce the risks towards humans and ecosystems. However, rapid industrialization and the need for more cultivable sources or habitable lands, for an increasing population, as well as fewer alternatives for waste disposal, make the pollution control tasks more challenging. Therefore, this topic will focus on assessing and managing environmental pollution. It will cover various subjects, including risk assessment due to the pollution of ecosystems, transport and fate of pollutants, restoration or remediation of polluted matrices, and efforts towards sustainable solutions to minimize environmental pollution.
",coverUrl:"https://cdn.intechopen.com/series_topics/covers/38.jpg",hasOnlineFirst:!1,hasPublishedBooks:!0,annualVolume:11966,editor:{id:"110740",title:"Dr.",name:"Ismail M.M.",middleName:null,surname:"Rahman",slug:"ismail-m.m.-rahman",fullName:"Ismail M.M. Rahman",profilePictureURL:"https://mts.intechopen.com/storage/users/110740/images/2319_n.jpg",biography:"Ismail Md. Mofizur Rahman (Ismail M. M. Rahman) assumed his current responsibilities as an Associate Professor at the Institute of Environmental Radioactivity, Fukushima University, Japan, in Oct 2015. He also has an honorary appointment to serve as a Collaborative Professor at Kanazawa University, Japan, from Mar 2015 to the present. \nFormerly, Dr. Rahman was a faculty member of the University of Chittagong, Bangladesh, affiliated with the Department of Chemistry (Oct 2002 to Mar 2012) and the Department of Applied Chemistry and Chemical Engineering (Mar 2012 to Sep 2015). Dr. Rahman was also adjunctly attached with Kanazawa University, Japan (Visiting Research Professor, Dec 2014 to Mar 2015; JSPS Postdoctoral Research Fellow, Apr 2012 to Mar 2014), and Tokyo Institute of Technology, Japan (TokyoTech-UNESCO Research Fellow, Oct 2004–Sep 2005). \nHe received his Ph.D. degree in Environmental Analytical Chemistry from Kanazawa University, Japan (2011). He also achieved a Diploma in Environment from the Tokyo Institute of Technology, Japan (2005). Besides, he has an M.Sc. degree in Applied Chemistry and a B.Sc. degree in Chemistry, all from the University of Chittagong, Bangladesh. \nDr. Rahman’s research interest includes the study of the fate and behavior of environmental pollutants in the biosphere; design of low energy and low burden environmental improvement (remediation) technology; implementation of sustainable waste management practices for treatment, handling, reuse, and ultimate residual disposition of solid wastes; nature and type of interactions in organic liquid mixtures for process engineering design applications.",institutionString:null,institution:{name:"Fukushima University",institutionURL:null,country:{name:"Japan"}}},editorTwo:{id:"201020",title:"Dr.",name:"Zinnat Ara",middleName:null,surname:"Begum",slug:"zinnat-ara-begum",fullName:"Zinnat Ara Begum",profilePictureURL:"https://mts.intechopen.com/storage/users/201020/images/system/201020.jpeg",biography:"Zinnat A. Begum received her Ph.D. in Environmental Analytical Chemistry from Kanazawa University in 2012. She achieved her Master of Science (M.Sc.) degree with a major in Applied Chemistry and a Bachelor of Science (B.Sc.) in Chemistry, all from the University of Chittagong, Bangladesh. Her work affiliations include Fukushima University, Japan (Visiting Research Fellow, Institute of Environmental Radioactivity: Mar 2016 to present), Southern University Bangladesh (Assistant Professor, Department of Civil Engineering: Jan 2015 to present), and Kanazawa University, Japan (Postdoctoral Fellow, Institute of Science and Engineering: Oct 2012 to Mar 2014; Research fellow, Venture Business Laboratory, Advanced Science and Social Co-Creation Promotion Organization: Apr 2018 to Mar 2021). The research focus of Dr. Zinnat includes the effect of the relative stability of metal-chelator complexes in the environmental remediation process designs and the development of eco-friendly soil washing techniques using biodegradable chelators.",institutionString:null,institution:{name:"Fukushima University",institutionURL:null,country:{name:"Japan"}}},editorThree:null,series:{id:"25",title:"Environmental Sciences",doi:"10.5772/intechopen.100362",issn:"2754-6713"},editorialBoard:[{id:"252368",title:"Dr.",name:"Meng-Chuan",middleName:null,surname:"Ong",slug:"meng-chuan-ong",fullName:"Meng-Chuan Ong",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRVotQAG/Profile_Picture_2022-05-20T12:04:28.jpg",institutionString:null,institution:{name:"Universiti Malaysia Terengganu",institutionURL:null,country:{name:"Malaysia"}}},{id:"63465",title:"Prof.",name:"Mohamed Nageeb",middleName:null,surname:"Rashed",slug:"mohamed-nageeb-rashed",fullName:"Mohamed Nageeb Rashed",profilePictureURL:"https://mts.intechopen.com/storage/users/63465/images/system/63465.gif",institutionString:null,institution:{name:"Aswan University",institutionURL:null,country:{name:"Egypt"}}},{id:"187907",title:"Dr.",name:"Olga",middleName:null,surname:"Anne",slug:"olga-anne",fullName:"Olga Anne",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bSBE5QAO/Profile_Picture_2022-04-07T09:42:13.png",institutionString:null,institution:{name:"Klaipeda State University of Applied Sciences",institutionURL:null,country:{name:"Lithuania"}}}]},onlineFirstChapters:{paginationCount:20,paginationItems:[{id:"80964",title:"Upper Airway Expansion in Disabled Children",doi:"10.5772/intechopen.102830",signatures:"David Andrade, Joana Andrade, Maria-João Palha, Cristina Areias, Paula Macedo, Ana Norton, Miguel Palha, Lurdes Morais, Dóris Rocha Ruiz and Sônia Groisman",slug:"upper-airway-expansion-in-disabled-children",totalDownloads:35,totalCrossrefCites:0,totalDimensionsCites:0,authors:null,book:{title:"Oral Health Care - An Important Issue of the Modern Society",coverURL:"https://cdn.intechopen.com/books/images_new/10827.jpg",subseries:{id:"1",title:"Oral Health"}}},{id:"80839",title:"Herbs and Oral Health",doi:"10.5772/intechopen.103715",signatures:"Zuhair S. 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Dr. Şentürk currently works as an professor of Biochemistry in the Department of Basic Pharmacy Sciences, Faculty of Pharmacy, Ağri Ibrahim Cecen University, Turkey. \nDr. Şentürk published over 120 scientific papers, reviews, and book chapters and presented several conferences to scientists. \nHis research interests span enzyme inhibitor or activator, protein expression, purification and characterization, drug design and synthesis, toxicology, and pharmacology. \nHis research work has focused on neurodegenerative diseases and cancer treatment. 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He then worked as an Assistant Professor at the Faculty of Science of the same University until 1984. In 1985, Prof. Iadarola became Associate Professor at the Department of Biology and Biotechnologies of the University of Pavia and retired in October 2017. Since then, he has been working as an Adjunct Professor in the same Department at the University of Pavia. His research activity during the first years was primarily focused on the purification and structural characterization of enzymes from animal and plant sources. During this period, Prof. Iadarola familiarized himself with the conventional techniques used in column chromatography, spectrophotometry, manual Edman degradation, and electrophoresis). Since 1995, he has been working on: i) the determination in biological fluids (serum, urine, bronchoalveolar lavage, sputum) of proteolytic activities involved in the degradation processes of connective tissue matrix, and ii) on the identification of biological markers of lung diseases. In this context, he has developed and validated new methodologies (e.g., Capillary Electrophoresis coupled to Laser-Induced Fluorescence, CE-LIF) whose application enabled him to determine both the amounts of biochemical markers (Desmosines) in urine/serum of patients affected by Chronic Obstructive Pulmonary Disease (COPD) and the activity of proteolytic enzymes (Human Neutrophil Elastase, Cathepsin G, Pseudomonas aeruginosa elastase) in sputa of these patients. More recently, Prof. Iadarola was involved in developing techniques such as two-dimensional electrophoresis coupled to liquid chromatography/mass spectrometry (2DE-LC/MS) for the proteomic analysis of biological fluids aimed at the identification of potential biomarkers of different lung diseases. He is the author of about 150 publications (According to Scopus: H-Index: 23; Total citations: 1568- According to WOS: H-Index: 20; Total Citations: 1296) of peer-reviewed international journals. He is a Consultant Reviewer for several journals, including the Journal of Chromatography A, Journal of Chromatography B, Plos ONE, Proteomes, International Journal of Molecular Science, Biotech, Electrophoresis, and others. 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She gained considerable experience in developing and validating new methodologies whose applications allowed her to determine both the amount of biomarkers (Desmosine and Isodesmosine) in the urine of patients affected by COPD, and the activity of proteolytic enzymes (HNE, Cathepsin G, Pseudomonas aeruginosa elastase) in the sputa of these patients. Simona Viglio was also involved in research dealing with the supplementation of amino acids in patients with brain injury and chronic heart failure. She is presently engaged in the development of 2-DE and LC-MS techniques for the study of proteomics in biological fluids. The aim of this research is the identification of potential biomarkers of lung diseases. She is an author of about 90 publications (According to Scopus: H-Index: 23; According to WOS: H-Index: 20) on peer-reviewed journals, a member of the “Società Italiana di Biochimica e Biologia Molecolare,“ and a Consultant Reviewer for International Journal of Molecular Science, Journal of Chromatography A, COPD, Plos ONE and Nutritional Neuroscience.",institutionString:null,position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"2",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"University of Pavia",institutionURL:null,country:{name:"Italy"}}},editorThree:null,series:{id:"11",title:"Biochemistry"}}},seriesLanding:{item:{id:"11",title:"Biochemistry",doi:"10.5772/intechopen.72877",issn:"2632-0983",scope:"Biochemistry, the study of chemical transformations occurring within living organisms, impacts all areas of life sciences, from molecular crystallography and genetics to ecology, medicine, and population biology. Biochemistry examines macromolecules - proteins, nucleic acids, carbohydrates, and lipids – and their building blocks, structures, functions, and interactions. Much of biochemistry is devoted to enzymes, proteins that catalyze chemical reactions, enzyme structures, mechanisms of action and their roles within cells. Biochemistry also studies small signaling molecules, coenzymes, inhibitors, vitamins, and hormones, which play roles in life processes. Biochemical experimentation, besides coopting classical chemistry methods, e.g., chromatography, adopted new techniques, e.g., X-ray diffraction, electron microscopy, NMR, radioisotopes, and developed sophisticated microbial genetic tools, e.g., auxotroph mutants and their revertants, fermentation, etc. More recently, biochemistry embraced the ‘big data’ omics systems. Initial biochemical studies have been exclusively analytic: dissecting, purifying, and examining individual components of a biological system; in the apt words of Efraim Racker (1913 –1991), “Don’t waste clean thinking on dirty enzymes.” Today, however, biochemistry is becoming more agglomerative and comprehensive, setting out to integrate and describe entirely particular biological systems. The ‘big data’ metabolomics can define the complement of small molecules, e.g., in a soil or biofilm sample; proteomics can distinguish all the comprising proteins, e.g., serum; metagenomics can identify all the genes in a complex environment, e.g., the bovine rumen. This Biochemistry Series will address the current research on biomolecules and the emerging trends with great promise.",coverUrl:"https://cdn.intechopen.com/series/covers/11.jpg",latestPublicationDate:"June 29th, 2022",hasOnlineFirst:!0,numberOfOpenTopics:4,numberOfPublishedChapters:318,numberOfPublishedBooks:32,editor:{id:"31610",title:"Dr.",name:"Miroslav",middleName:null,surname:"Blumenberg",fullName:"Miroslav Blumenberg",profilePictureURL:"https://mts.intechopen.com/storage/users/31610/images/system/31610.jpg",biography:"Miroslav Blumenberg, Ph.D., was born in Subotica and received his BSc in Belgrade, Yugoslavia. He completed his Ph.D. at MIT in Organic Chemistry; he followed up his Ph.D. with two postdoctoral study periods at Stanford University. Since 1983, he has been a faculty member of the RO Perelman Department of Dermatology, NYU School of Medicine, where he is codirector of a training grant in cutaneous biology. Dr. Blumenberg’s research is focused on the epidermis, expression of keratin genes, transcription profiling, keratinocyte differentiation, inflammatory diseases and cancers, and most recently the effects of the microbiome on the skin. He has published more than 100 peer-reviewed research articles and graduated numerous Ph.D. and postdoctoral students.",institutionString:null,institution:{name:"New York University Langone Medical Center",institutionURL:null,country:{name:"United States of America"}}},subseries:[{id:"14",title:"Cell and Molecular Biology",keywords:"Omics (Transcriptomics; Proteomics; Metabolomics), Molecular Biology, Cell Biology, Signal Transduction and Regulation, Cell Growth and Differentiation, Apoptosis, Necroptosis, Ferroptosis, Autophagy, Cell Cycle, Macromolecules and Complexes, Gene Expression",scope:"The Cell and Molecular Biology topic within the IntechOpen Biochemistry Series aims to rapidly publish contributions on all aspects of cell and molecular biology, including aspects related to biochemical and genetic research (not only in humans but all living beings). We encourage the submission of manuscripts that provide novel and mechanistic insights that report significant advances in the fields. Topics include, but are not limited to: Advanced techniques of cellular and molecular biology (Molecular methodologies, imaging techniques, and bioinformatics); Biological activities at the molecular level; Biological processes of cell functions, cell division, senescence, maintenance, and cell death; Biomolecules interactions; Cancer; Cell biology; Chemical biology; Computational biology; Cytochemistry; Developmental biology; Disease mechanisms and therapeutics; DNA, and RNA metabolism; Gene functions, genetics, and genomics; Genetics; Immunology; Medical microbiology; Molecular biology; Molecular genetics; Molecular processes of cell and organelle dynamics; Neuroscience; Protein biosynthesis, degradation, and functions; Regulation of molecular interactions in a cell; Signalling networks and system biology; Structural biology; Virology and microbiology.",annualVolume:11410,isOpenForSubmission:!0,coverUrl:"https://cdn.intechopen.com/series_topics/covers/14.jpg",editor:{id:"165627",title:"Dr.",name:"Rosa María",middleName:null,surname:"Martínez-Espinosa",fullName:"Rosa María Martínez-Espinosa",profilePictureURL:"https://mts.intechopen.com/storage/users/165627/images/system/165627.jpeg",institutionString:null,institution:{name:"University of Alicante",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"79367",title:"Dr.",name:"Ana Isabel",middleName:null,surname:"Flores",fullName:"Ana Isabel Flores",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRpIOQA0/Profile_Picture_1632418099564",institutionString:null,institution:{name:"Hospital Universitario 12 De Octubre",institutionURL:null,country:{name:"Spain"}}},{id:"328234",title:"Ph.D.",name:"Christian",middleName:null,surname:"Palavecino",fullName:"Christian Palavecino",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000030DhEhQAK/Profile_Picture_1628835318625",institutionString:null,institution:{name:"Central University of Chile",institutionURL:null,country:{name:"Chile"}}},{id:"186585",title:"Dr.",name:"Francisco Javier",middleName:null,surname:"Martin-Romero",fullName:"Francisco Javier Martin-Romero",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bSB3HQAW/Profile_Picture_1631258137641",institutionString:null,institution:{name:"University of Extremadura",institutionURL:null,country:{name:"Spain"}}}]},{id:"15",title:"Chemical Biology",keywords:"Phenolic Compounds, Essential Oils, Modification of Biomolecules, Glycobiology, Combinatorial Chemistry, Therapeutic peptides, Enzyme Inhibitors",scope:"Chemical biology spans the fields of chemistry and biology involving the application of biological and chemical molecules and techniques. In recent years, the application of chemistry to biological molecules has gained significant interest in medicinal and pharmacological studies. This topic will be devoted to understanding the interplay between biomolecules and chemical compounds, their structure and function, and their potential applications in related fields. Being a part of the biochemistry discipline, the ideas and concepts that have emerged from Chemical Biology have affected other related areas. 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Behind these definitions are hidden all the aspects of normal and pathological functioning of all processes that the topic ‘Metabolism’ will cover within the Biochemistry Series. Thus all studies on metabolism will be considered for publication.",annualVolume:11413,isOpenForSubmission:!0,coverUrl:"https://cdn.intechopen.com/series_topics/covers/17.jpg",editor:{id:"138626",title:"Dr.",name:"Yannis",middleName:null,surname:"Karamanos",fullName:"Yannis Karamanos",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002g6Jv2QAE/Profile_Picture_1629356660984",institutionString:null,institution:{name:"Artois University",institutionURL:null,country:{name:"France"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"243049",title:"Dr.",name:"Anca",middleName:null,surname:"Pantea Stoian",fullName:"Anca Pantea Stoian",profilePictureURL:"https://mts.intechopen.com/storage/users/243049/images/system/243049.jpg",institutionString:null,institution:{name:"Carol Davila University of Medicine and Pharmacy",institutionURL:null,country:{name:"Romania"}}},{id:"203824",title:"Dr.",name:"Attilio",middleName:null,surname:"Rigotti",fullName:"Attilio Rigotti",profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institutionString:null,institution:{name:"Pontifical Catholic University of Chile",institutionURL:null,country:{name:"Chile"}}},{id:"300470",title:"Dr.",name:"Yanfei (Jacob)",middleName:null,surname:"Qi",fullName:"Yanfei (Jacob) Qi",profilePictureURL:"https://mts.intechopen.com/storage/users/300470/images/system/300470.jpg",institutionString:null,institution:{name:"Centenary Institute of Cancer Medicine and Cell Biology",institutionURL:null,country:{name:"Australia"}}}]},{id:"18",title:"Proteomics",keywords:"Mono- and Two-Dimensional Gel Electrophoresis (1-and 2-DE), Liquid Chromatography (LC), Mass Spectrometry/Tandem Mass Spectrometry (MS; MS/MS), Proteins",scope:"With the recognition that the human genome cannot provide answers to the etiology of a disorder, changes in the proteins expressed by a genome became a focus in research. Thus proteomics, an area of research that detects all protein forms expressed in an organism, including splice isoforms and post-translational modifications, is more suitable than genomics for a comprehensive understanding of the biochemical processes that govern life. The most common proteomics applications are currently in the clinical field for the identification, in a variety of biological matrices, of biomarkers for diagnosis and therapeutic intervention of disorders. From the comparison of proteomic profiles of control and disease or different physiological states, which may emerge, changes in protein expression can provide new insights into the roles played by some proteins in human pathologies. Understanding how proteins function and interact with each other is another goal of proteomics that makes this approach even more intriguing. Specialized technology and expertise are required to assess the proteome of any biological sample. Currently, proteomics relies mainly on mass spectrometry (MS) combined with electrophoretic (1 or 2-DE-MS) and/or chromatographic techniques (LC-MS/MS). MS is an excellent tool that has gained popularity in proteomics because of its ability to gather a complex body of information such as cataloging protein expression, identifying protein modification sites, and defining protein interactions. The Proteomics topic aims to attract contributions on all aspects of MS-based proteomics that, by pushing the boundaries of MS capabilities, may address biological problems that have not been resolved yet.",annualVolume:11414,isOpenForSubmission:!0,coverUrl:"https://cdn.intechopen.com/series_topics/covers/18.jpg",editor:{id:"200689",title:"Prof.",name:"Paolo",middleName:null,surname:"Iadarola",fullName:"Paolo Iadarola",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bSCl8QAG/Profile_Picture_1623568118342",institutionString:null,institution:{name:"University of Pavia",institutionURL:null,country:{name:"Italy"}}},editorTwo:{id:"201414",title:"Dr.",name:"Simona",middleName:null,surname:"Viglio",fullName:"Simona Viglio",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRKDHQA4/Profile_Picture_1630402531487",institutionString:null,institution:{name:"University of Pavia",institutionURL:null,country:{name:"Italy"}}},editorThree:null,editorialBoard:[{id:"72288",title:"Dr.",name:"Arli Aditya",middleName:null,surname:"Parikesit",fullName:"Arli Aditya Parikesit",profilePictureURL:"https://mts.intechopen.com/storage/users/72288/images/system/72288.jpg",institutionString:null,institution:{name:"Indonesia International Institute for Life Sciences",institutionURL:null,country:{name:"Indonesia"}}},{id:"40928",title:"Dr.",name:"Cesar",middleName:null,surname:"Lopez-Camarillo",fullName:"Cesar Lopez-Camarillo",profilePictureURL:"https://mts.intechopen.com/storage/users/40928/images/3884_n.png",institutionString:null,institution:{name:"Universidad Autónoma de la Ciudad de México",institutionURL:null,country:{name:"Mexico"}}},{id:"81926",title:"Dr.",name:"Shymaa",middleName:null,surname:"Enany",fullName:"Shymaa Enany",profilePictureURL:"https://mts.intechopen.com/storage/users/81926/images/system/81926.png",institutionString:"Suez Canal University",institution:{name:"Suez Canal University",institutionURL:null,country:{name:"Egypt"}}}]}]}},libraryRecommendation:{success:null,errors:{},institutions:[]},route:{name:"profile.detail",path:"/profiles/195260",hash:"",query:{},params:{id:"195260"},fullPath:"/profiles/195260",meta:{},from:{name:null,path:"/",hash:"",query:{},params:{},fullPath:"/",meta:{}}}},function(){var e;(e=document.currentScript||document.scripts[document.scripts.length-1]).parentNode.removeChild(e)}()