Chapters authored
Electrodeposition of WO3 Nanoparticles for Sensing Applications
The motivation of using metal oxides is mainly due to its charge storage capabilities, and electrocatalytic, electrochromic and photoelectrochemical properties. But comparing with bulk, nanostructured materials present several advantages related with the spatial confinement, large fraction of surface atoms, high surface energy, strong surface adsorption and increased surface to volume ratio, which greatly improves the performances of these materials. The deposition of this materials can be accomplished by a variety of physical and chemical techniques but nowadays, electrodeposited metal oxides are generally used in both laboratories and industries due to the flexibility to control structure and morphology of the oxide electrodes combined with a reduced cost. Tungsten oxide (WO3) is a well-studied semiconductor and is used for several applications as chromogenic material, sensor and catalyst. The major important features is its low cost and availability, improved stability, easy morphologic and structural control of the nanostructures, reversible change of conductivity, high sensitivity, selectivity and biocompatibility. For the electrodeposition of WO3, more than one method can be adopted: electrodeposition from a precursor solution, anodic oxidation, and electrodeposition of already produced nanoparticles; however, in this case the mechanism of the electrodeposition is not fully understood. In this chapter, a review of the latest published work of electrodeposited nanostructured metal oxides is provided to the reader, with a more detailed explanation of WO3 material applied in sensing devices.
Part of the book: Electroplating of Nanostructures
Solution Combustion Synthesis: Applications in Oxide Electronics
Oxide-based electronics have been well established as an alternative to silicon technology; however, typical processing requires complex, high-vacuum equipment, which is a major drawback, particularly when targeting low-cost applications. The possibility to deposit the materials by low-cost techniques such as inkjet printing has drawn tremendous interest in solution processible materials for electronic applications; however, high processing temperatures still required. To overcome this issue, solution combustion synthesis has been recently pursued. Taking advantage of the exothermic nature of the reaction as a source of energy for localized heating, the precursor solutions can be converted into oxides at lower process temperatures. Theoretically, this can be applied to any metal ions to produce the desired oxide, opening unlimited possibilities to materials’ composition and combinations. Solution combustion synthesis has been applied for the production of semiconductor thin films based on ZnO, In2O3, SnO2 and combinations of these oxides, and also for high κ dielectrics (Al2O3). All of which are required for numerous electronic devices and applications such as fully oxide-based thin-film transistors (TFTs). The properties of produced thin films are highly dependent on the precursor solution characteristics; hence, the influence of several processing parameters; organic fuel, solvent and annealing temperature was studied. Although precursor solution degradation/oxide formation mechanisms are not yet fully understood, particularly for thin films, we demonstrate that high-performance devices are obtained with combustion solution-based metal oxide thin films. The results clearly show that solution combustion synthesis is becoming one of the most promising methods for low-temperature flexible electronics.
Part of the book: Developments in Combustion Technology
Hydrothermal Synthesis of Zinc Tin Oxide Nanostructures for Photocatalysis, Energy Harvesting and Electronics
The massification of Internet of Things (IoT) and Smart Surfaces has increased the demand for nanomaterials excelling at specific properties required for their target application, but also offering multifunctionality, conformal integration in multiple surfaces and sustainability, in line with the European Green Deal goals. Metal oxides have been key materials for this end, finding applications from flexible electronics to photocatalysis and energy harvesting, with multicomponent materials as zinc tin oxide (ZTO) emerging as some of the most promising possibilities. This chapter is dedicated to the hydrothermal synthesis of ZTO nanostructures, expanding the already wide potential of ZnO. A literature review on the latest progress on the synthesis of a multitude of ZTO nanostructures is provided (e.g., nanowires, nanoparticles, nanosheets), emphasizing the relevance of advanced nanoscale techniques for proper characterization of such materials. The multifunctionality of ZTO will also be covered, with special attention being given to their potential for photocatalysis, electronic devices and energy harvesters.
Part of the book: Novel Nanomaterials
Porous ZnO Nanostructures Synthesized by Microwave Hydrothermal Method for Energy Harvesting Applications
The ever-growing global market for smart wearable technologies and Internet of Things (IoT) has increased the demand for sustainable and multifunctional nanomaterials synthesized by low-cost and energy-efficient processing technologies. Zinc oxide (ZnO) is a key material for this purpose due to the variety of facile methods that exist to produced ZnO nanostructures with tailored sizes, morphologies, and optical and electrical properties. In particular, ZnO nanostructures with a porous structure are advantageous over other morphologies for many applications because of their high specific surface area. In this chapter, a literature review on the latest progress regarding the synthesis and applications of ZnO with a porous morphology will be provided, with special focus on the synthesis by microwave hydrothermal method of these nanomaterials and their potential for application in energy harvesting devices. Nanogenerators of a composite made by polydimethylsiloxane (PDMS) and porous ZnO nanostructures were explored and optimized, with an output voltage of (4.5 ± 0.3) V being achieved for the best conditions. The daily life applicability of these devices was demonstrated by lighting up a commercial LED, by manually stimulating the nanogenerator directly connected to the LED.
Part of the book: Nanopores
Perspective Chapter: Vertically Aligned 1D ZnO Nanostructures – Influence of Synthesis Parameters on the Nanomaterials’ Properties
View all chaptersZinc oxide (ZnO) is a widely explored semiconductor metal oxide. This material has interesting properties for several research areas, including energy storage and harvesting, sensing and electronic applications. Its versatility has led to the development of various approaches for synthesizing nanostructures with different morphologies according to the application. In this chapter, a literature review on vapor phase and solution phase synthesis approaches for synthesizing one-dimensional (1D) ZnO nanostructures on different substrates will be provided to establish a comparison between different processes’ parameters. Since hydrothermal synthesis is the most widely used approach for growing ZnO on different substrates due to its simplicity and cost-effectiveness, the principles of this technique will be detailed. As an experimental demonstration of such technique, novel results obtained at CENIMAT on microwave-assisted hydrothermal synthesis of ZnO nanorods, exploring the influence of seed layer thickness, ultraviolet/ozone (UVO) treatment to this layer, and synthesis time and temperature on the nanostructures’ morphology, will be presented. The nanostructures’ length, diameter and density were measured to establish a correlation between synthesis conditions and nanostructures’ features. A seed layer thickness of 100 nm, a 5 min UVO treatment, and a synthesis time and temperature of 60 min and 100°C led to the formation of ZnO nanorods with increased length and aspect ratio.
Part of the book: Zinc Oxide Nanoparticles - Fundamentals and Applications [Working title]