Normalised values for comparing conventional technology (basic case) with the SCT-CPO process schemes of Figures 8 and 9.
\r\n\t
",isbn:"978-1-83962-360-8",printIsbn:"978-1-83880-853-2",pdfIsbn:"978-1-83962-361-5",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!1,hash:"793751ee53f02ca84c8fe298a66208c9",bookSignature:"Dr. Kazuyuki Matsumoto",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/9885.jpg",keywords:"Affective Computing, Sentiment Analysis Systems, Information Processing, Information Extraction, Neural Computing, Deep Learning, Swarm Intelligence, Chatbot, Dialogue Breakdown, Nursing Information Systems, Nursing Management Systems, Clinical Pathways Systems",numberOfDownloads:43,numberOfWosCitations:0,numberOfCrossrefCitations:0,numberOfDimensionsCitations:0,numberOfTotalCitations:0,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"June 9th 2020",dateEndSecondStepPublish:"October 2nd 2020",dateEndThirdStepPublish:"December 1st 2020",dateEndFourthStepPublish:"February 19th 2021",dateEndFifthStepPublish:"April 20th 2021",remainingDaysToSecondStep:"3 months",secondStepPassed:!0,currentStepOfPublishingProcess:4,editedByType:null,kuFlag:!1,biosketch:"A member of the technical committee of the international conference of IEEE and other international societies with broad research experience in Sensibility Robotics.",coeditorOneBiosketch:null,coeditorTwoBiosketch:null,coeditorThreeBiosketch:null,coeditorFourBiosketch:null,coeditorFiveBiosketch:null,editors:[{id:"195756",title:"Dr.",name:"Kazuyuki",middleName:null,surname:"Matsumoto",slug:"kazuyuki-matsumoto",fullName:"Kazuyuki Matsumoto",profilePictureURL:"https://mts.intechopen.com/storage/users/195756/images/system/195756.png",biography:"Dr. Matsumoto received his Ph.D. degree in 2008 from the Faculty of Engineering, the University of Tokushima. He is currently an assistant professor at the University of Tokushima. His main research field is Sensibility Robotics. His research interests include affective computing, Emotion Recognition, and Natural Language Processing. He has published over 30 peer-reviewed articles as a leading author. He is a member of the technical committee of the international conference of IEEE and other societies. He is a member of Information Processing Society of Japan (IPSJ), The Institute of Electronics, Information and Communication Engineers (IEICE), The Japanese Society for Artificial Intelligence (JSAI), The Association for Natural Language Processing (ANLP), The Institute of Electrical Engineers of Japan (IEEJ) and Human Interface Society.",institutionString:"University of Tokushima",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"2",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"University of Tokushima",institutionURL:null,country:{name:"Japan"}}}],coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"9",title:"Computer and Information Science",slug:"computer-and-information-science"}],chapters:[{id:"73157",title:"Humanistic Next-Generation Artificial Intelligence Capable of Association",slug:"humanistic-next-generation-artificial-intelligence-capable-of-association",totalDownloads:43,totalCrossrefCites:0,authors:[null]}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},personalPublishingAssistant:{id:"194667",firstName:"Marijana",lastName:"Francetic",middleName:null,title:"Ms.",imageUrl:"https://mts.intechopen.com/storage/users/194667/images/4752_n.jpg",email:"marijana@intechopen.com",biography:"As an Author Service Manager my responsibilities include monitoring and facilitating all publishing activities for authors and editors. From chapter submission and review, to approval and revision, copyediting and design, until final publication, I work closely with authors and editors to ensure a simple and easy publishing process. I maintain constant and effective communication with authors, editors and reviewers, which allows for a level of personal support that enables contributors to fully commit and concentrate on the chapters they are writing, editing, or reviewing. I assist authors in the preparation of their full chapter submissions and track important deadlines and ensure they are met. I help to coordinate internal processes such as linguistic review, and monitor the technical aspects of the process. As an ASM I am also involved in the acquisition of editors. 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Venkateswarlu",coverURL:"https://cdn.intechopen.com/books/images_new/371.jpg",editedByType:"Edited by",editors:[{id:"58592",title:"Dr.",name:"Arun",surname:"Shanker",slug:"arun-shanker",fullName:"Arun Shanker"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"878",title:"Phytochemicals",subtitle:"A Global Perspective of Their Role in Nutrition and Health",isOpenForSubmission:!1,hash:"ec77671f63975ef2d16192897deb6835",slug:"phytochemicals-a-global-perspective-of-their-role-in-nutrition-and-health",bookSignature:"Venketeshwer Rao",coverURL:"https://cdn.intechopen.com/books/images_new/878.jpg",editedByType:"Edited by",editors:[{id:"82663",title:"Dr.",name:"Venketeshwer",surname:"Rao",slug:"venketeshwer-rao",fullName:"Venketeshwer Rao"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"4816",title:"Face Recognition",subtitle:null,isOpenForSubmission:!1,hash:"146063b5359146b7718ea86bad47c8eb",slug:"face_recognition",bookSignature:"Kresimir Delac and Mislav Grgic",coverURL:"https://cdn.intechopen.com/books/images_new/4816.jpg",editedByType:"Edited by",editors:[{id:"528",title:"Dr.",name:"Kresimir",surname:"Delac",slug:"kresimir-delac",fullName:"Kresimir Delac"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3621",title:"Silver Nanoparticles",subtitle:null,isOpenForSubmission:!1,hash:null,slug:"silver-nanoparticles",bookSignature:"David Pozo Perez",coverURL:"https://cdn.intechopen.com/books/images_new/3621.jpg",editedByType:"Edited by",editors:[{id:"6667",title:"Dr.",name:"David",surname:"Pozo",slug:"david-pozo",fullName:"David Pozo"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}]},chapter:{item:{type:"chapter",id:"40565",title:"Natural Gas Catalytic Partial Oxidation: A Way to Syngas and Bulk Chemicals Production",doi:"10.5772/48708",slug:"natural-gas-catalytic-partial-oxidation-a-way-to-syngas-and-bulk-chemicals-production",body:'The term Syngas is used for describing a mixture containing H2 and CO, together with minor amounts of CO2 and CH4. Syngas can be produced from Natural Gas (NG), refinery off-gases, naphtha, heavy hydrocarbons and also from coal. The choice of a particular raw material depends on cost and availability of the feedstock, and on downstream use of syngas.
Main utilisations of syngas (Figure 1) are: i) the synthesis of Ammonia/Urea, ii) the oil refining operations, iii) the synthesis of Methanol and its derivatives, iv) the synthesis of liquid hydrocarbons via Fischer-Tropsch processes and v) other “minor” applications such as Iron ores reduction, fine chemistry productions, electronic, glass industry activities (Song and Guo, 2006).
Worldwide H2 production capacity (2001) devoted to main H2 uses
The H2/Syngas production capacity has always been increasing and it is still rising, particularly in the growing economies, in Middle East Countries and in almost all refineries spread worldwide.
Since syngas is an intermediate for feeding very different processes its composition and particularly the H2/CO ratios are also very different (Moulijn et al., 2001). For example, in the synthesis of methanol, CO2 and CO are both reactants and its composition is determined by a module M = (H2-CO2)/(CO+CO2) that should be close to 2.0 (mole/mole). Instead for Fischer Tropsch synthesis Gas to Liquid (GTL) applications, in which CO2 is not a reactant molecule, the required synthesis gas compositions have a H2/CO ratio of about 2.0 (mole/mole). The optimal H2/CO ratio is lowered to 1.0 mole/mole for aldehydes productions via olefins hydroformylation. Sometimes, pure CO is required for the carbonylation process. However, the two main synthesis gas applications, the synthesis of Ammonia/Urea and the Oil Refining treatments, require the maximisation of H2 production.
The most utilised synthesis gas production processes are:
Steam reforming (SR)
Partial oxidation (POx)
Autothermal reforming (ATR)
Steam reforming is a catalytic and energy efficient technology for producing a H2 rich syngas from light hydrocarbons like NG, refinery off-gases, LPG or Naphta. Partial oxidation is a non-catalytic technology with a unique possibility of utilising heavy hydrocarbon feedstock and produces a CO rich syngas at temperatures between 1100-1400°C. Its energy efficiency is lower than SR. ATR combines gaseous phase combustion reactions and catalytic steam/CO2 reforming reactions; it is much less applied than SR and POx but it is the optimal choice for integration with large scale MeOH production plants and GTL processes (Holladay et al., 2009).
Despite the long term R&D and industrialisation effort that has lead to the optimisation of these technologies a relevant effort is still ongoing for defining new radical improvements allowing a reduction of the capital and energy requirements of the syngas production step. The Short Contact Time – Catalytic partial Oxidation technology, among the various proposed solutions, has reached enough reliability to promote its industrialisation and in the following chapters this promising new solution will be compared with the most consolidated technologies.
SR is the most utilised technology for producing synthesis gas. This technology reacts light desulphurised hydrocarbons (S content ca. 50 ppb) with steam; for instance SR of Methane is represented with eq. (1):
When utilised for H2 production the SR step is followed by a Water Gas Shift (WGS) step for CO conversion (2):
Subsequently H2 is purified with a Pressure Swing Adsorption (PSA) step (Song and Guo, 2006).
SR units include two sections, namely a radiant and a convective section. Reforming reactions take place inside the radiant section. In the convective section, heat is recovered from the hot product gases for preheating the reactants feeds and for generating superheated steam.
The endothermic SR reactions are catalysed by Ni based materials in which the Ni species are deposited onto ceramic supports composed by alumina and/or alumina and magnesium spinels (Rostrup-Nielsen, 1993). Some discussions on the possible utilisation of noble metal based catalyst also including alkaline earth species are reported in literature (Faur Ghenciu, 2002; Navarro et al., 2007). The catalysts are included inside tubes inserted into the radiant furnace. The catalytic tubes have a diameter between 3 and 5 inches and a length ranging between 6 and 13 m. A radiant furnace may contain 500-600 reaction tubes. Typically gas temperatures at the exit of the tubes are higher than 800°C and pressures are comprised between 15-30 barg. One criticality of SR is represented by the thermo-mechanical resistance of the tubes, whose skin temperature remains at values 100-150°C higher than those of the reaction environment for allowing high heat transfer rates. For this reason the tubes are casted with alloys having a high Cr and Ni content (25-35%) and their positioning inside the radiant furnace is determined both by the necessity of increasing heat fluxes towards the reaction zone and by the requirements on the avoidance of impingement between tubes and flames produced by the burners. This impingement would lead to rapid collapse of the tubes (Ahmed and Krumpelt, 2001).
The hydrocarbons feedstock is fed into the reforming tubes after being mixed with steam at steam/carbon ratios higher than 2.3 v/v, more often higher than 2.7 v/v; this excess Steam is required both for completing the hydrocarbon reactions and for avoiding the occurrence of carbon formation reactions (3-5).
CnH2n+2 = nC + (n+1)H2(3)
2CO = C + CO2(4)
CO + H2 = C + H2O(5)
Carbon and soot formation reactions would lead to pressure drop increase, catalyst deactivation and reaction rates reduction, causing serious heat transfer problems and tube damages (Peña et al., 1996).
Higher hydrocarbons are much more reactive towards reaction (3) than methane. For this reason, sometimes, these C2+ molecules are converted inside an adiabatic pre-reformer unit (Rostrup-Nielsen et al., 1998). This unit can be designed and operated at relatively low temperatures (ca. 550°C) leading to several advantages such as size reduction of the reformer furnace and/or increase of the production capacity (Joensen and Rostrup-Nielsen, 2002; Christensen, 1996).
The chemistry of the POx technology is based on the partial combustion of fuels that in case of CH4 is represented with equation (6)
CH4 + ½ O2 = CO + 2H2 (6)
However this process is mainly utilised for producing syngas from heavy hydrocarbons, including deasphalter pitch and petroleum coke. These are pre-heated and then mixed with Oxygen within a burner; after ignition, reactions occur inside a high temperature combustion chamber producing an effluent that contains various amounts of soot, depending on feedstock composition. Reactor exit gas temperatures are typically comprised between 1200-1400°C. The obtained syngas has to be cooled and cleaned within a “washing” section for removing the impurities. The high temperature (1400-1100°C) heat recovery in POx is not very efficient and indeed the POx advantage over SR is in the possibility of utilising a “low value” feedstock, even containing sulphur and other compounds that would poison the SR catalysts. Currently the main utilisations of POx are: (i) in H2 production for refinery applications, (ii) synthesis gas production from coal and (iii) in electric energy production from petroleum coke and deasphalter bottoms, through large Integrated Gas Turbine Combined Cycles (IGCC).
ATR combines non-catalytic partial oxidation and catalytic steam and CO2 reforming of light and highly de-sulphurated NG in a single reactor. The process was developed in the late 1950s by Haldor Topsøe A/S, mainly for producing syngas for methanol and ammonia plants and also for the Fischer-Tropsch synthesis (Christensen and Primdhal, 1994; Aasberg-Petersen et al., 2001). The NG is mixed at high temperature with a mixture of Oxygen and Steam and ignited in a combustion chamber originating a sub-stoichiometric flame that can be represented with eq. (7).
Subsequently Steam and CO2 reforming reactions (8) occur inside a catalytic bed positioned below the combustion chamber.
By proper adjustment of oxygen to carbon and steam to carbon ratios the partial combustion in the thermal zone (7) supplies the heat for completing the subsequent endothermic steam and CO2 reforming reactions (Joensen and Rostrup-Nielsen, 2002). The product gas composition at the exit of the reactor results very close to the thermodynamic equilibrium of an adiabatic reactor, especially in large scale processes (Rostrup-Nielsen, 2000).
ATR is also utilised as a “secondary reformer” (for lowering the CH4 residue) and it is placed after a primary SR in syngas plants integrated with Ammonia synthesis reactors. In this case the “secondary” ATR is fed with the syngas produced from SR and Air.
Initial observation on the occurrence of short contact time hydrocarbon oxidation processes were reported in the years 1992–1993 (Choudary et al., 1992; Hickman et al. 1992). These processes have been deeply studied since then, and the number of scientific articles published every year on this topic, is still high. They are produced by colliding for few milliseconds, gaseous premixed reactant flows with extremely hot catalytic surfaces. The fast and selective chemistry that is originated is confined inside a thin (<1 mm) solid–gas inter-phase zone surrounding the catalyst particles. Here, the molecules spend 10-6 s at temperatures variable between 600 – 1200° C. A key issue for the technological exploitation is in the possibility of avoiding the propagation of reactions into the gas phase, that has to remain at a “relatively low” temperature. This condition favours the formation of primary reaction products (namely CO and H2) inhibiting chain reactions. Indeed some experimental studies whose results have been partially described in literature (Schwiedernoch et al., 2003; Hickman et al., 1993; Basini et al., 2000; Grunwaldt et al., 2001; Grunwaldt et al., 2002; Bizzi et al., 2002; Bizzi et al., 2003; York et al., 2003) indicate that partial and total oxidation products are directly produced through parallel and competing surface reactions and that the formation of partial oxidation products is favoured under SCT conditions due to the very high surface temperatures. By proper choice of the operating conditions, surface temperatures are locally much higher than those predicted by thermodynamic equilibrium calculations assuming adiabatic reactors. The occurrence of the reactions in these local environments determines in some cases conversion and selectivity values higher than those predicted by the thermodynamic equilibrium at the reactor exit temperatures (Basini, 2001). Moreover, the very high surface temperatures inhibit catalyst deactivation phenomena related to chemical poison effects (Basini, 2005 and Basini, 2006). For these and other related reasons, this chemical process is carried out in very small reactors having a very high flexibility towards reactant flow variations. It has also been found that several hydrocarbon feedstocks, even containing sulphur and aromatic compounds can be fed to a SCT-CPO reactor for producing synthesis gas.
Now a long term R&D effort is approaching the industrialization phase of a technology whose main advantages concern:
Small dimensions, technical and operational simplicity
Possibility of modular construction of pre-fabricated and skid mounted units
Flexibility towards feedstock composition & production capacity
Reduction of investment costs and energy consumption
Reduction of CO2 production and possibility of an almost complete CO2 capture in case of H2 production plants
Selectivity and conversion of SCT-CPO are determined by the high temperatures of catalytic surfaces, much higher than gas phase temperatures resulting in an adiabatic equilibrium reactor. This allows mild pre-heating of the reactants, thus reducing CO2 emissions coming from pre-heating furnaces. Pre-heating is required only for the hydro-desulphurisation (HDS) of the feedstock, occurring in a temperature range typically comprised between 340–390°C depending on the hydrocarbon feedstock.
Figure 2 includes a schematic description of the SCT-CPO characteristics indicating that several feedstocks can be utilised for H2 production and showing that in the absence of pre-heating furnaces great part of the produced CO2 can be removed after the WGS section.
Main characteristics of SCT-CPO technology application devoted to H2 production and CO2 removal
Figure 3 includes some information for comparing the dimensions of SR and SCT-CPO reactors for producing 55,000 Nm3/h of pure H2. The figure shows that reactor dimensions are reduced of more than 2 orders of magnitude and that the complexity of the technology is greatly reduced too.
Comparisons between the dimensions and main characteristics of Steam Reforming and SCT-CPO technologies for H2 production
Now it is noted that CO2 emissions from SR result from two sources:
Steam Reforming and Water Gas Shift reactions producing ca. 60% of total CO2
Total combustion inside the reformer furnace producing the other 40% of total CO2
However, while the removal of CO2 from source (1) with an absorbent medium (i.e. amine or carbonate solutions) is feasible at a reasonable cost, the removal from source (2), a Flue Gas at low pressure including a large volume of Air, would be really expensive and complex. Indeed H2 production via SR is a very important Green House Gas (GHG) producer in refining operations (20-40% of the overall CO2 emissions).
Nowadays, in a context wherein CO2 taxation is increasing and refining operation are required to reduce GHG, the utilisation of SCT-CPO technology, particularly if integrated with CO2 removal, would be really advantageous. This point is further discussed by commenting the Process Flow Diagram of Figures 4 and 5.
In the PFD shown in Figure 4 the feed is mixed with hydrogen and pre-heated for the next HDS step accounting for 2% wt of the total produced CO2. The preheated stream is then mixed with steam and oxygen into the SCT-CPO reactor to produce synthesis gas. The hot synthesis gas is cooled in a Waste Heat Boiler (WHB) generating high pressure steam, partially utilized for a two-step WGS section, namely a high temperature shift (HTS) and a low temperature shift (LTS). Then a CO2 removal section is included before the H2 purification step, performed with a Pressure Swing Adsorption unit (PSA).
An alternative process scheme solution (see Figure 5) could also be utilized in situations in which a low H2 purity (ca. 98% v/v) is required.
An effort for assessing the potential advantages of these process scheme solutions has been performed by comparing the economics of SCT-CPO and SR in several different scenarios and for different plant capacities (10,000 - 50,000 and 100,000 Nm3/h of H2), as summarized in Figure 6 (Basini and Iaquaniello, 2011).
PFD including an SCT-CPO reactor for hydrogen production and CO2 sequestration
PFD including an SCT-CPO reactor for hydrogen production and CO2 sequestration avoiding the PSA step
Possible comparison conditions between SR and SCT-CPO processes for H2 production possibly including CO2 sequestration
It appears evident that in any scenario case (D), namely the H2 production with SR including a CO2 removal section would be the less advantageous solution. Instead in the great part of the examined conditions case (B), namely the H2 production with SCT-CPO including a CO2 removal section is the most advantageous solution.
Small size, technological simplicity and easy operability of SCT-CPO technology allows the pre-fabrication of the syngas production unit and the transportation of the reactor package to the utilisation site where it would be installed, requiring few interconnections minimising the interference risks with the ongoing industrial operations. Accordingly, one of the application of the SCT-CPO technology currently pursued, concerns removing the bottleneck of an existing SR (Figure 7). In this case the SCT-CPO reactor placed in parallel to an existing SR unit will utilise the same feedstock and will release the produced synthesis gas to an existing WGS and PSA “train”.
Scheme of the process solution in which SCT-CPO and SR are operated in parallel for increasing the H2 production capacity inside a refinery context.
A similar concept could be used to revamp ammonia/urea plant to enhance the urea production. In this case the CPO reactor installed in parallel to the exiting train provides the extra CO2 required increasing the urea production.
Ammonia/Urea production is currently achieved with the following main steps:
hydro-desulphurisation
pre-reforming (optional)
primary SR section with H2O/C ratio of about 3 v/v
secondary air blown ATR reformer
high temperature and low temperature shift conversion
CO2 removal
CO methanation
syngas compression
Two different schemes can be proposed for producing ammonia and Urea via SCT-CPO. These schemes are reported in Figures 8 and 9 and both include the following steps:
hydro-desulphurisation
mixing of desulfurized feed with enriched air and super-heated steam
SCT-CPO reforming for producing the syngas
cooling of the syngas in a process gas boiler (PGB) and Steam addition
high temperature and low temperature shift conversion
CO2 removal unit
CO methanation
syngas compression
Ammonia and urea production via SCT-CPO utilising enriched air
Ammonia and Urea production via O2 Blown SCT-CPO
In the PFD schematised in Figure 8 the SCT-CPO reactor is fed with enriched Air, while the PFD shown in Figure 9 utilises an O2-blown SCT-CPO reactor and a PSA unit, positioned after the CO2 removal unit for increasing H2 purity.
Both schemes consider that SCT-CPO allows producing a syngas mixture with an H2/CO2 ratio 3 v/v, very close to the most appropriate ratio for maximising the Urea production. In other words, the SCT-CPO technology would allow the increase of the urea production per unit volume of produced Ammonia. This point can be appreciated by considering equation (9) and assuming that the produced CO could be completely converted into CO2 and H2.
1.1 CH4 + 0.6 O2 + 0.3 H2O = 2.2 H2 + CO + 0.1 CO2 + 0.3 H2O(9)
Taking as basis an ammonia plant with a capacity of 3,000 MTPD (for an Urea production around 4,440 MTPD), we performed a preliminary technical economical comparison between the conventional process scheme, based on SR and ATR, and the two novel schemes based on SCT-CPO.
It is noted that an Urea production of 4,440 MTPD requires a syngas plant capacity corresponding to 352,000 Nm3/h of syngas with a H2/N2 ratio equal to 2.78 v/v and CH4 content lower than 1.0% v/v, delivered at a pressure around 30 barg. Table 1 includes a comparison between consumption and production features of the “state of the art” technological solutions and those achievable with SCT-CPO based on the process schemes of Figures 8 and 9.
State of the Art Case | ENRICHED AIR (Figure 8) | OXYGEN (Figure 9) | |
FEED + FUEL (103 Nm3/h) (1) | 1 | 0.94 | 0.81 |
FEED + FUEL (MM Kcal/tonn of NH3) | 1 | 0.95 | 0.82 |
OXYGEN (tonn/tonn Urea) | 0 | 0.26 | 0.41 |
EXTRA POWER (MWh) per Tonn of Urea | 0 | 0.14 | 0.52(2) |
IMPORT STEAM (tonn/h) | 1 | 1.39 | 1.11 |
EXPORT STEAM (tonn/h) | 1 | 0.86 | 0.65 |
CO2 EMITTED (tonn/h) | 1 | 0.00 | 0.00 |
CO2 RECOVERED (tonn/h) | 1 | 1.23 | 1.24 |
CO2 TO UREA (tonn/h) | 1 | 1.19 | 1.19 |
CO2 EXPORT OR VENT(tonn/h) | 1 | 2.02 | 2.24 |
AMMONIA PRODUCED (tonn/h) | 1 | 1.00 | 1.00 |
AMMONIA TO UREA (tonn/h) | 1 | 1.19 | 1.19 |
AMMONIA EXPORT (tonn/h) | 1 | 0.00 | 0.00 |
UREA PRODUCED (tonn/h) | 1 | 1.19 | 1.19 |
It is quite evident that with the above mentioned assumptions, Urea productivity can be increased by ca. 15% utilizing the same Ammonia production capacity and avoiding any excess ammonia export. Moreover the produced CO2 can be completely recovered achieving a 60% reduction of the CO2 emissions. Feed and fuel consumptions would also be reduced while power consumption would increase. The specific consumption is lowered of about 18% compared with the “state of the art” case. However it is also noted that the HP Steam Export would be reduced and if considered in the energy balance, this point would strongly reduce the energy consumption advantage. In other words, it can be said that the SCT-CPO based processes would be more efficient, but would produce a lower amount of HP Steam export. It also appears that the SCT-CPO processes would be favored by high NG price and low electric energy price scenarios. The data of Table 1 have been transformed in cost and incomes and an overall economical balance was done to make a preliminary assessment. The conclusions indicated that SCT-CPO based processes become very convenient in situations in which the excess of ammonia has to be converted into Urea and/or when the variation of the Ammonia/Urea prices require a flexible process. A first qualitative comparison indicated that either operating and investment costs are reduced with both SCT-CPO based process schemes (Table 2).
A typical large scale methanol production process (5,000 MTPD) requires a syngas flow (about 560.000 Nm3/h) at 36 barg with the following characteristics:
“Methanol Module” M = (H2-CO2)/(CO2+CO) = 2 (v/v)
ratio CO2/CO = 0.38 corresponding to CO/CO2=2.6 (v/v)
methane residue in the syngas lower than 1.30% (v/v dry basis)
The conventional process scheme for producing such a syngas includes the following main steps:
hydro-desulphurisation (HDS)
pre-reforming
splitting of the feed into two separate streams (60/40%) one to be processed from a SR (60% of total feed) the other (40% of total feed) from an O2 Blown ATR which combines the Steam Reformed Stream with the fresh feed
syngas cooling and high pressure steam generation
The utilisation of SCT-CPO integrated with MeOH synthesis loop can be envisaged accordingly to the scheme of Figure 10. Here in order to achieve a Methanol Module M = 2 v/v, 12% v/v of the synthesis gas has been shifted (WGS) and purified (PSA) for producing pure H2, that was added to the main synthesis gas stream (directly produced from the SCT-CPO reactor).
The scheme based on SCT-CPO technology (Figure 10) includes the following main steps for synthesis gas production:
hydro-desulphurisation (HDS)
mixing the de-sulphurated feed with super-heated Steam and Oxygen
SCT-CPO reforming
splitting the reformed gas for obtaining a pure H2 stream
mixing the pure H2 stream with the syngas directly produced from the SCT-CPO reactor for reaching an M value of 2 v/v
Block diagram for utilising the SCT-CPO technology in MeOH production
More in detail it is reported that desulfurized feed and steam flows are characterised by S/C = 0.6 v/v while in the “state of the art” process scheme this ratio corresponds to 1.8 v/v (this implies that extra heat is available from the synthesis loop). The feed + steam stream, at the outlet of saturator, is heated up to 480°C and mixed with Oxygen at 180°C for feeding the SCT-CPO reactor. The produced syngas at 1060°C is cooled down in the process gas boiler to raise HP steam, which is superheated in a separate furnace. The reformed gas at 320°C is split in two streams. One of these streams (ca. 42% v/v of total) is routed to a WGS section. The shifted gas is also split into two streams, the first, about 28% v/v of total is cooled and treated in a PSA unit to produce pure H2, the second is mixed as such with the un-shifted gas. In this way the Methanol Module is raised by adding a proper amount of H2 while CO/CO2 ratio is controlled via the WGS section. The purge gas together with others streams from the methanol synthesis section, are fired in a SSH heater, in a feed preheater and in a boiler to raise HP steam to be used within ASU for making the extra O2 required.
Ongoing technical and economical evaluations comparing the “State of the Art” and the SCT-CPO based technology figures are indicating that the new process scheme has the potential for reducing the CAPEX but slightly raises the OPEX. However it is clear that many of the possibilities accessible with this new “technological key”, have still to be examined.
Some Tecnimont KT S.p.A. R&D activities concerning the SCT-CPO have been developed within the framework of the European Project named: “Innovative Catalytic Technologies & Materials for Next Gas to Liquid Processes”, Coordinated by INSTM, Consorzio InterUniversitario per la Scienza e Tecnologia dei Materiali, Messina (Italy) (website, http://www.next-gtl.eu). The project, started in November 2009, has the duration of 4 years and is pursuing a multi-disciplinary long term approach for developing catalysts and pre-competitive technologies. The project is examining novel (at a pre-competitive level) routes, particularly suited for remote and stranded areas, for transforming NG into liquid products either for chemical or for fuel production. In this latter case, a better balance between diesel vs. gasoline pools would be achieved. In particular, one of the three lines investigated, for which Tecnimont KT S.p.A. is workpackage leader concerns the definition of new routes for syngas production utilising membrane systems (Capoferri et al., 2011) coupled with steam reforming reactors integrated in process schemes also including SCT-CPO.
The basic concept is that the use of membrane reactors for steam reforming reactions, enables the shift of chemical equilibrium towards products by removing the produced hydrogen, thus enhancing feed conversion or achieving the same feed conversion at lower temperature (as an example, conventional plants usually require outlet temperatures around 850-880°C, that can be lowered to 600-650°C by adopting membrane reactors).
The integration of selective membranes in a chemical process can be made: (i) directly inside the reaction environment (“closed” architecture), (ii) after the reaction step, thus realizing a sequence of reactor/membrane modules (“open” architecture, Iaquaniello and Salladini, 2011). The integrated approach can be more efficient and allows higher system compactness, however the possibility to integrate the membrane module outside the reaction environment can i) assure higher system flexibility, ii) simplify the reactor mechanical design and membrane geometry, iii) make possible the optimization of the operating conditions in each stage separately.
Such a conceptual membrane reactor scheme derives from recent experience developed by Tecnimont KT/INSTM together with other partners in the framework of the Italian FISR Project “Pure hydrogen from natural gas reforming up to total conversion obtained by integrating chemical reaction and membrane separation”. This consortium grouped Italian universities and the engineering company Tecnimont KT, cooperating in the development of this innovative technology, that individuated as critical points membrane manufacture and assembling and catalyst optimization. The project resulted in the design and operation of a demonstrative plant (capacity of 20 Nm3/h oh hydrogen), placed in Chieti Scalo, based on the integration of a steam reforming reactor with Pd and Pd/Ag based membranes for hydrogen separation (Barba et al., 2008; Iaquaniello et al., 2008; De Falco et al., 2011a; De Falco et al., 2011b). This installation, the first of this type and size, made it possible to completely understand the potential of selective membrane application in industrial high-temperature chemical processes.
During the first stage of the Next-GTL project, an optimized process scheme was developed, characterized by the sequence of the following steps: (i) pre-reforming stage; (ii) SCT-CPO reactor; (iii) membrane for H2 separation. The aim of the proposed architecture is to produce syngas and hydrogen with higher flexibility in terms of H2/CO ratio and H2 capacity at a more competitive production cost, exploiting all the advantages relevant to a prereformer unit, such as: (i) to increase the feedstock flexibility; (ii) to lower export steam production; (iii) to recover the maximum waste heat in the process (which in CPO architecture, downstream of the reactor, is largely available); (iv) to remove the bottleneck in an existing facility; (v) to protect downstream catalysts; (vi) to increase the capacity of an existing plant.
The experimental feasibility of the proposed architecture will be assessed at the pilot plant in Chieti Scalo, that will be operated at lower temperature (like a pre-reforming Unit).
The current plant configuration is reported in the block diagram in Figure 11.
Block diagram of the current configuration of the existing pilot plant in Chieti Scalo
NG from battery limits is fed to the feed desulphurization (HDS) reactor for sulphur compounds removal. The desulphurised feed is mixed with steam, preheated in the convective section and fed to the first reforming reactor (R-01). Reforming temperatures can be set as required by the tests, adjusting the amount of fuel fed to two independent hot gas generators coupled to two steam reforming reactors. Typically the reactors operate at temperatures around 500-600°C.
The reformed gas produced in the first reactor is cooled down at 400-450°C and routed to the first separation module (M-01): the retentate is preheated and recycled to the second reformer stage (R-02), and a mixture of H2 plus sweeping steam are produced. Reformed gas coming from the second reformer stage is cooled down and routed to the second separation module (M-02). H2 from both modules are mixed together and sent to final cooling and condensate separation while retentate from the second stage is collected to the flare.
According to our considerations, the current configuration could be modified as reported in the following block diagram (Figure 12), where it can be observed that the retentate coming from the first membrane module is sent to a SCT-CPO reactor whereas the second steam reformer is eliminated.
Block diagram of the modified configuration of the existing pilot plant in Chieti Scalo
The process scheme of the existing pilot plant after the rearrangement procedure is reported in Figure 13.
Process scheme of the pilot plant to be realized in the framework of “Next-GTL” project
It can be observed that the main difference with respect to the previous process scheme is represented by the fact that the retentate stream coming from the first separation module (M-01) is sent to the CPO reactor, which outlet is further routed to the second separation module (M-02). Before this passage, the exhaust stream coming from the CPO reactor is forced to flow through the second steam reformer reactor, which in this case is empty, so that any catalytic reaction occurs in it, thus simulating a reactor by-pass operation.
It is expected to have the first catalytic activity tests results within the end of 2012.
This system configuration could in principle be integrated also with membranes for O2 and CO2 separation since the former may contribute to a reduction of the costs for air separation, one of the more costly components of the overall GTL process, while the latter can be used to separate carbon dioxide to reduce greenhouse gas emissions and allow its reuse.
Syngas production is a key step for many industrial manufacturing schemes. The technological issues involved are quite relevant to determine the overall energy efficiency and the economic characteristics of syngas processes. Well established industrial solutions, namely the SR, the POx and the ATR will be soon challenged by a radical innovation; namely the SCT-CPO technology that has matured inside the ENI S.p.A., which has been extensively experimented in pilot scale plants and has reached the maturation for initiating the first industrial unit. Technimont KT S.p.A. has also been very active, among the other companies, in this field by studying in recent years, process scheme solution including SCT-CPO not only for H2 production but also with NH3/Urea and MeOH production units. This integration appears already feasible. Some more explorative studies are also ongoing for examining process scheme solutions including membranes separation units.
This work received a financial support by the European Community throughout the Next GTL project- Contract NMP3-LA-2009-229183
Modern automobiles have made a significant contribution to the growth of society and humankind. Automobile vehicles and power train technology refined over the century of focused hard work by automobile engineering and scientist. Modern internal combustion engine propelled automobiles have satisfied multiple needs humankind in everyday life. It is difficult to imagine a world without automobiles in the present time [1]. The contribution of bearing to enhance the performance of automobiles is also immense. Bearings play’s a critical role in the enhancement of any rotating systems performance by bearing loads and facilitating the load transfer with minimum friction in addition to other functions. All rotating components of automobile systems require bearings to do its functions appropriately. Bearings improve the performance of the automobiles by supporting heavy loads and reducing friction. Major automobile sub-systems where bearings are implemented are internal combustion engines, transmissions, wheels, steering, pumps, and other electrical systems.
\nHowever, the popularity of automobiles, population density in the urban areas as well as rapidly growing urbanization has negatively impacted the environment. It raised health-related concerns to humans as well as other habitats. Internal combustion engines played the critical role of being prime mover for automobiles however, it is also a major source of pollution in urban areas due to the burning of fossil fuels and its by-products like CO2, NOx, etc. In recent times focus on emission control from regularity bodies, country specific laws are increasing which is pushing researchers to look for solutions beyond internal combustion engines. In recent times electric powertrains, hybrid powertrains have already proven to be the strong alternatives to conventional engines.
\nPresent time, the global automobile industry is focusing on clean transportation solutions including hybrid and battery electric drives. Automobiles are typically considered person-driven, personal transportation internal combustion engine (fossil fuel) propelled and independently operated transportation medium. In present times automobiles (passenger vehicles) are majorly part of personal transportation, however, incoming times the way automobiles are being utilized in practice is transforming toward shared mobility, autonomous vehicles.
\nThe automobile industry is experiencing a major technology shift. Connected, Autonomous, Shared, and Electrified (CASE) are major technology trends in the automobile utilization and technology development (Figure 1).
\nMega trends in automobile industry.
Shared mobility is more of productive utilization of vehicle and related technology which connects vehicle or operator via internet-based communication for sharing the vehicle. Basically, vehicle ownership and utilization are extended for more productive utilization vehicle. Modern information technology, internet, and availability of electronic hardware making it feasible to ensure vehicle to vehicle, vehicle to device communication, and improve vehicle utilization to improve the uptime of vehicles. Modern automobiles are expected to utilize to its maximum potential, so it is becoming imperative to monitor the health of the system in real-time.
\nThe electrification of the powertrain is another megatrend in the automobile industry. The electric vehicle powertrain is a major shift from fossil fuel-based prime mover (engine) to battery operated electric motors as a prime mover. Electrified vehicles are more efficient, less polluting making it a more transportation friendly solution. Electrification of powertrains is a major technology shift in which the propulsion of vehicles needs a lesser number of rotating parts as well as it simplifies the complete powertrain. Electric powertrains operate at lower cost as well.
\nIn the present time, commuting to work in dense traffic is putting additional stress on vehicle operators and waste of precious productive time. Autonomous operation is the solution to these new challenges. Automobiles are using more electronics hardware than ever before due to these added functionalities. Driver assisted operation as well as complete autonomous drive powertrains are implemented in practice in modern automobiles. Real-time health monitoring of vehicle is important for the trouble-free operation as well as the safety of passengers in modern era vehicles.
\nAs the automobile powertrain technologies are changing it is also percolating to critical components/subsystems like bearing. Modern vehicle bearings are far refined and technologically superior compare to traditional automobiles bearings. They are having multiple additional functionalities over the primary bearing functions. This chapter is about understanding the role of bearings in modern automobiles vehicles to achieve the mega technology shift in the automobile industry. The subsequent text introduces bearing technology research focus areas like reliability improvement, power-dense solutions, integrated functions, friction optimization, sealing/lubrication solutions [2], adoption of sensors, and also special application-specific eMotors bearings.
\nModern automobile powertrains are working on the same engineering principles however, they are having far superior performance compare former powertrains. Modern powertrains are an integrated mechanical, electrical and electronics system to achieve the objective of lesser emission, better fuel efficiency, and higher overall efficiency. The modern powertrain can be classified into two major categories: Hybrid powertrain and battery electric powertrain.
\nHybrid powertrains are having dual power sources like internal combustion engine and motor + battery arranged in multiple layouts like parallel, series, balanced, etc.
\n\nFigure 2 is a typical layout of a hybrid powertrain. It can be observed in the figure that the complete powertrain is having all the systems of a conventional powertrain including an internal combustion engine, transmissions and additionally it is also having a battery and motor to support the vehicle propulsion.
\nTypical hybrid powertrain layout [3].
In a hybrid powertrain number of bearings are more compare to the conventional powertrain. The bearings are used in the engine, transmission, motors, and transfer case. The hybrid powertrains are having more rotating parts however, this powertrain runs efficiently as all special events in operations like peak power requirements are fulfilled by the battery powered electric motor.
\nFull battery-electric vehicle powertrains are simpler in construction and having lesser rotating components. Battery electric vehicle powertrains are also having multiple configurations like traction motor + transmission, independent in-wheel motors for each wheel, etc.
\n\nFigure 3 is a typical layout of a battery-electric powertrain, in which it is having a floor-mounted battery pack and traction motor drive for driving the wheels. Compare to conventional ICE vehicles this layout is simple and efficient. A lesser number of rotating parts means there are lesser possibilities of parts damage due to wear and tear and hence the system life is higher. This is one of the reasons Battery Electric vehicles are claimed to have higher life as well as OEMs offers longer warranty period. However, electric vehicles are having other challenges like higher speed, higher operating temperatures of parts, and risk of fire due electric system. It is important to mention here that batteries used in electric vehicles need proper cooling to operate at prescribed temperature limit to have extending time for battery discharge as well as minimizing other risks.
\nTypical full battery electric powertrain layout [4].
Refer Figure 4, which is indicating the battery packs construction in battery electric vehicles and its stacking, connection to electric motors.
\nTypical battery pack in battery-electric powertrain [5].
In the previous section, two main types of the modern powertrain are discussed i.e. hybrid power train and full battery-electric powertrains.
\nIn this section, a comparison of different types of powertrains is presented (refer Figures 5–7).
\nBattery electric vehicle powertrain.
Multiple parameters influence the selection of the powertrains types to implement in the vehicle such as vehicle operating range, power requirements, charging time, cost, availability of access to charging infrastructure, etc.
\nBattery electric vehicles powertrains (refer Figure 5) are comparatively simples in the structure. These vehicles operate very efficiently. However, they need significant time for the recharging so the vehicle will be down until it recharges. It is expensive to increase vehicle travel distance range mainly due to battery prices.
\nA hybrid power train (refer Figure 6) utilizes the current powertrain configuration and adds the battery/emotors to enhance the performance of the powertrain as well as extend the operating range by improving the fuel efficiency of the internal combustions’ engine. It does not require an exclusive charging infrastructure as it primarily runs on fossil fuels. However, this powertrain does have emission-related concerns and having more number of rotating parts makes the powertrain complex due to effective management of dual power sources is essential optimum performance.
\nHybrid electric powertrains (HEV).
Practically, environmental impact due to fuel should be considered from well to tailpipe or from the source of raw material to conversion into power for vehicle propulsion. Considering this criterion battery vehicles are not completely emission-free vehicles. In a true sense, fuel cell vehicles (refer Figure 7) are practically green vehicles as they are not emitting any emission to the environment. Fuel cell powertrain uses hydrogen as prime energy source and utilizes chemical reactions process to charge the battery. Post electric energy conversion hydrogen atoms react with oxygen and forms water (H2O) which gets emitted from the tailpipe. Battery electric vehicles and fuel cell vehicles are having similar configurations except in addition to battery storage the fuel cell vehicles also require hydrogen fuel storage.
\nFuel cell vehicle powertrain.
Conventional ICE automatic transmission [6].
All the modern powertrains are available commercially, however, its penetration is driven by multiple commercial factors including acquisition cost, operation cost, and ease of re-charging (refueling). All these modern powertrain configurations uses multiple types of bearings in the powertrain including deep groove ball bearings, needle roller bearings, special ceramic rolling element bearings with many other features to provide intended functions in the vehicles which are discussed in the following sections.
\nIn modern powertrain, bearings are utilized not only for primary functions i.e. supporting the load and reducing the friction but also bearings are used with multiple other integrated functions like signal transmitting device on the motor, rotor positioning sensing bearings, etc.
\nIn conventional powertrain bearings, functions are limited to its primary functions to support operating load on the shaft and facilitate the torque transfer smoothly.
\nAdditional functions like lower the noise, the vibration of the system, and providing stiffness to the shaft system are few of the expected functions of bearing in the powertrain.
\nHowever, modern powertrains are having different requirements from the bearing considering constrains like lower weight, space as well as demanding operating conditions includes higher temperatures, speeds, inability to lubrication as well as longer service intervals, or no service for the design life of the system. The role of bearing is changing in modern automobiles. This demanding operating requirements putting immense pressure on bearing performance and achieving the desired specifications of the bearings. The role of bearing is moving from shaft support component to system solution to achieve multiple performance parameters in the intended aggregates. Bearing plays the role of catapult for the system health monitoring utilizing the vibration signature on bearing for identifying, predicting, and proactively preventing the potential breakdown of the system. The modern electronics hardware and miniaturization of the sensors facilitate integration pf the same with bearing to achieve many other intended functionalities.
\nBattery electric powertrains run at higher rotational speed and having a higher operating temperature. Being an electric system ensuring the lubrication to rotating parts is one of the major challenges. Hence, maintenance-free silent operation is one of the critical technical requirements for the bearings. The bearing design must fulfill the criteria of high-speed operation, lower NVH characteristics, high-performance lubrication, and robust sealing to retain the lubrication inside the bearing as well as protecting the bearing raceways from foreign contaminations.
\nModern powertrains, particularly motors operates at a higher rate of acceleration as well as decelerations and to facilitate the same bearing design should be capable to handle the acceleration requirements. Inappropriately design of bearings can experience the functional as well as reliability issues in the system which may leads to system breakdown or reduced life the powertrain or also invite unwanted services of the system.
\nBearing load carrying capacity is required to be higher considering the higher power of the prime movers and availability of less space due to lower weight expected from the system. The design of bearing from geometry, material selection, and manufacturing process plays a critical role to achieve higher load carrying capacities in smaller envelope dimensions. The reduced the size of bearings facilitate lower overall system weight.
\nBearings are playing a mission-critical functions in modern automotive powertrains. A deeper understanding of applications and expected functionalities play a crucial role to design of appropriate bearing for the modern automobile systems.
\n\nFigure 8 illustrates the internal combustion engine vehicles’ conventional transmission. It can be observed that bearings in this transmission are having comparatively different technical requirements. The bearings are well lubricated, having comparatively lower speeds of operation.
\n\nFigure 9 is one of the EV power train configuration of modern electric vehicle transmission. Compare to conventional IC Engine vehicles the transmission layout is simpler in modern electric automotive vehicles. However, technical specifications and performance requirements of bearings are demanding.
\nTraction motor EV powertrain.
Application and intended function in the aggregate is having an influence on the selection of bearings as well as on the performance of bearing. It is important to understand the bearing working environment, technical requirements, and application details for optimizing the performance [7]. Different aggregate applications are having different technical requirements that need to be fulfilled by bearing for optimum performance of the system. In this section, different aggregate and technical requirements of bearing in these aggregates are discussed,
\nAutomobile transmission facilitates speed and torque variation as per vehicle requirements and support engine to run in optimum performance range. The transmission system is having gears, shafts, shift system, and bearings arranged in the housing which perform speed and torque variation function together in coordination with the control system.
\nTransmission bearings are having multiple requirements to achieve the desired functions, some of them are mentioned below,
\nTransmission bearings experience combined axial and radial loads during the operation based on types of gears as well as shaft arrangement. The magnitude of the load depending upon the bearing position, gear arrangement, and torque transmission. The transmission bearings must be capable of handling these varying speeds and loads.
\nVehicle powertrains are becoming compact due to the availability of space and emphasize on the reduction of the overall weight of vehicles. Power dense bearings that are capable to carry higher loads in a smaller size are the key selection criteria of bearings for modern transmission. Power density for the bearing is achieved with the usage of better material cleanliness from commonly used bearing materials like 100Cr6, 52100 with stringent specification of nonmetallic inclusions, oxygen content etc., optimized geometry, and precise manufacturing of bearings. It is worth mentioning here that each bearing manufacturer are having its own material specifications customized based on common bearing material chemistry. Most common bearing materials are SAE 52100, DIN 100Cr6, SUJ1, SUJ2 and many more.
\nSystem efficiency is largely influenced by friction. Bearing contributes to the transmission system largely. Generally, Sealed bearings are having more friction compared to open bearings. Transmission bearings selection must have consideration of the friction.
\nModern automobiles particularly battery electric vehicles operate quietly. In the case of ICE, the engine noise suppresses some of the bearing noise, however, in modern automobiles bearings, noise is one of the major concerns. It is expected bearings with lower noise are implemented in the transmission system. In addition to noise, vibration and harshness are also to be given due consideration for the transmission bearings.
\nAutomobile manufacturers specify the system level NVH requirements and typically bearing noise requirements are derived from system level requirements. However, very few manufacturers are having clearly defined NVH specifications for bearing. It is common practice in bearing industry to specify the bearing vibration level and measure at the end of the bearing assembly line. Each bearing manufacturer is having its specification for noise quality level of bearing. Low dB, Gen C, Q44 and other bearing manufacturer internal nomenclature of bearings quality classes have been developed and specified accordingly [8]. Low-frequency noise is barely audible while high-frequency vibration does not audible to human ear. Hence noise problems at low frequency are categorized as “vibration problems” and at high frequency vibration are as “noise problems”. As a rule of thumb, the arbitrary border separating vibration problems from noise problems is 1000 Hz. In other words, below 1000 Hz is vibration and above 1000 Hz is considered as sound or noise [8].
\nModern automobile transmissions are expected to be assembly and disassembly friendly considering the automation of the manufacturing process. Complex adjustment during bearing assemblies also calls for a complex assembly process, higher assembly time which increases the overall manufacturing process complexity as well as capacities.
\nIt is expected the bearings implemented in the transmission systems are assembly as well as disassembly friendly. Most suitable bearings need to have a minimum or no adjustment during the assembly.
\nLower viscosity lubricants with multiple other additives and chemicals are used as lubricants of the transmission for the reasons like reducing the churning losses in the system etc. However, lubricants in the system having influence on the bearing selection and bearing must be suitable to operate and compatible with lubricants in the transmission. Additionally, the sealed bearing application is also common in modern transmissions, so compatible seal material should be selected to avoid damage or performance issues.
\nBearing field issues analysis over the years suggests that external contamination, poor lubrication, and abusive operating conditions are major reasons for premature bearing failure. However, in modern powertrains, it is expected that bearing manufacturers should consider these conditions and develop bearing suitable to operate or having better capabilities to handle these operating conditions.
\nA hybrid powertrain utilizes dual power sources and one of the prominent power sources is the internal combustion engine. The importance of engine is prominent even though electric battery-powered vehicles are penetrating its presence. Engine is one of the great innovations of our time and will be around for many reasons. It is expected that more than half of the vehicles will be transformed into electric, but still majority will be hybrid vehicles. Engine bearings are having some typical requirements and some of them are mentioned below,
\nThe engine converts chemical energy into thermal/mechanical energy via the fuel-burning process. The engine operates at elevated temperatures due to fuel burning. Engine bearings must have dimensional stability at elevated temperature in addition to other performance parameters. Bearing mounting and operating clearances are largely affected due to different materials and their expansion rates.
\nEngine loads and speeds are varying during the operation. Bearing kinetic should be considered for varying speeds and loads. Rolling bearings use on crankshaft and camshaft is increased in recent time. However, at the connecting rod end, needle bearings or journal bearing are commonly used in an engine for multiple reasons including varying load and speeds.
\nCrankshaft bearings are positioned bottom of the crankcase in the engine. The engine piston is reciprocating (sliding motion), so the wear of the engine part is not uncommon. However, wear particles are mixed in the oil contaminate the oil. Engine oil is the primary source of lubrication to bearings. The contaminated oil is having a negative influence on bearing operation and due consideration should be given to have good performance of bearing in this condition. Special heat treatment can be considered on the bearings rolling elements and raceways in such demanding operating conditions. Optimum ball pass frequencies selection is also important to ensure the hunting of rolling elements is not affecting the raceways or rolling element.
\nEngine bearing mounting and dismounting is one of the important considerations, not only from a service, assembly perspective but also from the operational performance perspective. Appropriate fits must be applied to the bearing to ensure bearing is loaded and operates in favorable clearance zone. Wrong selection of fits can lead to catastrophic damages to bearing with prolonged use.
\nBattery electric vehicles are using motors as prime mover of the vehicle. Hybrid powertrain vehicles are also uses motors to propel the vehicle. Traction motors used in vehicles are having many special technical requirements that are different from conventional motors.
\nSome typical requirements are discussed in the following session,
\nTraction motors bearing arrangement plays an important role in bearing selection. In most of the traction motors application two bearing arrangement (drive and non-drive end) is preferred. However, integration of transmission and motors is also common practice in electric powertrain due to which three inline bearings arrangement is also implemented.
\nThe bearing arrangement adds complexity to the overall bearing system and the need for the appropriate distribution of bearing loads. Comparatively, two bearing arrangement is simple compare to three bearings arrangements.
\nThe traction motors that drive vehicles are required to run at very high speeds – up to 30,000 rpm, or almost three times the speed of the typical industrial motor. This high-speed operation places enormous strain on the bearings in the system. High-speed operation of bearing calls for special raceway geometry as well as separator designs to handle the additional centrifugal forces.
\nIn the conventional system, lubrication oil dissipates the heat from the system and ensure the specific operating temperature. However, in electric motors heat dissipation is done via a cooling fan. Additionally, bearings are running at high speed, so the heat generation rate is higher hence the operating temperature. Motor bearing with seals and grease must have the ability to retain the lubricant inside the bearing at elevated temperature.
\nMotor bearings are expected to operate at lower noise and lower vibrations. This is one of the key requirements for the motor bearings considering the high speed of operation, varying loads, and acceleration.
\nMotor bearings are expected to be maintenance free so the grease selection, seal selection plays a major role in bearings performance and life.
\nElectric motors are very responsive to vehicle operating conditions. Motors accelerate as well as decelerate faster compare to ICE. The bearings must be designed to handling this rapid acceleration as well as deceleration. Rolling element separators, raceways geometry should be designed appropriately. Rapid acceleration and deceleration generate sliding motion in the bearing which can lead to damage to bearing raceways or other surfaces. In extreme acceleration and deceleration conditions, may result in catastrophic bearing damage or malfunction of bearing.
\nPresent bearings are made up of bearing steel material which is good conductor of electric current. In electric motor current passed though the bearing for any reason is detrimental to bearing function. However, motor feature that can affect conventional steel bearings is the high-frequency voltage switching of the inverter that produces current leakage, particularly at high motor speeds. This current leakage can pass through the bearing and causes, surface damage like surface pitting also called fluting. The initial stage of surface damage generates bearing noise, but the advance stage of surface damage can be catastrophic.
\nFront End Accessories Drive (FEAD) system is a combination of multiple subsystem drives in the vehicle for the purpose like air condition compressor drive or alternator drive etc. The system requires basic requirements like axial and radial loads, static load carrying capacity, dynamic load-carrying capacity, speed, or rpm. However, the FEAD system requirement range beyond basic load-carrying capacities. Modern automobiles are expected to provide more comfort, steering pumps and air conditioner compressors have been added to the FEAD system in addition to alternator or BSG system. Modern automobiles are using comparatively more electronics parts/system operates using electricity which are rising the battery charging capacity. The charging capacity of alternators has increased its size, accordingly, leading to a rise in the amount of torque to be transferred to alternators. The increased torque transfer demands from higher load capacities for the FEAD system bearings.
\nBelow are few technical requirements of FEAD system bearings,
\nFEAD systems are running at higher speeds like alternators are running in excess of 20000 rpm, the bearing must-have capability to handle the system increased speed. Additionally, the tendency of the engine running at a slower idle speed is also implying bearing selection due to extended time slower speed operations.
\nAcceleration and deceleration handling requirements coming from higher system speed, variation in loads.
\nLower friction is a common requirement for all the modern automobile system bearings that are also applicable for FEAD system bearings.
\nHigher emphasis on the compact and lower weight of the system demands for lower size of the bearing with a higher load-carrying capacity.
\nHigher operating temperature due to proximity to the engine as well as higher operating speed requires bearings seals, lubrication as well as dimensional stability at the higher operating temperature. The alternator bearings are expected to work at 180 to 200 Deg C temperature.
\nMaintenance-free operation is predominantly driven from no lubrication to bearing for life and sealing performance. The seals should be capable of running for the life of the vehicle and retain the lubricant inside the bearing.
\nThe wheel bearings enable low-resistance rotations of the wheels by transferring axial and radial forces and support for wheel hub, wheel, and brake disc or brake drum. In modern automobiles, the wheel bearings are equipped with sensors that send rotational speed signals to driver assistance systems like ABS, ESP, etc. [9]. The wheel bearings perform multiple functions, some of them are listed below,
\nWheel bearing provides support to wheels, so rotation accuracy of bearing facilitates the guidance to the wheel. It is an important function for vehicle stability and control during operation.
\nWheel bearings are expected to have a lower weight. However, higher stiffness or rigidity requirement is an important consideration for wheel guidance and vehicle stability. As modern automobiles are having higher road speeds achieving safety of vehicle wheel bearings plays an important role.
\nUnbalanced wheel bearing adds the unsprung mass to the system which affects the vehicle driving dynamics. As the speed of the vehicle increases the unsprung mass becomes more detrimental from the driving dynamics perspectives.
\nWheel bearings are subjected to many unknown forces due to constant changing road conditions and speeds, corners, and other conditions. The wheel bearings must be capable of absorbing the external loads without affecting the performance.
\nIn operation, the wheel bearing is subjected to many unusual conditions like contact with mud, dirt, undulations, etc. However, in modern automobiles wheel bearing is expected to sustain all the working conditions without or with minimal need for maintenance. In addition to bearing design, lubricant and seal performance is an important parameter for long service life.
\nBearing should be stable in all aspects with all operating temperature ranges and perform as per the intended level. Temperatures can affect the preload of the bearing which can be detrimental for bearing performance.
\nAs mentioned in the transmission system section, modern manufacturing considerations like automatic assembly, less complex mounting to reduce the complexity in the assembly process as well as at service time (Figures 10 and 11).
\nThe steering system controls the direction of the vehicle, so the steering system bearings are having typical requirements to receive the feedback as well as facilitate the execution the operators’ intended command to operate the vehicle with minimum lag in the system.
\nSteering system bearing must have lower frictional torque for the system to be responsive.
\nHigher frictional torque adds operator fatigue as well as a slow response from the steering system which can influence the effective functioning of the vehicle control system.
\nSteering system bearing must have higher rigidity to enhance the system integrity as well as to achieve the system responsiveness and removing any sluggishness in the system.
\nAll the bearings should have a lower wear rate, however, the steering system bearing it is critical requirements. The higher wear rate of bearings calls for frequent system adjustments or malfunctioning of the system operation.
\nSuspension system bearing relates to comfort and vehicle stability. Suspension system bearing have some unique requirements are mentioned below considering other requirements are common with other bearings as well.
\nSuspension system bearings are connecting vehicle chassis with suspension/shock absorbers, so movement in response to road conditions should smooth.
\nSuspension bearing requires a self-aligning function considering the movement. It is expected that bearing should self-align without requirements of any additional external force for smooth operation.
\nSuspension bearings support and locate to shock absorbers so it should function to provide the full deflection of the shock absorber.
\nSuspension bearing connects the suspension system with the vehicle body so any noise or undulation coming from the system results in noise. The bearing should be capable to isolate such noise from the vehicle body. A non-metallic bearing body is one of the ways to achieve this function.
\nIn general, bearings play a significant role in vital aggregates to achieve the intended objective of modern automobiles. A deeper understanding of technical requirements and intended functions help bearing engineering to provide the most appropriate solutions which optimizes vehicle performance.
\n\nFigure 12 summarizes the requirements of bearings in modern automobiles and available options to achieve the same.
\nElectric vehicle transmission.
Refer to the discussions of the last section it can be observed that bearings requirements are driving trouble-free operations, longer service life, the lower total cost of ownership, compact construction, lower friction, noise, better sealing performance as well as integrated functions.
\nBearing engineers achieve these requirements in the right proportionately blending and integrating engineering know-how of different bearing materials, manufacturing processes like heat treatment, surface finishes, and geometries. Long service life functions are achieved with lubricants, better sealing in addition to optimized geometries and design parameters. Integrated functions and application-specific solutions make bearing versatile with few additional features to be used for multiple applications.
\nModern automobiles are improved by challenging the status quo as well as by adopting the technology changes to current level of performance. The modern automobiles are also empowering and enforcing bearings innovations and technological limits to further enhance the performance of the vehicles.
\nPatent filing data provide great insights about the innovation areas in the industry. In order to understand the bearing technology development focus areas patent analysis is performed on last 10 years of global patents filing in bearing area, modern automobiles. Figure 13 is a word cloud plot of 11,300 patents titles in bearing, modern automobiles areas filed in different global patent offices. The word cloud analysis provides quick insights into the analysis areas based on the frequency of keywords in the analysis data. It does not provide in-depth analysis; however, it is a good way of understanding the focus areas in technology development and the direction industry’s research is leading.
\nElectric vehicle transmission.
Rolling bearing and bearing assembly is an obvious appearing word in the patent title hence not considered for further analysis discussion (Figure 13).
\nBearing requirements and means to achieve in bearings.
Word cloud analysis pointing more research is being focused on electric motor bearings, bearing cage, sealing, anti-friction, fluid dynamics, lubrication (areas generally connected with the higher speed of operation), bearing steel, sintered bearing (areas indicating the material related research), motor control, sensors, active hub, load detection, level adjustment, abnormality detection (areas indicates the focus on bearing plus integrated functions like sensorization), camshaft, crankshaft, magnetic bearing, sealing devices, axial bearings (indicates areas of special bearing development, application-specific solutions development), special bearings in the current family of bearings also is the areas of technological research. Patent filing analysis is good indicator of the technology areas and direction.
\nInteractions with the automobile industry players are also summarized for connecting the technology focus areas with customer mandate or request for solutions. These areas can also be considered customer challenges, pain areas, or directions for the modern automobile development.
\nModern automobile powertrain and system customer’s voice is captured in two fundamental buckets i.e. must-have requirements (highly desirable) and good to have (differentiating) requirements.
\nHigh-speed bearings, high operating temperature, current insulations or conduction, lower friction bearings, power-dense solutions, and lower noise, vibration, and harshness (NVH) solutions are highly desired by automotive customers. However, long life, maintenance-free, better reliability, integrated functions, condition monitoring, sensor bearings, lower weight bearings are considered as differentiating features.
\nPatent analysis and modern automobile customer’s voices are having a high level of similitude to interpret that bearing technology development customer requirements are indicating future development trends for the bearing. The above analysis also indicates that bearings are playing a vital role in automobiles and will also play a vital role in modern automobiles in the future.
\nIn the previous section, it is mentioned that haptic requirements from bearings are fulfilled with blending the bearing constituents in different proportions. In this section, some of the key influencers are discussed which facilitate the bearing technology development as well as achieving the modern automobiles bearing requirements.
\n\nFigure 15 is a summary of different constituents of bearings is its influence on bearing requirement achievement.
\nBearing technology focus word cloud plot of patent analysis.
Typically, bearing materials are the backbones to achieve the bearings’ fundamental functions. Different grades of materials can be implemented based on the intended requirements of the application. Bearing materials also facilitate next processes like heat treatment, machining, and many other parameters.
\nHeat treatment of bearing is very important to achieve the next level requirements of bearing. Standard heat treatment also called through hardening is commonly used to all-purpose bearings. However, if the bearings are required to operate in the demanding operating conditions, appropriate special heat treatment can be considered to enhance the bearing utility to application.
\nBearing geometry plays a role in bearing friction, NVH, and different load handing areas. Bearings geometries need to be applied based on expected application requirements. Accuracy and functional requirement need to be well balanced to achieve economics.
\nLarge number lubricants are available based on application requirements. The right selection of lubricants and seals increases the bearing utility in the application. Many times, multiple application requirements can be achieved by applying suitable sealing/lubricant on the fundamentally same bearings (Figures 14 and 15).
\nModern automobile “Voice of Customers” for bearings requirements.
Means of achieving intended bearing functions for modern automobiles.
The left side of Figure 15, summarizes the special or application-specific functional requirement fulfilling means of bearings. Customization of bearings is addressing the exact application needs however, customized solutions make bearing special and expensive.
\nReliability improvement of bearing relates to bearing performance and service life in the actual application. Reliability improvement of bearing means increasing the mean time between failure of bearing.
\nBearing reliability can be improved by implementing special consideration to demanding operating conditions with special heat treatment, better materials, lesser intervention from the operator by unitized bearings, increasing wear resistance, implementing the better lubricants, tighter manufacturing tolerances.
\nBearing life can be increased by multifold by right selection of heat treatment like compare to through hardening heat treatment, case hardening heat treatment (CN) can give 2 to 5 times more life to bearing in contaminated working environment. In addition to base material bearings can be coated to increase resistance of bearing in specific working condition. Carbide based coatings are popular in some application, alumina material coatings are used for electrical insulations.
\nPower dense solutions related to more load carrying capacity per unit bearing size. As mentioned in the last sections, the bearings are catalysts to achieve a lower weight of the aggregate. Weight is the enemy for vehicle performance particularly in electric vehicles as it directly influences range as well as battery capacity. Lower size of bearings accumulates lesser space as well is makes the aggregate system compact. An additional advantage of power-dense bearing it utilizes lesser material, so it is also another means of achieving environmentally friendly solutions.
\nCurrent bearing material development and steel cleanliness is increase material mechanical properties. Additionally, manufacturing technologies increased control over the tolerances are enabling the power dense solution. Typically, 20 to 30% higher load carrying capacity can be improved within same envelope of bearings with right selection of material, geometries and manufacturing process including heat treatment.
\nIn recent times, frugal engineering is typically connected with terms like “more for less”. In this text, integrated functions can relate to frugal engineering and can be termed as “more functions per bearing”. Bearings can be attached with sensors and utilize for the position, speed as well as direction signals. Bearings are integrated with multiple functions like in new generation wheel bearings brake and wheel mountings are combined with bearings. Integrated bearing functions support compactness, reliability improvement, however, in some cases also adds complexity.
\nFriction optimization solutions are intended to achieve better efficiency, lower losses in the bearing. Type of bearing and depending upon the application requirements bearing friction level can be achieved with the manufacturing process and tighter specification controls. Generally, bearing friction is a function of multiple factors like internal geometry, type of seals, material, lubricant, and the rolling element grade. Kinetics of bearing also plays a role in achieving the optimum friction of bearing. Adjustment in assembly, preload requirements, and assembly process influence final friction behavior of bearing in the application.
\nLower friction of bearings directly contributes to wear performance as well as the efficiency of the system.
\n\nFigure 16 depicts the typical wheel bearing friction rate. Conventionally, vehicle manufacturers were assembling different parts together including bearings into wheel hubs. However, this arrangement is not effective considering the performance parameters. Hub 1 bearing is integration of two bearing into one, so it provides 10 to 15% better friction rate, Hub 2 is further improvement having integration of out race of bearing into housing and it provided 10 to 15% friction reduction compare Hub 1. Currently most of the modern automobiles are using Hub3 which are complete integration of bearing and wheel mounting.
\nTypical wheel bearing friction rate.
This arrangement provides 50 to 60% friction reduction compare to conventional arrangements and additional 10 to 12% improvement compare to hub 2 arrangement.
\nModern automobiles are targeting maintenance-free or maintenance less and fit for life reliable systems. Bearing sealing and lubrication solutions play a vital role in the achieving maintenance and reliability target of the system. Type of sealing (seal material, geometry, type of contacts, etc.) and lubrication selection for the bearing directly affect the bearing performance in operating conditions like temperature, speed, and friction. Good sealing on the bearings also increases bearing resistance to operating condition likes keeping the contaminations out of bearing raceways. Sealed bearings are not only maintenance-friendly but also environmentally friendly too.
\n\nFigure 17 depict the importance of capping (sealing) type in the bearing. Non-contact type of capping is good when bearing need to contain the lubricant like grease into the bearing with fair protection against exclusions, however, contact types of seals gives excellent protection against exclusions as well as retention of lubricants. Low contact capping compromise based on application requirements. However, all these capping is having impact on power loss or additional friction in the system. Non-contact type of capping gives lowest power lost among the all the capping types. Contact type capping is having highest power loss compare to both the non-contact and contact type capping. Typically, low contact type seals are having 30 to 40% higher power lost compare to non-contact type. Contact type capping is having 35 to 45% higher power lost compare to low contact type capping and about 70 to 80% higher power loss compare to non-contact type capping.
\nComparison of different type of capping and power loss.
Modern automotive uses of electronics are increasing for vehicle control as well as operator comfort purposes. Vehicle control systems primarily need feedback from various systems which required sensor. Sensors are typically mounted on or around the critical rotating parts, hence sensors integrated bearings are a natural good choice for reliable signals. It is already proven that in rotating system’s generate unique vibration signatures on the support bearing. These unique vibration signals can be processed electronically for multiple vehicle systems health monitoring via sensors. Sensor bearings provides better location as well as the accuracy of the signal for different feedbacks like speed, load, temperatures, etc. for effective vehicle monitoring. The miniaturization of sensor technology is an opportunity for the integration of bearings and sensors for modern automobile sensing needs.
\nAbove bearing technology focus areas are covering major areas of eMotor bearings as well. However, some special requirements like current leakage and performance of bearing need special mention in this section (Figure 18).
\nModern automotive eMotor challenges.
High-frequency current passing through the bearing is detrimental for the bearing performance and there is a high probability of current leakage in eMotor bearings. If the current passed through the bearing generally results in “fluting” or micro pitting on the bearing races and start generating noise. The continued running of the bearing in this condition may encounter catastrophic damage. Bearing with special electric insulation coating, special materials for the rolling element (e.g. Ceramic) are developed and also under development for mass vehicle adoption by lowering cost. In addition to electric current insulations, technology development is also focused on electrical conduction solutions so the leakage current can be bypassed from the rolling area.
\nModern Automobiles technology is transforming to enable “connected, autmonomous, shared and electric (CASE). Modern automobile powertrain development is focused on higher efficiency, maintenance free (higher reliability), compactness, light weight and autonomous control using mechatronics capabilities. New generation powertrains utilize lighter materials, lesser number of components and integrated fuctions to achieve these objectives. Battery electric powertrains, hybrid power trains and hydrogen fueled fuel cell technologies are becoming popular in modern automobiles. Bearings are one of critical component (sub-system) to achieve modern powertrain’s demanding technical requirements. It is imperative to bearing engineers to understand critical technical requirements of modern automobiles aggregates functions and bearing performance expection. Understanding aggregate performance and expected bearing technical requirements facilitate optimized solution development. Bearing plays crucial role in enhancing efficiency, integrating the functions, facilitate the compactness to achieve the lightweight powertrain. Bearing technology development focus area concentrating to addressing the modern powertrain’s requirements. Bearing technology research and development areas focused on reliability improvement, power dense solutions, integrated functions, friction optimization, sealing/lubrication solutions, adoption of sensors and special application specific eMotors bearings. In addition to primary functions of bearing with the help of modern electronic technologies bearings are performing critical role of overall system health monitoring in the vehicle.
\nBearing research is typically aligned to applications requirements and trends of the machine’s technology. Modern automobiles are focusing more of passenger comfort with focus on autonomous driving, connected vehicles and electrification of vehicle. These technological requirements pushing bearing research more on sensorization, lower noise, vibration and harshness in addition to reliability improvement, maintenance free operation and application specific solutions. Bearing noise is one of the key concerns in modern powertrain specifically in electric drive trains. Bearing technologist are focusing on this aspect more than ever before. The bearing noise is directly connected to passenger comfort as well as overall system health. Bearing noise is also indication of system health as the issues with any part in the chain directly reflect to bearing vibrations. Leading bearing manufacturers are focusing on the sensor bearing technology as this feedback from vehicle critical parts is key to autonomation of modern automobile vehicles. Chronologically bearing research focus is more on application specific solutions, sensorization, maintenance operations. At system level bearings research is also focused on the “connected vehicle technologies” using on-board diagnostic using vibration signature identification capabilities at the bearing.
\nHowever, bearings are having furthermore potential to contribute and enhance role in modern automobiles in future. Future bearing technologies will focus more on the “bearing as a service” than typical product. Bearing as a service includes ability to collect the data, process the data and transfer the data for better understanding of vehicle dynamic behaviors. In modern automobiles bearing role will be second to electronics. The miniaturization of electronics complements to bearings utility exploitations and expansion to bearing space for additional functionalities. In modern automobiles the role bearings are as important and vital as the electronics considering potentials bearings provide for further integration and research.
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