Typical values of parameters of fine particle plasmas.

## Abstract

Beginning with typical values of physical parameters, basic properties of the system of fine particles (dusts) in plasmas are summarized from the viewpoint of statistical physics. Mutual interactions and one-body shadow potential for fine particles are derived, and, by analytic treatments and numerical solutions of drift-diffusion equations, it is shown that one of their most important characteristics is the large enhancement of the charge neutrality in fine particle clouds. This observation leads to simple models for the structures of fine particle clouds under both microgravity and usual gravity. Due to large magnitudes of their charges and relatively low temperatures, fine particles are often in the state of strong coupling, and some interesting phenomena possibly expected in their system are discussed with concrete examples. Also reviewed is the shell model, a useful framework to obtain microscopic structures in strongly coupled Coulomb and Coulomb-like systems with specific geometry.

### Keywords

- interaction and one-body potential
- drift-diffusion equations
- charge neutrality enhancement
- cloud models under microgravity/gravity
- strong coupling
- shell model

## 1. Introduction

Fine particle (dusty) plasmas are weakly ionized plasmas including fine particles (dusts) of micron sizes [1, 2, 3, 4, 5]. As the gas species, inert gases such as He, Ne, Ar, etc. are usually (but may be not exclusively) used: one of the reasons is that various phenomena can be analyzed without considering chemical reactions including neutral atoms or ions and values of physical parameters are mostly known or easily estimated. To generate plasmas, the rf or dc discharge is used, and fine particles are intentionally added by particle dispensers in most cases. In this chapter, fine particles will be referred to simply as “particles.”

As for experimental observations, particles of micron sizes scatter laser beams, and their orbits are easily followed, for example, by ccd cameras. In addition to the importance of (often not welcome) effects of the existence of particles in reacting plasmas applied in semiconductor processes, the relative easiness of observation might be one of the motives of investigation.

Particles immersed in plasmas obtain negative charges of large magnitudes: the thermal velocity of electrons is much larger than that of ions. Even though the interaction between particles are screened by surrounding plasma (composed of electrons and ions), particles are sometimes mutually strongly coupled, and many phenomena in strongly coupled Coulomb or Coulomb-like systems are expected to be observed.

From the viewpoint of statistical physics, systems of particles resemble the Coulomb system with the charges of definite (negative) sign, the screening of charges by surrounding plasma being the most important difference from the pure Coulomb systems. The mutual interaction between particles is approximately given by the Yukawa or the screened Coulomb potential. The one-component plasma (OCP) is a typical model of Coulomb systems composed of charges of definite sign where the inert charges of opposite sign (the background charge) neutralize the particle charges. In fine particle plasmas, particle charges are screened and, at the same time, neutralized by the surrounding plasma.

Compared with electrons and ions, particles have macroscopic masses, and the gravity on the ground has significant influence on their behavior. In order to observe their generic properties, the experiments in the environment of microgravity have been and are performed on the International Space Station (ISS) as PK-3Plus and PK-4 Projects [6, 7].

The main topics in the statistical physics of fine particle plasmas may be the following:

Charging of fine particles

Interaction between particles and their microscopic structures

Behavior of electrostatic potential under the existence of particles

Effect of gravity

Simple models of fine particle clouds under microgravity and usual gravity

Effects of strong coupling

In what follows, we will discuss them as much as possible within a limited space.

## 2. Typical values of parameters

Here we show some typical values of important parameters related to fine particle plasmas discussed in this chapter. They are summarized in Table 1.

Quantities | Notation | Values |
---|---|---|

Electron density | ||

Ion density | ||

Electron temperature | ||

Ion temperature | 300 K | |

Fine particle size | 1 μm | |

Fine particle density | ||

Fine particle temperature | 300 K | |

Neutral gas pressure | ||

Neutral gas temperature | 300 K |

Since we have weakly ionized plasmas, the density of neutral atoms is much larger than that of electrons, ions, or particles. The neutral atom density

is to be kept in mind in considering phenomena in fine particle plasmas. It is sometimes necessary to take the effects of collisions between neutral atoms and electrons and ions into account: the collision cross section

The neutral gas is considered to be at room temperature. The temperature of electrons *Te* is often measured or reasonably extrapolated from the discharge conditions. As for the ion temperature *Ti*, on the other hand, we usually do not have measured values and implicitly assume it to be around room temperature. There exist experiments where the velocity of the ion motion suggests higher temperatures. Most of experimental results, however, seem to be compatible with the above assumption. It may be also justified by frequent collision with neutral atoms. The temperature of particles *Tp* can be measured by monitoring their motion, and the latter sometimes indicates rather high temperatures of even eVs. We here assume, however, that particles are also at room temperature, attributing apparent high temperatures to some instability.

As will be shown in Section 1.4, charges on particles are screened by the plasma of electrons and ions with characteristic screening or Debye lengths: the electron Debye lengths

Since

The thermal velocity of electrons

## 3. Charging of fine particles in plasmas

The charge on a particle

From the analysis of electron and ion currents, we have

where *z* is determined by

Here the first and second terms in [ ] on the right-hand side are given by the orbit-motion-limited (OML) theory [8, 9], and the third term is the effect of ion-neutral collisions,

## 4. Mutual interaction and one-body potential in fine particle system

In the system composed of the electron-ion plasma and particles, we are mainly interested in the latter and take statistical average with respect to variables related to the former. Such a treatment of the uniform system was given previously [11, 12]. For systems of particles in plasmas considered here, however, the effects of nonuniformity are of essential importance. The corresponding inhomogeneous system has been analyzed, and mutual interactions and the one-body potential have been obtained [13]. In the process of statistical average, the importance of the charge neutrality of the whole system is pointed out. The main results are summarized below.

Since the thermal velocity of particles is much smaller than that of electrons or ions, we adopt the adiabatic approximation and regard configurations of particles as static. Under the conditions of fixed volume and fixed temperature, the work necessary to change the configuration of particles (the effective interaction) is given by the change in the Helmholtz free energy of the electron-ion system [14]. The effective interaction energy

Here,

and

The (microscopic) particle charge density *e* and − for *i*)

and have

where

with the screening parameter evaluated at the midpoint

We expand

where

The electrostatic energy is written as

From (18) and (20), we have finally

The last term of (21) is rewritten as

The first two terms on the right-hand side of (22) reduce to the mutual Yukawa repulsion and the free energy stored in the sheath:

and the Helmholtz free energy is finally given by

The averages

describe the Helmholtz free energy for a given configuration of particles

can be regarded as the Yukawa potential at *shadow* to *particles are mutually interacting via the Yukawa repulsion and, at the same time, confined by the attractive potential due to the shadow charge density*

The last term in (24) and (25), the free energy stored in the sheath around each particle, works as a one-body potential for particles: this is called the polarization force [15].

## 5. Description by drift-diffusion equations

In Section 4, we have derived the effective interaction and the one-body *shadow* potential for particles. The behavior of average densities can be analyzed on the basis of the drift-diffusion equations [16, 17]. Here we derive average densities of electrons, ions, and particles and determine the one-body potential for particles [18, 19, 20, 21] which enables microscopic simulations of fine particle distribution.

For densities

where

Here

with the temperature of each component,

### 5.1 Microgravity

We first neglect the gravity or consider the case under microgravity [18]. Examples of solutions of drift-diffusion equations are shown in Figure 1 where we assume the cylindrical symmetry expecting applications to discharges in cylindrical tube. The main results are:

The charge neutrality is largely enhanced in fine particle clouds.

The ion distribution compensates the negative charge of particles.

The electron distribution is not sensitive to the existence of particles.

The enhancement of the charge neutrality is shown also analytically [23]. We obtain the condition for the formation of voids around the center: voids are formed when the electron density is high and the neutral gas pressure is low and the radius of particles is large. The critical density is given approximately by [18]

### 5.2 Gravity

In the case under gravity, we have the same equations, but the effect of gravity is to be taken into account for the force on particles [20, 21]. The distributions do not have symmetries even in cylindrical discharges. Here we assume the one-dimensional structures: the assumption is applicable to the case under gravity at least at the central part of the distributions. Examples of solutions are shown in Figure 2 [20, 21]. We also observe the large enhancement of the charge neutrality as in the case of microgravity. The enhancement is derived also analytically [24].

## 6. Enhancement of charge neutrality in fine particle clouds: application to models

In clouds of particles, we have largely enhanced charge neutrality as in Figures 1 and 2, shown by numerical solutions of the drift-diffusion equations and analytically [18, 20, 21, 24]. This observation enables us to construct simple models of particle clouds in plasmas. The charge neutrality in the domain of fine particles’ existence was noticed previously [25, 26, 27] but first established as one of the most important characteristics in particle clouds by our analyses.

### 6.1 Microgravity

In cylindrical fine particle plasmas under microgravity, particles gather around the center where the potential is maximum. Based on the enhanced charge neutrality in particle clouds, we are able to derive a relation between the radii of particle cloud and of the discharge tube from the boundary conditions of the potential. As shown in Figure 3, the cloud radius increases with the tube radius, and there exists a minimum of tube radius for the existence of the central cloud [23].

### 6.2 Gravity

In the case under gravity, we have a structure shown in the upper panel of Figure 4. In this case, the thickness of particle cloud is related to that of whole plasma as shown in the lower left panel, and the center of the cloud is located under the center of the whole plasma as in the lower right panel [24].

The result under gravity is extended to the case where we have multiple species of particles as shown in Figure 5. We have stratified clouds in the order of the charge/mass ratio, and the spacings are expressed by simple formulae [28].

## 7. Example of numerical simulations

For microscopic structures of Coulomb or Coulomb-like systems, there have been developed various theoretical methods including the ones applicable to inhomogeneous cases. Once the interaction and the one-body potentials for particles are established, however, numerical simulations of particle orbits may be the most useful. Their charges being screened by surrounding electron-ion plasma, particles mutually interact via the Yukawa repulsion. Since their charges are of the same (negative) sign, the system naturally tends to expand if we have no confinement.

In the case of infinite uniform system, one usually confines particles implicitly by imposing the periodic boundary conditions (with fixed volume). The number of particles being also fixed, we have effective background of smeared-out Yukawa particles with the opposite charge.

The necessity of confinement becomes clearer when one simulates finite and/or inhomogeneous systems. We here emphasize that, as shown in Section 4, particles are actually confined by the *shadow* potential corresponding to the average density of particles which, in principle, is to be determined self-consistently with the distribution of particles. It is also to be noted that, in addition to the *shadow* potential, there may exist additional external one-body potential, depending on experimental setups. In most cases, however, some kinds of parabolic confining potential or the *shadow* potential for the expected average distribution have been assumed, and its self-consistency has not been rigorously achieved.

### 7.1 Microgravity

Under microgravity, we may assume simple symmetries of the system coming from the geometry of the apparatus. The cylindrical symmetry is one such common example.

From the result of the drift-diffusion analyses, we expect the formation of clouds of fine particles around the symmetry axis. In the cloud, we have almost flat electrostatic potential due to enhanced charge neutrality in clouds. Microscopic structure of particles in the cloud can be obtained by numerical simulations.

Before drift-diffusion analyses, microscopic structures have been analyzed by assuming the *shadow* potential corresponding to the uniform distribution of particles [29]. This shadow potential is not exact but almost identical to the real one. The assumed uniform average distribution and the shadow potential are shown in Figure 6.

At low temperatures, particles take shell structures as shown in Figure 7, and these structures are expressed by simple interpolation formulae [29]. One may almost justify *aposteriori* the *shadow* potential corresponding to flat average distribution which was assumed in advance of the analysis given in Section 4.

### 7.2 Gravity

Examples of the potential under gravity are given by drift-diffusion analyses shown in Figure 2 [20, 21]: potentials (not shown in figures) correspond to the almost charge-neutral density distribution in particle clouds. Microscopic distribution of particles has been simulated by assuming the *shadow* potential given by the drift-diffusion analysis as shown in Figure 8 [20]. In this case, parameters approximately correspond to the case shown in the left part of Figure 2, and particles are organized into two horizontal layers.

Though the *shadow* potential has to be determined self-consistently, there may be the case where particles are vertically confined by a given potential: with the effect of the gravity, we may assume a one-dimensional parabolic confining potential. In this case, the structure of particle cloud at low temperatures is determined by the relative strength of the confinement and the mutual repulsion:

At low temperatures, particles form horizontal layers, and the number of layers is shown in a phase diagram in Figure 9 [30]. Parameters characterizing strengths of confinement

Note that the mean distance

Results of simulations are reproduced by the shell model to a good accuracy (see Appendix).

## 8. Aspects as strongly coupled system

The system of particles with the Yukawa mutual interaction

has long been explored as a model which interpolates systems with the short-ranged and long-ranged interactions [31]. Since particles of the same charge repel each other, the existence of the uniform *shadow* potential is (often implicitly) assumed. There are three phases at thermal equilibrium: fluid, bcc lattice, and fcc lattice. The parameters

*shadow* potential coming from the uniform average particle density is automatically built in.

When the coupling parameter *shadow* potential without any cost of energy. In reality, we have the surrounding plasma which has positive pressure of sufficient magnitude, and these negative pressures usually cannot be observed.

In fine particle plasmas, the magnitude of particle charge can become very large, and we have a possibility of negative pressures and divergent isothermal compressibility of the whole system including the surrounding plasma [32]. As physical phenomena, the latter is very interesting, and the corresponding conditions have been predicted [33]. An example of the phase diagram is shown in the left panel of Figure 11. Here

Along these considerations, the enhancement of long wavelength fluctuations of density has been expected in the PK-3Plus experiments on ISS, but, since the nonuniformity of the system (particle cloud) gives similar behavior of the fluctuation spectrum, the results have not been conclusive.

## 9. Conclusions

In this chapter, we have discussed important aspects of fine particle systems immersed in fine particle (dusty) plasmas from the viewpoint of basic physics. We have introduced them as an example of many body system, which allows direct observations of orbits of constituent particles. Mutual interactions and one-body potential for particles are derived on the basis of statistical mechanics, and the enhancement of charge neutrality in fine particle clouds is emphasized as a basis for constructing models of structures. Due to large magnitudes of fine particle charges, these systems have a possibility to manifest some interesting but not yet observed phenomena related to the strongly coupled Coulomb or Coulomb-like systems. They are also discussed with concrete examples.

Fine particles show various interesting dynamic behaviors which are not included in this chapter of limited space. From a theoretical point of view, we would like to stress the importance of understanding the structure of the electrostatic potential and distributions of electrons and ions which are usually not directly observable but are playing a fundamental role to determine the visible behavior of particles.

## Acknowledgments

The author would like to thank organizers/participants of series of Workshop on Fine Particle Plasmas supported by the National Institute for Fusion Science (NIFS), Japan, for useful information exchange. For discussions, he is also indebted to Dr. K. Takahashi, Dr. S. Adachi, and the members of the previous ISAS/JAXA Working Group of dusty plasma microgravity experiments (supported by Japan Aerospace Exploration Agency). In relation to the PK-3Plus project, thanks are due to members of the Max Planck Institute for Extraterrestrial Physics (MPE) and Joint Institute for High Temperatures (JIHT, RAS), especially to Professor G. Morfill, Dr. H. Thomas, and Professor V. E. Fortov, including the late Dr. Vladimir Molotkov.

When the temperature is sufficiently low, particles are organized into some kind of lattice structures. In the case of uniform system, it is not difficult to determine the structure with the lowest energy. When the symmetry of the system is restricted by the geometry of boundary conditions, however, it is not so easy to determine the lowest energy state theoretically. For Coulomb or Coulomb-like systems, the shell model which has been first proposed for the structure analysis of ions in traps [34] is known to reproduce low-temperature structures to a good accuracy [35].

This model consists of three steps:

Assume that particles are organized into a collection of two-dimensional systems (generally not-planar sheets) which are in accordance with the symmetry of the system.

Calculate the energy taking the cohesive energy in sheets into account.

Minimize the energy of the system with respect to all parameters, the number of sheets, number densities in the sheets, and positions of sheets.

In the above steps, the consideration of the two-dimensional cohesive energy is essential: without its contribution (which have a negative contribution of magnitudes increasing with the density in sheets), we have infinite number of sheets with infinitely low density at the ground state. We can reproduce numerical simulation or real experiments in the cases of Coulomb system in a cylindrically symmetric confining potential [34], Yukawa system in a one-dimensional confining potential, [30] and Yukawa system in a spherically symmetric confinement (Coulomb ball) [36, 37, 38].

An example of three-dimensional confinement by the *shadow* potential corresponding to uniform average distribution is shown in Figure 12 [36, 37]. The case of four shells is in agreement with the experiment [38], and simulation results are reproduced by the shell model to a good accuracy [37].

When the temperature is sufficiently low, particles are organized into some kind of lattice structures. In the case of uniform system, it is not difficult to determine the structure with the lowest energy. When the symmetry of the system is restricted by the geometry of boundary conditions, however, it is not so easy to determine the lowest energy state theoretically. For Coulomb or Coulomb-like systems, the shell model which has been first proposed for the structure analysis of ions in traps [34] is known to reproduce low-temperature structures to a good accuracy [35].

This model consists of three steps:

Assume that particles are organized into a collection of two-dimensional systems (generally not-planar sheets) which are in accordance with the symmetry of the system.

Calculate the energy taking the cohesive energy in sheets into account.

Minimize the energy of the system with respect to all parameters, the number of sheets, number densities in the sheets, and positions of sheets.

In the above steps, the consideration of the two-dimensional cohesive energy is essential: without its contribution (which have a negative contribution of magnitudes increasing with the density in sheets), we have infinite number of sheets with infinitely low density at the ground state. We can reproduce numerical simulation or real experiments in the cases of Coulomb system in a cylindrically symmetric confining potential [34], Yukawa system in a one-dimensional confining potential, [30] and Yukawa system in a spherically symmetric confinement (Coulomb ball) [36, 37, 38].

An example of three-dimensional confinement by the *shadow* potential corresponding to uniform average distribution is shown in Figure 12 [36, 37]. The case of four shells is in agreement with the experiment [38], and simulation results are reproduced by the shell model to a good accuracy [37].