Open access peer-reviewed chapter

Nanocomposite Material Synthesized Via Horizontal Vapor Phase Growth Technique: Evaluation and Application Perspective

Written By

Muhammad Akhsin Muflikhun, Rahmad Kuncoro Adi and Gil Nonato C. Santos

Submitted: November 9th, 2021 Reviewed: November 15th, 2021 Published: December 21st, 2021

DOI: 10.5772/intechopen.101637

Chapter metrics overview

109 Chapter Downloads

View Full Metrics

Abstract

The synthesis of nanomaterials has been reported by many researchers using different methods. One of the methods that can be used with perfect pureness and have less pollution in the synthesized materials results is the vapor phase growth technique (VPGT). Several types of nano shapes materials were reported such as nanoparticles, nanorods, nano triangular, nanosphere, and nanocrystal. The synthesis method has a fundamental process where the nanomaterials evaporated and condensed based on the temperature difference. There are three important variables, i.e., stochiometric ratio of source materials, temperature and baking time. The synthesis was occured in the quartz tube and sealed in the vacuum condition. This create the material was synthesis in pure and isolated conditions. The application of the nanomaterials synthesized via Horizontal Vapor Phase Growth (HVPG) can be implemented in anti-pathogen, anti-bacterial, gas sensing and coating applications.

Keywords

  • HVPG
  • synthesis nanomaterials
  • phase transition
  • anti-bacterial
  • coating
  • sensing applications

1. Introduction

Recently, nanotechnologies and nanoscience have raised high hopes for a new potential industry revolution [1]. They produced materials of various types at nanoscales [2]. Nanotechnology is commonly used in many applications such as in industrial, medical, agriculture, aerospace, energy, automotive, and food. Many researchers have conducted to explore the field of nanotechnology. They focus to obtain to get the best nanomaterials with optimal mechanical and physical properties [3, 4, 5].

Nanomaterials are a wide class of materials that have a range of the dimension 1 nm-100 nm at least and they are made from nanoparticles [2, 6, 7]. There are several methods to synthesis a nanomaterial that was developed by many researchers. There is chemical reduction [8, 9], chemical vapor deposition [10], photochemical [11], electrochemical [12], green synthesis [13], photochemical [11], Horizontal Vapor Phase Growth (HPVG) [14, 15], photochemical [11], microwave [16], sol–gel [17], and sonochemical [18]. One of the methods that successfully synthesized nanocomposite materials is the HPVG technique. HVPG was proven to be used to develop and able to produce material with various dimensional of nanostructures like Fe2O3 [19], Ln2O3 [20], Ag-TiO2 and SnO2 [21]. This technique offers some advantages like economical, reliable method, and less source material with high purity [22, 23]. HVPG technique is also capable to create nanomaterials with various shapes such as nanoparticles, nanotubes, nanorods, and triangular nanomaterials [14, 24, 25, 26]. They were evaluated to investigate the structure, chemical composition, hardness, and morphological behavior of the nanocomposite material [27]. Previous research about evaluated nanocomposite material synthesized with the HVPG technique is present in Table 1.

SourceMethod to evaluateFunction
Muflikhun et al. [28]SEMTo determine the image and measure the synthesized nanomaterial
EDXTo determine the composition of the material
AFMTo determine the 3D surface roughness of nanocomposite material
Tibayan et al. [29]SEMTo determine the image and measure the zone in synthesized nanomaterial
DFTTo determine the atomic geometry and electronic properties the nanocomposite material
ABATo determine the metabolic activity in the material
Motlagh et al. [30]SEMTo investigate the dispersion of nanoparticles
AFMTo investigate the surface roughness of the coating
Elcometer Motorized ScratcherTo determine the scratch resistance
Sheen Pendulum Hardness (707 KP)To determine the surface hardness
Micro-Tri Gloss Meter (BYK-Gardner)To determine the gloss coating
Reyes and Santos [31]SEMTo determine the image of nanomaterial
EDXTo determine the composition of the material

Table 1.

Nanocomposite materials evaluation on previous research.

The applications of HVPG techniques on synthesized nanomaterials were varies among the different sectors. Tibayan et al. [23, 29] used HVPG to synthesized Ag/SnO2 nanocomposite materials that can be used in coating applications. The characterization process used UV filtering analysis to evaluate the UV blocking. The results showed that the UV can be blocked efficiently. Moreover, DFT analysis using An and Ag as the sample material also showed that the entire spectrum of UV light can be absorbed with the model. The summary of the previous research about synthesized nanomaterials using the HVPG techniques can be seen in Table 2.

SourceYearsNanomaterials name
Muflikhun et al. [32]2019Synthetic Silver (Ag/TiO2)
Shimizu et al. [24]2016Skewered phthalocyanine [FeIII(Pc)(SCN)]n
Quitaneg and Santos [33]2011Cadnium Selenide (CdSe)
Reyes and Santos [31]2011Tin Dioxide (SnO2)
Buot and Reyes [34]2012Carbon-silver (C/Ag)
Muflikhun et al. [15]2017Silver-graphene (Ag/Ge)

Table 2.

Previous research of synthesized nanomaterials using HVPG technique.

Based on the explanation above, nanomaterials were synthesized by the HVPG technique and evaluated using several tests such as Scanning Electron Microscope (SEM), Energy-Dispersive X-ray Spectroscopy (EDX), X-Ray Diffraction Analysis (XRD), Density-Functional Theory (DFT), Applied Behavior Analysis (ABA), and Atomic Force Microscope (AFM), representing advances in the development of nanomaterials. The above discussion can also be used for further research in developing large-scale nanomaterials that can be applied in the industrial world.

Advertisement

2. The HVPG method

Detailed of the HVPG method are described in the study of Muflikhun et al. [21]. The step-by-step synthesis of nanomaterials is shown in Figure 1. It can be explained in the sub chapter 2.1 to 2.3 where all process was followed.

Figure 1.

(a) Material measurement, (b) pouring the materials into the tube, (c) final sealing process in vacuum condition, (d) baking process.

2.1 Preparation

Before the source material is inserted into the tube, the materials should be measured in the high precision weight scale to get the exact amount of material with a total weight of 35 mg. If the sample was composed of more than 1 sample, it should be divided into the individual sample. For example, the target synthesis was Ag/TiO2 nanocomposite materials. The source materials that need to be prepared were Ag powder 17.5 mg and TiO2 powder 17.5 mg. the combination should be equal to reach optimum results.

After material measurement, the next step was tube preparation. The tube was purchased from the general market nearby the university. The tube was originally used as the heater tube used in the toaster or heating unit. The tube before used as the place to grow nanomaterials, it should be washed in the ultrasonicator to remove the pollutant and impurity. After washed, the tube then dried until the water was evaporated. The one-side seal was applied to ensure the material that poured into the tube is trapped in the base. The one edge seal was also the final point of preparation where the specimen can be poured into the tube and then placed in the Thermionic High Vacuum System (THVS).

2.2 Sealing

Sample sealing is another important aspect to ensure the material is sealed properly. The tube before final sealing was placed vertically where the material was at the bottom. The upper tube is then joined with the pipe for the vacuum process. The process was occurred at a very low pressure (10 Torr−6 Torr). The low pressure has purposes pushing the melting point of the materials. Sealing is also a critical process when the sealing is not proper, the leak will allow outer air to go inside the tube and the vacuum process failed. The sealing process also needs special treatment due to the used blow torch that used LPG and O2 gas.

2.3 Baking

The HVPG method to synthesis nanomaterial is based on the temperature difference between 2 points. It is shown that the material that received heat in a continuous-time, the phase of material will change as follow:

From Figure 2, it is shown that the phase of the material will be melt and then evaporate after the critical point was overlapped. This phase transition occurred due to high temperatures in the furnace. The material then condenses and then become solid after moving from high temperature (inside the tube) to low temperature (outside the tube).

Figure 2.

Phase transition of materials in HVPG [21].

Advertisement

3. The study results and discussion

After cured with designated temperature and time, the nanomaterial inside the tube can be characterized and evaluated using the electron microscope. Since the unique phase transition of the materials that flow inside the tube, the nanomaterial growth inside the tube is also fascinating in terms of shape and size. The study from Muflikhun et al. [15] showed that flower-like and jellyfish-like nano-silver was successfully grown from the combination of Ag/Ge materials. The silver was grown on the graphene multilayer as shown in Figure 3. The growth variable in HVPG for the Ag/Ge was 1200°C and 6 hours baking time.

Figure 3.

(a) Jellyfish-like silver nanomaterial, (b) flower-like silver nanomaterial.

Another study conducted by Bernardino and Santos [35] shows that HVPG can be used to synthesis Gallium Oxide/Tin Oxide Nanostructures. The synthesis was used variable temperature 1200°C and 6 hours baking time. The results showed that different nano shape was grown such as nanowire, nano particles, and nano crystal.

There are 3 main variables to grow nanomaterial using the HVPG technique: time, temperature, and the weight ratio of the source material. During the baking process in the furnace, time and temperature play an important role to develop the shape of nanomaterials in the results. These two variables have been reported by Muflikhun et al. [28, 32]. The time was set to 4 hours, 6 hours, and 8 hours and the temperature was set to 800°C, 1000°C, and 1200°C. By using these 6 parameters, the 27 combinations of time and temperature can be achieved. The results of these results showed that the more different nanomaterials shape was successfully synthesized with different shapes of nanomaterials as reported below (Table 3).

No.TemperatureBaking timeZoneMaterial shape and diameter
1800°C4 Hours1Nanoparticles
22Micro particles
33Micro particles
46 Hours1Nanospheres, Nanoparticles
52Nanoparticles
63Nanoparticles
78 Hours1Nanoparticles
82Nanotubes, Nanospheres
93Nanoparticles
101000°C4 Hours1Nanoparticles
112Nanospheres, Nano-triangular, Nanorods
123Nanospheres, Nano-triangular
136 Hours1Nanoparticles
142Nanoparticles, Nanospheres
153Nanoparticles
168 Hours1Nanoparticles, Nanorods
172Nanorods, Nanoparticles
183Nanorods, Nanoparticles
191200°C4 Hours1Nanoparticles
202Nanospheres, Nanoparticles
213Nanoparticles
226 Hours1Nanoparticles
232Nanocrystal, Nano-triangular
243Nanoparticles
258 Hours1Nanoparticles
262Nanospheres, Nanorods, Nanocrystal
273Nanorods

Table 3.

The different shapes of nanomaterials with different temperatures and baking times.

The third variable that play the important role was the ratio of the source material. For that variable, the combination of two different materials was reported by Tibayan et al. [23, 29]. The study was used Ag/SnO2 and HVPG as the method to synthesis nanomaterial. The variable study based on the ratio between Ag and SnO2 where stoichiometric ratio mixtures of 0:5, 1:4, 2:3, 3:2, 4:1, and 5:0 were used. Since the different of material mixture were added, the results showed that different nano shape have been reported as seen in the Figure 4. The time for baking is 8 hours in the 800°C temperature condition.

Figure 4.

Representative sample of Ag/SnO2 with different ratio. (Ag:SnO2) (a) 0:5, (b) 1:4, (c) 2:3, (d) 3:2, (e) 4:1, (f) 5:0. Pictures were retrieved from [23].

Based on the previous work done by many researchers used HVPG to synthesis nanomaterials, it is shown that the HVPG method can ensure the pureness and the high quality of the nano shape due to the excellent sealing process and occurred in the vacuum condition.

Advertisement

4. Future trend

The pandemic that occurred in 2019 as known as COVID-19 has demonstrated the need for rapid, excellent, and robust technology that can prevent the virus and future diseases that may occur in the world. Researchers have been searching the new technology and they found that one of the best fits of the future technology that can be applied in almost all aspects of human life was founded in nanomaterials and nanotechnology [36, 37].

Nanotechnology become the most relevant solution for the problem of human life in the present day and the future due to the fact that nanotechnology has been proven to be applied in a different application. The various metal oxide was summarized by Shkodenko et al. [38] that useful to be applied as anti-bacterial technology. Pasquale et al. [37] were given an alternative perspective to disinfect the virus using a combination of TiO2 nanomaterials in the photocatalytic process. It is shown that future applications can be nearly applied that photocatalysts for air, surface and water were available. Moreover, in medical based especially in dentistry, the graphene-based nanomaterial can be applied to eradicate microbial with good results [39]. Future manufacturing technology can potentially be combined with nanotechnology, as in additive manufacturing. Different nanomaterials, such as Carbon Nano Tubes, Carbon Nano Fibers, Graphene Oxide, Metal Nanoparticles, and Metal Oxide Nanoparticles, can be combined in the various polymer matrices [40]. It is shown that by adding nanomaterials, the properties of the matrices can be significantly improved. The field of automotive also become concerned by the scientist. Kotia et al. [41] reported that nanomaterials were used in automotive engine to improve the efficiency and performance of the machine. The future application in the field of optical sensing, biological imaging and photodynamic therapy was reported by Chen et al. [42]. The studies from many researchers were summarized and they reported that chemiluminescence resonance energy transfer platform based on nanomaterial successfully fabricated. The study related to drug delivery and toxicity have been evaluated by Jia et al. [43]. The nanomaterial was tested on the zebrafish to determine the effect of toxicity and biological related safety concerns. The in vivo toxicological profiles of different nanomaterials, including Ag nanoparticles (NPs), CuO NPs, silica NPs, polymeric NPs, quantum dots, nanoscale metal–organic frameworks, etc., that appear in zebrafish have been evaluated. Furthermore, mechanical testing related to strain sensing using graphene nanomaterial has been reported by Mehmood et al. [44]. Graphene nanomaterial has been chosen because its excellent properties in thermal, electrical and mechanical strength.

There are several aspect that related to nanomaterials. One of the most important aspects related to the synthesis of nanomaterials were about the environmental aspect where many syntheses processes were used catalysts or other materials that can harm the environment. To prevent the issue related to the environment, green synthesis was launched by many researchers as an alternative to producing nanomaterials. Different materials were introduced such as: biocompatible reagents, synthesis process by microorganisms, using plant mediated synthesis, improve the waster treatment system using nano filtering process, etc. [45]. It can be summarized that in the future, nanomaterials and nanotechnology still became the alternative and major material that used in various applications. In that point of view, HVPG technique that used to synthesis nanomaterial can be applied in further high scale synthesis process to fulfill the community needs related to nanomaterials [46].

Advertisement

5. Conclusion

The characteristics of synthesis nanomaterials using HVPG has been described and reported in the present study. The details aspect of the synthesis and the sample of the results of the synthesis nanomaterial also presented. It is shown that the HVPG can be used to synthesis various type of nanomaterials with the following advantages: excellent pureness ratio, free of external impurity during synthesis process, simple procedure and setup, environmentally friendly, and used recycle material (quartz tube) that previously used as the heating components. Since the application of nanomaterials can be found in very wide aspects, the synthesis process of nanomaterials using HVPG can be an alternative method. The future trend as shown in the present study ensure the sustainability of the synthesis nanomaterial without compromising with the environment and related to human healthy aspect.

Advertisement

Acknowledgments

The authors would like to thank Mechanical and Industrial Engineering Department, Gadjah Mada University and De La Salle University, Philippines, for the support and funding.

Advertisement

Conflict of interest

“The authors declare no conflict of interest.”

References

  1. 1. Kreyling WG, Semmler-Behnke M, Chaudhry Q. A complementary definition of nanomaterial. Nano Today. 2010;5:165-168. DOI: 10.1016/j.nantod.2010.03.004
  2. 2. Khan I, Saeed K, Khan I. Nanoparticles: Properties, applications and toxicities. Arabian Journal of Chemistry. 2019;12:908-931. DOI: 10.1016/j.arabjc.2017.05.011
  3. 3. Mitter N, Hussey K. Moving policy and regulation forward for nanotechnology applications in agriculture. Nature Nanotechnology. 2019;14:508-510. DOI: 10.1038/s41565-019-0464-4
  4. 4. Keskinbora KH, Jameel MA. Nanotechnology applications and approaches in medicine: A review. Journal of Nanoscience & Nanotechnology Research. 2018;2:6
  5. 5. Baris K. Availibility of renewable energy sources in Turkey: Current situation, potential, government policies and the EU perspective. Energy Policy. 2012;42:377-391. DOI: 10.1016/j.enpol.2011.12.002
  6. 6. Goyal RK. Nanomaterials and Nanocomposites: Synthesis, Properties, Characterization Techniques, and Applications. CRC Press. 2017. DOI: 10.1201/9781315153285
  7. 7. Bratovcic A. Different applications of nanomaterials and their impact on the environment. International Journal of Materials Science and Engineering. 2019;5:1-7. DOI: 10.14445/23948884/ijmse-v5i1p101
  8. 8. Khan Z, Al-Thabaiti SA, Obaid AY, Al-Youbi AO. Preparation and characterization of silver nanoparticles by chemical reduction method. Colloids and Surfaces. B, Biointerfaces. 2011;82:513-517. DOI: 10.1016/j.colsurfb.2010.10.008
  9. 9. Liu D, Pan J, Tang J, Liu W, Bai S, Luo R. Ag decorated SnO2 nanoparticles to enhance formaldehyde sensing properties. Journal of Physics and Chemistry of Solids. 2019;124:36-43. DOI: 10.1016/j.jpcs.2018.08.028
  10. 10. Beier O, Pfuch A, Horn K, Weisser J, Schnabelrauch M, Schimanski A. Low temperature deposition of antibacterially active silicon oxide layers containing silver nanoparticles, prepared by atmospheric pressure plasma chemical vapor deposition. Plasma Processes and Polymers. 2013;10:77-87. DOI: 10.1002/ppap.201200059
  11. 11. Gabriel JS, Gonzaga VAM, Poli AL, Schmitt CC. Photochemical synthesis of silver nanoparticles on chitosans/montmorillonite nanocomposite films and antibacterial activity. Carbohydrate Polymers. 2017;171:202-210. DOI: 10.1016/j.carbpol.2017.05.021
  12. 12. Khaydarov RA, Khaydarov RR, Gapurova O, Estrin Y, Scheper T. Electrochemical method for the synthesis of silver nanoparticles. Journal of Nanoparticle Research. 2009;11:1193-1200. DOI: 10.1007/s11051-008-9513-x
  13. 13. Patra S, Mukherjee S, Barui AK, Ganguly A, Sreedhar B, Patra CR. Green synthesis, characterization of gold and silver nanoparticles and their potential application for cancer therapeutics. Materials Science & Engineering. C, Materials for Biological Applications. 2015;53:298-309. DOI: 10.1016/j.msec.2015.04.048
  14. 14. Muflikhun MA, Chua AY, Santos GNC. Statistical design analysis of silver-titanium dioxide nanocomposite materials synthesized via horizontal vapor phase growth (HVPG). Key Engineering Materials. 2017;735:210-214. DOI: 10.4028/www.scientific.net/KEM.735.210
  15. 15. Muflikhun MA, Castillon GB, Santos GNC, Chua AY. Micro and nano silver-graphene composite manufacturing via horizontal vapor phase growth (HVPG) technique. Materials Science Forum. 2017;901:3-7. DOI: 10.4028/www.scientific.net/msf.901.3
  16. 16. Hong Y. Van der Waals epitaxy of InAs nanowires vertically aligned on single-layer graphene. Nano Letters. 2012;12:1431-1436. DOI: 10.1021/nl204109t
  17. 17. Nair KK, Kumar P, Kumar V, Harris RA, Kroon RE, Viljoen B, et al. Synthesis and evaluation of optical and antimicrobial properties of Ag-SnO2 nanocomposites. Physica B: Condensed Matter. 2018;535:338-343. DOI: 10.1016/j.physb.2017.08.028
  18. 18. Kumar B, Smita K, Cumbal L, Debut A, Pathak RN. Sonochemical synthesis of silver nanoparticles using starch: A comparison. Bioinorganic Chemistry and Applications. 2014;2014:1-8. DOI: 10.1155/2014/784268
  19. 19. De Mesa DMB, Santos GNC, Quiroga RV. Synthesis-and-characterization-of-Fe2O3-nanomaterials-using-HVPC-growth-technique. International Journal of Scientific & Engineering Research. 2012;3(8):1-12
  20. 20. Ayeshamariam A, Kashif M, Muthu Raja S, Sivaranjani S, Sanjeeviraja C, Bououdina M. Synthesis and characterization of In2O3nanoparticles. Journal of the Korean Physical Society. 2014;64:254-262. DOI: 10.3938/jkps.64.254
  21. 21. Muflikhun MA, Santos GNC. A standard method to synthesize Ag, Ag/Ge, Ag/TiO2, SnO2, and Ag/SnO2 nanomaterials using the HVPG technique. MethodsX. 2019;6:2861-2872. DOI: 10.1016/j.mex.2019.11.025
  22. 22. Uon L, Santos GN, Chua A. Synthesis and characterization of titanium dioxide nanomaterials via horizontal vapor phase growth (hvpg) technique. ASEAN Engineering Journal. 2020;10:93-100. DOI: 10.11113/aej.v10.16699
  23. 23. Tibayan EB, Muflikhun MA, Villagracia ARC, Kumar V, Santos GNC. Structures and UV resistance of Ag/SnO2 nanocomposite materials synthesized by horizontal vapor phase growth for coating applications. Journal of Materials Research and Technology. 2020;9(3):4806-4816. DOI: 10.1016/j.jmrt.2020.03.001
  24. 24. Shimizu E, Santos GN, Yu DE. Nanocrystalline axially bridged iron phthalocyanine polymeric conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III). Journal of Nanomaterials. 2016;2016:1-7
  25. 25. Espulgar WV, Santos GNC. Antimicrobial silver nanomaterials synthesized by HVPCG Technique. International Journal of Scientific and Engineering Research. 2011;2:8-11.http://www.ijser.org
  26. 26. Briones JC, Castillon G, Delmo MP, Santos GNC. Magnetic-field-enhanced morphology of tin oxide nanomaterials for gas sensing applications. Journal of Nanomaterials. 2017;2017:1-11. DOI: 10.1155/2017/4396723
  27. 27. Qadir A, Le TK, Malik M, Amedome Min-Dianey KA, Saeed I, Yu Y, et al. Representative 2D-material-based nanocomposites and their emerging applications: A review. RSC Advances. 2021;11:23860-23880. DOI: 10.1039/d1ra03425a
  28. 28. Muflikhun MA, Chua AY, Santos GNC. Structures, morphological control, and antibacterial performance of ag/tio 2 nanocomposite materials. Advances in Materials Science and Engineering. 2019;2019:1-12. DOI: 10.1155/2019/9821535
  29. 29. Tibayan EB, Muflikhun MA, Kumar V, Fisher C, Villagracia ARC, Santos GNC. Performance evaluation of Ag/SnO2 nanocomposite materials as coating material with high capability on antibacterial activity. Ain Shams Engineering Journal. 2020;11(3):767-776. DOI: 10.1016/j.asej.2019.11.009
  30. 30. Labbani Motlagh A, Bastani S, Hashemi MM. Investigation of synergistic effect of nano sized Ag/TiO2 particles on antibacterial, physical and mechanical properties of UV-curable clear coatings by experimental design. Progress in Organic Coatings. 2014;77:502-511. DOI: 10.1016/j.porgcoat.2013.11.014
  31. 31. Reyes RDL, Santos GNC. Growth mechanism of SnO2 nanomaterials De- rived from backscattered electron image and EDX observations. International Journal of Scientific and Engineering Research. 2011;2:1-4
  32. 32. Muflikhun MA, Frommelt MC, Farman M, Chua AY, Santos GNC. Structures, mechanical properties and antibacterial activity of Ag/TiO2 nanocomposite materials synthesized via HVPG technique for coating application. Heliyon. 2019;5:1-21. DOI: 10.1016/j.heliyon.2019.e01475
  33. 33. Quitaneg AC, Santos GNC. Cadmium selenide quantum dots synthesized by HVPC growth technique for sensing copper ion concentrations. International Journal of Scientific and Engineering Research. 2011;2:1-4
  34. 34. Buot RMN, Santos GNC. Synthesis and characterization of C-Ag nanomaterials for battery electrode application. International Journal of Scientific and Engineering Research. 2012;3:1-3
  35. 35. Bernardino LD, Santos GNC. Synthesis and characterization of gallium oxide/tin oxide nanostructures via horizontal vapor phase growth technique for potential power electronics application. Advances in Materials Science and Engineering. 2020;2020:1-14. DOI: 10.1155/2020/8984697
  36. 36. Hussain CM. Handbook of Functionalized Nanomaterials for Industrial Applications. Amsterdam: Elsevier; 2020
  37. 37. De Pasquale I, Lo Porto C, Edera MD, Curri L, Comparelli R. TiO 2 -based nanomaterials assisted photocatalytic treatment for virus inactivation : perspectives and applications. Current Opinion in Chemical Engineering. 2021;34:1-10.100716. DOI: 10.1016/j.coche.2021.100716
  38. 38. Shkodenko L, Kassirov I. Metal oxide nanoparticles against bacterial biofilms : Perspectives and limitations. Microorganisms. 2020;2:1-21
  39. 39. Radhi A, Mohamad D, Suhaily F, Rahman A, Manaf A. Mechanism and factors influence of graphene- based nanomaterials antimicrobial activities and application in dentistry. Journal of Materials Research and Technology. 2020;11:1290-1307. DOI: 10.1016/j.jmrt.2021.01.093
  40. 40. N.V. Challagulla, V. Rohatgi, D. Sharma, R. Kumar, ScienceDirect recent developments of nanomaterial applications in additive manufacturing : A brief review, Current Opinion in Chemical Engineering. 2020;28:75-82.https://doi.org/10.1016/j.coche.2020.03.003
  41. 41. Kotia A, Chowdary K, Srivastava I, Kumar S, Kamal M, Ali A. Carbon nanomaterials as friction modi fi ers in automotive engines : Recent progress and perspectives. Journal of Molecular Liquids. 2020;310:113200. DOI: 10.1016/j.molliq.2020.113200
  42. 42. Chen J, Qiu H, Zhao S. Trends in Analytical Chemistry Fabrication of chemiluminescence resonance energy transfer platform based on nanomaterial and its application in optical sensing , biological imaging and photodynamic therapy. Trends in Analytical Chemistry. 2020;122:115747. DOI: 10.1016/j.trac.2019.115747
  43. 43. Jia H, Zhu Y, Duan Q, Chen Z, Wu F. Nanomaterials meet zebrafish : Toxicity evaluation and drug delivery applications. Journal of Controlled Release. 2019;311-312:301-318. DOI: 10.1016/j.jconrel.2019.08.022
  44. 44. Mehmood A, Mubarak NM, Khalid M, Walvekar R, Abdullah EC, Siddiqui MTH, et al. Journal of environmental chemical engineering graphene based nanomaterials for strain sensor application — a review. Journal of Environmental Chemical Engineering. 2020;8:103743. DOI: 10.1016/j.jece.2020.103743
  45. 45. Mondal P, Anweshan A, Purkait MK. Chemosphere green synthesis and environmental application of iron-based nanomaterials and nanocomposite : A review. Chemosphere. 2020;259:127509. DOI: 10.1016/j.chemosphere.2020.127509
  46. 46. Muflikhun MA, Chua AY, Santos GNC. Dataset of material measurement based on SEM images of Ag/TiO2 nanocomposite material synthesized via Horizontal Vapor Phase Growth (HVPG) technique. Data Br. 2020;28:1-9. DOI: 10.1016/j.dib.2019.105018

Written By

Muhammad Akhsin Muflikhun, Rahmad Kuncoro Adi and Gil Nonato C. Santos

Submitted: November 9th, 2021 Reviewed: November 15th, 2021 Published: December 21st, 2021