DC/DC converter specifications in simulation.
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These books synthesize perspectives of renowned scientists from the world’s most prestigious institutions - from Fukushima Renewable Energy Institute in Japan to Stanford University in the United States, including Columbia University (US), University of Sidney (AU), University of Miami (USA), Cardiff University (UK), and many others.
\\n\\nThis collaboration embodied the true essence of Open Access by simplifying the approach to OA publishing for Academic editors and authors who contributed their research and allowed the new research to be made available free and open to anyone anywhere in the world.
\\n\\nTo celebrate the 50 books published, we have gathered them at one location - just one click away, so that you can easily browse the subjects of your interest, download the content directly, share it or read online.
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IntechOpen and Knowledge Unlatched formed a partnership to support researchers working in engineering sciences by enabling an easier approach to publishing Open Access content. Using the Knowledge Unlatched crowdfunding model to raise the publishing costs through libraries around the world, Open Access Publishing Fee (OAPF) was not required from the authors.
\n\nInitially, the partnership supported engineering research, but it soon grew to include physical and life sciences, attracting more researchers to the advantages of Open Access publishing.
\n\n\n\nThese books synthesize perspectives of renowned scientists from the world’s most prestigious institutions - from Fukushima Renewable Energy Institute in Japan to Stanford University in the United States, including Columbia University (US), University of Sidney (AU), University of Miami (USA), Cardiff University (UK), and many others.
\n\nThis collaboration embodied the true essence of Open Access by simplifying the approach to OA publishing for Academic editors and authors who contributed their research and allowed the new research to be made available free and open to anyone anywhere in the world.
\n\nTo celebrate the 50 books published, we have gathered them at one location - just one click away, so that you can easily browse the subjects of your interest, download the content directly, share it or read online.
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Divided into two parts, Analysis and Real-World Applications, the book describes the application of the wavelet method to several interesting complex systems across various disciplines. The book is designed for students, postdocs, and researchers interested in studying the wavelet method and its applications.",isbn:"978-1-83962-659-3",printIsbn:"978-1-83962-658-6",pdfIsbn:"978-1-83962-660-9",doi:"10.5772/intechopen.77457",price:119,priceEur:129,priceUsd:155,slug:"wavelet-transform-and-complexity",numberOfPages:124,isOpenForSubmission:!1,isInWos:1,isInBkci:!1,hash:"74bd7559ad44e50940d35974905e98ee",bookSignature:"Dumitru Baleanu",publishedDate:"November 6th 2019",coverURL:"https://cdn.intechopen.com/books/images_new/7653.jpg",numberOfDownloads:6357,numberOfWosCitations:4,numberOfCrossrefCitations:8,numberOfCrossrefCitationsByBook:0,numberOfDimensionsCitations:10,numberOfDimensionsCitationsByBook:0,hasAltmetrics:1,numberOfTotalCitations:22,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"August 30th 2018",dateEndSecondStepPublish:"September 20th 2018",dateEndThirdStepPublish:"November 19th 2018",dateEndFourthStepPublish:"February 7th 2019",dateEndFifthStepPublish:"April 8th 2019",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6,7",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"105623",title:"Dr.",name:"Dumitru",middleName:null,surname:"Baleanu",slug:"dumitru-baleanu",fullName:"Dumitru Baleanu",profilePictureURL:"https://mts.intechopen.com/storage/users/105623/images/system/105623.jpg",biography:"Dumitru Baleanu received a B.Sc. degree in Physics from the University of Craiova, Romania, in 1988, an M.Sc. degree from the University of Bucharest, Romania, in 1989, and a Ph.D. degree from the Institute of Atomic Physics, Romania, in 1996. He is Professor at the Institute of Space Sciences, Romania, and since 2000 he is visiting staff member at Cankaya University, Turkey. He published 500 papers in journals indexed in SCI. He is a co-editor of five books published by Springer. He is coauthor of three books published by Elsevier and World Scientific. He is an editorial board member of six ISI journals and is on the 2015 Highly Cited Researcher list in mathematics. 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In motor terms, this disease can generate alterations such as tremors, festination, rigidity, unbalance, slowness, and freezing of gait. Additionally, it is estimated that for the year 2040, the number of people with Parkinson’s in the world will be between 12.9 and 14.2 million people. These alarming figures make Parkinson’s disease an important focus of attention. In this chapter, we present contributions that suggest wavelet techniques as a useful tool to perform a gait and arm swing analysis; this represents an important approximation that can contribute to describe and differentiate people with Parkinson’s disease in early stages of the disease.",signatures:"Yor Jaggy Castaño-Pino, Andrés Navarro, Beatriz Muñoz and Jorge Luis Orozco",downloadPdfUrl:"/chapter/pdf-download/65988",previewPdfUrl:"/chapter/pdf-preview/65988",authors:[{id:"79143",title:"Prof.",name:"Andres",surname:"Navarro Cadavid",slug:"andres-navarro-cadavid",fullName:"Andres Navarro Cadavid"},{id:"272198",title:"Mr.",name:"Yor",surname:"Castano",slug:"yor-castano",fullName:"Yor Castano"},{id:"285963",title:"Dr.",name:"Jorge",surname:"Orozco",slug:"jorge-orozco",fullName:"Jorge Orozco"},{id:"285964",title:"Dr.",name:"Beatriz",surname:"Munoz",slug:"beatriz-munoz",fullName:"Beatriz Munoz"}],corrections:null},{id:"66832",title:"Analysis of Wavelet Transform Design via Filter Bank Technique",doi:"10.5772/intechopen.85051",slug:"analysis-of-wavelet-transform-design-via-filter-bank-technique",totalDownloads:777,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:0,abstract:"The technique of filter banks has been extensively applied in signal processing in the last three decades. It provides a very efficient way of signal decomposition, characterization, and analysis. It is also the main driving idea in almost all frequency division multiplexing technologies. With the advent of wavelets and subsequent realization of its wide area of application, filter banks became even more important as it has been proven to be the most efficient way a wavelet system can be implemented. In this chapter, we present an analysis of the design of a wavelet transform using the filter bank technique. The analysis covers the different sections which make up a filter bank, i.e., analysis filters and synthesis filters, and also the upsamplers and downsamplers. We also investigate the mathematical properties of wavelets, which make them particularly suitable in the design of wavelets. The chapter then focuses attention to the particular role the analysis and the synthesis filters play in the design of a wavelet transform using filter banks. The precise procedure by which the design of a wavelet using filter banks can be achieved is presented in the last section of this chapter, and it includes the mathematical techniques involved in the design of wavelets.",signatures:"Peter Yusuf Dibal, Elizabeth Onwuka, James Agajo and Caroline Alenoghena",downloadPdfUrl:"/chapter/pdf-download/66832",previewPdfUrl:"/chapter/pdf-preview/66832",authors:[null],corrections:null},{id:"65146",title:"Wavelets for Differential Equations and Numerical Operator Calculus",doi:"10.5772/intechopen.82820",slug:"wavelets-for-differential-equations-and-numerical-operator-calculus",totalDownloads:976,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:1,abstract:"Differential equations are commonplace in engineering, and lots of research have been carried out in developing methods, both efficient and precise, for their numerical solution. Nowadays the numerical practitioner can rely on a wide range of tools for solving differential equations: finite difference methods, finite element methods, meshless, and so on. Wavelets, since their appearance in the early 1990s, have attracted attention for their multiresolution nature that allows them to act as a “mathematical zoom,” a characteristic that promises to describe efficiently the functions involved in the differential equation, especially in the presence of singularities. The objective of this chapter is to introduce the main concepts of wavelets and differential equation, allowing the reader to apply wavelets to the solution of differential equations and in numerical operator calculus.",signatures:"Riccardo Bernardini",downloadPdfUrl:"/chapter/pdf-download/65146",previewPdfUrl:"/chapter/pdf-preview/65146",authors:[{id:"219317",title:"Prof.",name:"Riccardo",surname:"Bernardini",slug:"riccardo-bernardini",fullName:"Riccardo Bernardini"}],corrections:null},{id:"66826",title:"DWT-Based Data Hiding Technique for Videos Ownership Protection",doi:"10.5772/intechopen.84963",slug:"dwt-based-data-hiding-technique-for-videos-ownership-protection",totalDownloads:894,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:0,abstract:"This chapter proposes a wavelet data hiding scheme for video authentication and ownership protection. A watermark in the shape of a logo image will be hidden. In this research, a discrete wavelet transform (DWT) process is implemented using orthonormal filter banks, where the Y components of the YUV color space of the video frames are decomposed using DWT, and a watermark is inserted in one or more of the resulting sub-bands in a way that is fully controlled by the owner. Then, the watermarked video is reconstructed. The filters used for the DWT decompositions are randomly generated to increase the security of the algorithm. An enhanced detection technique is developed to increase the reliability of the system. The overall robustness of this scheme is measured when common attacks are applied to the test videos. Moreover, the proposed algorithm is used with the high-efficiency video coding (HEVC) technique to examine the whole performance. Furthermore, a selective denoising filter is built to eliminate the effect of the noise. The simulation results show that the proposed algorithm achieves well under both the visual and the metric tests. Moreover, it performed well against intentional and unintentional attacks. The average normalized correlation achieved is 97%, while the mean peak signal-to-noise ratio (PSNR) is 45 dB.",signatures:"Farhan Al-Enizi and Awad Al-Asmari",downloadPdfUrl:"/chapter/pdf-download/66826",previewPdfUrl:"/chapter/pdf-preview/66826",authors:[null],corrections:null},{id:"66641",title:"Wavelet Transform Analysis to Applications in Electric Power Systems",doi:"10.5772/intechopen.85274",slug:"wavelet-transform-analysis-to-applications-in-electric-power-systems",totalDownloads:1324,totalCrossrefCites:2,totalDimensionsCites:3,hasAltmetrics:0,abstract:"The wavelet transform has received great importance in the last years on the power system analysis because the multi-resolution analysis presents proprieties good for the transient signal analysis. This chapter presents a review on main application of wavelet transform in electric power systems. The study areas have been classified as power system protection, power quality disturbances, power system transient, partial discharge, load forecasting, faults detection, and power system measurement. The areas in which more works have been developed are the power quality and protections field, where both cover 51% of the articles analyzed.",signatures:"Mario Orlando Oliveira, José Horacio Reversat and Lucas Alberto Reynoso",downloadPdfUrl:"/chapter/pdf-download/66641",previewPdfUrl:"/chapter/pdf-preview/66641",authors:[null],corrections:null},{id:"66025",title:"Wavelet Transform Applied to Internal Defect Detection by Means of Laser Ultrasound",doi:"10.5772/intechopen.84964",slug:"wavelet-transform-applied-to-internal-defect-detection-by-means-of-laser-ultrasound",totalDownloads:1331,totalCrossrefCites:3,totalDimensionsCites:3,hasAltmetrics:0,abstract:"Laser-generated ultrasound represents an interesting nondestructive testing technique that is being investigated in the last years as performative alternative to classical ultrasonic-based approaches. The greatest difficulty in analyzing the acoustic emission response is that an in-depth knowledge of how acoustic waves propagate through the tested composite is required. In this regard, different signal processing approaches are being applied in order to assess the significance of features extracted from the resulting analysis. In this study, the detection capabilities of internal defects in a metallic sample are proposed to be studied by means of the time-frequency analysis of the ultrasonic waves resulting from laser-induced thermal mechanism. In the proposed study, the use of the wavelet transform considering different wavelet variants is considered due to its multi-resolution time-frequency characteristics. Also, a significant time-frequency technique widely applied in other fields of research is applied, the synchrosqueezed transform.",signatures:"Hossam Selim, Fernando Piñal Moctezuma, Miguel Delgado Prieto, José Francisco Trull, Luis Romeral Martínez and Crina Cojocaru",downloadPdfUrl:"/chapter/pdf-download/66025",previewPdfUrl:"/chapter/pdf-preview/66025",authors:[null],corrections:null}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},subseries:null,tags:[{id:"65",label:"highly cited contributor"}]},relatedBooks:[{type:"book",id:"2278",title:"Advances in Wavelet Theory and Their Applications in Engineering, Physics and Technology",subtitle:null,isOpenForSubmission:!1,hash:"43f8c4f3571860f51c18deef213fa8cb",slug:"advances-in-wavelet-theory-and-their-applications-in-engineering-physics-and-technology",bookSignature:"Dumitru Baleanu",coverURL:"https://cdn.intechopen.com/books/images_new/2278.jpg",editedByType:"Edited 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He has published over 153 papers, has edited 12 books, and written around 50 book chapters. Head of the Laboratory of Neuroimmunoendocrinology, Institute of Biomedical Research in UNAM, Mèxico.",coeditorOneBiosketch:"A pioneering researcher in molecular parasitology of Taenia solium cysticerci. He was part of the team that sequenced the Taenia solium genome. He has published over 33 papers on cysticercosis. Head of the Laboratory of Molecular Parasitology in UNAM, Mèxico.",coeditorTwoBiosketch:"A pioneering researcher in studying the immunology of taeniasis/cysticercosis, appointed Head of the Unit of Experimental Biomedicine. 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The AC power system are more common due to its advantages for long distance power transmission (i.e., transformers can be used to adjust optimal voltage levels). Thus, the development of micro-grid technology has been mostly confined to AC micro-grids [4, 5]. However, as the number of local micro-grids increase the need for long distance power transmission will significantly decline. Therefore, local DC micro-grids can potentially be more efficient due to the fact that many loads require DC power (e.g., electronic loads, LED lighting systems, electric vehicle charging, etc.). In addition, most renewable energy systems and energy storage systems are either inherently DC (batteries, solar panels) or incorporate a DC stage (inverter connected wind turbines) [6]. Since the number of DC sources and loads will inevitably increase in the future, the need for a DC MGs will also increase. The reason is that the need for PV cells and ESSs is increasing. The advantages of the DC MGs over the AC MGs are summarized as follows [7, 8]:
DC MGs are more efficient and the natural fits for DC sources and loads.
Most of the existing challenges in AC MGs are due to reactive power flow, power quality, and frequency regulation, which do not exist in the DC MGs.
In terms of transmission efficiency (loss associated with the reactive current is eliminated) and power supply reliability (more reliability overall because of fewer components), DC MGs have a superior performance in comparison to AC MGs [8].
Thus, DC microgrids seem to be a natural framework for future power delivery [9].
In DC MGs, regulating the common DC-bus voltage is the main control task. To gain this goal, two different methods have been proposed in the literature [10, 11, 12, 13, 14], autonomous droop-based control schemes and non-autonomous centralized controllers (that are based on communication links). Droop-based methods are widely used due to their simplicity and reliability (centralized methods can not be relied upon due to their dependency on the communication links) [15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31]. However, the existing and conventional droop-based methods cannot propose an optimal performance in terms of reliability and efficiency exclusively in the islanded mode of operation. In addition, existing droop controllers usually result in large voltage variations at the DC bus during transients in the islanded mode. Large voltage fluctuations may jeopardize the system reliability and damage power electronic converters in MGs [3, 4]. However, the proper performance of linear or conventional droop controllers with a constant droop gain is reduced in light and full load conditions. This is due to a trade-off between voltage deviation and current sharing. In terms of current sharing accuracy and stabilization of Constant Power Loads (CPLs), high droop gains are preferable [11]. In term of voltage regulation low droop gains are desirable. Due to this trade-off between current sharing and voltage deviation, constant droop gains can not guarantee high performance, and it would be a big challenge. Figure 1 shows this trade-off in the conventional droop control in a simplified DC MG’s with two DC sources. It shows that constant droop gain can not be a precise and comprehensive method in both light and full load conditions [11].
(a) A simple DC MG with two DGs, (b) the effect of small drop causes voltage deviation with current splitting error at full load, and (c) the effect of the large droop gains in voltage deviation with current sharing error under light load conditions, respectively.
To address this issue, different methods have been proposed in the literature to maintain a high level of reliability [5, 6]. A fuzzy logic strategy for energy balancing is proposed in [12]. This method is based on utilizing the virtual resistances which are calculated based on the
Three nonlinear droop control methods are proposed in [17, 18, 19]. In [17], it is claimed that the effect of sensor calibration errors and cable resistances is minimized, while it improves voltage regulation and load sharing compared to linear droop control techniques. This method adaptively adjusts the droop gains based on three novel high-order polynomial droop equations. The three methods are proposed in this research are High-Droop Gain (HDG), Polynomial Droop Curve (PDC), and Polynomial Droop Curve With Voltage Compensation (PDCVC), which are shown in Figure 2. However, the chosen droop gain value in the HDG method exhibits poor current sharing near the operating point. On the other hand, the PDC method could improve load sharing near the operating point, but shows an unexpected performance in voltage regulation under heavy-loading condition. In the PDCVC method, both current sharing and voltage regulation are improved except near no-load conditions. Two important factors were not considered in this paper, the impact of output impedance on the stability of the whole DC MG and the impact of droop control on the efficiency of system. Later in [18], a split droop controller is investigated, which droop gain can be calculated based on voltage error measurement. This strategy calculates several different slopes for each load conditions to reduce the current sharing and voltage deviation errors, which shows this task well implemented. However, differences between droop slopes create switching modes, which will be abrupt. The sudden changes in output resistance of the power converters may lead to undesired transients and oscillations. In [19], the performance of the different second order droop expressions namely parabola and ellipse droop as nonlinear droop control methods are evaluated and compared with the linear droop. The parabola and ellipse droop equations showed a good performance in both load sharing and voltage regulation but a weak performance with negative current [16]. A nonlinear programmable droop method for a low-voltage DC MG is proposed in [20] considering the effects of line resistances and the state of charge of the batteries in the power- sharing process. This method has been able to reduce the impacts of sensor and cable errors at heavy load. It also reduces the voltage variation while load sharing is still guaranteed. However this method does not have a good performance, when the converter output current is negative. Moreover, under light-loading conditions, the values of droop gain lead to creating poor load sharing [20].
(a) Droop characteristics for HDG method, (b) droop characteristics for PDC method, and (c)
In this paper a novel control system has been proposed to improve the reliability and efficiency of DC micro-grids operating in the islanded mode. Figure 3 shows the block diagram of the DC MG considered in this paper. Two energy storage systems along with two solar energy harvesting systems are connected to the DC bus to feed 4 kW DC loads. The focus of this paper is on small scale DC micro-grids for residential applications, which means the line impedance can be negligible [14, 19]. The main contribution to this article is that the proposed control system allows RESs to operate at their maximum power point whenever it’s possible. The main advantage of the proposed control system is that the MG can optimally utilize energy storage system in conjunction with renewable energy systems. Additionally, the proposed control system can maintain tight regulation of the DC bus voltage within a predefined range. Unlike the aforementioned nonlinear methods, the presented method has a precise performance in negative current (when the output power is absorbed by the battery) which is similar to the positive current (when the battery converter injects power to the MG). The calculations of the droop gain in the proposed method are independent of the measured output current. Therefore, this method immunizes the proposed control system from current ripples and sensor errors in comparison to the methods with high order polynomial droop methods. This method has an ability to change the droop gain smoothly from light load to full load conditions, without switching modes resulting in no abrupt in the control system. Voltage deviation and current sharing improved in this method in comparison to other nonlinear and conventional droop control, and it will be shown and explain in the following section. This method has been implemented and analyzed in the Micro-Grid systems due to this fact, the most difficult tasks and challenges have occurred in the MG system, not in the grid- connected system. In the grid-connected system the bus voltage is constant with less complexity and less non-ideal elements or parameters. Various power flow scenarios have been analyzed to verify the performance of the MG.
DC microgrid configuration (implemented system).
This paper is organized as follows. The proposed control system and various operating scenarios are described in Section 2, respectively. Moreover, two subsections called the definition and ranges of the adaptive parameter are added in Section 2. In Section 3, the optimal selection of the the adaptive parameters is presented. The stability analysis performed in Section 4. Finally the simulation and experimental results are presented in Section 5.
In order to describe the performance of the proposed control system in all operation modes, a scenario will be discussed. Energy devices and systems in which the solar system and battery are connected to the grid/load through power converters have four operating modes which are listed as follows:
Grid-connected mode: When the system is connected to the grid, in order to transmit the maximum power, the power converter connected to the solar cells performs maximum power point tracking (MPPT). During this mode, the battery’s state of charge should be controlled so that when the system is disconnected from the grid and turns into an island system, the battery has enough energy to supply the island system. Therefore, in accordance with the battery’s state of charge, the battery is charged or discharged, which are two modes of operation.
Island mode: In this mode, the power converter connected to the solar cells still performs MPPT. During this mode of operation, the DC-bus voltage should be kept constant (within the range of 10%) by the power converter; whereas, in grid-connected mode, the voltage of DC-bus is relatively constant for various conditions. Therefore, to achieve power-sharing and load voltage regulation, the battery connected power converter is controlled with the droop control method. For instance, if the load voltage decreases, battery is discharged to transmit more power; and when the load voltage increases, power is transmitted back to the battery and charges it.
Special case of island mode: If the battery is fully charged/discharged during the island mode, the power-sharing and output voltage regulation are achieved by the solar connected power system. Hence the power system evades MPPT and is controlled with the droop control method.
In the islanded mode of operation, one of the main problems with the existing droop-based controller is that the MG components are not utilized in an efficient manner [30, 31]. For example, in several scenarios, to keep the stability of the system, renewable energy sources must deviate from their maximum PowerPoint [30, 31]. The main contribution of this method shows the presented control system allows RESs to operate at their maximum power point whenever it can be possible. Figure 4 shows the general block diagram of the proposed control systems for the solar energy harvesting system and the energy storage system (ESS) in the DC MG. The solar control system consists of one MPPT control and one adaptive droop control, which are separated from each other by a state modifier. The structure of the solar control system will be discussed in the next paragraph. After that, the battery control system will be discussed in details as the main proposed control method. The battery control system consists of a supervisory adaptive droop control to manage energy through the DC MG system. The optimal utilization is performed through incorporating the adaptive charge/discharge terms to the control system of the ESS. These terms implement a nonlinear adaptive droop profile for the ESS in order to perform a tighter voltage regulation. Moreover, due to working in a high level of power (More than 100 W), all the analysis are preferred in continues conduction modes, because working in discontinuous conduction mode in high-level power comes with high peak current and power loss, which it is not desired.
Block diagram of the proposed control scheme for PV units and energy storage systems in DC MG.
According to Figure 5, the schematic of the solar controller along with its boost converter is illustrated. The outer control loop of the solar energy harvesting system consists of two blocks: the MPPT controller that ensures maximum power is extracted from the solar module, and the adaptive DC-bus voltage controller. The switching between these two control algorithms is preformed by the state modifier block as follows:
The block diagram of control system in solar converter.
where
The block diagram of the ESS is discussed according to the Figure 4. In this figure, the presented control method offers four modes of operations: charging mode, discharging mode, fast charging mode, and fast discharging mode while the conventional droop control method offers only, charging mode and discharging mode. Using the two extra modes, the control system is able to offer voltage regulation, while improving the reliability of the system. The outer loop produces a reference value for the inner current control loop. The outer loop is optimized droop controller that incorporates two extra modes (i.e., fast charge, and fast discharge) into the control system. These modes are incorporated through two nonlinear functions,
Control systems based on optimization methods can be the proper solutions in determining the critical and unknown parameters of the MG systems [28, 29]. According to Figure 3, the optimal droop controller produces the reference value for the output current of the ESS. This current is given by:
The reference current includes three terms. The first term is produced by the DC-bus voltage droop controller given by:
where
The other two terms,
where
Figure 6 shows the way to calculate the current reference based on the DC-bus voltage for the Battery or ESS. This figure shows, the proposed controller provides two extra modes (i.e., fast charge and fast discharge), when the DC-bus voltage is lower than
The performance of the step and exponential functions in the proposed controller.
The current sharing and voltage deviations in the proposed system in comparison to the conventional one in
In order to achieve a stable and reliable system, the limitation on the numerical domain of Eq. (2) should be considered. The aforementioned limitation is set to meet the requirements of the implemented control system. The considered limitation, which is defined according to voltage regulation range, resources power rating, and load demanded power, will be discussed in detail as follows. In the Table 1 all the implemented components and variables are listed. The natural Logarithm domain and charge/discharge rate limitations of the implemented batteries, specified the values of
Symbols | Parameters | Values |
---|---|---|
Nominal Output Power for Battery#1 converter | 1 kW | |
Nominal Output Power for Battery#2 converter | 1 kW | |
Nominal Output Power for PV#1 converter | 1 kW | |
Nominal Output Power for PV#2 converter | 1 kW | |
Switching Frequency | 100 kHz | |
Nominal DC MG Voltage | 190 V DC | |
Battery Bank Voltage | 80 V DC | |
PV Bank Voltage | 80 V DC | |
Battery input Inductor | 150 | |
PV input Inductor | 330 | |
Output Capacitor | 200 |
DC/DC converter specifications in simulation.
The upper range of
Finally the upper and lower range of
In the implemented control system, the proposed range of the DC-bus voltage is considered to be
and
Therefor, the upper and lower range of
The main advantages of the profile proposed in Figure 5 are twofold. It provides a much better dynamical result for the ESS to utilize the available energy optimally. It also provides a small margin in the range of DC-bus voltage or its variations. Thus, it gives a chance for the converters to operates more optimally. The proper voltage deviation and desired power-sharing can be achieved by this method adaptively and autonomously, without any switching modes which lead to the harsh transients. Figure 8 shows the flowchart of the control system for ESS. This figure shows how various modes of operation get activated by the DC-bus voltage. The (
The flowchart of the proposed control scheme for the ESS.
Proposed adaptive droop controller with adaptive charge/discharge functions.
In this section, the procedure to determine the optimal values of the parameters for the proposed optimal droop controller is described. The objective is to find appropriate values for four parameters:
The proposed algorithm is based on sequential quadratic programming (SQP) [33], which is an iterative method for nonlinear optimizations. It can handle any degree of non-linearity, including non-linearity in the constraints [32]. Figure 10 shows the block diagram of the energy storage system with the proposed control system with the all details. This diagram shows the nonlinear optimization block with its inputs and outputs. Figure 11 shows that the SQP algorithm calculates the optimal values for the adaptive parameters. The proposed controller uses these values to generate the nonlinear functions
The optimization variables are defined as:
The DC/DC converter for the ESS with its control system.
Structure of charge/discharge control functions in the proposed method.
where
The general form of the objective function is defined as:
where
Having two modes of operation (charge and discharge modes) and more than one optimization variable, the need for the cost function to optimize more than one variable simultaneously, will be increased. The cost functions for this optimization problem are defined as:
Discharging mode:
Charging mode:
The total cost function is defined as the weighted sum of the aforementioned functions given by:
where
The
Case 1:
Case 2:
Case 3:
According to (25) and (26), two operating cases have been considered for the discharge mode based on
An example of SQP algorithm performance in the situation of SOC = 20%.
In this section, the stability analysis of the proposed control method is performed. The proposed optimal droop control system utilizes profiles with linear and nonlinear parts. When the system operates in the linear part (i.e., conventional droop profile), the stability analysis is straight forward. However, nonlinear methods (e.g. the Lyapunov stability theory) must be used to analyze the stability of the nonlinear part (the stability analysis has been carried out only for the islanded mode of operation) [34, 35].
Figure 13 shows the block diagram of the closed-loop control systems and the schematic diagram of the converter. According to Figure 13, the dynamical model of the battery is also considered in the schematic block diagram. According to Figure 13, the state-space model of the ESS is given by [29]:
(a) Closed-Loop block diagram of the battery controller. (b) DC-DC converter schematic.
where,
According to (28), the system dynamics include fast changing current,
According to (28) and Figure 13, the dynamics of the DC/DC converter for the current loop is given by:
In (29),
where
According to Figure 13, the voltage loop includes the nonlinear droop block and the closed loop block of the inner current control loop. It is worthwhile to mention that the voltage loop does not try to render the voltage error zero. Thus, the asymptotic stability is not required and the boundedness of the voltage variables is the only requirement. In order to investigate the boundedness, the energy function for the voltage error signal is defined as:
where
According to (28) the dynamics of the voltage error is given by (due to the fast varying current loop, it is assumed that the inductor current and duty cycle have already reached their final values):
The derivative of the energy function (32) is given by:
due to the fact that
Simulation and experimental results are presented in this section. In Tables 1 and 2 the specifications of the DC/DC converter used in the experimental prototype and simulations software are given in.
Symbols | Parameters | Values |
---|---|---|
Nominal Output Power for Battery#1 converter | 500 W | |
Nominal Output Power for Battery#2 converter | 250 W | |
Nominal Output Power for PV converter | 500 W | |
Switching Frequency | 100 kHz | |
Nominal DC MG Voltage | 190 V DC | |
Battery Bank Voltage | 80 V DC | |
PV Bank Voltage | 80 V DC | |
Battery input Inductor | 150 | |
PV input Inductor | 330 | |
Output Capacitor | 200 |
DC/DC converter specifications in experimental.
The DC MG configuration is shown in Figure 3 which implemented to obtain the simulation results. The concept of dropbased control is based on reducing the voltage deviation caused by the change in MG load. Therefore, to simulate voltage deviation, two types of step change are applied in MG Load. The performance of the proposed control system is compared with the conventional drop-down method in reducing the MG voltage deviation. All the simulation results are implemented with
Step changes (type 1) of the DC-load in DC MG.
Simulation result to compare the output power of the solar and battery between the proposed and conventional control method in
Simulation result to compare the DC-bus voltage regulation in the battery between the proposed and conventional control method in
Step changes (type 2) of the DC-load in DC MG.
Simulation results of
Simulation results of
Figures 20 and 21 show the DC-bus voltage variations for different values of
Simulation result of the DC-bus voltage regulation of the battery by the load step changes in the conventional control method.
DC-bus voltage regulation of the battery by the load step changes in the implemented SQP method in the proposed control method.
A small-scale DC micro-grid set-up has been implemented to evaluate the performance of the proposed method. The implemented experimental setup includes three boost converters in the power conditioning systems for the two energy storage (battery1 = 500 W and battery#1 = 250 W) and solar systems (PV panel = 500 W) with variation of DC loads. The specifications of the implemented converters are given in Table 2. Figure 22 shows the experimental prototype of the bidirectional DC/DC converters, solar, battery#1, and battery#2 converters. The implemented converters use three separate phases for optimal performance (each phase changes phase 120 degrees to reduce the current wave). Figure 23 shows a test prototype including two battery converters, a PV converter, a PV simulator, a battery simulator and a DC load to evaluate the proposed control system in the case of practical situation. For cost and safety reasons, experiments are performed at reduced power scale (1/2). All test results are based on a nominal voltage of
Top side of the prototype DC/DC bidirectional-boost converters, the converters of the solar, battery one, and battery two.
The test bench of two batteries and PV simulator with the DC load developed in the laboratory.
Figure 24 shows the high frequency wave forms of the implemented boost converter. Figure 25 shows the performance of the PI controller in tracking the reference value of the output current. The proposed method is validated under light and heavy load changing conditions with
Experimental result of the boost converter high frequency waveforms.
Experimental result of the PI controller performance by creating a step change in the load value.
Load step change | Method | Batteries SOC value | Voltage deviation | Voltage deviation improvement* | Compensated load current | |
---|---|---|---|---|---|---|
Battery #1 | Battery #2 | |||||
Reference to Light Load (500 W to 50 W) | Conventional | NA (80%) | 17 V | NA (0%) | 0.9A | 0.42A |
Proposed | 80% | 7 V | 58% | 1.2A | 0.65A | |
Reference to Full Load (500 W to 1100 W) | Conventional | NA (80%) | 20 V | NA (0%) | 1.1A | 0.55A |
80% | 6 V | 71% | 1.8A | 0.93A | ||
Proposed | 60% | 11 V | 45% | 1.5A | 0.75A | |
40% | 14 V | 31% | 1.3A | 0.65A |
Performance of the proposed control system in improving the DC-bus voltage deviation as well as compensating the load demanded power in comparison with the conventional droop controller.
Figure 26 illustrates the performance of the conventional droop control when the load is changing from reference value to the light load (from 500 W to 50 W). The minimum voltage devotion in the conventional method is
Experimental result of the DC-bus voltage and batteries output current in conventional droop control method operating by one step change of load value from
Experimental result of the DC-bus voltage and batteries output current in proposed droop control method operating by one step change of load value from
Figure 28 presented the conventional droop control performance when the load changes from reference value to the full load (from
Experimental result of the DC-bus voltage and batteries output current in conventional droop control method operating by one step change of load value from
Experimental result of the DC-bus voltage and batteries output current in proposed droop control method operating by one step change of load value from
Experimental result of the DC-bus voltage and batteries output current in proposed droop control method operating by one step change of load value from
Figures 29–31 illustrated the proposed control system performance in maintaining the DC voltage at three values of
Experimental result of the DC-bus voltage and batteries output current in proposed droop control method operating by one step change of load value from
Figure 32 shows the efficiency curve of the battery converter in the full range of output power variation from zero to full load. The rated power of the battery converter is 500 W as mentioned in Table 2. It should be mentioned that the proposed control system is a supervisory control system that control the flow of power between the converter and the DC grid by providing power references of the converter controller. Therefore, the proposed control system does not have any effect on the efficiency level of the converters and there are no extra losses caused by the proposed method. Moreover, the proposed method affects the control system only in transients and in steady-state operation, the control system is not affected by the proposed method.
Efficiency curves of the DC converter when the load is changing from light to full load.
In this chapter, a new adaptive droop control technique for the Battery or ESS has been proposed in the islanded mode. The proposed method provides a very tight DC-bus voltage regulation, while charge/discharge control task of the battery system is performed. In this control scheme, two extra operation modes (i.e., fast charge and fast discharge) has been proposed, which can offer an optimal performance for the DC MG. Thus, the extra power generated by the renewable energy sources can effectively charge the battery so fast. In case of voltage dropping, the battery is fast discharged, which can keep the desired DC-bus voltage range. In addition, a nonlinear optimization method has been introduced to determine the adaptive parameters in the optimal droop controller. Experimental and simulation results have validated the superior performance of the presented controller in comparison with the conventional controller.
Carotenoids are a class of natural pigments broadly distributed in nature and synthesized by plants, certain bacteria, fungi and algae. These molecules are classified in two main groups: carotenes, which are pure hydrocarbons (α−/β-carotenes and lycopene), and xanthophylls, which represent the oxygenated derivatives (lutein, zeaxanthin, astaxanthin, fucoxanthin and cryptoxanthin) [1]. These hydrocarbons are formed by eight five-carbon isoprenoid units with conjugated double bonds, responsible of multiple geometrical isomers (cis/trans), although carotenoids are mainly found in the most stable configuration, the all-trans one [2, 3]. These double bonds act as chromophores and are responsible for light absorption in the visual range of the spectrum [4], providing yellow, orange and red coloration [5]. Among the main biological properties described for carotenoids, they stand out for their antioxidant capacity and ability to quench singlet oxygen species [6]. Carotenoids have also been described to wield anti-inflammatory, antimicrobial and anti-hyperglycemic activities, to prevent cardiovascular and/or neurodegenerative diseases and to stimulate the immune system [7, 8]. These beneficial properties made them emerge as a promising alternative to synthetic additives, which have been related with negative side-effects. Besides, these pigments improve the nutritional value of foodstuff and can be used for food coloring. These reasons have boosted carotenoids’ market size, which is expected to reach $300 billion by 2024, due to the interest shown by food, animal feeding, pharmaceutical, nutraceutical and cosmetic industries [9].
Found primarily in microalgae species such as
Chemical structure of α-carotene and β-carotene.
Lycopene can be found in fruits and vegetables, especially in tomatoes (Figure 2), being the carotenoid with the highest antioxidant capacity. It has been seen that this pigment is involved in modulating many anti-inflammatory processes, and some authors have linked it with the prevention of bone diseases, such as osteoporosis [15]. Furthermore, lycopene also shown anticancer effects against several tumoral and normal cell lines, particularly prostate cancer cell lines (PrEC and PC-3), in
Chemical structure of lycopene.
Xanthophylls comprise oxidized derivatives of carotenoids, being broadly available in nature. These pigments are characterized for having yellow, orange or red coloration. Some of the most common xanthophylls present in nature include lutein, zeaxanthin, astaxanthin, β-cryptoxanthin and fucoxanthin (Figure 3) [6]. These compounds are polar molecules and, unlike non-polar carotenes, they get accumulated, contributing to skin pigmentation [1]. Antioxidant, neuroprotective, antiplasmodial or anticancer are some of the biological activities that pointed xanthophylls as a promising nutraceutical. These beneficial bioactivities may have preventive effects in an extensive variety of diseases such as oral, allergic, neurologic, ophthalmologic and immune affections [6]. Moreover, beneficial properties may be transferred to food. Hence, these characteristics have prompted the incorporation of xanthophylls as natural additives to obtain products with a better appearance according to the consumers’ standards [1, 19].
Chemical structure of a) lutein, b) zeaxanthin, c) astaxanthin, d) cryptoxanthin and e) fucoxanthin.
Lutein is a dihydroxy derivative of β-carotene with hydroxyl groups at both sides of the molecule (Figure 3a), converting it in a dipolar xanthophyll. This chemical configuration confers hydrophilic characteristics and improves its capacity to scavenge free radicals [6, 20]. The most common chemical configuration of lutein is acylated with different fatty acids [1], such as lauric (C12:0) or palmitic acid (C16:0), becoming mono- and diacylated derivatives [21]. Leafy vegetables and plants, flower petals and yellow and orange fruits are the most important sources of lutein. Its extraction is mainly carried out with organic solvents from flower petals that have been previously fermented and/or dried [1].
Zeaxanthin (Figure 3b) is a structural isomer of lutein with a darker yellow tone, closer to orange [20]. It is naturally found in leaves of green vegetables, flower petals, in some yellow and orange fruits, corn and even in microbial
Astaxanthin (Figure 3c) is a lipophilic carotenoid with a reddish-orange color [23]. This pigment is found in high concentrations in microalgae like
β-cryptoxanthin is a naturally occurring pigment mainly found in tropical fruit like papaya, highlighting its accumulation in citrus fruit such as oranges and tangerines [28]. This xanthophyll is closely related to β-carotene since, aside from being a vitamin A precursor, their structures are very similar, varying by just the addition of a hydroxyl group in one of the β-ionone rings in β-cryptoxanthin’s structure (Figure 3d), resulting in a bipolar conformation. These conformation makes its bioaccumulation easier, facilitating food coloring as well as being more nutritionally valuable, contributing to vitamin A production [29]. Moreover, β-cryptoxanthin intake has been associated with a reduced risk of inflammatory diseases, like polyarthritis or rheumatoid arthritis, by suppressing bone resorption and stimulated bone formation [30].
Fucoxanthin (Figure 3e) is mostly known for giving the characteristic brownish/olive-green color to brown algae (Phaeophyceae), as in species belonging to the genus
Generally, natural sources of carotenoids are divided into: i) fruits, vegetables and flowers; ii) microorganisms (microalgae, cyanobacteria, fungi, bacterial and yeasts); and iii) by-products (peels, seeds and skin).
There is a wide variety of fruits and vegetables recognized as natural sources of carotenoids in human diet. Besides, flowers, recently introduced in gastronomy, appeared to be a suitable source of carotenoids (Table 1). In general terms, the most relevant carotenoid found among these groups is β-carotene, although lutein, β-cryptoxanthin, lycopene and zeaxanthin are also highlighted as major carotenoids. Reviewed literature showed very different ranges of carotenoid concentrations depending on the analyzed tissue, variety, ripening stage, geographical origin, etc. [40, 41]. Nevertheless, Table 1 points to fruit as the most relevant source of carotenoids.
Source | Main Carotenoids | Carotenoid Content (mg/g) | Ref. | |
---|---|---|---|---|
Apricot | β-car, β-crypt, Lut, Zea | 0.07–0.08 (DW) | [42] | |
‘Gac’ oil | α−/β-Car, Lyc | 1.8–11 (FW) | [43, 44] | |
Goji | β-car, β-crypt, Zea | 0.04–0.51 (FW) | [45] | |
Kaki | β-car, β-crypt, Lut, Zea | 0.03–0.07 (DW) | [42] | |
Banana and plantain | α−/β-Car, Lut | 0.01–0.04 (DW) | [46, 47] | |
Mandarin juice | ζ−/ β-car, β-crypt | 0.01 (DW) | [41] | |
Mango | α−/β-Car, β-crypt, Lut, Zea | 3–129 (FW) | [40] | |
Orange | α−/ β−/ζ-car, β-crypt, Lut, Zea | 0.01–0.03 0.01–0.02 (DW) | [41, 48] | |
Papaya | β−/ζ-car, β-crypt, Lyc, Vio, Zea | 0.14–4.13 (FW) | [49, 50] | |
Peach | β-car, β-crypt, Lut, Zea | 0.04–0.09 (DW) | [42] | |
Broccoli | Lut, Neo | 8.5–11.6 (DW) | [51] | |
Carrot | α−/β-car, Lut, Lyc | 0.01–0.8 (DW)(TC’s) | [52, 53] | |
Kale | Zea | 1.6–2.5 (DW) | [54] | |
β-car | 0.10 (DW) | |||
Neo | 0.12 (DW) | |||
Lettuce | Lut | 0.1–0.13 (DW) | [55] | |
β-car | 2.2–2.9 (DW) | |||
Pea | Lut | 0.01–0.02 (DW) | [56] | |
β-car | 0.01–0.02 (DW) | |||
Pepper | β-car | 0.39–0.71 (DW) | [57] | |
Zea | 0.31–0.73 (DW) | |||
Spinach | Neo | 0.1–0.2 (FW) | [58] | |
Lut | 0.34–0.53 (FW) | |||
β-car | 0.2–0.32 (FW) | |||
Sweet corn | Lut | 0.02 (DW) | [59] | |
β-car | 0.01 (DW) | |||
Tomato | β-car | 0.01 (FW) | [60] | |
Lyc | 0.05–0.08 (FW) | |||
TCs | 0.04–0.2 (FW) | |||
Blue centaurea | β-car, Lut | 0.06 (DW) | [61] | |
Blue borage | β-car, Lut | 1.8 (DW) | ||
Camelia | β-car, Lut | 0.2 (DW) | ||
Xanthophylls | 0.001–0.003 (P) (DW) 0.04–0.07 (L) (DW) | [62] | ||
Marigold | Lut | 0.0002–0.006 (DW) | [63] | |
Nasturtium | Lut | 0.4–1.2 (DW) | [64] | |
Pansies | β-car, Lut, Zea | 0.2–1.1 (DW) | [61, 65] | |
Snapdragon | β-car, Lut, Zea | 0.03 (DW) | [65] |
Quantitative and qualitative analysis of carotenoids content in different species of fruits, vegetables, and flowers.
Abbreviations: DW: dry weight, FW: fresh weight, L: leaves, P: petals. Carotenoids: α−/β−/γ−/ζ-car: α−/β−/γ−/ζ-carotene, β-crypto: β-cryptoxanthin, lyc: lycopene, lut: lutein, neo: neoxanthin, TCs: total carotenoids content, vio: violaxanthin, zea: zeaxanthin.
Carotenoids extracted from fruits, vegetables and flowers become too expensive due to high production costs associated with large production areas required. Besides, the supply of carotenoids extracted from plants becomes unstable, since it is dependent on unpredictable climatologic conditions [66]. Therefore, more sustainable and green approaches have been explored for a more efficient carotenoids’ collection, including the use of microorganism or the reutilization of agricultural by-products
Nowadays, the interest on microbial carotenoids has increased because of their low production area requirements when compared to plants. Besides, microbial cultures are nearly independent of climatic conditions, seasonality and soil composition. Current technological advances permit a tight control of culturing conditions, which improves the efficiency of microbial carotenoid production and reduces costs. Examples of efficient production of carotenoids using microalgae, bacteria, yeasts or fungi are displayed in Table 2, that demonstrates the huge variability of microorganisms capable of producing specific types of carotenoids being the most relevant β-carotene, lutein, astaxanthin, canthaxanthin and torulene (Table 2).
Species | Most abundant Carotenoids | Content (mg/g) | Ref. | |
---|---|---|---|---|
β-car | 0.001–0.0045 (DW) | [67] | ||
Ast | 2–20 (DW) | [68] | ||
Ast | 6–19 (DW) | [69] | ||
Canthaxanthin | N.D | [70] | ||
Lut | 0.01 (DW) | [71] | ||
β-car | 1.50 (DW) | |||
Decaprenoxanthin and derivatives mono−/diglucosides; Lyc | 0.3–0.4 (DW) | [72] | ||
β-Car | 0.01–3.1 (CDW) | [73] | ||
Zea | 0.01–0.9 (CDW) | |||
Carotenoids, glucoside derivatives | 0.4–0.5 (DW) | [72] | ||
Zea; β-Crypto; β-Car; β-Zeacarotene | 0.5–0.6 (DW) | |||
Zea; β-Crypto; β-Car; β-Zeacarotene | 0.7–0.8 (DW) | |||
Carotenoids and glucoside derivatives | 0.7 (DW) | [72] | ||
Carotenoids and glucoside derivatives | 0.5 (DW) | [72] | ||
Fungi | β-car | 30 (DW) | [68] | |
Lyc | >900 (DW) | |||
β-car | 0.275–0.698 (DW) | [74] | ||
β-car | 0.05–10 (DM) | [68] | ||
Yeasts | Ast | 0.000725–0.007642 (DW) | [75, 76] | |
β-car | 0.0172 (DW) | [77] | ||
Torulene | 5–14 (DW) | [78, 79] | ||
Torularhodin | 32.2 (DW) | |||
Torulene | 18.2 (DW) | [79, 80] | ||
Torularhodin | 9.3 (DW) | |||
Torulene | 0.0001 (DW) | [79] | ||
Torularhodin | 0.00001 (DW) | |||
Ast | 0.0026–0.001 (DW) | [112] |
Quantitative and qualitative analysis of carotenoids content in different species microorganisms such as microalgae, bacteria, yeasts, filamentous fungi and cyanobacteria.
Abbreviations: DW: dry weight; CDW: cold-water-dispersible; N.D: not determined. Carotenoids: ast: astaxanthin, β-car: β-carotene, β-crypto: β-cryptoxanthin, lut: lutein, lyc: lycopene, TCs: total carotenoids content; zea: zeaxanthin.
Food waste has been increased in the last years driven by an increasing population, expected to reach 10 billion people by 2050, and inefficient and unsustainable production systems [81]. These factors boosted waste production, which is usually composted or burnt, emitting high amounts of CO2 to the atmosphere. To counteract this situation, multiple strategies have been explored in the last decades, such as the revalorization of wastes as source of biomolecules. In fact, peels, seeds, husks, pomace or pulp are recognized as alternative sources of compounds with diverse biological properties [82].
Table 3 collects information about potential agricultural and food by-products as sustainable sources of carotenoids.
By-product | Most abundant Carotenoids | Content (μg/g) | Ref. |
---|---|---|---|
Tucumã peels | β-car | 68–88 (FW) | [83] |
Peach palm peel | 71–75 (FW) | ||
Mandarin epicarp | β-car | 1397–1417 (DW) | [84] |
Melon peels | β-car | 67–915 (DW) | [85] |
β-crypto | 3–49 (DW) | ||
Atlantic shrimp cooked shell | Ast | 57.3–284.5 (DW) | [86] |
Grape canes | Lut; β-car | 0.3–2.4 (DW) | [87] |
Peels and pulp of persimmon | β-crypto | 6500–167,000 (DW) | [88] |
β-car | 6900–45,000 (DW) | ||
Pressed palm fibers | α-car | 142–305 (DW) | [89] |
β-car | 317–713 (DW) | ||
Mango peel | α−/β-car; crypto | 5600 (β-car) (DW) | [90] |
Skin and seeds of tomatoes | Lyc | 3.8–166.4 (DW) | [91] |
β-car | 0.6–26.4 (DW) | ||
Lut | 0.8–10.8 (DW) | ||
Carrot by-products | β-car | 230 (FW) | [92] |
Carrot juice processing waste | β-car | 240 (DW) | [93] |
Tomato peels and seeds | Lyc | 410 (P);28 (S) (FW) | [94] |
β-car | 31 (P); 5.2 (S) (FW) |
Quantitative and qualitative analysis of carotenoids content in different by-products derived from agricultural and food industries.
Abbreviations: P: peel; S: seeds. Carotenoids: ast: astaxanthin, α−/β-car: α−/β-carotene, β-crypto: β-cryptoxanthin, lut: lutein, lyc: lycopene. FW – Fresh weight, DW – Dry weight.
In the last decades, macroalgae have been pointed out as a promising source of carotenoids. These photosynthetic organisms contain high amounts of pigments involved in light absorption for nourishment. However, they also have a secondary role related with damage protection from UV exposition. The main xanthophylls found in macroalgae include fucoxanthin, lutein, or zeaxanthin, being fucoxanthin the most abundant one, while β-carotene stands out from carotenes (Table 4). The main advantage of using macroalgae, is that invasive species can be used as an alternative source of carotenoids.
Species | Most abundant Carotenoids | Content (mg/g) | Ref. |
---|---|---|---|
Fuco | 2.0–3.5 (DW) | [95] | |
Fuco | 0.4–6.4 (DW) | [96] | |
Fuco | 0.42 (DW) | [97] | |
Fuco, Lut | 5.2 (DW) 0.3 (DW) | [98] | |
1.4 (DW) 0.1 (DW) | |||
Fuco | 18.6 (DW) | [99] | |
β-car, lut, zea | 0.0029 (TCs, FW) | [100] | |
Lut | 0.3 (FW) | [101] | |
Fuco | 0.0084 (TCs, DW) | [102] |
Quantitative and qualitative analysis of carotenoids content in different macroalgae species.
Abbreviations: DW: dry weight, FW: fresh weight, β-car: β-carotene, fuco: fucoxanthin lut: lutein, TCs: total carotenoids content, zea: zeaxanthin.
In the last century, pigment extraction has been performed using solid–liquid extraction with different organic solvents. Extracts were later purified via semipreparative high-performance liquid chromatography (HPLC) [103] or clean up and separation columns using organic solvents such as hexane or dichloromethane [104]. The use of non-polar solvents for carotenoid extraction like petroleum ether or hexane has been linked with toxicity, having a negative impact in the environment in the long term. In addition, in the current legislation regarding the use of these solvents for the production of food ingredients is not allowed. For this reason, in the latest years, novel “greener” extraction processes have been developed for pigment recovery, including supercritical fluid extraction (SFE), pressurized liquid extraction (PLE), ultrasonic assisted extraction (UAE) and microwave assisted extraction (MAE) (Table 5). Implementing these techniques improved, among other things, extraction times, yields and solvent usage [105].
Source | Carotenoids | Conditions | Recovery (μg/g) | Ref. |
---|---|---|---|---|
SFE | ||||
β-car | CO2, 60 °C, 300 bar | 15,000 (DW) | [113] | |
α−/β-car, β-crypto, lyc, lut, zea | CO2 + EtOH, 30 MPa | 392 (TCs) | [108] | |
Carotenoids | CO2 + EtOH, 25°C, 20 min, 20 MPa | 47,000–53,000 | [109] | |
Lut | CO2, 65°C, 55 MPa | 3000 (DW) | [114] | |
Ast, β-car, lut, neo, zea | CO2 + 10% EtO, 25°C, 20 min, 20 Mpa | 73; 60, 436, 671, 90 | [115] | |
Tomato, apricot, peach, pumpkin (Fl, Pe), pepper (Fl, wastes) | β-car, lut, lyc | CO2/EtOH, 59°C, 30 min, 350 bar | 88–100% β-car | [116] |
PLE | ||||
Carrot by-products | β-car | EtOH 99%, 60–180°C, 5 min, 50 bar, 1–5 cycles of 2 min | 120–230 (FW) (soft soggy carrots) 80–190 (FW) (orange carrots) | [92] |
β-crypto, β-car, lut, zea | MeOH: THF 2:8 (v:v), 40 °C, 5 min, 103 bar | Kaki: β-crypto ≤29, lut ≤ 13, zea ≤ 18 Apricot: ≤48 (β-car) | [42] | |
Fucoxanthin | 90% EtOH, 110°C, 5 min, 1500 psi | 420 | [97] | |
β-car, zea | 125°C, 20 min, 10.5 MPa | Zea ≤14,000 β-car ≤8000 | [117] | |
UAE | ||||
Dark red tomato | Lyc | EtAc: tomato paste 8:1 (V/W), 86°C, 29 min | 89,000 | [118] |
MAE | ||||
Carrot juice wastes | β-car | Flaxseed oil: wastes 8:1 g/g, 165 W, 9.4 min | 775,000 | [93] |
Novel extraction techniques to efficiently recover carotenoids from natural sources.
Abbreviations: DW: dry weight, EtOH: ethanol, EtAc: ethyl acetate, Fl: flesh, FW: fresh weight, L: leaves, MeOH: methanol, Pe: peels, THF: tetrahydrofuran. Carotenoids: ast: astaxanthin, α−/β-car: β-carotene, β-crypto: β-cryptoxanthin, lyc: lycopene, lut: lutein, neo: neoxanthin, TCs: total carotenoids, zea: zeaxanthin.
Supercritical fluid extraction (SFE) emerged in 80s decade as a promising alternative to conventional organic extractions [106]. This is a process where a compound is separated from its matrix making use of the unique properties of supercritical fluids as solvents, being CO2 the most commonly used. Supercritical fluid technology applies pressures and temperatures above the critical point of the extracting solvent, leading to a balanced state between liquid and gas phases. This balance confers low viscosity, high diffusivity, enhanced solubility and no surface tension, facilitating mass transfer [107]. However, this process involves a high cost, due to high temperatures and pressures requirements. Moreover, CO2 only dissolves non-polar molecules, although using a co solvent overcomes this issue, being ethanol the most employed [108, 109].
As well as in SFE, pressurized liquid extraction (PLE), also called accelerated solvent extraction (ASE), makes use of high temperature and pressure, although along with a liquid solvent to accelerate the extraction of specific analytes from solid matrices. In this system, pressure is high enough to keep the solvent liquid without hampering extraction performance. However, extraction time, temperature, solvent type and volume have influence on extraction performance, especially temperature and solvent type. Temperature range is mostly comprised from 40 to 180°C and it has been seen that the use of
Ultrasonic assisted extraction (UAE) also emerged as a novel technique, which employs using ultrasonic waves that propagate causing the implosion of bubbles, phenomenon known as cavitation. This perturbation leads to a diffusion of the solute from the porous matrix to the solvent. Nowadays, UAE is used for extracting various compounds including carotenoids from a wide diversity of matrices, such as macroalgae, microalgae and plants. This technique is environment-friendly, simple, cheap and efficient, reporting high yields when compared to conventional techniques, although the reproducibility of the samples is jeopardized by equipment’s aging [111].
Microwave assisted extraction (MAE) is a relatively new extraction technique that combines microwave and traditional solvent extraction. Since the late 1980s, MAE has become one of the most popular and cost-effective extraction methods [112]. This technique is based on the application of microwaves for heating both solvents and matrices, increasing the kinetic of the extraction. Compared to conventional and novel (SFE and PLE) techniques, MAE reduced extraction time and solvent usage, leading to higher extraction rates and reduced costs [93].
Color is an important sensory attribute associated with safety and nutritional values of food, reason why, in the last years, consumer awareness regarding the use of synthetic food coloring has been increased. In order to develop a more natural food industry, natural pigment demand has raised, as is the case for carotenoids. These pigments are used for their coloring properties as well as for their antioxidant potential and biological functions. Carotenoids can be either applied directly into food matrices like beverages or pasta, among others [119, 120], or indirectly, into animal feeding to improve pigmentation of final products as in eggs or fish flesh [1, 29, 121]. Moreover, carotenoids have pointed out as promising ingredients in active packaging films. Their inclusion in protective films can improve the storing properties of the package, extending the shelf-life of the product, as well as transferring carotenoids’ nutritional values [122, 123]. Several applications of carotenoids in the food industry have been collected in Table 6.
Carotenoid | Origin | Application | Properties | Ref. |
---|---|---|---|---|
β-Carotene | Fruits & vegetables | Free and encapsulated | Yellow colorant and antioxidant | [120] |
Incorporated into polymer materials | Antioxidant, O2 and light barrier | [123] | ||
α-Carotene | Free and encapsulated | Yellow colorant, anti-carcinogenic and antioxidant | [120, 124] | |
α-Tocopherol | High fat vegetables | Incorporated into polymer materials | Antioxidant | [123] |
Astaxanthin | Marigold flower | Incorporated into packaging material | Fish feeding for antioxidation and flesh coloring | [125] |
Bixin | Annatto seeds | Incorporated into polymer materials | Antioxidant, O2 and light barrier | [123] |
Canthaxanthin | Mushrooms | Alginate-pectin microencapsulation | Red colorant and antioxidant | [126] |
Cryptoxanthin | Mandarin, papaya, orange | Free and encapsulated | Orange colorant and antioxidant | [120] |
Lutein | Green vegetables | Encapsulation in food | Eye protection against AMD development or cataracts. Anticancer | [124] |
Lycopene | Tomato, watermelon, pink grapefruit, guava | Free and encapsulated | Red colorant, eye UV-protection, antioxidant | [120, 123, 124] |
Incorporated into polymer materials | Antioxidant, O2 and light barrier | |||
Zeaxanthin | Mandarin, papaya, orange | Orange colorant | Eye protection against macular degeneration and cataracts | [120, 124] |
Carotenoids applications in food industry.
Since the late 1980s, carotenoids implementation into food has significantly increased. Among all, β-carotene is the most applied one, being used for coloring oils and butters, providing a yellowish color. In addition, it has been also used to fortify different food matrices for its provitamin A activity [127]. Apart from β-carotene, other carotenoids have been incorporated as free molecules into food matrices (Table 6). However, the direct application of these natural pigments is limited by their low stability, so micro- and nanoencapsulation technologies have been applied. Multiple encapsulation technologies including spray or freeze drying, emulsion, spray chilling, extrusion coating, liposome entrapment, coacervation and ionic gelation [128] have been applied to improve solubility, chemical stability and bioavailability of pigments, as well as for masking unpleasant organoleptic properties [129]. Most of these technologies have been applied to encapsulate carotenoids, generally on a nanometric scale (≤100 nm). The type of encapsulation materials used for food applications have to be food-graded biopolymers such carbohydrates or gums (Persian gum), proteins (gelatin or whey), and animal or vegetal lipids [22, 26, 130]. Emulsion is also a prominent encapsulation processes, which results in an improved bio accessibility and bioavailability [131]. Lutein emulsions, β-carotene oil-in-water emulsions or microcapsules containing lycopene are just some examples of microencapsulation found in the food industry to improve the stability, bio accessibility and bioavailability of these pigments [129, 132, 133]. Similarly, multiple studies support carotenoids’ nanoencapsulation [134, 135].
A different way to incorporate natural pigments in human food is through animal feeding. By doing so, pigments get incorporated in foodstuff such as in fish flesh or eggs, giving a characteristic pigmentation and an increased nutritional value that will be further transferred to humans or animals [121, 136]. One of the main industries where carotenoids have been implemented is aquaculture. Fish factories have been making use of pigments such as β-carotene as an important source of provitamin A, which has been shown to improve the antioxidant capacity and immune system of fish, enhancing growth and preventing lipid peroxidation [137]. In fact, in aquaculture, different biological sources of xanthophylls such as green microalgae, yeast, krill, or crab waste have been utilized as feeding supplements. This complementary pigmentation enhances the nutritional value of fish products by providing strong antioxidant activity and higher amounts of provitamin A [1]. Other industry where pigments are widely use is poultry. EU approved egg yolk and poultry tissues pigmentations with yellow and red carotenoids, including lutein, zeaxanthin, β-cryptoxanthin, violaxanthin and capsanthin [136].
Natural pigments can also be incorporated into packaging materials to improve food preservation. Carotenoids such as lycopene or β-carotene prevent color alterations due to oxidation processes and UV-induced damage, providing stability to packaging polymers [123]. Besides, pigment migration from active packaging into food matrices has been reported, transferring the beneficial properties. As could be seen in Table 6, several carotenoids such have been included in active packaging, achieving promising results.
Synthetic pigments have been frequently used as food additives to improve food appearance since colorful products have been associated with healthy and high-quality properties by consumers. However, tendency has slowly shifted towards a stronger presence of natural ingredients due to a raising concern about the negative side effects associated with synthetic molecules. In this context, carotenoids have come up as an attractive replacement of synthetic pigments, being found in multiple sources, like plants, algae, fungi, microorganisms and by-products. Moreover, carotenoids have been linked with diverse beneficial properties, such as antioxidant, prevention of degenerative diseases, cancer and stimulation of the immune system. For all these reasons, carotenoids have caught the attention of many industries, including food, nutraceutical and cosmetic industries.
In order to extract these pigments, novel technologies emerged to improve the extraction rates of traditional techniques, mostly based on maceration. Among these new strategies, SFE and PLE highlight. Equipment may result into an initial economic expense, but they offer satisfactory extraction rates while minimizing solvent usage and experimental times.
Regarding food industry, carotenoids have been widely used for their application into food matrices or as part of packaging materials. Their inclusion as food additives or feed supplements for animals is the most extended and explored application, improving the organoleptic properties and nutritional values, aiming for a higher commercial acceptance. Besides, carotenoids have also been used as ingredients for active packaging films to extend products’ shelf-life. Regardless the matrix of inclusion, natural carotenoids have been incorporated as free molecules or encapsulated. This last strategy prolongs the stability and bio accessibility of carotenoids, protecting core ingredients from chemical degradation.
Furthermore, due to their extensive bioactivities, carotenoids are very useful to formulate new cosmetic ingredients. Besides, its antioxidant properties that can benefit the skin and promote skin regeneration and healthy aging, carotenoids also mitigate the harmful effects of UV radiation, which makes them excellent candidates for their application in cosmetic formulations as preservatives with photoprotective, antioxidant and anti-aging properties.
The research leading to these results was funded by Xunta de Galicia supporting the Axudas Conecta Peme, the IN852A 2018/58 NeuroFood Project and the program EXCELENCIA-ED431F 2020/12; to Ibero-American Program on Science and Technology (CYTED—AQUA-CIBUS, P317RT0003) and to the Bio Based Industries Joint Undertaking (JU) under grant agreement No 888003 UP4HEALTH Project (H2020-BBI-JTI-2019). The JU receives support from the European Union’s Horizon 2020 research and innovation program and the Bio Based Industries Consortium. The project SYSTEMIC Knowledge hub on Nutrition and Food Security, has received funding from national research funding parties in Belgium (FWO), France (INRA), Germany (BLE), Italy (MIPAAF), Latvia (IZM), Norway (RCN), Portugal (FCT), and Spain (AEI) in a joint action of JPI HDHL, JPI-OCEANS and FACCE-JPI launched in 2019 under the ERA-NET ERA-HDHL (n° 696295).
The research leading to these results was supported by MICINN supporting the Ramón y Cajal grant for M.A. Prieto (RYC-2017-22891) and the FPU grant for Anxo Carreira Casais (FPU2016/06135); by Xunta de Galicia for supporting the post-doctoral grant of M. Fraga-Corral (ED481B-2019/096), the pre-doctoral grants of P. García-Oliveira (ED481A-2019/295), and by UP4HEALTH Project that supports the work of P. Otero and C. Lourenço-Lopes.
The authors declare no conflict of interest.
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Normal binocular single vision occurs with bifoveal fixation and normal retinal correspondence in everyday sight. There are various anatomical and physiological factors concerned in the development of Binocular vision. The development of binocular function starts at 6 weeks and is completed by 6 months. Any obstacles, sensory, motor, or central, in the flex pathway is likely to hamper the development of binocular vision. The presence of these obstacles gives rise to various sensory adaptations to binocular dysfunction. Clinically the tests used can be based on either of the two principles: (A) assessment of relationship between the fovea of the fixing eye and the retinal area stimulated in the squinting eye, viz. Bagolini striated glasses test, red filter test, synoptophore using SMP slides for measuring the objective and subjective angles, and Worth 4-dot test; and (B) Assessment of the visual directions of the two foveae, viz. after image test (Hering Bielschowsky); and Cuppers binocular visuoscopy test (foveo-foveal test of Cuppers). Anomalies of binocular vision results in confusion, diplopia, which leads to suppression, eccentric fixation, anomalous retinal correspondence, and amblyopia.",book:{id:"8418",slug:"eye-motility",title:"Eye Motility",fullTitle:"Eye Motility"},signatures:"Arvind Kumar Morya, Kanchan Solanki, Sahil Bhandari and Anushree Naidu",authors:[{id:"270083",title:"Prof.",name:"Arvind",middleName:null,surname:"Morya",slug:"arvind-morya",fullName:"Arvind Morya"},{id:"273705",title:"Dr.",name:"Kalpit",middleName:null,surname:"Jangid",slug:"kalpit-jangid",fullName:"Kalpit Jangid"},{id:"279906",title:"Dr.",name:"Kanchan",middleName:null,surname:"Solanki",slug:"kanchan-solanki",fullName:"Kanchan Solanki"},{id:"279907",title:"Dr.",name:"Sahil",middleName:null,surname:"Bhandari",slug:"sahil-bhandari",fullName:"Sahil Bhandari"},{id:"290171",title:"Dr.",name:"Anushree",middleName:null,surname:"Naidu",slug:"anushree-naidu",fullName:"Anushree Naidu"},{id:"290172",title:"Dr.",name:"Priyanka",middleName:null,surname:"Rathore",slug:"priyanka-rathore",fullName:"Priyanka Rathore"},{id:"290173",title:"Dr.",name:"Sujeet",middleName:null,surname:"Prakash",slug:"sujeet-prakash",fullName:"Sujeet Prakash"},{id:"290174",title:"Dr.",name:"Sonalika",middleName:null,surname:"Gogia",slug:"sonalika-gogia",fullName:"Sonalika Gogia"},{id:"290176",title:"Dr.",name:"Sulabh",middleName:null,surname:"Sahu",slug:"sulabh-sahu",fullName:"Sulabh Sahu"}]},{id:"46503",title:"Disorders of Optic Nerve and Visual Pathways",slug:"disorders-of-optic-nerve-and-visual-pathways",totalDownloads:3867,totalCrossrefCites:1,totalDimensionsCites:1,abstract:null,book:{id:"3848",slug:"ophthalmology-current-clinical-and-research-updates",title:"Ophthalmology",fullTitle:"Ophthalmology - Current Clinical and Research Updates"},signatures:"Ipek Midi",authors:[{id:"169657",title:"Dr.",name:"Ipek",middleName:null,surname:"Midi",slug:"ipek-midi",fullName:"Ipek Midi"}]},{id:"18960",title:"Measurement of Anterior Chamber Angle with Optical Coherence Tomography",slug:"measurement-of-anterior-chamber-angle-with-optical-coherence-tomography",totalDownloads:6192,totalCrossrefCites:0,totalDimensionsCites:1,abstract:null,book:{id:"517",slug:"the-mystery-of-glaucoma",title:"The Mystery of Glaucoma",fullTitle:"The Mystery of Glaucoma"},signatures:"De Orta-Arellano F, Muñoz-Rodriguez P and Salinas-Gallegos JL",authors:[{id:"31619",title:"Dr.",name:"Fabiola",middleName:null,surname:"de Orta Arellano",slug:"fabiola-de-orta-arellano",fullName:"Fabiola de Orta Arellano"},{id:"35207",title:"Dr.",name:"Pablo",middleName:null,surname:"Muñoz Rodriguez",slug:"pablo-munoz-rodriguez",fullName:"Pablo Muñoz Rodriguez"},{id:"35208",title:"Dr.",name:"José Luis",middleName:null,surname:"Salinas Gallegos",slug:"jose-luis-salinas-gallegos",fullName:"José Luis Salinas Gallegos"}]},{id:"42721",title:"Intracameral Mydriatics in Cataract Surgery",slug:"intracameral-mydriatics-in-cataract-surgery",totalDownloads:8492,totalCrossrefCites:0,totalDimensionsCites:3,abstract:null,book:{id:"239",slug:"cataract-surgery",title:"Cataract Surgery",fullTitle:"Cataract Surgery"},signatures:"Anders Behndig, Björn Lundberg and Gunnie Bäckström",authors:[{id:"47264",title:"Prof.",name:"Anders",middleName:null,surname:"Behndig",slug:"anders-behndig",fullName:"Anders Behndig"},{id:"53862",title:"Mr.",name:"Björn",middleName:null,surname:"Lundberg",slug:"bjorn-lundberg",fullName:"Björn Lundberg"},{id:"53863",title:"Mrs.",name:"Gunni",middleName:null,surname:"Bäckström",slug:"gunni-backstrom",fullName:"Gunni Bäckström"}]}],onlineFirstChaptersFilter:{topicId:"191",limit:6,offset:0},onlineFirstChaptersCollection:[{id:"79766",title:"Keratoconus: A Treatable Disease",slug:"keratoconus-a-treatable-disease",totalDownloads:5,totalDimensionsCites:0,doi:"10.5772/intechopen.101206",abstract:"Keratoconus is a very frequent disease and is no diagnosed in many cases. Our chapter will focus on the several diagnostic tools not to miss this disease and also will present a all the treatment options with special focus on Corneal Cross Linking. All the indications for this treatment will be analyzed and extensively discussed as it should be considered the only option to stop the progress of the cone. Also, statistical analysis from our clinic with more than 2000 treatments with Cross Linking and follow up since 2006 will be presented. Literature review with results of this treatment is also going to be presented. Finally, a case of keratoconus treated with PRK and follow up of 30 years will be discussed and analyzed as the introduction of the combination of Cross Linking and Wavefront as one very good option in cases of mild to moderate keratoconus.",book:{id:"10879",title:"Vision Correction and Eye Surgery",coverURL:"https://cdn.intechopen.com/books/images_new/10879.jpg"},signatures:"Gustavo E. Tamayo, Eduardo J. 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Moreover, they presented different techniques to correct the refractive errors after transplantation for different corneal pathologies, in the plastic phase (managing of transplant sutures) as well as in the static phase (different refractive techniques: incisional (AK, FemtoAK), ablative (PRK, FemtoLASIK), or IOL implantation (Phakic IOL, PHACO + IOL)). Thus, it is necessary to study accurately every single clinical case to choose the best surgery for each patient. Due to the high risk of graft damage or graft rejection, the patient must be adequately informed about the risks and benefits of the surgery proposed and must specifically accept the possibility of a new corneal transplant in the event of surgery failure or graft damage. Certainly, the refractive surgeon must be able in managing all the different refractive surgery techniques to reach the best result in every single case.",book:{id:"10879",title:"Vision Correction and Eye Surgery",coverURL:"https://cdn.intechopen.com/books/images_new/10879.jpg"},signatures:"Laura Guccione, Luigi Mosca, Luca Scartozzi, Emanuele Crincoli, Romina Fasciani, Tomaso Caporossi and Stanislao Rizzo"},{id:"80389",title:"Anterior Segment Trauma: The Fundamentals of Management",slug:"anterior-segment-trauma-the-fundamentals-of-management",totalDownloads:33,totalDimensionsCites:0,doi:"10.5772/intechopen.101610",abstract:"Anterior segment trauma is the one of most common ocular condition seen in accident and emergency The ocular trauma may vary from minor injury such as a corneal abrasion to a grievous sight threatening injury such as a corneo-scleral tear or a chemical injury. The most crucial element in the management of ocular injuries is a thorough examination to identify all possible injuries to the eye and institute the appropriate treatment. The initial management plays a very important role in determining the prognosis of the vision, the need for further surgeries and also provide us with a realistic goals of visual rehabilitaion. In this chapter we aim to enumerate the common modes of ocular injury, manifestations of ocular trauma, the diagnostic features and provide the reader with a comprehensive overview of the treatment instituted. We will also include the accepted international trauma scoring systems and their utility in prognosticating the visual rehabilitation.",book:{id:"10879",title:"Vision Correction and Eye Surgery",coverURL:"https://cdn.intechopen.com/books/images_new/10879.jpg"},signatures:"Thanuja Gopal Pradeep and Deepthi Rameshbabu Honniganur"},{id:"79778",title:"Evaluation and Management of Ocular Traumas",slug:"evaluation-and-management-of-ocular-traumas",totalDownloads:93,totalDimensionsCites:0,doi:"10.5772/intechopen.101776",abstract:"Ocular trauma affecting the ante