Typical empirical heat transfer correlations of supercritical fluids.

## Abstract

The drastic changes of thermophysical properties in the pseudo-critical region of supercritical fluids bring very big challenges to the traditional Dittus-Boelter-type heat transfer correlations. In this chapter, we will talk about the principles and applications of two kinds of heat transfer correlations of supercritical fluids: the empirical type and the semiempirical type. For the empirical correlations, the modification methods taking into account the variable properties and body force effects will be introduced. We will focus on the proposal of nondimensional parameters describing the buoyancy effect and flow acceleration; while for the semiempirical ones, we mainly talk about the new kind of correlation which is based on the momentum and energy conservations in the mixed convective flow.

### Keywords

- heat transfer correlation
- empirical type
- semiempirical type
- buoyancy effect
- flow acceleration

## 1. Introduction

Establishing an accurate heat transfer correlation of supercritical fluid is the prerequisite of the design of the apparatus and devices, such as the supercritical boilers, generation IV reactors, and heat exchangers [1, 2, 3, 4]. However, the drastic change of the thermodynamic properties in the pseudo-critical region and the complex mechanism of turbulent heat transfer lead to difficulties in predicting the heat transfer performance accurately. There are three distinguished heat transfer regimes for supercritical fluid: normal heat transfer (normal HT), improved heat transfer (improved HT), and deteriorated heat transfer (deteriorated HT). The normal HT regime is characterized by the heat transfer coefficients similar with those predicted by the Dittus-Boelter (DB) correlation at subcritical condition; the improved HT regime can be characterized by the higher heat transfer coefficients and lower wall temperatures compared with the normal HT; and the deteriorated HT regime is accompanied with lower heat transfer coefficients than the normal HT; hence, the wall temperature peak can be observed. Figure 1 illustrates the heat transfer performances of supercritical CO_{2} under different mass fluxes and heat fluxes [5] of the upward flow in a circular tube with an inner diameter of 6.32 mm and heated length of 2.65 m. At relatively lower heat flux/mass flux ratio, the heat transfer will be obviously improved due to the large specific heat in the pseudo-critical region. The heat transfer coefficients will be higher than the ones calculated by the Dittus-Boelter correlation. As the heat flux/mass flux ratio increases, the mixing convective heat transfer occurs, and the wall temperature peak caused by the heat transfer deterioration can be observed. The experiment conducted by Kurganov and Kaptil’ny [6] offered an insight into the mechanism of heat transfer deterioration, the M-shaped velocity profile was observed, and it was considered to be closely associated with the flattened velocity gradient, reduced turbulent shear stress, and turbulent kinetic energy due to the body force (also known as the buoyancy effect). Bae et al. [7, 8] obtained the budgets of the turbulent kinetic energy in the deteriorated heat transfer by using direct numerical simulation, and the mechanism of buoyancy and flow acceleration were analyzed.

The heat transfer correlations are established on the basis of heat transfer mechanism, and a vast majority of correlations are intended for use only for normal HT and improved HT regimes. They can be categorized into two types: the empirical type and the semiempirical type. In the empirical correlations, the correction terms composed of different thermophysical properties (such as the density, thermal conductivity, specific heat, and viscosity) are introduced to the heat transfer correlation of the constant-property fluid (i.e., DB correlation) [9]. However, the performance of the empirical correlations deteriorates with the increasing of the heat flux/mass flux ratio; thus, the empirical correlations considering the nondimensional numbers which reflect the buoyancy and thermally induced flow acceleration effects have also been proposed [10]. It is shown that the predictions on the mixing convection cases can be improved by this method. In order to further improve the performances of the empirical correlations under the strong buoyancy effect, some researchers tried to establish the semiempirical correlations based on the theoretical analysis approaches [11, 12]. The existing semiempirical correlations mainly aim to derive the qualitative relationship between the heat transfer impairment and turbulent shear stress reduction; the coefficients appeared in the correlation are obtained by fitting the experimental data.

In this chapter we mainly talk about the heat transfer correlations of supercritical fluid. Both the empirical type and the semiempirical type will be introduced here. We mainly focus on the principles, applications, and comparisons of these correlations.

## 2. Empirical heat transfer correlations

For the improved HT and normal HT regimes, abundant empirical correlations have been proposed, and most of them can give satisfying predictions [13, 14, 15]. Morky et al. [9] and Gupta et al. [16] proposed the correlations based on the Buckingham Π theorem, and the comparison with the experimental results confirmed their capability on the calculating the heat transfer improvement regime. However, as the increasing of the heat flux, the effect of the mixing convection increases. The fluid near the heated wall is accelerated under the effect of the buoyancy force and the flow acceleration, leading to the attenuation of heat transfer [17]. On the basis of this, researchers tried to modify the correlations by considering the nondimensional numbers reflecting the buoyancy force and the flow acceleration. Bae and Kim [10] and Komita et al. [18] analyzed the momentum balance under the mixed convection case and proposed a nondimensional parameter Bu to describe the effect of the buoyancy on the shear stress; then, they proposed a new function to describe the relationship between the Nusselt numbers and Bu based on the experimental data. This heat transfer correlation takes the form of the piecewise function divided by the value of the Bu number. Deev et al. [19] discussed the heat transfer of supercritical water in the channel. Two nondimensional criteria considering the effects of the viscous force and inertial force on heat transfer were proposed, and the weight constant treating the superposition between the forced and natural convection was introduced. Such practices were also conducted by Cheng et al. [20], Yu et al. [21], and Kuang et al. [22]. In their work, the dimensionless numbers such as the buoyancy number and the acceleration number were proposed to correct the deviation of the real heat transfer from that of the normal HT regime. Figure 2 shows the approach establishing the empirical correlations. The dimensionless groups are firstly chosen, and the coefficients in the correlation can be obtained by the linear regression analysis. Through variable transformations the dimensionless groups are reduced, and the final form can be obtained. Some typical empirical correlations are listed in Table 1.

Ref. | Fluid | Parameters range | Correlation |
---|---|---|---|

Mokry et al. [9] | H_{2}O | = 22.8–29.4 MPa = 200–1500 kg m^{−2} s^{−1} = 70–1250 kW m^{−2} = 3–38 mm | |

Gupta et al. [16] | H_{2}O | = 24 MPa = 200–1500 kg m^{−2} s^{−1} = 70–1250 kW m^{−2} | |

Jackson [23] | H_{2}O | After review of the existing literatures and data | where the exponent is taken asi. < _{pc} < 1.2_{b};_{pc}ii. < _{b} < _{pc};_{w}iii. = 0.4 for < _{b} < _{w} and 1.2_{pc} < _{pc} < _{b}._{w} |

Bae and Kim [10] | CO_{2} | = 7.75–8.55 MPa < 1200 kg m^{−2} s^{−1}_{w} < 150 kW m^{−2} | ^{−8} < Bu < 7 × 10^{−7}, ii. For 7 × 10 ^{−7} < Bu < 1 × 10^{−6}, iii. 1 × 10 ^{−6} < Bu < 1 × 10^{−5}, iv. For 1 × 10 ^{−5} < Bu < 3 × 10^{−5},v. For 3 × 10 ^{−5} < Bu < 1 × 10^{−4}, |

Cheng et al. [20] | H_{2}O | = 10, 20 mm = 22.5–25 MPa < 3500 kg m^{−2} s^{−1}_{w} < 2000 kW m^{−2} = 300–450°C_{b} | |

Deev et al. [19] | H_{2}O | = 2.67–12.0 mm = 22.6–26 MPa < 2000 kg m^{−2} s^{−1}_{w} = 200–2250 kW m^{−2} | _{1} = 1 + _{1}exp(_{1}_{h}^{2} + _{1}_{h})_{2} = 1 + _{2}exp(_{2}_{h}^{2} + _{2}_{h}) = exp(−0.5()_{Am}^{2}) = _{h}(_{Am}−_{b})/_{pc}_{pc}_{1} = 1.5, _{1} = −30, _{1} = 3_{2} = −0.15, _{2} = −125, _{2} = −25 = (10_{Am}^{−5}Re)_{pc}^{0.5}/(10^{3})_{qm} = _{qm}/(_{w}β_{pc}_{p,pc}) |

Yu et al. [21] | H_{2}O | After review of the existing literatures and data | |

Kuang et al. [22] | H_{2}O | After review of the existing literatures and data |

## 3. Semiempirical heat transfer correlations

As is mentioned before, as the heat flux increases, the heat transfer deterioration phenomenon will happen. Heat transfer deterioration is characterized with lower values of the heat transfer coefficients and very high wall temperatures. A widely used quantitative expression to define the heat transfer deterioration of supercritical fluid [24, 25, 26] is shown by Eq. (1):

where * h* refers to the heat transfer coefficient of the heat transfer deterioration and

h

_{DB}is the heat transfer coefficient given by the Dittus-Boelter correlation (i.e., normal HT regime). The coefficient

*is taken as 0.3 by Schatte et al. [24]. Unfortunately, under the deteriorated HT regime, most of the empirical correlations will lose their accuracy. When deteriorated HT regime occurs, the dominated mechanism of the turbulent heat transfer is the interaction among the buoyancy, flow acceleration, and variable thermophysical properties. Unfortunately the empirical correlations can hardly reflect the heat transfer mechanism. Thus, their performances are unsatisfying, as is shown in Figure 3.*c

### 3.1 Correlation by Jackson

Jackson [12] investigated the semiempirical correlation considering the effect of the mixed convective heat transfer in a vertical heated tube. The author proposed an equivalent “buoyancy-free forced convective flow” which has the same heat transfer effect with the real supercritical fluid flow. He tried to establish the relationship between the heat transfer coefficients attenuation and the shear stress reduction based on the equivalent Nusselt and Reynolds numbers of the equivalent flow with the aid of the empirical equation under forced convective condition. Integrating the equations of momentum across the entire flow and the near-wall layer of thickness * δ*, respectively, then reorganizing the two equations leads to

_{t}

where * y* =

*, and the integrated average value of the density*δ

_{t}

ρ

_{ave}across the near-wall layer is defined by

*=*y

*in a turbulent shear flow. Then the author proposed a model which reflects the shear stress distributions in the supercritical fluid flow:*δ

_{t}

where the

where * K* is the constant and then

Combining Eqs. (4) and (5) follows that

Combining Eqs. (2) and (5) the author obtained

Or equivalently

The above equation shows the relationship between the heat transfer and the reduced shear stress across the near-wall layer. Based on this, the author considered three cases of mixing convective heat transfer in a vertical heated tube to fluid flowing either in the upward direction (i.e., the buoyancy-aided case) or the downward direction (i.e., the buoyancy-opposed case). Firstly, a model of the buoyancy-influenced heat transfer was proposed:

where * C* is a constant, Bo

_{B}

*is the buoyancy number, and*

_{b}

*is the modification on the variable properties for the buoyancy-influenced flow. As can be seen from Eq. (9),*F

_{VPB}

The second model proposed by the author was about the heat transfer due to the thermally induced flow acceleration. It shows how the acceleration of a heated flow causes the reduced turbulence production, the deteriorated HT, and the turbulence laminarization. The final form of this model is given as

where * C* is a constant, Ac

_{A}

*is the flow acceleration number, and*

_{b}

*is the modification on the variable properties for the acceleration-influenced flow. As is shown in Eq. (10), the product*F

_{VPA}

The third model was presented which describes the heat transfer under the condition where the influence of the buoyancy and the thermally induced bulk flow acceleration are combined together. Using the approach developed earlier to relate the Nusselt number ratio and the shear stress ratio, the author proposed

Here the parameter * r* indicates the ratio of

*and produced the curves of*r

*. Thus, for the upward flow, the acceleration influence promotes the buoyancy effect, whereas for the downward flow, the acceleration opposes the buoyancy effect. These trends are illustrated in Figure 5 for three values of*r

*= 0, 0.5, and 0.8.*r

### 3.2 Correlation by Li and Bai

Li and Bai [11] proposed a semiempirical correlation based on the momentum and energy integration equations in the thermal boundary layer. The authors observed the direct numerical simulation (DNS) data under deteriorated HT regime in Bae et al. [7], Hu [27], Peeters et al. [28], and Zhang et al. [29], and they found that in the turbulent core, the temperature gradient is negligible; therefore, the fluid temperature in the core is approximately the bulk temperature, especially when * T* <

_{b}

*<*T

_{pc}

*. While in the thermal boundary layer*T

_{w}

*, the fluid temperature increases from*δ

*to*T

_{b}

*(where*T

_{w}

*is the thickness of the thermal boundary layer). This can be explained as follows: the fluid within the pseudo-critical region absorbs considerable energy due to the high*δ

*, leading to the small temperature gradient in the turbulent core [7]. Based on these characteristics, Li and Bai built a “two-layer model” for deteriorated HT (as is shown in Figure 6) [11, 30]. The turbulence in the tube is divided into two layers: the thermal boundary layer and the core layer. In the thermal boundary layer, the buoyancy is strong and leads to the shear stress redistribution. However, in the core layer, the temperature and density gradients are small; hence, the buoyancy effect can be neglected.*c

_{p}

Figure 6 shows the straight tube the authors analyzed, and the flow direction is vertically upward. As is shown, the element * abcd* with a thickness of

*and a length of d*δ

*in the thermal boundary layer is chosen to build up the momentum equation:*x

In the above equation, * τ* is the shear stress at the wall and

_{w}

Assume that the pressure gradient on the cross section keeps constant. In a similar way, for the bulk flow, we could get

Subtracting Eq. (15) and Eq. (12), the pressure gradient could be eliminated and the following result could be obtained:

It is obvious that for the vertically upward flow, the radial part of the velocity (* u*) is small enough to be neglected. Thus, the term

_{r}

*. Then Eq. (16) can be simplified as*G

Note that the thickness of the thermal boundary layer * δ* is negligible compared with the radius of the tube

*. Concerning with this fact*R

The effects of the buoyancy and flow acceleration on the shear stress redistribution are reflected by the two terms at the right side of Eq. (18), respectively. According to Negoescu et al. [31], in the upward flow, the influence of the flow acceleration is much weaker compared with the buoyancy. In order to simplify Eq. (18), the authors adopted the assumption that the axial velocity * u* linearly varies within the thermal boundary layer thickness

_{b}

*. This leads to*δ

The gradient of the bulk velocity can be obtained by the analysis on the energy balance of the bulk fluid:

The authors made further assumption that * δ*(d

*/d*u

_{b}

*) in Eq. (19) is much smaller than*x

*(d*u

_{b}

*/d*δ

*). This can be interpreted as follows: the axial thickness variation of the thermal boundary layer (*x

*) is negligible compared with the axial bulk velocity (*δ

*) variation. Then Eq. (19) could be simplified as*u

_{b}

Thus, the drop of the shear stress across the thermal boundary layer can be rewritten as the following pattern:

where * k* is a nondimensional parameter reflecting the expansion of the fluid:

_{T}

Therefore, Eq. (22) can also be rewritten as

In order to build the connection between the shear stress and heat transfer, the authors analyzed the energy balance of the element * abcd* shown in Figure 6:

The physical interpretation of the budgets in the above equation can be given as follows: the first term is the wall heat flux (i.e., energy input from the boundary * ad*); the second term is the net energy input by the convection through the boundaries

*and*ab

*; the third term is the fluid energy from the core layer through the boundary*cd

*. The axial heat conduction is ignored here. The fourth and fifth terms are the energy output by the heat conduction and turbulence diffusion through the boundary*bc

*, respectively. As is indicated by Kurganov and Kaptil’ny [6], the turbulent viscosity in the thermal boundary layer drastically attenuates under the deteriorated HT regime. A factor*bc

C

_{μ1}is introduced here to reflect the ratio of the turbulent viscosities under the deteriorated HT regime and normal HT regime. Moreover, based on the mixing length assumption, the turbulent viscosity at the boundary

*is*bc

In order to give the qualitative description of * μ*, the authors applied the Bo* number and

_{t}

ρ

_{w}/

*into Eq. (27) to reflect the influence of the buoyancy force and the variable thermophysical properties:*ρ

_{b}

where * m* and

*are the exponents. Then the Nikuras-Van Driest mixing length model was chosen here [32]:*n

The wall distance ^{+} was taken as the dimensionless thickness of the thermal boundary layer, and it is defined as

For the variable-property turbulence, the local value of the thermophysical properties is more advantageous [33, 34]. Therefore, in Eq. (30) the local definitions of the density and viscosity were adopted. Considering the thermal boundary layer thickness (* δ*) minuteness, the authors omitted the terms higher than the second order in the Taylor series of the two terms at the right side of Eq. (26):

The terms on the left side of Eq. (26) can be dealt as follows:

where * H* is the average specific enthalpy across the thermal boundary layer. Then the heat transfer coefficient can be obtained based on Eq. (26):

_{ave}

The * μ* in Eq. (26) is determined by Eq. (25) and Eqs. (20)–(22). The fitting curve among

_{t}

C

_{μ1}, Bo* number, and the density ratio (

*/*ρ

_{w}

*) is obtained by the dataset of the vertically upward water flow in the circular tube under the deteriorated HT reported by Mokry et al. [9], Hu [27], Wen [35], and Wang et al. [36]. The total number of the data points is 700, with 495 data points as the fitting set and 205 data points as the assessment set. The parameters range of the dataset is given in Table 2.*ρ

_{b}

In Eq. (26), the thermal boundary layer thickness * δ* is expressed as

According to the analysis on the temperature profiles based on the data presented in the Ref. [29] which has similar working conditions, the dimensionless excess temperature exceeds 0.9 at ^{+} = 300 in the tube turbulence (for details, see Ref. [11]). For simplicity, the authors assumed an approximate value of 300 for * δ*, and then the expression of

^{+}

*can be expressed as*δ

According to Eqs. (36), (13), and (14), it can be found that the thickness of the thermal boundary layer * R* ≈ 100

*. Thus, the assumption that the thermal boundary layer thickness is negligible compared with the tube radius is reasonable. The order of magnitude of the terms in Eq. (19) is listed as follows based on the dataset:*δ

The authors got that the * u*(d

_{b}

*/d*δ

*) could be ignored compared with the term*x

*(d*δ

*/d*u

_{b}

*). Therefore, the assumption simplifying Eq. (19) is reasonable. Similarly, the order of magnitude of the parameters in Eqs. (32) and (33) could be analyzed as follows:*x

Therefore,

The second and third terms at the left side of Eq. (26) are far less than the _{w} in the left side; thus, they could also be ignored. Eq. (34) could be simplified as

Plugging Eqs. (25), (27)–(30), and (36) into Eq. (43), the final form of the model could be obtained after some arrangements:

where _{μ1} was obtained as follows:

For

For

Here the parameter * P*,

*,*G

*,*q

_{w}

*). The range of the parameters in the new correlation is*d

*= 23–30 MPa,*P

*= 200–900 kg m*G

^{−2}s

^{−1},

*= 129–700 kW m*q

^{−2},

*= 7.6–26 mm, 3 × 10*d

^{−6}<

^{−4}.

Figure 7 depicts the results of the model evaluation based on the above assessing procedure. It is clear that all the existing correlations could not obtain the tendencies of the wall temperature under the heat transfer deterioration regime. The semiempirical model proposed by Li and Bai shows comparatively higher accuracy compared with the existing correlations, especially at the peak region of the wall temperature. Most of the existing correlations significantly overestimate the heat transfer coefficients under the heat transfer deterioration regime.

In Figure 8, the error graphs of different heat transfer correlations (here the fitting set and the assessment set are both included) are shown. It is shown that the semiempirical correlations introduced here are correlated well with the heat transfer coefficients dataset. Seventy-two percent and 63% of the data points fall into the error bars of ±30% and ±25%, respectively. In order to further investigate the predicting capacity under the deteriorated HT regime, the authors introduced another two statistical parameters: the mean relative error (* MRE*) and the root mean square error (

*) to evaluate the different correlations performance. Their definitions are given in Eqs. (47)–(49), and the comparison results are shown in Table 3. As can be seen, the Li and Bai correlation can give the smallest prediction errors, thus proving its suitability and superiority.*RMSE

## 4. Conclusions

The approach to establishing the heat transfer correlations of supercritical fluids is a critical issue since the correlations play very important role in the design and optimization of the systems and devices. In this chapter, we have discussed the principles and applications of the heat transfer correlations of supercritical fluids. The modeling approaches of the correlations of supercritical fluid heat transfer are reviewed, including the nondimensional parameters applied on the modification of the empirical correlations and the “equivalent buoyancy-free flow method” used for the semiempirical correlations.

Then we introduce a new physically based semiempirical correlation which is based on the momentum and energy conservations in the mixing convective flow. Considering the mechanism of heat transfer deterioration, a physical model characterizing the redistribution of the shear stress under the combined effect of buoyancy and flow acceleration was obtained. Then the model about the heat transfer coefficients under the influence of the reduced shear stress was derived by the energy integration equation within the thermal boundary layer. Based on this, a semiempirical heat transfer correlation was proposed and then verified with a wide range of experimental data. Compared with the existing correlations, the prediction accuracy of this newly developed correlation is significantly improved under the heat transfer deterioration regime. The investigation on the different statistical parameters shows that this semiempirical correlation is superior to the empirical ones.

## Acknowledgments

This study is supported by the National Key Research and Development Program of China (no. 2016YFB0600100) and the China National Funds for Distinguished Young Scientists (no. 51425603).

## Abbreviations

Dittus-Bolter

direct numerical simulation

EXP

experimental results

heat transfer

MRE

mean relative error

PRE

results given by correlations

RE

relative error

RSME

root mean square error

## Appendices and nomenclature

flow acceleration parameter

Jackson buoyancy parameter

***

_{m}

the maximum Jackson buoyancy number under a specified working condition

Bae and Kim buoyancy parameter

c

_{1},

c

_{2},

c

_{k}

exponents in the empirical correlations (in Figure 2)

c

_{p}

specific heat (J kg^{−1} K^{−1})

average specific heat in the thermal boundary layer (=(* H* −

_{w}

*)/(*H

_{b}

*−*T

_{w}

*)) (J kg*T

_{b}

^{−1}K

^{−1})

*,*C

_{μ}

C

_{μ1}

the correction coefficients under heat transfer deterioration in the Li and Bai correlation

*,*C

_{A}

*,*C

_{B}

C

_{μ1},

*,*C

_{d}

*,*m

n

constants in the Li and Bai correlation

d

inside diameter of the circular tube (m)

f

Fanning resistance coefficient

*,*F

F

_{1},

F

_{2}

constants in the Cheng correlation

the modifications on the variable properties for the “equivalent” buoyancy-free flow

the modifications on the variable properties for the real flow

the modification on the variable properties for the acceleration-influenced flow

the modification on the variable properties for the buoyancy-influenced flow

g

gravitational acceleration (m s^{−2})

G

mass flux (kg m^{−2} s^{−1})

Grashof number

h

local heat transfer coefficient (kW m^{−2} K^{−1})

H

enthalpy (kJ kg^{−1})

k

_{T}

the dimensionless number reflecting the expansion of the fluid

l

_{m}

the mixing length (m)

m

_{1},

m

_{2},

m

_{4},

n

_{2}

the exponents in the Jackson’s semiempirical model

Nusselt number

P

pressure (MPa)

Prandtl number

average Prandtl number across the thermal boundary layer

_{t}

turbulent Prandtl number

q

wall heat flux (kW m^{−2})

r

radial coordinate (m)

R

tube radius (m)

Reynolds number

T

temperature (K)

*,*X

Y

nondimensional parameters in the empirical correlation (in Figure 2)

*,*Y

Y

_{1},

Y

_{2},

*,*K

_{h}

*,*K

_{Am}

K

_{qm}

constants in the Deev correlation

y

distance from the wall (m)

y

^{+}

nondimensional distance from the wall

Greek symbols

λ

thermal conductivity (W m^{−1} K^{−1})

β

thermal expansion rate (K^{−1})

ρ

density (kg m^{−3})

μ

dynamic viscosity (Pa s)

δ

thermal boundary layer thickness (m)

δ

^{+}

nondimensional thermal boundary layer thickness in wall units

θ

nondimensional excess temperature

φ

the constant in the Li and Bai correlation

ψ

the functional expression for the acceleration-influenced or buoyancy-influenced heat transfer

τ

shear stress (Pa)

Supercripts

T

transpose matrix

Subscripts

A

flow acceleration effect

ave

average value over the thermal boundary layer

B

buoyancy effect

BA

combined effect of the buoyancy and flow acceleration

b

bulk value

max

maximum

F, f

forced convection

l

definition based on the local values

t

turbulence

pc

pseudo-critical point

w

values at the wall

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