Solar cell and module efficiency ranges reported in late 2018.
\r\n\tgas sensors.
",isbn:"978-1-80356-963-5",printIsbn:"978-1-80356-962-8",pdfIsbn:"978-1-80356-964-2",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!0,isSalesforceBook:!1,isNomenclature:!1,hash:"8eeb7ab232fa8d5c723b61e0da251857",bookSignature:"Dr. Soumen Dhara and Dr. Gorachand Dutta",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/11513.jpg",keywords:"Fabrication Technologies, Applications, Characterizations, Case Studies, Various Gas Sensors, Improvement of Lifestyle, Societal Benefit, Bio-Sensors, Bioreceptor Molecules, Integration, Packaging, Lab-on-Chip",numberOfDownloads:null,numberOfWosCitations:0,numberOfCrossrefCitations:null,numberOfDimensionsCitations:null,numberOfTotalCitations:null,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"April 8th 2022",dateEndSecondStepPublish:"June 17th 2022",dateEndThirdStepPublish:"August 16th 2022",dateEndFourthStepPublish:"November 4th 2022",dateEndFifthStepPublish:"January 3rd 2023",dateConfirmationOfParticipation:null,remainingDaysToSecondStep:"2 months",secondStepPassed:!0,areRegistrationsClosed:!1,currentStepOfPublishingProcess:4,editedByType:null,kuFlag:!1,biosketch:"A pioneering researcher in nanowire heterostructures and laser spectroscopy, recipient of JSPS (Govt. of Japan) and NPDF (Govt. of India) fellowships, and member of MRS(USA), MRS(India), IPA(India).",coeditorOneBiosketch:"Assistant Professor with the School of Medical Science and Technology, Indian Institute of Technology Kharagpur with research interests that include the design and characterization of portable biosensors, biodevices, and sensor interfaces for miniaturized systems and biomedical applications for point-of-care testing.",coeditorTwoBiosketch:null,coeditorThreeBiosketch:null,coeditorFourBiosketch:null,coeditorFiveBiosketch:null,editors:[{id:"196334",title:"Dr.",name:"Soumen",middleName:null,surname:"Dhara",slug:"soumen-dhara",fullName:"Soumen Dhara",profilePictureURL:"https://mts.intechopen.com/storage/users/196334/images/system/196334.jpeg",biography:"Dr. Dhara received his Ph. D in Physics in 2012 from Indian Institute of Technology Guwahati, India. Presently, he is associated with the Faculty of Science, Sri Sri University, India as an Assistant Professor in Physics. Prior to joining the current\naffiliation, he was a postdoctoral fellow at different renowned institutions, Kobe University Japan, S. N. Bose National Centre for Basic Sciences, India and Cardiff University, United Kingdom. He was awarded prestigious JSPS postdoctoral fellowship based on his research contribution on semiconducting nanowires. He has published more than 32 research articles including 1 review article in high profile international journals and 3 book chapters to his credit. His research trust areas of interests are semiconductor nanostructures, optoelectronics, solid state lighting and light sensors, spectroscopy of nanomaterials, thin-film transistors (TFTs) etc.",institutionString:"Sri Sri University",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"2",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"Sri Sri University",institutionURL:null,country:{name:"India"}}}],coeditorOne:{id:"442408",title:"Dr.",name:"Gorachand",middleName:null,surname:"Dutta",slug:"gorachand-dutta",fullName:"Gorachand Dutta",profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:"Dr. Gorachand Dutta, PhD is an Assistant Professor with the School of MedicalScience and Technology, Indian Institute of Technology Kharagpur. His research interests include the design and characterization of portable\r\nbiosensors, biodevices and sensor interfaces for miniaturized systems and biomedical applications for point-of-care testing. He received his Ph.D in Biosensor and Electrochemistry from Pusan National University, South Korea,\r\nwhere he developed different class of electrochemical sensors and studied the electrochemical properties of gold, platinum, and palladium based metal electrodes. He completed his Post-doctoral fellowships in the Department of\r\nMechanical Engineering, Michigan State University, USA and Department of Electronic and Electrical Engineering at University of Bath, UK. He has expertise on label-free multichannel electrochemical biosensors, electronically\r\naddressable biosensor arrays, aptamer- and DNA-based sensors and surface bio-functionalization.",institutionString:"Indian Institute of Technology Kharagpur",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"0",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"Indian Institute of Technology Kharagpur",institutionURL:null,country:{name:"India"}}},coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"11",title:"Engineering",slug:"engineering"}],chapters:null,productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},personalPublishingAssistant:{id:"429341",firstName:"Paula",lastName:"Gavran",middleName:null,title:"Ms.",imageUrl:"//cdnintech.com/web/frontend/www/assets/author.svg",email:"paula@intechopen.com",biography:null}},relatedBooks:[{type:"book",id:"10198",title:"Response Surface Methodology in Engineering Science",subtitle:null,isOpenForSubmission:!1,hash:"1942bec30d40572f519327ca7a6d7aae",slug:"response-surface-methodology-in-engineering-science",bookSignature:"Palanikumar Kayaroganam",coverURL:"https://cdn.intechopen.com/books/images_new/10198.jpg",editedByType:"Edited by",editors:[{id:"321730",title:"Prof.",name:"Palanikumar",surname:"Kayaroganam",slug:"palanikumar-kayaroganam",fullName:"Palanikumar Kayaroganam"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1591",title:"Infrared Spectroscopy",subtitle:"Materials Science, Engineering and Technology",isOpenForSubmission:!1,hash:"99b4b7b71a8caeb693ed762b40b017f4",slug:"infrared-spectroscopy-materials-science-engineering-and-technology",bookSignature:"Theophile Theophanides",coverURL:"https://cdn.intechopen.com/books/images_new/1591.jpg",editedByType:"Edited by",editors:[{id:"37194",title:"Dr.",name:"Theophile",surname:"Theophanides",slug:"theophile-theophanides",fullName:"Theophile Theophanides"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3161",title:"Frontiers in Guided Wave Optics and Optoelectronics",subtitle:null,isOpenForSubmission:!1,hash:"deb44e9c99f82bbce1083abea743146c",slug:"frontiers-in-guided-wave-optics-and-optoelectronics",bookSignature:"Bishnu Pal",coverURL:"https://cdn.intechopen.com/books/images_new/3161.jpg",editedByType:"Edited by",editors:[{id:"4782",title:"Prof.",name:"Bishnu",surname:"Pal",slug:"bishnu-pal",fullName:"Bishnu Pal"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"371",title:"Abiotic Stress in Plants",subtitle:"Mechanisms and Adaptations",isOpenForSubmission:!1,hash:"588466f487e307619849d72389178a74",slug:"abiotic-stress-in-plants-mechanisms-and-adaptations",bookSignature:"Arun Shanker and B. 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Although market grows day by day and correspondingly employment rate increases, this brings many problems associated with the quality of the system due to several factors [1]. PV system installations have increased, and now in annual installations, PV is one of the leading power capacity additions. In 2018, over 100 GW of new PV power capacity was added. The annual PV capacity addition in 2018 was more than the total installed capacity in 2012. Total installed PV power capacity was in excess of 500 GW at the end of 2018 [2]. The power produced by a PV system depends on a range of factors which need to be examined when the system is designed [3]. These factors can be given such as operating conditions, the details of the configuration of the system, the location of the system, the amount of received solar radiation, the ambient temperature, and other climate-related aspects.
\nThis chapter provides an introduction to the PV system configuration and the influences of these parameters on PV system performance.
\nThere are two main classifications of PV systems. The first one is grid-connected where PV modules produce their maximum energy and they always feed the produced electricity in the form of local electricity grid. The other is stand-alone PV systems that operate independent from the grid, and they supply the electricity for the specified load. In these types of systems, PV modules do not operate at their maximum. Thus, power and generated energy values are limited with the capacity of storage. Grid-connected PV system schematic is simple and given in Figure 1.
\nSchematic diagram of a grid-connected PV system.
The grid-connected system is often classified into two as distributed and centralized systems. Small systems are generally distributed and have a capacity less than 100 kW. Most of these systems are installed on roofs or at the top (garage, patio, winter garden, etc.) or beneath the buildings. Although distributed systems are connected to low-voltage grid and meet the local load centralized PV systems which are connected at a higher voltage, the main purpose of them is feeding the general grid supply. There has been an increase on the side of grid-connected ratio since 2009 because of the high-efficiency ratio of the PV system with respect to stand-alone PV systems as well as simplifications and improvements in grid connections. According to the IEA PVPS data, grid-connected PV systems represented around 62% of the cumulative installed PV capacity at the end of 2017 where this ratio is only 22% in 2009 [4].
\nThe stand-alone system operates independently from the grid and provides the power and electricity of the specified load or loads. There is a charge controller and a battery bank different from the grid connected to the PV system. Moreover the inverter operates in a different way. The charge controller controls the charging and discharging of batteries and consists of a maximum power point (MPP) tracker for operating PV modules at a maximum power. A schema of stand-alone PV system is given in Figure 2 with different loads.
\nSchematic diagram of a stand-alone PV system.
The hearth of the PV system is the solar cell itself where a range of semiconductors are used in solar cells. PV modules have to offer a high performance, a stability in operation, and good and low-cost manufacturability, and they have to perform a long lifetime. Electricity yield is important for PV modules. Currently the installations in the established PV market are dominated by crystalline silicon (c-Si, including mono- and multicrystalline silicon). Other commercial PV technologies in the market are cadmium telluride (CdTe), copper indium gallium diselenide (CIGS), amorphous silicon (a-Si), and several hybrid designs. There are also different types of solar cells like organic and polymer-based cells and some multi-junction cells. Some of them are in the market with a small ratio, and they are classified in emerging PV technologies [5]. In terms of performance, the most important difference between the module types is the conversion efficiency which is the ratio of the electrical output and the amount of solar irradiation received to the solar cell or module plane. There is a continuing development in cell and module efficiencies under tests, and the results are periodically publicized in some journals, and the latest solar cell and module efficiencies are summarized in Table 1 [6].
\nModule technology | \nEfficiency range under standard test conditions, large area (module efficiency) (%) | \nHighest reported laboratory efficiency, small area (%) | \n
---|---|---|
Crystalline silicon (sc-Si) | \n16–24.4 | \n26.7 | \n
Multicrystalline silicon (mc-Si) | \n15–19.9 | \n22.3 | \n
Amorphous silicon (a-Si) | \n6–11.9 | \n14.0 | \n
CdTe | \n14–18.6 | \n21.0 | \n
CIGS | \n15–19.2 | \n22.9 | \n
Multi-junction | \n21–31.2 | \n32.6 | \n
Organic | \n6–8.7 | \n11.2 | \n
Solar cell and module efficiency ranges reported in late 2018.
The other parameters affecting the PV system performance are spectral distribution of light, temperature coefficients of PV module, cell stability, encapsulation quality, shading effect, design of PV modules (wiring of PV modules, number of series-parallel-connected PV modules), and other components like inverter and wiring other than the PV modules, namely, balance of system (BOS) equipment.
\nSolar cells are the hearth of electrical conversion, and their electrical characteristics are similar with diodes. Therefore their current, I, and the voltage, V, relation will be given in Eq. (1):
\nHere, \n
In real devices, some parasitic resistances have to be defined. \n
Under these acceptances I-V characteristics of a real solar cell can be given by Eq. (2):
\nSolar cells can be connected in series or parallel to achieve higher current and voltage values. Only the values of current and voltage values can be changed in larger PV arrays. This equation can be applied to a variety of solar cell types. Only some parameters (like diode quality factor) will show different values which cannot be physically described easily. But mathematically the equation overlaps the experimentally obtained values. As power is the product of current and voltage \n
The current-voltage and power-voltage characteristics for a solar cell/PV module/array.
Most of the PV module performance parameters are given in Eq. (2), and the resulting characteristics are given in Figure 3. \n
where A is the total area of the device [6, 7].
\nUnder ideal circumstances, PV devices operate at MPP, but in real operating conditions, PV devices operate round MPP, and most PV systems have maximum power point tracking units to operate with a minimum loss of power available from the device. In electrical connection of PV modules in forming PV arrays, it is very important to connect identical PV modules in the same lines for the best performance. Sometimes while designing the PV array, there should be some restrictions in obtaining uniform irradiation on the same array. If the PV modules do not have uniform irradiation, the electrically series-connected units obey the weakest one, and this results in a decrease in the output and loss of performance.
\nThe output of the PV devices changes under operating conditions, so PV modules are produced and launched to the market according to the power values of the device obtained at a standard set of operating conditions. These conditions are standard test conditions (STC): irradiance of \n
PV device/module efficiency and performance parameters are given above. But a PV system consists of other components. For this reason, these components’ efficiency values have to be taken into account while calculating the system efficiency. The end user is interested in the electricity produced by the PV system and its lifetime under real operating conditions because this directly influences the payback period or return time of the investment. The commonly used energy-rating standard for PV modules is given by the International Electrotechnical Commission (IEC) with IEC61853 (PV performance testing and energy rating part 1) [7]. Also the location of the system has to be considered while sizing the PV system. Energy yield measurements of PV systems at different climatic locations play an important role in the validation of the energy rating standard, deeper understanding of PV performance, and lifetime. Long-term and accurate measurements under real operating conditions are necessary, but there is currently no standard on how these measurements should be performed [9]. Most analyzers use inverter output or meter data for calculating the performance of PV systems. If the system is stand-alone, some other parameters like night loads and loss of load probability have to be regarded while designing the system. Energy yield and performance ratio (PR) values are the other parameters which defines the system’s overall performance. Only PV efficiency is given in Eq. (3), but the power output of the whole system and calculation of efficiency using this output is very important, considering the other losses like wiring losses and inverter losses. In grid-connected PV systems, electricity output, solar resource, and system losses are the main parameters. Accurate evaluation of PV system performance is critical for PV industry.
\nPerformance ratio defines the performance of the system [10, 11]. It is dimensionless and given as the ratio of \n
where the final PV system yield \n
And the reference PV system yield \n
Long-term PR calculation takes the system failures into consideration so it gives better results. But PR is neglected by some researchers, and only the electricity output per installed power is taken into account. Namely, they calculate only \n
Instead of defining the overall performance of the system, sometimes it is useful to consider the specific performance of a certain part of the system to find the correct design. Sometimes the output will not match the expectations. It will be PV array output or PV system output. In that situation, some modules, wirings, or other components will be analyzed. Most inverters give DC and AC power values at a certain time, so it is easy to calculate their exact efficiency. PV system operates during the daytime, so inverters also operate and their output values also vary. In semi-cloudy days, sometimes there should be a sudden decrease and increase in the irradiation level, and this causes a big difference in electrical value. Also the inverter efficiency varies sharply. At low irradiation levels, inverter efficiencies are low, but generally after 15% of their nameplate power, their efficiency is round 90%. Because of the variation in the irradiation level, input and output power, a new efficiency classification is defined in inverter efficiency calculation. It is Euro Efficiency or California Energy Commission (CEC) efficiency. Both are weighed efficiency values, and they use different efficiency values at different power input values and give lower than the peak efficiency but more representative values.
\nThe output of a PV system depends on various parameters, but one of the most important parts is the PV modules used. The electrical performance and output are given in Section 3 with module characteristics. Whether these characteristics are taken in laboratory conditions or in outdoor conditions, it is possible to translate the parameters to STC values and compare the nameplate values. A typical setup for laboratory I-V curve measurements is shown in Figure 4. The setup consists of a light source, a reference device for the determination of irradiance during the measurement, some temperature sensors, and an electronic load [12]. Measurement systems also include software for collecting the measured data and translating the desired values to STC with existing I-V curve with given parameter coefficients.
\nSchematic setup for I-V curve measurements at laboratory [
It is well known that PV modules operate under a wide range of temperature, irradiation level, angles of incidence of the sunlight, and spectral distribution. All these conditions affect the electricity output of the PV module. The temperature dependency of the PV module can be determined from the I-V curves at different temperature values and constant irradiance values in laboratory tests. In a similar line with these temperature dependencies, irradiance dependency, spectral response, and thermal behavior characteristics can be determined. There are a lot of universities and research labs all over the world that use several setups for measuring I-V at indoor, but it is not so easy to control and arrange some outdoor parameters. Generally, some meteorological parameters are used in the calculations and measured in different setups, or they can be included in the I-V curve measurement system shown in Figure 5.
\nSchematic setup for I-V curve measurements at outside.
In some measurements, sense measurements are not used, but the presence of sense measurements supports the accuracy of the collected data. And, current measurements are evaluated with a precisely known value of shunt resistors. These sets of measurements increase the accuracy of the data. It is also difficult to get data close to short circuit, because the presence of a load complicates collecting data. An external power supply helps overcoming this problem, and researchers get more precise data for drawing the I-V curve and determining the PV module parameters [14].
\nPV module characterization methods are outlined in Section 4. Computer simulation tools are used to predict the electricity production of PV systems which are necessary for economic decisions [15]. Some input parameters like operation situations, environmental conditions and the location of the system are necessary for characterizing PV module and for electricity output of the system. The required number of input parameter depends on the complexity of the tool. The prediction of PV electricity yield is very important. Different technologies are used in PV systems [16, 17, 18]. Crystalline silicon technology based on PV modules dominates the market. Besides, there are other technologies which are used as PV modules that depend on the location of the installation and amount of electricity produced and meet in seasons. In sunny and coastal regions in summer, thin-film PV modules will perform better than crystalline silicon PV modules, while in high locations and during winter season crystalline silicon-based PV modules perform better than thin film because of the temperature coefficients. To understand technological differences and over or under performance of one technology with respect to other under specific climatic conditions, not only the power under STC is enough. It should be necessary to know the quality and the performances of other equipment in PV system [9]. Most of the people (users or investors) mind only the electricity yield while they decided to install a PV system. For grid-connected PV systems, electricity cost (levelized cost of electricity (LCOE)) has to be comparable with grid prices. For increasing the PV electricity usage or producing PV system equipment, there are different support schemes in countries. This support appears sometimes in tax incentives sometimes like feed in tariff (FiT) and sometimes in self-consumption or various schemes. Grid parity is caught for several countries which have higher annual irradiation and sometimes different supporting schemes like self-consumption are applied. For the other countries, there are different support schemes for declining electricity cost. LCOE as a function of solar resource for some countries are given in Figure 6 [4]. Installation cost per kW-dependent LCOE is also given in Figure 6. LCOE depends on PV system size and location, so retail prices for some countries are wide (e.g., USA; although PV system has the same size, electricity prices are in the range of 0.04–0.32 USD).
\nPV electricity cost as a function of solar irradiance [
In this chapter, PV electricity and the characterization methods used to determine PV module are summarized. PV performance measurement methods and electricity cost per installed power is discussed. Although installed PV capacity on earth is about 500 GW, PV contribution to global electricity demand is still less than 3%, PV installation cost continues to decrease, and the main point is the cost of PV electricity. In order to be competitive with the market prices, PV electricity cost will have to be as low as it. This will be achieved with large-scale PV installations, low installation costs, and low maintenance cost.
\nGeopolymers are inorganic amorphous aluminosilicates. Geopolymers are made up of chains of AlO45− and SiO44− tetrahedra that are irregularly connected by these tetrahedra. These chains are arranged in layers, and between them, there are cations of sodium as well as groups of OH and H2O. In this structure, there are periodic cations of aluminium, surrounded by four oxygen atoms [1].
The geopolymer binder binds and hardens as a result of many chemical reactions between aluminosilicate oxides in a strongly alkaline environment, forming three-dimensional polymer chains Si–O–Al–O [2, 3]. The geopolymerisation mechanism is highly dependent on the nature of alkaline activators as well as the chemical composition of precursors. The components used as precursors for geopolymerisation are low calcium aluminosilicates, e.g. silicious fly ash or blast-furnace slag. As shown in the figure, in addition to fly ash and granulated blast-furnace slag, raw materials such as metakaolin, halloysite and volcanic tuff are good precursors (Figure 1). According to Davidovits [2], the process of geopolymerisation consists of four main stages (dissolution, diffusion, polycondensation and hardening). This process was also described in a similar way by Glukhovsky [1]. De Silva et al. [3] suggested a three-step description of the geopolymerisation process (dissolution, agglomeration and polycondensation). Currently, one of the most important experts in the technology, microstructure and process of geopolymerisation of geopolymer materials is an Australian professor – John Provis, who promotes renaming geopolymers as Alkali-Activated Materials (AAM) [4].
Scheme for obtaining geopolymers.
Geopolymers are cementless, hardened, mechanically resistant materials with properties similar to natural stone or well-known concrete. The bonding process of such materials is different compared with the hydration process of cement, which involves the hydrolysis of calcium silicates and the formation of a hydrated C-S-H phase, with the simultaneous release of calcium hydroxide. The bonding process of geopolymers is slower compared with cement bonding. However, according to the literature, this time is sufficient to use the geopolymer binder to obtain concrete [2].
The preliminary research, held in the 1970s of the twentieth century in Poland, had led to development of geopolymer material by alkaline activation of granulated blast-furnace slag [5, 6, 7, 8]. These studies were pioneering research in the country, which was a starting point for the numerous studies on geopolymer binder in other research centres such as Ł-ICIMB in Cracow, AGH in Cracow, Cracow University of Technology, and Poznan University of Technology. As it turned out, the volcanic tuff from Filipowice proved to be a good precursor for obtaining geopolymer materials [9]. In addition, the authors of the cited study have shown that post-mining waste such as coal shale [10], fly ash from lignite combustion [11] and calcined clay [12] can be an attractive material for the production of geopolymer binders.
The Ł-ICIMB (Łukasiewicz Research Network – Institute of Ceramics and Building Materials) has been conducting research on the use of fly ash from national power plants as a precursor for the production of geopolymer concrete [13, 14, 15]. Based on the XRD, SEM and thermal studies, it was found that the binding and hardening processes of cementless binder, based on fly ash, are the result of the dissolution of the active components of fly ash in a solution of sodium hydroxide. Obtained gel of silicoaluminates crystallises to form a hydrated sodium aluminosilicate of the sodalite or other type of zeolites such as: hydrosodalite, zeolite P, chabazite-Na and faujasite [16]. The resulting phases are durable and resistant to water and ambient environment, as confirmed by long-term strength tests [15, 17].
The degree of suitability of fly ash for geopolymerisation is determined by the SiO2/Al2O3 ratio [18] and the CaO/SiO2 ratio [19, 20] in fly ash, which determine the content of active components, which enter the solution under the influence of an alkaline activator [21]. According to the literature, most fly ashes have suitable properties, allowing the obtaining of binding cementless binders [18, 22]. However, as shown in [13, 15], the most advantageous fly ash allowing the production of high-strength binders and concrete is silicious micro-fly ash. The ability to convert the fly ash into geopolymer material is related mainly to the glassy phase composition, degree of gradation and loss of ignition [23, 24, 25].
Many studies have been conducted on the production of geopolymer materials based on fly ash [13, 17, 26, 27, 28]. The properties of hardened materials depend not only on the properties of the precursors, but also on the used activators. The most commonly used activators are sodium or potassium water glass, NaOH or KOH solution or a mixture of these compounds at experimentally determined proportions and concentrations [29, 30, 31, 32]. The use of hydrothermal treatment (low-pressure steaming or autoclaving) accelerates the geopolymerisation reaction [16, 33, 34].
Geopolymer binder and concrete are widely considered to be low-carbon materials. Recently, many research centres around the world are undertaking research in the field of technology to obtain such materials. This has been included in the Roadmap of the European Cement Association (CEMBEREAU) as one of the options for reducing direct carbon dioxide emissions from the cement industry [35]. Taking into account that the cement industry is currently responsible for around 7% of anthropogenic CO2 emissions [36], the proposal of the use of geopolymer binders in a partial exchange for high-energy and energy-consuming cement binders can significantly reduce the environmental burden and protect raw materials resources by increasing the use of waste materials and industrial waste. However, according to the literature review, most of the available studies have used either large quantities of alkaline activators or thermal processing in order to obtain geopolymer materials with properties comparable to or superior to traditional cement concrete. Such procedures raise production costs and energy consumption [37].
However, high cost of activators is a serious hindrance in the wide and industrial application of cementless geopolymer materials. This main reason hinders the competitiveness of alkali activated binders to Portland cement in spite of a much less energy-consuming of geopolymer binders. According to the data presented in [38], almost 60% of carbon dioxide emission from the process of producing geopolymer materials is associated with the production of alkaline activators. Therefore, some authors of publications on the production of geopolymer concrete believe that this technology does not lead to a significant reduction in carbon dioxide emission [39, 40, 41]. When making a reliable assessment of the environmental impact of the production and use of geopolymer materials, it is important to pay attention to the method of calculation and the data adopted by the authors. As Davidovits [42] explains, taking into account the life cycle of concrete, the production and use of geopolymer concrete lead to a reduction in CO2 emissions. Furthermore, a majority of the authors believe that using geopolymer concrete instead of traditional cement concrete reduces CO2 emission into the atmosphere [43, 44, 45, 46].
The development of geopolymer technologies is justified because of the environmental and economic aspects, as well as the expectations of civil engineers. This technology is currently under research not only in the sphere of aggregate concrete but also in the technologies of obtaining lightweight geopolymer concrete [47, 48], self-compacting geopolymer concrete [43, 49] and even geopolymer foam concrete [44] or reinforced geopolymer concrete [27, 47].
The number of publications devoted to geopolymer concrete is constantly growing. In 2019–2020, it amounted to around 5200 and was almost twice as high as in 2017–2018 and more than eight times as high as in 2011–2012 [50]. However, only about 10% of the publications concern research on the aspects of construction and engineering applications [28], while the remainder is confined to laboratory-scale research [48, 51]. Despite many studies, the results of which can be observed in numerous publications [27, 28, 43, 44, 47, 48, 49, 51, 52, 53, 54], geopolymer concrete has not received international appreciation as a construction material. It seems to be necessary to develop standards for the production of geopolymer concrete and procedures for designing geopolymer concrete structures [50].
An example of one of the first uses of geopolymer concrete is the building of the University of Queensland – Global Change Institute (GCI). The structure of this four-storey building is constructed from, among other, suspended slab floors and facade panels made of geopolymer concrete. The precursor used for the production of geopolymer concrete was a mixture of fly ash and blast-furnace slag [55]. In Australia, a widely developed technology is the production of sewer pipes, railway sleepers, burial crypts, culverts and wall panels from geopolymer concrete [56, 57]. Currently, one of the largest applications of geopolymer concrete is the element of the taxiway at Brisbane West Wellcamp Airport [58]. Long-term durability studies preceded the use of this concrete as a structural material [57]. However, according to Srividya et al. [50], in the current state of knowledge, it is necessary to further document the durability of such material under different exposure conditions and over a longer period of time. Regardless of ongoing research around the world, extensive literature reviews summarising scientific achievements in the field of geopolymer concretes have been published in recent years [37, 50].
The presented chapter presents the results of research on geopolymer materials obtained in the process of alkaline activation of fly ash and on geopolymer concrete with their participation. The optimal parameters of the activator quantity and the cure method for obtaining high-strength concrete were determined in previous works [13, 15]. Preliminary research carried out at the Ł-ICIMB on the development of an active additive for cement and concrete based on domestic kaolin resources has led to the establishment of optimal conditions for the thermal processing of raw clay for the conversion of the kaolin component into amorphous metakaolin [59]. The chapter also presents extensive studies and their results on increasing the durability of concrete in a low-temperature environment by enriching the concrete formula with kaolin mineral additive which were partially discussed in [15].
Three types of fly ash were selected for the study: siliceous fly ash from hard coal combustion (FA1, FA2), fluidised fly ash from lignite combustion (FA3) and calcareous fly ash (FA4, FA5, FA6). FA2 ash, termed ‘micro-fly ash’ was selectively sampled. The FA5 and FA6 calcareous fly ashes were subjected to special treatment to improve some of their properties. The carbon fractions were extracted and rejected from the FA5 and FA6 ash. Moreover, the FA6 ash was additionally ground after the separation of the carbon fractions. Figure 2 shows SEM image of the ashes used in the study.
SEM image of: A: ‘micro-fly ash’ - FA2, B: calcareous fly ash after the carbon extraction - FA5, C: extracted carbon particles from calcareous fly ash -FA4, and D: calcareous fly ash after additional grinding - FA6 [
Based on SEM image observations, it was found that the ashes used in the studies differed significantly in size and shape of the particles. While micro-fly ash (FA2) is characterised by fine oval-shaped particles (Figure 2A), calcareous fly ash is characterised by a more irregular shape (Figure 2B). The additional grinding of the calcareous ash after extraction of the carbon fractions (Figure 2C) resulted in the release of fine particles from conglomerates of larger ash particles as shown in Figure 2D. As a result of this procedure, very fine-grained ash was obtained. The results of the laser analysis obtained for FA2 and FA6 ashes are shown in the diagram (Figure 3).
Cumulative curve of particle size distribution of FA2 and FA6 fly ashes.
FA2 and FA6 ash particles showed significant differences in the granulometric distribution of these samples. FA2 fly ash is characterised by a predominant number of grains smaller than 10 μm (more than 90%). The maximum FA2 ash particle size was about 50 μm. The FA6 fly ash sample is characterised by larger particles. The percentage of particles smaller than 10 μm is about 40%, despite the additional grinding of the ash. The maximum particle size for this sample is about 100 μm. By analysing the particle size distribution curve of FA6 fly ash, it can be concluded that this material has a particle accumulation in the range of 10–60 μm and 0.5–1 μm.
As an additive to increase the durability of geopolymer concrete, a material containing a metakaolin component obtained by calcination of waste clay was used in the studies. The conditions of calcination were established on the basis of XRD studies and on the basis of the results of studies obtained using thermal analysis [13]. The phase composition of the clay used, as determined by XRD studies, is shown below.
The clay used contains significant amounts of calcite (Figure 4, Table 1). As can be seen fromFigure 4, characteristic lines for calcite of considerable intensity are observed. The other components of the clay are kaolinite, quartz and a trace of minerals with a total content of less than 1%.
XRD pattern of the raw waste clay.
Material | Quantitative contribution of phase composition [%] | Standard deviation [%] |
---|---|---|
Calcite | 67.7 | 0.38 |
Kaolinite | 17.9 | 0.42 |
Quartz | 13.6 | 0.14 |
Anatase | 0.40 | 0.06 |
Calcium titanate | 0.40 | 0.10 |
Quantitative phase composition of the raw waste clay.
Based on DTA and DTG curves, dihydroxylation of kaolinite present in the waste clay begins in the temperature above 400°C, with the maximum of the endothermal effect at the temperature of 560°C (Figure 5). As a result of dihydroxylation, the metakaolin arises. According to Kurdowski [61], simultaneously with further temperature increase, the OH− ions are eliminated and the structure of metakaolin is destroyed. The spinel phase of aluminosilicate and silicon is formed. Further temperature increase leads to conversion of these phases into mullite.
DTA and DTG curves of the raw waste clay sample.
The DTA and DTG curves (Figure 5) also show an endothermic effect with a maximum temperature of 800°C associated with the decomposition of calcite. According to the accepted assumptions, the thermal activation temperature used in the waste clay studies should lead to the transformation of kaolinite into metakaolin, preventing its crystallisation into mullite. In addition, the thermal activation of clay assumes the lowest possible calcination temperature to prevent the complete decomposition of calcium carbonate in order to achieve the lowest possible level of CO2 emissions. For the waste clay used in the study, the time of calcination was established to 2 hours and the optimum temperature of this process was determined as 700°C.
The fly ash was activated using the 8 M NaOH solution. The ratio of the alkaline solution (as an activator) to the fly ash was determined experimentally. It was 0.5 or 0.6 depending on the applicable fly ash. The samples in the form of prisms with dimensions of 40 x 40 x 160 mm were prepared for testing. After ash paste was obtained, the samples were cured under low-pressure conditions at 80°C with an ongoing 24-hour heating-maturing-cooling cycle. The samples were then subjected to compressive strength tests, which are summarised in Figure 6.
Compressive strength of the fly ash pastes activated with the 8 moles/dm3 NaOH solution and steam cured under low pressure at 80°C [
In addition, to determine the effect of curing conditions of alkali-activated micro-fly ash (FA2), strength tests of hardening samples of geopolymer binder under ambient conditions were carried out. Figure 7 shows the results of the compressive strength tests of the curing samples at room temperature and humidity. It has been observed that, without the use of low-pressure steam curing conditions, curing the geopolymer binder at room temperature (20
The influence of the curing condition on the compressive strength of alkali activated fly ash FA2.
Figure 8A shows the microstructure of the hardened geopolymer (FA2) characterised by the highest compressive strength. SEM image observations show a porous geopolymer structure formed between the fly ash particles under the influence of alkaline activation. The formed geopolymer phase adheres closely to the fly ash particles, forming a compact structure of hardened material (Figure 8B). A larger ash particle with a diameter of about 30 μm is visible in the test area.
SEM images of: A: of the hardened binder obtained from the FA2 (magnification 2000), and B: magnification 20,000 [
The studies carried out at a higher magnification, together with the EDS analysis, made it possible to identify the composition of the formed compounds. At selected points of this sample, EDS analysis shows the formation of the geopolymer microstructure around the ash particles under the influence of alkaline activation with a variable Si/Al ratio (Figure 8B and Table 2 p. 2, p. 3 and p. 4).
Point | Na | Mg | Al | Si | S | K | Ca | Ti | Fe | O |
---|---|---|---|---|---|---|---|---|---|---|
1 | 3.57 | 0.78 | 19.8 | 31.8 | 0.00 | 6.96 | 0.64 | 0.00 | 5.16 | 31.3 |
2 | 2.57 | 0.73 | 16,0 | 41.2 | 0.41 | 7.99 | 0.48 | 0.00 | 1.31 | 29.4 |
3 | 7.42 | 1.48 | 14.9 | 27.6 | 0.44 | 3.89 | 1.31 | 0.00 | 5.09 | 37.8 |
4 | 7.96 | 0.99 | 13.1 | 17.8 | 1.45 | 2.14 | 1.91 | 0.41 | 4.48 | 48.8 |
According to XRD analysis, quartz and mullite derived from fly ash are present in the hardened geopolymer paste (Figure 9). Identified reflections for hydrosodalite, recorded on the diffractogram, prove the presence of this phase in the hardened matrix of the material obtained from FA2 fly ash in alkali activation process.
XRD pattern: 1) – of the FA2 fly ash, 2) – of the hardened geopolymer paste obtained from the FA2 ash [
The compositions of concrete mixes to obtain cementless geopolymer concrete were determined on the basis of the principles of designing ordinary concrete, assuming that in place of cement, the ashes selected for the study were used as the binder component in the concrete mix.
To prepare the reference concrete (B0FA1), the developed concrete mix was used, where the content of binder was 260 kg/m3 in which 23% of cement was replaced by silicious fly ash (FA1). This fly ash is coherent with requirements from PN-EN 450 standard. Three aggregates’ fractions were used: fine sand (0/2 mm), fine gravel 2/8 mm and gravel 8/16 mm. Apart from the micro fly ash (FA2), during the BFA2 + G mix preparation, the mineral additive – calcined at 700°C waste clay was added in place of 15% of micro fly ash FA2. The 8 mole/dm3 NaOH solution was used as the activator, while for the BFA2 + G concrete mix, the mixture of 8 mole/dm3 NaOH solution with water glass with an SiO2/Na2O molar modulus of 2.5 was used. Table 3 shows the designations of the concrete samples, consisting of a member containing the type of initial components used to obtain the cementless geopolymer concrete.
Concrete designation | Binder | w/s | Kind of activator | Compressive strength [MPa] |
---|---|---|---|---|
B0 FA1 | 77% OPC + 23% FA1 | 0.5 | — | 30.8 |
BFA1 | FA1 | 0.5 | 8 M NaOH | 14.8 |
BFA2 | FA2 | 0.5 | 8 M NaOH | 26.6 |
BFA3 | FA3 | 0.6 | 8 M NaOH | 5.5 |
BFA6 | FA6 | 0.6 | 8 M NaOH | 10.6 |
BFA2 + G | 85% FA2 + 15% calcined waste clay | 0.6 | 8 M NaOH/Na2SiO2 = 1/2 | 73.5 |
List of materials used as a binder to obtain geopolymer concrete and kind of the activator [15].
The concrete mixes, after being cast into 100 x 100 x 100 mm cubes, were cured at 80°C under low-pressure steam conditions. In Figure 10, the compressive strength of tested geopolymer concretes hardened in 24 h low-pressure process is shown. From all tested concretes, which contain different fly ashes subjected to alkali activation by 8 mol NaOH solution, the highest compressive strength (26.6 MPa) was obtained by BFA2 concrete; however, it does not receive the value of compressive strength for reference concrete (30.8 MPa). BFA2 + G concrete with the addition of waste clay is characterised by exceptionally high compressive strength (73.5 MPa), exceeding the strength of the cement reference concrete samples by almost 180%. In order to check the influence of the environmental conditions under which the samples were cured after steam curing, they were additionally stored in ambient conditions and in water at temperature of 20°C.
Compressive strength of concrete samples after low-pressure steam curing [
The concrete samples were additionally stored for a period of 28 days, both in ambient condition and in water, they did not lose the original strength, which they had obtained immediately after steam curing and obtained the high compressive strength, sometimes exceeding those of the initial sample. Figure 11 shows the compressive strength of samples of the tested concretes after the low-pressure steam curing, stored additionally 28 days in water and in the ambient condition. To test the freeze-thaw resistance of the developed geopolymer cementless concretes, concrete samples were subjected to impact of low temperature. Unfortunately, not all samples of geopolymer concretes passed this test, which include of 150 freeze-thaw cycles. All samples prepared exclusively from fly ash as a binder, were completely destroyed, some of them after only 50 freeze-thaw cycles. The modification of the BFA2 concrete composition by replacing fly ash with 15% of a specially prepared additive—calcined waste clay—significantly improved the frost resistance of the geopolymer BFA2 + G concrete (Figure 12).
Compressive strength of the concrete samples stored in ambient conditions and in water for 28 days after steam curing [
Compressive strength of the geopolymer concretes after steam curing compared with the samples after frost resistance testing [
Studies on the effect of carbonisation on the durability of the obtained geopolymer concrete were carried out in a test chamber. The pre-steamed samples were stored for another 28 days in ambient conditions and then were placed in a chamber, where they were subjected to the impact of high concentration of CO2 (4%) for 56 days. The geopolymer concrete samples obtained higher strengths after the carbonisation process (Figure 13), which means that the samples after a period of preliminary steaming and further exposure show an increase in strength. The process of low-pressure curing does not lead to the achievement of the maximal strength of the material.
Compressive strength of geopolymer concretes after low-pressure steam curing compared with the results of tests after carbonisation process.
The tests were carried out on the sample of the BFA2 + G concrete, which, due to the results achieved and the potential possibilities of use, as well as scientific value, raises universal interest. It is a cementless concrete made from secondary and waste materials which, after alkaline activation and subjected to low-pressure steam curing, was characterised by high compressive strength, high freeze-thaw resistance and durability both during curing in ambient conditions and in water and after conducting the carbonisation tests.
Figure 14 shows photograph exemplifying the structure of the fracture surface of the concrete sample after 3 years of storage in ambient conditions.
Macroscopic image of the structure of a geopolymer concrete sample.
Further testing was carried out on the sample of the BFA2 + G, obtained by alkaline activation of fly ash with the addition of calcined clay. Figure 15 shows the image under the scanning microscope of the microstructure of the fractured surface of the BFA2 + G concrete sample after 3 years of storage under ambient conditions. The test sample, extracted from the solidified matrix that bonds the aggregate particles, is not homogeneous. It contains partially reactivated fly ash particles. (Figure 16A) or more degraded fly ash particle (Figure 16B) which is a result of alkaline activation. The geopolymerisation products occur in a different morphology (Figure 17 and 18). The basic filler is a material formed by the reaction of the phase components of fly ash with an alkaline activator, which surrounds the unreacted fly ash particles (Figure 15A). The extender, formed by the alkaline activation of the components of the fly ash with the addition of calcined clay, is visible between the particles of the aggregate and the sand, which has a compact microstructure well bonded to the aggregate surface (Figure 15A). This substance consists mainly of silicon, aluminium and sodium. In the observed area of the sample, round, smooth ash particles are visible, which indicates that the alkaline reaction with the ash components occurs mainly in their surface layer (Figure 18). This is a normal phenomenon. They mainly contain silicon and aluminium and are characterised by a high sodium content. This component comes from the activator. In addition to the amorphous extender, clusters of crystallised hexagonal needle-like forms of the zeolite group are visible (Figures 15B and 17).
SEM images of selected areas of the BFA2 + G concrete sample: A: zeolite phase of alkaline fly ash activation products [
SEM images of: A: partially reactivated fly ash particle with geopolymerisation products surrounding it and B: degraded fly ash particle as a result of alkaline activation.
The morphology of alkaline activation products in the form of needle-shaped, hexagonal crystals. They are the needle crystals of the zeolite group with high sodium content [
SEM image of alkaline activation products formed around the surface of fly ash particles [
Analysis of the phase composition conducted in the papier [15], as well as the SEM studies (Figure 17 and 18), indicates the content of crystalline phases in the test sample, originating from the base materials used. These include quartz, mullite, haematite and calcite. Based on the recorded in the papier [15] peaks with ‘d’ values of 4.7 Å and 3.64 Å on XRD pattern, it can be assumed that cancrinite (Na6Ca2Al6Si6O24 (CO3)2), a zeolite occurring in hexagonal needle-like forms, is present in the tested sample. The cluster of needle-like forms shown in Figure 17, with the EDS analysis carried out at point 1, indicates the possibility of the formation of this compound. The results of elemental X-ray microanalysis shown in the table show significant differences in the composition of geopolymer compounds formed as a result of the alkaline activation of FA2 ash with the addition of clay (Table 4).
Point | Na | Mg | Al | Si | S | K | Ca | Fe | O |
---|---|---|---|---|---|---|---|---|---|
1 on Figure 17 | 14.5 | 0.13 | 1.37 | 3.30 | 0.15 | 0.44 | 0.47 | 0.80 | 46.1 |
1 on Figure 18 | 3.00 | 0.59 | 8.02 | 12.2 | 0.64 | 1.04 | 0.66 | 1.21 | 33.5 |
EDS analyses of selected points in the micro region on Figures 17 and 18 (atomic percentage (%).
The identified cancrinite (Figure 17, Table 4) contains significantly more sodium than the zeolite formed around the surface of the fly ash particle (Figure 18, Table 4). The content of this compound in concrete with other zeolites, such as hydrosodalite, formed by alkaline activation of fly ash, has been indicated by many researchers, as described by Davidovits [62] and Zhao et al. [63].
Probably, this phase crystallised from the amorphous precursors under the influence of CO2 from the air, in which the developed geopolymer concrete was kept during the 3-year conditioning period. More likely, the crystallisation of this phase seems to be caused by alkali activation of mineral components of calcined clay which includes apart from metakaolinite some amounts of undecomposed calcite. This thesis could be based according to tests carried out by Esaifan et al. [64], who proved the presence of both minerals: hydrosadalite and cancrinite by conducting the synthesis of those zeolites’ minerals from calcite-containing clay under hydrothermal conditions. Calcite is a source of the necessary Ca2+ ions required to form cancrinite. This phase can crystallise already in a use of NaOH solution, not only by using a mixture of sodium silicate with NaOH solution [64]. In the results interpretation of XRD tests, the structure of hydrosadalite and cancrinite tested by Barnes et al. [65] turned out very helpful. According to these authors for those mineral phases on XRD pattern, many common diffraction peaks occur. The main identifying peaks for cancrinite unlike hydrosadalite are 4.67 Å and 3.24 Å.
The presented work is based on the results of many years of studies carried out at Ł-ICIMB in Cracow, aiming the decrease of CO2 emission from cement and concrete production. One of many ways of achieving this aim is the development of new, low-emission binders and concrete, which could complement the so-called classic materials such as cement and cement concrete and replace cement in certain areas of its application.
In the conducted research, focused on utilisation for obtaining the cementless binders and concrete, commonly available fly ashes from Polish power plants. According to conducted freeze-thaw tests, all samples of geopolymer concretes containing as a binder fly ash had been damaged after 150 freeze-thaw cycles. Even BFA2 concrete, despite high fresh compressive strength, failed this test. Especially low freeze-thaw resistance was demonstrated by geopolymer concretes based in alkali activated fluidised fly ash and untreated calcareous fly ash. After 50 cycles of freeze-thaw, those concretes were totally destroyed. The modification attempt of increasing the durability of concrete by addition of calcinated clay, as a partial replacement of fly ash, became a success. This test was conducted for the BFA2 concrete, which is characterised by the highest compressive strength among from tested concretes. Although it is known that the addition of metakaolin increases the strength of the fly ash based geopolymer [66], the results presented in this chapter are difficult to interpret unambiguously because, at the same time, the type of activator was changed, introducing 30% of water glass in place of sodium hydroxide. Consequently, the structure of the geopolymer filler of the hardened BFA2 + G geopolymer concrete is different compared with BFA2 concrete containing the same silicious micro fly ash from coal combustion.
The results obtained confirm the statements of numerous authors on the possibility of shaping the functional properties of geopolymer materials by selecting the suitable base materials, the type and quantity of activator, as well as hardening conditions. Currently, one of the factors determining the development of geopolymer in civil engineering will be the cost of material production. Therefore, it is advisable to look for cheaper, alternative activators. Reducing the carbon footprint is also an important element. It is worth paying attention to the comparison of the CO
Taking into account the tendency to reduce coal burning in the energy sector, it should be noted the possibility of the limitation the extraction of the best for geopolymer concrete, silicious fly ash. This will be followed by work on the identification of other aluminosilicate precursors from both waste materials and industrial waste. A suitable example is an attempt to obtain appropriately transformed calcareous fly ash as the main component of cementless geopolymer concretes. The presented results of the use of refined calcareous fly ash, through the separation of carbon fractions and additional grinding, confirmed the possibility of obtaining cementless geopolymer concrete from such a material. A similar effect was obtained by Blaszczyński and Król [67], who, as one of the few authors, also obtained a geopolymer binder from tentatively refined calcareous ashes by removing carbon particles and pre-grinding them. Ash of this kind has not found application as an ingredient for cement production, so there are great opportunities for its acquisition.
For the widespread production of structural materials based on geopolymer binders and concrete, it is necessary to carry out long-term durability studies and develop guidelines for testing procedures and standard requirements so that the geopolymer material “native to ancient Egypt” with the new name AAM (Alkali-Activated Material) becomes the material of the future [4].
Part of the research results on the development of geopolymer concrete based on waste aluminosilicate materials, in particular fly ash, were published in the journal Cement Wapno Beton [15]. Results of tests, showed in this chapter, make a significant contribution, which led to interpret the phenomenon that occurs during alkali activation of chosen aluminosilicates industrial wastes. It has extended current knowledge in a field of geopolymer materials.
Among the fly ashes described, selected for research as base materials for obtaining cementless binders and geopolymer concretes, the best properties were demonstrated by fine-grained, specially selected siliceous fly ash from hard coal combustion—so-called micro fly ash.
It was demonstrated that a large role in the formation of the microstructure of the hardened geopolymer concrete showing high durability under the tested conditions of exposure to both water and ambient condition and low temperatures can be attributed to the modification of developed geopolymer microstructure by the presence of metakaolin and calcium carbonate in the calcined at 700°C clay [14, 60, 64, 66]. This modification resulted by the occurrence in the geopolymer microstructure, in which needle-like forms were identified using a scanning microscope, which, following other authors, can be attributed to the formation of cancrinite [64, 68].
We would like to thank the Cement Wapno Beton foundation for disseminating the results of our research in the article entitled ‘Microstructure and properties of geopolymers formed in the alkali activation process of fly ash’, which resulted in our invitation to take part in the preparation of the chapter of the book entitled ‘Advanced Cement-Based Materials’. This research was accomplished within statutory activity at Research Network – Institute of Ceramics and Building Materials by the team represented Materials Engineering Research Group.
The authors declare no conflict of interest.
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He also obtained an MSc in Molecular and Genetic Medicine, and a Ph.D. in Clinical Immunology and Human Genetics from the University of Sheffield, UK. He also completed a short-term fellowship in Pediatric Clinical Immunology and Bone Marrow Transplantation at Newcastle General Hospital, England. Dr. Rezaei is a Full Professor of Immunology and Vice Dean of International Affairs and Research, at the School of Medicine, Tehran University of Medical Sciences, and the co-founder and head of the Research Center for Immunodeficiencies. He is also the founding president of the Universal Scientific Education and Research Network (USERN). Dr. Rezaei has directed more than 100 research projects and has designed and participated in several international collaborative projects. He is an editor, editorial assistant, or editorial board member of more than forty international journals. He has edited more than 50 international books, presented more than 500 lectures/posters in congresses/meetings, and published more than 1,100 scientific papers in international journals.",institutionString:"Tehran University of Medical Sciences",institution:{name:"Tehran University of Medical Sciences",country:{name:"Iran"}}},{id:"180733",title:"Dr.",name:"Jean",middleName:null,surname:"Engohang-Ndong",slug:"jean-engohang-ndong",fullName:"Jean Engohang-Ndong",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/180733/images/system/180733.png",biography:"Dr. Jean Engohang-Ndong was born and raised in Gabon. After obtaining his Associate Degree of Science at the University of Science and Technology of Masuku, Gabon, he continued his education in France where he obtained his BS, MS, and Ph.D. in Medical Microbiology. He worked as a post-doctoral fellow at the Public Health Research Institute (PHRI), Newark, NJ for four years before accepting a three-year faculty position at Brigham Young University-Hawaii. Dr. Engohang-Ndong is a tenured faculty member with the academic rank of Full Professor at Kent State University, Ohio, where he teaches a wide range of biological science courses and pursues his research in medical and environmental microbiology. Recently, he expanded his research interest to epidemiology and biostatistics of chronic diseases in Gabon.",institutionString:"Kent State University",institution:{name:"Kent State University",country:{name:"United States of America"}}},{id:"188773",title:"Prof.",name:"Emmanuel",middleName:null,surname:"Drouet",slug:"emmanuel-drouet",fullName:"Emmanuel Drouet",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/188773/images/system/188773.png",biography:"Emmanuel Drouet, PharmD, is a Professor of Virology at the Faculty of Pharmacy, the University Grenoble-Alpes, France. As a head scientist at the Institute of Structural Biology in Grenoble, Dr. Drouet’s research investigates persisting viruses in humans (RNA and DNA viruses) and the balance with our host immune system. He focuses on these viruses’ effects on humans (both their impact on pathology and their symbiotic relationships in humans). He has an excellent track record in the herpesvirus field, and his group is engaged in clinical research in the field of Epstein-Barr virus diseases. He is the editor of the online Encyclopedia of Environment and he coordinates the Universal Health Coverage education program for the BioHealth Computing Schools of the European Institute of Science.",institutionString:null,institution:{name:"Grenoble Alpes University",country:{name:"France"}}},{id:"131400",title:"Prof.",name:"Alfonso J.",middleName:null,surname:"Rodriguez-Morales",slug:"alfonso-j.-rodriguez-morales",fullName:"Alfonso J. Rodriguez-Morales",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/131400/images/system/131400.png",biography:"Dr. Rodriguez-Morales is an expert in tropical and emerging diseases, particularly zoonotic and vector-borne diseases (especially arboviral diseases). He is the president of the Travel Medicine Committee of the Pan-American Infectious Diseases Association (API), as well as the president of the Colombian Association of Infectious Diseases (ACIN). He is a member of the Committee on Tropical Medicine, Zoonoses, and Travel Medicine of ACIN. He is a vice-president of the Latin American Society for Travel Medicine (SLAMVI) and a Member of the Council of the International Society for Infectious Diseases (ISID). Since 2014, he has been recognized as a Senior Researcher, at the Ministry of Science of Colombia. He is a professor at the Faculty of Medicine of the Fundacion Universitaria Autonoma de las Americas, in Pereira, Risaralda, Colombia. He is an External Professor, Master in Research on Tropical Medicine and International Health, Universitat de Barcelona, Spain. He is also a professor at the Master in Clinical Epidemiology and Biostatistics, Universidad Científica del Sur, Lima, Peru. In 2021 he has been awarded the “Raul Isturiz Award” Medal of the API. Also, in 2021, he was awarded with the “Jose Felix Patiño” Asclepius Staff Medal of the Colombian Medical College, due to his scientific contributions to COVID-19 during the pandemic. He is currently the Editor in Chief of the journal Travel Medicine and Infectious Diseases. His Scopus H index is 47 (Google Scholar H index, 68).",institutionString:"Institución Universitaria Visión de las Américas, Colombia",institution:null},{id:"332819",title:"Dr.",name:"Chukwudi Michael",middleName:"Michael",surname:"Egbuche",slug:"chukwudi-michael-egbuche",fullName:"Chukwudi Michael Egbuche",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/332819/images/14624_n.jpg",biography:"I an Dr. Chukwudi Michael Egbuche. I am a Senior Lecturer in the Department of Parasitology and Entomology, Nnamdi Azikiwe University, Awka.",institutionString:null,institution:{name:"Nnamdi Azikiwe University",country:{name:"Nigeria"}}},{id:"284232",title:"Mr.",name:"Nikunj",middleName:"U",surname:"Tandel",slug:"nikunj-tandel",fullName:"Nikunj Tandel",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/284232/images/8275_n.jpg",biography:'Mr. Nikunj Tandel has completed his Master\'s degree in Biotechnology from VIT University, India in the year of 2012. He is having 8 years of research experience especially in the field of malaria epidemiology, immunology, and nanoparticle-based drug delivery system against the infectious diseases, autoimmune disorders and cancer. He has worked for the NIH funded-International Center of Excellence in Malaria Research project "Center for the study of complex malaria in India (CSCMi)" in collaboration with New York University. The preliminary objectives of the study are to understand and develop the evidence-based tools and interventions for the control and prevention of malaria in different sites of the INDIA. Alongside, with the help of next-generation genomics study, the team has studied the antimalarial drug resistance in India. Further, he has extended his research in the development of Humanized mice for the study of liver-stage malaria and identification of molecular marker(s) for the Artemisinin resistance. At present, his research focuses on understanding the role of B cells in the activation of CD8+ T cells in malaria. Received the CSIR-SRF (Senior Research Fellow) award-2018, FIMSA (Federation of Immunological Societies of Asia-Oceania) Travel Bursary award to attend the IUIS-IIS-FIMSA Immunology course-2019',institutionString:"Nirma University",institution:{name:"Nirma University",country:{name:"India"}}},{id:"334383",title:"Ph.D.",name:"Simone",middleName:"Ulrich",surname:"Ulrich Picoli",slug:"simone-ulrich-picoli",fullName:"Simone Ulrich Picoli",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/334383/images/15919_n.jpg",biography:"Graduated in Pharmacy from Universidade Luterana do Brasil (1999), Master in Agricultural and Environmental Microbiology from Federal University of Rio Grande do Sul (2002), Specialization in Clinical Microbiology from Universidade de São Paulo, USP (2007) and PhD in Sciences in Gastroenterology and Hepatology (2012). She is currently an Adjunct Professor at Feevale University in Medicine and Biomedicine courses and a permanent professor of the Academic Master\\'s Degree in Virology. She has experience in the field of Microbiology, with an emphasis on Bacteriology, working mainly on the following topics: bacteriophages, bacterial resistance, clinical microbiology and food microbiology.",institutionString:null,institution:{name:"Universidade Feevale",country:{name:"Brazil"}}},{id:"229220",title:"Dr.",name:"Amjad",middleName:"Islam",surname:"Aqib",slug:"amjad-aqib",fullName:"Amjad Aqib",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/229220/images/system/229220.png",biography:"Dr. Amjad Islam Aqib obtained a DVM and MSc (Hons) from University of Agriculture Faisalabad (UAF), Pakistan, and a PhD from the University of Veterinary and Animal Sciences Lahore, Pakistan. Dr. Aqib joined the Department of Clinical Medicine and Surgery at UAF for one year as an assistant professor where he developed a research laboratory designated for pathogenic bacteria. Since 2018, he has been Assistant Professor/Officer in-charge, Department of Medicine, Manager Research Operations and Development-ORIC, and President One Health Club at Cholistan University of Veterinary and Animal Sciences, Bahawalpur, Pakistan. He has nearly 100 publications to his credit. His research interests include epidemiological patterns and molecular analysis of antimicrobial resistance and modulation and vaccine development against animal pathogens of public health concern.",institutionString:"Cholistan University of Veterinary and Animal Sciences",institution:{name:"University of Agriculture Faisalabad",country:{name:"Pakistan"}}},{id:"333753",title:"Dr.",name:"Rais",middleName:null,surname:"Ahmed",slug:"rais-ahmed",fullName:"Rais Ahmed",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/333753/images/20168_n.jpg",biography:null,institutionString:null,institution:{name:"University of Agriculture Faisalabad",country:{name:"Pakistan"}}},{id:"62900",title:"Prof.",name:"Fethi",middleName:null,surname:"Derbel",slug:"fethi-derbel",fullName:"Fethi Derbel",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/62900/images/system/62900.jpeg",biography:"Professor Fethi Derbel was born in 1960 in Tunisia. He received his medical degree from the Sousse Faculty of Medicine at Sousse, University of Sousse, Tunisia. He completed his surgical residency in General Surgery at the University Hospital Farhat Hached of Sousse and was a member of the Unit of Liver Transplantation in the University of Rennes, France. He then worked in the Department of Surgery at the Sahloul University Hospital in Sousse. Professor Derbel is presently working at the Clinique les Oliviers, Sousse, Tunisia. His hospital activities are mostly concerned with laparoscopic, colorectal, pancreatic, hepatobiliary, and gastric surgery. He is also very interested in hernia surgery and performs ventral hernia repairs and inguinal hernia repairs. He has been a member of the GREPA and Tunisian Hernia Society (THS). During his residency, he managed patients suffering from diabetic foot, and he was very interested in this pathology. For this reason, he decided to coordinate a book project dealing with the diabetic foot. Professor Derbel has published many articles in journals and collaborates intensively with IntechOpen Access Publisher as an editor.",institutionString:"Clinique les Oliviers",institution:null},{id:"300144",title:"Dr.",name:"Meriem",middleName:null,surname:"Braiki",slug:"meriem-braiki",fullName:"Meriem Braiki",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/300144/images/system/300144.jpg",biography:"Dr. Meriem Braiki is a specialist in pediatric surgeon from Tunisia. She was born in 1985. She received her medical degree from the University of Medicine at Sousse, Tunisia. She achieved her surgical residency training periods in Pediatric Surgery departments at University Hospitals in Monastir, Tunis and France.\r\nShe is currently working at the Pediatric surgery department, Sidi Bouzid Hospital, Tunisia. Her hospital activities are mostly concerned with laparoscopic, parietal, urological and digestive surgery. She has published several articles in diffrent journals.",institutionString:"Sidi Bouzid Regional Hospital",institution:null},{id:"229481",title:"Dr.",name:"Erika M.",middleName:"Martins",surname:"de Carvalho",slug:"erika-m.-de-carvalho",fullName:"Erika M. de Carvalho",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/229481/images/6397_n.jpg",biography:null,institutionString:null,institution:{name:"Oswaldo Cruz Foundation",country:{name:"Brazil"}}},{id:"186537",title:"Prof.",name:"Tonay",middleName:null,surname:"Inceboz",slug:"tonay-inceboz",fullName:"Tonay Inceboz",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/186537/images/system/186537.jfif",biography:"I was graduated from Ege University of Medical Faculty (Turkey) in 1988 and completed his Med. PhD degree in Medical Parasitology at the same university. I became an Associate Professor in 2008 and Professor in 2014. I am currently working as a Professor at the Department of Medical Parasitology at Dokuz Eylul University, Izmir, Turkey.\n\nI have given many lectures, presentations in different academic meetings. I have more than 60 articles in peer-reviewed journals, 18 book chapters, 1 book editorship.\n\nMy research interests are Echinococcus granulosus, Echinococcus multilocularis (diagnosis, life cycle, in vitro and in vivo cultivation), and Trichomonas vaginalis (diagnosis, PCR, and in vitro cultivation).",institutionString:"Dokuz Eylül University",institution:{name:"Dokuz Eylül University",country:{name:"Turkey"}}},{id:"71812",title:"Prof.",name:"Hanem Fathy",middleName:"Fathy",surname:"Khater",slug:"hanem-fathy-khater",fullName:"Hanem Fathy Khater",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/71812/images/1167_n.jpg",biography:"Prof. Khater is a Professor of Parasitology at Benha University, Egypt. She studied for her doctoral degree, at the Department of Entomology, College of Agriculture, Food and Natural Resources, University of Missouri, Columbia, USA. She has completed her Ph.D. degrees in Parasitology in Egypt, from where she got the award for “the best scientific Ph.D. dissertation”. She worked at the School of Biological Sciences, Bristol, England, the UK in controlling insects of medical and veterinary importance as a grant from Newton Mosharafa, the British Council. Her research is focused on searching of pesticides against mosquitoes, house flies, lice, green bottle fly, camel nasal botfly, soft and hard ticks, mites, and the diamondback moth as well as control of several parasites using safe and natural materials to avoid drug resistances and environmental contamination.",institutionString:null,institution:{name:"Banha University",country:{name:"Egypt"}}},{id:"99780",title:"Prof.",name:"Omolade",middleName:"Olayinka",surname:"Okwa",slug:"omolade-okwa",fullName:"Omolade Okwa",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/99780/images/system/99780.jpg",biography:"Omolade Olayinka Okwa is presently a Professor of Parasitology at Lagos State University, Nigeria. She has a PhD in Parasitology (1997), an MSc in Cellular Parasitology (1992), and a BSc (Hons) Zoology (1990) all from the University of Ibadan, Nigeria. She teaches parasitology at the undergraduate and postgraduate levels. She was a recipient of a Commonwealth fellowship supported by British Council tenable at the Centre for Entomology and Parasitology (CAEP), Keele University, United Kingdom between 2004 and 2005. She was awarded an Honorary Visiting Research Fellow at the same university from 2005 to 2007. \nShe has been an external examiner to the Department of Veterinary Microbiology and Parasitology, University of Ibadan, MSc programme between 2010 and 2012. She is a member of the Nigerian Society of Experimental Biology (NISEB), Parasitology and Public Health Society of Nigeria (PPSN), Science Association of Nigeria (SAN), Zoological Society of Nigeria (ZSN), and is Vice Chairperson of the Organisation of Women in Science (OWSG), LASU chapter. She served as Head of Department of Zoology and Environmental Biology, Lagos State University from 2007 to 2010 and 2014 to 2016. She is a reviewer for several local and international journals such as Unilag Journal of Science, Libyan Journal of Medicine, Journal of Medicine and Medical Sciences, and Annual Research and Review in Science. \nShe has authored 45 scientific research publications in local and international journals, 8 scientific reviews, 4 books, and 3 book chapters, which includes the books “Malaria Parasites” and “Malaria” which are IntechOpen access publications.",institutionString:"Lagos State University",institution:{name:"Lagos State University",country:{name:"Nigeria"}}},{id:"273100",title:"Dr.",name:"Vijay",middleName:null,surname:"Gayam",slug:"vijay-gayam",fullName:"Vijay Gayam",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/273100/images/system/273100.jpeg",biography:"Dr. Vijay Bhaskar Reddy Gayam is currently practicing as an internist at Interfaith Medical Center in Brooklyn, New York, USA. He is also a Clinical Assistant Professor at the SUNY Downstate University Hospital and Adjunct Professor of Medicine at the American University of Antigua. He is a holder of an M.B.B.S. degree bestowed to him by Osmania Medical College and received his M.D. at Interfaith Medical Center. His career goals thus far have heavily focused on direct patient care, medical education, and clinical research. He currently serves in two leadership capacities; Assistant Program Director of Medicine at Interfaith Medical Center and as a Councilor for the American\r\nFederation for Medical Research. As a true academician and researcher, he has more than 50 papers indexed in international peer-reviewed journals. He has also presented numerous papers in multiple national and international scientific conferences. His areas of research interest include general internal medicine, gastroenterology and hepatology. He serves as an editor, editorial board member and reviewer for multiple international journals. His research on Hepatitis C has been very successful and has led to multiple research awards, including the 'Equity in Prevention and Treatment Award” from the New York Department of Health Viral Hepatitis Symposium (2018) and the 'Presidential Poster Award” awarded to him by the American College of Gastroenterology (2018). He was also awarded 'Outstanding Clinician in General Medicine” by Venus International Foundation for his extensive research expertise and services, perform over and above the standard expected in the advancement of healthcare, patient safety and quality of care.",institutionString:"Interfaith Medical Center",institution:{name:"Interfaith Medical Center",country:{name:"United States of America"}}},{id:"93517",title:"Dr.",name:"Clement",middleName:"Adebajo",surname:"Meseko",slug:"clement-meseko",fullName:"Clement Meseko",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/93517/images/system/93517.jpg",biography:"Dr. Clement Meseko obtained DVM and PhD degree in Veterinary Medicine and Virology respectively. He has worked for over 20 years in both private and public sectors including the academia, contributing to knowledge and control of infectious disease. Through the application of epidemiological skill, classical and molecular virological skills, he investigates viruses of economic and public health importance for the mitigation of the negative impact on people, animal and the environment in the context of Onehealth. \r\nDr. Meseko’s field experience on animal and zoonotic diseases and pathogen dynamics at the human-animal interface over the years shaped his carrier in research and scientific inquiries. He has been part of the investigation of Highly Pathogenic Avian Influenza incursions in sub Saharan Africa and monitors swine Influenza (Pandemic influenza Virus) agro-ecology and potential for interspecies transmission. He has authored and reviewed a number of journal articles and book chapters.",institutionString:"National Veterinary Research Institute",institution:{name:"National Veterinary Research Institute",country:{name:"Nigeria"}}},{id:"158026",title:"Prof.",name:"Shailendra K.",middleName:null,surname:"Saxena",slug:"shailendra-k.-saxena",fullName:"Shailendra K. Saxena",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRET3QAO/Profile_Picture_2022-05-10T10:10:26.jpeg",biography:"Professor Dr. Shailendra K. Saxena is a vice dean and professor at King George's Medical University, Lucknow, India. His research interests involve understanding the molecular mechanisms of host defense during human viral infections and developing new predictive, preventive, and therapeutic strategies for them using Japanese encephalitis virus (JEV), HIV, and emerging viruses as a model via stem cell and cell culture technologies. His research work has been published in various high-impact factor journals (Science, PNAS, Nature Medicine) with a high number of citations. He has received many awards and honors in India and abroad including various Young Scientist Awards, BBSRC India Partnering Award, and Dr. JC Bose National Award of Department of Biotechnology, Min. of Science and Technology, Govt. of India. Dr. Saxena is a fellow of various international societies/academies including the Royal College of Pathologists, United Kingdom; Royal Society of Medicine, London; Royal Society of Biology, United Kingdom; Royal Society of Chemistry, London; and Academy of Translational Medicine Professionals, Austria. He was named a Global Leader in Science by The Scientist. He is also an international opinion leader/expert in vaccination for Japanese encephalitis by IPIC (UK).",institutionString:"King George's Medical University",institution:{name:"King George's Medical University",country:{name:"India"}}},{id:"94928",title:"Dr.",name:"Takuo",middleName:null,surname:"Mizukami",slug:"takuo-mizukami",fullName:"Takuo Mizukami",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/94928/images/6402_n.jpg",biography:null,institutionString:null,institution:{name:"National Institute of Infectious Diseases",country:{name:"Japan"}}},{id:"233433",title:"Dr.",name:"Yulia",middleName:null,surname:"Desheva",slug:"yulia-desheva",fullName:"Yulia Desheva",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/233433/images/system/233433.png",biography:"Dr. Yulia Desheva is a leading researcher at the Institute of Experimental Medicine, St. Petersburg, Russia. She is a professor in the Stomatology Faculty, St. Petersburg State University. She has expertise in the development and evaluation of a wide range of live mucosal vaccines against influenza and bacterial complications. Her research interests include immunity against influenza and COVID-19 and the development of immunization schemes for high-risk individuals.",institutionString:'Federal State Budgetary Scientific Institution "Institute of Experimental Medicine"',institution:null},{id:"238958",title:"Mr.",name:"Atamjit",middleName:null,surname:"Singh",slug:"atamjit-singh",fullName:"Atamjit Singh",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/238958/images/6575_n.jpg",biography:null,institutionString:null,institution:null},{id:"252058",title:"M.Sc.",name:"Juan",middleName:null,surname:"Sulca",slug:"juan-sulca",fullName:"Juan Sulca",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/252058/images/12834_n.jpg",biography:null,institutionString:null,institution:null},{id:"191392",title:"Dr.",name:"Marimuthu",middleName:null,surname:"Govindarajan",slug:"marimuthu-govindarajan",fullName:"Marimuthu Govindarajan",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/191392/images/5828_n.jpg",biography:"Dr. M. Govindarajan completed his BSc degree in Zoology at Government Arts College (Autonomous), Kumbakonam, and MSc, MPhil, and PhD degrees at Annamalai University, Annamalai Nagar, Tamil Nadu, India. He is serving as an assistant professor at the Department of Zoology, Annamalai University. His research interests include isolation, identification, and characterization of biologically active molecules from plants and microbes. He has identified more than 20 pure compounds with high mosquitocidal activity and also conducted high-quality research on photochemistry and nanosynthesis. He has published more than 150 studies in journals with impact factor and 2 books in Lambert Academic Publishing, Germany. 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