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IntechOpen Book Series will also publish a program of research-driven Thematic Edited Volumes that focus on specific areas and allow for a more in-depth overview of a particular subject.
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\\n\\nLaunching 2021
\\n\\nArtificial Intelligence, ISSN 2633-1403
\\n\\nVeterinary Medicine and Science, ISSN 2632-0517
\\n\\nBiochemistry, ISSN 2632-0983
\\n\\nBiomedical Engineering, ISSN 2631-5343
\\n\\nInfectious Diseases, ISSN 2631-6188
\\n\\nPhysiology (Coming Soon)
\\n\\nDentistry (Coming Soon)
\\n\\nWe invite you to explore our IntechOpen Book Series, find the right publishing program for you and reach your desired audience in record time.
\\n\\nNote: Edited in October 2021
\\n"}]',published:!0,mainMedia:{caption:"",originalUrl:"/media/original/132"}},components:[{type:"htmlEditorComponent",content:'With the desire to make book publishing more relevant for the digital age and offer innovative Open Access publishing options, we are thrilled to announce the launch of our new publishing format: IntechOpen Book Series.
\n\nDesigned to cover fast-moving research fields in rapidly expanding areas, our Book Series feature a Topic structure allowing us to present the most relevant sub-disciplines. Book Series are headed by Series Editors, and a team of Topic Editors supported by international Editorial Board members. Topics are always open for submissions, with an Annual Volume published each calendar year.
\n\nAfter a robust peer-review process, accepted works are published quickly, thanks to Online First, ensuring research is made available to the scientific community without delay.
\n\nOur innovative Book Series format brings you:
\n\nIntechOpen Book Series will also publish a program of research-driven Thematic Edited Volumes that focus on specific areas and allow for a more in-depth overview of a particular subject.
\n\nIntechOpen Book Series will be launching regularly to offer our authors and editors exciting opportunities to publish their research Open Access. We will begin by relaunching some of our existing Book Series in this innovative book format, and will expand in 2022 into rapidly growing research fields that are driving and advancing society.
\n\nLaunching 2021
\n\nArtificial Intelligence, ISSN 2633-1403
\n\nVeterinary Medicine and Science, ISSN 2632-0517
\n\nBiochemistry, ISSN 2632-0983
\n\nBiomedical Engineering, ISSN 2631-5343
\n\nInfectious Diseases, ISSN 2631-6188
\n\nPhysiology (Coming Soon)
\n\nDentistry (Coming Soon)
\n\nWe invite you to explore our IntechOpen Book Series, find the right publishing program for you and reach your desired audience in record time.
\n\nNote: Edited in October 2021
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",isbn:"978-1-80356-747-1",printIsbn:"978-1-80356-746-4",pdfIsbn:"978-1-80356-748-8",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!1,isSalesforceBook:!1,isNomenclature:!1,hash:"a4b9a00a0b9b0718ef37413d53a5c146",bookSignature:"Dr. Ashutosh Sharma",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/11940.jpg",keywords:"Materials, Conventional Soldering, Modern Soldering, Shear Strength, Wetting, Intermetallic Growth Kinetics, Fracture Toughness, Solder Pastes, Solder-Joints, Wire Bonding, Flip Chip Packages, Metallization",numberOfDownloads:null,numberOfWosCitations:0,numberOfCrossrefCitations:null,numberOfDimensionsCitations:null,numberOfTotalCitations:null,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"March 25th 2022",dateEndSecondStepPublish:"June 1st 2022",dateEndThirdStepPublish:"July 31st 2022",dateEndFourthStepPublish:"October 19th 2022",dateEndFifthStepPublish:"December 18th 2022",dateConfirmationOfParticipation:null,remainingDaysToSecondStep:"2 months",secondStepPassed:!0,areRegistrationsClosed:!0,currentStepOfPublishingProcess:4,editedByType:null,kuFlag:!1,biosketch:"A pioneering scientist in the field of advanced microelectronic packaging and fabrication technologies, holder of Extraction and Processing Division (2016) Award, TMS USA, and 17 registered patents and several publications.",coeditorOneBiosketch:null,coeditorTwoBiosketch:null,coeditorThreeBiosketch:null,coeditorFourBiosketch:null,coeditorFiveBiosketch:null,editors:[{id:"145236",title:"Dr.",name:"Ashutosh",middleName:null,surname:"Sharma",slug:"ashutosh-sharma",fullName:"Ashutosh Sharma",profilePictureURL:"https://mts.intechopen.com/storage/users/145236/images/system/145236.jpeg",biography:"Ashutosh Sharma is currently working in the Department of Materials Science and Engineering, Ajou University, Suwon, South Korea. He earned his Ph.D. degree in Metallurgical and Materials Engineering from the Indian Institute of Technology (IIT) Kharagpur, India. His research interests include electrochemical deposition, lead-free soldering and brazing, additive manufacturing, high entropy alloys, gas sensors, and composites. Dr. Sharma is a life member of various scientific and professional bodies. In a very short time, he has contributed more than 100 international journals, 17 patents, 8 book chapters, and 1 authored book, and 1 edited book so far. 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Many authors have emphasized the ethical and vocational nature of teaching profession [1, 2]. In this chapter, teaching is presented as both a profession with professional competencies and a vocation with personal meaningfulness. The discussion is presented in the context of Finnish teacher education, where teachers are ethical professionals [3]. Finland was the first Nordic country to establish the ethical codes for teachers in 1998. During the last 20 years, these codes have been revised and updated. In these codes, the basic values for teaching profession are established. These values are dignity, truthfulness, fairness, responsibility, and freedom [4].
\nIn 2017, Teachers’ Union in Finland established the Comenius’ Oath for teachers that would support teachers in their work and provide a concrete reminder of the ethical foundation of their profession [5]. Teachers in Finland are trusted and they can practice pedagogical freedom in their work if they observe the legislation and the curriculum guidelines. Also, the schools in Finland have a lot of freedom in curriculum development and pedagogical approaches. The Finnish principals and teachers rank among the most autonomous education professionals in Europe [6] who are responsible for supporting students’ holistic development. The national core curriculum provides only the basic values and goals for schools to develop their own curricula and instructional approaches [7]. This kind of freedom can be identified as a challenge, for example, related to curriculum integration, especially for the subject-teachers in Finland [8].
\nTo be able to meet the challenges and requirements of ethical professionals, teachers need a long-term goal and commitment to teaching; in other words, they need to be purposeful in their work. The term “purpose” refers to “a stable and generalized intention to accomplish something that is both meaningful to the self and of intended consequence to the world beyond the self” [9]. In this definition, purpose can be conceptualized along three dimensions. The dimensions are intention, engagement, and prosocial reasoning [10]. All these dimensions are needed to fulfill the criteria of a purposeful teacher. Purposeful teachers are ethical professionals with long-term commitment to their students and educational goals they intend to meet in their teaching. In this work, they need to find meaningful purposes for themselves that at the same time go beyond themselves and serve their students and school communities.
\nThe purposeful teacher is always an ethical teacher with moral purposes. Our research data with both Finnish elementary and secondary school teachers indicate that teachers share certain features in their pedagogical thinking and teaching practice [11]. We have identified these collective features in teachers’ thinking to be field-invariant epistemological standards guiding their practical knowledge [12]. The sense of vocation provides teachers with a sense of personal identity and fulfillment referring to meaningful purpose in their work. Moreover, teachers have reported that they cannot separate personal and professional aspects in their practical reasoning. Their own moral character informs their moral reasoning, having an influence on how they interact with their pupils and providing long-term purposes in teaching. The professional rules and principles related to teachers’ ethical codes also help them in their pedagogical practice with their students and colleagues. Our empirical studies with both elementary and secondary teachers indicate that teaching is both a vocation with a deep personal commitment and a profession with clear rational principles. Purposeful teachers are those who can combine the vocational and professional aspects in their work.
\nIn the following subsections, the current challenges in teachers’ work in Finland are discussed with the empirical findings on the purpose profiles of our future teachers. Some methods to teach purpose in teacher education and in schools are introduced with a more detailed example from Finnish teacher education. Finally, purposeful teacher is identified as a goal for teacher education in the twenty-first century.
\nThe Finnish education system and teacher education are internationally recognized as high-performing without control and standardized testing [13]. The status of the teaching profession is very high in Finland, and teachers are trusted and respected. Beginning in the 1970s, the professionalism of teaching has been supported by an academic university education, with more and more trust given to teachers during the 1980s and 1990s through the decentralized curricula.
\nThe teaching profession also attracts good students year after year. This is a unique advantage to teacher education in Finland by comparison with other countries [3]. Teacher education in Finland has become increasingly research-based during the last 40 years. The master’s degree given to both elementary and secondary teachers with thesis provides opportunities for teachers to continue their studies in the doctoral programs that Finnish universities have in their teacher education departments. The professors and lecturers in these programs teach future teachers with scientific competence. They teach what they research and research what they teach. The results of their studies are published in leading international educational journals and monograph series. The faculty has pedagogical competence and most of them have been educated as teachers themselves. These developments have made Finnish teacher education very visible and competitive judged by international standards; for example, we have more international students applying to our doctoral programs than we can admit [3]. Lavonen lists several reasons why teaching is an attractive occupation in Finland. In addition to the academic status of teachers, they enjoy collaboration with and receive support from school leaders and communities. The strong culture of quality and the key role of teachers in assessment activities also support the professional ethos of teachers. Decentralization allows teachers to consider local contexts and to address diversity among the students they teach in flexible ways [13].
\nEthical sensitivity can be identified as a core competent for Finnish teachers in teacher-student relationships [4]. The best interest of a student is guiding the teacher to understand different needs of all kinds of learners and especially those who need special care and guidance. With the youngest learners, the teacher needs viewpoints from the other adults who know the child in need. This means that the teacher works together with the adults responsible for the child. Team-teaching, cooperation between home and school, and other experts are needed to meet the diverse educational needs of students. Many times, the needs require the view of a school psychologist or some other expert. These relationships make real the African saying “It takes a whole village to educate a child.”
\nThe professional attitude is present in the ethical codes in the teacher’s relationship to his or her work [4]. Accordingly, teachers should attend to their tasks responsibly and develop their work and evaluate their own activities. Teachers are also supposed to accept their fallibility and to be ready to revise their viewpoints if needed. Lifelong learning is necessary also in the ethical domain. Teachers in Finland have the right and responsibility to personal development and care. Teachers are also expected to respect their colleagues as members of a profession. A constant challenge in their work involves finding the balance between personal autonomy and the work community. In schools, teachers are advised to rely on the principles of mutual aid and support, understanding, and accepting the individuality of their colleagues. Teachers work together with the home, the surrounding community, and the larger society. This means that teachers have a relationship to the society in large and their work also guides the future of our society [4].
\nThe current challenges in Finnish teacher education include the growing diversity among students in our schools and the expectations of teachers to meet the varied needs of diverse learners. This will demand high-level ethical and pedagogical skills to cope with these new challenges. Also, the learning environments are changing and teachers need to master the rapidly changing developments in information and communication technology to function in the same learning environments as their students. Teachers should also be able to prepare their students for the future by teaching them the twenty-first century skills. These skills can be defined as an integration of the knowledge, skills, attitudes, and values that all young people of our time are required to have [14].
\nIn the Finnish national curriculum, seven areas of core competencies related to twenty-first century skills have been proposed, including: (1) thinking and learning to learn; (2) cultural competence, interaction, and self-expression; (3) taking care of oneself, managing daily life; (4) multi-literacy; (5) competence in information and communication technology; (6) working-life competence and entrepreneurship; and (7) participation, involvement, and building a sustainable future [7]. All these new learning goals call for purposeful teachers who have internalized the ethical nature of their profession and who find personal meaning in meeting the needs of their students.
\nFinnish teacher education has been mostly influenced by the German tradition and lately more and more influences have been drawn from Anglo-American thinkers [15]. Hopmann defines “The German Didaktik” with the idea that any given matter or subject in school can represent many different meanings, and many different matters or subjects in school context can open any given meaning. But there is no matter or subject without meaning, and no meaning without matter or subject [16]. Meaning is created when the content is presented in a classroom with some pedagogical method the teacher has decided to use; meaning making becomes possible for students when teachers provide room for their pupils to reflect upon what is meaningful to them, and how the issues presented relate to their aims and goals in life. In this pedagogical process, the goals of each student are addressed with the pedagogical aim to foster purpose development.
\nThe goal of Finnish teacher education is to educate pedagogically thinking teachers who can teach the contents of the curriculum and at the same time reflect on the meaningfulness of their teaching. Teachers should be able to take the perspective of their students and ask if their teaching is helping their students to find purpose in their studies and in their lives. We know that in Finland, both in-service teachers and student teachers find similar purposes in their teaching, regardless of the subject they teach [15, 17]. Finnish teachers are ethical professionals who want to make sure that their students master the basic knowledge of the subjects they teach. Moreover, they are responsible for the holistic development of their students, with the aim to educate moral citizens.
\nThe Finnish studies on teachers’ purpose [18] among the student teachers (N = 372) indicate that most of them (N = 144, 39%) can be called as
The second profile (N = 90, 24%) among the Finnish student teachers was the
The teachers who expressed neither purpose to their teaching nor showed any signs that they were seeking purpose were
Teachers all over the world need education in the specific competencies that make purposeful and purpose-oriented teaching possible. In a comparative study among youth, both American (N = 386) and Finnish (N = 336) students (13–19 years of age) acknowledged their need for teachers’ support in finding purpose in their studies and in their lives [20]. A special issue on purposeful teaching around the world presents several articles from different countries on this topic giving concrete examples on culture-specific approaches to purpose education [21, 22]. For example, in Brazil, action research approaches are adapted with student teachers by using problem-based and design thinking methods to promote purposeful teaching [23]. In American context, service-learning is regarded as one of the most promising pedagogical approach for supporting purpose development of student teachers [24]. Also, in Korea, service-learning approaches are used in colleges to enhance purpose education among their students [25]. In a comparative study comparing Iranian and Finnish teachers’ competence to teach purpose, the Iranian teachers taught their students reflection on purpose in life and plans, whereas Finnish teachers emphasized the importance and consequences of one’s actions and decisions. In Finland, teachers’ own purposefulness was related to their competence for teaching purpose [26]. Teachers in Finland, Iran and China all rated their competence to teach purpose highly, but Chinese teachers rated their competence much higher than their students rated them [27].
\nIn her book, Malin argues that purpose can be taught in the classroom when the curriculum is responsive to students’ questions and interests. She identifies purposeful projects as pedagogical tools to engage students in deeper learning about topics that are intrinsically motivating and personally meaningful to them. According to her, projects are meaningful when the content and activities are responsive to students’ questions and curiosities. Projects become meaningful as students engage intentionally with the questions, ideas, or materials posed by the teacher, and the teacher shapes the project according to student’s emerging ideas and interests as they take shape. Purposeful projects have the following characteristics: they are inquiry-driven, they are sustained over time, they involve reflection throughout, they are collaborative and community building, they elevate students’ social awareness, and they set high expectations for students [24].
\nTirri and Kuusisto [28] present a case-study approach to promote purposeful teaching in teacher education. The core of purposeful teaching in the classroom context is based on the didactic relationship between the teacher and the student’s relation to content. To be able to create a didactic relation in learning, a teacher needs to illuminate the meaning of the subjects she teaches to her students [17]. Purposeful teaching takes place when a teacher creates conditions for learning that help students to find personal meaning from the contents and subjects taught. The practical case method for purposeful teaching, the didactic approach, is modified from the methods used in moral education [29].
\nThis specific case method has been used as part of a course in didactics, which is taught at the University of Helsinki at the beginning of all student teachers’ (approximately N = 600) pedagogical education. The student teachers who take this course include kindergarten teachers, elementary and secondary school teachers, and adult education teachers with different subject specialization. The process starts with the writing task in which the student teachers write a story of a personally meaningful teaching or learning experience from their school years or university classes, the most significant one they can remember. The aim of the writing task is to help the student teachers to remember a personally meaningful case related to teaching and engage them in reflecting on it. Students’ reflection is assisted with concrete questions related to the real-life teaching or learning experience they described. The emotions and situational details should be recalled with the help of questions to be able to relive them as authentic as possible.
\nThe writing task is followed by a group work in which the students reflect on their purposeful teaching or learning experiences more systematically. The aim of this group work is to guide the student teachers to pay attention to the content and meaning of teaching. They should also think the ways a teacher used to illustrate the meaning of the contents. After that, students share their experiences and discuss situational factors and relational characteristics of the case. Helpful questions are provided to help the students in their analysis and reflection on the case. Following this phase, the student teachers discuss together all the purposeful teaching and learning experiences identified and issues related to them. The individual work is widened to collective reconstruction and argumentation of the cases with peers and teacher educators. This would help the students to deepen their arguments and gain a broader understanding of the cases presented. Other student teachers’ experiences help individual students to build a holistic understanding of the case and situate it in a wider pedagogical and educational context. In best circumstances, some new understanding of the case emerges. The group work is followed by a reflective essay written individually by the students which is returned to the teacher educator. A case example of one teacher’s reflection on her purposeful teaching experience is reported in details in [28].
\nThe purposeful teacher needs to adapt to the needs of twenty-first century learners. One of the twenty-first century skills students should learn in school is competence in information and communication technology. Finland has taken an active role since 1990 in implementing information and communication technology (ICT) in schools and educating teachers for their pedagogical use [3]. In the twenty-first century, Finnish education is emphasizing digital teaching and learning even more and investing in improving our teachers in this area [13]. This new emphasis is a challenge for many Finnish teachers and students. A purposeful teacher pays attention to her students’ abilities, gender, prior knowledge, motives, and expectations to make learning meaningful for them. The skills related to information and communication technology differ a lot among students and teachers. Some of the students are more advanced in their use of information and communication technology than the teacher and others might not have any prior experience in this area. The teacher needs to find new pedagogical approaches to teach technology for the diversity of learners and differentiate teaching according to students’ abilities. The teacher might need in-service education to update her knowledge and skills and find purpose in learning new twenty-first century skills herself. The new information and communication technology has the potential to make learning more meaningful to some students, for example boys who do not have the patience to follow traditional teaching in classrooms or for talented students, who can advance faster in their studies. The needs for twenty-first century learners are the starting point for teacher’s search for purposeful teaching.
\nThe twenty-first century curricula in Finnish schools continue the trend of individualism and make room for purpose education for diverse learners in all school subjects. Education for purpose can be included for the school-based curricula integration projects in all grade levels. In teacher education, we want to educate teachers who can reflect on the educational purposefulness of their teaching from different points of views and help their students to find a purpose in their lives [20].
\nLifelong learning is one of the aims for twenty-first century teaching and teachers need to find a meaning in their work that would be sustainable for the years to come. In the search of long-term purpose for teaching, teachers can profit from the growth mindset identified by Dweck [30]. Mindsets are beliefs that teachers hold about their most basic qualities and abilities. In a growth mindset thinking, a teacher believes that her cognitive skills, teaching competencies, and personal strengths can be improved. A teacher believes that purposeful teaching is possible with hard work and effort and she is ready to invest her time to reach that goal. A teacher with a fixed mindset thinking believes that her cognitive skills and teaching competencies cannot be improved and her personal strengths are also static. This kind of thinking prevents the teacher from finding a long-term purpose for teaching that would sustain in the changing world. Growth mindset is a key to lifelong learning and creative thinking [31].
\nThe twenty-first century skills include an open-minded attitude from a teacher, a growth mindset, to learning to make it possible to be continually challenged to learn new things and guide the students in their search for purposeful learning. Purpose and growth mindset in learning needs to be complemented with ethical skills to combine excellence with ethics [32]. The ethical nature of teaching profession and the values underlying teachers’ ethical conduct provide excellent ground for teachers’ professional development with the goal of growing to be a purposeful teacher.
\nThe earlier version of this chapter was presented as a keynote talk at the Sixth Biennial Conference of EARLI SIG19 Religious and Spiritual Education in the University of Eastern Finland in June 13th, 2018.
Catalysts are the most effective and economically feasible way to increase yield of the product(s) in various production processes. The catalysts prepared with innovative approaches could have novel catalytic properties such as increased number of active sites, highly selective to the target product, resistance to deactivation, and extended lifetime. The precious metal-based catalysts with these properties could provide significant economic benefits for the production of hydrogen which is currently expensive. The hydrothermal gasification technologies (sub- and supercritical water gasification and aqueous-phase reforming) have considerable economic, environmental, and technical advantages over other energy-extensive conversion technologies [1]. These processes are compatible with water-soluble feedstocks such as biomass and gasification reactions that take place at lower temperatures. However, the absence of practical catalysts in hydrothermal conditions is a main challenge that impedes upscaling of these technologies for hydrogen gas production. Increasing demand, limited supply, and undesirable byproducts due to current methods indicate the need for the development of innovative, economically feasible, highly active, and stable catalysts for hydrothermal conversion of biomass-derived compounds to hydrogen in higher yield and richer composition.
Raney nickel and platinum-based catalysts are common catalysts that have been used for hydrogen gas production in various processes including hydrothermal gasification methods [2, 3]. Despite Raney nickel catalysts exhibit better activity than precious metals, the use of these catalysts in hydrothermal gasification processes is not the best because of the following reasons:
On the other hand, precious metals also show high activities in the reformation of oxygenated hydrocarbons. Since these metals are expensive, they are widely used in the supported form on activated carbon, alumina, titanium dioxide, silica, etc., for recycling [2]. Dispersion of small metal particles on the support with high specific surface area is considered more advantageous. The decrease in the particle size of metals on the support could enhance metal-support interaction and increase the activity of the catalyst for hydrogen production [6]. Large metal particles could cause more severe carbon formation and deposition on the catalyst surface [7].
Dispersion of metals on the support, resistance of metal particles to sintering, and the accessibility of active sites to reactants are highly affected by physical and chemical properties of the catalyst support [8]. Numerous studies showed that catalyst support could significantly affect the catalytic performance of metal catalysts in the various reactions including hydrothermal processes [9, 10]. The catalyst support provides a physical surface for the dispersion of metal particles and affects the catalytic activity [11]. The catalytic activities of the catalysts can be increased by the selection of a novel supportive material for better catalytic action (more active sites) and excellent mechanical strength and high surface area. The supportive materials can be chemically modified to increase surface area and porosity and create specific functional groups on the surface.
Carbon materials have been recognized as the most active supports for aqueous-phase reforming of biomass-derived compounds for hydrogen-rich gas production [2]. The interaction between active metal component and support plays an important role in the catalytic reactions. Therefore, catalytic properties of supported catalysts depend on the combination of the type of metal and supportive material. The catalytic activity of these catalysts for hydrogen production has been significantly improved with recent research activities; however, they are still not good as Raney nickel catalysts. The activity of the supported precious metal catalysts reduce because of aggregation or poisoning of metal particles in reaction environment or coke deposition on active surfaces of the catalysts [12]. Leaching of the metal particles from support is another problem that causes decay of catalyst activity. Increasing the catalytic activity and stability of the catalysts is a challenge for high-yielding hydrogen gas production.
The porous structure and surface chemistry of activated carbon as a support material highly affect the activity of the catalyst. Porous carbon materials are of interest in many applications due to their high surface area and physicochemical properties. Those carbon materials can be categorized according to their pore sizes as microporous (pore size <2 nm), mesoporous (2 nm < pore size <50 nm), and/or macroporous (pore size >50 nm) [13]. Mesoporous carbons have large surface areas and are rich in oxygen-containing functional groups in the surfaces. They can enhance the affinity between the substrate molecules and the catalyst through abundant functional groups and large uniform pores. Those materials may offer great advantages over other carbon materials owing to their well-controlled pore structures in the mesopores, which might be favorable to the transportation of large molecules such as polysaccharides released from cellulose and hemicellulose structures in the biomass.
The oxygen-containing functional groups on the surface of carbons significantly influenced their performance in catalytic reactions [14]. Many different activating agents such as strong or weak acids and bases or oxidants (H2SO4, H3PO4, HNO3, CH3COOH, NH3, KOH, H2O2, O3, etc.) can be used in this process to introduce oxygen-containing functional groups on the carbon surface [15, 16]. The abundant oxygen groups in the supports facilitate the access of oxygenated biomass components to the surface of the catalyst; the open pore structure permits the molecules (solubilized biomass components) to effectively diffuse to the active sites and reacts with metal catalyst particles.
HPCs structured with micro-, meso-, and macropores can provide multi-active sites in the catalytic conversion processes and better accessibility for the feeds that are composed of different molecular weight organic compounds such as lignocellulosic biomass hydrolysates. The mass transport of different sized biomass compounds can be easily facilitated by the macropores and micro−/mesopores that provide access to the metal catalysts deposited in HPC. Currently, HPC preparation methods are expensive and complex. Synthesis of HPCs by utilization of abundant and widely available waste materials can provide opportunity to develop such materials in a sustainable way for many applications including hydrogen production. Direct carbonization of biomass or any solid organic wastes for the synthesis of HPCs is not applicable because of heterogeneity and uncontrollability in morphology and pore structure of the resulted carbon products. It is almost impossible to produce same carbon materials continuously from direct carbonization of nonuniform solid precursors.
Hierarchical structures with uniform and controllable pore sizes can be prepared by carbonization of different precursors using various templates. Low-density HPCs are prepared from various carbon nanomaterials such as graphene, and the resulted HPCs are aerogel-type carbon materials with moderate surface areas and different sized micro−/mesopore structures [17]. Unfortunately, all these and other existing methods have various drawbacks such as using nonrenewable precursors or templates, long synthesis period (e.g., solvent exchange and supercritical drying in the case of aerogels), involving multiple steps that make the process more costly and time-consuming, etc. [18].
The most common carbon aerogels are prepared by sol–gel polymerization of resorcinol and formaldehyde mixtures followed with supercritical drying and carbonization that were first prepared by Pekala [19]. In addition to resorcinol-formaldehyde, various monomers can be used to prepare these materials, including melamine-formaldehyde, phenol-formaldehyde, cresol-formaldehyde, phenol-furfural, and some polymers such as polystyrenes and polyurethanes [20, 21, 22, 23].
A wide spectrum of different carbon aerogel materials with unique properties can be prepared depending on synthesis and processing conditions. Synthesis conditions of organic aerogel (e.g., resorcinol/formaldehyde ratio, catalysts, and pH), curing and drying methods, and carbonization conditions determine surface area, pore volume, and pore size distribution of final carbon aerogel [24].
Supercritical carbon dioxide and freeze-drying are preferable methods to dry the organic gel while retaining skeletal pore structure during drying stage. During carbonization, dried aerogel is heated under inert atmosphere to obtain carbon-rich structure by removing oxygen and hydrogen functionalities.
Different metal-doped carbon aerogels have been developed including W-, Ru-, Co-, Ni-, Pd-, and Pt-carbon aerogels for various catalytic reaction, and these catalysts can show good activity in hydrogen production processes as well (Figure 1).
Resorcinol-formaldehyde aerogel and its carbonized form (carbon aerogel).
Reactivity of the graphene support can be increased by different approaches. Chemical doping is important approach to tailor the property of graphene that can change its surface reactivity and increase its performance as catalyst support. Introduction heteroatoms, such as nitrogen, boron, phosphorus, or sulfur atoms, into the carbon lattice of graphene by chemical doping can change the electronic properties of graphene [25].
Carbon nanotubes (CNTs) are cylindrical molecules that consist of rolled-up typical graphene sheets (Figure 2). Different CNTs (different rolling up direction of graphene layers or single-walled and multi-walled carbon nanotubes) determine the mechanical, electrical, and structural properties of the nanotubes that affect their catalytic activities. Metal particles supported on CNT can poorly be affected from carbon monoxide poisoning than traditional catalyst systems [26], and for this reason CNTs are good candidates to be used as catalyst supports.
Chemical structures of graphene, single-walled, and multi-walled carbon nanotubes.
A reported study showed that Pt on a single-walled carbon nanotubes catalyst were better catalysts in terms of hydrogen production activity and selectivity than Pt on a multi-walled carbon nanotube for hydrothermal gasification of biomass hydrolysates. Since the biomass hydrolysates tested were composed of large carbohydrate molecules (consisting of two carbohydrate fractions with 69,800 and 25,400 Da), these compounds were unable to enter narrow graphene sheets of multi-walled carbon nanotubes to react with Pt metals deposited inside the graphene layers. On the other hand, when the simplest biomass model compound, glucose, was used as feed solution, same catalytic activity was observed for both catalysts [27]. These results indicated that the catalytic activity of graphene-based carbon materials is strongly dependent on how the graphene sheet is shaped. Different shaped graphene-based structures with new properties could be promising supportive materials for Pt deposition, and resulting reforming catalysts could exhibit unique properties for hydrogen production (e.g., more active sites and suitable gaps between graphene sheets for the entrance of biomass molecules). The controlled graphene structure permits the small biomass molecules (oligo- and monosaccharides) to effectively diffuse the active sites and react with Pt particles to produce hydrogen gas.
Different graphene nanostructures can be prepared by growing graphene on presynthesized nanostructured metal templates by chemical vapor deposition and then etching away the metal to get a free-standing graphene nanostructure with novel properties to be used as catalyst support in hydrothermal gasification processes [28].
The introduction of heteroatom into carbon structure can change the physicochemical and electronic properties of the carbon material and enhance the catalytic functions [29]. Nitrogen atoms can create high positive charge distribution in the nearby C atoms due to its high electron withdrawing ability. Atomic sizes of nitrogen and carbon atoms are similar, and five available valence electrons in nitrogen can lead to the formation of valence bonds with C atoms and covalent bonding between N and C network of carbon results in more stable structure. Dual or multiple heteroatoms (B, N, P, S, F
HPCs with heteroatom (e.g., nitrogen and sulfur)-doped carbon network are important carbon-based functional materials and have attracted great attentions because of their excellent properties [32]. Incorporation of nitrogen into the carbon improved the stability of precious metal particles by reducing sintering and leaching of the metals in aqueous-phase furfural hydrogenation reaction [33]. The studies showed that dual or multiple elements-doped carbon catalysts exhibited synergistic effects with enhanced activity in
Carbon-supported precious metal (e.g., platinum) catalysts are active catalysts for hydrothermal conversion of biomass-derived compounds to hydrogen [2]. For better hydrogen production yield, Pt particles deposited on the support should be nanosized, uniform, and well dispersed that highly depend on the type of support, deposition method for metals including solvents and other active chemicals used during deposition process, type of metal precursors, reduction method for metal precursors, drying and calcination treatments, etc.
Catalysts can be deactivated during gasification process due to strong adsorption of feed impurities, aggregation or poisoning of metal particles in reaction medium, or coke deposition on active surfaces of the catalysts [12]. These drawbacks can be partially eliminated or lowered by integrating non-precious metals in precious metals containing catalyst system. Catalytic activity of supported Pt catalyst considerably improved when some certain metals deposited on the support along with Pt. It was reported that the activity of Pt catalysts could be improved by the addition of transition metals that have C-C bond breaking ability (Co, Ni, Fe, Sn, etc.) to a supported Pt catalyst. For instance, the addition of Fe to Pt at a 1:1 Pt:Fe atomic ratio significantly increased hydrogen production yield and selectivity [35]. Addition of a non-expensive metal in precious catalysts can reduce oxidation of precious metal particles by diluting them with non-expensive metals, reduce metal sintering, and favor water-gas shift reaction [36].
Catalytic activity of alumina nanofibers supported Pt catalyst considerably improved when Ni was deposited on the support along with Pt [9]. Kunkes et al. reported that addition of Re to Pt on carbon catalyst enhanced the Pt dispersion and favored water-gas shift reaction [37]. Pt-Co and Pt-Ni catalysts have been reported to be highly active catalysts with high hydrogen selectivity and low coking tendency [7, 38]. Co-deposition of Sn with Pt on to Al2O3 support caused dilution of Pt particles with Sn particles that improved activity and selectivity of the catalyst [39].
A recent study showed that performance of Pt-only catalyst could be considerably enhanced by replacing some of Pt particles with different non-expensive metals for hydrothermal conversion of biomass compounds to hydrogen-rich gas mixture. As can be seen in Figure 3, the gas mixture produced from hydrothermal gasification of glucose was composed of hydrogen, carbon monoxide, and carbon dioxide. As expected, monometallic Pt catalyst resulted in the highest conversion with highest hydrogen yield as this metal is known to be best catalyst for hydrogen production. Incorporating W and Ni metals to Pt-only catalyst showed promising activity despite replacing half amount of Pt with Ni and W metals [4].
Comparison of activity of the catalysts prepared with different metals and combination of these metals with Pt for hydrothermal conversion of glucose to hydrogen-rich gas mixture [
Metal core-carbon shell catalysts have exhibited a great potential for various applications, and fabrication of these types of catalysts for specifically hydrogen gas production can be promising. Metal particles are encapsulated in hollow porous carbon shell or heteroatom-doped hollow porous carbon (shell) (Figure 4).
Core-shell-structured catalysts.
Metal nanoparticles that are made of various combinations of precious metal (e.g., Pt) and/or inexpensive metals (Ni, Sn, Co, and W) in different compositions (e.g., mono and bimetallic) can be used as core materials. It is possible to improve the catalytic activity in this core-shell approach due to increased surface area and the closed interfacial interaction between the core and the shell. Reactants/products can transfer through penetrable shell structure. The shell prevents sintering of the metal nanoparticles in the core. Because of heterogeneous nature, the catalysts can be reused in the process after collecting from aqueous reaction medium by simple separation methods (centrifugation, filtration, etc.).
The encapsulation of metal nanoparticles in a penetrable shell catalyst has recently become a new strategy in the catalyst design area. The encapsulation of precious metal nanoparticles in a stable protective shell can enhance the activity and extent lifetime of the catalyst by maintaining and protecting the size and shape of the precious metal nanoparticles. This core-shell-type catalyst exhibits high stability, catalytic activity, and selectivity in various reactions [40, 41]. For an example, Pt nanoparticles-mesoporous silica core-shell catalyst was reported to have excellent stability for alkene hydrogenation [42].
In the core-shell type of catalysts, the metal nanoparticles are embedded in a protective matrix with channels, which can avoid aggregation or sintering of the metal nanoparticles in the core even at high temperatures and enables transfer of reactants/products through the channels [41]. The metal nanoparticles in the core are mainly responsible for the catalytic activity for a specific reaction. The channels in the shell give access to organic compounds to react with metal particles in the core. This protects metal particles from unwanted reactions in the reaction medium. Ikeda et al. developed such a catalyst design for platinum catalyst for hydrogenation of nitrobenzene in liquid phase [43]. The core-shell catalyst showed very high activity and exhibited almost same activity even after reused. Various porous materials have been used as shell materials to develop such catalysts for a wide range of applications (e.g., mesoporous silica, mesoporous carbon, metal oxides, titanium dioxide, and polymers) [44, 45].
Hollow porous carbon materials have unique properties, such as low density, controllable morphologies, available cavities, high surface areas, tunable porosity, and good chemical stabilities. The encapsulation of metal nanoparticles in a such selectively penetrable shell, hollow porous carbon, can result in novel catalysts for hydrothermal conversion technologies. Hollow porous materials not only have pores in their shell but also contain a hollow core and have higher porosity. Porous carbon shell with hollow structure can enhance the overall activity of the catalysts by increasing the accessibility of the reactants to the active phase. These nanostructures have emerged as an important class of carbon materials in many fields including energy, catalysis, and nanomedicine.
Lack of economically feasible, highly active, and stable catalysts for hydrothermal conversion of biomass-derived compounds to hydrogen is a main challenge that impedes application of these technologies for large-scale hydrogen gas production systems. Choice of appropriate inexpensive metals with right combination of precious metal(s) could reduce catalyst cost and improve the catalytic activity of precious metal-based catalysts. However, the stability of these catalysts in an aqueous processing environment is an important issue that needs to be studied in detail.
Since protection of metal catalyst is a big challenge in hydrothermal condition in which organic-rich solutions/materials are used as feeds, the metal core-carbon shell catalysts could also be a solution. Hollow porous carbon materials can be synthesized in desirable morphologies, sizes, compositions, and pore structures depending on templating strategies used in the preparation steps. The physicochemical and electronic properties of the hollow porous carbon materials can be changed by the introduction of a heteroatom such as nitrogen into carbon shell that enhance the activity and stability of the catalyst.
Graphene-based carbons with controlled graphene nanostructures could show unique properties as catalyst support for metal particles and effectively diffuse the biomass compounds to the active sites and leave agglomeration byproducts and large-sized contaminants in the solution.
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In this expository article, we review all previous works done in the field of identifying potential spreaders in a network.",book:{id:"5842",slug:"graph-theory-advanced-algorithms-and-applications",title:"Graph Theory",fullTitle:"Graph Theory - Advanced Algorithms and Applications"},signatures:"Reji Kumar Karunakaran, Shibu Manuel and Edamana Narayanan\nSatheesh",authors:[{id:"200190",title:"Dr.",name:"Reji Kumar",middleName:null,surname:"Karunakaran",slug:"reji-kumar-karunakaran",fullName:"Reji Kumar Karunakaran"},{id:"200193",title:"Mr.",name:"Manuel",middleName:null,surname:"Shibu",slug:"manuel-shibu",fullName:"Manuel Shibu"},{id:"200194",title:"Dr.",name:"E N",middleName:null,surname:"Satheesh",slug:"e-n-satheesh",fullName:"E N Satheesh"}]},{id:"57940",doi:"10.5772/intechopen.72145",title:"Graph-Based Decision Making in Industry",slug:"graph-based-decision-making-in-industry",totalDownloads:1724,totalCrossrefCites:3,totalDimensionsCites:3,abstract:"Decision-making in industry can be focused on different types of problems. Classification and prediction of decision problems can be solved with the use of a decision tree, which is a graph-based method of machine learning. In the presented approach, attribute-value system and quality function deployment (QFD) were used for decision problem analysis and training dataset preparation. A decision tree was applied for generating decision rules.",book:{id:"5842",slug:"graph-theory-advanced-algorithms-and-applications",title:"Graph Theory",fullTitle:"Graph Theory - Advanced Algorithms and Applications"},signatures:"Izabela Kutschenreiter-Praszkiewicz",authors:[{id:"218951",title:"Associate Prof.",name:"Izabela",middleName:null,surname:"Kutschenreiter-Praszkiewicz",slug:"izabela-kutschenreiter-praszkiewicz",fullName:"Izabela Kutschenreiter-Praszkiewicz"}]},{id:"72140",doi:"10.5772/intechopen.91972",title:"Comparative Study of Algorithms Metaheuristics Based Applied to the Solution of the Capacitated Vehicle Routing Problem",slug:"comparative-study-of-algorithms-metaheuristics-based-applied-to-the-solution-of-the-capacitated-vehi",totalDownloads:685,totalCrossrefCites:0,totalDimensionsCites:2,abstract:"This chapter presents the best-known heuristics and metaheuristics that are applied to solve the capacitated vehicle routing problem (CVRP), which is the generalization of the TSP, in which the nodes are visited by more than one route. To find out which algorithm obtains better results, there are 30 test instances used, which are grouped into 3 sets of problems according to the position of the nodes. The study begins with an economic impact analysis of the transportation sector in companies, which represents up to 20% of the final cost of the product. This case study focuses on the CVRP for its acronym capacitated vehicle routing problem, analyzing the best-known heuristics such as Clarke & Wright and sweep, and the algorithms GRASP and simulated annealing metaheuristics based.",book:{id:"8241",slug:"novel-trends-in-the-traveling-salesman-problem",title:"Novel Trends in the Traveling Salesman Problem",fullTitle:"Novel Trends in the Traveling Salesman Problem"},signatures:"Fernando Francisco Sandoya Sánchez, Carmen Andrea Letamendi Lazo and Fanny Yamel Sanabria Quiñónez",authors:[{id:"155426",title:"Ph.D.",name:"Fernando",middleName:"Francisco",surname:"Sandoya",slug:"fernando-sandoya",fullName:"Fernando Sandoya"},{id:"313162",title:"M.Sc.",name:"Carmen",middleName:null,surname:"Letamendi",slug:"carmen-letamendi",fullName:"Carmen Letamendi"},{id:"319376",title:"Dr.",name:"Fanny",middleName:null,surname:"Sanabria",slug:"fanny-sanabria",fullName:"Fanny Sanabria"}]},{id:"55541",doi:"10.5772/intechopen.68703",title:"Modeling Rooted in‐Trees by Finite p‐Groups",slug:"modeling-rooted-in-trees-by-finite-p-groups",totalDownloads:1148,totalCrossrefCites:2,totalDimensionsCites:2,abstract:"Graph theoretic foundations for a kind of infinite rooted in-trees T(R)=(V,E) with root R, weighted vertices v ∈ V, and weighted directed edges e∈E⊂V×V are described. Vertex degrees deg(v) are always finite but the trees contain infinite paths (vi)i≥0. A concrete group theoretic model of the rooted in-trees T(R) is introduced by representing vertices by isomorphism classes of finite p-groups G, for a fixed prime p, and directed edges by epimorphisms π: G → πG of finite p-groups with characteristic kernels ker(π). The weight of a vertex G is realized by its nuclear rank n(G) and the weight of a directed edge π is realized by its step size s(π)=logp(#ker(π)). These invariants are essential for understanding the phenomenon of multifurcation. Pattern recognition methods are used for finding finite subgraphs which repeat indefinitely. Several periodicities admit the reduction of the complete infinite graph to finite patterns. The proof is based on infinite limit groups and successive group extensions. It is underpinned by several explicit algorithms. As a final application, it is shown that fork topologies, arising from repeated multifurcations, provide a convenient description of complex navigation paths through the trees, which are of the greatest importance for recent progress in determining p-class field towers of algebraic number fields.",book:{id:"5842",slug:"graph-theory-advanced-algorithms-and-applications",title:"Graph Theory",fullTitle:"Graph Theory - Advanced Algorithms and Applications"},signatures:"Daniel C. Mayer",authors:[{id:"198580",title:"Dr.",name:"Daniel C.",middleName:null,surname:"Mayer",slug:"daniel-c.-mayer",fullName:"Daniel C. Mayer"}]},{id:"57771",doi:"10.5772/intechopen.71774",title:"Governance Modeling: Dimensionality and Conjugacy",slug:"governance-modeling-dimensionality-and-conjugacy",totalDownloads:1347,totalCrossrefCites:1,totalDimensionsCites:2,abstract:"The Q-analysis governance approach and the use of simplicial complexes—type of hypergraph—allow to introduce the formal concepts of dimension and conjugacy between the network of entities involved in governance (typically organizations) and the networks of those attributes taken into account (e.g. their competences), which offer a specific angle of analysis. The different sources of existing data (e.g. textual corpora) to feed the analysis of governance—environmental in particular—are mentioned, their reliability is briefly discussed and the required pre-processing steps are identified in the perspective of evidence-based analyses. Various indices are constructed and evaluated to characterize the context of governance as a whole, at mesoscale, or locally, i.e. at the level of each of the entities and each of the attributes considered. The analysis of ideal-type stylizing boundary cases provides useful references to the analysis of concrete systems of governance and to the interpretation of their empirically observed properties. The use of this governance modeling approach is illustrated by the analysis of a health-environment governance system in Southeast Asia, in the context of a One Health approach.",book:{id:"5842",slug:"graph-theory-advanced-algorithms-and-applications",title:"Graph Theory",fullTitle:"Graph Theory - Advanced Algorithms and Applications"},signatures:"Pierre Mazzega, Claire Lajaunie and Etienne Fieux",authors:[{id:"220099",title:"Dr.",name:"Pierre",middleName:null,surname:"Mazzega",slug:"pierre-mazzega",fullName:"Pierre Mazzega"},{id:"220102",title:"Dr.",name:"Claire",middleName:null,surname:"Lajaunie",slug:"claire-lajaunie",fullName:"Claire Lajaunie"},{id:"220103",title:"Prof.",name:"Etienne",middleName:null,surname:"Fieux",slug:"etienne-fieux",fullName:"Etienne Fieux"}]}],mostDownloadedChaptersLast30Days:[{id:"71899",title:"Moments of Catalan Triangle Numbers",slug:"moments-of-catalan-triangle-numbers",totalDownloads:562,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"In this chapter, we consider the Catalan numbers, \n\n\nC\nn\n\n=\n\n1\n\nn\n+\n1\n\n\n\n\n\n\n2\nn\n\n\n\n\nn\n\n\n\n\n\n, and two of their generalizations, Catalan triangle numbers, \n\n\nB\n\nn\n,\nk\n\n\n\n and \n\n\nA\n\nn\n,\nk\n\n\n\n, for \n\nn\n,\nk\n∈\nN\n\n. They are combinatorial numbers and present interesting properties as recursive formulae, generating functions and combinatorial interpretations. We treat the moments of these Catalan triangle numbers, i.e., with the following sums: \n\n\n∑\n\nk\n=\n1\n\nn\n\n\nk\nm\n\n\nB\n\nn\n,\nk\n\nj\n\n,\n\n∑\n\nk\n=\n1\n\n\nn\n+\n1\n\n\n\n\n\n2\nk\n−\n1\n\n\nm\n\n\nA\n\nn\n,\nk\n\nj\n\n,\n\n for \n\nj\n,\nn\n∈\nN\n\n and \n\nm\n∈\nN\n∪\n\n0\n\n\n. We present their closed expressions for some values of \n\nm\n\n and \n\nj\n\n. Alternating sums are also considered for particular powers. Other famous integer sequences are studied in Section 3, and its connection with Catalan triangle numbers are given in Section 4. Finally we conjecture some properties of divisibility of moments and alternating sums of powers in the last section.",book:{id:"8142",slug:"number-theory-and-its-applications",title:"Number Theory and Its Applications",fullTitle:"Number Theory and Its Applications"},signatures:"Pedro J. Miana and Natalia Romero",authors:null},{id:"55642",title:"Monophonic Distance in Graphs",slug:"monophonic-distance-in-graphs",totalDownloads:1550,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"For any two vertices u and v in a connected graph G, a u − v path is a monophonic path if it contains no chords, and the monophonic distance dm(u, v) is the length of a longest u − v monophonic path in G. For any vertex v in G, the monophonic eccentricity of v is em(v) = max {dm(u, v) : u ∈ V}. The subgraph induced by the vertices of G having minimum monophonic eccentricity is the monophonic center of G, and it is proved that every graph is the monophonic center of some graph. Also it is proved that the monophonic center of every connected graph G lies in some block of G. With regard to convexity, this monophonic distance is the basis of some detour monophonic parameters such as detour monophonic number, upper detour monophonic number, forcing detour monophonic number, etc. The concept of detour monophonic sets and detour monophonic numbers by fixing a vertex of a graph would be introduced and discussed. Various interesting results based on these parameters are also discussed in this chapter.",book:{id:"5842",slug:"graph-theory-advanced-algorithms-and-applications",title:"Graph Theory",fullTitle:"Graph Theory - Advanced Algorithms and Applications"},signatures:"P. Titus and A.P. Santhakumaran",authors:[{id:"198301",title:"Dr.",name:"P.",middleName:null,surname:"Titus",slug:"p.-titus",fullName:"P. Titus"},{id:"199035",title:"Prof.",name:"A. P.",middleName:null,surname:"Santhakumaran",slug:"a.-p.-santhakumaran",fullName:"A. P. Santhakumaran"}]},{id:"71501",title:"Accelerating DNA Computing via PLP-qPCR Answer Read out to Solve Traveling Salesman Problems",slug:"accelerating-dna-computing-via-plp-qpcr-answer-read-out-to-solve-traveling-salesman-problems",totalDownloads:820,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"An asymmetric, fully-connected 8-city traveling salesman problem (TSP) was solved by DNA computing using the ordered node pair abundance (ONPA) approach through the use of pair ligation probe quantitative real time polymerase chain reaction (PLP-qPCR). The validity of using ONPA to derive the optimal answer was confirmed by in silico computing using a reverse-engineering method to reconstruct the complete tours in the feasible answer set from the measured ONPA. The high specificity of the sequence-tagged hybridization, and ligation that results from the use of PLPs significantly increased the accuracy of answer determination in DNA computing. When combined with the high throughput efficiency of qPCR, the time required to identify the optimal answer to the TSP was reduced from days to 25 min.",book:{id:"8241",slug:"novel-trends-in-the-traveling-salesman-problem",title:"Novel Trends in the Traveling Salesman Problem",fullTitle:"Novel Trends in the Traveling Salesman Problem"},signatures:"Fusheng Xiong, Michael Kuby and Wayne D. Frasch",authors:[{id:"14757",title:"Prof.",name:"Wayne",middleName:null,surname:"Frasch",slug:"wayne-frasch",fullName:"Wayne Frasch"},{id:"317054",title:"Prof.",name:"Michael",middleName:null,surname:"Kuby",slug:"michael-kuby",fullName:"Michael Kuby"},{id:"317055",title:"Dr.",name:"Fusheng",middleName:null,surname:"Xiong",slug:"fusheng-xiong",fullName:"Fusheng Xiong"}]},{id:"72027",title:"Identification of Eigen-Frequencies and Mode-Shapes of Beams with Continuous Distribution of Mass and Elasticity and for Various Conditions at Supports",slug:"identification-of-eigen-frequencies-and-mode-shapes-of-beams-with-continuous-distribution-of-mass-an",totalDownloads:939,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"In the present article, an equivalent three degrees of freedom (DoF) system of two different cases of inverted pendulums is presented for each separated case. The first case of inverted pendulum refers to an amphi-hinge pendulum that possesses distributed mass and stiffness along its height, while the second case of inverted pendulum refers to an inverted pendulum with distributed mass and stiffness along its height. These vertical pendulums have infinity number of degree of freedoms. Based on the free vibration of the above-mentioned pendulums according to partial differential equation, a mathematically equivalent three-degree of freedom system is given for each case, where its equivalent mass matrix is analytically formulated with reference on specific mass locations along the pendulum height. Using the three DoF model, the first three fundamental frequencies of the real pendulum can be identified with very good accuracy. Furthermore, taking account the 3 × 3 mass matrix, it is possible to estimate the possible pendulum damages using a known technique of identification mode-shapes via records of response accelerations. Moreover, the way of instrumentation with a local network by three accelerometers is given via the above-mentioned three degrees of freedom.",book:{id:"8142",slug:"number-theory-and-its-applications",title:"Number Theory and Its Applications",fullTitle:"Number Theory and Its Applications"},signatures:"Triantafyllos K. Makarios",authors:[{id:"69418",title:"Prof.",name:"Triantafyllos",middleName:"Konstantinos",surname:"Makarios",slug:"triantafyllos-makarios",fullName:"Triantafyllos Makarios"}]},{id:"57940",title:"Graph-Based Decision Making in Industry",slug:"graph-based-decision-making-in-industry",totalDownloads:1723,totalCrossrefCites:3,totalDimensionsCites:3,abstract:"Decision-making in industry can be focused on different types of problems. Classification and prediction of decision problems can be solved with the use of a decision tree, which is a graph-based method of machine learning. In the presented approach, attribute-value system and quality function deployment (QFD) were used for decision problem analysis and training dataset preparation. A decision tree was applied for generating decision rules.",book:{id:"5842",slug:"graph-theory-advanced-algorithms-and-applications",title:"Graph Theory",fullTitle:"Graph Theory - Advanced Algorithms and Applications"},signatures:"Izabela Kutschenreiter-Praszkiewicz",authors:[{id:"218951",title:"Associate Prof.",name:"Izabela",middleName:null,surname:"Kutschenreiter-Praszkiewicz",slug:"izabela-kutschenreiter-praszkiewicz",fullName:"Izabela Kutschenreiter-Praszkiewicz"}]}],onlineFirstChaptersFilter:{topicId:"1399",limit:6,offset:0},onlineFirstChaptersCollection:[],onlineFirstChaptersTotal:0},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:90,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:107,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:33,numberOfPublishedChapters:330,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:14,numberOfPublishedChapters:145,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:9,numberOfPublishedChapters:139,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:123,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:112,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:21,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:10,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:"2753-6580",doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}},{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}}]},series:{item:{id:"7",title:"Biomedical Engineering",doi:"10.5772/intechopen.71985",issn:"2631-5343",scope:"Biomedical Engineering is one of the fastest-growing interdisciplinary branches of science and industry. The combination of electronics and computer science with biology and medicine has improved patient diagnosis, reduced rehabilitation time, and helped to facilitate a better quality of life. Nowadays, all medical imaging devices, medical instruments, or new laboratory techniques result from the cooperation of specialists in various fields. The series of Biomedical Engineering books covers such areas of knowledge as chemistry, physics, electronics, medicine, and biology. This series is intended for doctors, engineers, and scientists involved in biomedical engineering or those wanting to start working in this field.",coverUrl:"https://cdn.intechopen.com/series/covers/7.jpg",latestPublicationDate:"August 3rd, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:12,editor:{id:"50150",title:"Prof.",name:"Robert",middleName:null,surname:"Koprowski",slug:"robert-koprowski",fullName:"Robert Koprowski",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYTYNQA4/Profile_Picture_1630478535317",biography:"Robert Koprowski, MD (1997), PhD (2003), Habilitation (2015), is an employee of the University of Silesia, Poland, Institute of Computer Science, Department of Biomedical Computer Systems. For 20 years, he has studied the analysis and processing of biomedical images, emphasizing the full automation of measurement for a large inter-individual variability of patients. Dr. Koprowski has authored more than a hundred research papers with dozens in impact factor (IF) journals and has authored or co-authored six books. Additionally, he is the author of several national and international patents in the field of biomedical devices and imaging. Since 2011, he has been a reviewer of grants and projects (including EU projects) in biomedical engineering.",institutionString:null,institution:{name:"University of Silesia",institutionURL:null,country:{name:"Poland"}}},editorTwo:null,editorThree:null},subseries:{paginationCount:3,paginationItems:[{id:"7",title:"Bioinformatics and Medical Informatics",coverUrl:"https://cdn.intechopen.com/series_topics/covers/7.jpg",isOpenForSubmission:!0,editor:{id:"351533",title:"Dr.",name:"Slawomir",middleName:null,surname:"Wilczynski",slug:"slawomir-wilczynski",fullName:"Slawomir Wilczynski",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000035U1loQAC/Profile_Picture_1630074514792",biography:"Professor Sławomir Wilczyński, Head of the Chair of Department of Basic Biomedical Sciences, Faculty of Pharmaceutical Sciences, Medical University of Silesia in Katowice, Poland. His research interests are focused on modern imaging methods used in medicine and pharmacy, including in particular hyperspectral imaging, dynamic thermovision analysis, high-resolution ultrasound, as well as other techniques such as EPR, NMR and hemispheric directional reflectance. Author of over 100 scientific works, patents and industrial designs. Expert of the Polish National Center for Research and Development, Member of the Investment Committee in the Bridge Alfa NCBiR program, expert of the Polish Ministry of Funds and Regional Policy, Polish Medical Research Agency. Editor-in-chief of the journal in the field of aesthetic medicine and dermatology - Aesthetica.",institutionString:null,institution:{name:"Medical University of Silesia",institutionURL:null,country:{name:"Poland"}}},editorTwo:null,editorThree:null},{id:"8",title:"Bioinspired Technology and Biomechanics",coverUrl:"https://cdn.intechopen.com/series_topics/covers/8.jpg",isOpenForSubmission:!0,editor:{id:"144937",title:"Prof.",name:"Adriano",middleName:"De Oliveira",surname:"Andrade",slug:"adriano-andrade",fullName:"Adriano Andrade",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRC8QQAW/Profile_Picture_1625219101815",biography:"Dr. Adriano de Oliveira Andrade graduated in Electrical Engineering at the Federal University of Goiás (Brazil) in 1997. He received his MSc and PhD in Biomedical Engineering respectively from the Federal University of Uberlândia (UFU, Brazil) in 2000 and from the University of Reading (UK) in 2005. He completed a one-year Post-Doctoral Fellowship awarded by the DFAIT (Foreign Affairs and International Trade Canada) at the Institute of Biomedical Engineering of the University of New Brunswick (Canada) in 2010. Currently, he is Professor in the Faculty of Electrical Engineering (UFU). He has authored and co-authored more than 200 peer-reviewed publications in Biomedical Engineering. He has been a researcher of The National Council for Scientific and Technological Development (CNPq-Brazil) since 2009. He has served as an ad-hoc consultant for CNPq, CAPES (Coordination for the Improvement of Higher Education Personnel), FINEP (Brazilian Innovation Agency), and other funding bodies on several occasions. He was the Secretary of the Brazilian Society of Biomedical Engineering (SBEB) from 2015 to 2016, President of SBEB (2017-2018) and Vice-President of SBEB (2019-2020). He was the head of the undergraduate program in Biomedical Engineering of the Federal University of Uberlândia (2015 - June/2019) and the head of the Centre for Innovation and Technology Assessment in Health (NIATS/UFU) since 2010. He is the head of the Postgraduate Program in Biomedical Engineering (UFU, July/2019 - to date). He was the secretary of the Parkinson's Disease Association of Uberlândia (2018-2019). Dr. Andrade's primary area of research is focused towards getting information from the neuromuscular system to understand its strategies of organization, adaptation and controlling in the context of motor neuron diseases. 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