Phonon-transmission histogram in ballistic, diffusive, and localization regimes . Copyright 2011 American Physical Society.
We give a theoretical review of recent development of the mesoscopic physics of phonon transport in carbon nanotubes, including the quantization of phonon thermal conductance, phonon Anderson localization, and so on. A single-walled carbon nanotube (SWCNT) can be regarded as a typical one-dimensional phonon conductor and exhibits various interesting phenomena originating from its one dimensionality. For example, a pristine SWCNT without any defects shows the quantization of phonon thermal conductance at low temperature. On the other hand, a defective SWCNT with randomly distributed carbon isotopes shows the phonon Anderson localization originating from the interference between phonons scattered by isotope impurities.
- carbon nanotube
- ballistic phonon
- quantized thermal conductance
- phonon Anderson localization
- phonon waveguide
Heating of electronic devices is an unavoidable serious problem toward the realization of next-generation nanoscale devices. Carbon nanotube (CNT) is expected to be a potential material for removing the heat from heated devices because of its high thermal conductivity. However, concern has been raised that intrinsic high thermal conductivity of pure CNTs is lost because of the presence of defects in synthesized CNTs.
In this chapter, we give a review of recent progress of theoretical works on phonon transport in CNTs focusing on the quantization of phonon thermal conductance, phonon Anderson localization, and so on. The phonon transport in CNTs shows fully quantum behaviors at low temperatures and exhibits strong nonlinear behaviors due to phonon-phonon interaction at high temperatures. Therefore, traditional transport theories for bulk objects are not applicable to the thermal transport in CNTs. In the chapter, we will introduce a novel theory for mesoscopic phonon transport we developed and will describe various results and their physical interpretations.
2. Coherent phonon thermal transport in carbon nanotubes
2.1. Quantized thermal conductance of carbon nanotubes
where a phonon energy dispersion of wave number and a phonon mode index , a group velocity,the Bose-Einstein distribution function in heat baths, and is the transmission probability between the system and heat baths .
Analytically, performing the integration in Eq. (1) is, generally, very difficult, and it requires a knowledge of and as a function of and . However, transformation of the integration variable in Eq. (1) from to leads to a cancelation between and the density of state, , so that Eq. (1) is rewritten as
Here and are the minimum and maximum angular frequencies of the th phonon dispersion, respectively. It is noted that Eq. (2) depends on only and regardless of the energy dispersion. Furthermore, within the linear response limit, , and the limit of adiabatic contact between the system and heat baths, , the thermal conductance, , is simplified as
Carrying out the integration in Eq. (3), we can derive an analytical expression of the thermal conductance, which can easily apply to various 1D ballistic phonon systems, :
Here, denotes “min” or “max,” is the Appel function, and . In particular, an acoustic mode () contributes a universal quantum of to the thermal conductance.
The thermal conductance in single-walled carbon nanotubes (SWCNTs) can be obtained by knowing the values of and for all . These values can be obtained from the diagonalization of the dynamical matrix, constructed with the scaled force-constant parameters [4, 5]. Figure 1 shows energy dispersion curves for the region near for a CNT with chiral vector , where is the magnitude of the unit vector along the tube axis. Here, the chiral vectoruniquely determines the geometrical structure of CNTs [5, 7]. Figure 1 shows four acoustic modes with linear dispersion: a longitudinal acoustic one, doubly degenerate transverse acoustic ones, and a twisting one. The lowest doubly degenerate optical (Raman active) modes have an energy gap of at . As shown in the inset of Figure 1, depends only on the tube radius and decreases approximately according to [5, 7]. These modes always lie in low-energy dispersion relations, independent of the geometry of SWCNTs.
Figure 2(a) shows the thermal conductances normalized to a universal value of (as explained later) as a function of temperature. The calculated values approach unity in the low-temperature limit, meaning that the phonon thermal conductance of SWCNTs is quantized in unit of a universal value of , independent of the chirality of SWCNTs. The origin of the quantization of thermal conductance is low-energy excitations of long wavelength acoustic phonons (four branches in Figure 1) at temperatures sufficiently low that the two lowest optical modes with are not excited (lowest gapped branch in Figure 2). The quantization can also be derived analytically from Eq. (4). Only the first term contributes to the conductance at the low-limit, leading to . Here, 4 is the number of acoustic branches.
As another important finding, the different curves of for various SWCNTs seen in Figure 2(a) exhibit a universal feature when a scaled temperature is introduced, . Taking account of the four acoustic and two lowest optical modes and substituting the values of for these branches at the into Eq. (2), the thermal conductance can be given as
The curves in Figure 2(a) are replotted against the curve of Eq. (5) with in Figure 2(b). It is evident that all curves (only three curves are shown for clarity) fall on a single curve coinciding with the curve of Eq. (5) in the low-limit. The curves turn upward at around from a linear region in this plot (quantization plateau), with the plateau width determined by the relation (see result in the inset of Figure 1). This universal feature of of SWCNTs indicates that the optical phonon energy gap, which is decided only by , characterizes low-temperature phonon transport, as shown in the inset of Figure 1. This theoretical result supports both the experimental observations and the inferred tube-radius dependence of the width of the thermal conductance plateau, although the unknown extrinsic factors in the experiment makes it impossible to compare the absolute values between the experiment and theory directly [8, 9].
The contribution of electrons to thermal conductance can be determined in a simple manner by replacing in Eq. (1) with and then substituting the electron energy bands, , into the formula. According to this formulation, all conduction bands crossing the Fermi energy level yield , as that of phonons, even though electrons obey different statistics. Generally, the quantum of thermal conductance should be universal out of relation to particle statistics [1, 10].
The low-behavior of the electronic thermal conductance in SWCNTs is dependent on whether the SWCNT is metallic or semiconducting, which is sensitive to radius and chirality [11, 12]. For semiconducting SWCNTs, the electronic thermal conductance, , should vanish roughly exponentially in the limit of , having an energy gap of the order of 0.1 eV [13, 14, 15]. For metallic SWCNTs, two linear energy bands crossing the Fermi level at  contribute toat low temperatures, resulting in a universal value of , where 4 is the number of two spin-degenerate channels crossing the Fermi level. This result also satisfies the Wiedemann-Franz relation between electrical conductance and electronic thermal one [16, 17, 18]. The total thermal conductance of metallic SWCNTs is given by at low temperatures.
Finally, in this subsection, a significant difference was recognized between the widths of the quantization plateau for phonons and those for electrons in metallic SWCNTs. The characteristic energy for phonon transport at low temperature is , typically a few meV, as described in Figure 2(b), while that for electron transport is of the order of 0.1 eV, which corresponds to the energy at a Van Hove singularity measured from the Fermi level . As a result, it is predicted that the quantized nature of electron thermal conductance survives up to room temperature, at which phonons already cease to exhibit thermal quantization, giving rise to high thermal conductance. In other words, the contribution from electrons to thermal conductance is negligible compared to that from phonons at moderate temperatures. In Figure 3, the temperature dependence of the ratio of thermal conductance for electrons and phonons is illustrated. The experimentally observed ratio  is 1 order of magnitude lower than the present value. The discrepancy is attributed to the theoretical treatment of SWCNTs as purely metallic, whereas only a certain fraction [5, 11] of the crystalline ropes of SWCNTs in the experiment will be metallic and contribute to .
2.2. Carbon nanotube as phonon waveguide
In this subsection, nonequilibrium molecular dynamics (NEMD) simulations are carried out with the Brenner bond-order potential for carbon-carbon covalent bonds  and the Lennard-Jones one for van der Waals interaction between the tube walls . In our NEMD simulations, different temperatures, () and (), are assigned to several layers of the left- and right-hand sides of a SWCNT. This leads to a thermal current from the right to left through the SWCNT, as shown in Figure 4. The Nosé-Hoover thermostat is utilized to control the temperature of the left and right-hand side several layers [24, 25], and we impose the fixed boundary condition, so that the edge atoms of SWCNTs are fixed rigidly. The length of the temperature-controlled layers is taken to be , where is the length of the phonon-conduction region. The tunable parameters in the Nosé-Hoover thermostat method were optimized so as to minimize contact thermal resistance . In our simulations, we solve Hamilton’s classical equations of motion using second-order operator splitting integrators  with the molecular-dynamics (MD) time step of 0.5 fs.
In this subsection, the thermal conductance is treated as
Here, the steady-state thermal current, , is calculated as follows:
where represents the number of MD steps and −is the amount of heat added to the right temperature-controlled layers (removed from the left ones) per unit time (see Figure 4).
First, the influence of bending deformation on the thermal conductance of SWCNTs is discussed. In our simulations, shortening the distance between the two ends of a SWCNT realizes bending. The right panels (a)-(c) in Figure 5 illustrate the bent SWCNT for compression lengths and nm, respectively. It can be seen that the CNT is severely bent as the edge-layer distance decreases. In the simulations, the bending deformation arises from stretching of carbon-carbon bond lengths, and the hexagonal network of carbon atoms in the SWCNT is not broken. The left panel in Figure 5 shows the thermal conductance of the SWCNT with as a function of the compression length. Our simulations exhibits that the bending does not affect the thermal conductance. Although the value of thermal conductance depends on , the -dependence is not discussed here because the conclusion of the study does not change qualitatively within the range from to nm as calculated. For the -dependence, we refer the reader to other published papers [26, 28, 29, 30, 31].
The bending robustness of can be understood through a perspective of the phonon dispersion relations as shown in Figure 6, given by the power spectra of velocity fluctuations calculated by MD simulations [26, 28]. Figure 6(a)-(c) show the dispersion relations of the bent SWCNT for and nm, respectively. Since the bending deformation does not break the hexagonal network of the SWCNT is not broken by the bending deformation, a change of the dispersion structure due to the bending is very small. More specifically, the dispersion structure in the low-energy region remains unchanged after the bending, whereas that in the high-frequency region is slightly changed as shown in Figure 6. Consequently, at the room-temperature is unaffected by the local bond-length deformation due to the bending. The bending robustness obtained by our simulations supports the experimental results of Chang et al. .
2.3. Phonon Anderson localization in isotope-disordered carbon nanotube
This subsection is focused on the interference effects of coherent phonons in SWCNTs. Here, we performed calculations for two typical examples: a (5,5) metallic SWCNT with 15.0% 13C and a (8,0) semiconducting SWCNT with 9.4% 14C. Our simulation is based on the Landauer theory of phonon transport combined with the nonequilibrium Green’s function (NEGF) technique [33, 34, 35]. We used the Brenner bond-order potential for the interaction between carbon atoms , as used in the previous subsection. It is assumed that isotope disorder exists only in a central region with a length . This region is connected to semi-infinite pristine SWCNT leads, not including any defects or impurities (Figure 7). In accordance with the Landauer theory within the linear response with the temperature difference between hot and cold baths , the phonon derived thermal conductance can be expressed as , where s is Planck’s constant, is the average temperature of the hot and cold baths, is the Bose-Einstein distribution function for a phonon with a frequency in the baths, and is the phonon-transmission function averaged over an ensemble of samples with different isotope configurations. We adopted over 200 realizations for each at each .
In the NEGF technique, the phonon-transmission function is given by , where is the retarded Green’s function in the central region and is the level broadening function due to the left (right) lead [33, 34, 35]. Here, is a dynamical matrix in the central region, a diagonal matrix with elements corresponding to the masses of the constituent atoms, and a self-energy due to the left (right) lead. A merit of NEGF technique is that the phonon transport in micrometer-length nanotubes can be efficiently computed. We can easily calculate the statistical average of the phonon transmission for nanotubes within the wide range of tube length with respect to huge number of isotope configurations. On the other hand, consideration of many-body interactions such as phonon-phonon scattering requires much computation time in the NEGF technique.
To perform the NEGF simulations, we first optimized the structures of a pristine (5,5) metallic and (8,0) semiconducting SWCNTs, and then calculated from the second derivative of the total energy of the optimized structures with respect to the atom coordinate. By using and the recursion method, we can easily compute . Moreover, we assume that the isotopes are taken into account only in .
Coherent-phonon transport is classified into three regions based on a relation among the length of the central region: the ballistic regime for , the diffusive one for , and the localization one for . Here, is the mean free path and the localization length. Before discussing the phonon-transmission histogram, we first determine and for isotope-disordered SWCNTs. We adopt the procedure used in Ref.  to estimate these lengths. Figure 8(a) shows the average phonon transmission of the (5,5) SWCNT with 15% 13C for various up to 5 m. In the very low-frequency region, does not decrease and is almost four, even in the presence of isotope impurities. Perfect transmission (i.e., ballistic transport) is realized because the wavelength of acoustic phonons in the low-region is much longer than . The Landauer expression of thermal conductance eventually exhibits universal quantization of 4at low temperatures irrespective of the presence and absence of isotope impurities (the factor 4 reflects the number of acoustic phonon modes).
In contrast, decreases rapidly in the higher frequency region with increasing , as shown in Figure 8(a). There are two possible mechanisms for the reduction of : diffusive scattering and phonon localization. For the former, decreases with according to , where means the number of phonon modes. On the other hand, for the latter mechanism, the phonon-transmission function decays exponentially with according to the scaling law . In other words, is defined by the scaling law. To clarify these mechanisms for the phonon-transmission reduction, the -dependences of and are plotted in Figure 8(b) and (c) for the two mechanisms, respectively. As Figure 8(b) shows that the numerical data of at and are well fitted by the dashed lines. In particular, the slope of the dashed line for is almost zero, implying that is very long and the phonon transport is ballistic at this frequency, as has been discussed above. For , the slope is finite, which indicates that phonon transport at this frequency is in the diffusive regime. In contrast to the low frequencies, at higher frequencies (,, and ), the calculated values deviate from the dashed lines with increasing , although they are well fitted in the short-region. This deviation means that the phonon-transmission reduction for high-phonons of a long-SWCNT cannot be explained by the diffusive scattering mechanism. As shown in Figure 8(c), the data for ,, and are well fitted by the dashed lines in the plot. Thus, it can be concluded that phonon localization causes the phonon-transmission reduction for high-phonons in a long-SWCNT.
and can be estimated from the slope of dashed lines in Figure 8(b) and (c), respectively. The estimated and for the (5,5) SWCNT with 15% 13C are presented in Figure 8(d). This result is in excellent agreement with the phenomenological Thouless relation, , similar to electron systems with time-reversal symmetry . Thus, the three distinct regimes (ballistic, diffusive, and localization) could be clarified.
Figure 9 shows the 13C-concentration dependence of in the (8,0) semiconducting SWCNT with 2 μm length at 300 K. As seen in Figure 9, thermal conductance decreases rapidly as the concentration increases. When the concentration overs about 20%, decreases by 80% in comparison with the pristine (8,0) SWCNT.
We now discuss the phonon-transmission fluctuation, defined by a standard deviation . Figure 10 shows for (a) 625 nm-long (5,5) SWCNT with 15% 13C and (b) 210 nm-long (8,0) SWCNT with 9.4% 14C. The fluctuation of a physical quantity generally decreases as its average value increases. However, the fluctuation of phonon transmission is constant within the frequency region in the diffusive regime although varies depending on [see also Figure 8(a)]. The constant value is estimated to be and indicated by the dashed lines in Figure 10(a) and (b). Thus, in the diffusive regime is universal and is independent of the background phonon transmission, the tube chirality and length, the isotope concentration, and the type of isotopes. This universal fluctuation is realized only in the diffusive regime and not in the ballistic and localization regimes. Interestingly, the value of is the same as the value of the universal conductance fluctuation (UCF) for coherent electron transport in disordered quasi-1D systems, , within the statistical error. Here, and are respectively the electrical conductance quantum and the electrical conductance fluctuation. This means that the universal phonon-transmission fluctuation is closely related to the UCF even though electrons and phonons obey different quantum statistics. Similar to the UCF, the reason for the macroscopically observable phonon-transmission fluctuation can be qualitatively understood as follows: the fluctuations of phonon-transmission channels cannot cancel each other because there are very few effective transmission channels due to isotope scattering. To obtain a quantitative and complete understanding of the universal phonon-transmission fluctuation, some sophisticated microscopic theories are required.
In the final of this subsection, we discuss the phonon-transmission histogram that contains information for every moment of . In Figure 11(a) and (b), for several typical frequencies in the diffusive regime of (a) 625 nm-long (5,5) SWCNT with 15% 13C and (b) 210 nm-long (8,0) SWCNT with 9.4% 14C are shown. All the histograms in these figures are well described by a Gaussian distribution function with the universal fluctuation . This is similar to the fact that the electrical conductance histogram in the diffusive region is expressed by a Gaussian distribution function with the UCF .
In regime, becomes no longer a symmetric Gaussian distribution. By analogy with the electrical conductance histogram in the localization regime , one can easily expect that the asymmetric histogram is a lognormal function of . In fact, can be well described by a Gaussian distribution as shown in Figure 11(c) and (d). Unlike the other regimes, the variance of decreases with increasing according to as shown in the insets of these figures, similar to the situation for electrons . The transmission fluctuation in the localization regime is material independent in the sense that the slope of does not depend on the tube geometry, isotope concentration, or the type of isotopes. The above-mentioned results for the ballistic, diffusive, and localization regimes are summarized in Table 1.
3. Crossover from ballistic to diffusive phonon transport
This section discusses the crossover from ballistic to diffusive phonon transport in SWCNT using some basic arithmetic which follows from the fictitious-probe idea. In this idea, the thermal conductance was found to formally have the same expression as the Landauer formula for coherent phonon transport [1, 6]:
even when phonon-phonon scattering exists. Here, is an averaged temperature as descried in the previous section, and is a phonon transmission function, effectively including the phonon-phonon scattering given as
where is the transmission function of a coherent phonon with a phonon mode and frequency flowing from to leads. Note that the inelastic component of thermal conductance in Eq. (8) is neglected, because it negligibly contributes toof CNTs in the quasiballistic regime.
Thus far, we have discussed the role of a single probe with temperature . Generally, a spatial distribution of temperature exists inside the conductor. In order to incorporate this distribution
, a conductor attaching probes in series, with respective temperatures is introduced. For probes, the transmission function propagating in a conductor of length can be written as
where the characteristic length is expressed by the density of scatters in the conductor, and . The derivation process of Eq. (10) is analogous to that of effective transmission for inelastic electronic transport in mesoscopic conductors . Here, it is explained that we can regard in Eq. (10) as the mean free path , where and are the backscattering time and group velocity of a phonon with , respectively. For phonon propagation over the distance between neighboring probes , the reflection probability is given by . Thus, the phonon’s mean free path is , and in the large-(or small-) limit where the transmission probability of each small segment with length is close to one ().
According to the above discussion, a general expression of thermal conductance is given as
We now apply the developed formula (11) to thermal transport in SWCNTs at room temperature. Instead of estimating from Eq. (9), we use an phenomenological expression for three-phonon Umklapp scattering events in the low-frequency limit , where is the coupling constant for graphene  and represents the curvature effect of a CNT (corresponds to a graphene). By using this expression we can perform integration in Eq. (11) analytically. Strictly speaking, this expression can apply only to acoustic phonon modes with linear dispersion, but it has been shown to be useful to represent other modes as well . Consequently, the thermal conductance is expressed simply as:
where is an
In Eq. (10), effects of phonon scattering at interfaces between a CNT and the left/right leads were not included. One of simple treatments of the interfacial thermal resistance is to introduce it by the following way: . The interfacial resistance can be decided by fitting experimental or numerical calculation data.
Now, we estimate the thermal conductance of SWCNTs by performing the NEMD simulations [26, 28] with Brenner’s bond-order potential , and compare the MD results to the above-described theory. The -dependence of thermal conductance was quantified for various tube lengths, up to micrometers at (and ). We refer the detailed simulation procedure to Ref. . The thermal conductances for (3,3) and (5,5) SWCNTs obtained from the NEMD simulations are shown by blue and red circles in Figure 12, respectively. The solid curves representing theoretical curves given the proper choice of two parameters and (e.g., and for the (3,3) SWCNT) excellently agree with the MD data. Most recently, the -dependent thermal conductance (or conductivity) of SWCNTs shown here has been measured in experiments [31, 44], although we cannot compare the theory with the experiments because the detailed information on tube structure such as number of walls and their chiralities was not described.
We return to discuss the ballistic-diffusive crossover. The relative position of with respect to the phonon dispersion relation determines the thermal-transport properties of SWCNTs. As illustrated in Figure 13, the dashed blue line indicates the position of relative to the dispersion relation. As seen in Figure 12, nanometer-length SWCNTs display the thermal conductance independent of , reflecting purely ballistic phonon transport. At nanometer length, is much larger than the energies of the phonons, as shown in the left panel of Figure 13.
With an increase in , up to micrometer length, the value of decreases, lying in the middle of the phonon dispersion relation, as shown in the central panel of Figure 13. In this situation, low-frequency phonon modes () give -independent thermal conductance reflecting a ballistic nature, whereas the high-frequency modes show reflecting a diffusive nature. The intermediate-frequency phonon modes () cannot be described in terms of both Landauer and Boltzmann-Peierls formulae, and the thermal conductance exhibits nonlinear -dependence described by Eq. (12). Thus, it is concluded that micrometer-length SWCNTs belong to the quasi-ballistic thermal transport regime in which ballistic and diffusive phonons coexist.
Next, the case when is much lower than the excitation frequency of the lowest optical phonons is discussed, as shown in the right panel of Figure 13. In this case, the tube lengthreaches millimeters and the contribution of optical phonons to thermal conductance has a behavior as , resulting in constant thermal conductivity, as . Here, is the cross-sectional area of a SWCNT. On the other hand, the acoustic modes show , leading to a power-law divergence of thermal conductivity [29, 30]. This divergence closely relates to the long-standing problem pointed out by Pomeranchuk in the 1940s that the low-frequency acoustic phonon contribution to thermal conductivity diverges in the thermodynamic limit
4. Thermal properties of graphene modulated by strain
Finally, we shortly mention the recent theoretical work about the thermal property in another carbon material, a graphene . In this work, the strain response of the phonon specific heat was investigated. The low temperature behavior of the specific heat is dominated by the three acoustic modes, i.e., the longitudinal acoustic (LA) mode, transverse acoustic (TA) mode, and out-of-plane acoustic (ZA) mode. It is well known that the LA and TA modes have a linear dispersion in the long wavelength region while the other has a quadratic one in the absence of the strain . This means that the ZA mode is critical for low-temperature dependence of the specific heat. As a result, the specific heat has a linear dependence at low temperature. As the strain increases, the dispersion of the ZA mode drastically changes, so that this dispersion becomes linear in the same as the LA and TA modes [50, 51]. Due to the ZA mode linearized by the strain, the low-temperature dependence of the specific heat becomes quadratic. Therefore, since the specific heat directly relates the thermal conductivity, it is easily expected that the strain can also modulate the temperature dependence of the thermal conductivity.
This chapter reviewed recent progress of theoretical studies on phonon transport in SWCNTs focusing on the quantization of phonon thermal conductance, phonon Anderson localization, and so on. At low temperature, the phonon thermal conductance of SWCNTs has a quantized universal value of , where the factor, 4 is the number of the acoustic modes in SWCNTs. As the temperature increases, the crossover from the ballistic transport to diffusive one occurs and the thermal conductance in the intermediate region between them indicates the non-linear dependence of tube length.
The authors would like to thank Kazuyuki Watanabe, Satoshi Watanabe, Shigeo Maruyama, Junichiro Shiomi, and Satoru Konabe for their useful discussions during this work. This work was supported, in part, by JSPS KAKENHI grants (nos. 19710083, 20048008, 22013004, 24681021, 15H03523 and 18H01816).
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