Characteristics of TiO2 films grown by MOCVD on borosilicate.
Abstract
The aim of this work was to characterize and evaluate the influence of the thickness on the photocatalytic efficiency of titanium dioxide thin films on the degradation of methyl orange dye under UV light irradiation. The films of 280 and 468 nm thick were deposited on borosilicate substrates at 400°C by the MOCVD technique using titanium isoproxide IV as precursor. XRD analyses showed the formation of anatase-TiO2 phase. Cross-sectional FE-SEM images show that the films presented a dense columnar structure and grown perpendicularly to the substrate surface. The photocatalytic activity of the catalysts was studied using UV-vis spectrophotometry The TiO2 film with 468 nm of thickness presented higher photocatalytic activity exhibiting 69% of dye degradation. The increase of grain size and thickness of the films promoted an improvement of photocatalytic efficiency.
Keywords
- TiO2 films
- MOCVD
- photocatalytic activity
1. Introduction
The availability of water is of great importance for the development of economic activities and mainly for human health. However, the rapid increase in industrial production resulted in serious consequences to the environment by generating waste and contaminating the water reserves [1, 2, 3]. The pharmaceutical products, pesticides, azo dyes, herbicides, and hormones are the main contaminants in water [4, 5, 6]. The textile activities are responsible for 15% of the industrial consumption of water [7]. It is estimated that approximately 15–20% of the chemical species, including dyes, are disposed of as effluent after processing [8].
Among the more than 10,000 types of dyes available [9], the azo compounds stand out and are characterized by the presence of one or more chromophore groups (─N═N─) in their chemical structure [10, 11, 12]. The intensity of absorption and also the shades of color vary according to the other electrons
Methyl orange dye (C14H14N3NaO3S−Na+) is a compound generally used as acid-base indicator [14]. Sha et al. [14] shows that a decrease in pH causes a shift in the absorption band of MO, and a change in its coloration occur, being orange in basic pH and red in acidic condition [15]. The MO structure is characterized by the azo group among the aromatic rings [15, 16] and is shown schematically in Figure 1.
Several researches have been done to develop new technologies to remove dyes and others pollutants from wastewater effluent. Hassan et al. [17] studied the use of heterogeneous photocatalysis for the treatment of landfill leachate, comparing the efficiency of this technique to other methods, besides the parameters that influence the process results. The study revealed to be possible to remove pollutants found in landfill leachate using TiO2 as catalyst. The best photocatalytic results were obtained for anatase and anatase-rutile mixture. Jorfi et al. [18] developed TiO2 catalyst supported on magnetic activated carbon for the oxidative degradation of benzotriazole (BTA) by UV-Fenton process. According to the authors, the catalyst showed good reusability, since after five cycles of reuse, the efficiency in the degradation of BTA dropped from 92.2 to 71.6%. Konstantinou and Albanis [19] and Sleiman et al. [20] evaluated the photocatalytic degradation of azo dyes by photocatalytic oxidation using TiO2 under UV-vis irradiation. Both works state the efficiency of the heterogeneous photocatalysis method in water treatment. Akrout and Bousselmi [21] carried out the electrochemical degradation of synthetic wastewater containing biazo dye on boron-doped diamond anode (BDD) at current densities from 8 to 48 Am−2. The authors verified the influence of pH and of the applied current density on degradation. The decrease of pH and the increase of current density showed a positive effect on the oxidation. Vallejo et al. [22] presented a review about the capacity for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) remediation by means of Advanced Oxidation Processes.
Advanced Oxidation Processes (AOPs) are the most attractive methods used to degrade polluting compounds based on the use of highly oxidizing species to promote greater efficiency in the treatment process [23].
AOPs are characterized by generating free radicals, especially the hydroxyl radical (OH•), transforming the organic contaminants in simpler species, such as carbon dioxide, water, and inorganic anions [24]. Hydroxyl radicals can be generated from reactions involving ozone (O3) and hydrogen peroxide (H2O2)—oxidants with high degrading power—semiconductors such as titanium dioxide (TiO2) and ultraviolet irradiation (UV) [25, 26]. Figure 2 presents the main techniques of AOP [22].
The first studies in photocatalysis were developed by Fukushima and Honda [27], when they observed that TiO2 exposed to the sunlight could produce the photocatalytic dissociation of water, producing hydrogen. Recent researches deal with heterogeneous photocatalysis for applications in water treatment [2, 6, 23, 26]. Figure 3 shows the schematic diagram of photocatalytic process, showing the photoactivation of a catalyst semiconductor and the production of oxidizing radicals. This process is based on the electronic excitation of certain semiconducting oxides (catalyst) by means of radiant energy—visible or UV light [28, 29]. The reaction is activated by absorption of a photon with energy equal or higher than the bandgap energy (Ebg) of the catalyst [5]. When an electron is promoted from the valence band (VB) to the conduction band (CB), a hole (h+) is generated in the VB (Eq. (1)). The electrons transferred to CB are responsible for reduction reactions, producing gaseous hydrogen and other oxidizing species (Eqs. (2) and (3)). The holes react with the adsorbed water molecules on the surface of the photocatalyst to generate OH• radicals (Eqs. (4) and (5)), allowing the oxidation of organic molecules and ionized species [5, 6].
The main factors that influence the photocatalytic degradation are pH, initial concentration of dyes, reaction temperature, catalyst concentration, oxidizing agents, light intensity, and irradiation time [6, 17, 20]. Acid pH is more favorable for photocatalytic applications than neutral or alkaline pH [30]. Chanathaworn et al. [31] studied the effects of irradiation intensity of black light lamp on the degradation of the Rhodamine B. According to the results, an increase in the irradiation intensity intensified the dye degradation.
Titanium dioxide (TiO2) is the most crystalline semiconductor used in photocatalytic process [26, 32]. It presents three polymorphic phases: anatase and rutile, with tetragonal structure; and brookite, orthorhombic [33, 34], being anatase the phase of greater degradative efficiency [17]. Due to the TiO2 bandgap energy being relatively wide (Eg = 3.2 eV for anatase; Eg = 3.0 eV for rutile; Eg = 3.1 eV for brookite) [6, 33, 34], the material can only be activated by UV irradiation with λ < 380 nm [35].
Absalan et al. [36] developed TiO2 nanoparticles in anatase, rutile, and brookite phases by sol-gel method using different calcination temperature and time and doped by transition metals (cadmium, chromium, nickel, manganese, iron, and cobalt). According to the authors, the proportion of anatase phase increased after doping process, besides improving the photocatalytic efficiency. According to Carp et al. [37], the doping process reduces the bandgap, making the material active in the region of the visible spectrum of light.
Among several techniques used on the synthesis of TiO2 [38, 39, 40, 41], the chemical vapor deposition (CVD) is widely employed [42]. Pierson [43] defines CVD as the deposition of a solid on a heated surface from a chemical reaction in the vapor phase. In this process, the vapor of a volatile compound reacts near or over the surface to be coated (substrate), forming a solid deposit by nucleation of the chemical element that composes the material to be deposited, from a movement governed by processes of diffusion and convection of matter [43].
The crystalline structure, grain size, and, mainly, the chemical composition and the thickness of the films are essential parameters to define its properties and applications [44]. The present research aims the structural and morphological characterization of TiO2 thin films grown at 400°C by MOCVD process and to study the influence of the thickness on the photocatalytic efficiency to degrade methyl orange dye under UV light.
2. Experimental procedure
The growth of TiO2 thin films was realized by metalorganic chemical vapor deposition (MOCVD) in a conventional horizontal reactor at 400°C under a pressure of 50 mbar. Titanium(IV) isopropoxide (
2.1. Characterization of the films
X-ray diffraction (XRD) diagrams, obtained in a
2.2. Photocatalytic tests
The photocatalytic activities of the TiO2 films were estimated by measuring the degradation of methyl orange dye (MO, 5 mg L−1) in an aqueous solution (pH = 2), under UV light irradiation (Sankyo Denki Co., Ltd., 15 W, λ = 352 nm). The changes in the MO concentration were monitored using a UV-vis spectrophotometer (
The photocatalytic reactor consists of a glass chamber containing the MO dye solution to be degraded, the TiO2 catalyst supported in borosilicate, and the source of radiation. The components of the photoreactor were arranged in a box to prevent loss of photons and to protect users against the emitted UV radiation. The distance between the photocatalyst and the UV lamps was set at 25 cm.
3. Results and discussion
The cross section of the samples was observed and the thickness of the TiO2 films grown on borosilicate was measured. Figure 6a shows the FE-SEM image of the 280 nm thick film, revealing the formation of a dense film. The AFM image (Figure 7a) shows that the film presents homogeneous morphology, composed of rounded grains of 124 nm mean size and of 19 nm RMS roughness, which can be considered favorable for photocatalytic applications [37], since it facilitates the contact of the adsorbed substances with the film, increasing its photocatalytic efficiency [46].
The RMS (
where
The morphology of the surface of the TiO2 film grown with thickness of 468 nm (Figure 8a) presents a mean grain size of 214 nm and roughness values of the order of 16 nm (Table 1). It can be observed as a dense film with columnar structure (Figure 6b). Results presented by Krumdieck et al. [48] showed that the increase of the thickness of the films caused a decreased of the roughness, similar trend with the values exhibited in the present work. The results clearly show that the increase of the growth time (Table 1) caused an increase in the film thickness, as evidenced by Antunes et al. [49].
Temperature of deposition [°C] | Growth time [min] | Film thickness [nm] | Mean grain size [nm] | RMS roughness [nm] |
---|---|---|---|---|
400 | 30 | 280 | 124 | 19 |
400 | 40 | 468 | 214 | 16 |
Figure 9 shows the XRD patterns of TiO2 films grown at 400°C with different thickness. The characteristic peaks correspond to the crystalline anatase phase (JCPDS 21–1272).
Figure 10 shows the XPS spectra of the 280 nm TiO2 thin film. The surface of the films contains high quantities of Ti and O elements and C (Figure 10a). According to Liu et al. [50] and Babelon et al. [51], the presence of C1s peak was ascribed to the residual carbon from the metalorganic precursor and to surface pollution provoked for the sample exposition to air before the XPS experiments. Ti2p spectrum (Figure 10b) appeared at 459.5 and 465.2 eV attributed, respectively, to Ti2p3/2 and Ti2p1/2 peaks of O─Ti─O in TiO2 [50, 52]. Bharti et al. [53] and Lin et al. [54] suggested that these peaks are consistent with Ti4+ in TiO2 lattice. The O1s spectrum (Figure 10c) reveals two peaks at 530.7 and 532.4 eV. The first one can be attributed to the oxygen present in the TiO2 lattice, and the other one represents the surface oxygen [52].
Figure 11 exhibits the C/C0 graphs as a function of the time of exposure to UV radiation, where
A large surface area is necessary for the light irradiation and the photocatalyst contacting with pollutant compound and, consequently, the photocatalysis efficiency of the TiO2 films is intensified [55, 56]. The increase in thickness is also favorable for the photocatalytic performance, since thinner films have a higher electron recombination rate than thicker films [57].
4. Conclusions
TiO2 films grown by MOCVD process were demonstrated to be effective for methyl orange dye degradation under UV irradiation. The films presented the formation of anatase phase, and surface morphology composed of rounded grains. The methyl orange dye does not degrade under UV radiation without the presence of the TiO2 photocatalyst. The best photocatalytic result occurred for the film with thickness of 468 nm, which exhibited 69% of dye degradation in 300 minutes. The results suggest that the morphology and structural characteristics influence the photocatalytic activity of the TiO2 films.
Conflict of interest
The authors declare that there is no conflict of interest regarding the publication of this chapter.
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