Some bottom type mines and their characteristics.
\\n\\n
Released this past November, the list is based on data collected from the Web of Science and highlights some of the world’s most influential scientific minds by naming the researchers whose publications over the previous decade have included a high number of Highly Cited Papers placing them among the top 1% most-cited.
\\n\\nWe wish to congratulate all of the researchers named and especially our authors on this amazing accomplishment! We are happy and proud to share in their success!
Note: Edited in March 2021
\\n"}]',published:!0,mainMedia:{caption:"Highly Cited",originalUrl:"/media/original/117"}},components:[{type:"htmlEditorComponent",content:'IntechOpen is proud to announce that 191 of our authors have made the Clarivate™ Highly Cited Researchers List for 2020, ranking them among the top 1% most-cited.
\n\nThroughout the years, the list has named a total of 261 IntechOpen authors as Highly Cited. Of those researchers, 69 have been featured on the list multiple times.
\n\n\n\nReleased this past November, the list is based on data collected from the Web of Science and highlights some of the world’s most influential scientific minds by naming the researchers whose publications over the previous decade have included a high number of Highly Cited Papers placing them among the top 1% most-cited.
\n\nWe wish to congratulate all of the researchers named and especially our authors on this amazing accomplishment! We are happy and proud to share in their success!
Note: Edited in March 2021
\n'}],latestNews:[{slug:"intechopen-supports-asapbio-s-new-initiative-publish-your-reviews-20220729",title:"IntechOpen Supports ASAPbio’s New Initiative Publish Your Reviews"},{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"}]},book:{item:{type:"book",id:"2996",leadTitle:null,fullTitle:"Computational Intelligence in Electromyography Analysis - A Perspective on Current Applications and Future Challenges",title:"Computational Intelligence in Electromyography Analysis",subtitle:"A Perspective on Current Applications and Future Challenges",reviewType:"peer-reviewed",abstract:"Electromyography (EMG) is a technique for evaluating and recording the electrical activity produced by skeletal muscles. EMG may be used clinically for the diagnosis of neuromuscular problems and for assessing biomechanical and motor control deficits and other functional disorders. Furthermore, it can be used as a control signal for interfacing with orthotic and/or prosthetic devices or other rehabilitation assists. \nThis book presents an updated overview of signal processing applications and recent developments in EMG from a number of diverse aspects and various applications in clinical and experimental research. It will provide readers with a detailed introduction to EMG signal processing techniques and applications, while presenting several new results and explanation of existing algorithms. This book is organized into 18 chapters, covering the current theoretical and practical approaches of EMG research.",isbn:null,printIsbn:"978-953-51-0805-4",pdfIsbn:"978-953-51-7033-4",doi:"10.5772/3315",price:139,priceEur:155,priceUsd:179,slug:"computational-intelligence-in-electromyography-analysis-a-perspective-on-current-applications-and-future-challenges",numberOfPages:462,isOpenForSubmission:!1,isInWos:null,isInBkci:!1,hash:"eec43ca5106bfbac5321a0945acf723d",bookSignature:"Ganesh R. 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Naik received his B.E. degree in electronics and communication engineering from the University of Mysore, Mysore, India, in 1997, M.E. degree in communication and information engineering from the Griffith University, Brisbane, Australia, in 2002, and PhD degree in the area of digital signal processing from RMIT University, Melbourne, Australia, in 2009.\nHe is currently an academician and researcher at RMIT University. As an early career researcher, he has authored more than 60 papers in peer reviewed journals, conferences and book chapters over the last five years. His research interests include pattern recognition, blind source separation techniques, audio signal processing, biosignal processing, and human–computer interface. Dr. Naik was the Chair for the IEEE Computer Society CIT08 Conference, Sydney and a member of the organising committee for IEEE BRC2011 conference, Vitoria, Brazil. He was a recipient of the Baden–Württemberg Scholarship from the University of Berufsakademie, Stuttgart, Germany (2006–2007). Recently Dr. Naik was awarded with ISSI overseas fellowship from skilled Institute Victoria, Australia.",institutionString:null,position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"2",totalChapterViews:"0",totalEditedBooks:"5",institution:{name:"RMIT University",institutionURL:null,country:{name:"Australia"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"1004",title:"Clinical Diagnosis",slug:"clinical-diagnosis"}],chapters:[{id:"40116",title:"EMG Modeling",doi:"10.5772/50304",slug:"emg-modeling",totalDownloads:3257,totalCrossrefCites:15,totalDimensionsCites:18,hasAltmetrics:0,abstract:null,signatures:"Javier Rodriguez-Falces, Javier Navallas and Armando Malanda",downloadPdfUrl:"/chapter/pdf-download/40116",previewPdfUrl:"/chapter/pdf-preview/40116",authors:[{id:"65172",title:"Dr.",name:"Javier",surname:"Navallas",slug:"javier-navallas",fullName:"Javier Navallas"},{id:"127894",title:"Dr.",name:"Armando",surname:"Malanda Trigueros",slug:"armando-malanda-trigueros",fullName:"Armando Malanda Trigueros"},{id:"151104",title:"Dr.",name:"Javier",surname:"Rodriguez-Falces",slug:"javier-rodriguez-falces",fullName:"Javier Rodriguez-Falces"}],corrections:null},{id:"40115",title:"Modelling of Transcranial Magnetic Stimulation in One-Year Follow-Up Study of Patients with Minor Ischaemic Stroke",doi:"10.5772/50136",slug:"modelling-of-transcranial-magnetic-stimulation-in-one-year-follow-up-study-of-patients-with-minor-is",totalDownloads:2555,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:null,signatures:"Penka A. 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Generally speaking, land/sea mines are intended to prevent the use of or passage through an area in land or sea. Considering that maritime areas provide a vital dimension of the world’s economy (90% of global trade and about half of the world’s oil are transported by sea), sea mines are a complex hazard of international concern.
Defensively, military forces deploy sea mines to discourage undesired entrance into territorial waters. Offensively, sea mines are deployed to hobble a target’s naval assets or channel an enemy through a designed route. Mine warfare is an old military technique and has been applied in many conflicts since the nineteenth century. Like land mines, sea mines can still be active after many years of being deployed. More than 550,000 sea mines were laid during World War II (WW-II); some of them were removed after the conflict but part of them were missed [1, 2]. The legacy of recent conflicts in the north of Africa means that even today, sea mines can be laid in European waters (and in any critical maritime space where vital resources are transported) and therefore remain a very real threat to shipping, sailors and any maritime exploitation of ocean and coastal resources.
To address this problem, governments around the world have traditionally relied on a standing mine countermeasures (MCM) force, which involves both passive and active tactics. Passive countermeasures entail changing the specific target vessel characteristics or signatures, since these trigger sea mines (see next section for more information about sea mines). These might include building vessels with fibreglass or wood instead of steel or even attempting to alter a steel vessel’s magnetic field through degaussing. Alternatively, active countermeasures aim to discover mines using specially designed ships or platforms for the purpose of either avoiding or destroying them. Mine sweeping and mine hunting are two of these measures. Mine sweeping uses either a contact sweep, a wire dragged through the water by one or two ships to cut the mooring wire of floating mines, or a distance sweep that mimics a ship to detonate the mines. Mine hunting is very different from sweeping. It requires searching for all the mines in an area before disposing them. The latter is generally decomposed in four stages:
Detection: finding targets or contacts from signals of different sensors (e.g. acoustic, magnetic).
Classification: determining if the contact is mine-like or friendly object.
Identification: using additional information (e.g. from a diver or autonomous underwater vehicle (AUV)-based camera) to validate the classification result.
Disposal: neutralizing the mine.
As mines have become smarter, MCM have become more complex and sophisticated. Modern navies employ an array of different mine warfare countermeasures. The trend in mine hunting operations goes towards keeping the human operators out of the minefield. In order to achieve this, modern MCM forces use (semi)autonomous platforms (e.g., AUV, remotely operating vehicles [ROV], unmanned surface/underwater vehicles [USV/UUV]), equipped with high-resolution (HR) sensors (e.g. sonars, magnetometers, optical cameras) and employing computer-aided detection (CAD) and classification (CAC) algorithms as well as automated target recognition (ATR) processes.
Not only high-tech hardware and software are developed for mine hunting operations, but biotechnology is also applied. Just as dogs and rodents can be trained to detect land mines, maritime mammals such as dolphins are trained by the United States and Soviet navies to detect sea mines while keeping the deminer out of the minefield. Dolphins are trained to detect and mark the location of tethered mines floating off the bottom, mines on the sea floor or mines buried in sediment. They learn to use their natural echolocation bio-sonar to find a target and to report back to their handler, giving particular responses to communicate whether a target is detected. The handler then sends the dolphin to mark the location of the object by releasing a buoy. The US Navy reported that mine-clearance dolphins were deployed in the Persian Gulf during the Iraq war in 2003. The Navy said these dolphins were effective in helping to detect more than 100 sea mines [3].
This chapter reviews research carried out at the Royal Military Academy addressing the applicability of acoustic, magnetic and optical sensors used in mine hunting operations and introduce some of the challenges these techniques encounter in order to detect and classify sea mines.
Sea mines typically are explosive devices designed in different forms whose dimensions can vary from around 50 cm up to almost 3 m and can contain from 50 kg to over 1000 kg of high explosives. Aside from their dimensions and explosive charges, mines can be further categorized by their method of deployment, position in the water column and method of actuation (or detonation) [2].
Sea mines can be laid in many different ways, which depend on the size of the mine itself. Certain conventional surface vessels, e.g. war vessels and patrol vessels, can have sea mines deploying capabilities. Some smaller, unusual surface vehicles (e.g. smaller fishing boat) could drop sea mines too. They can also be deployed from air using either fixed or rotary wing aircraft or deployed underwater using the torpedo tubes of submarines.
Depending on the type, sea mines can be positioned at different altitudes in the water column. The most common type of sea mines deployed during both World War I (WW-I) and WW-II was drifting mines. They float freely on the water surface following the direction of water currents or winds. The latter have been banned by international law for over 70 years; however, some countries still use them in their defensive/offensive strategies in conflicts since 1980 [2]. Highly versatile drifting mines can be deployed by small boats, warships or aircraft. Drifting sea mines can be activated remotely or by contact.
As their name suggests, bottom sea mines stay on the seafloor utilizing negative buoyancy or are partially/totally buried at the bottom of the sea. Most of these sea mines are influence mines; a few ones can also be activated remotely or by contact. Since they rest on the bottom of the sea, bigger explosive charges (around 1000 kg) can easily fit inside them. To be able to sense vessels on the surface and reach the ship’s hull floating near the surface with their explosive energy, bottom sea mines tend to be used in relatively shallow water (less than 50 m). Bottom mines are generally laid by aircraft or submarine.
In contrast with bottom or drifting sea mines, moored sea mines must maintain buoyancy to float at certain water depths. In order to achieve this, part of their structure must be designated to maintaining their buoyancy and therefore the weight and size are key factors in their design. Moored sea mines are filled with smaller amounts of explosives than bottom sea mines. Additionally, they can be tethered to allow for various altitudes in the water column. The latter are by far the most sophisticated and expensive types of sea mines. Deployed most commonly by conventional surface ships, moored mines can be contact, influence or remote-controlled mines.
The most easy-to-use mines, contact sea mines, actuate when a vessel physically comes into contact with (or very close to) the mine in the water. Contact sea mines have been fitted with many ingenious anti-sweep devices including explosive charges to cut sweeping wires and ratchet devices that enable a sweep wire to pass through the mooring cable without cutting it [2]. Contact mines are available at costs between US$2000 and US$15,000 [1].
Influence sea mines are becoming more sophisticated, complex and technically advanced. These categories of sea mines do not need physical pressure to detonate. Instead, these mines hold different kinds of sensors that can respond to different vessel signatures. The latter sense magnetic, acoustic, pressure or underwater electrical potential signals. Originally, magnetic sea mines used the vertical component of the vessel’s magnetic field to activate themselves when a given field density was reached. During the 1930s, magnetic mines worked off the horizontal component of the ship’s magnetic field [2]. This apparently insignificant change made it possible to design a mine fuse which responded to the rate of change of field strength rather than absolute field strength. This made defence against magnetic sea mines by degaussing and magnetic sweeping procedures far less effective. Magnetic mines are available at costs between US$10,000 and US$25,000 [1].
Due to the vessel’s machinery, the design of the hull and the propellers (and many other factors), all ships and submarines have a specific acoustic signature. This principle is used in the fabrication of acoustic sea mines. Delay clocks can be included to leave the sea mine inert (and thus unsweepable) for some days after it has been deployed, while the incorporation of counters means that the sea mine will only be detonated after a certain number of impulses have been received. This means a sweeper would have to make a large number of passes over a suspected field before it could be sure that all the mines within the field had been exploded. The cost of acoustic sea mines differs dramatically depending on the capability of its system (bandwidth). They are available at costs between US$50,000 and US$150,000 [1].
Pressure mines are invariably bottom mines since they measure the absolute drop in pressure associated with the difference between the known pressure due to water depth and the depth of water under the hull of a passing ship. This differential is directly related to the depth at which the mine is situated. Pressure mines are inevitably unsweepable, are shallow-water inshore weapons and are specifically intended to destroy amphibious craft. They are located in such shallow water (even surf zone) that even minute pressure signatures would detonate them. Pressure mines have been adopted for an entire generation of small anti-invasion mines [2]. They are available at costs between US$25,000 and US$50,000 [1].
In this chapter, focus will be made on bottom and drifting mines. Table 1 lists some of them with their characteristics and dimensions.
Mine name | Shape | Weight (in air, kg) | Dimensions (mm) | |
---|---|---|---|---|
Murena | Cylindrical | 780 | Length | 2096 |
Diameter | 533 | |||
Manta | Truncated cone | 220 | Height | 440 |
Diameter | 980 (max) | |||
Rockan | Wedge | 190 | Length | 1020 |
Height: | 385 | |||
Width | 80 |
Some bottom type mines and their characteristics.
SONAR is an acronym for SOund Navigation And Ranging, and its basic principle is to locate objects by using acoustic (or sound) waves. Sound is a series of pressure perturbations that travel as a wave and exhibit phenomena like reflection, diffraction and interference. These acoustic vibrations can be characterized by their sound velocity
The propagation velocity of an acoustic wave is determined by the local propagation medium characteristics: the density
In sea water,
The frequency usable for a particular underwater sonar application is constrained by the sound wave attenuation, which increases very rapidly with frequency and limits the reachable distance (or range). In mine hunting, the frequencies of underwater sonars vary between 0.1 and 1 MHz (and their range between 1 and 0.1 km, respectively).
Underwater sonar is composed of hydrophones, which can transmit and receive acoustic waves or only receive echoes from the underwater. The first case is referred as active sonar and the latter as passive sonar. For the purpose of sea mine detection, active sonar is applied. Figure 1 shows a scheme of a generic active sonar system. When an hydrophone transmits an acoustic wave, this propagates underwater and is reflected by any interface with a different characteristic impedance
Material | Characteristic acoustic impedance (in Rayl) |
---|---|
Air | 415 |
Sea water | 1.54 × 106 |
Clay | 5.3 × 106 |
Sand | 5.5 × 106 |
Sandstone | 7.7 × 106 |
Granite | 16 × 106 |
Steel | 47 × 106 |
Some materials and their characteristic acoustic impedance.
Schematic representation of a hull-mounted active sonar system.
The underwater propagation medium is limited by two well-defined interfaces: the sea surface and the sea bottom. Considering the reflection coefficient
and replacing the values by the impedance of sea water
When acoustics waves propagate, the most evident effect is their loss of intensity because of the
There are other aspects associated with the propagation of acoustic waves in sea water that are not introduced here, since it is not the scope of this chapter. For more information, the interested reader should refer to Ref. [4].
Acoustic imaging is an inverse problem where the goal is to construct an image which represents the locations of discrete targets. This image results from the estimation of the reflectivity (or backscattered acoustic energy) for all ranges and in all directions. In sonar, it is common to have a horizontal array of receiver hydrophones. The azimuth (or along-track) resolution is given by the array length measured in wavelengths. The range resolution is given by the bandwidth of the system. The along-track resolution can be increased either by increasing the array length or by increasing the frequency. As very large arrays are impractical, the along-track resolution is usually improved by increasing the signal frequency. However, high-frequency signals suffer from attenuation and will therefore limit the application to shorter ranges. This reduces the area coverage rate and makes the sonar impractical for surveying large areas. A solution (adapted from radar) is to use synthetic aperture processing, where successive sound pulses (or pings) are coherently combined to synthesize a longer array. An excellent introduction to synthetic aperture sonar (SAS) can be found in Ref. [5].
Figure 2 shows the acoustic image (in grey scale) of an area of the Belgian continental shelf surveyed using the ROV SHADOWS. SHADOWS is a SAS which works in the range of 100–300 kHz, depending on the mode of operation, and it can achieve a resolution of 5 × 5 cm2. It has two horizontal arrays (lateral sonars) of 36 receiver hydrophones each, one located at the port side and the other at the starboard (see Figure 3). The length of the arrays is 192.5 cm and that of the SHADOWS platform is 220.6 cm. In order to gather data, SHADOWS is towed at the back of a vessel (in this case, at the back of the oceanographic research vessel BELGICA, or RV BELGICA [6]). Data in Figure 2 were collected by moving the platform following several lines (or tracks) from south-west to north-east and back at an average ground speed of 2 m/s and at an altitude of about 18 m (water column height is 28–30 m). The total covered area is about 2600 × 700 m2. In the acoustic image, two main zones with different sea bottom characteristics can be observed. In one part of the image, a rocky and rippled area appears, and it is well differentiated from a second, flatter area. The reflections of some bottom trawling lines across track are also visible. These man-made structures are created by a fishing method which involves a towed bottom fish net or trawl.
Image of a surveyed area at the Belgian Continental Shelf using the ROV SHADOWS SAS.
The ROV SHADOWS SAS and its deployment from the RV BELGICA.
Generally speaking, CAD/CAC and ATR schemas are based on the calculation and extraction of different types of image characteristics, which can mainly be grouped in three categories [7]:
Texture-based features, e.g. patterns and local variations of the image intensity.
Spectral (or radiometric) features, e.g. colour, energy.
Shape-based (or geometrical) features, e.g. length, area.
CAD/CAC and ATR systems developed to classify objects from real aperture or lateral sonar images are generally built on a combination of different features extracted from the spectral highlight response produced by the target and the geometrical characteristics of its shadow on the seafloor. In SAS, since the resolution is improved compared to a real aperture or lateral sonar, more complete geometrical information from the object shadow and highlight (or echo) is available, which could be exploited to improve classification results. Therefore, the approach presented here is based on geometrical features obtained from the increased image accuracy available in both object echo and shadow acoustic responses.
Before extracting geometrical features, two pre-processing steps are applied: (i) a speckle reduction filter is applied to improve the quality of the image and (ii) a segmentation algorithm is applied to detect echo and shadow pixels from the target. Multiplicative speckle noise is always present in SAS images, which is due to the coherent nature of scattering phenomena from rough interfaces. In Ref. [8], some speckle reduction techniques from synthetic aperture radar images are proposed and developed or adapted to be applied to SAS HR images. Those filters include anisotropic diffusion filter, adaptive neighbourhood and mean adaptive and are compared with other linear and non-linear filters, such as the Lee filter, Kuan filter and a wavelet-based methodology. A performance analysis is carried out considering image quality and better speckle suppression index. Results of the study concluded that the anisotropic diffusion filter was the best choice for this application. Some results after applying anisotropic diffusion and comparison with other filters are presented in Figure 4. Data were collected using the MUSCLE AUV from Centre of Maritime Research and Experimentation, NATO Science and Technology Organization (CMRE-STO) during the COLOSSUS measurement campaign along the Elba Island (Italy). MUSCLE AUV is equipped with a 300-kHz interferometric SAS, and it can achieve a resolution of 2.5 cm along track and 1.5 cm across track.
Results after applying different spackle reduction filters to a snapshot of MUSCLE data.
To detect the echo and shadow pixels from the despeckled image, some segmentation techniques are presented and evaluated in Ref. [8]. A rudimentary methodology for segmenting the image is to set an intensity such that all pixels below a level
where
This membership function
where
The next processing level uses morphological filtering. The latter is described by two functions, opening and closing, which are based on two tasks, erosion and dilatation. Imaging a structure
For classification purposes, synthetic data are needed in order to train the algorithms. SIGMAS (Synthetic Image Generator for Modelling Active Sonar) simulator is used to generate the training data. SIGMAS has been developed by CMRE-STO and allows the generation of SAS test sets for arbitrary target models, including mine-like objects (MLO) and friendly objects (FO). SIGMAS also includes bottom topography effects such as ripples, sea bottom slope variations and partial burial of targets [7]. Results for the segmentation approach applied to both synthetic and real data can be seen in Figures 5 and 6, respectively.
Segmentation of echo and shadow pixels performed on synthetic data for a cylindrical (left) and truncated cone (right) MLOs. Two angles at the same range are shown for the cylindrical MLO and two ranges are shown for the truncated cone.
Segmentation of echo and shadow pixels performed on real data for a truncated cone (left) and a cylindrical (right) MLOs at different ranges.
Three regions are considered for the feature extraction. Two of them (shadow and echo) have been already calculated following the
Since there is a large set of features for this application, an appropriate methodology to classify the detected target signatures could be the Markov Chain Monte Carlo approach (MCMC). An MCMC simulation is applied to list the parameters from the most indicative ones down to the less revealing ones, according to their discriminative power across distinct classes of data. This is realized by establishing as an importance criterion, the accuracy, obtained using the specific parameters as inputs in the classifier model.
Considering a training set
Sample a large number,
The
with
The MCMC simulation consists in reiterate processing levels 1 and 2 explained before until convergence.
We index the features by assessing an amount of variation Var[
where
In order to measure the dissimilarity of objects, a suitable distance function can be used. Although the common Euclidean distance function is well explained for a set of parameters of subjective dimension, it reveals major limitations with respect to similarity measurement. This is especially the case if the individual parameters of the feature vector are treated as independent from of each other. In some situations (mostly for spatial data), the components of the feature vector may be correlated. Considering this correlation, methodologies that apply a weighted Euclidean distance have been analyzed. It is relevant to mention that the ordinary Euclidean distance may be studied as being a special case of the weighted Euclidean distance, where the similarity matrix is the identity matrix. There is a large number of choices for these similarity matrices containing correlation coefficients between attributes.
An alternative technique based on the MCMC methodology introduced before is proposed in this section. Listing the parameters from the most indicative ones down to the less revealing ones in each MCMC simulation from until convergence results in a discriminative power weight that can be designated to each characteristic. Assuming that the MCMC simulation is reiterated
and can be used as a distance measurement between the observed probability vectors
Figure 7 shows an example of the classification approach proposed here. We select a certain synthetic image (object) as a query one, and we retrieved the most similar objects from the snapshots selected out of the real data set. The similarity was defined with respect to the weighted Euclidean distance of the initial normalized feature vectors. In this figure, a query cylindrical object is shown in the upper left corner followed by the corresponding retrieved ones from a COLOSSUS data subset. Note that the recovering system (metallic bars attached to the body of the dummy mine) can be easily recognized in the sonar images (four last cropped images in Figure 7). This means that the reflected signature (echo) is distinguished as well, having an influence on the classification results. Despite the fact that such objects are designated as cylinder-like, their similarity values are rather lower than the values calculated for the other targets. There is still some analysis to do regarding this effect.
A query object (up, left) and the corresponding retrieved ones using the MCMC-based proposed approach.
It is important to note that the approach presented here does not transform the initial feature domain into a complicated set of characteristics, and therefore, it is very useful for the mine-hunting application, where both classification accuracy and indicative feature dependencies are important.
Bottom mines can be challenging to detect since they can be buried in the sediment or in the sand. Since sea mines usually contain magnetic materials, a possible technique to detect them is to use a magnetic detector. Several kinds of magnetic detectors can be used to detect sea mines. Total field magnetometers measure the magnetic field magnitude; they can be used to detect dipole targets [10]. Three axis magnetometers measure the three magnetic field vector components and can be applied to mine hunting [11]. The same is true for tensor gradiometers which measure the gradient of the magnetic field [12]. We here consider a total-field gradiometer. It is composed of three total field magnetometers which measure the magnitude of the magnetic field with a sensitivity of 0.01 nT. The gradiometer is towed behind a ship, and its measurements are used to calculate an estimation of the gradient of the magnetic field magnitude.
A mine can be modelled as a dipolar magnetic source. In this section, a new technique is presented to localize and characterize bottom mines based on a dipolar model. Experimental results achieved in the bay of Gdansk in Poland are also presented.
A sketch of the gradiometer is presented in Figure 8. The considered gradiometer is composed of three magnetometers: starboard, port and down, separated by distances
The considered gradiometer is composed of three magnetometers.
This is only an approximation since the components of the gradient are calculated by finite differences. This vector can be expressed in an absolute reference frame by multiplying by a rotation matrix:
The aim of the inversion method is to estimate the magnetic moment
Traditionally, magnetic targets are localized by looking at the maxima of the magnitude of the gradient [10]. This is achieved by producing a map of this quantity. This method is not optimal because a single target can exhibit several maxima at low latitude. Some interpolation artefacts are also often present, leading to ambiguous interpretation. Moreover, it does not provide precise information about the burial depth or the magnetic moment, which can be used to reduce the false alarm rate [14]. We propose an alternative method for the localization of the target. Instead of producing a map, we directly use the raw data collected by the gradiometer and inverse the dipole model of the field. This allows for a real-time detection. Our method also provides the magnetic moment of the target and its depth. It works regardless of the latitude.
The gradiometer measures a finite difference approximation of the gradient. If the distance between the gradiometer and the target is large compared to the size of the gradiometer, this approximation will be satisfying. This allows one to estimate the position of the target by solving a linear system of equations. This is called the Euler method.
We assume that the magnetic field measured by the magnetometers has two contributions: the earth’s magnetic field
where
and
The anomaly field is defined as
A function
A homogeneous function of degree
One can easily see that if
This forms a first linear system of equations that allows to estimate the position of the source. This system can be solved by the linear least mean square method which does not require any initial parameters.
Once the position is known, one can estimate the magnetic moment by solving another linear system. Indeed, Eqs. (12) and (13) show that the anomaly is a linear function of the magnetic moment, and the magnetic gradients are also linear in
In practice, the hypothesis that the gradiometer measures the true gradient can be a bad approximation at small distance from the target. Estimating the parameters with the linear method leads to inaccurate results, even without noise. Therefore, a more general method is developed and presented here.
Eqs. (11) and (12) can be injected in Eq. (10) to give a system of equations that are nonlinear in terms of
This nonlinear system of equations can be solved by the Levenberg-Marquardt algorithm that finds the solution of the least mean square problem. This method is iterative and requires good initial parameters to avoid problems of local minima. We take the output of a linear method as initial values.
Figure 9 shows a comparison of the different localization techniques in the absence of noise on the basis of simulations. It allows one to compare the localization accuracy of the map method, the Euler method and the nonlinear method. The nonlinear method provides the best results.
Comparison of the different localization methods. The map represents of the simulated magnitude of the gradient due to a dipole target. The map is produced on the basis of synthetic data taken on five tracks separated by a distance of 10 m. The circle is the true position of the dipole. The star is the position found with the linear method and the cross is the position found with the nonlinear method. The location is best estimated with the nonlinear method.
The effect of the noise on the precision of the estimated parameters is discussed in Ref. [15].
Some experiments were carried out in the bay of Gdansk, Poland, in September 2015. Two dummy bombs (
The gradiometer was attached to a platform with remotely controlled depth/altitude. The system was towed behind a boat. This picture was taken by TNO.
Signal collected by the gradiometer at the vicinity of the target T4.
Targets positions (lighter dots) and position estimated on the basis of the gradiometer measurements (darker dots) together with the platform trajectory.
The original inversion method developed to retrieve the position and the magnetic moment of a dipole target from magnetic gradiometer measurements works regardless of the latitude, and it can be performed in real time. The knowledge of the horizontal position is important for the localization of the target and the knowledge of the burial depth and the magnetic moment can be used to reduce the false alarm rate. The method is tested on the basis of real measurements and shows promising results. Further refinements need to be done and an analysis of the noise should allow for the computation of the target presence probability distribution and for data fusion with other sensors.
The threat of untethered drifting sea mines became apparent during the Gulf War of 1990–1991 between Iraq and the international coalition lead by the US. International regulations impose that floating sea mines have to be moored in place, and supplied with a self-disarming mechanism in case anchoring fails. Most nations, even those against international regulations, are inclined to follow these laws, since a buoyant mine carried by random currents is a very inefficient weapon, and could promptly leave the battle area.
Nevertheless, when the hostilities take place in more limited areas with several crafts navigating through, the damage probability rises significantly and floating sea mines can be transformed into a very effective anti-ship weapon. An example of such a region is the Persian Gulf, where a large number of sea mines drifting freely were found by the coalition forces during the Gulf War.
The efficacy of this military tactic was evident when US Navy’s amphibious assault carrier Tripoli was brought to a standstill by a sea mine. After this incident, floating sea mines were classified as a principal menace to US Navy aircraft carriers. As a result, warfare was considerably decelerated and risk-reluctant shipping companies heavily diminished their number of times they transit in the conflict area.
Since then, floating sea mines have continued to show up, as recently as during the NATO intervention in Libya in 2011. A similar concern has arisen from the recent terrorist threat: floating IEDs released within a commercial harbour could cause tremendous economic damage, though no such cases have emerged until now.
Conventional subsurface mines are mainly detected through sonar techniques. This proved inadequate for spotting floating mines; on the one hand, due to the practical matter of downward sensor inclination and on the other hand, because of the cluttered background caused by the active sea surface. The same applies above water: the target is small and partially submerged, and the sea surface acts as a dynamic background hiding the target. In practice, the only reliable detection method so far proved to be a human visual detection and identification. Therefore, an automated detection system would provide a huge benefit in military campaigns, in clean-up operations and even for a number of civilian applications such as collision avoidance, salvaging and search and rescue.
The conditions required here are for a ship-based system to be able to operate 24 hours a day and in different weather conditions. Although the diameter of the expected targets is rather limited, it has been demonstrated that it is possible for a human operator to visually detect the target. Therefore, an infrared video imager is selected for this application.
Automated detection of the floating mine is hard, because waves on the sea surface are similar in size, shape and thermal emissivity as a partially submerged floating mine in thermal equilibrium with the water. This makes even advanced background subtraction methods such as EGMM1 and ViBE2 [13], which are capable of dealing with significant amounts of noise in the image, unsuitable for detecting objects on the dynamic scene presented by the sea surface [14].
A better feature to discriminate between object and background is the motion behaviour of the dynamic elements in the scene. Waves propagate in a linear fashion across the scene along the wind direction, whereas the drifting mine shows a vertical oscillation and a slower drift with the subsurface current (not necessarily along the wind’s vector). Both may change shape and appear/disappear, complicating matters.
Different target-based tracking techniques, e.g. mean-shift tracking [15] and particle filters [16], could be applied to create a background motion model. The latter could be useful when classifying object tracks as foreground or background. Essentially, the main disadvantages of these approaches are dealing with the large quantity and high variability of the dynamic background targets, and with the restrained target information delivered by infrared image arrays [17]. Optical flow [18] and block-matching [19] techniques have been applied with promising results. Besides, real-time performance is needed in order to make this application useful, and therefore, algorithms operating at the pixel level are preferred here.
The method we describe here is the behaviour subtraction method [14] first described in Ref. [20]. This is a pixel-based method in which behaviour signatures over a time window are evaluated and compared to a learned background model. It is fairly simple, computationally quick and easily extended to use multiple features. We will continue to describe this method in the following sections.
The behaviour subtraction method has at its core the idea that one should look at events in a video sequence, not at objects in individual frames. Then, the features of these events can be extracted, analysed, used to construct a background model and to detect outliers to that background model.
For this, activity in the scene needs to be detected first. The background subtraction methods mentioned earlier provide us with the necessary tools for this: they detect change in the image on a per-pixel level. Now, while state-of-the-art background subtractions such as EGMM or ViBE try to minimize unnecessary detections, we actually prefer having lots of events. This, and computational simplicity, is why typically a very simple running mean background subtraction is used.
Background subtraction converts the video stream into a stream of binary activity images, where pixels contain the value 1 if change was detected (and hence an event is occurring) or 0 if not. When we look at a set time-window’s worth of these, each pixel will be characterized by a behaviour signature, a sequence of 0’s and 1’s describing the activity in this scene. From this, a number of simple activity features can be extracted [21, 22]:
The total activity in the time window, summing all of the activity bits in it and giving a general measure of the event’s ‘business’ in that pixel.
The number of transitions between activity and nonactivity, giving us some form of frequency information.
These two measures are ideally suited for the drifting mine problem, as both generic movement behaviour and frequency are deemed characteristic features distinguishing between the mine and the surface waves.
The next step in behaviour subtraction is the construction of a background model and a method for detecting outlier behaviour. A probabilistic approach is possible [23], but a more pragmatic and computationally simpler method is possible. For this, behaviour features are calculated for a set of training data. If we just look at one behaviour feature, say the total activity in a time window of set length, for each pixel, we can find the maximum value of the said feature. The resulting image will be called the behaviour image representing the background model.
Outlier detection then simply becomes calculating the online behaviour image at time
From left to right: IR image, activity image, behaviour subtraction.
In order to validate the performance of the algorithm on actual measurements, we used the Elbit MicroCompass MWIR camera system mounted on the P901 Castor patrol vessel of the Belgian Navy (see Figures 14–16). Since policing belongs to the tasks of the ship, recording capability is provided, allowing us to obtain video footage from the infrared camera.
P901 Castor patrol vessel.
MicroCompass sensor.
Operator station for the MicroCompass camera on P901 Castor.
Measurements with this system were done in the harbour where the Castor was at anchor. A small practice mine was released in the dock at a distance of approximately 250 m, and the camera was zoomed out to cover the entire width of the mouth of the dock. This resulted in the target being observed with an object size of about 6 pixels, making detection a hard (but not impossible) task for both a human observer and our detection algorithm.
The mine was released in the middle of the mouth of the dock by a RHIB and let free to be carried by the current. Sea state was approximately 1–2, so unfortunately the amount of wave activity was limited and not representative of tests at sea. Still, the tests provide us with a best-case scenario using an MWIR sensor against which future tests may be compared.
Four sequences of video footage of the drifting mine were recorded during these tests, along with a number of sequences of swimmer and small boat activity. Figure 17 shows a snapshot of one of those videos. Ground truth annotation was performed on the mine sequences for performance evaluation of the detection algorithm.
Drifting mine in the Zeebrugge harbour as captured by the MicroCompass MWIR sensor on the P901 Castor.
Video files amount to 10 minutes of footage and are encoded to MPEG-4 format using the H264 codec with a resolution of 720 × 576 pixels at 25 fps. Compression settings were not accessible, and neither were temperature ranges, but no problematic compression artefacts were observed in the data.
We applied the behaviour subtraction algorithm to these video sequences varying training sets, behaviour features, time window lengths and thresholds, and compared the detection results to the annotated ground truth position of the drifting mine, in order to obtain sets of true positive ratio (TPR) and false positive ratio (FPR) values. These values are plotted and the resulting convex hull provides us with an ROC curve for each parameter set describing the algorithm’s performance. The calculated ROC curves can be seen in Figures 18–20.
Comparing activity sum performance for different time window sizes.
Comparing transition count performance for different time window sizes.
Comparing activity sum and transition count performances.
Behaviour subtraction accumulates per-pixel activity features over a sliding time window in order to build up a ‘behaviour image’ of the scene, which is compared to a prior learned behaviour model in order to detect behavioural anomalies. The two main behaviour features are the activity sum, adding all the pixels in which a background subtraction has indicated that an activity is taking place, and the transition count, in which all of the changes between active and non-active during the time window
The size or length of the time window
When we evaluate the transition count feature for the same time window sizes, we obtain very similar results. Both behaviour features perform equally well, something we also see when comparing both in the same plot for the optimal window sizes of 25 and 50 frames.
These results do not allow us to make a choice as to whether the 25- or 50-frame time windows are better suited to the problem. We assume that in higher sea state conditions, the 50-frame window will perform better, but this will have to be determined with additional data.
These results demonstrate that the detection of floating mines (and similar objects) on the sea surface using passive sensors and behaviour analysis is possible. The behaviour subtraction algorithm seems to be an ideal method for the initial detection of floating targets. Further classification procedures can build upon this, with or without human operator involvement.
To implement this as an operational collision avoidance system on a moving ship, we would recommend a scanning setup, in which a stabilized camera system (thermal or optical) scans staggered sections of a designated safety zone for periods of 5–10 seconds.
In future work, we would like to see to what extent behaviour subtraction can be improved by using different or multiple activity features. Furthermore, we would like to validate the method on data obtained at greater distances and higher sea states.
Some techniques developed at RMA in order to detect and/or classify sea mines are summarized in this chapter. These techniques include different sensors and apply different advanced signal processing approaches. Due to the complexity of the ocean environment, these techniques have their advantages and drawbacks. Each of the methodologies presented here is focused in a particular type of sea mine, and therefore, they are complementary. Further research should be focused in the integration of these techniques in a MCM system that accomplishes an end-to-end mission from search to disposal using autonomous vehicles. Processing and decision-making capabilities should be integrated on-board of the sensor’s vehicles. In order to improve mine hunting capabilities in conditions that are difficult for conventional systems, new sensing modalities should also be investigated.
The work related to the sonar is carried out at the Royal Military Academy of Belgium for the Belgian Navy Component, in the scope of research projects MRN09 and MRN17, both funded by the Belgian Ministry of Defence. Ship time on board of the RV Belgica was provided by BELSPO and RBINS–OD Nature. OD-NATURE and the RV Belgica are gratefully acknowledged for outstanding support in collecting SHADOWS data. CMRE is gratefully acknowledged for sharing MUSCLE data through the Joint Research Program MIAMS.
The work related to the gradiometer is carried out at the Royal Military Academy of Belgium for the Belgian Navy Component, in the scope of research projects MRN10 and MRN16, both funded by the Belgian Ministry of Defence. The experiments were done within the EDA UMS BURMIN project, in collaboration with TUS, ATLAS, TNO, CTM, IPHT Jena, Fraunhofer Institute and ECA.
The work related to drifting mines detection is carried out at the Royal Military Academy of Belgium for the Belgian Navy Component, in the scope of research project MRN13, funded by the Belgian Ministry of Defence. The P901 Castor patrol vessel of the Belgian Navy is gratefully acknowledged for outstanding support during the experiments.
Finally, the authors would like to thank Adm Yves Dupont for his help in improving this manuscript.
The global population growth and the resulting development of commercial and industrial activities, especially in the transportation sector, have stimulated scholars in various institutions to search for sustainable renewable energy. With the continual depletion of conventional primary energy, the need for renewable alternative energy sources becomes more and more important for energy utilization in social and industrial activities. Biodiesel has as a renewable energy has received much attention and research over the year. Biodiesel in neat form or mixed with conventional diesel can be used in compression ignition (CI) engines and stationary engines [1, 2]. The production of biodiesel can be from vegetable oils or animal fats by means of a transesterification reaction, which uses alcohols in the presence of a catalyst [3]. A catalyst is used to chemically convert triglyceride molecules into alkyl esters, generally known as biodiesel fuels [4, 5]. Methanol and ethanol are the most commonly used alcohols for transesterification due to their low cost and high activity [6]. A free fatty acid (FFA) content of higher than 0.5% in vegetable oil renders it a low-grade feedstock due to saponification under alkali catalyzed reaction. The production of conventional biodiesel comprises two stages: the first stage is acidic catalytic esterification and the second stage is the transesterification method using an alkaline or base catalyst. The production process is a time-consuming and tedious procedure because of certain mandatory stages, i.e., time taken for the water to settle at the base and the transesterification process in the presence of an alkaline catalyst in the second stage. The volume of wastewater generated during esterification is high. The drying process of the esterified mixture and further application of transesterification is also a highly taxing process. The catalytic conversion process of low-grade vegetable oil with a high percentage of FFA or high moisture content into biodiesel requires a high-temperature reaction as reported in the literature [7, 8]. The high content of oxygen in biodiesel results in deficiencies such as low oxidative stability, high viscosity, low cloud point, and high pour point in the cold region [9]. Biodiesel also shows lower stability during storage and it attacks metals like copper, zinc, tin, and lead, which can lead to corrosion of some parts of the engines. Another shortcoming of biodiesel is the low energy content and nitrogen oxide (NOX) [10] which reduces thermal and break power efficiency [11]. The deficiencies mentioned above limit the application of biodiesel in CI engines.
The focus of this study is the processing of biodiesel as a feedstock to obtain a green diesel product which can offer sufficient properties without any adverse effects on the CI engine and environment. The following vegetable oils have been discovered and have been used as a feedstock for the production of biofuel for decades, viz., rapeseed, palm, cottonseed, sunflower, peanut oil, soybean oil [12, 13] and animal fats like butter, fish oil, and tallow. These renewable energy sources from biomass sources are the major feedstock sources of biofuel production. However, vegetable oil cannot be used directly to fuel CI engines because it is not compatible due to its high viscosity. The triglycerides and fatty acids present in vegetable oil are the promising components of vegetable oil feedstocks for the production of sustainable biofuel. These feedstocks produce diesel and gasoline type of hydrocarbons via hydroprocessing that can be used in CI engines [14]. HDRD is produced via hydroprocessing of triglycerides contained in edible oil such as used cooking oils and vegetable oils (e.g. rapeseed, soybean, cottonseed, palm, corn, sunflower, coconut, peanut, camelina, carinata, and jatropha oils), fats, and micro-algal oils [15]. These vegetable oils cannot be applied directly in the modern CI engine due to their high viscosity but can be used as a fuel source after some modifications in the fuel properties [16]. Feedstock sourced from edible oil for the production of biofuel has become a problem because of the threat to food security. The need for large land space for farming, the cost, and the resulting threat of deforestation is a major challenge for edible oil, therefore, UCO as a feedstock for HDRD application has recently been adopted. Sunflower oil constitutes about 40–50% of vegetable oil produced in Europe, Russian Ukraine, Turkey, and Argentina. It was reported in literature that sunflower and rapeseed oil are the major sources of feedstock for renewable energy in Europe [17]. The percentage production of the main vegetable oils across the globe are sunflower (10%), rapeseed (55%), cottonseed (10%), and soybean (55%) [18]. Palm oil has been discovered as a potential feedstock for biofuel production in Malaysia [19, 20]. This novel research study focuses on the potential of biodiesel fuel as a better feedstock for production of green diesel.
The main feedstock for the production of biodiesel is vegetable oil [21]. Biodiesel is an alternative fuel that has similar properties to conventional or ‘fossil’ diesel. Conventional homogeneously catalyzed processes for fatty acid methyl esters (FAME) biodiesel production can be used to convert waste vegetable oils but is limited to oils with a relatively low FFA content. Some of the shortcomings of biodiesel that makes it necessary to convert it first to green diesel are: variation in the quality of biodiesel, food shortages, clogging in engine, not suitable for use in low temperatures, water shortages, slight increase in nitrogen oxide emissions. Biodiesel can be hydrotreated to obtain a quality green diesel fuel.
Da Rocha Filho et al. reported that more than 600,000 tons of used cooking oil are generated in South Africa per/annum [22, 23]. HDRD could be produced annually from this waste; given a yield rate of 80%, this will provide 205 million liters. However, this would cater for 50% supply targeted for renewable fuel in the biofuel policy of the government of the South Africa government. The current price of UCO is R3/liter and diesel is R14/liter. A value-added industry generating R2.04 billion can be created producing premium diesel (HDRD) along with the creation of thousands of jobs. Other potential secondary sources of feedstock are cellulose from pulp and paper industries plus a diverse range of agricultural waste with a far greater capacity than UCO [24]. UCO is an oil generated from vegetable oils after frying. UCO is readily available and abundant from food industries, restaurants, households, and fast food outlets using vegetable oils for cooking and frying. The demand for vegetable oil is on the increase in the continent. The yearly consumption of edible vegetable oils in China is approaching 22 million tons, and the country produces more than 4.5 million tons of used oil and grease per year [25]. Vegetable oil used for cooking undergoes various form of chemical and physical changes. Some unwanted compounds like FFAs and some polymerized triglycerides are formed during frying which causes a rise in the molecular mass and condenses the volatility of the oil. Used cooking oils are renewable and do not contain any aromatics, metal, or sulfur contaminants. Reuse of UCO can exacerbate environmental problems, health challenges including hypertension, diabetes, vascular inflammation, and other health effects [26]. Vegetable oil is an oil used for cooking a various type of food items which include, chicken, beef, yam/potatoes. Currently, the major factor that hinder the commercialization of renewable fuel the high cost of feedstock compared to fossil fuel. It has been reported in literature that about 70–85% cost of production of HDRD arises from the raw materials. However, the use of UCO as a feedstock for production of HDRD will enhance the commercialization of green diesel due to the availability at a low price. The HDRD production process involves the conversion of fatty acids in triglycerides into normal and/or iso-paraffin which can be obtained by hydrodeoxygenation, decarbonylation, decarboxylation, isomerization and hydrocracking or a combination of two or more thereof (Tables 1 and 2).
Fuel properties | Used cooking oil | Biodiesel | Commercial |
---|---|---|---|
Kinetics viscosity (mm2/s, @313 k) | 36.4 | 5.3 | 1.9–4.1 |
Flash points (k) | 485 | 469 | 340–358 |
Cetane Number | 49 | 54 | 40–46 |
Density (kg/l, @ 288 k) | 0.924 | 0.897 | 0.75–0.840 |
Pour points(k) | 284 | 262 | 254–260 |
Sulfur contents (%) | 0.09 | 0.06 | 0.35–0.55 |
Water contents (%) | 0.42 | 0.04 | 0.02–0.05 |
Ash contents (%) | 0.06 | 0.004 | 0.008–0.010 |
Free fatty acid (mgkoH/g oil) | 1.32 | 0.10 | — |
High heating value (MJ/kg) | 41.40 | 42.65 | 45.62–46.48 |
Comparison of properties of UCO, biodiesel, and commercial diesel fuel [27].
S/N | Name of industry | Feedstock/Technology | Targeted product/ton | Properties of product | References |
---|---|---|---|---|---|
1 | UOP/Ecofining | Triglyceride, hydro-processing of UCO | Green diesel | Similar to the properties of fossil fuels, Good cool flow | [28, 29, 30, 31] |
2 | Tyson Foods Inc. Gesmar LA, USA | Hydrotreating of non-edible and animal fats | Green diesel, 75 Mil.P/annum | Good storage stability, High cetane numbers, properties similar to petroleum fuel | [32] |
3 | Haldor Topsoe | New hydrotreating raw tall | Green diesel | Similar to fossil fuel properties | [33] |
4 | ConcocoPhillips | Hydrogenation of Vegetable oil | Green diesel 365,000 barrel/annum | Sulful free fuel content, emission of less NOx | [33] |
5 | Valero Energy Corporation, St. Charles | Hydrogenation of UCO/Animal fats | Renewable diesel | Similar to fossil fuel properties | [34] |
Commercialization of green diesel by selected industries.
The high acid value of UCO is due to the high content of FFAs [23]. In recent years, several petroleum companies have directed their resources into the production of renewable green fuels from hydro-processing of vegetable oils feedstock, with considerable commercial success.
The Neste Oil Co. developed a technology to convert vegetable oil and animal fat into high-quality hydrocarbons. The plant start operation by Neste Oil in Singapore in 2012 using NExBTL technology targeted production of over 800,000 tons renewable diesel per annum from feedstocks [35]. The experimental analysis of the samples by Neste Oil shows a high cetane value of between 84 and 99, a low cloud point value (as low as minus 30°C), and can withstand storage for extended periods. These properties enhance its performance in both car and truck engines [36].
The commercialization of bio hydroformed diesel (BHD) by the joint effort of Toyota Motor Corporation (TMC), Hino Motors, the Tokyo Metropolitan Government, and Nippon Oil Corporation (NOC) have commenced operation in recent time, a second-generation renewable diesel fuel produced by hydrogenating a vegetable oil feedstock. Nippon Oil and Toyota have worked jointly on the development of BHD technology since 2005. The use of refinery-based for hydro processing of vegetable oil for the production of a synthetic, second-generation biofuel depends on several issues, including the properties and effects of first-generation FAME (storage, oxidation, possible effect on fuel handling systems). In its studies, Nippon Oil explored reaction temperatures ranging from 240–360°C, with reaction pressures of 6 MPa and 10 MPa, and used a common hydrodesulfurization catalyst. The resulting fuel is claimed to be aromatics- and sulfur-free, with a cetane number of 101 [33].
The daily consumption of vegetable oil has witnessed a tremendous increase globally due to the increasing population and modernization. The global total primary energy consumption(GTPEC) has recorded over 150,000,000 GW h and this is expected to increase by 57% in the year 2050 [37]. This significant growth of energy consumption will eventually result in more environmental problems [38]. Currently, over 80% of the total energy used across the globe is sourced from fossil fuels, leading to their high contribution to environmental and health challenges [39]. UCO, which is considered waste, is collected before disposal. The annual collection of UCOs is evidence of the high consumption rate of UCO in some countries. The Energy Information Administration (EIA) of the United States reported an estimate of 100 million gallons of UCO produced per day in the USA [40]. About 135,000 and 140,000 tons of UCO are generated per annum in Canada [41, 42]. In South Africa, 0.6 million tons of UCO are collected annually from bakeries, takeaway outlets, and restaurants [43, 44]. The UK and the European Union countries produced 0.7 million tons to1.0 million tons and 0.2 million tons of UCO per annum, respectively [45]. The generation of a large amount of used cooking oil is a panacea to food security and fuel sustainability if properly harnessed for hydrogenation purposes. UCO is readily available, sustainable and cost–effective. Reports show that 17% of UCO offer a yield of 11.92 million tons while about 9% of the feedstock for the production of 26.62 million tons of biofuel is obtained globally in 2015 [46]. UCO was investigated, and the outcome of the chemical properties show that oleic acid has the highest value of 43.67%, followed by palmitic acid with 38.35%, and linoleic acid, 11.39% [47]. These properties of used cooking oils make it viable as a l feedstock for conversion into hydrocarbon. Table 3 shows the properties of UCO samples of sunflower oil, palm oil and sunfoil.
Properties | UCO Samples | ||
---|---|---|---|
Sunflower oil | Palm oil | Sunfoil | |
Density (Kg/m3) | 920.4 | 913.4 | 923.2 |
pH value | 5.34 | 6.19 | 6.61 |
Viscosity (mm2/s) | 31.381 | 38.407 | 35.236 |
Acid value | 2.29 | 1.13 | 1.44 |
Congealing temperature °C | −5.15 | 14.7 | −3.4 |
Molecular weight (g/mol) | 51.94 | 586.05 | 395.28 |
Iodine value (cg/g) | 111.1 | 54.2 | 54.2 |
Properties of feedstock compared to other vegetable oil [46].
The feedstock is one of the key resources in determining the production costs of biofuel. The adoption of biodiesel as feedstock will reduce the total cost of production and this will support the profitability and commercialization of an HDRD product. Biodiesel can be hydrotreated to combat the challenges of storage stability, cetane number to obtain superior HDRD as known as renewable fuel at a lesser cost and labor. UCO oil makes up approximately 80% of the total production expenses [29]. Biodiesel oil is readily available, does not affect food security, is cheap, requires not much effort to source, and offers a good yield when used. Green diesel is oxygen-free; hence oxidation stability is high, and has a high cetane number (CN) similar to fossil fuel. Hydrogenation derived renewable diesel(HDRD) possess high pour point better than biodiesel, It reduces NOX emissions, and has a high heating value which is a significant property of diesel fuel because it gives the energy content of the fuel and aid the performance of CI engines. Furthermore, green diesel produced by the hydro-processing of triglycerides has propane as a by-product which is a gaseous fuel of good market value. This property makes HDRD production more feasible in economic terms when compared to the production of FAME [48]. The composition of biodiesel products can be improved by hydro-processing techniques to obtain HDRD.
Biodiesel fuel has been investigated by researchers with varying outcomes. Table 4 shows some problems and possible solutions related to biodiesel fuel. Some important properties of biodiesel are cloud and pour point, storage stability, viscosity, acid value, cetane number. These are the properties of biofuel that must meet the set ASTM standard of biofuel. These properties are deficient when considering using biodiesel in CI engines, particularly in a cold, temperate, regions. The cloud points of ethyl ester produced from use cooking oil, linseed oil, canola, sunflower, and rapeseed oil are −1°C, −2°C, −1°C, −1°C, and −2°C, respectively. Lang et al. (2001) [49] reported that the cloud point of ethyl esters of linseed oil, canola, sunflower, and rapeseed oil were −2°C, −1°C, −1°C, and −2°C, respectively,whereas the corresponding methyl esters had cloud points of 0°C, 1°C, 1°C, and 0°C. Currently, internal combustion engine are controlled by compression ignition(CI) engine and the spark ignition (SI) engine. The operations of Spark engine (SI) is done by premixed charge near stoichiometric air-fuel ratio (Ø ~ 1), the flame is spread with the aid of a spark plug, the throttling effect of the charges into the cylinder leads to low thermal efficiency at partial load. Moreover, with the high temperature at peak load, cause generation of massive NOX, this have advert effect on the environment, is form a major challenge of the SI engine applications. The compression ratio of CI engine is between 12 and 24, in addition CI engine, is characterized by turbulent flame, diffused flame, auto-ignition via elevated pressure and temperature around the top dead center. The CI engine has a higher thermal efficiency compared to a SI engine. The major part of its operation is ignition delay (this is the time difference between the start of injection and the self-ignition). The ignition delay mechanism is controlled by physical and s chemical kinetic processes. The physical process proceeds sequentially through droplet formation, collision, break-ups, evaporation, and vapor diffusion. The chemical kinetic process involves species and radical formation proceeding through low-temperature reaction (LTR), negative temperature coefficient (NTC), and high-temperature reaction (HTR). The challenge is that the time scales for the physical processes are often larger than those of the chemical processes, hence ignition often commences before the physical processes are completed. This inevitably leads to a complex system of charge, flame, and thermal stratification that produces both high NOX in some regions and high soot precursors and unburnt hydrocarbon (UHC) in others. Research focus, therefore, has been to hydroprocess biodiesel fuel into HDRD to mitigate NOX, UHC, and soot formation (as is the case with the SI engine). From the foregoing, it is clear that there are many challenges facing the efforts to utilize biodiesel as a fuel in transportation.
Problem | Causes | Possible solutions |
---|---|---|
Cold weather starting | High viscosity, low cetane, and low flash point of vegetable oils | Preheat fuel before fuel injection. Chemically alter fuel to an ester |
Plugging and gumming of filters lines and injectors | Natural gums (phosphatides) in vegetable oil. Other ash | Partially refine the oil to remove gums. Filter to 4-microns |
Excessive engine wear | The high viscosity of vegetable oil, incomplete combustion of fuel. Poor combustion at part load with vegetable lubricating oil due to blow-by of vegetable oil | Heat fuel before injection. Switch engine to diesel fuel when operating at part load. Chemically alter the vegetable oil to an ester. Increase motor oil changes. Motor oil additives to inhibit oxidation |
Engine knocking | Very low cetane number of some oils. Improper injection timing | Adjust injection timing. Use higher compression engines. Preheat fuel before injection. Chemically alter fuel to an ester |
Coking of injectors on piston and head of engine | The high viscosity of vegetable oil, incomplete combustion of fuel. Poor combustion at part load with vegetable oils | Heat fuel before injection. Switch engine to diesel fuel when operating at part load. Chemically alter the vegetable oil to an ester |
Failure of engine lubricating oil due to polymerization | Collection of polyunsaturated vegetable oil blow-by in the crank case to the point where polymerization occurs | Heat fuel before injection. Switch engine to diesel fuel when operating at part load. Chemically alter the vegetable oil to an ester. Increase motor oil changes. Motor oil additives to inhibit oxidation |
Problems, causes, and possible solutions regarding biodiesel products.
The rapid urbanization, abundant land resources, and vegetable oil in Africa offer adequate opportunity for biodiesel production on a large scale. FAME product obtained from this resource provide insight into the new option of sourcing for renewable energy. Traditionally, biodiesel had been produced from vegetable oil; about 93% of biodiesel is produced from edible oil, and the feedstock sourced from agricultural sector [50]. However, the edible vegetable oil is unsustainable due to the food security threat [51]. Biodiesel production uses around 4.4 million hectares of arable land in the European Union [52]. The consequence of deforestation is greenhouse gas (GHG) which great effect on man, plant, animal. The alternative option to these is the use of non-edible oils, hence the focus on biodiesel and used cooking oil as feedstock. Other vegetable oils can be propagated easily in drought-prone areas and are highly adaptable in tropical areas [53]. Biodiesel fuel converted to HDRD is set to play an important role in the future around the world. Africa’s population is projected to reach 1.5 billion by 2030, with 53.5% of this population living in developed countries [54]. This trend is set to accelerate and a greater supply of green diesel will be necessary in order to meet the growing demand for HDRD. The only economically beneficial and sustainable ways to achieve this goal is to embark on aggressive production of HDRD using biodiesel as a feedstock.
The technology for petroleum-based fuel production has been in existence for many years. The same catalyst, reactor type, and distillation facilities used for the production of fossil-based fuel are also applicable for hydro-processing of vegetable oil-derived feedstocks to obtain high-quality hydrocarbon. Thus, massive savings are achievable since the same production plant facilities can be used for the purpose. Conversion of used vegetable oil via hydro processing using stand-alone units can be achieved by optimizing and controlling the facilities to obtain high yield green diesel. The design and construction of this facility as an attachment to existing plants and hydrogen in the refinery can be streamlined as recycled gas. The only shortcoming of a stand-alone unit as a production facility is the high cost of construction. In recent times the feedstock used for the production of HDRD has been plant-derived oils such as rapeseed, soybeans, and palm [55, 56, 57, 58] which are edible oils, with the non-edible oils like Jatropha, algal oils and waste cooking oil products being the most popular feedstock ion recent times [57, 59]. Many researchers have confirmed UCO as being the most viable, cost-effective, and available feedstock. Researchers are still investigating the most suitable technology for the production of green diesel that is cost-effective and CI engine compatible. No research has been done yet on the viability of biodiesel oil as a potential feedstock for HDRD production. When this is explored it will boost the supply of renewable fuel in energy sector. Green diesel obtained from biomass can be processed through four technologies: (i) Pyrolysis and upgrading of bio-oil, (ii) Hydro-processing, (iii) Catalytic upgrading of sugars, starches, and alcohols. (iv) Biomass to liquid (BTL) thermochemical processes. FT green diesel is produced by the Fischer-Tropsch [60, 61]. Hydrocracking and hydrotreating are the two major step in hydroprocessing technique [62]. The following yield was obtained via hydro processed used vegetable oil; biofuel (85%), non-condensable gases (10%), and water(5%) [63]. Green diesel is a biofuel product that comprises of branched saturated hydrocarbons and straight chain which contain carbon atoms of C15–C18. The properties of green diesel is similar to fossil fuel making it compatible with CI engines [64, 65]. Therefore, green diesel has superior fuel properties like high cetane number, oxidation stability, and cold flow and cloud point compared to FAME and petroleum based diesel [66]. Othman et al. investigated the value of cetane number, the outcome shows that green diesel has value of cetane number between 80 to 90 which is higher than the petrol based diesel standard [67]. The density and the net heating value of green diesel are in the range 0.77 g/ml to 0.83 g/ml and 42 MJ/kg and 44 MJ/kg respectfully, which also meets the biodiesel and petrol diesel standard [68].
The global population and consumption of vegetable oils have a direct relationship. The increase in population has triggered the consumption of vegetable oil that gives rise to massive volumes of UCO. The largest percentage of these vegetable oils is used in households, restaurants, and fast-food outlets for cooking and frying. Table 5 shows the estimated amount of UCO collected by some countries. Canada is reported to generate between 0.120 and 0.135 million tons of UCO per year [42, 69], while the United States of America produced 0.6 million tons of yellow grease in 2011. The United Kingdom and the European Union countries generate ∼0.7 million tons to 1.0 million tons and 0.2 million tons of UCO per year, respectively [45, 70]. In South Africa 0.6 million tons of UCO are collected per year, while more than an estimated 0.2 million tons of UCO is produced but not collected from households, bakeries, takeaway outlets, and restaurants per year [44, 70], which contributes to soil and water contamination, sewage blockages, and damage to aquatic life [71]. China, Malaysia, and Japan generated 0.6 million tons, 0.5 million tons, and 0.6 million tons of UCO, respectively, annually. It is reported that more than 60% UCO generated globally is indiscriminately disposed of [24].
Country | UCO collection (million ton/annum) |
---|---|
Canada | 0.14 |
China | 0.15 |
Malaysia | 0.5 |
South Africa | 0.6 |
United Kingdom | 0.2 |
Annual collection of UCOs in some countries.
UCO is produced when vegetable oils sourced from palm, soybean, sunflower, cottonseed, olive, palm kernel, and rapeseed or animal fats like butter, fish oil, and tallow, are used for cooking or frying food [72]. With feedstock accounting for between 80% and 85% of the production cost of biodiesel, the use of UCO can result in a substantial reduction in production costs, thereby significantly reducing the cost of biodiesel fuel. This makes biodiesel more viable as a feedstock for green diesel production as a substitute fuel for internal combustion engines, particularly unmodified CI engines. The focus of this research work has been on the conversion of biodiesel product into HDRD via the hydrogenation technique.
The pH value of UCO varies between 5.13 and 6.61, indicating a weak acid for a biodiesel feedstock. The pH value reported in the literature were not uniform but depended on the type and degree of usage. Food such as sausage triggered higher pH values than fish etc. This is a result of fats from fish being more acidic than those of beef [39]. The value of acidity is reduced in used palm oil after repeated frying due to the effects of thermal degradation and contamination from the food items. UCO which is normally subjected to heating witnesses a reduction in pH as a result of usage. Generally, due to repeated and high cooking temperatures, the acid value of the oil tends to reduce. However, the transformation and the mechanism for the generation of cyclic and noncyclic hydrocarbon in vegetable oil during high-temperature repeated cooking can be difficult to predict as a result of the many reactions that produce many unstable intermediate hydrocarbons. In contrast, the results obtained as reported in the literature show that biodiesel is a feasible feedstock for the production of HDRD which is also known as green diesel. From the previous report research analysis, EN 14214 and other standard test methods were used for the analysis of biodiesel. Density at 15°C and kinematic viscosity at 40°C of the fuel were measured under EN ISO 3675:1998 and EN ISO 3104:1994,with 926 kg/cm3 and 37.3 1mm2/s values being reported respectively [73]. The acid value and iodine value analysis were done by titration under EN 14104:2003 and EN 14111:2003, with 0.63 mgKOH/g and 109.98 mgI2/100 g being reported respectively [74]. The flashpoint was measured using the Pensky-Martens method ISO 2719:2002 [75], and the sulfur content was quantified under EN ISO 13032:2012 [76]. The aforementioned properties prove the viability of biodiesel as a potential feedstock for HDRD production. The application of HDRD derived from biodiesel fuel offers high yield, excellent storage stability, high cetane number, and flashpoint.
The continuous search for sustainable renewable energy has stimulated researchers to develop solutions to the global environmental crises and demand for renewable biofuel. HDRD has received significant attention across the global economy due to its higher stability, higher heating value, and emission of harmless pollutants. The use of biodiesel as a feedstock is more viable as it reduces the production cost and has the potential to settle the concerns related to the edible oil market. This critical review has identified biodiesel fuel as a potential feedstock for hydrogenation into HDRD. The main conclusions are:
Commercialization of HDRD production requires government attention without delay. Implementation of government policies and regulations that directly address the challenge of demand, production, and trade of this HDRD must be spearheaded by ministries and governmental bodies.
The outcome of this research shows that biodiesel fuel can be harnessed as a potential feedstock for the commercial production of HDRD.
HDRD possesses superior fuel qualities such as CN, low pour point, and excellent oxidation stability which offers a great benefit for the CI engine and the environment.
The goal of producing cost-efficient HDRD is still far from being reached. The economic feasibility of the production of HDRD using biodiesel is sustainable.
The authors are grateful to the leadership of Green Energy Solutions, Discipline of Mechanical Engineering, Howard College, University of KwaZulu-Natal, Durban for their contributions towards the success of this work.
No conflict of interest.
The Authors hereby acknowledge the funding support from TETFUND.
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All published Book Chapters are licensed under a Creative Commons Attribution 3.0 Unported License. Monographs are licensed under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) license granted to all others. Our Copyright Policy aims to guarantee that original material is published while at the same time giving significant freedom to our Authors. IntechOpen upholds a flexible Copyright Policy meaning that there is no copyright transfer to the publisher and Authors hold exclusive copyright to their work.
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\n\n\n\nIntechOpen publishes different types of publications.
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