\r\n\tRisk management aims to develop an efficient organizational development environment through risk planning, assessment, analysis, and control. This process will apply in all areas of activity, and the evaluation framework is the same regardless of the field. This volume will aim to appeal to chapters that address methods, models, evaluation frameworks, benefits, barriers, and other dimensions of risk management. \r\n\tSustainability and the circular economy are approaches approached by many companies and have become activities of global interest. Protecting the environment, streamlining the consumption of organizational resources, reducing the amount of waste generated, and other activities are objectives of these efforts. The circular economy contributes to the sustainable development of the company or country and the achievement of the global objectives of sustainable development. This book will aim to collect various studies for organizational and global sustainability. \r\n\tLeadership has become a globally desirable approach that can help improve organizational competitiveness and reduce organizational risks. Risks and barriers in risk-free management can be well managed through effective organizational leadership. This book will aim to bring together chapters that explore different areas of leadership.
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She is the president of the scientific committee of the Academy of Political Leadership and vice-president of the Society for Ergonomics and Work Environment Management. Dr. Ivascu has been involved in national and international projects and has published nine books, and contributed scientifically to more than 200 scientific articles.",coeditorOneBiosketch:"Dr. Ben-Oni Ardelean obtained Ph.D. in Political Science and Ph.D. in Theology; he has extensive academic and political experience. He is the author of several books and numerous academic articles. He is highly preoccupied with supporting those in need, helping others to help themselves, and motivating people to live a life of purpose, love, and compassion. 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1. Introduction
\n
The promise of the ‘fourth industrial revolution’ relies on the development and integration of the so‐called Internet of Things, cyberphysical systems and associated services and process improvements. The basis of the promise is the ability to instrument, connect, automate and remotely manage the majority of industrial systems and processes. The underlying assumption is that cheap, wirelessly communicating sensors and actuators can contribute to providing this capability, either autonomously or as part of a decision support system with a human in the loop.
\n
In many cases, it is assumed that monitoring and control applications will require the use of devices that operate without persistent energy availability. Where no mains power is available, energy becomes a major constraint for applications expected to operate for increasingly long time periods. These periods are determined by the feasibility of maintenance of devices, with respect to both practicality and cost. Therefore, a major recent theme of research has been to attempt to achieve energy neutrality. This has been approached from many different angles, including novel ultra‐low power receiver circuits (wake‐up radio, WuR) [1, 2], energy harvesting and hybrid‐storage (battery‐supercapacitor) systems [3], compressive and predictive sensing [4–6], and traditionally, energy‐efficient communications protocols [7].
\n
Achieving energy neutral operation requires a comprehensive understanding of the application at design time and is seen as a ‘holy grail’ for networked embedded computing devices. However, applications tend to be characterised by heterogeneous performance requirements [8], deployment environments and criticalities. Therefore, there are few, if any, ‘one size fits all’ solutions. If one assumes that sensors and actuators are low cost with respect to energy in terms of sampling and information processing (which is not always true in the case of industrial applications [9]), communication is widely accepted to be the primary consumer of energy [10]. This energy consumption occurs when the radio transceiver is in an active state to send, receive and/or route packets. Assuming a worst‐case scenario whereby the radio transceiver is always active (a state which tends to require tens of milliwatts of power [11]), the obvious way to reduce energy consumption is to place the device in the lowest power mode available for as long as possible—a technique known as duty cycling [12], which can be applied to the radio transceiver (radio duty cycling, RDC) and the other components of the device. This is equally true for recent system on chip (SoC) solutions that integrate transceiver and microcontroller circuitry on the same chip.
\n
However, the device must also be able to participate in a network, which necessitates the implementation of a communications protocol stack (Section 1.1.1). This is a long‐standing research area in the wireless sensor networks (WSN) community, which in the past 10–15 years has developed numerous energy‐efficient communications mechanisms that operate at and across various layers. The remainder of this chapter is dedicated to exploring the evolution of energy‐efficient communications primitives, explaining the inherent trade‐offs in the design space and providing a comprehensive description of the state of the art. The emphasis is placed on link and routing layers.
\n
1.1. Wireless communication
\n
There are several well‐known wireless communications technologies in popular use. These range from cellular, now on the verge of the 5th Generation (5G) [13], to WiFi (IEEE 802.11) and Bluetooth Low Energy (BLE) [14], among the most widespread
Full coverage of wireless communication fundamentals is available in [15].
Recent WiFi and BLE chip‐sets are significantly lower power than their predecessors and are increasingly competitive for certain classes of energy‐efficient ‘IoT’‐type applications, particularly in the consumer electronics market.
\n
This chapter focuses on wireless communications protocols suitable for use with RF transceivers and SoCs typically considered ideal for low‐power WSN‐type applications, such as the (now obsolete) TI CC2420 [16], CC2538 (used in the recent OpenMote devices) [17], and the NXP JN5168. These are compliant with the IEEE 802.15.4 standard for low‐rate wireless personal area networks (LR‐WPAN) [18], which is responsible for underlying much of the research in this area and has found its way into numerous industrial standards and specifications including ZigBee [19], WirelessHART [20] and ISA100.11a [21].
\n
1.1.1. Communications protocol suites
\n
A communications protocol suite specifies how data should be formatted (i.e. in packets), transmitted and received (channel access), and routed in a network
The practical implementation of a protocol suite is typically referred to as a ‘stack’.
. Layers of abstraction are used to describe the various networking functions involved and vary somewhat depending upon the model of abstraction. For example, the OSI model specifies seven layers, whereas the TCP/IP model (Internet Protocol suite) specifies four. This is a particularly relevant issue in WSN design, as it is well known that efficiencies are best achieved by co‐designing the layers [22], but they are often designed independently (e.g. RPL) [23] to enable interoperability. The most recent IETF stack proposed by the 6TiSCH working group, which is particularly suited to IoT, is shown in Figure 1 and loosely maintains the TCP/IP model. In this case, IEEE 802.15.4 time synchronised channel hopping (TSCH) is used at the ‘link layer’ (which includes medium access control), 6top is an interface layer to the 6LoWPAN adaptation and compression layer (used to reduce the size of the IPv6 header such that it comfortably fits in the 127‐bytes available in an IEEE 802.15.4 physical layer packet), and RPL (Section 3.2.5) at the Internet/routing layer. UDP is used at the transport layer to mitigate the overheads associated with TCP (i.e. end‐to‐end handshaking), and the Constrained Application Protocol (CoAP) [24] handles application layer functionality.
Figure 1.
The 6TiSCH Protocol Stack [84].
\n
While the higher layers of the stack benefit from having an understanding of, and in many instances real‐time information from, the lower layers, the most critical from an energy efficiency perspective are the physical layer (i.e. the radio transceiver itself) and the link layer, the latter of which is responsible for medium access control, and therefore, how long the transceiver remains in an active or sleep state. Energy‐efficient medium access control (MAC) protocols are discussed in Section 2. However, as discussed in Section 2, the selection of a suitable MAC protocol is heavily dependent upon the application, specifically with regard to the statistical properties of the traffic generated in the network, the network topology and environmental factors. A well‐designed application will take each of these factors into account at design time.
\n
1.2. Hardware
\n
The electrical characteristics of the hardware play a significant part in the overall energy efficiency of a networked device and the performance of a network. While a complete analysis of each component is beyond the scope of this chapter, it is worth highlighting where hardware mostly impacts the design of applications and implications for various layers in the protocol stack.
\n
Firstly, selection of the radio itself is a key. From an application standpoint, basic quality of service requirements must be met, primarily bandwidth—otherwise the application is probably infeasible (without resorting to trickery in software, such as compressive or predictive sensing, and assuming this is satisfactory for an end‐user). The worst‐case scenario from an energy perspective is that the radio must be on 100% of the time. Therefore, once a wireless technology is selected (e.g. take IEEE 802.15.4), the designer sets about choosing a chip. The majority are reasonably similar in terms of their electrical characteristics, irrespective of the manufacturer. This makes life easier but it is worth considering the features of the chip selected. For example, on‐board hardware acceleration of security functions can greatly reduce the overheads associated with implementation in software. Most contemporary RFICs compliant with IEEE 802.15.4 are in the tens of milliwatts range in active modes and drop to the microwatt range in low power modes, making them good candidates for long‐term low‐power applications. They require additional RF front‐end design, including antenna and matching networks, plus an oscillator circuit to drive the clock. The latter requires the selection of inductors and capacitors, which are variable in their characteristics.
\n
Important performance characteristics are often affected by environmental conditions such as temperature and humidity. In the case of a wireless node, these have effects internally (i.e. on each device) and externally (i.e. the effects on the wireless medium), which both impact on the performance of a network. In the case of the device, temperature effects and component selection have a significant effect on relative clock drift, which must be taken into account when tuning and learning protocol parameters like guard times and phase offsets, respectively (Section 2). Understanding clock drift is essential to tightly configure networking parameters, such as guard times to ensure accurate synchronisation, and has been studied in [25] where the authors investigate the effects of environmental temperature on clock drift and propose strategies to help designers choose optimal resynchronisation periods for given accuracies, and in [26] where the authors study the impact of oscillator drift on end‐to‐end latency over multiple hops using varying capacitor accuracies and show how to determine optimal parameters to minimise energy consumption in duty‐cycled wireless sensor networks using low power medium access control techniques. It is also worth noting that temperature influences battery performance, particularly as temperatures reduce, where capacity is degraded and voltage is known to reduce. This is a relatively understudied area in terms of IoT/WSN technologies, but is likely to be very important where devices are deployed outdoors in cold environments.
\n
2. Energy‐efficient medium access control
\n
A large body of research exists concerning MAC protocols for WSNs. Notable examples of energy‐efficient implementations include A‐MAC [27], BoX‐MAC [28], HuiMAC [29], SCP‐MAC [10], ContikiMAC [30] and WiseMAC [31]. These MAC protocols are based on globally asynchronous, radio duty‐cycled (RDC) approaches, where the objective is to minimise the active time of the RF transceiver. Typically, trade‐offs are assumed to be inherent in the design of these protocols, and the Pareto‐optimal solution is sought when considering energy efficiency and application level or performance requirements, such as throughput, reliability and latency. In [32], the authors consider low data‐rate applications and attempt a tractable analytical approach to modelling latency and energy efficiency as functions of protocol parameters including duty cycle, slot duration and total slots, seeking to determine optimal settings for given workloads defined by application‐level parameters. They find that WiseMAC best balances energy efficiency and latency based on the scenarios considered, and attribute minimising protocol overhead through local synchronisation (also referred to as phase lock optimisation in the literature, and exploited in several subsequent proposed MACs [30, 33]) and random channel access as key to achieving this balance.
\n
These protocols, however, are just the tip of the iceberg (and are heavily oriented towards aggressively duty‐cycled, energy‐efficient scenarios for low data‐rate applications). In [34], Bachir et al. present a comprehensive taxonomy of MAC protocols according to the various techniques being used, classifying them according to the challenge they address. They describe the importance of understanding the statistical properties of the network traffic when selecting and tuning a MAC protocol, which is argued to be a more useful approach for the application developer. The authors classify the traditional ‘MAC families’ as Reservation‐Based Protocols and Contention‐Based Protocols at the highest level, where the former is synonymous with scheduled approaches such as Time Division Multiple Access (TDMA), and the latter with simpler, popular approaches such as ALOHA and Carrier Sense Multiple Access (CSMA). They proceed to explore the functions relative to: high—scheduled protocols for high‐rate applications such as multimedia; medium—protocols with common active periods for medium rate applications such as those found in many industrial applications; and low—preamble sampling for low‐rate applications with rare event‐reporting, such as long‐term monitoring or metering, and finally consider hybrid protocols for time‐varying application‐level functionality. Table 1 borrows the structure and updates the taxonomy of that presented in [34]. Specifically, A‐MAC, Reins‐MAC and IEEE 802.15.4e, which leverages TSMP and is closely linked with ongoing standardisation initiatives, are notable protocols published since Bachir et al. presented their study.
Summary of MAC protocols by functionality, updates [34].
\n
Another interesting development relates to the exploitation of constructive interference, which is contrary to CSMA mechanisms and seeks to benefit from concurrent transmissions. Flip‐MAC [39] and Glossy (not strictly a MAC protocol) [40], for example, make good use of this with regard to packet acknowledgements and efficient network flooding, respectively.
\n
2.1. Standards and evolution
\n
The IEEE 802.15.4 standard is one of the most important standards in WSN/IoT. First published in 2003, it specified the physical and medium access control mechanisms for low‐rate wireless personal area networks and became part of the industrial standards and specifications listed in Section 1. The medium access control layer specified in the standard is effectively a hybrid construct that allows the use of slotted or un‐slotted CSMA‐CA with optional guaranteed timeslots and packet delivery. It was designed to accommodate a range of topologies, including star and peer‐to‐peer, specifying device classes that allowed for reduced protocol complexity for ‘reduced’ function devices (RFD) opposed to ‘full’ function device (FFD) capable of communication with any device in the network. While this allows for relatively low duty cycles to be achieved, there is an inherent trade‐off between energy saving and latency and bandwidth. This was studied immediately, and simulations were used to illustrate the trade‐offs related to using the various modes, for example, in [41].
\n
De facto standards simultaneously emerged in the research community where a number of competing objectives made it difficult to build practical implementations for the hardware available at the time. Factors such as ultra‐low power operation, collision avoidance, efficient channel utilisation, robustness to time‐varying channel and networking conditions, scalability, and efficiency in terms of implementation and memory requirements needed to be addressed by design. B‐MAC (short for Berkeley) was one of the earliest protocols built into an open source ‘operating system’ for WSNs, namely TinyOS [42]. B‐MAC (2004) is a carrier sense protocol that improved upon the performance of S‐MAC (one of the first to use RTS/CTS in sensor networking) under certain conditions, making use of clear channel assessments, acknowledgements, back‐offs and low power listening (LPL). This was later improved upon by merging features with X‐MAC (a link‐layer only approach, 2006), resulting in the BoX‐MAC (2008) protocols which eventually shipped with TinyOS [28]. BoX‐MAC demonstrates cross‐layer design and how to achieve significant energy efficiencies and throughput improvements for reasonable workloads.
\n
Within the Contiki community, a number of the same protocols were implemented and extended into standard link layers and radio duty cycling mechanisms in a cross layer fashion. Features from BoX‐MAC and X‐MAC, such as periodic wake‐ups and strobes, and WiseMAC, specifically the phase lock optimisation, were integrated to form the ContikiMAC protocol, which has shipped as a de facto standard link layer since around 2011.
\n
TSMP is one of the most notable TDMA MAC layers developed in the last decade [43]. It uses synchronisation between devices to communicate in scheduled timeslots (allowing low‐energy radio management) and operates reliably in noisy environments by using channel hopping to avoid interference, with different time‐slotted packets sent on different channels depending on the time of the transmission. Therefore, the approach is suitable for applications that require relatively low‐power and high‐reliability performance, characteristic of industrial automation scenarios, and has thus been included in the WirelessHART and ISA standards (Section 1.1). More recently, it has become fundamental to the development of the IEEE 802.15.4e amendment to the standard, which is actively being included as a core technology in the IETF standardisation effort (e.g. Figure 1).
\n
2.2. Design trade‐offs
\n
It is important to understand the trade‐offs inherent in the link layer design choice. From an energy efficiency perspective, selection of a low‐power transceiver is critical, but selection of the appropriate link layer will depend on the application\'s performance requirements. All of the aforementioned protocols are relatively energy efficient. Therefore, depending on the reliability, throughput and latency required, certain protocols perform better than others. For critical applications, it is usual that energy efficiency is not prioritised as highly as reliability and low latency. Therefore, in a high‐criticality application, TSMP would be preferable to an asynchronous protocol such as ContikiMAC.
\n
Table 1 shows that the area of MAC design for wireless sensor network applications has been comprehensively researched. As a result, many recently proposed protocols integrate and build upon ideas previously presented. The parameters of importance are now reasonably well known. CSMA‐CA protocols with arguably the best performance typically operate using request‐to‐send/clear‐to‐send (RTS/CTS) signalling, where networked devices periodically listen to the channel to determine whether any neighbours want to send packets, or alternatively begin to strobe RTS packets and wait for a CTS message from a listening neighbour if the device wants to transmit. The choice of what to send in the RTS packet is an interesting one, with many designers proposing to effectively send an entire data packet as the RTS strobe, such as in ContikiMAC, whereupon the receiving node sends an ACK having received the data payload. However, this can be suboptimal considering variable length data packets. It is argued in [33] that the use of a fixed‐length RTS packet can bring efficiencies when considering its relationship to strict timing parameters. Addressing information (to enable unicast, broadcast and/or multicast communication) is a key inclusion for such a packet.
\n
Timing parameters for such protocols are bounded by performance characteristics of the RFIC (such as turnaround times between TX and RX modes) and the theoretical minimum times required to transmit, receive and act upon packets. Perhaps the most critical parameters are the receive check (RC) and receive check intervals (RCI). It is also worth noting that receive checks can be performed at both the physical (L1) and link layers (L2), which enforces a trade‐off between absolute energy efficiency and reliability. Where L1 only methods are used, the RC operation is cheaper, but net energy efficiency may be worse if devices that are not being addressed stay in RX mode and parse packets not specifically intended for them.
\n
The RC is where a node samples the wireless medium for energy to determine whether or not there is an incoming packet. An optimal duration for the RC is tightly coupled with the time taken to listen for a CTS strobe during a wake‐up stream. Minimising the RC is a key to optimising energy efficiency, but this period is also closely related to reliability performance. Theoretical minimum values for length of the RC and the CTS listen period are calculated using the RXTX turnaround times for the transceiver, its bit rate and processing time.
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The RCI is the interval between performing RCs, typically measured in Hz. It is possible to determine an optimal RCI with regard to energy efficiency, but this is detrimental to latency (where a latency is fundamentally lower bounded by the RCI and the number of hops over which a packet must travel to reach its destination). RCIs are often lengthened to reduce their impact on the quiescent power consumption of a device. Where large RCIs are used, for example, >0.5 Hz, it becomes more important to implement phase or offset learning (resulting from positive or negative relative clock drift) to ensure that energy consumption is minimised when beginning the next RTS/CTS wake‐up stream.
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Transmitting nodes may or may not, depending on the application, have an enforced periodic data reporting interval. This is often referred to as the inter‐packet interval (IPI) in the literature and broadly reflects the frequency with which sensor data are transmitted from each device in the network. It is worth remembering that the IPI is not necessarily the same as the sampling rate of the sensor, where in many cases an aggregate or average values may be returned periodically (i.e. at the IPI rate of the node).
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A factor less studied in the literature is the implementation of the CSMA algorithm itself. In [33], the authors demonstrate that a quantised approach to the implementation of back‐offs performs better with regard to energy efficiency and reliability than randomised approaches.
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So called receiver‐initiated protocols have more recently been studied, whereby when a node wants to transmit a packet it waits for a neighbour (i.e. a potential receiver) to send a probe. Upon hearing the probe, the sending node transmits its packet. Examples of this approach are Low‐Power Probing (LPP) as introduced in Koala [37], RI‐MAC [38] and A‐MAC [27].
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The physical and link layers determine the lower bound for energy efficiency with respect to point‐to‐point communication. When a network extends beyond a one‐hop (or star) topology, devices in the network must implement some routing functionality (usually referred to as Layer 3 or the NWK layer), to ensure that packets arrive at the intended destination, which is explored in the next section.
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3. Energy‐efficient networking, data collection and dissemination
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Routing algorithms are essential for every WSN as they define how packets flow within the network. Algorithms differ from each other based on their capabilities, effectiveness, amount of memory required to store the routing state, agility and energy awareness.
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Routing protocols for WSNs can be categorised into three main groups depending on the functionality they provide: (i) protocols that route data only towards one or more predefined base‐station or sink nodes, referred to as data collection protocols or many‐to‐one patterns of communication, (ii) protocols that allow peer‐to‐peer or any‐to‐any patterns of communication between nodes in the network and (iii) protocols allowing one node to disseminate a message to all or a subset of the nodes in the network, also referred to a one‐to‐many pattern of communication. Protocols which belong to the first group are usually based on building routing trees which are rooted at one (or more) sink node(s). Every node in the network forwards all data towards a sink via a selected parent. Protocols from the second group support peer‐to‐peer communication, that is, any node in the network can send a message to any other node. These protocols either exploit some kind of routing table, learned beforehand, to forward data towards the destination or they first need to find the destination node and establish a connection. Protocols from the last group are usually based on gossiping or flooding the whole network.
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3.1. Data collection
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Typically, WSNs have been deployed to collect data about certain phenomena in predefined geographic areas (sensing field). Nodes in such a network sample a sensor at a predefined rate and report the sensed data towards a sink node. The network may contain several base‐stations, in which case a node typically forwards data towards the closest base‐station only.
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Two of the most common routing protocols are Collection Tree Protocol (CTP) [44] and Routing Protocol for Low Power and Lossy Network (RPL)
RPL is in fact designed to support any-to-any communication; however, very little work has been done in this regard, with early evaluations suggesting that it is not ready for actuation-type messages [45].
[23]. CTP is a standard library of the TinyOS [42] operating system, while the Contiki [46] operating system comes with two standard alternatives: (i) Collect, which is part of the basic Rime network stack [47] and is an alternative implementation of CTP for Contiki OS and (ii) RPL, which is part of the more complex IPv6 stack. There is also an RPL implementation for TinyOS called TinyRPL. These protocols are based on creating a directed acyclic graph rooted at the base‐station. Each node in the network forwards all data towards the root.
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A primary challenge in the design of these protocols is defining the metric by which a node chooses its parent, via which the node will forward all packets. Early adopters of this approach used hop count to the base‐station as a metric [48]. Later, CTP used a new metric: Expected Transmission Count (ETX). ETX uses the number of transmissions required to deliver the packet to the destination without error. ETX depends on the quality of the link. Many protocols vary by how the quality of the link is measured and computed (e.g. based on RSSI, or a statistical measure of the number of packets lost, or a function of both). It has been shown that using this metric decreases the network traffic and leads to lower energy consumption.
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Energy efficiency can be described as the ratio between the total number of packets received at the destination node (i.e. the base‐station, in the case of collection protocols) and the total energy spent by the network to deliver these packets. Due to the overhead of IPv6 protocol, researchers were concerned about the energy efficiency of the RPL protocol. However, it was shown that packet delivery ratio of CTP and RPL is very similar, while the overall energy consumption is only 3% higher for the latter [49]. Similar results were observed in a study focused on interoperability of RPL implementation for Contiki and TinyOS operating systems [50].
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A disadvantage of building rigid routing trees is that the nodes along the path towards the base‐station have to transfer more data than other nodes, and hence their batteries deplete faster. This especially applies to the nodes closer to the base‐station. To tackle this problem, Lindsey et al. proposed Disjoint Paths and Braided Paths algorithms [51]. Disjoint Paths algorithm constructs a small number of alternative paths from each sensor to the base‐station. These paths are sensor‐disjoint, that is, paths have no intermediate nodes in common. Braided Paths algorithm creates partially disjoint paths from the primary path, that is, for each node on the path an alternative path is created which does not contain given nodes. Therefore, in the case of a node failure, an alternative path can be used without the need to first find the path.
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An alternative approach to creating rigid routing trees is the back‐pressure protocol (BCP) [52] presented by Moeller et al. In networks with BCP, the routing decision depends on the size of the packet queue and the packet rate between two nodes. Each node maintains a queue of packets, where a base‐station has a queue of zero length. A node forwards a packet to a neighbour only if the neighbour\'s queue is shorter than the queue of the sending node. The received packet is put on the top of the queue and in the next iteration forwarded to a node with a shorter queue. This can lead to more evenly spread network traffic while exploiting various routes towards the base‐station.
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An older approach which tries to eliminate rigid routing trees is hierarchical routing. This approach breaks the network into clusters, each of which has a cluster‐head. Nodes send data to these cluster‐heads which are then responsible for delivering data to the base‐station.
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Heinzelman et al. presented Low‐Energy Adaptive Clustering Hierarchy (LEACH) [53], a popular clustering algorithm whose goal is to reduce energy consumption of nodes in a WSN. The operation of the algorithm is split into two phases: (i) the setup phase during which cluster‐heads are elected and nodes choose which cluster they will be part of and (ii) the steady phase during which sensor nodes transfer data to the cluster‐heads which aggregate received data and forward them to the base‐station. Cluster‐head election is distributed, and nodes do not require any global knowledge of the network. A disadvantage of this algorithm is that the communication between nodes and cluster‐heads, as well as the communication between the cluster‐heads and the base‐station is single‐hop only, which limits the size of the network. Additionally, cluster‐head selection does not take into account the residual energy of the node. Being a cluster‐head is very energy demanding, as the cluster‐head has to be 100% duty‐cycled in order to receive messages from all nodes. If a node with small residual energy is elected, it may deplete its battery before it collects all data and forwards them to the base‐station.
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One of the extensions of LEACH algorithm presented by Lindsey and Raghavendra, Power‐Efficient Gathering in Sensor Information Systems (PEGASIS) [54], creates chains of sensor nodes where each node aggregates data received from the previous node with its local data. In each iteration, a random node from the chain is chosen to forward aggregated data to the base‐station. A disadvantage of PEGASIS is that it assumes that each node has global knowledge of the network layout, particularly the position of the nodes.
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Younis and Fahmy presented another LEACH extension called Hybrid, Energy‐Efficient Distributed Clustering (HEED) [55]. Unlike LEACH, it operates in multi‐hop networks and for cluster selection it uses both the residual energy of the node and the node degree or density. Thus, the algorithm may better balance energy consumption amongst the nodes, hence prolonging the lifetime of the network.
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Each of these hierarchical routing protocols scored three out of four points for energy efficiency in a large survey on routing protocols [56], meaning that these protocols achieved average packet delivery rates while choosing routes based on the residual energy, thereby prolonging the lifetime of the network.
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3.2. Peer‐to‐peer routing
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For networks deployed for the purpose of monitoring and continuous collection of data, peer‐to‐peer (P2P) communication is often not necessary. Each node only needs to know how to deliver data to one of the base‐stations. However, as WSNs become more common and serve a wider range of purposes, communication among nodes in the network will become more important. WSNs are not only used to collect data but also to react to the environment and control it via actuators, that is, components of emerging cyberphysical systems. Nodes in the network need to send messages directly to other nodes, while lowering the overall traffic. With actuation networks, this requirement becomes even more important to send an actuation message directly to the actuator. For that purpose, routing protocols which allow P2P communication were developed.
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Such P2P protocols may be categorised into five groups, depending on how they locate and forward messages to the communicate with a peer: (i) geographic routing, (ii) routing based on trees, (iii) hierarchical routing, (iv) ad hoc shortest path routing and (v) routing based on routing tables.
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3.2.1. Geographic routing
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In geographic routing, each node is not addressed by its ID or IP address but by its geographic location. The routing decision is then based on the position of the node making the forwarding decision, the position of the destination node and the position of the neighbours of the forwarding node. The neighbour which is closest to the destination node is chosen as the next‐hop. As geographic routing heavily relies on the exact geographic position of the nodes, specialised hardware is required (e.g. GPS) and/or a localisation algorithm must be used. However, specialised hardware increases the price of the node, increases the energy requirements and is sometimes not very precise. Similarly, using localisation algorithms tends to lead to additional network traffic and may also be imprecise [57–59].
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Among others, Karp and Kung proposed Greedy Perimeter Stateless Routing (GPSR) [60], Kuhn et al. proposed Geometric Ad hoc Routing [61], and Yu et al. proposed Geographic and Energy Aware Routing (GEAR) [62], all of which implement greedy geographic routing. Even though this type of greedy routing works well under ideal conditions, it fails when a routing void is encountered. The routing void is a situation when there is no neighbour which is closer to the destination node. In practice, this situation is common when there is either an error in the localisation algorithm or a physical obstacle prevents radio communication between nearby nodes. Additionally, there is currently no practical way of porting geographic routing to the three‐dimensional space [63], for example, in a network deployed in a building or a tower.
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According to the survey on routing protocols in [56], GEAR outperforms GPSR in terms of the packet delivery; however, it scores only two points out of four for energy efficiency.
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3.2.2. Routing trees
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In networks where P2P communication is based on routing trees, the nodes are organised in one or several trees where each node stores its parent\'s ID only. The root of a tree is represented by a more powerful node storing connectivity information of the whole network. The packet is first routed to the root of a tree, where the central router computes the shortest path to the destination. The packet is then routed downwards towards the destination via this shortest path. The advantage of this approach is minimal memory requirements on the nodes and simplicity of the routing algorithm. The disadvantage is potentially high routing stretch, that is, the ratio between the length of the found path and the optimal one, and the requirement that the central router is aware of the whole network topology. Additionally, top‐level nodes may become overloaded by the network traffic, especially in large networks.
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To tackle some of the disadvantages mentioned above, several improvements to the routing trees have been introduced. The key improvements are based on storing meta‐data on the nodes within the network. Dedicated nodes store meta‐data about all nodes in a sub‐tree rooted in given node. Then, a node can decide to route a packet down a tree without forwarding it to the root node. In RPL, the base‐station holds a routing table for the whole network. However, any node in the network, provided it has enough memory, can store a routing table for a sub‐tree rooted in given node. These nodes are referred to as routing nodes. If a routing node receives a packet, it first checks its local routing table to see whether it contains a record for the destination. If so, the packet is forwarded directly to the destination. Otherwise, it is forwarded towards the root.
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Duquennoy et al. presented an opportunistic version of RPL called Opportunistic RPL (ORPL) [64]. Here, each node uses a Bloom filter [65] to store all node IDs from the sub‐tree rooted in a given node. Each node then uses the summary to decide whether the packet should be forwarded up towards the root of the tree or down the sub‐tree rooted in a given node. When the packet travels up the tree, it does not necessary follow the spanning tree. Any node which is closer to the root can opportunistically forward the packet. These two improvements can significantly lower the routing stretch. However, the possibility of a false positive in Bloom filters is the main disadvantage of this approach. In this case, a special algorithm is required which can recover from the situation when a packet is routed down the tree based on a false positive. The packet has to be sent to the root of the tree which can then find the correct path to the destination. This leads to unnecessary traffic and large routing stretch.
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Mihaylov et al. use a similar approach in their Innet algorithm [66], but, to reduce the routing stretch, they build up to three routing trees, each rooted in a different part of the network. Each node stores a summary for each sub‐tree rooted in given node. The search for the destination node is performed in all routing trees in parallel. Furthermore, to avoid the problem of false positives in Bloom filters, the packet is always also forwarded up, until it reaches the root of a tree. The packet stores the path it takes until it reaches the destination node. The destination node replies to the source node by reversing this path. As the reply packet travels back to the source node, each node uses several techniques to find a shortcut between the communicating nodes. Innet was designed to support long‐term communication, that is, the communicating peers exchange messages for a longer period of time. Therefore, the main goal of the algorithm is to minimise the routing stretch. The higher cost of the search phase is outbalanced by savings that could be achieved during the long‐term communication amongst the nodes.
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3.2.3. Hierarchical routing
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In hierarchical routing, each node is a part of multi‐level hierarchically organised clusters [63, 67]. At the lowest level 0, each node is a member of its own singleton cluster. Then, a neighbourhood of level 0 clusters is organised into level 1 cluster, which in turn are grouped into level 2 cluster, until all nodes are member of one (or very few) big cluster(s). At each level, a node is a member of exactly one cluster.
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At the centre of each cluster is a cluster‐head. At each level i the cluster‐head is advertised Ri hops away. The R depends exponentially on the level i. A node can be a member of a level i cluster if it is at most ri hops away from the cluster‐head, where ri≤Ri−1. In practice, usually Ri=2i and ri=⌊Ri/2⌋. Each node is addressable by concatenating the cluster‐head ID at each level (e.g. X.Y.Z, where node\'s ID is X, Y is a level 1 cluster‐head, and Z is a level 2 cluster‐head).
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The routing table, stored at each node, consists of entries for each cluster‐head the node received an advertisement from. Remember that each cluster‐head is at most Ri hops away at every level. Because the routing table is stored at every node, each node in a network acts as a router. When a node receives a packet, it tries to find the record in the routing table for the cluster‐head from the lowest level. For example, if the packet\'s destination is X.Y.Z, the node first tries to locate a record for X. If it is not found, it tries the same for Y, and Z, respectively. Because Z is the top‐level cluster, every node in the network will know a route to it. The packet is routed towards the first found record. Because ri≤Ri−1 it is guaranteed that as the packet is routed towards the level i cluster‐head, there will be a node on the path which knows the route towards the level i−1 cluster‐head. Therefore, the packet will eventually reach the destination node. In practice, hierarchical routing achieves relatively small average routing stretch of 25% [63]; however, additional network traffic is required to keep the routing tables updated.
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3.2.4. Ad hoc routing
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Unlike other routing algorithms, ad hoc routing does not require any global preparation phase during which the network is prepared for P2P communication. However, when a node needs to communicate with a peer, a path between the nodes must be established first. This is usually done by flooding the network with a request [68–70]. The request contains the source node ID, the destination node ID and a path taken by the request so far. Each node, unless the node is the destination that receives the request, adds itself to the path and re‐broadcasts the request. Once the destination node receives the request, it replies to the source node by reversing the path of relay nodes. The algorithm leads to discovery of the shortest path between two nodes.
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The disadvantage of this approach is a very expensive path discovery. As the whole network is flooded with a request, this results in poor energy efficiency. Even though other approaches like routing via trees also rely on path discovery, the search in those networks is more directed and does not flood the entire network.
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3.2.5. Routing based on routing tables
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Approaches based on routing tables first execute a learning or a bootstrapping phase during which every node learns routes to nodes that are of interest. For every node, two other pieces of information are usually stored: 〈distance,next_hop〉. As a distance, usually number of hops is used, but any other additive metric could be used. Once the bootstrapping phase is complete, each node can independently forward the packet using the locally stored routing table.
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Routing algorithms like RPL [23] use a subset of nodes to store the routing table and only for nodes that are in the sub‐tree rooted in a given node. Other approaches like Energy Aware Routing (EAR) [71] use a routing table to store several alternative routes to the base‐station so a node can choose alternative routes in order to better distribute network load. Kolcun et al. proposed Dragon [72], where every node in the network stores a path to every other node in the network. The platform also includes algorithms for quick update of the routing table in the case of a node failure while keeping the network overhead low.
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3.3. Dissemination protocols
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The purpose of dissemination protocols is to deliver information to either all or a subset of the nodes in the network. This type of communication is often referred to as a one‐to‐manycommunication pattern. Often the initiator of the communication is the base‐station when it wants to, for example, update the reporting interval. Because most of the collection protocols do not support one‐to‐one communication, dissemination protocols are also often used if a node wants to deliver a message to one particular node only, even at the expense of flooding the whole network.
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Two of the basic techniques used are flooding and gossiping [73]. While in the case of flooding each node just re‐broadcasts every message it receives, in the case of gossiping, a node upon receiving a message randomly chooses a neighbour to which it forwards the message. The disadvantage of flooding is the implosion and duplication of messages, while the disadvantage of gossiping is a possible large delay in propagation of the message.
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Heinzelman et al. proposed a family of Sensor Protocols for Information via Negotiation (SPIN) [74]. A node running SPIN, upon receiving a new message, broadcasts an advertising message containing meta‐data of the received message. Nodes which have not previously received the message reply with a request message. The node then broadcasts the data message to all the nodes that requested the data. SPIN can significantly decrease the network traffic by eliminating redundant data. However, SPIN cannot guarantee delivery of the message to all the intended recipients due to message loss and unreliable communication.
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Braginsky and Estrin proposed Rumor Routing (RR) [75] where nodes that wish to distribute information about a certain event generate special long‐lived packets called agents which are then gossiped through the network. Every node which receives an agent packet creates a record in its event table. Subsequently, if a node is interested in a given event, the node generates a query and uses the gossip protocol to propagate it through the network. Any node that has a record in its event table can forward the query to the node that holds the information about the event. Rumor Routing can significantly decrease the network traffic in cases where the number of events is small and the number of queries is large.
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Both SPIN and RR scored the lowest mark for energy efficiency—one out of four—in the survey on routing protocols [56], due to their low packet delivery rate and not being energy aware when disseminating the data.
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Levis et al. introduced probably the most popular dissemination protocol called Trickle [76]. It uses a ‘polite gossip’ policy where a node periodically broadcasts the message it wants to propagate, but stays quiet if it hears a message from a neighbour which is identical to its own. Because the time interval after the same message is re‐broadcast increases exponentially, each node hears only a small trickle of packets. The algorithm can achieve global dissemination of the message at a very low maintenance cost. Trickle facilitates the DRIP, DIP and DHV dissemination libraries available in TinyOS and is a key component of the CTP and RPL protocols.
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Kolcun et al. introduced the Static Attribute Propagation algorithm as a part of their Dragon platform [72]. The algorithm eliminates unnecessary re‐broadcasts of the message by overhearing the messages of its neighbours. It relies on the knowledge of a list of common neighbours at every node. A node upon receiving a message sets up a random timer. While waiting, the node overhears all its neighbours broadcasting the message. Upon expiration of the random timeout, the node checks whether the set of neighbours which broadcast the message cover all the nodes neighbours. If so, the message is discarded, and otherwise, the node broadcasts the message. This approach can significantly decrease the network traffic, especially in dense networks where the number of common neighbours is high.
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3.3.1. Special case: low‐power wireless bus
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The low‐power wireless bus (LWB) is a special case that considers multiple traffic patterns, including one‐to‐many, many‐to‐one and many‐to‐many traffic by exploiting the aforementioned Glossy mechanism to facilitate efficient and reliable floods [77]. It uses time synchronisation to manage access to the bus, where a global communication schedule is maintained (computed online based on immediate traffic) and flooded periodically to nodes (thus avoiding relative clock drift). The authors demonstrate that the LWB is comparable to or outperforms a number of state‐of‐the‐art stacks with regard to many‐to‐one (i.e. collection) traffic, adapts well to varying traffic volumes, significantly outperforms contemporary approaches in terms of many‐to‐many, is robust to inference and intermittent node participation, and supports mobile nodes as source or sink network devices (Table 2).\x3c!--
Please check the suggested in-text citation for Table 2.
With arrival of IPv6, researchers set about implementing it for sensor networks. This was met with several challenges. Because the main usage domain of IPv6 is Ethernet, to cope with increased Internet traffic, the maximum transmission unit (MTU) was increased from 576 to 1280 bytes, when compared to IPv4. IPv6 addresses are 128‐bit long, and the standard IPv6 header size is 40 bytes. This is in strict contrast with the IEEE 802.15.4 standard whose throughput is limited to 250 kbps and the length of the frame to 127 bytes. The standard supports two addresses: short 16‐bit and EUI‐64 extended addresses. With link headers included, the effective size of the payload could be as small as 81 bytes, which make IPv6 headers seem too large.
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In 2007, Mulligan and an Internet Engineering Task Force (IETF) working group published a proposal on how to transfer IPv6 packets in low‐rate wireless personal area networks. A new protocol called 6LoWPAN [79] was introduced. The aim of the working group was to define a stateless header compression that would decrease the header size so it can be used with the IEEE 802.15.4 standard. The reduction was achieved by introducing four basic header types: (i) Dispatch Header, (ii) Mesh Header, (iii) Fragmentation Header and (iv) HC1 Header (IPv6 Header Compression Header). 6LoWPAN implements variable‐sized headers, where the header size varies from 4 to 13 bytes, depending on what kind of communication is required. The protocol is also prepared to support new types of headers in the future.
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When an address needs to be included in the header, 6LoWPAN supports either 16‐bit short addresses or full 64‐bit addresses. These addresses are then translated to full 128‐bit IPv6 addresses by a border router. The border router is a router that enables communication between a WSN and the Internet.
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If a node needs to send a packet whose size is larger than the size of the payload of 802.15.4 frame (107 bytes), 6LoWPAN defines a fragmentation header which allows the node to split the original datagram into several packets. The header includes the size of the original datagram as well as the ordering number. Fragmentation is also necessary as the specification of IPv6 requires support of a minimum MTU of 1280 bytes.
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6LoWPAN supports two types of routing: (i) mesh‐under and (ii) route‐over. In the mesh‐under approach, routing is done by the link layer (layer two) using IEEE 802.15.4 frame or 6LoWPAN header. To send a packet to a destination node, EUI 64‐bit or 16‐bit short addresses are used to forward the packet to the next‐hop neighbour, preferably closer to the destination. To complete a single IP hop multiple link layer hops may be required. If an IP packet is fragmented into several fragments, these fragments may travel over different paths. The packet is reassembled at the final destination only. The advantage of mesh‐under is that the forwarding nodes do not need to reassemble the whole packet to make the routing decision which lowers the memory requirements. Additionally, because the packets may travel via different paths, mesh‐under can increase throughput and lower the congestion of the network. On the other hand, if the destination node is missing, a fragment of the IP packet, the whole packet (i.e. all fragments) needs to be resent.
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In the route‐over approach, the routing decision is done on the network layer (layer 3) and each node acts as an IP router. Each link/hop is considered to be an IP hop too. If a packet is fragmented, then all fragments are first reassembled on the next hop neighbour and the packet is passed to the network layer. The network layer decides whether the packet should be processed on the node or forwarded to a neighbour. To make this decision, the node has to either store the routing table which maps the destination address to the next‐hop address or the packet itself has to contain this information. In route‐over approach, each node must have enough memory to reconstruct the packet, and all fragments are routed via one path only. On the other hand, if a fragment is lost during the transmission, the whole IP packet must be resent over one link layer hop only.
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Recalling Figure 1, a full stack implementation requires some higher and lower layer primitives. At the application layer, the IETF has worked to standardise the so‐called Constrained Application Protocol (CoAP), which is essentially a RESTful (Representational State Transfer) protocol that uses a small subset of HTTP commands, and more recently TSCH at the link layer, detailed earlier. To‐date, there are no comprehensive evaluations of the energy performance of the entire stack. However, there are several which evaluate snapshots of the stack, or subsets thereof (e.g. by layer), such as in the case of CoAP in [80], where the authors show that CoAP is efficient when implemented over RPL, 6LoWPAN and ContikiMAC (and reiterate that the key efficiencies are to be gained at the link layer), and 6TiSCH [81], where a realistic energy model presented for TSCH demonstrated that under certain conditions, sub‐1% duty cycles are demonstrable for real and simulated networks under reasonable traffic loads.
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4.2. Composable stacks
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Many of the protocols described thus far have open source, modular implementations available in the libraries of the various operating systems. Therefore, they can easily be composed to suit an intended application scenario. We know that performance and appropriate selection depend on application level requirements and statistical properties of the network traffic generated by that application. Therefore, there are very few studies that explore in‐depth full‐stack implementations on per‐application bases. However, there are a number well‐documented implementations that comparatively evaluate performance such as in [77], where the authors compare the performance of LWB against Dozer (a highly efficient TDMA‐based data collection protocol) [82], CTP+A‐MAC and CTP+LPL, under a variety of conditions. CTP+A‐MAC, LWB and more recently Chaos [78] are representative state‐of‐the‐art stacks from the research community that rival the standards‐based stacks which tend to adopt something very similar to the 6TiSCH approach (Figure 1), for example. While many of the protocols described so far have been implemented in the longer‐standing operating systems developed in the research community, a number of more recent such operating systems have emerged, such as OpenWSN—https://openwsn.atlassian.net/wiki/, and RIOT—https://www.riot‐os.org/#features, which provide implementations of the standardised stack for a variety of recent hardware development platforms.
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4.3. Energy analysis
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One of the most comprehensive evaluations of a relatively complete stack is presented in [44], where CTP is run on a number of heterogeneous test‐beds, over a number of link layers, for a variety of inter‐packet intervals (typically determined by the application scenario) and at a variety of radio frequencies on various channels. While the evaluation shows that the combination of beaconing and data path validation used in its design is robust over a variety of physical and link layers, the performance characteristics still do not quite meet those needed for ultra‐long‐lived, large (i.e. extremely dense) and highly reliable applications. The authors also leave open the question of whether these methods are suitable for distance vector algorithms synonymous with ad hoc networking.
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Generally speaking, it is extremely difficult to validate or comparatively evaluate the energy performance of a protocol stack relative to another. The use of simulators and non‐standard test facilities (e.g. community‐known test‐beds set‐up with arbitrary configurations) contribute to this problem. This could be mitigated against by having a set of standard simulation and test‐bed configurations against which to benchmark protocols at each layer, and in combination. This has been recently alluded to in the literature in [83], wherein the authors conclude that there is insufficient knowledge available for a majority of the community when it comes to trialling experiments on real‐world facilities such that they can be trustworthy, reproducible and thus independently verifiable.
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5. Conclusion and future directions
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Practical, energy‐efficient wireless communications protocols have been comprehensively studied and documented in the literature in the preceding decades. We have presented a comprehensive summary review of the state‐of‐the‐art concerning link and routing layer technologies developed during this period suitable for constrained wireless sensor network, IoT and CPS applications.
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A great deal is known about their limitations and the trade‐offs inherent in their selection and implementation. It is arguable that fundamental performance limits have been reached in the design of link layer technologies for contemporary radio transceivers. For this reason, and understanding the time‐varying nature of the wireless medium, routing protocols are being developed by the standards bodies that take into account lower layer parameters in their design (e.g. IEEE 802.15.5). These may include link quality, residual energy and dynamic energy availability in the case of energy harvesting devices.
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Devices are incrementally more efficient, and their inter‐networking based on link and routing layer technologies is maturing to the point where protocols can confidently be selected where certain performance requirements must be satisfied. We tend to readily trade energy efficiency against reliability and determinism for industrial and high‐criticality applications. This is problematic, however, because many potential application scenarios are dismissed as economically infeasible due to high network maintenance costs. Simultaneously, as devices and protocols maximise efficiency, the gap with feasible energy harvesting from devices’ ambient environments is reducing. Coupled with other techniques and technologies, like compressive and predictive sensing, ultra‐low power wake‐up radio circuits and so on, there is an emergent design space—where applications can be holistically co‐designed with regard to energy. It is almost certain that such approaches will be investigated in the short to medium term, which will result in the economic feasibility of a range of new connected monitoring and control applications.
\n',keywords:"Internet of Things, sensor networks, energy efficiency, communications protocols",chapterPDFUrl:"https://cdn.intechopen.com/pdfs/53177.pdf",chapterXML:"https://mts.intechopen.com/source/xml/53177.xml",downloadPdfUrl:"/chapter/pdf-download/53177",previewPdfUrl:"/chapter/pdf-preview/53177",totalDownloads:1945,totalViews:716,totalCrossrefCites:4,totalDimensionsCites:6,totalAltmetricsMentions:0,impactScore:2,impactScorePercentile:74,impactScoreQuartile:3,hasAltmetrics:0,dateSubmitted:"May 18th 2016",dateReviewed:"September 27th 2016",datePrePublished:null,datePublished:"March 22nd 2017",dateFinished:"November 26th 2016",readingETA:"0",abstract:"This chapter describes the evolution of, and state of the art in, energy‐efficient techniques for wirelessly communicating networks of embedded computers, such as those found in wireless sensor network (WSN), Internet of Things (IoT) and cyberphysical systems (CPS) applications. Specifically, emphasis is placed on energy efficiency as critical to ensuring the feasibility of long lifetime, low‐maintenance and increasingly autonomous monitoring and control scenarios. A comprehensive summary of link layer and routing protocols for a variety of traffic patterns is discussed, in addition to their combination and evaluation as full protocol stacks.",reviewType:"peer-reviewed",bibtexUrl:"/chapter/bibtex/53177",risUrl:"/chapter/ris/53177",book:{id:"5350",slug:"ict-energy-concepts-for-energy-efficiency-and-sustainability"},signatures:"David Boyle, Roman Kolcun and Eric Yeatman",authors:[{id:"191964",title:"Dr.",name:"David",middleName:null,surname:"Boyle",fullName:"David Boyle",slug:"david-boyle",email:"david.boyle@imperial.ac.uk",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:null}],sections:[{id:"sec_1",title:"1. Introduction",level:"1"},{id:"sec_1_2",title:"1.1. Wireless communication",level:"2"},{id:"sec_1_3",title:"1.1.1. Communications protocol suites",level:"3"},{id:"sec_3_2",title:"1.2. Hardware",level:"2"},{id:"sec_5",title:"2. Energy‐efficient medium access control",level:"1"},{id:"sec_5_2",title:"2.1. Standards and evolution",level:"2"},{id:"sec_6_2",title:"2.2. Design trade‐offs",level:"2"},{id:"sec_8",title:"3. Energy‐efficient networking, data collection and dissemination",level:"1"},{id:"sec_8_2",title:"3.1. Data collection",level:"2"},{id:"sec_9_2",title:"3.2. Peer‐to‐peer routing",level:"2"},{id:"sec_9_3",title:"3.2.1. Geographic routing",level:"3"},{id:"sec_10_3",title:"3.2.2. Routing trees",level:"3"},{id:"sec_11_3",title:"3.2.3. Hierarchical routing",level:"3"},{id:"sec_12_3",title:"3.2.4. Ad hoc routing",level:"3"},{id:"sec_13_3",title:"3.2.5. Routing based on routing tables",level:"3"},{id:"sec_15_2",title:"3.3. Dissemination protocols",level:"2"},{id:"sec_15_3",title:"Table 2.",level:"3"},{id:"sec_18",title:"4. Full stack implementations",level:"1"},{id:"sec_18_2",title:"4.1. IPv6 over LR‐WPAN",level:"2"},{id:"sec_19_2",title:"4.2. Composable stacks",level:"2"},{id:"sec_20_2",title:"4.3. Energy analysis",level:"2"},{id:"sec_22",title:"5. Conclusion and future directions",level:"1"}],chapterReferences:[{id:"B1",body:'L. Gu and \x3c!--
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'}],footnotes:[{id:"fn1",explanation:" Full coverage of wireless communication fundamentals is available in [15]."},{id:"fn2",explanation:" The practical implementation of a protocol suite is typically referred to as a ‘stack’."},{id:"fn3",explanation:" RPL is in fact designed to support any-to-any communication; however, very little work has been done in this regard, with early evaluations suggesting that it is not ready for actuation-type messages [45]."}],contributors:[{corresp:"yes",contributorFullName:"David Boyle",address:"david.boyle@imperial.ac.uk",affiliation:'
Department of Electrical and Electronic Engineering, Imperial College London, England
Department of Electrical and Electronic Engineering, Imperial College London, England
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1. Introduction
Photodetectors (PDs) are the photonic devices that convert an incoming light signal into an output electrical signal. High-performance PDs are crucial for the advancements in the industrial and scientific communities, and these are being extensively used in areas such as video imaging, space and optical communications, flame detection, photovoltaic applications, environmental monitoring, and so on [1, 2, 3, 4, 5]. Some of the most extensively employed inorganic semiconductors for the development of PDs are zinc oxide (ZnO) [6], gallium arsenide (GaAs) [7], indium gallium antimonide (InGaSb) [8], germanium silicide (GeSi) [9] and gallium oxide (Ga2O3) [10], due to their excellent electronic properties like high charge carrier mobility and high light absorption coefficients. However, large exciton binding energies, low values of responsivity, slower response and narrow-band detection are some of the major downsides associated with these materials [11]. Moreover, the synthesis as well as post-processing steps in the fabrication of antimony and arsenic-based devices involves toxic precursors as well as products, which are extremely hazardous for human health and for the environment as well. Thus, the quest is on for the development of high-performance PDs consisting of environment-friendly constituents.
The recent developments in the III-Nitride semiconductors-based devices have made a tremendous impact upon a number of technological areas such as information storage, lighting and full color displays, underwater and space communications, high-power and high-frequency electronic devices, photovoltaics, sensors and detectors, and so on [12, 13, 14, 15]. The wurtzite polytypes of indium nitride (InN), aluminum nitride (AlN), and gallium nitride (GaN) have proved to be excellent semiconductors for band gap engineering, due to formation of continuous range of alloys with direct and tunable band gaps in the range of 0.7 to 6.2 eV [16]. Therefore, their intrinsic physical and chemical properties along with intense technological efforts have made the realization of versatile and reliable detectors in the entire ultraviolet (UV)-visible–near infrared (NIR) spectrum.
In spite of the significant progresses, the growth of epitaxial group III-Nitride thin films for practical devices, having low defect densities, has always been a challenge due to the lack of availability of lattice matched substrates. As of now, among various epitaxial growth techniques for III-Nitrides, plasma assisted molecular beam epitaxy (PAMBE) has emerged as the most versatile and environment-friendly synthesis technique, involving low growth temperature, controlled growth rates which result into the formation of heterostructures with sharp interfaces, and non-hazardous precursors and by-products. Since pristine III-Nitride substrates are immensely costly and therefore, not yet available for research and industrial purposes, the development of this family of semiconductors proceeds entirely by the heteroepitaxial growth on various foreign substrates such as sapphire, Si (111) and 6H-SiC [16, 17, 18], and one has to often compromise with the device performance. It may be noted here that hybrid structures of III-Nitrides with other semiconductors such as ZnO, perovskites, and two-dimensional (2D) layered materials such as MoS2 are expected to deliver competitive device performance as compared to the commercial PDs ( [19, 20, 21]. In the forthcoming sections, we discuss about the figures of merit involved in the evaluation of a PD, followed by a brief overview of III-Nitrides and their properties. Then, a detailed analysis about the recent advancements in the MBE-grown III-Nitrides for photodetection application has been presented and finally, we wind up by discussing the unresolved difficulties and propose an outlook in this developing field of optoelectronics.
2. Basic concepts about photodetection
A PD is a sensor that detects an incoming electromagnetic radiation. Whenever light waves of energy greater than or equal to the band gap of a semiconductor are absorbed, there is an overall change in the conductivity of the semiconductor. Thus, PD is a device developed on the principle of this photoconducting effect and it quantifies the speed and the amplitude of the change in the conductivity, in respect of incoming electromagnetic radiations.
2.1 Important figures of merit of a PD
Several figures of merit and parameters are used for the evaluation of a PD, and these performance metrics allow us to compare various devices. Mostly, the output electrical signal is recorded from the device and realized in the form of an output photocurrent, and thus, all the key figures of merit are defined in terms of this output photocurrent. The output photocurrent (IP) is defined [11] as
IP=IIlluminated−IDarkE1
whereIIlluminatedis the output current detected upon light illumination and IDark is the dark current in the device (i.e. without any light illumination). Photocurrent can be enhanced by reducing the probability of recombination of photogenerated electrons and holes, and this can be achieved by fabricating high-quality and defect-free devices, using heterojunctions with type-II band alignment which result into the effective separation of charge carriers. Devices utilizing p-n junctions which operate in reverse bias, usually show a large photocurrent due to the enhanced carrier separation as well as lower dark current.
2.1.1 Responsivity
Responsivity (Rλ) is defined as the ratio of the photocurrent generated and the incident optical power of a specific wavelength on a predefined device area. It is given [11] by the following mathematical formula
Rλ=IPP×AE2
where P is the incident power density of light and A is the device area where light is being illuminated. Its units are AW−1. It quantifies the extent of achievable electrical signal in a PD when illuminated by a light of certain power density. Thus, a larger responsivity signifies a larger electrical output signal for a specific optical excitation power. Replacing a single material-based or homojunction-based device with heterojunction-based devices with type-II band alignment is an effective way to enhance the responsivity due to minimized recombination of photogenerated electrons and holes [22]. Another approach is to promote devices which possess a strong built-in potential that supports the external electric field to enhance the carrier separation and transport [15]. Growth of high-quality crystals reduces the defect density present in the system, thereby suppressing the scattering and recombination of the charge carriers which enhances the responsivity of the device. Manohar et al. [6] recently demonstrated a highly cost effective and an elegant method to immensely enhance the photoresponsivity of a PD by suppressing the carrier recombination through coatings of different materials which facilitate either electron or hole transfer to the metal contacts.
2.1.2 Specific detectivity
A fundamental performance parameter for a PD is its specific detectivity, that measures the ability of a PD to detect weak light signals. For a PD, this metric can be defined in terms of the noise equivalent power (NEP). The NEP of a PD is proportional to the ratio of the square root of the dark current (IDark) to the responsivity (Rλ) of the PD at a given wavelength. It can be defined by the following relation:
NEP=√2∗e∗IDarkRλE3
where e is the electronic charge. The specific detectivity (D∗) of a PD is defined as the ratio of the square root of the active area (A) to its NEP [4], and is given by the following equation
D∗=√ANEPE4
It is measured in Jones. Higher detectivity of a PD indicates that even a very weak signal can be detected. It may be noted that lower is the dark current, higher is the detectivity. PDs based on p-n junctions operated in the reverse bias generally exhibit very high specific detectivities because of low values of dark current.
2.1.3 Internal gain
The internal gain (G) of a PD refers to the number of electrons collected at the electrodes per incident photon. It can be determined [4] by the following relation
G=hc∗RληeλE5
whereh, c, η and λ are the Planck’s constant, the velocity of light in vacuum, the EQE of the device and the illumination wavelength, respectively.
In other words, internal gain is the ratio of the hole carrier lifetime to the electron transit time and is given [4, 10] by
G=τ/tE6
where τ is the mean hole carrier lifetime and t is the electron transit time. So, high internal gains can be achieved by fabricating devices which exhibit high responsivities. Another approach to enhance gain is by trapping one kind of charge carrier (generally holes), so as to prevent it from recombination. Thus, the carrier lifetime of the holes increases and in turn gain increases.
2.1.4 Sensitivity
Sensitivity (S) of a PD is defined [23] as the ratio of the photocurrent to the dark current.
S=IPIDarkE7
Hence, sensitivity can be improved by either enhancing the value of photocurrent or lowering the dark current. The enhanced photocurrent can be achieved by fabricating high quality and defect-free interfaces and devices, thus, reducing the scattering effects of the photogenerated electrons and holes, and leading to higher photocurrents. Devices consisting of p-n junctions show ultralow values of dark currents exhibiting higher sensitivities.
2.1.5 Response/recovery time
An important aspect of a PD is how fast it detects the incident light, and how fast it comes back to its initial state once the incident light is removed. This is quantified by estimating the response/recovery times of the PD. Lower the values of these time constants, faster is the detection process. Mukhokosi et al. [23] have demonstrated that the response times of a PD are controlled by the carrier mobilities of the constituent semiconductors of the PD. The transit time (τtransit) of a p-n heterojunction is given [23] by the following relation
τtransit=Wvdrift=WμdriftEoE8
whereWis the depletion region width, μdrift is the carrier mobility and Eo is the built-in electric field at the junction. Therefore, high-quality substrates with high carrier mobilities such as p-Si, usually result into very small response time. The depletion width can be narrowed down by fabricating highly doped p-n junctions, which in turn decreases the transit time in accordance with Eq. (8).
Other parameters that affect the response speed of a PD are the junction capacitance (C) and the series load resistance (R), and thus, the corresponding RC time constant. The rise time of a PD with an RC circuit is given by:
τr≅2.2RCE9
Therefore, decreasing the junction capacitance can further improve the response time. The junction capacitance depends on the width of the depletion layer, and smaller depletion widths increase the capacitance. Therefore, the width of the depletion region should be optimum to minimize the carrier transit time.
In addition, defect-free semiconductors exhibit faster response times, because of reduced recombination of the photogenerated carriers. For the case of linear devices, high-quality photosensitive materials as well as defect-free semiconductor/electrode interfaces are required to minimize the carrier scattering and recombination processes, and result into the lowering of the carrier transit time.
2.1.6 Power consumption
One of the most critical parameters associated with a PD is its power consumption. Generally, PDs require an external power source as the driving force to separate the photogenerated electrons and holes efficiently. Thus, a lot of external energy is required in a system that consists of several such detectors. Therefore, it is a big concern in the present energy scenario. Hence, a lot of research is being focussed these days on achieving self-powered or zero-biased PDs [24, 25], which utilize a built-in electric potential for the effective charge carrier separation. The extensively used technique for fabricating self-powered PDs is by utilizing a p-n junction, where a strong electric field is created at the interface, and therefore, the device can operate in zero-bias mode.
2.1.7 Spectral range
Another crucial aspect of PDs is their detection range. PDs are generally classified into two categories based on their spectral range of detection: broad-band (which shows a considerable detection to a wide range of wavelengths) and narrowband or wavelength-selective (whose detection range is very limited) PDs. The most common way to fabricate a wavelength-selective PD is by using a single semiconductor (of desired band gap) as the active material in the device. Another way to achieve wavelength selectivity is by integrating an optical microcavity within the PD. This optical microcavity consists of distributed Bragg reflectors (DBR), which allow multiple reflections of a specific wavelength. These reflections interfere constructively, leading to increased light-matter interactions and result into the enhancement of photocurrent. This occurs only at the design wavelength of the cavity, whereas all the off-resonance wavelengths incident on the PD are rejected by the cavity. On the other hand, broad-band photodetection can be realized by making heterojunctions-based devices consisting of different semiconductors of appropriate band gaps, as demonstrated by Singh et al. [26] by making a hybrid device based on SnS2/p-Si heterojunction, which shows a broad-band response in the entire ultraviolet to near infrared range. Usually, conventional PDs suffer from the trade-off between selective and broad-band detection. Recently, a few devices have been reported to exhibit a unique feature wavelength-selectivity in a broad-band spectral response, through the phenomenon of polarity switching [27, 28].
2.2 Different mechanisms of photodetection
PDs rely on distinct sensing mechanisms depending upon the intrinsic properties of the photosensitive materials used as well as the architecture of the device structures. We now briefly discuss the most commonly adopted sensing mechanisms.
2.2.1 Photoconductive and photogating effects
The photoconductive effect involves photogeneration of excess free carriers in a semiconductor material, when photons with energy higher than the band gap of the semiconductor are absorbed, which eventually leads to a change in its electrical conductivity. The photoconductive effect is the most primitive form of photodetection, where two Ohmic contacts are deposited on the semiconductor surface to form a metal–semiconductor–metal (MSM) type linear device configuration [29]. The schematic of a PD depicting the process of photoconduction is shown in Figure 1(a). It is important to note that this change in conductivity is a result of the change in the free charge carrier concentration due to the photogeneration process. Thus, the effective spectral range of photoconductive PDs is limited by the band gap of the semiconducting material or the photoactive layer. Additionally, a photoconductive PD usually requires an externally applied voltage for the effective separation and the directional propagation of the photogenerated carriers. This generally results in relatively larger values of the dark current, which leads to a lower on/off ratio and higher energy consumption. Additionally, conventional photodiodes (non-linear devices) also work in the photoconductive mode when operated in the reverse bias condition.
Figure 1.
Schematic view of (a) a photoconductor depicting the process of electron–hole pairs generation and their transport and (b) a PD based on the photogating effect under illumination. The defect states capture electrons which eventually modulates the conductivity of the material.
Photogating effect is a type of photoconducting effect, wherein certain localized states such as defects or surface states exist within the forbidden gap of the semiconductor. The effect normally originates when the photogenerated charge carriers are captured by the localized trapping states present within the system [30] as depicted in Figure 1(b). This effect is pronounced in low-dimensional material systems such as 2D layered materials and quantum dots, which have very large surface-to-volume ratio and less screening in the z-direction. Since one type of charge carriers are trapped, it leads to prolonged carrier lifetimes, and therefore, PDs which exhibit the photogating effect usually show higher photogains. In addition, faster transit times and enhanced photocurrent is observed due to suppressed carrier recombination.
2.2.2 Photovoltaic effect
Photovoltaic effect is the phenomenon of spontaneous generation of a photocurrent upon light illumination in a PD. This effect is generally realized in p-n junction-based devices, where a built-in electric potential exists at the interface [31]. Upon light illumination, electrons and holes are created near the semiconductor interface. Under the influence of the existing built-in voltage, these electrons and holes get separated, thereby, causing a photocurrent to flow along the direction of this built-in potential (Figure 2). The photovoltaic effect is closely related to the photoelectric effect and therefore, the effective wavelength range is usually limited by the band gap of the constituent photosensitive material. However, in the case of p-n heterojunctions, due to the intimate energy band coupling that enables interband transition between different semiconductors, the effective detection range can be modulated beyond the limitation of the band gaps. The biggest advantage associated with PDs based on the photovoltaic effect is that due to the intrinsic built-in electric potential, the PDs do not require any external power for their operation [11]. Furthermore, the photovoltaic PDs possess low dark current under the zero-biased working mode, which is beneficial for the detector.
Figure 2.
Schematic depicting the photovoltaic effect.
2.2.3 Photothermoelectric effect
The origin of photothermoelectric (PTE) effect is the temperature gradient (ΔT) developed due to the thermal effects of the light illumination. Subsequently, a potential gradient (ΔVPTE) is created that serves as the driving force for the transport of the photocurrent through the device (Figure 3). The thermoelectric voltage generated is given [32] by
Figure 3.
(a) Schematic of a PTE based device illuminated locally by focused light. An open circuit voltage which is equal to the thermoelectric voltage ΔVPTE gets developed across the electrodes. (b) Thermal circuit equivalent to the device depicted in (a). Figure is reproduced with permission from Ref. [33].
ΔVPTE=SΔTE10
where S is Seebeck coefficient of the material [33]. PTE effect-based PDs can operate without external power, i.e. they are self-powered in nature. However, the thermoelectric potential created is very low, generally in the range of millivolts (mV) and microvolts (μV), which seriously limits the popularization and hence, wide scale applications of PTE-based PDs.
2.2.4 Piezophototronic effect
The devices that make use of the piezo-potential of the constituent materials for controlling the carrier generation and transport, for improving the overall performance of the opto-electronic devices are referred to as piezophototronic [32]. The basic requirement of such devices is a piezo-electric material such as ZnO, GaN, etc. which can produce an electric potential upon variations in the applied stress. The operational mechanism of a piezophototronic device is based upon the fundamental principles of the conventional Schottky contacts and p–n junctions. Ionic charges are introduced by the effect of piezoelectric polarization, which tune the charge transport at the junction. The effect of piezophototronicity on a p-n junction (GaN/MoS2 in this case) under compressive strain is shown in Figure 4(a). When the [0001]-oriented GaN film is under a compressive strain, negative piezopotential is produced inside GaN. This results into the lowering of the junction barrier. Therefore, more photogenerated charge carriers can cross the junction [34]. Hence, the photoresponsivity gets enhanced. An opposite effect (positive piezopotetial in GaN film, which increases the junction barrier) is observed in the case of applied tensile stress.
Figure 4.
(a) Piezophototronic enhancement observed in p-GaN/n-MoS2 heterojunction. When the [0001]-oriented GaN film is compressed, negative piezoelectric charges develop in the GaN film near the interface, and the junction barrier gets lowered. This allows a greater number of carriers to pass through the junction. Figure is reproduced with permission from Ref. [34]. (b) Schematic depicting bolometric effect. The red shaded region indicates elevated temperature with the temperature gradient (ΔT) and ΔR denotes the resistance change across the channel. Figure is adapted from Ref. [35].
2.2.5 Photobolometric effect
Photobolometric effect is the alteration in the electrical resistance of a material, which is induced by the heating effect of uniform light illumination [32]. Typically, the active material layer absorbs the incident photons and then converts them into heat energy. The extent of this effect is proportional to the conductance change in the photoactive material with temperature (dG/dT) as well as the homogeneous temperature change (ΔT) induced by light illumination (Figure 4(b)). The change in conductance is influenced by change in the charge carrier mobility of the material because of the induced temperature change. Photobolometric effect generally occurs in the wavelength range of mid-infrared to far-infrared. Additionally, similar to PDs based on photoconductive effect, photobolometric PDs also require an external power source, which differentiates them from the PTE-based PDs.
3. Group III-Nitride semiconductors
From the early decades, silicon has been considered as one of the major components in the semiconductor industry because of its unique properties. Later, III-V materials, particularly the arsenic based compounds, gained much attention because of their superior properties such as high electron mobility, direct and tunable band gap, etc. The group III-Nitrides came into the picture around 1960s, and active research on this material system started with the development of blue light emitting diodes. Over the time, much of the attention of the researchers and scientists has been diverted on different classes of materials. However, group III-Nitride semiconductors continue to maintain their stronghold due to the exceptional properties and the unique advantages they offer.
3.1 Crystal structure and optical properties of group III-Nitrides
Group III-Nitride semiconductors, mainly comprising of AlN, GaN and InN, exist in three different crystal structures, namely, wurtzite, zincblende and rocksalt. Among these, the most stable and the lowest energy structure is the wurtzite system [36]. The wurtzite structure has a hexagonal unit cell and contains six atoms of each type, with space group P63mc. The wurtzite polytype is made up of two interpenetrating hexagonal close-packed unit cells, each containing one type of atom, and with an offset along the c-axis by 5/8 of the cell height. The stacking sequence in the hexagonal structure consists of alternating hexagonal planes of group III and N atom, with a stacking sequence of ABAB [36]. A stick-and-ball model-based diagram of the hexagonal unit cell of III-Nitride semiconductors is shown in Figure 5. The group III semiconductors and the nitrogen atoms have been shown in different colors [37]. The polytypes of the III-Nitrides having wurtzite structure, form a continuous alloy system, with direct band gaps ranging from 0.7 eV for InN, 3.4 eV for GaN, and to 6.2 eV for AIN [16]. Therefore, the III-Nitrides are potential candidates for fabrication of optical devices which are active at wavelengths ranging from the NIR to the UV.
Figure 5.
The wurtzite crystal structure of III-nitrides. Nitrogen and group III atoms are represented by gray and yellow spheres, respectively. Figure has been reproduced with permission from Ref. [37].
3.2 Growth of group III-Nitride semiconductors
The first successful synthesis of GaN dates back to as early as 1930s. In 1969, Maruska and Tietjen [38] synthesized single crystalline GaN layers on sapphire substrates by using the technique of hydride vapor phase epitaxy (HVPE). Although most of the III-Nitride semiconductors, especially for industrial-scale production, are usually synthesized via metal–organic chemical vapor deposition (MOCVD), metal–organic vapor phase epitaxy (MOVPE) and HVPE, however, these techniques have some serious drawbacks associated with them. These fabrication methods are generally characterized by quite high growth temperatures (>900°C). Thus, the sample is subjected to a high level of stress when cooled down to the room temperature from such high temperatures. Moreover, the inevitability of such high temperatures has hindered the growth of high-quality InN and its alloys, which are potential candidates for IR and terahertz (THz) optoelectronic applications, due to the dissociation of InN at such high temperatures [16]. There are also various other less-known techniques used for the synthesis of the group III-Nitrides, which are derivatives of the above three methods. However, all these processes involve the treatment and usage of toxic precursors as by-products, and therefore, making these techniques less environment-friendly and hazardous to human health, which has become a major concern at the global level.
PAMBE, on the other hand, is a much cleaner synthesis technique and offers the advantage of fabrication of better-quality samples, along with a very important benefit of growth at much lower substrate temperatures when compared with most of its counterparts. MBE is an epitaxial and layer-by-layer growth technique involving precise control of the supply of thermally evaporated atomic species (Figure 6(a)). This results into construction of 2D layers on a substrate by means of lattice matching (Figure 6(b)). The major advantages of MBE are that it is clean, scalable and highly controlled with a high product quality. The involvement of ultra-high vacuum growth environment and the use of ultra-high purity elements as the source materials, minimize the inclusion of contaminants and impurities in the grown structures. Additionally, with the advent of higher growth rate RF-plasma sources, the synthesis times have been significantly reduced without compromising in the structural quality. One of the earliest works demonstrating growth of GaN by MBE was reported by Yoshida et al. [39] in 1983, wherein they successfully synthesized high electrical and optical quality GaN thin films on sapphire, with an AlN buffer layer via reactive MBE using ammonia as nitrogen source. Figure 6(c) shows the MBE setup located in Materials Research Centre, Indian Institute of Science, Bangalore, India.
Figure 6.
(a) Schematic of a typical MBE system, showing various components. Figure has been adapted with permission from Ref. [40]. (b) Schematic depicting epitaxial growth of a material on a substrate. (c) MBE system located in materials research Centre, Indian Institute of Science, Bangalore, India.
3.3 Approaches to improve device performance of group III-Nitride semiconductors-based PDs
Researchers across the world have employed various approaches to improve the performance of the III-Nitrides-based devices. These include improvement in growth quality by the employment of different growth techniques, adopting novel growth methods like epitaxial lateral overgrowth (ELO), using different materials as buffer layers such as AlN, and by fabricating improved structures to reduce defects. Another way to improve the growth quality of III-Nitrides is to find the alternatives to conventional silicon and sapphire substrates. In this regard, transition metal dichalcogenides, having a small lattice mismatch with III-Nitrides, can be used as potential substrates. Engineering the device structures can also result into the improvement of the device performance, and this can be achieved by making quantum confinement architectures, and by making hybrid structures using 2D materials like graphene and MoS2.
4. Recent advancements in the MBE grown III-Nitrides-based PDs
In the preceding sections, we have focused on the important figures of merit of PDs along with the different mechanisms of photodetection, and the properties and growth methods for group III-Nitride-based devices. Numerous reports exist which demonstrate the photodetection properties of III-Nitrides-based PDs. The recent state-of-the-art III-Nitride-based PDs have been discussed wherein a special emphasis on self-powered photodetection has been given.
4.1 III-Nitrides-based devices
Some early accomplishments in the field of GaN-based PDs grown by MBE have been achieved by several researchers such as Van Hove et al. [41], Son et al. [42], Torvik et al. [43], Osinsky et al. [44], Xu et al. [45], and so on. In 2005, Calarco et al. [46] reported the electrical transport of GaN nanowhiskers grown by MBE, in dark and under UV illumination. The photoresponse has been found to be sensitively dependent on the column diameter of the nanowhiskers and this effect has been quantitatively described through a mechanism of size dependent surface recombination. Jain et al. [47] have shown the effect of symmetric and asymmetric contact electrodes on c-GaN/sapphire based UV PD. In 2018, Goswami et al. [48] reported the growth of self-assembled GaN nanostructures on Si(111) for applications in UV photodetection (Figure 7). The device exhibited a responsivity of 5.7 mAW−1 at a bias of 1 V. Numerous other reports exist demonstrating the photodetection properties of GaN-based PDs.
Figure 7.
(a) Schematic of the fabricated MSM device and (b) trend of photocurrent variation with respect to the applied bias. Inset shows the optical image of the actual PD. Figure has been reprinted with permission from Ref. [48].
In the meantime, researchers have also started exploring InN-based devices. One such work has been carried out by Shetty et al. [49]. They have grown InN quantum dots of varying densities on Si substrates using MBE. The device shows a strong response towards infrared illumination. The photoresponse studies revealed that the increasing dot density results in the improvement in the sensitivity of the PD. The increase in the photocurrent with the density of the quantum dots has been attributed to the increase in the number of photogenerated carriers in InN, which add up with the carriers generated in Si upon light illumination. The results have also been validated using simulations and it has been observed that the experimental as well as theoretical results have sufficient agreement between them.
However, the epitaxial growth of high-quality III-Nitrides has been always hindered by the lack of lattice-matched substrates, that hinders the development of high-performance devices. In all the above-mentioned reports, the growth has been accomplished on substrates (c-plane sapphire, Si(111), etc) which promote the c-plane oriented growth of the III-Nitrides i.e., in the polar direction. Moreover, the structures grown along the polar c-axis exhibit larger internal electric fields at the heterostructure interfaces, affecting the radiative recombination rates. To overcome these issues, non-polar III-Nitrides are being extensively explored now-a-days because of their several benefits over the polar III-Nitrides. Epitaxial growth of GaN in the non-polar (a-plane) direction seems to be a feasible way for the growth of high-quality films as the lattice mismatch between a-plane [11, 12, 13, 14, 15, 16, 17, 18, 19, 20] GaN and the r-plane [1–102] sapphire is the least (1.19%) along one of the azimuth directions. Additionally, the absence of internal polarization fields in non-polar structures may enhance the photodetection performance. Mukundan et al. [50] in 2015 have shown improvement in the performance of non-polar GaN in comparison to that of the polar GaN in terms of figures of merit as well as the device stability.
In 2018, the mechanism of the higher device performance parameters of the non-polar GaN has been explained by Pant et al. [18] by performing azimuth angle-dependent photodetection. They have shown the non-uniformity in the defects present along the different azimuth directions. This is a consequence of the asymmetry in the strain between the substrate and film, as the lattice mismatch is asymmetric along various in-plane crystal directions. The mismatch in the lattice constants along the [0002] direction is ∼1% whereas, along the [1–100] direction, it is ∼13%. This induces a large number of defects along the [1–100] direction as compared to the [0002] azimuth direction. Figure 8(a) shows the a-GaN-based device used in this study. Furthermore, it has been shown in Figure 8(b) that the overall photocurrent in the UV region is also dependent on the different azimuth angles. A maximum responsivity of ~1.9 AW−1 and ~ 13.0 AW−1 have been obtained at a bias of 1 V and 5 V, respectively. These results underlined the importance of aligning the contact electrodes along the favorable azimuth direction in order to restrict the transport of the charge carriers. In a subsequent work, Pant et al. [51] have further shown improvements in the photodetection properties of the non-polar GaN by optimizing the growth parameters and therefore, improving the overall quality of the thin film. A maximum responsivity of 25 AW−1has been achieved at a low bias of 1 V and is among the highest reported responsivities at such low voltages.
Figure 8.
(a) Fabrication of contact electrodes in different directions and (b) I–V characteristics of the device taken along different azimuth directions. Figure has been reprinted with permission from Ref. [18].
Another approach to overcome the problem of lattice mismatch is by using AlN as a buffer layer. Wang et al. [52] in 2007 exhibited a Schottky-based metal–semiconductor–metal PD, fabricated on 1 μm-thick and crack-free GaN on Si(111), utilizing an optimized AlxGa1–xN/AlN complex buffer layer. The device showed a high photoresponsivity of 4600 AW−1 at 1 V bias (366 nm) and this superior performance has been attributed to both the crack-free GaN film as well as the high internal gain. In another report, the growth of GaN p-n junction on AlN/Si(111) and the effects of thermal annealing of the Ni/Ag contact electrodes on the photodetector applications have been explored by Yusoff et al. [14]. Recently, Ravikiran et al. [53] have demonstrated GaN UV PDs grown on AlN/Si(111) which exhibited a peak responsivity of 0.183 AW−1 at 15 V.
4.2 III-Nitride heterostructures-based devices
In the reports discussed above, various methods leading to enhancement in the responsivity have been highlighted. However, the responsivities and the transit times (in the order of a ms) of most of these PDs still remain inferior to that of the state-of-the-art detectors, and therefore, hamper their usage for the design and development of practical devices. The most elegant way to enhance the device performance is by utilizing a heterojunction with high-quality materials. There are many reports demonstrating PDs based on the heterojunctions of III-Nitrides with other III-Nitride semiconductors, ZnO, perovskites, 2D materials, and so forth.
In 2010, Rigutti et al. [54] have shown a single-nanowire PD relying on the charge carrier generation in the GaN/AlN quantum discs (QDs). The photoluminescence studies have shown that the emission energy of the QDs is lesser than the band gap of GaN, which is a consequence of the quantum confined Stark effect. The QD-based PDs exhibited a strong reduction in the dark current with responsivity (300 nm, −1 V) as high as 2 × 103 AW−1. Yusoff et al. [55] have demonstrated AlN/GaN/AlN heterostructures grown via PAMBE on Si substrates. The photoresponse shows promising results towards applications in UV detection. Pandey et al. [21] have reported the fabrication of a BaTiO3/GaN (BTO/GaN)-based Schottky junction PD on c-plane sapphire and its selective UV photodetection in temperature range of 313–423 K. The responsivity increased with increase in the temperature till 393 K and then it decreased. Such behavior has been explained by the enhancement in the device’s dark current with increase in the temperature, which is also evident from the ideal diode equation. The device shows potential to be used as an UV PD in high-temperature applications.
In another report, Roul et al. [13] have demonstrated hybrid ZnO/AlN/Si-based UV PDs with infrared- and visible-blind photoresponse. The heterostructures have been formed by depositing ZnO films on Si(111) substrate with an introduction of AlN as an intermediate layer. The AlN layer helps in improving the crystallinity of the ZnO films and results in excellent optical properties. The vertical transport characteristics of the ZnO/AlN/Si heterojunction-based device under light illumination and in the dark demonstrate an intrinsic infrared- and visible-blind response, with excellent UV responsivity of 14.5 AW−1. The AlN layer acts as an electron blocking layer and allows the holes to get transported across the heterojunction in the reverse biasing condition.
In the past few years, loads of efforts have been made in the field of III-Nitrides/2D materials-based heterostructures for high-performance optoelectronic devices. These 2D materials such as graphene, MoS2, etc. are characterized by weak inter-layer van der Waals (vdW) forces, which lead to exceptional electronic properties, and can offer an open platform to design high-performance electronic devices. Moreover, the absence of surface dangling bonds in 2D materials results in high-quality heterointerfaces. Such an integration has been recently demonstrated by Goel et al. [20], wherein they have shown a high responsivity UV PD based on 2D/3D heterojunction, which has been formed by depositing few-layer of MoS2 on GaN thin film. The superior light absorption properties of MoS2 resulted in high performance MoS2/GaN-based PD. The device shows a high responsivity of 3 × 103 AW−1 and detectivity of ~1011 Jones (at a wavelength of 365 nm) at an applied reverse bias of 1 V under a light intensity of 12 mWcm−2. The rise and the decay times of the PD were 5.3 and 5.6 ms, respectively.
Until now, all the reported devices discussed above require an external applied bias for achieving significant photodetection. In recent times, a lot of efforts are being made towards energy storage and energy producing devices due to the current situation of energy crisis [56, 57, 58, 59, 60, 61]. Therefore, PDs that do not consume any external power are gaining a lot of attention. These self-powered devices depend upon the built-in potential at the interface, which enables the effective separation of the photogenerated charge carriers. Additionally, the built-in electric potential lowers the dark current, which is another advantage of such PDs. Thus, these self-powered nanodevices have a great outlook for the next-generation optoelectronic devices.
4.3 III-Nitrides and their heterostructures for self-driven photodetection
Off late, as mentioned above, there has been a tremendous focus on the self-powered PDs. In this section, we emphasize on the various methods unveiled to achieve self-driven photodetection with III-Nitrides-based PDs.
Prakash et al. [62] in 2016 have demonstrated a simple approach to fabricate a self-powered PD utilizing reduced graphene oxide (rGO) asymmetrical electrodes on MBE-grown GaN thin film as shown in Figure 9(a). This integration of the transparent rGO contact electrodes on GaN has been realized through a simple drop-casting method, leading to a simple fabrication process as well as reduced processing time and cost. The hybrid shows a low photoresponsivity of 1.5 μAW−1 towards UV light at zero bias (Figure 9(b)), with fast response and recovery times of ~60 and ~267 ms, respectively. The difference in the work functions of rGO and GaN leads to formation of depletion regions at the two rGO/GaN interfaces. The drop casted contact electrodes are inhomogeneous in nature, which results into two unlike built-in fields at these interfaces. Therefore, a net internal electric field is developed, leading to the self-powered detection (Figure 9(c, d)).
Figure 9.
(a) GaN-based device with rGO electrodes, (b) I-V characteristics of the PD, (c) energy band diagram and (d) mechanism for self-powered photodetection. Figure has been reproduced with permission from Ref. [62].
Using the same approach as described above, Pant et al. [63] have reported a self-driven a-GaN-based UV-A PDs showing a responsivity and detectivity of ~4.67 mAW−1 and 3.0 × 1013 Jones, respectively at a wavelength of 364 nm. In another work, Aggarwal et al. [64] have shown a UV PD based on GaN nanoflowers grown via MBE on Si(111) substrate. Under self-biased condition, the PD exhibits a very low dark current in the range of ≈nA, with a high responsivity of 132 mAW−1 and fast rise/fall times of 63/27 ms. In another report, Chowdhury et al. [25] have reported self-powered photodetection of an InN/AlN/Si semiconductor–insulator–semiconductor-based PD (λ = 1550 nm), where a photoresponsivity of ~3.36 μAW−1 has been observed with response/recovery times in milliseconds.
The major shortcoming of such devices lies with the obtained responsivities, which is entirely reliant on the degree of inhomogeneity or asymmetry between the electrodes, hence, limiting the PD’s performance. One of the most effective ways for realizing self-driven PDs is by fabricating heterojunctions and utilizing the built-in potential at the heterointerface. Heterojunctions of III-Nitrides with several semiconductors such as Si, ZnO, Ga2O3, and so on have been explored and promising results have been achieved. In 2015, the advances in the high growth quality of epitaxial InGaN films on Si substrates synthesized via MBE along with the maturity in the Si-based technology have resulted in the demonstration of highly efficient PDs, as shown by Chandan et al. [65]. A self-powered n-InGaN/n-Si isotype heterojunction-based PD has been reported. The device shows a non-linear behavior and a responsivity of 0.094 AW−1, with rise/fall times less than 100 ms. The mechanism of self-powered photodetection has been explained based on the presence of interfacial internal electric field.
Recently, a high-performance PD based on the p-GaN/n-ZnMgO heterojunction has been demonstrated [24]. The PD shows a clear rectifying I–V behavior characterized with a turn-on voltage of ~2.5 V. At zero-bias condition, the device exhibits a responsivity of 196 mAW−1 at a wavelength of 362 nm. The rise and the decay times of the PD are as short as 1.7 and 3.3 ms, respectively. This high performance of the device has been attributed to the excellent crystalline quality and electrical properties of p-GaN epilayer.
In another work, a simple approach has been reported [66] to fabricate a GaN/rGO: Ag nanoparticles (NPs) p–n heterojunction-based PD, integrated with a network of transparent Au nanowires (NWs) as the top contact electrode. The device demonstrates an excellent rectification ratio of ~105 with a broad-band photoresponse due to the presence of both the GaN layer (UV region) and the silver-loaded reduced graphene oxide (visible to infrared region). Furthermore, the reducing effect of the Ag NPs to graphene oxide in addition to the localized surface plasmon resonance has been utilized to improve the photoresponse in the NIR and the visible regions. The transparent Au NWs network efficiently collects the charge, ensuing high photoresponsivity and fast switching behavior. The heterojunction exhibits a responsivity of ~266 mAW−1 and detectivity of ~2.62 × 1011 Jones, under illumination of 360 nm light. Owing to the high built-in electric potential at the heterointerface, the self-powered operation is demonstrated under the entire excitation wavelength range (360–980 nm).
Exploiting the criterion of the difference between the electron affinities of the constituent semiconductors to create an internal field, an improvisation in the InGaN/Si-based structure has been demonstrated by Chowdhury et al. [15], where introduction of an AlN layer in between InGaN and Si leads to the formation of a semiconductor–insulator–semiconductor type structure, resulting in the multi-fold enhancement in the device performance. The n+-InGaN/AlN/n-Si(111) hybrid structure has been realized by growing an n+-InGaN thin film on a commercially obtained AlN/n-Si template using MBE. The device exhibits an exceptional self-powered and broad-band photorespnse under the illumination of UV–visible light (300–800 nm). The self-powered PD exhibits a high responsivity of 9.64 AW−1 at light illumination of 580 nm, with an ultrafast response/recovery time of ~20/21 μs, respectively. The maximum response at 580 nm is believed to be because of the deep donor defect states present in the InGaN epilayer.
In a recent work, Singh et al. [4] have fabricated an MoS2/AlN/Si-based PD, combining the mature technologies of III-Nitride and Si with the unique properties of MoS2. Additionally, due to the large difference between the work functions of these semiconducting materials, the band bending at the heterointerfaces resulted into the self-driven behavior. The vertical transport behavior of the device shows a broad-band photoresponse (300–1100 nm) with maximum responsivity of ~10 AW−1 under self-biased condition as shown in Figure 10(a). The device also shows an ultrafast detection speeds (response/recovery times: ~13/15 μs). The importance of sandwiching the AlN layer has been shown as the MoS2/Si-based PD shows a responsivity ~5 times less in the zero-bias mode. The authors have confirmed through transmission electron microscopy and X-ray photoelectron spectroscopy that oxygen defects exist throughout the AlN layer. These impurities form deep donor levels in AlN and moderate the charge transport, which leads to the enhanced device performance (Figure 10(b)).
Figure 10.
(a) Spectral response of the MoS2/AlN/Si-based PD. (b) Schematic of the deep defect states-modulated carrier transport in MoS2/AlN/Si-based device. Figures have been reproduced with permission from Ref. [4].
5. Summary
The last two decades have indisputably witnessed incredible advances in the MBE growth of III-Nitrides and their applications in the area of photodetection. In this chapter, the important concepts about PDs, including the fundamental evaluation parameters and the various sensing mechanisms have been discussed. These mechanisms usually depend on the type of the photoactive material used to fabricate the device. Next, the basic properties of III-Nitrides and the common synthesis techniques used for their production have been reviewed briefly. Finally, a progressive discussion about the PDs based on the III-Nitrides fabricated through MBE has been given and summarized in Table 1. These extensive achievements have indisputably established MBE as one of the most reliable methods for fabricating high-quality III-Nitrides and these devices certainly have a lot of potential for the development of the advanced III-Nitrides-based PDs in future.
Comparison of the device performance parameters of various PDs discussed.
6. Outlook
Based upon the analysis of the reported devices in this field, a perspective regarding the future of III-Nitrides-based devices and the related follow-up work have been summarized below:
The use of transition metal dichalcogenides (TMDCs) as substrates for epitaxial growth of III-Nitrides has been unexplored. TMDCs have a very small lattice mismatch with the III-Nitrides [67], and therefore, high-quality growth can be expected which would result into better device performance.
The use of 2D transparent materials like graphene, graphene derivatives and 1T phase of TMDCs (semi-metallic), can be used as contact electrodes instead of the conventional metals, as the area for the light absorption gets maximized along with the outstanding electronic properties of these 2D semiconductors.
Another interesting possibility would be combining non-polar nitrides with layered materials. The absence of the internal polarization field would provide a band to band transition, which is usually absent in the polar devices because of the quantum confined Stark effect at the interfaces. This property is very important for effective photodetection and has been evident from some of the very early works reported on the nonpolar a-GaN. Additionally, the presence of anisotropy in electrical conductivity as well as mobility can be helpful in tuning the optoelectronic and electronic properties of the PD.
Till now, scientists across the world have generally exploited heterojunctions of III-Nitrides with 2D materials in the form of thin films. Heterojunctions based upon the one-dimensional (1D) nanostructures can provide new ways for the development of high-performance optoelectronic devices. The nanorods-based heterointerfaces of the III-Nitrides with 2D materials (growth along these nanorods or a core-shell structure) would enable a much higher aspect ratio and therefore, a much larger area for light absorption as well as a larger active interface, therefore, an enhancement in the optoelectronic performance.
Overall, the excellent properties of the III-Nitride semiconductors make them promising candidates for the applications in photodetection, and these PDs have exhibited outstanding device performance that competes with those available commercially. Thus, III-Nitrides and their heterojunctions-based PDs can be used for the development of futuristic self-biased and ultrafast PDs.
Acknowledgements
DKS is thankful to Council of Scientific and Industrial Research, Government of India, New Delhi for providing senior research fellowship. SBK acknowledges INSA senior scientist fellowship.
\n',keywords:"group III-nitrides, molecular beam epitaxy, photodetectors, hybrid structures, next-generation photonic devices",chapterPDFUrl:"https://cdn.intechopen.com/pdfs/74602.pdf",chapterXML:"https://mts.intechopen.com/source/xml/74602.xml",downloadPdfUrl:"/chapter/pdf-download/74602",previewPdfUrl:"/chapter/pdf-preview/74602",totalDownloads:263,totalViews:0,totalCrossrefCites:0,dateSubmitted:"September 21st 2020",dateReviewed:"December 6th 2020",datePrePublished:"July 15th 2021",datePublished:"September 29th 2021",dateFinished:"December 28th 2020",readingETA:"0",abstract:"In the last few decades, there has been a phenomenal rise and evolution in the field of III–Nitride semiconductors for optoelectronic applications such as lasers, sensors and detectors. However, certain hurdles still remain in the path of designing high-performance photodetectors (PDs) based on III-Nitride semiconductors considering their device performance. Recently, a lot of progress has been achieved in devices based on the high quality epilayers grown by molecular beam epitaxy (MBE). Being an ultra-high vacuum environment based-technique, MBE has enabled the realization of high-quality and highly efficient PDs which have exhibited competitive figures of merit to that of the commercial PDs. Moreover, by combining the novel properties of 2D materials with MBE-grown III-Nitrides, devices with enhanced functionalities have been realized which would pave a way towards the next-generation photonics. In the current chapter, the basic concepts about photodetection have been presented in detail, followed by a discussion on the basic properties of the III-Nitride semiconductors, and the recent advancements in the field of MBE-grown III-Nitrides-based PDs, with an emphasis on their hybrid structures. Finally, an outlook has been provided highlighting the present shortcomings as well as the unresolved issues associated with the present-day devices in this emerging field of research.",reviewType:"peer-reviewed",bibtexUrl:"/chapter/bibtex/74602",risUrl:"/chapter/ris/74602",signatures:"Deependra Kumar Singh, Basanta Kumar Roul, Karuna Kar Nanda and Saluru Baba Krupanidhi",book:{id:"10459",type:"book",title:"Light-Emitting Diodes and Photodetectors",subtitle:"Advances and Future Directions",fullTitle:"Light-Emitting Diodes and Photodetectors - Advances and Future Directions",slug:"light-emitting-diodes-and-photodetectors-advances-and-future-directions",publishedDate:"September 29th 2021",bookSignature:"Maurizio Casalino and Jagannathan Thirumalai",coverURL:"https://cdn.intechopen.com/books/images_new/10459.jpg",licenceType:"CC BY 3.0",editedByType:"Edited by",isbn:"978-1-83968-556-9",printIsbn:"978-1-83968-555-2",pdfIsbn:"978-1-83968-564-4",isAvailableForWebshopOrdering:!0,editors:[{id:"106767",title:"Dr.",name:"Maurizio",middleName:null,surname:"Casalino",slug:"maurizio-casalino",fullName:"Maurizio Casalino"}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"}},authors:[{id:"196960",title:"Dr.",name:"Basanta",middleName:null,surname:"Roul",fullName:"Basanta Roul",slug:"basanta-roul",email:"basantaroul@gmail.com",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:null},{id:"328314",title:"Emeritus Prof.",name:"Saluru Baba",middleName:null,surname:"Krupanidhi",fullName:"Saluru Baba Krupanidhi",slug:"saluru-baba-krupanidhi",email:"sbkrupanidhi@gmail.com",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:null},{id:"331999",title:"Mr.",name:"Deependra Kumar",middleName:null,surname:"Singh",fullName:"Deependra Kumar Singh",slug:"deependra-kumar-singh",email:"deependras@iisc.ac.in",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:{name:"Indian Institute of Science Bangalore",institutionURL:null,country:{name:"India"}}},{id:"332001",title:"Prof.",name:"Karuna Kar",middleName:null,surname:"Nanda",fullName:"Karuna Kar Nanda",slug:"karuna-kar-nanda",email:"nanda@iisc.ac.in",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:{name:"Indian Institute of Science Bangalore",institutionURL:null,country:{name:"India"}}}],sections:[{id:"sec_1",title:"1. Introduction",level:"1"},{id:"sec_2",title:"2. Basic concepts about photodetection",level:"1"},{id:"sec_2_2",title:"2.1 Important figures of merit of a PD",level:"2"},{id:"sec_2_3",title:"2.1.1 Responsivity",level:"3"},{id:"sec_3_3",title:"2.1.2 Specific detectivity",level:"3"},{id:"sec_4_3",title:"2.1.3 Internal gain",level:"3"},{id:"sec_5_3",title:"2.1.4 Sensitivity",level:"3"},{id:"sec_6_3",title:"2.1.5 Response/recovery time",level:"3"},{id:"sec_7_3",title:"2.1.6 Power consumption",level:"3"},{id:"sec_8_3",title:"2.1.7 Spectral range",level:"3"},{id:"sec_10_2",title:"2.2 Different mechanisms of photodetection",level:"2"},{id:"sec_10_3",title:"2.2.1 Photoconductive and photogating effects",level:"3"},{id:"sec_11_3",title:"2.2.2 Photovoltaic effect",level:"3"},{id:"sec_12_3",title:"2.2.3 Photothermoelectric effect",level:"3"},{id:"sec_13_3",title:"2.2.4 Piezophototronic effect",level:"3"},{id:"sec_14_3",title:"2.2.5 Photobolometric effect",level:"3"},{id:"sec_17",title:"3. Group III-Nitride semiconductors",level:"1"},{id:"sec_17_2",title:"3.1 Crystal structure and optical properties of group III-Nitrides",level:"2"},{id:"sec_18_2",title:"3.2 Growth of group III-Nitride semiconductors",level:"2"},{id:"sec_19_2",title:"3.3 Approaches to improve device performance of group III-Nitride semiconductors-based PDs",level:"2"},{id:"sec_21",title:"4. Recent advancements in the MBE grown III-Nitrides-based PDs",level:"1"},{id:"sec_21_2",title:"4.1 III-Nitrides-based devices",level:"2"},{id:"sec_22_2",title:"4.2 III-Nitride heterostructures-based devices",level:"2"},{id:"sec_23_2",title:"4.3 III-Nitrides and their heterostructures for self-driven photodetection",level:"2"},{id:"sec_25",title:"5. Summary",level:"1"},{id:"sec_26",title:"6. Outlook",level:"1"},{id:"sec_27",title:"Acknowledgements",level:"1"}],chapterReferences:[{id:"B1",body:'Wu W, Zhang Q, Zhou X, Li L, Su J, Wang F, et al. 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Enhanced capacitance and stability of p-toluenesulfonate doped polypyrrole/carbon composite for electrode application in electrochemical capacitors. Journal of Power Sources. 2014;246:800-7.'},{id:"B59",body:'Kumar A, Singh HK, Singh RK, Singh R, Srivastava P. P-toluenesulfonate doped polypyrrole/carbon composite electrode and a process for the preparation thereof. United States patent US 10,074,453. 2018.'},{id:"B60",body:'Rambabu A, Singh DK, Pant R, Nanda KK, Krupanidhi SB. Self-powered, ultrasensitive, room temperature humidity sensors using SnS2 nanofilms. Scientific Reports. 2020;10(1):14611.'},{id:"B61",body:'Kumar S, Faraz M, Khare N. Enhanced thermoelectric properties of Sb2Te3-graphene nanocomposite. Materials Research Express. 2019;6(8):085079.'},{id:"B62",body:'Prakash N, Singh M, Kumar G, Barvat A, Anand K, Pal P, et al. Ultrasensitive self-powered large area planar GaN UV-photodetector using reduced graphene oxide electrodes. Applied Physics Letters. 2016;109(24):242102.'},{id:"B63",body:'Pant R, Singh DK, Chowdhury AM, Roul B, Nanda KK, Krupanidhi SB. Highly Responsive, Self-Powered a -GaN Based UV-A Photodetectors Driven by Unintentional Asymmetrical Electrodes. ACS Appl Electronic Materials. 2020;2(3):769-79.'},{id:"B64",body:'Aggarwal N, Krishna S, Sharma A, Goswami L, Kumar D, Husale S, et al. A Highly Responsive Self-Driven UV Photodetector Using GaN Nanoflowers. Advanced Electronic Materials. 2017;3(5):1700036.'},{id:"B65",body:'Chandan G, Mukundan S, Mohan L, Roul B, Krupanidhi SB. Trap modulated photoresponse of InGaN/Si isotype heterojunction at zero-bias. Journal of Applied Physics. 2015;118(2):024503.'},{id:"B66",body:'Sarkar K, Hossain M, Devi P, Rao KDM, Kumar P. Self-Powered and Broadband Photodetectors with GaN: Layered rGO Hybrid Heterojunction. Advanced Materials Interfaces. 2019;6(20):1900923.'},{id:"B67",body:'Gupta P, Rahman AA, Subramanian S, Gupta S, Thamizhavel A, Orlova T, et al. Layered transition metal dichalcogenides: promising near-lattice-matched substrates for GaN growth. Scientific Reports. 2016;6(1):23708.'}],footnotes:[],contributors:[{corresp:null,contributorFullName:"Deependra Kumar Singh",address:null,affiliation:'
Materials Research Centre, Indian Institute of Science, India
Materials Research Centre, Indian Institute of Science, India
Central Research Laboratory, Bharat Electronics, India
'},{corresp:null,contributorFullName:"Karuna Kar Nanda",address:null,affiliation:'
Materials Research Centre, Indian Institute of Science, India
'},{corresp:"yes",contributorFullName:"Saluru Baba Krupanidhi",address:"sbkrupanidhi@gmail.com",affiliation:'
Materials Research Centre, Indian Institute of Science, India
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This broad application of natural and synthetic zeolites is given by their main properties: adsorption, molecular sieving and cation exchange capacity. In this chapter the main use of zeolites in veterinary medicine is reviewed. The beneficial effects of zeolites in animal nutrition, on mycotoxins, as an adjuvant in anticancer treatment and in increasing passive immunity of newborn ruminants are reported. Furthermore, multiple advantageous immune effects of zeolites such as their antioxidant capacity or their non-specific superantigen-like immunoglobulin action are also reviewed. Finally, their main positive effect on passive immunity in newborn calves is discussed. 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The aim of this review is to determine virulence factors of S. aureus, resistance mechanisms of methicillin, and the influence of methicillin resistance on biofilm phenotype of S. aureus.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Sahra Kırmusaoğlu",authors:[{id:"179460",title:"Associate Prof.",name:"Sahra",middleName:null,surname:"Kırmusaoğlu",slug:"sahra-kirmusaoglu",fullName:"Sahra Kırmusaoğlu"}]},{id:"53022",doi:"10.5772/65980",title:"Antimicrobial Activity of Chitosan Membranes Against Staphylococcus Aureus of Clinical Origin",slug:"antimicrobial-activity-of-chitosan-membranes-against-staphylococcus-aureus-of-clinical-origin",totalDownloads:2244,totalCrossrefCites:2,totalDimensionsCites:7,abstract:"Healthy human skin has beneficial microflora and many pathogens causing infections. Staphylococcus aureus is the most prevalent and can have multiresistance to antibiotics. Chitosan is a polysaccharide composed of glucosamine and N-acetyl-D-glucosamine, which is biodegradable and has antimicrobial activity. As part of a national scientific research project for the development and application of biomaterials, we decided to study the effect of different membranes based on chitosan against strains of S. aureus isolated from infected ulcers. The study found that seven of nine strains of S. aureus are sensitive to rifampin and the least eight of nine strains were multiresistant to more than ten antibiotics. All chitosan-based membranes confirm its antimicrobial effect on direct contact with an increase in its diameter. The contact area of the membranes is increased according to the concentration of chitosan. The highest average area increase was the chitosan membranes with honey and glycerin, 88.32%. Chitosan membranes have shown their effectiveness against S. aureus strains of clinical origin. Thus, these materials can be applied for the treatment of chronic ulcers without toxic hazards and resistance caused by antibiotics.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Ana A. Escárcega-Galaz, Jaime López-Cervantes, Dalia I. Sánchez-\nMachado, Olga R. Brito-Zurita and Olga N. Campas-Baypoli",authors:[{id:"190199",title:"Dr.",name:"Dalia I.",middleName:null,surname:"Sánchez-Machado",slug:"dalia-i.-sanchez-machado",fullName:"Dalia I. Sánchez-Machado"},{id:"194979",title:"Dr.",name:"Ana A.",middleName:null,surname:"Escárcega-Galaz",slug:"ana-a.-escarcega-galaz",fullName:"Ana A. Escárcega-Galaz"}]},{id:"53494",doi:"10.5772/66736",title:"Staphylococcus aureus Enterotoxin Production in Relation to Environmental Factors",slug:"staphylococcus-aureus-enterotoxin-production-in-relation-to-environmental-factors",totalDownloads:2309,totalCrossrefCites:0,totalDimensionsCites:6,abstract:"Staphylococcal enterotoxins (SEs) and SE-like toxins (SEls) are the most notable virulence factors associated with Staphylococcus aureus. They are involved in food poisoning, toxic shock syndrome and staphylococcal infectious diseases in human. In dairy practise, the initial numbers of S. aureus play an important role especially at the beginning of the milk fermentation within the first 6 h or in 24-h-old cheese. As we presented in our previous works, one of the most effective tools to inhibit S. aureus growth is by adding a sufficient amount of active dairy starters, which are able to produce lactic acid very rapidly. Thus, by inhibiting the growth of S. aureus the production of SEs may be reached. Based on this study focusing on the effect of temperature, pH, water activity and initial numbers of lactic acid bacteria on the growth and the ability of S. aureus 14733 to produce SED, we consider it as a strong SED producer. The SED production was not limited with the incubation temperatures and the NaCl addition related to traditional cheese manufacture. As this isolate comes originally from such an artisanal cheese production, we can expect that other strong SE producer could be present in milk or environment. Besides strict prerequisites approach in production hygiene, it is necessary to add the starters ensuring the initial dominance of lactic acid bacteria (LAB) and supporting the growth of the natural LAB present in raw milk.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Alžbeta Medved’ová, Adriana Havlíková and Ľubomír Valík",authors:[{id:"139980",title:"Prof.",name:"Ľubomír",middleName:null,surname:"Valík",slug:"lubomir-valik",fullName:"Ľubomír Valík"},{id:"143466",title:"Dr.",name:"Alžbeta",middleName:null,surname:"Medveďová",slug:"alzbeta-medvedova",fullName:"Alžbeta Medveďová"},{id:"191311",title:"Dr.",name:"Adriana",middleName:null,surname:"Havlíková",slug:"adriana-havlikova",fullName:"Adriana Havlíková"}]},{id:"53612",doi:"10.5772/66954",title:"Effects of Alterations in Staphylococcus aureus Cell Membrane and Cell Wall in Antimicrobial Resistance",slug:"effects-of-alterations-in-staphylococcus-aureus-cell-membrane-and-cell-wall-in-antimicrobial-resista",totalDownloads:1585,totalCrossrefCites:2,totalDimensionsCites:6,abstract:"Staphylococcus aureus is one of the most successful opportunistic pathogen able to cause serious infections due to its ability to produce virulence factors and acquire antimicrobial resistance. Recent reports indicate that the phenotypic changes in the cell wall and cell membrane are essential mechanisms related to the resistance to several antibacterial drugs (such as daptomycin and vancomycin). These alterations involve changes in cell wall composition and chemical modifications of some components (point mutation leading to modification in phosphatidylglycerol molecule, in the production of the aberrations in peptidoglycan structure and decrease in autolytic activity of the components of the cell envelope), leading to changes in electric charge of the cell surface, cell membrane fluidity and cell morphology. In fact, S. aureus develops several multifactorial and strain-specific adaptive mechanisms to survival in host. The study of such mechanisms is very important. The aim of this chapter is to review the phenotypic mechanisms related to drug resistance in S. aureus.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Andrea de Souza Monteiro, Wallace Ribeiro Nunes Neto, Aleff\nRicardo Santos Mendes, Bruna Lorrana dos Santos Pinto, Luís\nCláudio Nascimento da Silva and Gabriella Freitas Ferreira",authors:[{id:"139215",title:"Dr.",name:"Andrea",middleName:"De Souza",surname:"Monteiro",slug:"andrea-monteiro",fullName:"Andrea Monteiro"},{id:"189830",title:"Prof.",name:"Luís Cláudio",middleName:null,surname:"Nascimento Da Silva",slug:"luis-claudio-nascimento-da-silva",fullName:"Luís Cláudio Nascimento Da Silva"},{id:"195589",title:"Mr.",name:"Aleff",middleName:null,surname:"Mendes",slug:"aleff-mendes",fullName:"Aleff Mendes"},{id:"195590",title:"Ms.",name:"Bruna",middleName:null,surname:"Pinto",slug:"bruna-pinto",fullName:"Bruna Pinto"},{id:"195591",title:"Mrs.",name:"Wallace",middleName:null,surname:"Neto",slug:"wallace-neto",fullName:"Wallace Neto"},{id:"195592",title:"Prof.",name:"Gabriella",middleName:null,surname:"Ferreira",slug:"gabriella-ferreira",fullName:"Gabriella Ferreira"}]}],mostDownloadedChaptersLast30Days:[{id:"53240",title:"Staphylococcus aureus Biofilms and their Impact on the Medical Field",slug:"staphylococcus-aureus-biofilms-and-their-impact-on-the-medical-field",totalDownloads:3780,totalCrossrefCites:18,totalDimensionsCites:34,abstract:"Despite the discovery of antibiotics, the battle against bacteria is so far in their favor, specifically because bugs are able to develop a superstructure named biofilm, to resist and to survive in the environment. Nosocomial infections, a major health problem, are due at 80% to biofilm‐associated infection, and Staphylococcus aureus is the leading bacteria species in this domain. Moreover, the antimicrobial resistance of this bacterial community is accentuated when it is formed by superbugs such as methicillin‐resistant S. aureus (MRSA). In this chapter, the mechanism and the physiology of S. aureus biofilm as well as their consequences in the clinical domains are described. To complete the vision on S. aureus biofilms, some “anti‐biofilm” strategies will be highlighted.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Fany Reffuveille, Jérôme Josse, Quentin Vallé, Céline Mongaret and\nSophie C. Gangloff",authors:[{id:"54351",title:"Prof.",name:"Sophie C.",middleName:null,surname:"Gangloff",slug:"sophie-c.-gangloff",fullName:"Sophie C. Gangloff"},{id:"190356",title:"Ph.D.",name:"Fany",middleName:null,surname:"Reffuveille",slug:"fany-reffuveille",fullName:"Fany Reffuveille"},{id:"191408",title:"Dr.",name:"Jérome",middleName:null,surname:"Josse",slug:"jerome-josse",fullName:"Jérome Josse"},{id:"203850",title:"Dr.",name:"Quentin",middleName:null,surname:"Vallé",slug:"quentin-valle",fullName:"Quentin Vallé"},{id:"203852",title:"Dr.",name:"Céline",middleName:null,surname:"Mongaret",slug:"celine-mongaret",fullName:"Céline Mongaret"}]},{id:"52471",title:"MRSA and MSSA: The Mechanism of Methicillin Resistance and the Influence of Methicillin Resistance on Biofilm Phenotype of Staphylococcus aureus",slug:"mrsa-and-mssa-the-mechanism-of-methicillin-resistance-and-the-influence-of-methicillin-resistance-on",totalDownloads:3159,totalCrossrefCites:6,totalDimensionsCites:9,abstract:"Staphylococcus aureus (S. aureus), which is one of the most common causes of indwelling device–associated, nosocomial, and community-acquired infections, can produce biofilm as a virulence factor. Methicillin-resistant S. aureus (MRSA) that is resistant to β-lactam antibiotics causes life-threatening infections. Biofilm producer strains of S. aureus that causes indwelling device–associated infections resist to antimicrobials and immune system. The combination of methicillin resistance and the ability of biofilm formation of S. aureus makes treatment difficult. Methicillin resistance of S. aureus can affect biofilm phenotype of S. aureus; the mecA gene of MRSA increases biofilm production by inactivating accessory gene regulator (agr) quorum sensing regulator system, which is a two-component regulator system of virulence factor production. The aim of this review is to determine virulence factors of S. aureus, resistance mechanisms of methicillin, and the influence of methicillin resistance on biofilm phenotype of S. aureus.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Sahra Kırmusaoğlu",authors:[{id:"179460",title:"Associate Prof.",name:"Sahra",middleName:null,surname:"Kırmusaoğlu",slug:"sahra-kirmusaoglu",fullName:"Sahra Kırmusaoğlu"}]},{id:"53157",title:"Surface Proteins of Staphylococcus aureus",slug:"surface-proteins-of-staphylococcus-aureus",totalDownloads:2467,totalCrossrefCites:2,totalDimensionsCites:2,abstract:"Staphylococcus aureus is a commensal bacterium that causes infections such as sepsis, endocarditis, and pneumonia. S. aureus can express a variety of virulence factors, including surface proteins. Surface proteins are characterized by presence of a Sec‐dependent signal sequence at the amino terminal, and the sorting signal domain. Surface proteins are covalently attached to peptidoglycan and they are commonly known as cell wall–anchored (CWA) proteins. CWA proteins have many functions and participate in the pathogenesis of S. aureus. Furthermore, these proteins have been proposed as therapeutic targets for the generation of vaccines. In this chapter, different topics related to CWA proteins of S. aureus are addressed. The molecular structure of CWA proteins and their role as virulence factors of S. aureus are described. Furthermore, the involvement of CWA proteins in the processes of adhesion, invasion of host cells and tissues, evasion of the immune response, and the formation of biofilm is discussed. In addition, the role of CWA proteins in skin infection and the proposal to use them as potential vaccine antigens are described. The information contained in this chapter will help the readers to understand the biology of CWA proteins and to recognize the importance of surface molecules of S. aureus.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Janet Jan-Roblero, Elizabeth García-Gómez, Sandra Rodríguez-\nMartínez, Mario E. Cancino-Diaz and Juan C. Cancino-Diaz",authors:[{id:"181148",title:"Dr.",name:"Juan C.",middleName:null,surname:"Cancino-Diaz",slug:"juan-c.-cancino-diaz",fullName:"Juan C. Cancino-Diaz"},{id:"184949",title:"Dr.",name:"Janet",middleName:null,surname:"Jan-Roblero",slug:"janet-jan-roblero",fullName:"Janet Jan-Roblero"},{id:"184950",title:"Dr.",name:"Sandra",middleName:null,surname:"Rodríguez-Martínez",slug:"sandra-rodriguez-martinez",fullName:"Sandra Rodríguez-Martínez"},{id:"184951",title:"Dr.",name:"Mario E.",middleName:null,surname:"Cancino-Diaz",slug:"mario-e.-cancino-diaz",fullName:"Mario E. Cancino-Diaz"},{id:"194929",title:"Dr.",name:"Elizabeth",middleName:null,surname:"García-Gómez",slug:"elizabeth-garcia-gomez",fullName:"Elizabeth García-Gómez"}]},{id:"53644",title:"Exfoliative Toxins of Staphylococcus aureus",slug:"exfoliative-toxins-of-staphylococcus-aureus",totalDownloads:2363,totalCrossrefCites:3,totalDimensionsCites:6,abstract:"Virulent strains of Staphylococcus aureus secrete exfoliative toxins (ETs) that cause the loss of cell‐cell adhesion in the superficial epidermis. S. aureus ETs are serine proteases, which exhibit exquisite substrate specificity, and their mechanisms of action are extremely complex. To date, four different serotypes of ETs have been identified and three of them (ETA, ETB and ETD) are associated with toxin‐mediated staphylococcal syndromes related to human infections leading to diseases of medical and veterinary importance.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Ricardo B. Mariutti, Natayme R. Tartaglia, Núbia Seyffert, Thiago\nLuiz de Paula Castro, Raghuvir K. Arni, Vasco A. Azevedo, Yves Le\nLoir and Koji Nishifuji",authors:[{id:"192121",title:"Ms.",name:"Natayme",middleName:null,surname:"Tartaglia",slug:"natayme-tartaglia",fullName:"Natayme Tartaglia"},{id:"192122",title:"Dr.",name:"Núbia",middleName:null,surname:"Seyffert",slug:"nubia-seyffert",fullName:"Núbia Seyffert"},{id:"192124",title:"Dr.",name:"Thiago",middleName:null,surname:"Castro",slug:"thiago-castro",fullName:"Thiago Castro"},{id:"192125",title:"Dr.",name:"Koji",middleName:null,surname:"Nishifuji",slug:"koji-nishifuji",fullName:"Koji Nishifuji"},{id:"192126",title:"Dr.",name:"Yves",middleName:null,surname:"Le Loir",slug:"yves-le-loir",fullName:"Yves Le Loir"},{id:"192129",title:"Dr.",name:"Ricardo",middleName:null,surname:"Mariutti",slug:"ricardo-mariutti",fullName:"Ricardo Mariutti"},{id:"192131",title:"Dr.",name:"Raghuvir",middleName:null,surname:"Arni",slug:"raghuvir-arni",fullName:"Raghuvir Arni"},{id:"192132",title:"Dr.",name:"Vasco",middleName:null,surname:"Ariston de Carvalho Azevedo",slug:"vasco-ariston-de-carvalho-azevedo",fullName:"Vasco Ariston de Carvalho Azevedo"}]},{id:"53224",title:"Mechanisms of Horizontal Gene Transfer",slug:"mechanisms-of-horizontal-gene-transfer",totalDownloads:2123,totalCrossrefCites:1,totalDimensionsCites:3,abstract:"Horizontal gene transfer plays important roles in the evolution of S. aureus, and indeed, a variety of virulence factors and antibiotic resistance genes are embedded in a series of mobile genetic elements. In this chapter, we review the mechanisms of horizontal gene transfer, including recent findings on the natural genetic competence. Then, we consider the transfer of two important antibiotic resistance genes: the methicillin resistance gene, mecA (in Staphylococcal Cassette Chromosome) and the linezolid resistance gene, cfr (in plasmid). In either case, distinct mechanisms driving the gene dissemination support the prominent evolutionary ability of this important human pathogen.",book:{id:"6045",slug:"the-rise-of-virulence-and-antibiotic-resistance-in-staphylococcus-aureus",title:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus",fullTitle:"The Rise of Virulence and Antibiotic Resistance in Staphylococcus aureus"},signatures:"Fabio Cafini, Veronica Medrano Romero and Kazuya Morikawa",authors:[{id:"190494",title:"Prof.",name:"Kazuya",middleName:null,surname:"Morikawa",slug:"kazuya-morikawa",fullName:"Kazuya Morikawa"},{id:"196517",title:"Dr.",name:"Fabio",middleName:null,surname:"Cafini",slug:"fabio-cafini",fullName:"Fabio Cafini"},{id:"196518",title:"Ms.",name:"Veronica",middleName:null,surname:"Medrano Romero",slug:"veronica-medrano-romero",fullName:"Veronica Medrano Romero"}]}],onlineFirstChaptersFilter:{topicId:"901",limit:6,offset:0},onlineFirstChaptersCollection:[],onlineFirstChaptersTotal:0},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:0,limit:8,total:null},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:87,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:99,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:27,numberOfPublishedChapters:288,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:9,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:11,numberOfPublishedChapters:139,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:8,numberOfPublishedChapters:129,numberOfOpenTopics:0,numberOfUpcomingTopics:2,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!1},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:107,numberOfOpenTopics:3,numberOfUpcomingTopics:1,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:104,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:12,numberOfOpenTopics:2,numberOfUpcomingTopics:1,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:0,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!1},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:0,numberOfPublishedChapters:11,numberOfOpenTopics:4,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"24",title:"Sustainable Development",doi:"10.5772/intechopen.100361",issn:null,scope:"
\r\n\tTransforming our World: the 2030 Agenda for Sustainable Development endorsed by United Nations and 193 Member States, came into effect on Jan 1, 2016, to guide decision making and actions to the year 2030 and beyond. Central to this Agenda are 17 Goals, 169 associated targets and over 230 indicators that are reviewed annually. The vision envisaged in the implementation of the SDGs is centered on the five Ps: People, Planet, Prosperity, Peace and Partnership. This call for renewed focused efforts ensure we have a safe and healthy planet for current and future generations.
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\r\n\tThis Series focuses on covering research and applied research involving the five Ps through the following topics:
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\r\n\t1. Sustainable Economy and Fair Society that relates to SDG 1 on No Poverty, SDG 2 on Zero Hunger, SDG 8 on Decent Work and Economic Growth, SDG 10 on Reduced Inequalities, SDG 12 on Responsible Consumption and Production, and SDG 17 Partnership for the Goals
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\r\n\t2. Health and Wellbeing focusing on SDG 3 on Good Health and Wellbeing and SDG 6 on Clean Water and Sanitation
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\r\n\t3. Inclusivity and Social Equality involving SDG 4 on Quality Education, SDG 5 on Gender Equality, and SDG 16 on Peace, Justice and Strong Institutions
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\r\n\t4. Climate Change and Environmental Sustainability comprising SDG 13 on Climate Action, SDG 14 on Life Below Water, and SDG 15 on Life on Land
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\r\n\t5. Urban Planning and Environmental Management embracing SDG 7 on Affordable Clean Energy, SDG 9 on Industry, Innovation and Infrastructure, and SDG 11 on Sustainable Cities and Communities.
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\r\n\tThe series also seeks to support the use of cross cutting SDGs, as many of the goals listed above, targets and indicators are all interconnected to impact our lives and the decisions we make on a daily basis, making them impossible to tie to a single topic.
",coverUrl:"https://cdn.intechopen.com/series/covers/24.jpg",latestPublicationDate:"May 23rd, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:0,editor:{id:"262440",title:"Prof.",name:"Usha",middleName:null,surname:"Iyer-Raniga",slug:"usha-iyer-raniga",fullName:"Usha Iyer-Raniga",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRYSXQA4/Profile_Picture_2022-02-28T13:55:36.jpeg",biography:"Usha Iyer-Raniga is a professor in the School of Property and Construction Management at RMIT University. Usha co-leads the One Planet Network’s Sustainable Buildings and Construction Programme (SBC), a United Nations 10 Year Framework of Programmes on Sustainable Consumption and Production (UN 10FYP SCP) aligned with Sustainable Development Goal 12. The work also directly impacts SDG 11 on Sustainable Cities and Communities. She completed her undergraduate degree as an architect before obtaining her Masters degree from Canada and her Doctorate in Australia. Usha has been a keynote speaker as well as an invited speaker at national and international conferences, seminars and workshops. Her teaching experience includes teaching in Asian countries. She has advised Austrade, APEC, national, state and local governments. She serves as a reviewer and a member of the scientific committee for national and international refereed journals and refereed conferences. She is on the editorial board for refereed journals and has worked on Special Issues. Usha has served and continues to serve on the Boards of several not-for-profit organisations and she has also served as panel judge for a number of awards including the Premiers Sustainability Award in Victoria and the International Green Gown Awards. Usha has published over 100 publications, including research and consulting reports. Her publications cover a wide range of scientific and technical research publications that include edited books, book chapters, refereed journals, refereed conference papers and reports for local, state and federal government clients. She has also produced podcasts for various organisations and participated in media interviews. She has received state, national and international funding worth over USD $25 million. Usha has been awarded the Quarterly Franklin Membership by London Journals Press (UK). Her biography has been included in the Marquis Who's Who in the World® 2018, 2016 (33rd Edition), along with approximately 55,000 of the most accomplished men and women from around the world, including luminaries as U.N. Secretary-General Ban Ki-moon. 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Thus proteomics, an area of research that detects all protein forms expressed in an organism, including splice isoforms and post-translational modifications, is more suitable than genomics for a comprehensive understanding of the biochemical processes that govern life. The most common proteomics applications are currently in the clinical field for the identification, in a variety of biological matrices, of biomarkers for diagnosis and therapeutic intervention of disorders. From the comparison of proteomic profiles of control and disease or different physiological states, which may emerge, changes in protein expression can provide new insights into the roles played by some proteins in human pathologies. Understanding how proteins function and interact with each other is another goal of proteomics that makes this approach even more intriguing. Specialized technology and expertise are required to assess the proteome of any biological sample. 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Since then, he has been working as an Adjunct Professor in the same Department at the University of Pavia. His research activity during the first years was primarily focused on the purification and structural characterization of enzymes from animal and plant sources. During this period, Prof. Iadarola familiarized himself with the conventional techniques used in column chromatography, spectrophotometry, manual Edman degradation, and electrophoresis). Since 1995, he has been working on: i) the determination in biological fluids (serum, urine, bronchoalveolar lavage, sputum) of proteolytic activities involved in the degradation processes of connective tissue matrix, and ii) on the identification of biological markers of lung diseases. In this context, he has developed and validated new methodologies (e.g., Capillary Electrophoresis coupled to Laser-Induced Fluorescence, CE-LIF) whose application enabled him to determine both the amounts of biochemical markers (Desmosines) in urine/serum of patients affected by Chronic Obstructive Pulmonary Disease (COPD) and the activity of proteolytic enzymes (Human Neutrophil Elastase, Cathepsin G, Pseudomonas aeruginosa elastase) in sputa of these patients. More recently, Prof. Iadarola was involved in developing techniques such as two-dimensional electrophoresis coupled to liquid chromatography/mass spectrometry (2DE-LC/MS) for the proteomic analysis of biological fluids aimed at the identification of potential biomarkers of different lung diseases. He is the author of about 150 publications (According to Scopus: H-Index: 23; Total citations: 1568- According to WOS: H-Index: 20; Total Citations: 1296) of peer-reviewed international journals. 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She gained considerable experience in developing and validating new methodologies whose applications allowed her to determine both the amount of biomarkers (Desmosine and Isodesmosine) in the urine of patients affected by COPD, and the activity of proteolytic enzymes (HNE, Cathepsin G, Pseudomonas aeruginosa elastase) in the sputa of these patients. Simona Viglio was also involved in research dealing with the supplementation of amino acids in patients with brain injury and chronic heart failure. She is presently engaged in the development of 2-DE and LC-MS techniques for the study of proteomics in biological fluids. The aim of this research is the identification of potential biomarkers of lung diseases. 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Biochemistry examines macromolecules - proteins, nucleic acids, carbohydrates, and lipids – and their building blocks, structures, functions, and interactions. Much of biochemistry is devoted to enzymes, proteins that catalyze chemical reactions, enzyme structures, mechanisms of action and their roles within cells. Biochemistry also studies small signaling molecules, coenzymes, inhibitors, vitamins, and hormones, which play roles in life processes. Biochemical experimentation, besides coopting classical chemistry methods, e.g., chromatography, adopted new techniques, e.g., X-ray diffraction, electron microscopy, NMR, radioisotopes, and developed sophisticated microbial genetic tools, e.g., auxotroph mutants and their revertants, fermentation, etc. More recently, biochemistry embraced the ‘big data’ omics systems. Initial biochemical studies have been exclusively analytic: dissecting, purifying, and examining individual components of a biological system; in the apt words of Efraim Racker (1913 –1991), “Don’t waste clean thinking on dirty enzymes.” Today, however, biochemistry is becoming more agglomerative and comprehensive, setting out to integrate and describe entirely particular biological systems. The ‘big data’ metabolomics can define the complement of small molecules, e.g., in a soil or biofilm sample; proteomics can distinguish all the comprising proteins, e.g., serum; metagenomics can identify all the genes in a complex environment, e.g., the bovine rumen. 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Dr. Blumenberg’s research is focused on the epidermis, expression of keratin genes, transcription profiling, keratinocyte differentiation, inflammatory diseases and cancers, and most recently the effects of the microbiome on the skin. He has published more than 100 peer-reviewed research articles and graduated numerous Ph.D. and postdoctoral students.",institutionString:null,institution:{name:"New York University Langone Medical Center",institutionURL:null,country:{name:"United States of America"}}},subseries:[{id:"14",title:"Cell and Molecular Biology",keywords:"Omics (Transcriptomics; Proteomics; Metabolomics), Molecular Biology, Cell Biology, Signal Transduction and Regulation, Cell Growth and Differentiation, Apoptosis, Necroptosis, Ferroptosis, Autophagy, Cell Cycle, Macromolecules and Complexes, Gene Expression",scope:"The Cell and Molecular Biology topic within the IntechOpen Biochemistry Series aims to rapidly publish contributions on all aspects of cell and molecular biology, including aspects related to biochemical and genetic research (not only in humans but all living beings). 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Thus proteomics, an area of research that detects all protein forms expressed in an organism, including splice isoforms and post-translational modifications, is more suitable than genomics for a comprehensive understanding of the biochemical processes that govern life. The most common proteomics applications are currently in the clinical field for the identification, in a variety of biological matrices, of biomarkers for diagnosis and therapeutic intervention of disorders. From the comparison of proteomic profiles of control and disease or different physiological states, which may emerge, changes in protein expression can provide new insights into the roles played by some proteins in human pathologies. Understanding how proteins function and interact with each other is another goal of proteomics that makes this approach even more intriguing. Specialized technology and expertise are required to assess the proteome of any biological sample. Currently, proteomics relies mainly on mass spectrometry (MS) combined with electrophoretic (1 or 2-DE-MS) and/or chromatographic techniques (LC-MS/MS). MS is an excellent tool that has gained popularity in proteomics because of its ability to gather a complex body of information such as cataloging protein expression, identifying protein modification sites, and defining protein interactions. 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