Municipal population, total municipal area, and insertion in Iguaçu-Sarapuí River Basin
\r\n\tThis book chapter’s main theme will be focused on transmission dynamics, pathogenesis, mechanisms of host interaction and response, epigenetics and markers, molecular diagnosis, RNA interacting proteins, RNA binding proteins, advanced development of tools for diagnosis, possible development of concepts for vaccines and anti drugs for RNA viruses, immunological mechanisms, treatment, prevention and control.
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The Brazilian National Water Resources Policy, instituted by Law no. 9.433 in 1997, is based on six fundamental principles that structure the whole National Water Resource Management System: 1) water is a commodity in the public domain; 2) water is a limited natural resource, endowed with economic value; 3) in situations of scarcity, the priority water resources use is for human consumption and watering animals; 4) the management of water resources must always provide multiple water uses; 5) the hydrographical basin is the territorial unit for the implementation of the National Water Resources Policy and the activities of the entities belonging to the of National Water Resources Management System; 6) the water resource management must be decentralized and have the participation of public authorities, water users, civil society and communities.
This Law and its regulatory texts incorporate municipalities, along with users and civil organisations, into the management system, ensuring a greater balance of power on water resource committees and boards. However, no legal text has clearly defined the relation between water management, which is a state or federal attribution, and land use planning, which is responsibility of the municipalities. In this sense, there remains a lack of definition regarding the fundamental role of municipal administrations as formulators and implementers of urban policies with impacts on water resources, whether through direct investment, or by means of actions of regulatory nature.
Besides the gap pointed out above, the occurrence of conflicts of competency is also observed in the hydrographical basins related to metropolitan areas, given that the 1988 Brazilian Constitution did not establish clear management rules for these territories. The definition of the needed and related administrative organisation for the metropolitan areas is left to the federative states. On the other hand, overlaps is observed in the attributions of the local, state, or even federal administrations, and various undefined roles are identified, which make the task of coordination and sharing of the responsibilities even more complex.
Based on these elements, and departing from Brazilian reality, the proposed chapter deals with the need of integration of land use planning with water resource management, seeking to establish relations between the types of land use, urban settlements and the problems involving urban flooding.
A case study was developed for the Iguaçu-Sarapuí River Basin, located in the western portion of the Guanabara Bay Basin, which lies at the Rio de Janeiro State Metropolitan Region, in Brazil, and is one of the most critical areas in the state in relation to urban flooding. In this region, urban expansion dynamics is, in general, marked by irregular occupation of risk areas, without the appropriated infrastructure in terms of land tenure.
The significant investments in infrastructure in progress in the region, mainly the construction of the Metropolitan Ring Road The Metropolitan Ring Road is a Federal Government work, whose estimated cost is approximately US$ 1.6 billion. It will have an intersection with five federal highways, a railroad and a link with various large scale industrial poles being set up in the Rio de Janeiro Metropolitan Region.
The competence of municipalities in federated countries is concentrated on functions that, in general, are related with the allocation or rendering of local public services and with the functions of planning, incentive and inspection of the territorial order, environmental protection and also with some level of regulation of economic activities [1]. In the case of Brazil, recently, municipalities with greater capacity of investment have begun to incorporate functions related with the provision of more comprehensive social services, which, traditionally, were restricted to the state and federal spheres.
In the specific case of water resource management, however, municipal participation in basin committees has been the main form, if not the sole, of interaction with other public and private actors related with water. Many factors hinder the municipality action in the water management sphere, the main one being the legal impossibility, by Constitutional definition, of the municipalities directly managing water resources, even in the case of basins entirely contained by their territories. The exceptions may be associated to the transfer of some specific attributions through cooperation agreements with the states or the Federal Government.
Although local administrations are closer to local populations, their politico-administrative role does not allow a systemic vision of the territory in which they lie. More effective participation of local governments in water management is hindered, or even made unviable, also by the absence of clear definitions about its nature and functions, and by the fact that the majority of municipalities have limited budgetary autonomy, bearing in mind that they depend heavily on fund transfers from the other levels of government administration.
Regarding the financial restrictions [2], it is alarming that most of the multilateral financial agencies, except the Global Environment Facility – GEF, still have not included, in their agenda, projects of integrated natural resources management articulated to land use planning, particularly in urban areas. There are few planning experiments implemented articulating water conservation and/or preservation measures and land use regulation, despite the dysfunctions of urban growth.
Another aspect is that the sectoral nature of local government interests makes them act more as users than as “impartial” managers of water resources [3]. The debility and lack of institutional hierarchy of local governments confronted by actors wielding greater power would lead to greater vulnerability and to the possibility of capture and politicisation in water management [3]. These aspects are aggravated in metropolitan areas, where municipal administrations often express antagonistic interests and priorities among themselves, creating atmospheres of dissension with little space for cooperation.
Although there are restrictions on the participation of municipalities as direct managers of water resources, there is no doubt related to the importance of local governments in territorial planning, as well as in its consequences to water resources conservation. It is the attribution of municipalities to devise, approve and inspect instruments related with territorial order, such as master plans, zonings, development of housing programs, delimitation of industrial, urban and environmental preservation areas, among other activities with impacts on water resources, mainly in the case of predominantly urban hydrographical basins.
These attributions have recently been strengthened upon approval of the Brazilian Statute of the City. This is a Federal Act, established in 2001, which proposes standards of public and social interest to govern the use of the urban property in favour of the collectivity safety and welfare, as well as the environmental balance. The urban policy established aims to organise the fulfilment of the social functions of the city and of the urban property by the application of a set of general guidelines, from which the following topics are detached:
the guarantee of the right to sustainable cities, meaning the right to urban land, housing, environmental sanitation, urban infrastructure, transport and public services, work and leisure for present and future generations;
the democratic management through people\'s participation representing segments of the community in the formulation, implementation and monitoring of plans, programs and projects for urban development;
the planning of city development to prevent and correct the distortions of urban growth and its negative effects on the environment;
the supply of urban infrastructure and community equipments, transport and public services to serve the interests and needs of the population;
the protection, preservation and restoration of the natural and built environment, besides cultural, historical, artistic and landscape heritages.
Several important urban management tools were made available in the context of the Statute of the City and the Urban Master Plan is considered to be the basic instrument for the urban developing policy.
The possibility of achieving a sustainable water resource management must necessarily pass through a clear articulation with land use plans. What is observed in Brazil, however, is the disarticulation between instruments of water resource management and land use planning, reflecting, perhaps, the lack of legitimacy of planning and urban legislation in Brazilian cities, marked by a high degree of informality, and even illegality, in land use occupation. According to Tucci [4], the greatest difficulty for the implementation of integrated planning arises from the limited institutional capacity of municipalities in facing complex interdisciplinary problems, and in the sectoral ways in which local administrations are organized.
Here, however, it is worth stressing the differences among municipalities: while in large cities, mainly metropolitan cores, it is possible to find efficient administrations, with good capacity to access information and with relatively modern legislation, in other minor cities, like peripheral municipalities in metropolitan areas, a total obsolescence in the legislation is verified. This is aggravated by the absence of reliable general data and information about the processes of urban structuring and also by the small number and low qualification of the technical staff [5].
This inequality in the municipal scale presents a great obstacle for a greater effectiveness of water resource management structures and for the cooperation among the different hierarchical levels of government.
Baixada Fluminense lowland is located in the western portion of the Guanabara Bay basin, in one of the most critical regions of Rio de Janeiro State, in terms of urban flooding. It is particularly interesting as an empirical study, considering the following aspects:
its location is in the metropolitan periphery;
there are areas with consolidated urban and industrial growth;
there rural areas in a process of urban development
the basin also contains rural areas still protected from urbanisation;
several areas present land use patterns that do not ensure minimal standards of living, especially those of poor drainage;
consequently, several serious flooding problems occur in the watershed plain areas;
water sources found in the basin area are used for complementing the Metropolitan Region drinking water supply;
Tinguá Biological Reserve, the main remnant of the Atlantic Forest in Rio de Janeiro State, is situated in this territory;
organised social movements, congregating federations of residents associations and entities involved in matters of environment, sanitation, housing, among others, are present in the basin, what demonstrates the great organisation capacity of its population vis-à-vis the questions related to citizenship and quality of life;
local administrations are becoming more committed to efficiency in public affairs, although in a still timid process;
the presence of major private and public investments in infrastructure will lead to significant transformations in the present urban configuration of the region.
The Iguaçu-Sarapuí River basin is situated in Baixada Fluminense lowlands. Its drainage area covers around 727 km2, all of which is situated in the Rio de Janeiro Metropolitan Region. Iguaçu River springs in Serra do Tinguá massif, at an altitude of 1,600m. Its course runs southeast for approximately 43 km, until it reaches the outfall at Guanabara Bay. Its main tributaries from the left margins are Tinguá, Pati and Capivari Rivers, and, from the right margins, Botas and Sarapuí Rivers.
The physiography of Iguaçu-Sarapuí river basin is characterized by two main elements: the Serra do Mar Mountains and Baixada Fluminense lowlands, with a marked difference in altitude. The climate in the basin is hot and humid with a rainy season in the summer, the average annual precipitation being around 1,700mm, and the mean annual temperature approximately 22o C. The rivers run down the mountains in torrents with great erosive force, losing speed after reaching the plains, often overflowing their banks into large wetlands.
The basin fully encompasses the municipalities of Belford Roxo and Mesquita, also hosting part of the municipalities of Rio de Janeiro (covering the neighbourhoods of Bangu, Padre Miguel and Senador Câmara), Nilópolis, São João de Meriti, Nova Iguaçu and Duque de Caxias (Figure 1). According to the 2010 Brazilian census, the population of these municipalities reached 9,225,557 habitants (Table 1). However, just two of these municipalities are totally inserted in the basin.
Total Area1) (ha) | ||||||
Belford Roxo | 469.332 | - | 469.332 | 7.350 | 7.350 | 10 |
Duque de Caxias | 852.138 | 2.910 | 855.048 | 46.570 | 27.359 | 38 |
Nilópolis | 157.425 | - | 157.425 | 1.920 | 1.042 | 1 |
Mesquita | 168.376 | - | 168.376 | 3.477 | 3.477 | 5 |
Nova Iguaçu | 787.563 | 8.694 | 796.257 | 53.183 | 27.894 | 38 |
Rio de Janeiro | 6.320.446 | - | 6.320.446 | 126.420 | 3.290 | 5 |
São João de Meriti | 458.673 | - | 458.673 | 3.490 | 2.293 | 3 |
Municipal population, total municipal area, and insertion in Iguaçu-Sarapuí River Basin
Iguaçu-Sarapuí River Basin
It is in the lower parts of the basin, with elevations near the medium sea level, where it is concentrated mostly of the urban area, with something about 1.5 million people living there. Calculations from IBGE, the Brazilian Institute of Geography and Statistics, show that the incidence of poverty in these municipalities is quite significant, especially in Belford Roxo, Nova Iguaçu and Duque de Caxias, affecting more than half of their populations (Table 2).
Belford Roxo | 60,06 |
Duque de Caxias | 53,53 |
Mesquita | - |
Nilópolis | 32,48 |
Nova Iguaçu | 54,15 |
Rio de Janeiro | 23,85 |
São João de Meriti | 47,00 |
Poverty and inequality map – Brazilian Municipalities, 2003- Poverty incidence in Baixada Fluminense Lowlands
The structural analysis of per capita income and the capability to finance investments by municipalities in the region, according to the Observatory of the Metropolis [6], demonstrate the strong differences between the municipalities belonging to the Metropolitan Region of Rio de Janeiro. Such differences constitute obstacles to cooperation in solving common problems. Moreover, the fragile financial structure, coupled with the shortage of technical capacity, particularly in the areas of planning and budget, strengthen the uncertainty, discouraging long-term partnerships in infrastructure projects that could be used to promote social and economic development for the region.
After a century of intense population growth, Brazil has entered the new millennium with quite modest rates of population growth. As shown by the data of the last Census, the Brazilian population grew at an average rate of 1.6% per year in the 1990s, following a decline trend after the strong growth happened from the 1950 to 1970. Projections developed recently estimated that the Brazilian population is growing at rates below 1.3% per year.
The city of Rio de Janeiro has been the centre of services for the Metropolitan region, although this characteristic has not reflected in a high degree of attractiveness for population in recent times. The region remained with the lowest population growth rate among large Brazilian cities. It should be noted, however, that in absolute terms, there was a warming of migration in the last decade towards Rio de Janeiro. Between 1980 and 1991 the total number of migrants towards the metropolitan area of Rio de Janeiro was around 570,000 people, while between 1995 and 2000 (just in five years) the total migration reached 330,000 people. The capital of the state remained the main pole centre, receiving these migration flows and housing 195,000 migrants, i.e. 62% of the total [6].
According to Britto and Bessa [7], historical investments were made in the region by different state governors, like the one of the 1980s, with an amount up to R$ 3 billion, without, however, effectively guaranteeing universal access to environmental sanitation, housing and a better quality of life. Explanations for this are related with: (i) the lack of a profound diagnosis of the dimension of the problem in the region to correctly orient the profile of the interventions; (ii) the discontinuity and non-integration among the programs and projects implemented throughout these years; (iii) the political disputes in the region often decharacterised the projects, again lacking continuity; (iv) the fragility of social control in the process, once the format of the implemented programs have not provided an effective participation of the population (although this component existed in various of these projects); (v) the lack of institutional capacity, allied to the centralizing culture of the state governors in relation to sanitation management; (vi) the strong clientelistic culture in the municipal administrations; (vii) the growing demobilisation of organized social movements, which need members qualification for following up the policies implementation.
Floods in the Iguaçu-Sarapuí River Basin are aggravated basically by the f inadequate land use occupation, in the particular conditions of the lowlands of Baixada Fluminense. In this process, the most important factors are: lack of adequate urban infrastructure; deficiency of the sewage services and solid waste collection; uncontrolled exploitation of mineral deposits, mainly sand for construction purposes; disorderly, illegal occupation of river banks and floodplains; lack of adequate treatment for public roadways pavements; obstruction or strangulation of drainage due to structures built without the proper concerns (railway and road bridges, and water pipelines interferences), as well as walls and even buildings that partially obstruct river channels. At the heart of these problems one always finds either inadequate legislation regarding land use, or, in the great majority of cases, non-compliance with the existing legislation.
It is estimated that floods in the basin directly affect 189,000 people. However, the damage caused and the total number of people indirectly affected by floods are both difficult to estimate. Included in this latter category there are, for example, employees who cannot reach their workplaces and the interruption of traffic and commerce along the flooded roadways or nearby areas that become inaccessible.
In this context, in order to properly discuss the adequate possible planning actions for mitigating these problems, and to figure out the cause-effect process related to future scenarios, a mathematical model will be applied as an aiding tool. The case study alternatives are then introduced in order to allow the development of the discussions in practical terms, using examples of what may happen in the future without the proper concerns. The aim of hydrodynamic modelling was to evaluate the possible impacts of the expansion of urbanisation towards the interior of the basin without the adequate planning process and considering the construction of Metropolitan Ring Road, which is being taken as an urban development inductor factor. Another objective of the modelling consisted of evaluating the impact of an average rise in mean sea level, regarding the drainage system conditions, according to forecasts made by the Intergovernmental Panel on Climate Change (IPCC) [8]. In both situations, which may critically combine effects, planning actions are required in order to control future negative effects, otherwise the human and material losses could become irremediable.
In order to proceed with the proposed analysis, it was necessary to choose a mathematical model to support the simulations. With this aim, a hydrodynamic model for representing rural and urban floods – MODCEL [9, 10 e 11] was used.
The construction of MODCEL, based on the concept of flow cells [12] intended to provide an alternative tool for integrated flood solution design and research. MODCEL is a model that integrates a hydrologic model, applied to each cell in the modelled area, with a hydrodynamic looped model, in a spatial representation that links surface flow, channel flow and underground pipe flow, This arrangement can be interpreted as a hydrologic-hydrodynamic pseudo 3D-model, although all mathematical relations written are one-dimensional. Pseudo 3D representation may be materialised by a vertical hydraulic link used to communicate two different layers of flow: a superficial one, corresponding to free surface channels and flooded areas; and a subterranean one, related to free surface or surcharged flow in storm drains.
The representation of urban surfaces by cells, acting as homogeneous compartments, in which rainfall run-off transformations are performed, allows the integration of all the basin area. The cells interact through hydraulic laws, represented by cell links capable to model different possible flow patterns. Different types of cells and links give versatility to the model. The cells, considered individually as units or taken in pre-arranged sets, are capable to represent the watershed landscape, composing more complex structures. Therefore, the task related to the topographic and hydraulic modelling is an important phase of the process. In large floodable areas, when leaving the drainage network, the water can follow any path, dictated by the topography and by the urban built patterns. Marginal sidewalks may become weirs for the spilling waters from the rivers, the streets may act as canals and the buildings, parks or squares may act like reservoirs. In this situation, it is perceived that overflowed waters may have an independent behaviour from the drainage network, generating their own flow patterns. These characteristics are adequately represented in MODCEL.
The modelled area of Iguaçu-Sarapuí River basin extended from Guanabara Bay to Botas River confluence. The upstream reaches of the basin, which were not divided in cells, had their flows determined through a hydrological model called HIDRO-FLU [13].
The main objective of the modelling of the lower and middle reaches of the Iguaçu River was to evaluate impacts caused by the expansion of uncontrolled urbanisation towards the middle/upper basin, arising from the development expected from the construction of the Metropolitan Ring Road, an important axial roadway.
The effective rainfall calculation method used was that of the SCS [Soil Conservation Service] of the Department of Agriculture of the USA - USDA. The
Past situation: the CN values were defined based on soil types and land use mapping from 1994 (LANDSAT satellite images) [14].
Present situation: the CN values were determined by land use mapping, made on the basis of images from the 2006 Aster sensor [14].
Future situation: assumed that the flat, still rural areas of the sub-basins of the Rivers Iguaçu (upper reach), Botas, Capivari, Pilar and Calombé, and the Outeiro canal will suffer a disorderly process of urbanisation, following the trend of peripherisation in progress in Baixada Fluminense lowlands. This future scenario corresponds to a horizon of approximately 20 years (2030).
Controlled future situation: assumed an alteration in the current pattern of urbanisation of these areas, with the introduction of land use control by means of urban planning actions and adoption of more sustainable urban drainage techniques.
Each modelled cell in the basin representation had an individualised CN, depending on its particular characteristics.
Another objective of the modelling consisted of evaluating the impact of the mean sea level rise, as forecasted by the IPCC, on the drainage conditions of the hydrographical basin. The proposed scenarios tested the isolated and/or associated effect of the following variables:
different hydro-meteorological conditions, alternating typical tidal situations and the effect of meteorological tide;
variation in the soil impervious rates arising from the behaviour of future urbanisation, considering the maintenance of the current rates (without any increase in new urban areas); an increase in the impervious rates due to unplanned urban expansion; and a moderate increase in the rates due to planned control of urban expansion. For each of the simulated scenarios, CN values were adopted as presented in Table 3.
It is important to stress that this paper does not intend to look for final solutions in order to minimise present flood conditions (although this discussion will be considered conceptually in the context of this study, in a nest topic). The main aim refers to the possibility of discussing future conditions worsening due to the inadequate planning process that take place today.
Iguaçu | 65 | 66 | 77 | 72 |
Botas | 81 | 81 | 82 | 81 |
Capivari | 67.5 | 65 | 77.9 | 72 |
Outeiro | 72 | 84 | 84 | 84 |
Pilar | 75 | 76 | 78.2 | 76 |
Calombé | 68 | 79 | 79.8 | 79 |
Curve Number (CN) used in each simulated scenario
The return period considered for the design rainfall was 20 years. The hydrologic parameters and rainfall information adopted were based on the Iguaçu Project [15] calculations. Regarding to the impacts caused by alterations in mean sea level, a local tide table was used as the base information. This table was produced by the Diretoria de Hidrografia e Navegação da Marinha do Brasil (Hydrography and Shipping Directorate of the Brazilian Navy), with values ranging from 0.09 to 0.90m, representing the tidal variation on the Rio de Janeiro coast. The meteorological tides were considered to influence this value with a majoring of 0.80m. Besides, a possible increment of 0.60m in the mean sea level was also considered (IPCC forecast), due to climate change expectative. With the values mentioned, the proposed scenarios were simulated, considering the tidal variations, the dynamics of urbanisation, the rise in the mean sea level, and combinations among these variables.
Figure 2 represents the areas susceptible to flooding for the former conditions of urbanisation (at the time of Iguaçu Project [15]), in the 90’s, without taking into account the meteorological tides and the effects of climate change. It is, therefore, a condition of reference for the current and future scenarios comparison, referring to flooding conditions of more than 15 years ago. It is observed that there are significant differences in floods in past conditions from those in the present scenario. The alteration already occurred in the land occupation in the upper reaches of the basin in the period justifies this result.
The flood maps presented in Figures 3 and 4, respectively, were obtained through the following conditions: current situation of urbanisation in the basin, without considering meteorological tides and the effects of climate change (Scenario 1); and future condition of the basin urbanisation, considering disorderly urban expansion, typical tides and without the effects of climate change (Scenario 2).
Reference flood map for former urban condition
Flood map obtained for the present condition - Scenario 1
Flood map obtained for future condition - Scenario 2
The comparison among these three scenarios allows the assessment of the isolated effect of the urban expansion in the flooding aggravation. When the CN is altered for the upper reaches of the drainage area, in the simulation corresponding to Scenario 2, a significant worsening is noticed in flood conditions, even without any other worsening factor acting, as seen in the comparison of Figures 3 and 4
If effective measures were implemented for land use development control, in order to prevent disorderly occupation in the middle and upper reaches of the basin, it can be seen, in Figure 5 (Scenario 3), that it is possible to avoid the worsening of floods in the referred sub-basins. It is perceived a reduction in the water levels in the densely urbanized areas, when compared with the previous development situation, without any control over land occupation.
The figures 6 and 7, presented in sequence, correspond to the following scenarios:
Figure 6: Flood map obtained for the future conditions of basin urbanisation with urban expansion without control over land use; meteorological tide of 80 cm and a 60 cm rise in the mean sea level due to climate changes (Scenario 4);
Flood map obtained for controlled future condition - Scenario 3
Flood map obtained for future condition, in the context of climate changes - Scenario 4
Figure 7: Flood map obtained for the future conditions of basin urbanisation, with control over the land use development; meteorological tide of 80cm and climate change effects, with a 60 cm rise in mean sea level (Scenario 5).
Flood map obtained for controlled future condition, in the context of climate changes- Scenario 5
These two scenarios test the conjugated effect of the three variables considered in the simulations: urbanisation of the upper basin, presence of meteorological tide and mean sea level rise. Based on these scenarios, it is possible to conclude that the disorderly urbanisation of the upper basin causes flooding aggravation in the downstream urban areas already consolidated, while the tidal variations cause even greater floods in the lower reaches (under tidal influence). The sea level rise will worsen the floods in the urban areas situated at low elevations, near the Iguaçu River estuary.
Both the urban expansion and the sea level rise are going to cause great impacts on the urban areas of the basin. Despite having their causes explained by independent variables, these factors, if combined, would lead to serious impacts on the population resident in the basin. If planning measures are not taken in advance, it will be very difficult to mitigate their impacts later.
The urban drainage system includes two major subsystems: micro-drainage and macro-drainage. The micro-drainage system consists of the paving of streets, gutters, gullies, stormdrains and channels of small dimensions, intending to collect the runoff and conduct it to the macro-drainage net. Macro-drainage generally consists of natural or built channels of larger dimensions, receiving the input from micro-drainage, concentrating flows and discharging in the receiving water body. A complementary set of structures also take part in drainage systems, among which is possible to mention: reservoirs, protective dikes, and pumping stations. All these structures are arranged and designed to work in an n integrated way, intercepting, conveying, possibly infiltrating or temporarily storing and discharging the generated runoff. Ultimately, the receiving water body is the sea and this is the case of Iguaçu-Sarapuí Rivers.
The urban flooding process, by its turn, is directly associated with the failure of these subsystems, due to lack of maintenance, obsolescence, disordered urban growth or, as stated in recent discussions, due to the possibility of climate changes worsening flow conditions. Specifically to the drainage systems, the negative effects that may arise from the situation of climate changes refer to the increase of extreme rainfall events intensity, and to the restriction imposed by the expected sea level rise at the basin outfall. Evaluating this context, the increase in the mean sea level causes a reduction in the discharge capacity of the system, causing the drainage net to lose efficiency. The worsening of the extreme rainfall events intensity works in the other part of the problem, generating greater volumes to be drained by a system whose discharge capability diminished because of the new outfall restrictions. In this situation, in a context of already serious urban flooding problems, the effects generated by the possibility of climate changes can dramatically increase flooding areas, causing them to reach locations not previously affected by floods, increasing inundation depths and residence times, making the situation even worse.
Understanding how urbanisation affects floods is very important for urban flood control design. In general, it is possible to say that the urban flood control conjugates the adoption of structural measures that change the landscape of the basin, introducing interventions inside and outside the drainage network, to act directly in minimising the problem, and non-structural measures, associated with land use planning, environmental education and several possible other measures that allow a more harmonious coexistence with the phenomenon of flooding. The combination of structural and non-structural measures, in a context of planning integrated with urban growth, allows a composition capable of solving the problem of flooding in a harmonious and sustainable way. This approach, which is relatively recent, is being considered more appropriate to treat the urban flooding problem, by treating the problem in a systemic way and proposing actions that seek to minimize the impacts of urbanization.
This trend, though not motivated by the possibility of climate change, also goes toward this theme, with the possibility of reaching effective results, in opposition to the traditional approach that basically considers propositions of rectifying and canalising water courses. In this perspective, the traditional approach treats the consequence of the problem, related to the generation of exceeding superficial flows. The possibility of the mean sea level rising, however, limits the discharge capacity of the system and makes the traditional approach to fail. Thus, in this context, it is necessary to treat the problem of flow generation, acting in the causes of flooding, while trying to introduce infiltration and storage measures spread over the urban basin landscape in order to reduce and delay flood peaks, allow groundwater recharge and seek to restore the approximate natural flow conditions. This approach introduces the sustainable urbanization concept, proposing that the flood should not be transferred in space or time. This way, storage and infiltration measures may be important measures for sustaining adequate drainage conditions. Storage measures should consider detention or retention reservoirs, acting in-line with rivers or in the base of hill slopes, or combined in multifunctional landscapes in parks and public squares, or even in the plot level, as an on-source control option. By its turn, infiltration measures may involve reforestation actions, the use of pervious paving, or infiltration trenches, among others. All these measures, properly designed in an integrated manner, might be able to work preventively or correctively, if necessary, modifying the spatial and temporal distribution of flows, to face the new challenges.
The storage measures, because of their applicability and diversity of use, in different combinations with the drainage net configuration, are highlighted in this conceptual discussion. The reservoirs are able to attack the problem of flooding worsening, both from the point of view of the uncontrolled urban growth, as well as from the point of view of possible climate changes. The storage capacity of these reservoirs allows facing the larger volumes and to control surface runoff released to the network, minimising chances of system failure, with a time of response that matches the velocity of the critical superficial processes that generates floods. Infiltration measures are very important, because they are able to reduce flow volumes, but infiltration process takes more time and, in this case, time may be a critical factor when trying to control floods. So, infiltration measures are desirable, but may usually they do not prescind from storage measures.
The Iguaçu Project, related to the first Water Resources Management Master Plan, was the reference scenario used in this study. After more than one decade, the revision of the Water Resources Management Master Plan for Iguaçu-Sarapuí River Basin started in 2007 and finished in 2009. Lack of an adequate urban land use control and unplanned city growth led to several problems, as discussed previously. In the newer version of The Master Plan, the original set of proposed measures was reviewed. Part of these measures was maintained, especially in consolidated areas; however, whenever possible, new concepts on sustainable urban drainage were introduced. The basin was considered in an integrated way and environmental recovery concerns were added to the new plan. Irregular occupations of risky areas, subjected to frequent flooding, and especially riverbanks occupations, were considered not appropriated and people living in these houses without proper safe conditions needed to be relocated.
Both structural and non-structural measures were proposed for flood control purposes, ranging from short to long-term actions. Some of the proposed actions aiming to give more sustainable solutions considered:
the maintenance of natural spaces free from urbanisation, preventing vegetation removal and the aggravation of flooding at the consolidated urban areas;
the recovery of lost vegetated areas;
a land use regulation and control, by means of the establishment of formal Environmental Preservation Areas;
the implementation of urban parks;
the creation of public consortiums for integrated planning of policies for multi-counties interests (recognising the importance of the metropolitan planning);
the revision and adaptation of the municipalities urban planning instruments.
In terms of flood control, riverbanks protection and natural vegetation preservation, three types of parks were proposed, as basic measures to be reproduced in a distributed way over the basin, encompassing the following functions (figure 8):
Fluvial Urban Park – longitudinal parks along rivers, with the purpose of protecting river banks from irregular occupation by low income population.
Flooding Urban Park – longitudinal parks implemented in low elevation areas to allow frequent inundations, with a storage function intending to help in damping flood peaks.
Environmental Urban Park – parks with greater dimensions, flat or not, with the purpose of environmental preservation and land use valuing, aiming to minimise runoff generation and maintaining a buffer of pervious surfaces.
The figures 9 and 10 show two more detailed examples of the proposed parks, in practical conditions, being one for Sarapuí River, and another for Iguaçu River.
Complementary actions held by the State include the articulation with every Municipality in the basin, in order to implement the proposed measures, create local conditions for urban land use control and develop environmental education campaigns, with the financing of the Federal Government, through a specific Program of Developing Acceleration (PAC, in Portuguese). Besides, a habitation program is also being conducted in the basin, in order to support and allow people relocation from risky areas to safer near areas.
Fluvial parks typology – proposed distributed measures for flood control and environmental recovery
Flooding Urban Park examples – Sarapuí River
Flooding Urban Park examples – Iguaçu River
Promoting integration of public policies that interact with the water resources is probably the most urgent and complex task on the agenda of public administrators who are really committed to a sustainable future for the metropolitan areas.
There are reasons to believe that the new institutional arrangements in place in the country offer alternatives for the shared responsibilities involving states and municipalities, mainly in the large urban agglomerations. Specifically, in relation to municipalities, there is a vast spectrum of possibilities to be pursued within the Statute of the City. The new Master Plans can and must incorporate more effective mechanisms for land use management, using a greater range of legal, economic and fiscal instruments focused on urban development on a sustainable basis. However, master plans for urban development still lack mechanisms of inter-municipal coordination and regional agreements orientations that may prevent eventual unintended consequences of land use regulations, from one municipality to another.
The Iguaçu-Sarapuí River basin still embodies conditions favourable to planning for urban flooding, albeit devised to apply for the long term. A significant part of its territory remains in the form of areas still not incorporated into the urban fabric – notably the areas situated between the mountains that rise abruptly and the lowland itself. This enables the maintenance of areas with high soil pervious rates, provided that the urban fabric does not expand to those areas.
The disorderly occupation in Baixada Fluminense lowlands is going to increase the frequency and intensity of the urban floods, causing major damage to the already urbanized areas. The main limiting factor for the expansion of the urban perimeter is the lack of highway connection and regular mass transport lines in the upper parts of the basin, maintaining low occupation rates and rural activities in these areas. It is also worth highlighting the lack of preparation of local administrations to deal with the probable resulting impacts of climate change, above all in urban areas situated at low elevations in relation to the sea level.
Some of the actions proposed by this study were:
maintenance of spaces free from urbanisation, preventing the aggravation of flooding at the consolidated urban areas;
land use regulation and control, by means of the establishment of formal Environmental Preservation Areas;
implementation of urban parks, mainly for storage purposes, minimising flooding impacts and preparing the basin for future worse climatic conditions;
creation of public consortiums for integrated planning of policies for multi-counties interests (recognizing the importance of the metropolitan planning);
revision and adaptation of the urban planning instruments for the municipalities.
Complementary actions of state responsibility include articulation with every Municipality in the basin, in order to implement the proposed measures, create local conditions for urban land use control and develop environmental education campaigns about the risks of worsening the floods.
The first author is grateful to the Support Program Postdoctoral CAPES/FAPERJ. The second author acknowledges CNPq for his research support.
Lignocellulosic biomass is the most abundant, renewable, and one of the cheapest carbon neutral raw materials in the biosphere that can be used to produce sustainable products such as biofuels, using different technologies [1]. The lignocellulosic biomass consists of mainly cellulose carbohydrate polymer, hemicellulose, and the aromatic component, lignin [2]. Lignocellulose biomass can store up to 47 MJkg−1 more energy than lithium ion batteries (0.8 MJkg−1) [3]. Lignocellulose biomass is considered a potential candidate to sustainable green alternative source of energy and chemicals due to its high energy density, volatile matter content, and global widespread [3]. The release of volatile matter and other contents in biomass has been extensively studied using pyrolysis technology. Pyrolysis involves the conversion of biomass into bio-oil, gases (volatile matter) and biochar, in the absence of oxygen [4, 5]. The technique is robust and essential in providing vital knowledge of kinetics of devolatilization of any biomass prior to further processing via different conversion technologies. In addition, pyrolysis is effective in reducing the bulky biomass into uniform, energy dense, and easily transportable fuel [6]. Despite always being the first stage in most combustion or gasification process, there are no accurate and enough data on the kinetics and reaction mechanisms of different lignocellulosic biomass [7]. This is attributed to the complexity and the varying physico-chemical properties in different lignocellulosic biomass [7]. In addition, there may be many reactions occurring from the extremely complex pyrolysis process of the lignocellulose biomass [8]. Therefore, developing accurate kinetic models to account for all reactions taking place remains a challenge [6]. Isolation of the complex lignocellulosic biomass into individual fractions and characterization of the individual fractions can provide a better understanding of the combustion kinetics and reaction mechanism. Different biomass isolation/extraction techniques such as liquid-liquid, liquid-solid, acid-base, ultrasound, and microwave-assisted extractions, among others, have been reported before [9]. The choice of the method depends on the biomass type and its fraction to be isolated [9]. Hence, each procedure affects the sample’s product yields and physical, chemical, kinetic, and thermodynamic properties differently. Despite the studies on the yields and operating parameters such as solvent and time [9], less or no information is available regarding the kinetic and thermodynamic parametric studies for the combustion of the isolated lignocellulose fractions to assess the difference in the extraction processes. Different general kinetic models on lignocellulose biomass have been suggested [10, 11].
Date palm waste constitutes about 500,000 metric tons per year from ca. 44 million date palm trees found in the United Arab Emirates where this research was conducted. The aims of this research are to isolate cellulose from date palm lignocellulose complex using low concentration acid-base solutions and Organosolv techniques and to model nonisothermal combustion kinetics using model-free methods and finally to predict the most probable mechanistic reaction mechanism of the isolated celluloses. Using thermal-gravimetric technique at different heating rates, kinetic and thermodynamic parameters were calculated using model-free methods, namely Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO), and Starink models. The FWO model-free method compensates the experimental measurement errors. However, the KAS and Starink methods depend on the choice of good constant degree of conversion from the derivative mass loss function to provide precision of the kinetic data [12]. In addition, application of different model-free methods involves wide conversion range that allows for study of change in mechanism during a reaction and reduces mass transfer limitations by using multiple heating rates [13].
The rachis part of adult date palm waste (DPW) (10–15 years old) was supplied by the UAE University farm, Al foah, Al Ain. The samples were ground to 180-micron particle size to reduce the effects of heat and mass transfer limitations. All the solvents (ACS grade) and reagents were supplied by Sigma Aldrich and were used with no further purification. Prior to cellulose isolation, 10 g biomass was valorized with benzene/ethanol (2, 1 v/v) for 48 h using Soxhlet extraction to reduce extractives such as waxes and resins surrounding the lignocellulose complex.
For acid-base isolation; DPW (5 g) extractive-free sample of particle size 180 μm was placed in a 250-mL beaker and leached with 200 mL of 0.1 M HCl while heating at 100°C for 2 h under stirring at 150 rpm. After vacuum filtration, the cellulose and lignin-rich residue was washed with 20 mL of deionized water to remove any residual hemicellulose and then air dried overnight. The hemicellulose was solubilized by HCl and heating due to its labile nature making it easy to dissolve out of the lignocellulose complex. The cellulose- and lignin-rich residue was further treated with 200 mL of 0.1 M NaOH while heating at 100°C for 2 h under constant stirring at 150 rpm. After subsequent vacuum filtration of the mixture, the cellulose-rich residue was washed with 20 mL of 0.1 M NaOH to remove any residual lignin. The isolated cellulose was air dried under laboratory conditions overnight prior to characterization.
For Organosolv isolation, DPW were isolated using methanol/water solvents as reported in literature, with some modifications [14]. The 6.7 g sample of particle size 180 μm was placed in high pressure/temperature reactor vessel (Parr 4848, U.S.A). A mixture of 84 mL sulfuric acid (0.045 N), 13.4 mL formaldehyde (37 wt.%), and 84 mL methanol was added to the reactor vessel containing the sample. The reactor was sealed and purged with nitrogen gas (6–10 bars), and the reaction was performed for 1 h at 160°C under constant stirring at 700 rpm. The product mixture was vacuum filtered after cooling to room temperature. The cellulose-rich residues were air dried overnight prior to characterization, and the yield was determined by a gravimetric analysis technique. The ultimate analysis was conducted, and the results are recorded in Table 1.
Proximate and ultimate analyses | Date palm lignocellulose | Organosolv cellulose | Acid-base cellulose |
---|---|---|---|
Moisture content (wt.%) | 6.72 ± 0.4 | 7.08 ± 0.4 | 8.72 ± 0.4 |
Volatile matter (wt.%) | 78.62 ± 0.04 | 65.22 ± 0.02 | 66.92 ± 0.01 |
Ash content (wt.%) | 6.12 ± 0.1 | 7.36 ± 0.04 | 7.24 ± 0.01 |
Fixed carbon (wt.%) | 5.40 ± 0.01 | 4.40 ± 0.10 | 4.80 ± 0.14 |
HHV (MJkg−1) | 17.28 | 15.46 | 15.18 |
Cellulose yield (wt.%) | — | 43.15 ± 2.40 | 64.15 ± 2.40 |
Physicochemical analysis of biomass (dried basis).
The IRTrace-100 FTIR spectrophotometer (Shimadzu, Kyoto, Japan) was used for the FTIR analysis. The extracted celluloses were analyzed to investigate the difference in the functional groups after extraction. The spectral results were recorded within a range of 500–4000 cm−1 wavelength using 4 cm−1 spectral resolution and 34 scans. Figure 1 shows several major absorption bands and the difference between the samples. DPW sample before isolation showed typical lignocellulose strong band absorption bonds. For instance, the bands at 1037 cm−1 indicating C▬O, C〓C and C▬C bond stretching, between 2840 and 2926 cm−1 indicating C▬H stretching and 3200–3474 cm−1 for O▬H stretching, were assigned to cellulose, hemicellulose and lignin, respectively. Similar results were reported for other biomass in the literature [15]. However, there were noticeable changes in the functional groups of celluloses from the same biomass with reduction in the peak intensity, an indication of component(s) removal (plausibly lignin and hemicellulose). For instance, the would-be lignin and hemicellulose band intensity at 1037 cm−1 greatly reduced an indication of component(s) removal. The C▬H bond stretching in the region of 2840 assigned to lignin in DPW was absent in isolated cellulose samples. In addition, the reduced peak intensity between 845 and 1156 cm−1 associated with the C▬O▬C asymmetrical stretching and glycosidic bond, a characteristic of cellulose, was observed. Furthermore, the decrease in OH vibration strength around 3200–3474 cm−1 indicates a reduction in some of the OH-containing compounds which are phenolics from lignin. It is worth to note that both extraction methods showed similar functional groups except that the Organosolv cellulose had C▬H bond assigned to lignin in the region around 2326 and 2363 cm−1 which was absent for the acid-base cellulose samples. The FTIR results showed the effectiveness of the cellulose isolation methods from DPW biomass complex. The samples were further characterized for their morphological differences using SEM imaging technique.
FTIR spectrum of (a) lignocellulose DPW, (b) Organosolv cellulose and (c) acid-base cellulose.
The structural morphologies of the isolated cellulose were analyzed using the scanning electron microscope (JEOL Neoscope JCM-5000, Tokyo Japan). The samples were Au/C coated using vacuum spatter while clamped on the sample holder. The images were captured on spot size of 40 using 10 kV. The SEM results in Figure 2 show a difference in the structural morphologies between the cellulose samples from the two methods. Figure 2(a) shows the original DPW with ring-like structures (see the arrow point) plausible to be the cellulose chiral nematic ordering, surrounded by irregular shaped structures which could be assumed to be lignin and hemicellulose. Acid-base cellulose in Figure 2(b) showed porous surface similar to those reported for cellulose from the teak wood [16]. However, Organosolv cellulose (Figure 2(c)) showed an aggregate of cellulose block structure with uneven polished surface.
SEM images of the (a) original rachis, (b) acid-base cellulose and (c). Organosolv cellulose captured at magnification X1000.
The combustion characteristics of isolated celluloses were studied using thermogravimetric analysis (TGA). The analysis was done on a TGA (Q500, TA instrument). Samples of 6 mg (±1.0) were first equilibrated at 25°C for 5 min and then heated at specific heating rates of 10, 15, 20, and 25°C/min to 900°C. The process was performed under constant nitrogen environment flowing at 20 mL/min. As the thermal decomposition progressed, the change in weight was recorded continuously as a function of temperature and time. Figure 3 shows the isoconversion versus temperature at different heating rates for the isolated celluloses from DPW. The conversion curves for acid-base (colored) and Organosolv (black) methods below 300 and 340°C, respectively, showed similar thermal decomposition patterns at all heating rates. There was a slight shift toward higher temperature side with increasing heating rates, possibly due to the increasing thermal energy in the system [17]. However, at higher temperatures, the conversion pattern changed for both methods, possibly due to the change in the degradation chemistry of components under pyrolysis. It is worth to note that Organosolv cellulose showed better thermal stability than the acid-base cellulose. Figure 4 shows the differential thermogravimetric (DTG) results against temperature at different heating rates for the DPW and the isolated celluloses. The results showed a typical thermal degradation of lignocellulose biomass. The curves of both samples moved downward as the heating rate increased, owing to the shorter reaction time at increasing temperature, a phenomenon known as thermal hysteresis. However, Figure 4(a) showed a noticeable difference between the peak mass loss patterns compared to Figure 4(b) for the two cellulose methods, which suggests a difference in the degradation chemistry. Table 2 shows the temperature ranges that define the major stages of mass loss in response to increasing temperature for isolated celluloses from both methods, as given in Table 3. Stage I started from minimum temperature, Tmin to T1, the total average celluloses mass loss for acid-base and Organosolv were 9.46 ± 0.1 and 5.28 ± 0.1%, respectively. This was attributed to the inherent moisture and water molecules embedded in the intercellular and intracellular void spaces of the celluloses. Stage II, from T1 to T3 for both methods, there was only one major clear peak (Figure 4(b)) and the average mass loss in this region was 72.51 ± 0.7 and 55.82 ± 1.1%, for acid-base and Organosolv celluloses, respectively. The weight loss in this stage is associated with pyrolysis of mainly cellulose and to a lesser extent hemicellulose [18]. Compared to the three peaks observed in Figure 4(a) for the original DPW, this clearly shows that both methods were effective for cellulose isolation from the complex lignocellulose matrix of DPW. Stage III had total average mass loss of 8.68 ± 1.2 and 33.08 ± 0.8%, for acid-base and Organosolv methods, respectively. This represented combustion of the carbonaceous and some part of char oxidation [19]. In addition, the higher mass loss for Organosolv cellulose was plausibly due to residual lignin. Moreover, the FTIR results showed some lignin functional groups for this method. The last stage was associated with charring process and ash formation. The average total mass loss for acid-base and Organosolv methods in this stage were 9.57 ± 1.3 and 5.20 ± 0.4%. TGA analysis data was used for kinetic modeling using the model-free methods.
The relationship of conversion against temperature for acid-base cellulose (colored) and Organosolv cellulose (black).
The relationship of DTG against temperature for (a) date palm waste and (b) isolated celluloses (acid-base, colored; Organosolv, black).
Heating rate (°C min−1) | Tmin (°C) | T1 (°C) | T2 (°C) | T3 (°C) | Tmax (°C) |
---|---|---|---|---|---|
10 | 30 | 192 | 266 | 402 | 900 |
15 | 197 | 273 | 406 | ||
20 | 199 | 279 | 411 | ||
25 | 201 | 381 | 415 | ||
10 | 30 | 220 | 318 | 422 | 900 |
15 | 226 | 324 | 435 | ||
20 | 227 | 328 | 441 | ||
25 | 228 | 330 | 450 |
Characteristic temperatures associated with mass loss during pyrolysis of cellulose.
Stages | Temperature | Heating rate (°C min−1) | |||
---|---|---|---|---|---|
10 | 15 | 20 | 25 | ||
Stage I, WL% | Tmin–T1 | 10.06 | 9.17 | 9.33 | 9.26 |
Stage II, WL % | T1–T3 | 71.59 | 72.76 | 73.16 | 72.52 |
Stage III, WL % | T3–Tmax | 10.18 | 8.88 | 7.30 | 8.35 |
Final residue at 900-100 °C (%) | 7.99 | 9.19 | 11.21 | 9.87 | |
Stage I, WL % | Tmin–T1 | 4.35 | 5.24 | 5.72 | 5.79 |
Stage II, WL % | T1–T3 | 54.42 | 56.16 | 57.16 | 55.55 |
Stage III, WL % | T3–Tmax | 35.57 | 33.30 | 32.24 | 33.69 |
Final residue at 900-100 °C (%) | 5.66 | 5.30 | 4.88 | 4.97 |
Mass loss (%) during different stages of cellulose pyrolysis.
The TGA data were used to calculate the nonisothermal kinetic and thermodynamic parameters using model-free equations of Flynn-Wall-Ozawa (FWO), Kissinger-Akahila-Sunose (KAS), and Starink reported in the literature [20].
where
where
The choice for these model-free methods is because no previous knowledge about reaction mechanism is required to determine the reaction activation energy [21]. The preexponential factor (A) and thermodynamic parameters [enthalpy (
where
The activation energies for both sample methods were calculated using the three models, namely FWO, KAS, and Starink. These model-free methods avoid the shortcomings during model fitting and kinetic compensation effects. The FWO model-free method compensates the experimental measurement errors. However, the KAS and Starink methods depend on the good constant degree of conversion from the derivative mass loss function to provide precision of the kinetic data [12]. Therefore, application of different model-free methods involves a wide conversion range that allows for the study of change in mechanism during a reaction and reduces mass transfer limitations by using multiple heating rates [13]. Figure 5 shows the relationship of activation energy and enthalpy from the three model-free methods for acid-base and Organosolv celluloses. Results showed little or no difference between
Activation energy and enthalpies of (a) acid-base cellulose and (b) Organosolv by three model-free methods.
Tables 4–6 show other thermodynamic parameters from the three model-free methods for the acid-base and the Organosolv cellulose samples, respectively. The
FWOa | FWOb | |||||
---|---|---|---|---|---|---|
α | Log A (s−1) | ΔG (kJmol−1) | ΔS (Jmol−1) | Log A (s−1) | ΔG (kJmol−1) | ΔS (Jmol−1) |
0.1 | 10.17 | 151.46 | −0.12 | 27.20 | 84.18 | 0.21 |
0.2 | 10.96 | 164.16 | −0.11 | 27.24 | 91.96 | 0.21 |
0.3 | 11.34 | 171.76 | −0.10 | 27.26 | 94.86 | 0.21 |
0.4 | 11.79 | 178.07 | −0.09 | 27.15 | 97.26 | 0.21 |
0.5 | 12.13 | 183.36 | −0.08 | 27.17 | 100.17 | 0.21 |
0.6 | 12.25 | 189.25 | −0.08 | 27.53 | 109.59 | 0.21 |
0.7 | 12.17 | 198.03 | −0.08 | 25.07 | 136.91 | 0.17 |
0.8 | 11.15 | 216.34 | −0.10 | 21.64 | 167.53 | 0.10 |
0.9 | 11.28 | 243.04 | −0.10 | 23.20 | 192.64 | 0.13 |
Av |
The kinetic and thermodynamic parameter values of celluloses determined by FWO model.
Acid-base.
Organosolv.
R2 were above 0.98.
KASa | KASb | |||||
---|---|---|---|---|---|---|
α | Log A (s−1) | ΔG (kJmol−1) | ΔS (Jmol−1) | Log A (s−1) | ΔG (kJmol−1) | ΔS (Jmol−1) |
0.1 | 31.09 | 138.51 | 0.28 | 76.86 | 81.66 | 1.16 |
0.2 | 34.78 | 149.86 | 0.35 | 76.54 | 89.24 | 1.15 |
0.3 | 36.56 | 156.67 | 0.38 | 76.62 | 92.06 | 1.16 |
0.4 | 38.05 | 162.34 | 0.41 | 76.69 | 94.38 | 1.16 |
0.5 | 39.18 | 167.12 | 0.43 | 76.76 | 97.21 | 1.16 |
0.6 | 40.29 | 172.40 | 0.46 | 76.72 | 106.42 | 1.16 |
0.7 | 41.65 | 180.30 | 0.48 | 72.62 | 132.86 | 1.08 |
0.8 | 43.89 | 196.73 | 0.52 | 71.44 | 162.07 | 1.05 |
0.9 | 46.97 | 220.82 | 0.58 | 78.19 | 186.28 | 1.18 |
Av |
The kinetic and thermodynamic parameter values of celluloses determined by KAS model.
Acid-base
Organosolv.
R2 were above 0.98.
STARINKa | STARINKb | |||||
---|---|---|---|---|---|---|
α | Log A (s−1) | ΔG (kJmol−1) | ΔS (Jmol−1) | Log A (s−1) | ΔG (kJmol−1) | ΔS (Jmol−1) |
0.1 | 29.65 | 138.69 | 0.25 | 74.89 | 81.73 | 1.12 |
0.2 | 33.82 | 149.97 | 0.33 | 74.76 | 89.30 | 1.12 |
0.3 | 35.63 | 156.78 | 0.37 | 74.59 | 92.13 | 1.12 |
0.4 | 36.99 | 162.47 | 0.39 | 74.71 | 94.46 | 1.12 |
0.5 | 38.15 | 167.24 | 0.41 | 74.80 | 97.28 | 1.12 |
0.6 | 39.22 | 172.53 | 0.43 | 74.83 | 106.50 | 1.12 |
0.7 | 40.55 | 180.43 | 0.46 | 70.70 | 132.96 | 1.04 |
0.8 | 42.60 | 196.89 | 0.50 | 69.46 | 162.20 | 1.01 |
0.9 | 45.58 | 221.00 | 0.55 | 76.04 | 186.43 | 1.14 |
Av |
The kinetic and thermodynamic parameter values of celluloses determined by STARINK model.
Acid-base
Organosolv.
R2 were above 0.98.
Malek method which is the commonly used approach to determine probable reaction mechanism involving heterogeneous reaction was used [26]. The Malek method is described by the following equation.
where
The theoretical z(α) plots versus α depend on
Experimental and theoretical Z(α) master plots for pyrolysis of acid-base cellulose at (a) 10°Cmin−1, (b) 15°Cmin−1, (c) 20°Cmin−1 and (d) 25°Cmin−1.
Experimental and theoretical Z(α) master plots for pyrolysis of Organosolv cellulose at (a) 10°Cmin−1, (b) 15°Cmin−1, (c) 20°Cmin−1 and (d) 25°Cmin−1.
The experimental and the fitted z(α) master plots of acid-base cellulose showed a normal distribution behavioral curve trend for all model-free methods at investigated heating rates. However, Organosolv cellulose showed a sigmoid curve skewed more to the left hand side. The correlation coefficient of acid-base method ranged between 0.9789 and 0.9884, while that of Organosolv ranged between 0.9525 and 0.9795, signifying the accuracy in the reported data. It is worth to note that both methods had best fit at 15°C/min. The data were fit with polynomial curves of n = 3 and n = 4 for Organosolv and acid-base celluloses, respectively, implying third and fourth dimension growth as described by general Avrami-Erofeev model of multidimensional nuclei and random growth reaction mechanism (
The low cost and high yield acid-base and Organosolv methods were assessed for isolation of cellulose from date palm lignocellulose waste biomass. The structural, chemical, and morphological characterizations of the isolated celluloses were studied. The nonisothermal combustion studies were investigated using three different model-free methods. The reaction mechanism was studied using Malek method.
The SEM images revealed chiral nematic orderings structures distinctive of cellulose. The change in FTIR peak intensity and the difference in the vibrational bond stretching among the isolated celluloses and between original biomass signified component removal from the lignocellulose complex. The TGA results from both methods showed one major decomposition peak assigned to cellulose in contrast to original biomass with three peaks. The results further revealed a possible difference in the degradation chemistry at higher temperature where isoconversion was higher than 0.6.
The FWO model for the acid-base method gave the lowest activation energy (99.77–173.76 kJmol−1) and the Organosolv method by KAS model gave the highest activation energy (419.63–934.49 kJmol−1). There was a strong relationship between activation energy and enthalpy, and the positive enthalpy values confirmed that endothermic reaction took place during the pyrolysis of the cellulose samples. The Gibbs’s free energy, ΔG, results revealed that Organosolv cellulose pyrolysis reaction would easily reach equilibrium, much easier in a trend of KAS > Starink> FWO models. The measure for disorder was less favorable for the acid-base method with negative entropy values in the FWO model-free method.
The reaction mechanism by Malek method was described by Avrami-Erofeev model mechanism (
The results of this study confirm the existence of multistep mechanism occurring in solid-state reactions due to variations in activation energy with the heating rates. The study provides important data information and a robust approach to understanding the cellulose pyrolysis structures and mechanisms by different isolation methods across a broad range of temperature and different heating rates.
This work was financially supported by the Emirates Centre for Energy and Environment Research, UAEU (31R107).
The authors declare no conflict of interest.
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The Open Access publishing movement started in the early 2000s when academic leaders from around the world participated in the formation of the Budapest Initiative. They developed recommendations for an Open Access publishing process, “which has worked for the past decade to provide the public with unrestricted, free access to scholarly research—much of which is publicly funded. Making the research publicly available to everyone—free of charge and without most copyright and licensing restrictions—will accelerate scientific research efforts and allow authors to reach a larger number of readers” (reference: http://www.budapestopenaccessinitiative.org)
\n\nIntechOpen’s co-founders, both scientists themselves, created the company while undertaking research in robotics at Vienna University. Their goal was to spread research freely “for scientists, by scientists’ to the rest of the world via the Open Access publishing model. The company soon became a signatory of the Budapest Initiative, which currently has more than 1000 supporting organizations worldwide, ranging from universities to funders.
\n\nAt IntechOpen today, we are still as committed to working with organizations and people who care about scientific discovery, to putting the academic needs of the scientific community first, and to providing an Open Access environment where scientists can maximize their contribution to scientific advancement. By opening up access to the world’s scientific research articles and book chapters, we aim to facilitate greater opportunity for collaboration, scientific discovery and progress. We subscribe wholeheartedly to the Open Access definition:
\n\n“By “open access” to [peer-reviewed research literature], we mean its free availability on the public internet, permitting any users to read, download, copy, distribute, print, search, or link to the full texts of these articles, crawl them for indexing, pass them as data to software, or use them for any other lawful purpose, without financial, legal, or technical barriers other than those inseparable from gaining access to the internet itself. The only constraint on reproduction and distribution, and the only role for copyright in this domain, should be to give authors control over the integrity of their work and the right to be properly acknowledged and cited” (reference: http://www.budapestopenaccessinitiative.org)
\n\nOAI-PMH
\n\nAs a firm believer in the wider dissemination of knowledge, IntechOpen supports the Open Access Initiative Protocol for Metadata Harvesting (OAI-PMH Version 2.0). Read more
\n\nLicense
\n\nBook chapters published in edited volumes are distributed under the Creative Commons Attribution 3.0 Unported License (CC BY 3.0). IntechOpen upholds a very flexible Copyright Policy. There is no copyright transfer to the publisher and Authors retain exclusive copyright to their work. All Monographs/Compacts are distributed under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0). Read more
\n\nPeer Review Policies
\n\nAll scientific works are Peer Reviewed prior to publishing. Read more
\n\nOA Publishing Fees
\n\nThe Open Access publishing model employed by IntechOpen eliminates subscription charges and pay-per-view fees, enabling readers to access research at no cost. In order to sustain operations and keep our publications freely accessible we levy an Open Access Publishing Fee for manuscripts, which helps us cover the costs of editorial work and the production of books. Read more
\n\nDigital Archiving Policy
\n\nIntechOpen is committed to ensuring the long-term preservation and the availability of all scholarly research we publish. We employ a variety of means to enable us to deliver on our commitments to the scientific community. Apart from preservation by the Croatian National Library (for publications prior to April 18, 2018) and the British Library (for publications after April 18, 2018), our entire catalogue is preserved in the CLOCKSS archive.
\n\nOpen Science is transparent and accessible knowledge that is shared and developed through collaborative networks.
\n\nOpen Science is about increased rigour, accountability, and reproducibility for research. It is based on the principles of inclusion, fairness, equity, and sharing, and ultimately seeks to change the way research is done, who is involved and how it is valued. It aims to make research more open to participation, review/refutation, improvement and (re)use for the world to benefit.
\n\nOpen Science refers to doing traditional science with more transparency involved at various stages, for example by openly sharing code and data. It implies a growing set of practices - within different disciplines - aiming at:
\n\nWe aim at improving the quality and availability of scholarly communication by promoting and practicing:
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His studies in robotics lead him not only to a PhD degree but also inspired him to co-found and build the International Journal of Advanced Robotic Systems - world's first Open Access journal in the field of robotics.",institutionString:null,institution:{name:"TU Wien",country:{name:"Austria"}}},{id:"441",title:"Ph.D.",name:"Jaekyu",middleName:null,surname:"Park",slug:"jaekyu-park",fullName:"Jaekyu Park",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/441/images/1881_n.jpg",biography:null,institutionString:null,institution:{name:"LG Corporation (South Korea)",country:{name:"Korea, South"}}},{id:"465",title:"Dr",name:"Christian",middleName:null,surname:"Martens",slug:"christian-martens",fullName:"Christian Martens",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:null},{id:"479",title:"Dr.",name:"Valentina",middleName:null,surname:"Colla",slug:"valentina-colla",fullName:"Valentina Colla",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/479/images/358_n.jpg",biography:null,institutionString:null,institution:{name:"Sant'Anna School of Advanced Studies",country:{name:"Italy"}}},{id:"494",title:"PhD",name:"Loris",middleName:null,surname:"Nanni",slug:"loris-nanni",fullName:"Loris Nanni",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/494/images/system/494.jpg",biography:"Loris Nanni received his Master Degree cum laude on June-2002 from the University of Bologna, and the April 26th 2006 he received his Ph.D. in Computer Engineering at DEIS, University of Bologna. 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They were derived from erbium-doped fiber amplifiers, which are still important component for telecommunications. Since discovery, fiber laser has become a natural choice for many uses, primarily because of the physical characteristics of fiber waveguide structure. Their rapid progress may show how excellent they really are. Although fiber lasers are today widely used in various research and industrial areas, one of the most meaningful applications of fiber laser technology has been through its use in medicine. A wide variety of wavelengths generated by fiber lasers as well as the diversity of physical mechanisms employed in pulse generation also additionally underpins the flexibility of fiber laser technology. This study is devoted to background technology of fiber lasers in the light of medical applications. Basic physics and theories of optical fibers and their important properties are introduced.",book:{id:"6467",slug:"optical-amplifiers-a-few-different-dimensions",title:"Optical Amplifiers",fullTitle:"Optical Amplifiers - A Few Different Dimensions"},signatures:"Amira Tandirovic Gursel",authors:[{id:"240070",title:"Dr.",name:"Amira",middleName:null,surname:"Tandirovic Gursel",slug:"amira-tandirovic-gursel",fullName:"Amira Tandirovic Gursel"}]}],mostDownloadedChaptersLast30Days:[{id:"63129",title:"Laser Ablation Technique for Synthesis of Metal Nanoparticle in Liquid",slug:"laser-ablation-technique-for-synthesis-of-metal-nanoparticle-in-liquid",totalDownloads:2550,totalCrossrefCites:8,totalDimensionsCites:25,abstract:"Recently, the synthesis and application of metal and ceramic nanoparticle are significant subject in science and engineering. The metal nanoparticles such as silver, gold, and copper nanoparticles have more application in material science, nanomedicine, electronic, photonic, and art. One of the green methods for preparation of metal nanoparticles is laser ablation technique that offers a unique tool for nanofabrication of nanoparticles. In this technique, the high-power laser ablates the metal plate and the nanoparticles are formed in the liquid. The properties of nanoparticles using laser ablation are unique, and they are not reproducible by any other method such as chemical methods. The important parameters to produce the metal nanoparticles are energy, wavelength, repetition rate of laser, ablation time, and absorption of an aqueous solution. Laser ablation is a simple method for fabricating the metal nanoparticles without surfactant or chemical addition. In this chapter, the mechanism of formation of metal nanoparticles in liquid, significant parameters for using the laser ablation technique to prepare the metal nanoparticles, and the preparation of silver, gold and copper nanoparticles will be reviewed.",book:{id:"7349",slug:"laser-technology-and-its-applications",title:"Laser Technology and its Applications",fullTitle:"Laser Technology and its Applications"},signatures:"Amir Reza Sadrolhosseini, Mohd Adzir Mahdi, Farideh Alizadeh and\nSuraya Abdul Rashid",authors:null},{id:"73930",title:"Laser Chemical Elemental Analysis: From Total to Images",slug:"laser-chemical-elemental-analysis-from-total-to-images",totalDownloads:491,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"This book chapter focuses on laser ablation employed in elemental analysis and discusses the fundamentals and instrumentation of the laser-induced breakdown spectroscopy (LIBS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) techniques. The analytical performance of such techniques, challenges related to calibration, and strategies to improve sensitivity are discussed. In addition, the processes involved in data acquisition and imaging for acquiring the elemental spatial distribution are highlighted, and some representative examples in environmental, biological, medical, and forensic researches are presented.",book:{id:"10481",slug:"practical-applications-of-laser-ablation",title:"Practical Applications of Laser Ablation",fullTitle:"Practical Applications of Laser Ablation"},signatures:"Renata S. Amais, Danielle S. Francischini, Pedro S. Moreau and Marco A.Z. Arruda",authors:[{id:"327464",title:"Prof.",name:"Marco A.Z.",middleName:null,surname:"Arruda",slug:"marco-a.z.-arruda",fullName:"Marco A.Z. 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We describe the following applications of QD-SOA: the all-optical ultra-wideband (UWB) pulse generation based on the Mach-Zehnder interferometer (MZI) with a QD-SOA; the ultra-fast all-optical signal processor based on QD-SOA-MZI; the ultra-fast all-optical memory based on QD-SOA. The contents of the chapter are mainly based on the original results.",book:{id:"6467",slug:"optical-amplifiers-a-few-different-dimensions",title:"Optical Amplifiers",fullTitle:"Optical Amplifiers - A Few Different Dimensions"},signatures:"Yossef Ben Ezra and Boris I. Lembrikov",authors:[{id:"2302",title:"Prof.",name:"Yossef",middleName:null,surname:"Ben-Ezra",slug:"yossef-ben-ezra",fullName:"Yossef Ben-Ezra"},{id:"2359",title:"Dr.",name:"Boris I.",middleName:"I.",surname:"Lembrikov",slug:"boris-i.-lembrikov",fullName:"Boris I. Lembrikov"}]},{id:"73390",title:"Laser Machining",slug:"laser-machining",totalDownloads:544,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"The increasing demands of materials with superior properties are given priority by most of the industries in recent years due to their higher performance levels. Machining of hard materials is a challenging task since it involves higher cutting forces and rapid tool wear. This leads to complexity in shaping these difficult-to machine materials such as advanced composite and ceramics. There have been many alternative techniques developed to overcome the shortcomings of conventional machining processes. Laser beam machining (LBM) is one of the advanced noncontact machining processes that employ monochromatic light with high frequency for machining using thermal energy. The highly energized photos are focused on a material cause heating, melting and vaporizes the material which is effectively used to remove unwanted portion of a material. Due to higher coherency of laser beam, materials can be machined very precisely than conventional machining processes. Generally, the laser-based material processing is suitable for a brittle type of material with minimum conductivity. However, this laser machining can be used for all kinds of materials in most cases. This chapter provides the principle of laser and its types, mechanism of material removal using laser, applications, advantages, and limitations of LBM.",book:{id:"10481",slug:"practical-applications-of-laser-ablation",title:"Practical Applications of Laser Ablation",fullTitle:"Practical Applications of Laser Ablation"},signatures:"Natarajan Jeyaprakash, Che-Hua Yang and Manickam Bhuvanesh Kumar",authors:[{id:"32620",title:"Prof.",name:"Che-Hua",middleName:null,surname:"Yang",slug:"che-hua-yang",fullName:"Che-Hua Yang"},{id:"319416",title:"Dr.",name:"Jeyaprakash",middleName:null,surname:"Natarajan",slug:"jeyaprakash-natarajan",fullName:"Jeyaprakash Natarajan"},{id:"329306",title:"Dr.",name:"Bhuvanesh Kumar",middleName:null,surname:"M",slug:"bhuvanesh-kumar-m",fullName:"Bhuvanesh Kumar M"}]},{id:"63522",title:"Nonlinear Optical Response of Noble Metal Nanoparticles",slug:"nonlinear-optical-response-of-noble-metal-nanoparticles",totalDownloads:1420,totalCrossrefCites:2,totalDimensionsCites:6,abstract:"The special nonlinear optical response of noble metal nanoparticles (MNPs) when exposed to intense laser radiation has induced novel applications in nonlinear spectroscopy, optoelectronics, and optical switchers and limiters. In this chapter, recent results on the nonlinear optical properties of MNPs (including gold, silver, palladium, and platinum) have been discussed. 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Moreover, in the field of machine learning, evolutionary computation has carved out a significant niche both in the generation of learning models and in the automatic design and optimization of hyperparameters in deep learning models. This collection aims to include quality volumes on various topics related to evolutionary algorithms and, alternatively, other metaheuristics of interest inspired by nature. For example, some of the issues of interest could be the following: Advances in evolutionary computation (Genetic algorithms, Genetic programming, Bio-inspired metaheuristics, Hybrid metaheuristics, Parallel ECs); Applications of evolutionary algorithms (Machine learning and Data Mining with EAs, Search-Based Software Engineering, Scheduling, and Planning Applications, Smart Transport Applications, Applications to Games, Image Analysis, Signal Processing and Pattern Recognition, Applications to Sustainability).",coverUrl:"https://cdn.intechopen.com/series_topics/covers/25.jpg",keywords:"Genetic Algorithms, Genetic Programming, Evolutionary Programming, Evolution Strategies, Hybrid Algorithms, Bioinspired Metaheuristics, Ant Colony Optimization, Evolutionary Learning, Hyperparameter Optimization"},{id:"26",title:"Machine Learning and Data Mining",scope:"The scope of machine learning and data mining is immense and is growing every day. It has become a massive part of our daily lives, making predictions based on experience, making this a fascinating area that solves problems that otherwise would not be possible or easy to solve. This topic aims to encompass algorithms that learn from experience (supervised and unsupervised), improve their performance over time and enable machines to make data-driven decisions. It is not limited to any particular applications, but contributions are encouraged from all disciplines.",coverUrl:"https://cdn.intechopen.com/series_topics/covers/26.jpg",keywords:"Intelligent Systems, Machine Learning, Data Science, Data Mining, Artificial Intelligence"},{id:"27",title:"Multi-Agent Systems",scope:"Multi-agent systems are recognised as a state of the art field in Artificial Intelligence studies, which is popular due to the usefulness in facilitation capabilities to handle real-world problem-solving in a distributed fashion. The area covers many techniques that offer solutions to emerging problems in robotics and enterprise-level software systems. Collaborative intelligence is highly and effectively achieved with multi-agent systems. Areas of application include swarms of robots, flocks of UAVs, collaborative software management. Given the level of technological enhancements, the popularity of machine learning in use has opened a new chapter in multi-agent studies alongside the practical challenges and long-lasting collaboration issues in the field. It has increased the urgency and the need for further studies in this field. We welcome chapters presenting research on the many applications of multi-agent studies including, but not limited to, the following key areas: machine learning for multi-agent systems; modeling swarms robots and flocks of UAVs with multi-agent systems; decision science and multi-agent systems; software engineering for and with multi-agent systems; tools and technologies of multi-agent systems.",coverUrl:"https://cdn.intechopen.com/series_topics/covers/27.jpg",keywords:"Collaborative Intelligence, Learning, Distributed Control System, Swarm Robotics, Decision Science, Software Engineering"}],annualVolumeBook:{},thematicCollection:[],selectedSeries:{title:"Artificial Intelligence",id:"14"},selectedSubseries:null},seriesLanding:{item:{id:"7",title:"Biomedical Engineering",doi:"10.5772/intechopen.71985",issn:"2631-5343",scope:"Biomedical Engineering is one of the fastest-growing interdisciplinary branches of science and industry. The combination of electronics and computer science with biology and medicine has improved patient diagnosis, reduced rehabilitation time, and helped to facilitate a better quality of life. Nowadays, all medical imaging devices, medical instruments, or new laboratory techniques result from the cooperation of specialists in various fields. The series of Biomedical Engineering books covers such areas of knowledge as chemistry, physics, electronics, medicine, and biology. This series is intended for doctors, engineers, and scientists involved in biomedical engineering or those wanting to start working in this field.",coverUrl:"https://cdn.intechopen.com/series/covers/7.jpg",latestPublicationDate:"May 7th, 2022",hasOnlineFirst:!0,numberOfOpenTopics:3,numberOfPublishedChapters:96,numberOfPublishedBooks:12,editor:{id:"50150",title:"Prof.",name:"Robert",middleName:null,surname:"Koprowski",fullName:"Robert Koprowski",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYTYNQA4/Profile_Picture_1630478535317",biography:"Robert Koprowski, MD (1997), PhD (2003), Habilitation (2015), is an employee of the University of Silesia, Poland, Institute of Computer Science, Department of Biomedical Computer Systems. For 20 years, he has studied the analysis and processing of biomedical images, emphasizing the full automation of measurement for a large inter-individual variability of patients. Dr. Koprowski has authored more than a hundred research papers with dozens in impact factor (IF) journals and has authored or co-authored six books. Additionally, he is the author of several national and international patents in the field of biomedical devices and imaging. Since 2011, he has been a reviewer of grants and projects (including EU projects) in biomedical engineering.",institutionString:null,institution:{name:"University of Silesia",institutionURL:null,country:{name:"Poland"}}},subseries:[{id:"7",title:"Bioinformatics and Medical Informatics",keywords:"Biomedical Data, Drug Discovery, Clinical Diagnostics, Decoding Human Genome, AI in Personalized Medicine, Disease-prevention Strategies, Big Data Analysis in Medicine",scope:"Bioinformatics aims to help understand the functioning of the mechanisms of living organisms through the construction and use of quantitative tools. The applications of this research cover many related fields, such as biotechnology and medicine, where, for example, Bioinformatics contributes to faster drug design, DNA analysis in forensics, and DNA sequence analysis in the field of personalized medicine. Personalized medicine is a type of medical care in which treatment is customized individually for each patient. Personalized medicine enables more effective therapy, reduces the costs of therapy and clinical trials, and also minimizes the risk of side effects. Nevertheless, advances in personalized medicine would not have been possible without bioinformatics, which can analyze the human genome and other vast amounts of biomedical data, especially in genetics. The rapid growth of information technology enabled the development of new tools to decode human genomes, large-scale studies of genetic variations and medical informatics. The considerable development of technology, including the computing power of computers, is also conducive to the development of bioinformatics, including personalized medicine. In an era of rapidly growing data volumes and ever lower costs of generating, storing and computing data, personalized medicine holds great promises. Modern computational methods used as bioinformatics tools can integrate multi-scale, multi-modal and longitudinal patient data to create even more effective and safer therapy and disease prevention methods. Main aspects of the topic are: Applying bioinformatics in drug discovery and development; Bioinformatics in clinical diagnostics (genetic variants that act as markers for a condition or a disease); Blockchain and Artificial Intelligence/Machine Learning in personalized medicine; Customize disease-prevention strategies in personalized medicine; Big data analysis in personalized medicine; Translating stratification algorithms into clinical practice of personalized medicine.",annualVolume:11403,isOpenForSubmission:!0,coverUrl:"https://cdn.intechopen.com/series_topics/covers/7.jpg",editor:{id:"351533",title:"Dr.",name:"Slawomir",middleName:null,surname:"Wilczynski",fullName:"Slawomir Wilczynski",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000035U1loQAC/Profile_Picture_1630074514792",institutionString:null,institution:{name:"Medical University of Silesia",institutionURL:null,country:{name:"Poland"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"5886",title:"Dr.",name:"Alexandros",middleName:"T.",surname:"Tzallas",fullName:"Alexandros Tzallas",profilePictureURL:"https://mts.intechopen.com/storage/users/5886/images/system/5886.png",institutionString:"University of Ioannina, Greece & Imperial College London",institution:{name:"University of Ioannina",institutionURL:null,country:{name:"Greece"}}},{id:"257388",title:"Distinguished Prof.",name:"Lulu",middleName:null,surname:"Wang",fullName:"Lulu Wang",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRX6kQAG/Profile_Picture_1630329584194",institutionString:null,institution:{name:"Shenzhen Technology University",institutionURL:null,country:{name:"China"}}},{id:"225387",title:"Prof.",name:"Reda",middleName:"R.",surname:"Gharieb",fullName:"Reda Gharieb",profilePictureURL:"https://mts.intechopen.com/storage/users/225387/images/system/225387.jpg",institutionString:"Assiut University",institution:{name:"Assiut University",institutionURL:null,country:{name:"Egypt"}}}]},{id:"8",title:"Bioinspired Technology and Biomechanics",keywords:"Bioinspired Systems, Biomechanics, Assistive Technology, Rehabilitation",scope:'Bioinspired technologies take advantage of understanding the actual biological system to provide solutions to problems in several areas. Recently, bioinspired systems have been successfully employing biomechanics to develop and improve assistive technology and rehabilitation devices. The research topic "Bioinspired Technology and Biomechanics" welcomes studies reporting recent advances in bioinspired technologies that contribute to individuals\' health, inclusion, and rehabilitation. Possible contributions can address (but are not limited to) the following research topics: Bioinspired design and control of exoskeletons, orthoses, and prostheses; Experimental evaluation of the effect of assistive devices (e.g., influence on gait, balance, and neuromuscular system); Bioinspired technologies for rehabilitation, including clinical studies reporting evaluations; Application of neuromuscular and biomechanical models to the development of bioinspired technology.',annualVolume:11404,isOpenForSubmission:!0,coverUrl:"https://cdn.intechopen.com/series_topics/covers/8.jpg",editor:{id:"144937",title:"Prof.",name:"Adriano",middleName:"De Oliveira",surname:"Andrade",fullName:"Adriano Andrade",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRC8QQAW/Profile_Picture_1625219101815",institutionString:null,institution:{name:"Federal University of Uberlândia",institutionURL:null,country:{name:"Brazil"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"49517",title:"Prof.",name:"Hitoshi",middleName:null,surname:"Tsunashima",fullName:"Hitoshi Tsunashima",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYTP4QAO/Profile_Picture_1625819726528",institutionString:null,institution:{name:"Nihon University",institutionURL:null,country:{name:"Japan"}}},{id:"425354",title:"Dr.",name:"Marcus",middleName:"Fraga",surname:"Vieira",fullName:"Marcus Vieira",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y00003BJSgIQAX/Profile_Picture_1627904687309",institutionString:null,institution:{name:"Universidade Federal de Goiás",institutionURL:null,country:{name:"Brazil"}}},{id:"196746",title:"Dr.",name:"Ramana",middleName:null,surname:"Vinjamuri",fullName:"Ramana Vinjamuri",profilePictureURL:"https://mts.intechopen.com/storage/users/196746/images/system/196746.jpeg",institutionString:"University of Maryland, Baltimore County",institution:{name:"University of Maryland, Baltimore County",institutionURL:null,country:{name:"United States of America"}}}]},{id:"9",title:"Biotechnology - Biosensors, Biomaterials and Tissue Engineering",keywords:"Biotechnology, Biosensors, Biomaterials, Tissue Engineering",scope:"The Biotechnology - Biosensors, Biomaterials and Tissue Engineering topic within the Biomedical Engineering Series aims to rapidly publish contributions on all aspects of biotechnology, biosensors, biomaterial and tissue engineering. We encourage the submission of manuscripts that provide novel and mechanistic insights that report significant advances in the fields. Topics can include but are not limited to: Biotechnology such as biotechnological products and process engineering; Biotechnologically relevant enzymes and proteins; Bioenergy and biofuels; Applied genetics and molecular biotechnology; Genomics, transcriptomics, proteomics; Applied microbial and cell physiology; Environmental biotechnology; Methods and protocols. Moreover, topics in biosensor technology, like sensors that incorporate enzymes, antibodies, nucleic acids, whole cells, tissues and organelles, and other biological or biologically inspired components will be considered, and topics exploring transducers, including those based on electrochemical and optical piezoelectric, thermal, magnetic, and micromechanical elements. Chapters exploring biomaterial approaches such as polymer synthesis and characterization, drug and gene vector design, biocompatibility, immunology and toxicology, and self-assembly at the nanoscale, are welcome. Finally, the tissue engineering subcategory will support topics such as the fundamentals of stem cells and progenitor cells and their proliferation, differentiation, bioreactors for three-dimensional culture and studies of phenotypic changes, stem and progenitor cells, both short and long term, ex vivo and in vivo implantation both in preclinical models and also in clinical trials.",annualVolume:11405,isOpenForSubmission:!0,coverUrl:"https://cdn.intechopen.com/series_topics/covers/9.jpg",editor:{id:"126286",title:"Dr.",name:"Luis",middleName:"Jesús",surname:"Villarreal-Gómez",fullName:"Luis Villarreal-Gómez",profilePictureURL:"https://mts.intechopen.com/storage/users/126286/images/system/126286.jpg",institutionString:null,institution:{name:"Autonomous University of Baja California",institutionURL:null,country:{name:"Mexico"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"35539",title:"Dr.",name:"Cecilia",middleName:null,surname:"Cristea",fullName:"Cecilia Cristea",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYQ65QAG/Profile_Picture_1621007741527",institutionString:null,institution:{name:"Iuliu Hațieganu University of Medicine and Pharmacy",institutionURL:null,country:{name:"Romania"}}},{id:"40735",title:"Dr.",name:"Gil",middleName:"Alberto Batista",surname:"Gonçalves",fullName:"Gil Gonçalves",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYRLGQA4/Profile_Picture_1628492612759",institutionString:null,institution:{name:"University of Aveiro",institutionURL:null,country:{name:"Portugal"}}},{id:"211725",title:"Associate Prof.",name:"Johann F.",middleName:null,surname:"Osma",fullName:"Johann F. Osma",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bSDv7QAG/Profile_Picture_1626602531691",institutionString:null,institution:{name:"Universidad de Los Andes",institutionURL:null,country:{name:"Colombia"}}},{id:"69697",title:"Dr.",name:"Mani T.",middleName:null,surname:"Valarmathi",fullName:"Mani T. Valarmathi",profilePictureURL:"https://mts.intechopen.com/storage/users/69697/images/system/69697.jpg",institutionString:"Religen Inc. | A Life Science Company, United States of America",institution:null},{id:"205081",title:"Dr.",name:"Marco",middleName:"Vinícius",surname:"Chaud",fullName:"Marco Chaud",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bSDGeQAO/Profile_Picture_1622624307737",institutionString:null,institution:{name:"Universidade de Sorocaba",institutionURL:null,country:{name:"Brazil"}}}]}]}},libraryRecommendation:{success:null,errors:{},institutions:[]},route:{name:"chapter.detail",path:"/chapters/40774",hash:"",query:{},params:{id:"40774"},fullPath:"/chapters/40774",meta:{},from:{name:null,path:"/",hash:"",query:{},params:{},fullPath:"/",meta:{}}}},function(){var e;(e=document.currentScript||document.scripts[document.scripts.length-1]).parentNode.removeChild(e)}()