## Abstract

While improving the performance of excitonic solar cells (XSCs) has been a central effort of the scientific community for many years, theoretical approaches facilitating the understanding of electron-hole interaction, recombination and electron-phonon coupling effects on the cell performance are still needed. We present a novel simple model which is based on the quantum scattering theory, in particular on the Lippmann-Schwinger equation; this minimizes the complexity of the problem while providing useful and non-trivial insight into the mechanism governing photocell operation. In this formalism, both exciton pair creation and dissociation are treated in the energy domain, and therefore there is access to detailed spectral information, which can be used as a framework to interpret the charge separation yield. Our analysis helps to optimize the charge separation process and the energy transfer in excitonic solar cells.

### Keywords

- quantum model
- two-level system
- electron-hole interaction
- electron-phonon coupling
- charge separation yield

## 1. Introduction

Excitonic solar cells have attracted a broad interest in recent years due to their potential to provide an excellent alternative to conventional Si-based photovoltaic cells. The aim of this chapter is to discuss more details of this technology, their various types, basic operation principles and important challenges. Excitonic solar cells are structures that employ organic materials (carbon-based compounds) such as small molecules, polymers or the hybrids of these material sets to absorb light and produce photovoltaic current. Carbon-based semiconductors exhibit desirable light absorption and charge creation properties with the capability of manufacturing by low-temperature processes [1, 2, 3]. According to the type of materials used in their structure, excitonic solar cells are classified into two main categories: dye-sensitized solar cells (DSC) [4] and organic solar cells (OSC) [5] developed in single layers [6] and bi-layers [7] including planar [8] and bulk heterojunction configurations [9]. A schematic view of different excitonic solar cells is shown in Figure 1.

Historically, in the end of nineteenth century, by the emerging modern organic chemistry, the scientific and industrial interests in the research on organic materials enhanced. The photoconductivity phenomenon by an organic compound “Anthracene” for the first time was observed by Pochettino in 1906 [12]. Since then, it was realized that many conventional dyes such as methylene blue can show the semiconducting characteristics [13], and enormous number of organic semiconducting molecules do exist such that their electrical and optical properties can be fine-tuned to address the special applications [14]. In the 1970s, (semi)conducting polymers were discovered [15].

The first major breakthrough in the deployment of organic solar cells has been made in 1986 by Tang who developed the donor-acceptor solar cell and reported an efficiency of 1% [16]. The energy conversion efficiency of this cell was very low, but it showed a promising potential of organic photovoltaics when electron donor and acceptor molecules are used together. In 1992, Sariciftci et al. [17] displayed the photo-induced charge transfer within organic molecules that led to particular interests in OSC field. A report of 2.9%-efficient cells based on conducting organic polymers mixed with derivatives of C60 published by Yu et al. in 1995 [18] increased the excitement in this research area. After these achievements, the number of publications rose dramatically. Based on the aforementioned explanations, common organic solar cells use a donor and an acceptor organic material to build up a heterojunction favoring the separation of the exciton into free charge carriers. The same organic materials are also responsible for charge transport to their respective contacts. That a material for organic photovoltaic devices should have both good light absorption and carriers’ transporting properties is a hard task to achieve. On the other hand, the dye-sensitized solar cell technology separates the two requirements as the charge generation is done at the interface of semiconductor dye and on the other hand, the semiconductor and electrolyte are the responsible for charge transport. Therefore, modifying the dye alone can optimize the spectral properties, while carriers’ transporting properties can be improved by optimizing the semiconductor and the electrolyte phases. The first significant study of dye sensitization of semiconductors also goes back to the nineteenth century, when Vogel utilized silver halide emulsions sensitized by dyes for providing a black and white photographic film [19]. The mechanism of electron injection from photoexcited dye molecules into the conduction band of the semiconductor dates only from the 1960s [20]. The concept of dye adsorption on the surface of the semiconductor was started in 1976 by Tsubomura et al. [21] and developed in 1981 by Dare-Edwards et al. [22]. However, exploiting the dye-sensitization mechanism in photovoltaic technology was an unsuccessful process until the early 1990s when a breakthrough happened by Grätzel et al. at the EPFL. The Grätzel cell (DSC) revealed an energy conversion efficiency exceeding 7% in 1991 [23] and 10% in 1993 [24]. DSCs offer large flexibility in color, shape, and transparency [25] and perform relatively better compared with other solar cell technologies at higher temperatures [26]. Furthermore, due to the utilization of cheap and Earth-abundant materials and also simple preparation and easy fabrication processes, they are highly cost effective when compared with the conventional inorganic counterparts [27].

All the cons and pros pointed earlier make the excitonic solar cells a prospective and interesting research and innovation field. Although power conversion efficiencies (PCEs) of XSCs have represented a significant increase over the past 10 years, there are still problems in enhancing PCEs and stability to make them commercially available [28].

In 2005, the US Department of Energy published a report discussing the point that there exists insufficient microscopic intuition or theory to conduct material and device for better design of new-generation photovoltaic devices [29]. According to the mentioned report, developing theories that can provide unified, quantitative and comprehensive understanding of principle processes taking place in solar energy conversion such as photon absorption, exciton formation and dissociation, charge separation, and collection are essentially needed. Following this interesting report, here, we develop a new quantum formalism to describe the performance of excitonic solar cells in the presence of electron-hole interaction, recombination and electron-phonon coupling. This model is based on quantum scattering theory and in particular on the Lippmann-Schwinger Equation [30]. Of specific interests of the model is its development on the energy domain such that it provides detailed spectral information to interpret the exciton creation and dissociation phenomena and their effects on device properties as well.

## 2. Formalism and numerical methods

### 2.1. Two-level photovoltaic system

The basic idea of our methodology is described through the example of the two-level molecular photocell where the energy conversion process takes place in a single molecular donor-acceptor complex attached to electrodes. The two-level system is characterized by the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). Initially, the whole system is in the ground state with filled valence bands and empty conduction bands. Following the photon absorption by the molecule, one electron and one hole are created in LUMO and HOMO, respectively. Both charge carriers interact via the Coulomb potential and can be recombined in the molecule or can be transferred to their respective channels where they produce photovoltaic current (see Figure 2).

Here, the first coupling energies to the charge evacuation channels are denoted by

Since

### 2.2. The electron-hole pair Hamiltonian

The effective Hamiltonian of the system is of the tight-binding type

Here, the first term indicates the total on-site energy of each electron-hole basis state which is defined as a summation over the electron on-site energy, the hole’s on-site energy, and the Coulomb interaction energy between them:

The second term in Eq. (2) represents the coupling energy between two adjacent basis states. In the other words, coupling represents either the hoping of a hole or of an electron from a given initial site of the electron-hole pair to a neighboring site. As pointed earlier, the coupling energies between molecular states and their first neighbors are taken to be different from the other coupling energies.

### 2.3. Fluxes & quantum yield

In this formalism, we consider a photovoltaic cell as a system submitted to an incident flux of photons and assume that the whole system (PV cell plus electromagnetic field) is in a stationary state that obeys the fundamental Lippmann-Schwinger Equation [31, 32, 33, 34]. By applying quantum scattering theory, in particular the Lippmann-Schwinger equation, the photovoltaic system is described by a wave function. The incoming state of the theory

The second term in the right-hand side of the above equation is called the scattered wave function,

The average yield or in other words the charge separation yield,

where

## 3. Results and discussions

### 3.1. Two-level systems with local interaction

Relying on the new formalism described in the previous section, here we are going to investigate the effects of short-range electron-hole interaction on the performance of a molecular photocell. The short-range interaction term implies that interaction between the electron and the hole occurs only when they both are inside the absorber molecule. To simplify the discussion, only mono-channel configuration, where there is just one possible evacuation channel for each charge carrier (i.e.,

#### 3.1.1. Local density of states

For the numerical simulations, we use

The total energy continuum is simply the sum of the electron and hole energies. In Figure 3, the LDOS is plotted as a function of the absorbed photon energy. In these plots, the dependence of LDOS on short-range interaction energy (

#### 3.1.2. Charge separation yield

The other important quantity that can be investigated is the charge separation yield,

The dependence of the charge separation yield of the interacting electron-hole pair is examined as a function of short-range interaction strength

### 3.2. Two-level systems with non-local interaction

This section is intended to investigate the effects of non-local interaction on the performance of photovoltaic cells. This means that in contrast to the results presented in the previous section there are interactions even if the charge carriers are outside the molecule. An important case of non-local interaction is the long-range Coulomb interaction between the photo-generated electron and hole. This means that the electron and the hole do interact even if they are not both inside the molecule. Here of course the Coulomb interaction is not the bare interaction but is screened by all the charges of the materials around the electron-hole pair. This screening effect is well represented by considering an effective dielectric constant of the medium. The other case of non-local interaction is the coupling between the electron (or the hole) with the lattice distortion around it when the electron (or the hole) moves out of the initial two-level system. The first part of this section is devoted to the long-range Coulomb interaction case and the second part deals with the coupling to the optical phonon modes.

#### 3.2.1. Long-range electron: hole Coulomb interaction

Similar to the previous section, we consider the mono-channel case where there is only one evacuation channel for each charge carrier. We analyze photon absorption, energy conversion and quantum yield of the molecular photocell by considering the effects of long-range electron-hole interaction and non-radiative recombination.

#### 3.2.1.1. Local density of states

For the numerical simulation, the same parameters as in the previous section are used. In all the calculations,

In Figure 5, the LDOS is plotted as a function of the absorbed photon energy. In these plots, the dependence of LDOS on short- and long-range interaction energy (

#### 3.2.1.2. Charge separation yield

The dependence of the charge separation yield of the interacting electron-hole pair is examined as a function of

Additionally, for a given coupling parameter, the yield is higher for weakly interacting electron-hole pairs. This behavior can be understood based on the spectral information provided in Figure 5; explicitly under the influence of the strong interaction, the weight of localized states increases and consequently the possibility of recombination and annihilating the charge carriers enhances. For a given electron-hole interaction strength, the yield improves with increasing values of the coupling parameter. Since the strong coupling extends the width of the DOS line shape and consequently improves the escaping rate, this behavior is understandable. Furthermore, the effect of non-radiative recombination is to diminish the yield, and its impact is more important under the influence of the strong long-range interaction condition.

#### 3.2.2. Charge injection in polaronic bands and quantum yield of excitonic solar cells

In the performance of excitonic solar cells, coupling to the phonon modes can play a major role as it may lead to the occurrence of polarons, where a polaron is a moving charge surrounded by a cloud of virtual phonons. To address how the electron-phonon coupling (in addition to the electron-hole interaction) can affect the charge separation process, here we propose a simple tight-binding-based model. We analyze the spectrum of polaronic bands and focus on their effects on the charge separation yield, which is defined as a proportion of emitted electrons that arrive at the cathode electrode. We start the discussion by the model description.

#### 3.2.2.1. Coupling to the phonon modes: theoretical model in the small polaron limit

We present a mathematical model to investigate the influence polaron formation has on the charge separation process of excitonic solar cells. This model can be applied to any type of excitonic solar cells. We suppose that an electron emitted at first site (

In this model, the charge separation process follows an interesting scenario: after the exciton dissociation at the interface, the electron either recombines with the hole which is fixed at the interface or moves through a set of acceptor sites where it can be coupled to one single phonon mode. The physical interpretation of the model is that the charge-transfer process is viewed as a hopping process when the electron interacts sufficiently strongly with intramolecular vibrations. The Hamiltonian of the considered system can be written based on the Holstein model [35]:

where

Let us recall that the yield is the proportion of the electrons that arrive at the cathode electrode, the other electrons recombining at the interface with the hole. We assume that the hole is localized at the two-level system (called site

As can be seen, first, the yield keeps the periodic resonance structure as a consequence of polaronic band formation. Second, the combined effect of Coulomb interaction and polaronic dressing of the carriers leads to a strong overall suppression of the yield such that it never reaches one. To have clear understanding, again we refer to the spectral information. Figure 9 represents the yield and corresponding LDOS. The LDOS is represented in the bulk part (far from the interface) and also at the interface for different injection energies. The electronic structure in the bulk part gives a view of all possible polaronic bands and the energy gap regimes. For a given injection energy

The charge carriers lying in a polaronic band can evacuate and arrive at the electrodes. On the other hand, the charge carriers localized in the bound state in the gap recombine quickly and cannot lead to photovoltaic current which diminishes the yield. Through this physical interpretation, yield values around the red marked points are in good agreement with the corresponding electronic structure. As shown, the long-range Coulomb interaction leads to an intricate spectrum with many localized and nearly localized states. This tendency to localizing the spectrum induces a lowering of the efficiency of the cell. Figure 10 represents the effect of recombination (

## 4. Conclusions

The aim of this chapter was to acquire a deep understanding of the working mechanism of excitonic solar cells and to improve the device performance. Therefore, we developed a new quantum formalism based on the wave function of excitonic solar cells. The basic idea of this new methodology was shown through the example of two-level excitonic solar cells. We demonstrated that this new methodology provides a quantitative picture of the fundamental processes underlying solar energy conversion, including photon absorption, exciton dissociation and charge separation as well as an understanding of their consequences on the cell performance. Interestingly, this theory could successfully analyze excitonic solar cell in the presence of strong Coulomb interaction between the electron and the hole. Here we highlight some of the important achievements of this study.

We showed that there is a competition between injection of charge carriers in the leads and recombination in the two-level system. This competition depends sensitively on the parameters of the model such as the local electron-hole interaction, the recombination rate, the coupling to the leads, and the band structure of the leads.

We found that the electron-hole Coulomb interaction and non-radiative recombination reduce the photocell yield, especially under the weak coupling condition where the charge carriers cannot readily escape into the contacts.

Finally, we provided microscopic evidence that the efficiency of charge transfer is subtly controlled by interplay of electrostatic confinement and coherent coupling of charge carrier(s) to high-energy quantized vibrational modes.