Open access peer-reviewed chapter

Electronic Band Structure of Carbon Nanotubes in Equilibrium and None-Equilibrium Regimes

By Rahim Ghayour and Pakkhesal

Submitted: October 21st 2010Reviewed: April 24th 2011Published: July 27th 2011

DOI: 10.5772/17556

Downloaded: 2560

1. Introduction

The exploration of CNTs was a great contribution to the world of science and technology. After its exploration in 1991 by Iijima (Eq. 1), extensive practical and theoretical researches about its nature gradually began to develop (Eq. 2, Eq. 6). Today, we know about CNTs much more about its chemical, mechanical, optical and electrical properties than before. The methods of fabrication have also progressed. Due to their electrical and optical properties, CNTs are the subject of studies about their usage in new electronic and optoelectronic devices. In this chapter we will focus on their electronic band structure, because it is the most important characteristic of a solid that should be studied to be used in determination of its electronic, optical and optoelectronic properties. In order to investigate the electronic band structure of a solid, it is first necessary to have a good understanding of its crystal lattice and atomic structure. Therefore, as the first step of this chapter we will begin with the investigation of the geometry of SWCNTs. Then we will continue with the calculation of allowed wave vectors for the electronic transport. Having finished this step, we will introduce the electronic band structure of SWCNTs.

As is known, single walled carbon nanotube or SWCNT consists of grephene sheet that is rolled into a cylinder over a vector called “chiral vector” (Fig. 1 a) so that the beginning and the end of this vector join to form the circumstantial circle of the cylinder Fig. 1 b.

As is shown in Fig. 1(a) the chiral vector may be written in terms of unit vectors a1 and a2, therefore C may be written as:

Here |a1| = |a2|= a0 = √3aC-C where aC-C is the bonding distance of the two adjacent carbon atom and is equal to 0.142nm and m > n. Having been familiar with chiral vector, its usage and its relationship with unit vectors a1 and a2, one can investigate the geometry of carbon nanotube.

Figure 1.

a) Illustration of Chiral vector C and unit vectors a1 and a2, A and B the two lattice sites of the graphene lattice. (b) The graphene sheet when rolled over Chiral vector C.

2. Investigation of the geometry of SWCNT

2.1. The investigation of radius and the chiral angle

In this section of this chapter we continue with the calculation of some aspects of the geometry of SWCNT, e.g. radius, chiral angle. As is illustrated in Fig. 1(b), the chiral vector C coincides the circumference of the cross sectional circle of the cylinder. Now, keeping this reality in the mind, we can easily infer the radius of the cylinder:

C=ma1+na2E1

which yields:

|C|=2πrE2

Next, we are to investigate a quantity called chiral angle. Chiral angle is the angle between chiral vector and the unit vector a1. The value can simply be calculated as:

r=aCC2π3(m2+n2+mn)E3

This value is a symbol of the way that the carbon atomic pairs (unit cell of graphene) are arranged.

2.2. Translational, helical and rotational symmetries

In this section we explain the three major types of symmetries of SWCNT. As a chiral structure, SWCNT is expected to have a translational symmetry. Thus, if we represent this symmetry with the vector T, such that T = t1a1 + t2a2 (t1 and t2 are natural numbers) we are faced with shortest symmetry vector that is perpendicular to the vector C, so:

θ=tan1(3n2m+n)E4

Therefore:

C.T= 0E5

in solving this equation we note that ai.aj is equal to 0.5a02 if i ≠ j and is equal to a02 if i = j. Now, solving (Eq. 5), regarding that p1,p2,m and n are positive natural numbers, m > n and we are seeking for the smallest value of p1 and p2, we will have the following equation:

(t1a1+ t2a2).( ma1+ na2) = 0E6
t2t1=2n+mgcd(2n+m,2m+n)2m+ngcd(2n+m,2m+n)E7

where gcd is standing for Greatest Common Devisor. As described before, T is a translational symmetry vector which means that if we move on the surface of the nanotube by T vector we catch up similar points.

Now we are to investigate the second and the third types of symmetries on the surface of the SWCNT which are helical and rotational symmetries [Eq. 7]. As mentioned before, nanotube’s cylinder is formed by rolling graphene on the lattice vector C. Thus, we begin our investigation by means of a mapping process. We first, try to map the unit cell of graphene on the surface of the cylinder. We suppose that d is a vector such that it begins from the lattice site A and ends to lattice site B. The first atom can be placed on an arbitrary place on the surface of the cylinder. The second atom must be placed at the height of T=2n+mgcd(2n+m,2m+n)a1+2m+ngcd(2n+m,2m+n)a2from the first atom and the azimuthal angle of |d×C||C|with respect to the first atom. Until now, we have mapped a unit cell of graphene to the surface the cylinder. Where to place the next atomic pair? Now, we want to find a slice of the cylinder such that it includes the minimum number of graphene unit cells. We know that, the area of this slice is calculated using the formula: AM = 2πrh. Where h is the height of the mentioned section. h can be regarded as the magnitude of a vector H = p1a1 + p2a2 ; therefore, AM can be expressed as:

2π|d.C||C|2E8

Now we are to minimize the term: p1m-p2n. Mathematically, it can be shown that this term is minimized when:

AM=|H×B|=(p1mp2n)|a1×a2|E9

where N = gcd(m,n). In order to acquire unique values for p1 and p2 we find p1 and p2 such that p1mp2n=±Nand |H| has the minimum value. Knowing that the area of a unit cell of the graphene (which is an atomic pair) is equal top10, the mentioned slice contains N atomic pairs which are located in the multiples of the azimuthal angle of|a1×a2|. This implies a symmetry in azimuthal direction which is so called “rotational symmetry”. Now, we return to our question which is finding the place of the second atomic pair on the surface of the tubule. After finding the H vector with the mentioned conditions, it is clear that it implies a type of symmetry in the helical direction (along the vector H) [Eq. 7]. There for, the second atomic pair should be place at a position which is located by an H vector next to the first atomic pair. The third atomic pair is located 2H from the first one and so on. This “helical motif” should be copied N times in angular space of 2πNto construct whole the nanotube’s structure. Now that we have known the symmetries of the nanotube, we are ready to investigate the band structure of SWCNT.

Figure 2.

In this figure the “helical motif” and H vector are illustrated.

3. The band structure of SWCNT in equilibrium conditions

3.1. Bloch function

At this step we are facing the problem of finding the wave function for a crystal lattice. In this situation we are facing periodic boundary conditions. Therefore, it is expected that we acquire a periodic wave function. Using these facts, in 1927 Bloch showed that the electron wave function has the following form for a crystal lattice:

2πNE10

where ψk(r) is the electron wave function, uk(r) a periodic function with the period of the crystal and k is the electron wave vector. After this step, we find the energy of the electron, E, using the Hamiltonian operator, H, as follows:

ψk(r)=uk(r)eik.rE11

But we don’t have uk(r). Therefore, we don’t know the exact form of ψk(r). There are a variety of methods to describe the interaction of electron and the crystal lattice. In this chapter we investigate the mentioned interaction according to nearest neighbor π-Tight Binding (π-TB) and the third neighbor π-TB method.

3.2. Brillouin zone

Suppose that we have a wave function of the form eiG.r. We want to find G vector such that

Hψk(r)=Eψk(r)E12

or:

eiG.(r+R)=eiG.rE13

where l is an arbitrary integer. Now regarding the following equations for G and R:

G.R=2πlE14
G=g1k^1+g2k^2+g3k^3E15

whereR=n1a^1+n2a^2+n3a^3,a^1,a^2are unit vectors in lattice space anda^3,k^1,k^2are unit vectors in, so called, “reciprocal lattice” space. If we apply (Eq. 13) we will have:

k^3E16

which suggests that:

G.R=2π(n1g1+n2g2+n3g3)E17

Solving above equations [Eq. 8]:

k^1.a^1=2πk^1.a^2=0k^1.a^3=0k^2.a^1=0k^2.a^2=2πk^2.a^1=0k^3.a^1=0k^3.a^2=0k^3.a^3=2πE18
k^1=2πa^1×a^3a^1.(a^2×a^3)E19
k^2=2πa^3×a^1a^1.(a^2×a^3)E20

Now we have unit vectors of the reciprocal lattice. In order to get the Brillouin zone we should we should apply the following condition:

k^3=2πa^1×a^2a^1.(a^2×a^3)E21
or:
(k-G)2=k2E22

thus:

k.G=12G2E23

Using (18-c) we can draw the borders of the Brillouin zone. The inner most area is called the first Brillouin zone and hence, simply it is called “Brillouin zone”.

Now we return to our lattice which is graphene sheet, a two dimensional crystal. If we write (Eq. 16) for this kind of lattice we will have:

k=12GE24

From (Eq. 19) it is clear that k1 and k2 are perpendicular to a2 and a1 respectively. Having a1 and a2 from Fig. 1(a) we can easily find k1 and k2 and draw the Brillouin zone (Fig. 3).

Figure 3.

The Brillouin zone for the graphene lattice is illustrated. L, K and M are high symmetry points.

As mentioned earlier, theoretically, SWCNT can be considered as a graphene lattice that is rolled over into a cylinder. Thus, according to Fig. 1(b) we catch up the following:

k1.a1=2πk1.a2=0k2.a1=0k2.a2=2πE25

Therefore [Eq. 9]:

uk(r)eik.(r+C)=uk(r)eik.rE26

where l is again, an arbitrary integer. This boundary condition which is so called, “Born-von Karman” condition, makes the Brillouin zone to be quantized. Fig. 4 shows this fact. At this point we can begin our investigation about the band structure of SWCNT.

Figure 4.

The Born-von Karman condition makes the SWCNT’s Brillouin zone to be quantized.

3.3. Tight-binding approximation

As mentioned, there are many methods and approximations that are used to investigate the electronic band structure of a solid. In this section we use the tight-binding approximation. In this approximation we consider the wave function of an electron as the Linear Combination of Atomic Orbitals and hence the method is also called as LCAO.

As is known, the energy of an electron can be estimated using Schrödinger’s equation as follows:

k.C=2πlE27

where m is the mass of an electron and [222m+V(r)]ψk(r)=Eψk(r)is the wave function of a single electron with the wave vector k. Now ψk(r)is written as the following:

ψk(r)E28

whereψk(r)=rckrφkr(r)’s are basis functions that are made from atomic orbitals as:

φkr(r)E29

where Nt is the total number of unit cells in the system. We regard the single 2pz orbital of the carbon atoms to used in (Eq. 23); besides, we take into account the interaction of the nearest neighbor atoms (Fig. 5), because they have the most important role in formation of the energy states [10]. We write the wave functionφkr(r)=1Ntunitcellsofthesystemeik.Rχr(R-r)in terms of basis functions, |ψand|φ1as the following:

|φ2E30

Figure 5.

In this figure the nearest neighbor atoms with respect to atom 0 are illustrated.

|ψ=c1|φ1+c2|φ2corresponds to atom 0 and|φ1corresponds to atoms 1, 2 and 3 in Fig. 5. Now applying (Eq. 22) to (Eq. 25 yields:

|φ2E31

and consequently:

H|ψ=c1H|φ1+c2H|φ2=c1E|φ1+c2E|φ2E32
c1φ1|H|φ1+c2φ1|H|φ2=c1Eφ1|φ1+c2Eφ1|φ2E33

Now, we define the following values:

c1φ2|H|φ1+c2φ2|H|φ2=c1Eφ2|φ1+c2Eφ2|φ2E34
HAA=φ1|H|φ1E35
HAB=φ1|H|φ2E36
SAA=φ1|φ1E37

then (Eq. 27) becomes:

SAB=φ1|φ2E38

knowing that:

c1(HAAESAA)+c2(HABESAB)=0E39
|φ1=1NtLatticesiteAeik.RAχr(r-RA)E40

Replacing (Eq. 30 a) and (Eq. 30 b) in (Eq. 28 a) to (Eq. 28 d) yields:

|φ2=1NtLatticesiteBeik.RBχr(r-RB)E41
HAA=ε2pE42
HAB=(eik.R11+eik.R12+eik.R13)VppπE43
SAA=1E44
SAB=(eik.R11+eik.R12+eik.R13)s0E45
HBB=φ2|H|φ2=HAAE46
HBA=φ2|H|φ1=HAB*E47
SBB=SAA=1E48

which make (Eq. 27 b) to become:

SBA=SAB*E49

considering (Eq. 29) and (Eq. 32) together; to have a non trivial solutions for c1 and c2 we should have:

c1(HAB*ESAB*)+c2(HAAESAA)=0E50

Solving (Eq. 33) for E [11]:

|HAAESAAHABESABHAB*ESAB*HAAESAA|=0E51

where:

E(k)±=(2E0+E1)±(2E0+E1)24E2E32E3E52
E0=HAASAAE53
E1=SABHAB*+HABSAB*E54
E2=HAA2HABHAB*E55

Neglecting the overlap of 2pz orbitals of atomic neighbors, SAB, we get:

E3=SAA2SABSAB*E56

Now applying Born von-Karman boundary condition (equation (Eq. 21)) to (Eq. 36) one can draw the energy diagram or the electronic band structure of SWCNT. Illustrated in Fig. 6(a) to 6(f) are the electronic band structures for several chiral vectors. At this step of our work, it is necessary to mention a few points. First of all, according to their chiralities, SWCNTs are

Figure 6.

The electronic band structures of several nanotubes according to (36) are illustrated. (a) is the electronic band structure of chiral vector (6,0), (b) (6,3), (c) (8,0), (d) (5,5), (e) (8,8), (f) (5,4)

roughly divided to three classifications. A nanotube with chirality of (n,0) is called a “zig-zag” nanotube. A nanotube with chirality of (n,n) is called an “armchair” nanotube and a nanotube without the two mentioned chiralities, is called a “chiral” nanotube. As examples, illustrated in Fig. 6(a) and (c) are the band structure of SWCNTs with chiral vectors (6,0) and (8,0) which are zig-zag nanotubes, and Fig. 6(d) and (e) show the band structure of SWCNTs with chiral vectors (5,5) and (8,8) which are armchair nanotubes.

As the Second point, it worth noting that, if we examine (Eq. 36) with Born-von Karman boundary condition, it is observed that for any chiral vector (n,m) when (n-m) mod 3 is equal to 0, then the band-gap is equal to zero. Two samples of this type are shown in Fig. 6(a) and (b). It is clear that according to this model armchair nanotubes are of this type. At early days it was believed that these nanotubes are metallic, but next, the deeper researches and calculations with other methods and approximations showed that they are “semi-metallic”[12].

Until now, we have performed our analytic calculations with the two assumptions. First, we assumed that the overlap of the two nearest neighbors is zero. Second, we assumed that the 2pz orbitals of the second and the third neighbors have no participation in formation of the band structure. However, in the following lines, we take into account the donation of these neighbors to the formation of the band structure of SWCNT.

Shown in Fig. 7 are the second and the third neighbors of the atom 0 of this figure. According to this figure, one can write:

E(k)±=±Vppπ3+2cos(k.a1)+2cos(k.a2)+2cos(k.(a1a2))E57
R11-R0=2a1-a23E58
R12-R0=2a2-a13E59
R13-R0=a1+a23E60
R21-R0=a1a2E61
R22-R0=a1E62
R23-R0=a2E63

Now, if we apply the formalism of the tight-binding approach, we catch up the following formulae:

R24-R0=(a1a2)E64
E0=[ε2p+γ1u(k)][1+s1u(k)]E65
E1=2s0sγ0f(k)+(s0γ2+s2γ0)g(k)+2s2γ2f(2k)E66
E2= [ε2p+γ1u(k)]2γ02f(k) – γ0γ2g(k) –γ22f(2k)E67
E3 = [1+s1u(k)]2- s02f(k) – s0s2g(k) – s22f(2k)E68
g(k) = 2u(k) + u(2k1-k2,k1-2k2)E69
f(k) = 3+u(k)E70

where the hopping parameters γ0, γ1, γ2 and the overlap parameters s0, s1 and s2 are introduced as follows:

u(k)=2cos(k.a1)+2cos(k.a2)+2cos(k.(a1a2))E71
γ0=χ(r-R0)|H|χ(r-R1i)E72
s0=χ(r-R0)|χ(r-R1i)E73
γ1=χ(r-R0)|H|χ(r-R2i)E74
s1=χ(r-R0)|χ(r-R2i)E75
γ2=χ(r-R0)|H|χ(r-R3i)E76

Then, (Eq. 38 a) to (Eq. 38 g) should be replaced in (Eq. 34) to get the energy formula. The numerical values for γ0, γ1, γ2 and s0, s1,s2 in addition to a comparison between the results of the mentioned method with the nearest neighbor π-TB can be found in [13].

Figure 7.

In this figure the nearest neighboring atoms, the second and the third neighboring atoms are illustrated.

At this point, we continue our work by examining some SWCNTs with different chiral vectors to investigate the effect of radius and chiral angle on the band-gap of these nanotubes. In Table I we have collected chiral vectors that have the same radii but different chiral angles to investigate such an effect. In this table from left, the first column shows the pairs of chiral vectors with the same radii. The second column shows their radii; the third column, their chiral angle; the forth one, the difference between chiral angles; the fifth column indicates the energy gap and finally sixth column shows the difference in band-gap which emanates from the difference between the chiral angle of the nanotubes with the same radii. As can be seen in this table the effect radius on the band-gap is considerable and the band-gap is approximately proportional tos2=χ(r-R0)|χ(r-R3i). On the other hand, as can be concluded from this table, change of the chiral angle has a little effect on the band-gap of SWCNT.

C:(m,n)r (nm)θ (Degrees)|Δθ| (Degrees)G (eV)|ΔG| (eV)
(9,1)0.3735.2021.781.0914480.031806
(6,5)26.991.059642
(9,8)0.57628.0517.890.6941520.018414
(13,3)10.150.675738
(14,3)0.6159.5113.170.6550920.010044
(11,7)22.680.645048
(15,2)0.6306.179.430.6177060.021204
(13,5)15.600.63891
(15,4)0.67911.5115.170.5931540.000558
(11,9)26.690.593712
(18,2)0.7465.2021.780.52195320.0054126
(12,10)26.990.5273658
(19,2)0.7854.9417.890.51163020.001953
(14,9)22.840.5135832
(19,3)0.8087.227.340.4837860.01395
(17,6)14.560.497736
(19,5)0.85811.389.430.46849680.0026784
(16,9)20.810.4658184
(23,1)0.9202.1121.780.42486120.01607
(16,11)23.890.4409316
(23,4)0.9877.8816.420.39779820.014564
(17,12)24.310.412362
(29,4)1.2216.3721.780.3225240.019139
(19,17)28.160.3416634
(30,4)1.2606.179.430.31677660.0071982
(26,10)15.600.3095784

Table 1.

A comparison between the effects of the radius and the chiral angle on the band-gap of SWCNT. In this table G is the band-gap. ΔG is the difference in band-gap of the two SWCNT with the different chiral angles.

4. The electronic band structure of SWCNTs under non-equilibrium conditions

4.1. The investigation of the band gap under mechanical strain

In this section of this chapter, we investigate the effect of the two types of mechanical strain, namely uniaxial (tensile) and torsional strains, by means of the two mentioned approximations.

If we denote the amount of uniaxial strain by σt, the angle of shear by α and the bonding lengthes R11-R0, R12-R0, R13-R0 by r1, r2 and r3 respectively, then, under these two type of strain we have the following relations [14]:

1RE77
ritTensilerit(1+σt)E78

where rit is that part of ri that is along the axis of the nanotube (with the unit vectorricTorsionric+rittan(α)) and ric is that part of ri that is in azimuthal direction or along the circumference of the nanotube (with the unit vectort^). In order to use (Eq. 40 a) and (Eq. 40 b) we have to express (Eq. 37) in terms of c^andt^:

c^E79
r1=an12dc^13d(n2+n12)t^E80
r2=an22dc^+13d(n1+n22)t^E81

Using these relations in conjunction with (Eq. 40 a) and (Eq. 40 b), we have the following formulae for r1, r2 and r3:

r3=(r1+r2)E82
r1=[an12dtan(α)3d(n2+n12)]c^(1+σt)3d(n2+n12)t^E83

and (Eq. 41 c) is still valid. At this step, we are to derive the 3rd neighbor π-tight-binding formulation to investigate the effect of uniaxial and torsional strains. We know that, there is the following formula for the interaction energy [14]:

r2=[an22d+tan(α)3d(n1+n22)]c^+(1+σt)3d(n1+n22)t^E84

where aC-C is the bond length in the absence of strain and r1i with i =1,2,3 is |ri| in the presence of strain. After performing the formal routine of the deriving of the tight-binding approximation formulae, we find:

γ0iγ0=χ(r-R0)|H|χ(r-R1i)withstrainχ(r-R0)|H|χ(r-R1i)withoutstrain=(aCCr1i)2E85
E0=[ε2p+γ1u(k)][1+s1u(k)]E86
E1=fsγ(k)+γ2gs(k)+s2gγ(k)+2s2γ2f(k)E87
E2=[ε2p+γ1u(k)]2fγγ(k)γ2gγ(k)γ22f(2k)E88

where functions f (k), f(k), gs(k),gγ(k), fγγ(k), and fss(k) in addition to details of calculations are given in [15].

Now, it’s time to apply (Eq. 44 a) to (Eq. 44 d) and see the results in comparison to other methods. Illustrated in Fig. 8 are the results of application of mentioned method for uniaxial and torsional strains in comparison with the nearest neighbor π-TB and the four orbital tight-binding approximations.

Figure 8.

A comparison between the results obtained using the nearest neighbor π-TB (circles), the third neighbor π-TB (squares), four orbital TB (plus signs) for (a) -3 to +3 percents of uniaxial strain (b) -3 to +3 degrees of shear [15].

As shown in Fig. 8 the method is examined for three chiral vectors, namely (6,5), (8,1) and (7,5). It can roughly be seen that, the 3rd neighbor π-TB approach yields a better agreement with the four orbital TB than the nearest neighbor π-TB. If we examine the energy formulae for a wide variety of chiral vectors, we find that, there is an approximately, linear relation between the percents of strain (both uniaxial and torsional) and the increase in band-gap [15].

4.2. The investigation of the band structure under magnetic field

The effect of magnetic field on the electronic band structure of SWCNT is the second effect that is investigated in this section. The application of H field parallel to the tubule axis is investigated by k.p method in [16],[17] and an Aharanov-Bohm effect is shown during this investigation. In this section the effect of perpendicular magnetic field is investigated using π-TB model. The investigation is originally performed by R. Saito et al. [18]. The investigation is based on two assumptions: first, the atomic wave function is localized at a carbon site; second, the magnetic field varies sufficiently slowly over a length scale equal to the lattice constant. The vector potential A is declared as:

E3=[1+s1u(k)]2fss(k)s2gs(k)s22f(2k)E89

where L = |C|, HM is the magnetic field and the coordinates x and y are taken along the circumference and the axis of the nanotube, respectively. Under the perpendicular magnetic field the basis functions of (Eq. 30 a) and (Eq. 30 b) are changed to:

A=(0,LHM2πsin2πLx)E90

GR is the phase factor that is associated with the magnetic field and is expressed as the following:

|φs=1NtLatticeei(k.Rs+ecGR)χr(r-Rs)          = A,BE91

Under application of magnetic field Hamiltonian operator becomes:

GR=RrA(ξ).dξ=01(r-R).A[R+λ(r-R)]dλE92

After application of Hamiltonian to (Eq. 46):

H=(12m)[pecA]2+VE93

Since H|φs=1NtLatticeei(k.Rs+ecGR){(12m)[pecA]2+V}χr(r-Rs)and considering (Eq. 47), then:

B=×A=×(AGR)E94

In deriving the equation above the two mentioned assumptions are used, namely, it is assumed that the magnetic field is slowly changing compared with the change of H|φs=1NtLatticeei(k.Rs+ecGR){(12m)[pec(AGR)]2+V}χr(r-Rs)=1NtLatticeei(k.Rs+ecGR)(p22m+V)χr(r-Rs)and χr(r-Rs)is localized at r = Rs. Now, we can calculate the matrix elements of Hamiltonian between the two Bloch functions, χr(r-Rs)and |φ1and solve to obtain the eigenvalues. If we examine the π-TB calculated band structure, it is observed that when the magnetic field increases the energy dispersion of each tubule energy band becomes narrower and the total energy bandwidth decreases with increasing magnetic field,however, when we apply higher magnetic field the total energy bandwidth is found to oscillate as function of HM [18].

5. Conclusion

In this chapter we first described the concept of chiral vector, chiral angle and the radius of SWCNTs and formulated them. Then we explained different symmetries of single walled carbon nanotubes including translational, helical and rotational symmetries. We investigated the Brillouin zone and the electronic band structure of single walled carbon nanotube in the absence of perturbating mechanisms. Our investigation included the nearest neighbor π-TB and the third nearest neighbor π-TB approximations. Next, using these two models we investigated the effect of two types of mechanical strain and perpendicular magnetic field.

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Rahim Ghayour and Pakkhesal (July 27th 2011). Electronic Band Structure of Carbon Nanotubes in Equilibrium and None-Equilibrium Regimes, Electronic Properties of Carbon Nanotubes, Jose Mauricio Marulanda, IntechOpen, DOI: 10.5772/17556. Available from:

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