The low-dimensional allotropes of carbon have drawn much attention in a multitude of fields owing to their outstanding fundamental properties and potential for applications. Interest in such systems has branched out from carbon fullerenes and carbon nanotubes (CNTs) toward other novel carbon nanomaterials such as graphitic onions, cones, nanohorns, nanohelices, nanobarrels, and graphene. All of these unique carbon nanomaterials show promising capabilities for applications in electronic devices.
Especially, CNT has the potential to make the process of development of electronics comprehensible to us as well as conquering many of the size limitations of the circuits with possible applications in integrated circuits and energy conservation. It is believed that CNT-electronics shares the potential, together with Biotechnology and Artificial Intelligence to improve current devices. Such advances can then be used to solve problems not possible in present. Conductive and high-strength composites; energy conversion and energy storage devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects are some of the many potential applications based on carbon nanotubes. Some of these applications are now realized in products. Others are demonstrated in early to advanced devices.
In the field of electronics, experiments over the past several years have given researchers hope that wires and functional devices tens of nanometres or smaller in size could be made from such low-dimensional materials and incorporated into electronic circuits that work far faster and on much less power than those existing today. In the long term, the most valuable applications will take further advantage of the unique electronic properties of low-dimensional materials. Surrounded by such anticipation, the advancement of techniques for characterizing and manipulating of individual molecules and the availability of first-principles methods to describe electron tunneling through atomic chains or single molecules have facilitated the development of a variety of electronic devices, attesting to the potential utility of these molecules in nanoelectronic device architectures.
Few possible applications of CNT in electronics are discussed below:Carbon nanotube field-effect transistors (CN-FETs): CNT is one of the candidates for a quantum wire for the molecular-FET. Multi-channel carbon nanotube field-effect transistors (CNFETs) have been realized by depositing a large number of CNTs onto a metallic back gate. This work clearly demonstrates that CN-FETs are promising components for high-frequency (HF) applications. Recently, several works have been reported on the CNTs for FETs and CNT-logic applications.
Transistors: IBM has made CN-FET resembling to conventional MOSFET having conductional channel beneath the gate electrodes separated by a thin dielectric. The top gate devices exhibited excellent electrical characteristics, including steep sub-threshold slope and high transconductance at low voltages by reducing the gate-to-channel separation. Furthermore, the IBM scientists were able to fabricate both hole (p-type) and electron (n-type) transistors. The top-gate design allows independent gating of each transistor, making it possible to generate CMOS (complementary metaloxide semiconductor) circuits that have a simpler design and consume less power. The nanotube devices in this case outperformed the prototype silicon transistor.
Logic circuits: The first inter-molecular logic circuit has been created by IBM. The circuit is a voltage inverter made by using two nanotube field-effect transistors.
Diodes: A nanotube formed by joining nanotubes of two different diameters end to end can act as a diode, suggesting the possibility of constructing electronic computer circuits entirely out of nanotubes. A “p–n junction” is simulated along the single-walled carbon nanotube channel using two separate gates close to the source and drain of the CNTFET, respectively. The Schottky barrier field-effect transistor mechanism-based calculations of the current–voltage characteristics of the double-gated CNTFET show a good rectification performance of the p–n junction.
As like the applications, CNTs have been evinced as the material of future which will assist in extending the Moore’s law, which says that number of transistors per integrated circuit doubles every 18 months, and it has been the guiding principle for the semiconductor industry for over 30 years. The prime driving force in nanoelectronic industry is due to the continual miniaturization of electronic devices.
However, it will be progressively difficult to continue downscaling at this rate, as quantum tunneling, interconnect delays, gate oxide reliability, and excessive power dissipation, among other factors, start hampering the performance of such devices. While some of these issues can, in principle, be handled by improving device design, packaging, processing, and channel mobilities, the rapidly increasing cost of fabrication motivates exploration of entirely new paradigms, such as novel architectures and new channel materials. One promising direction involves replacing the “top-down” lithographic approach with a “bottom-up” synthetic chemical approach of assembling nanodevices and circuits directly from their molecular constituents. Molecules are naturally small, and their abilities of selective recognition and binding can lead to cheap fabrication using self-assembly. In addition, they offer tenability through synthetic chemistry and control of their transport properties due to their conformational flexibility.
In the case of CNTs, significant progress has been reported regarding synthesis, functionalization, and control of the electronic properties. Insertion into and doping of CNTs are steps toward nanotube functionalization, possibly opening pathways to the creation of nanoelectronic devices, to the synthesis of heteronanotubes, and to the application of CNTs in many fields of science. However, their use as building blocks for nanoelectronic devices has not yet been fully realized due to lack of control of the reactivity of the outer CNT walls and of the basic electronic structure.
Therefore, for electronics applications, it is very desirable to modify the electronic structure of CNT to obtain a metallic or a
In this chapter, I will show how we can design nanoelectronic component embodied with interesting device characteristics, especially rectifying diodes. Simple strategy for designing nanoelectronic diodes is creating CNT heterojunction and controlling their electronic structure. In view of incorporating CNTs into real operational nanodevices, CNT-based intramolecular junctions were proposed early on. As mentioned before, a diode electronic component has been realized by joining nanotubes of two different diameters end to end. Both theoretical and experimental studies of such nanojunctions are full of promise. The junctions can be designed through various conceivable linkages within one-dimensional morphologies, such as a direct covalent bond, organic or metallic linkages, and even spacing. Such formation of one-dimensional heterojunctions has led to materials with unique properties and multiple functionalities not realized in single-component structures that are useful for a wide range of applications.
Especially, I will introduce how we can design and simulate conventional three types of diodes, Zener-, Schottky-, and Esaki-type diodes. I will introduce that the CNT junctions with chemical or physical doping, and organic linkages open the door to the design nanoelectronic components embodied with unique electron transport characteristics as nanoelectronic devices. The designed nanoelectronic components will give an insight into the design and implementation of various electronic logic functions based on CNTs for applications in the field of nanoelectronics.
2. Theoretical methodology
Remarkable progress in the molecular(nano) electronics has been made in the last few years, as researchers have developed ways of growing, addressing, imaging, manipulating, and measuring small groups of molecules connecting metal leads. Several prototype devices such as conducting wires, insulating linkages, rectifiers, switches, and transistors have been demonstrated. In parallel, there has been significant theoretical activity toward developing the description of nonequilibrium transport through molecules.
Transport through a molecule under bias is essentially a nonequilibrium, quantum kinetic problem. Contacting a molecule with two leads effectively “opens up” the system, replacing the discrete molecular energy levels with a continuous density of states and establishing a common electrochemical potential and a band lineup between the contacts and the molecule. Under bias, the two contact electrochemical potentials split, and the molecule, in its bid to establish equilibrium with both contacts, is driven strongly out of equilibrium. Current flow thus requires a formal treatment of nonequilibrium transport, through a suitable wave function (scattering theory) or Green’s function technique. The Keldysh–Kadanoff–Baym nonequilibrium Green’s function (NEGF) formalism gives us a rigorous theoretical basis for describing quantum transport through such a system at an atomistic level.
This approach has been proven to be a powerful tool for studying electron-transport phenomena in nanodevices, and it provides a link between electron transport, first-principles electronic structure theory, and qualitative molecular orbital theory.
A typical simulation procedure consists of self-consistently coupling an electronic structure calculation with a suitable transport solver. Transport involves a nonequilibrium, open-boundary problem. We formally partition this problem into an active device and semi-infinite contacts that add or remove charges from it. The device energy levels and electrostatics are described by a Hamiltonian and a self-consistent potential, respectively, while the semi-infinite self-energy matrices with complex eigenvalues. Starting from an initial guess for the device density matrix described in a suitable basis set, we calculate the self-consistent potential, which, added with the device Hamiltonian, generates the device Fock matrix. The Fock matrix, together with the contact self-energies, determines the nonequilibrium Green’s function that describes the causal response of the device to a unit excitation. The NEGF formalism gives us exact prescriptions thereafter for recomputing the nonequilibrium density matrix and current density, including the effects of many-body interactions and scattering within the device. The great advantage of this method is its generality: within the same framework, we can describe transport through various materials such as molecules, silicon transistors, nanowires, nanotubes, spintronic devices, and quantum dots.
In the NEGF approach introduced above, the surface Green’s functions describing semi-infinite electrodes attached to the defined device part from the left and right sides are derived using the Hamiltonian and overlap matrices corresponding to each CNT contact. The Green’s function in this study is given by
Here E+ denotes the energy plus an infinitesimal imaginary part (usually 10-5 or 10-6), and
3. Designing nanoelectronic diodes
3.1. Conventional diodes
In electronics, a diode is a two-terminal electronic component that conducts electric current in only one direction. The term usually refers to a semiconductor diode, the most common type today. The most common function of a diode is to allow an electric current to pass in one direction (called the diode's forward direction) while blocking current in the opposite direction (the reverse direction). A semiconductor diode’s behavior in a circuit is given by its current–voltage characteristic, or
This unidirectional behavior is called rectification, and is used to convert alternating current to direct current, and to extract modulation from radio signals in radio receivers. However, diodes can have more complicated behavior than this simple on-off action. This is due to their complex non-linear electrical characteristics, which can be tailored by varying the construction of their
3.2. Designing strategy for nanoelectronic diodes
It has become clear through many studies that electron transport characteristics are influenced by the intrinsic properties of molecules, including their length, conformation, energy gap between the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO), and the alignment of molecular levels relative to the Fermi level of the contact. It has been demonstrated that the conductance of molecules can be controlled by the position of individual molecular levels. Therefore, the controlling the alignment of energy levels relative to the Fermi level of the contact allow us to design molecular scale devices using several building blocks such as carbon nonotubes.
Therefore, the strategy for designing nanoelectronic diodes is based on the control of the intrinsic properties, i.e. the electronic structure, of CNT by creating CNT junctions with organic linkages and chemical or physical doping. In this section, I will introduce four CNT junctions having Zener-, Schottky-, and Esaki-type diode characteristics.
3.3. Pure CNT
Detailed knowledge of the electron transport characteristics of pristine CNTs, both metallic (armchair) and semiconducting (zigzag) CNTs is a necessary requirement for investigating the designed CNT heterojunctions. Current–voltage (
The pure metallic CNT has two open conduction channels near the Fermi level at all applied bias ranges and shows a linear
3.4. Zener-like diode: Organic molecules encapsulation & charge transfer
One-dimensional carbon nanotube (CNT) junctions can be designed by encapsulating
The operational device characteristics of organic molecules encapsulated CNT junctions originate from distinct response of intrinsic transmission peaks of pure CNTs and the distinctive response is determined by the manner of the charge transfer. The charge transfer between CNT and doped organic molecules causes lateral shift of the transmission peaks, and the charge transfer between the encapsulated organic molecules cause vertical shift of the transmission peaks. Therefore, by controlling the charge transfer,
Each tetracyano–p–quinodimethane (TCNQ) and nucleophilic tetrakis(dimethylamino) ethylene (TDAE) molecules molecule is encapsulated in carbon nanotubes (13,0) and (17,0) (CNT13 and CNT17), as shown in Figure 6. Encapsulated organic molecules are separated by 4.342 Å or 4.480 Å for TCNQ and 5.675 Å for TDAE at periodic boundary condition with 12.780 Å of z-axis cell size. In the case of TCNQ molecule, we considered parallel(P) and tilted(T) stacking patterns at CNT17 due to a large diameter. So, we denote the designed models as “CNTa–b_c”, where “a”, “b”, and “c” respectively mean the size of zigzag CNT, encapsulated organic molecule, and stacking pattern.
3.4.2. Electron transport characteristics of TCNQ and TDAE encapsulated CNTs
When we encapsulate TCNQ and TDAE molecules into the semiconducting CNTs, the charge transfer between organic molecule and CNT affects the band structures of CNT. But the change of band structures is opposite each other because TCNQ and TDAE have different electrostatic features, electrophilic and nucleophilic. The electronic band structures of TCNQ and TDAE encapsulated CNT17s, pure CNT17 and organic molecules are shown in Figure 7.
The flat bands near the Fermi level are derived from the lowest unoccupied molecular orbital (LUMO) states of TCNQ, and the highest occupied molecular orbital (HOMO) states of TDAE, where each LUMO and HOMO creates acceptor and donor states in the gap of CNT. The band structures shift up and down by doping of TCNQ and TDAE, respectively. The band in CNT17-TDAE closely lies in the top of the CNT valence band, which induces charge transfer from CNT to TCNQ. The higher-lying band in CNT17-TDAE, however, overlaps with the bottom of the CNT conduction band. The bands are partially filled, indicative of effective electron transfer from TDAE to CNT. It is seen that the relatively large change of HOMO level in TDAE is derived from the large charge transfer, that is the doping effect of
Let us now discuss the electron transport characteristics of
TCNQ encapsulated CNTs show similar current behavior with pure semiconducting CNTs regardless of parallel or tilted conformation. There is almost no current until 0.6 V, beyond which the current starts to increase. In contrast TCNQ encapsulated CNTs, the change of energy level is larger for TDAE encapsulated CNTs and the direction of shift of transmission peak is opposite, moreover transmission peak crosses over the Fermi level and enters into the bias window as seen in Figure 8(b). Therefore, TDAE encapsulated CNTs have very small currents when applied bias is smaller than a critical bias voltage (~0.8 V), above which the current begins to increase owing to a new transmission peak within the bias window. Furthermore, this new transmission peak increases with increasing applied bias. It is seen that the
Accordingly, it is worth mentioning that the effect of non-covalent doping essentially originates from the shift of the transmission peaks. The charge transfer between CNT and doped organic molecules causes lateral shift of the transmission peaks, shift left or shift right, which gives different behavior under the applied bias voltages. And the shift can be controlled by tuning the electron affinity (EA) and ionization potential (IP) of the encapsulated molecules.
3.4.3. Electron transport characteristics of p-n junctions with TCNQ and TDAE encapsulated CNTs
We have investigated the operational device characteristics of the organic molecules encapsulated CNT
Figure 10 shows the
type CNT17-TDAE to the right
Junction1-3 show the decrease of current with increasing the size of empty region under forward bias (positive bias), and Junction4 and 5 have smaller current because the large empty region or absence of one type of dopant molecule suppresses a charge transfer between
In previous section, we have mentioned that lateral shift of the transmission peaks is seen for the TDAE or TCNQ encapsulated CNTs according to the dopants. In contrast, vertical shift of the transmission peaks is also seen the organic molecules encapsulated p-n junctions by charge transfer between encapsulated n-type and
It is concluded, that the effect of non-covalent doping and the rectifying behavior essentially originates from the shift of the transmission peaks through charge transfer between the CNT and different types of dopants. Therefore, we can realize conventional Zener-like diode using the organic molecule encapsulated CNT junctions.
3.5. Schottky-like diode: Organic linkage & dipole moment
One-dimensional carbon nanotube (CNT) junctions with peptide linkages can be designed, where the incorporation of peptide linkages and their associated dipole moments play an important role in determining the electron transport characteristics and lead to materials with unique properties, such as Schottky-like behavior.
The incorporation of peptide linkages gives rise to the suppression of current and the effects are more significant for metallic CNTs than for semiconducting CNTs. Furthermore, the electron transport characteristics of the designed junctions depend on the direction of the dipole moment associated to the peptide linkages, which brings about asymmetric I–V behavior.
The carbon nanotube models used in this study are metallic (armchair (5,5)) and semiconducting (zigzag (10,0)) CNTs. The intramolecular heterojunctions are assembled with two CNT units and five peptide linkages, shown in Figure 12. When less than five covalent linkages are employed or the chemical bridges are asymmetrically distributed around the CNT mouths, the conformational flexibility of the resulting model junctions increases considerably.
Figure 12 shows the investigated intramolecular heterojunctions composed of metallic and semiconducting CNTs, and peptide linkage. SM1 and SM2 indicate semiconductor/metal, and metal/semiconductor junctions with peptide linkages, respectively. The SM1 and SM2 junctions are distinguished by the asymmetric peptide linkage composed of C=O and N–H bonds. In the SM1 junction, the C=O and N–H bonds are, correspondingly, connected to the metallic and semiconducting CNTs and vice versa in the SM2 junction.
3.5.2. Electron transport characteristics
Figure 13 shows the
Junctions made by CNTs with different chiralites evoke unique properties and multiple functionalities. Indeed, the metal and semiconductor junction with a positive barrier height has a pronounced rectifying behavior, as in a typical Schottky diode. The difference in the electronic structures and screening properties of metallic and semiconducting CNTs gives rise to different band-bending profiles and, subsequently, a Schottky barrier at the junction interface, which explains the rectifying behavior across the junction. A large current exists under forward bias, while almost no current exists under reverse bias. In Figure 13, the SM1 junction displays a completely non-linear and asymmetric
The difference between the SM1 and SM2 junctions results from the connecting way between peptide linkages and CNT electrodes. In other words, the orientation of the dipole moment arising from the peptide linkages plays an important role in the resulting Schottky-like behavior. In the SM1 junction, the C=O and N–H bonds are correspondingly connected to the metallic and semiconducting CNTs, respectively, which sets up the direction of the dipole moment vector from the metallic CNT to the semiconducting CNT. Therefore, the charge transfer is induced from the semiconducting CNT to the metallic CNT, where the direction of the charge transfer is the same to the direction of the electron flow under a forward bias of the Schottky diode. It means that the SM1 junction resembles an
We have investigated the effects of the number of peptide linkage on the electron transport characteristics of the SM1 and SM2 junctions to clarify the effect of the dipole moment to the Schottky barrier and rectifying behavior. In Figure 14, it is seen that the tunneling current of the SM1 junction is suppressed at the reverse biases (positive biases) by increasing the number of peptide linkages, which reveals the dependence of the Schottky barrier on the dipole moment. In contrast, there is no significant dipole dependence at the SM2 junction. The increase of the tunneling current of both the SM1 and SM2 junctions at the negative biases originates from the increase of tunneling channels when the number of linkages increases from three to five peptides.
Based on these results, we can prove that the Schotkky barrier is basically induced by the intrinsic nature of the pure semiconducting–metallic CNT junctions; afterwards the induced Schotkky barrier can be controlled at the SM1 junction by varying the dipole moment through the number of incorporated peptide linkages, whereas the effect of the dipole moment is not significant at the SM2 junction.
3.6. Esaki-like diode / multi-switching: Chemical doping & donor state
One-dimensional carbon nanotube (CNT) junctions with two single- (or multi-)nitrogen-doped (N-doped) capped carbon nanotubes (CNTs) facing one another can be designed, where the modification of the molecular orbitals by the N-dopants generates a conducting channel in the designed CNT junctions, inducing a negative differential resistance (NDR) behavior, which is a characteristic feature of the Esaki-like diode, that is, tunneling diode. And by controlling doping level, NDR based multi-switching behaviour can be achieved.
The NDR behavior significantly depends on the N-doping site and the facing conformations of the N-doped capped CNT junctions. Furthermore, a clear interpretation is presented for the NDR behavior by a rigid shift model of the HOMO- and LUMO-filtered energy levels in the left and right electrodes under the applied biases.
The front end of the N-doped capped CNT(5,5) and CNT(9,0) is closed with a hemisphere of fullerene and the carbon atoms on the other end are passivated with hydrogen atoms. Then nitrogen atom is substituted at the cap or sidewall region as denoted by letters in Figure 15(a). In order to provide the device part of the two-probe system (contact–device–contact), that is, N-doped capped CNT junctions, saturated hydrogen atoms are detached from the optimized N-doped capped CNT(5,5) and CNT(9,0) and the modified structure is replicated so as to face one another with the proper distance, as shown in Figure 15(a). The distances between two facing N-doped capped CNTs are referred to as the distance of the fullerene dimer because the designed CNTs have a hemisphere of fullerene as a cap. Then the left and right sides of the CNT junctions are connected to appropriate semi-infinite CNT electrodes with the same chiralities of the CNT junctions.
In the single-N-doped capped CNT junctions, we consider four different conformations depending on the chirality of the CNTs (armchair(5,5) and zigzag(9,0)) and the spatial arrangement of the nitrogen atoms in the designed CNT junctions. Because of the distinct cap structures of the armchair(5,5) and zigzag(9,0) CNTs, pentagon- and hexagon-facing conformations are possible for the CNT(5,5) and CNT(9,0), respectively. In addition, both pentagon- and hexagon-facing conformations have the eclipsed and staggered conformations owing to the spatial arrangement of the N-dopants.
In addition, the designed multi-N-doped capped CNT junctions are considered, which are b-site_multi-N-doped CNT junctions according to the number of doped nitrogen atoms and their conformations compared to that of single-N-doped capped CNT(5,5) junction, 55b. In the multi-N-doped capped CNT junctions, only eclipsed arrangement of armchair(5,5) CNT junctions are considered. Whole designed geometries are depicted in the Figure 15(b).
3.6.2. Electron transport characteristics
Therefore, we have increased the number of doped nitrogen atoms at b site, b-site_multi-N-doped CNT(5,5) junctions, in order to investigate how NDR behavior response the number of doped nitrogen atoms.
The remarkable feature emerging from the
3.6.3. The role of the nitrogen dopants for the NDR behavior
Such distinguishable electron transport characteristics usually originate from the intrinsic nature of the molecule, such as the molecular energy level alignment with respect to the Fermi level and their response to the applied bias voltage. In this work, a new option is the doping of CNTs with nitrogen atoms, which tailors the electronic structure of the nanotube. Nitrogen has a profound effect on the structural arrangement and electronic properties of the CNTs, such as a strong donor state near the Fermi level. It has been shown theoretically that a small amount of dopant can drastically modify the electronic transport properties of the tube. For zigzag semiconducting CNTs, doping with a single nitrogen impurity increases current flow, whereas doped metallic CNTs with boron or nitrogen atoms produce quasibound impurity states of a definite parity and reduces the conductance via resonant backscattering. Although we designed 1D heterojunctions with two N-doped capped CNTs compared to the use of open-ended CNTs previously reported, the N-dopants correspondingly affect the electron transport characteristics of the N-doped capped CNT junctions, which are enhancement of tunneling current and appearance of NDR behavior through new conducting channels.
So, in advance we have investigated the molecular orbitals of one side of the designed junctions. If the molecular orbitals are well delocalized and contribute to the cap region, they can facilitate electron conduction between the linked CNTs. In Figure 19, it can be seen that the doped nitrogen atom enhances the contribution of the molecular orbitals at the cap region, especially the majority-spin HOMO-1 and minority-spin HOMO. In addition, the majority-spin LUMO and LUMO+1, and minority-spin LUMO+1 and LUMO+2 orbitals expand into the sidewall region from the cap region. Accordingly, in the N-doped capped CNT(5,5), two groups of energy levels (HOMOs and LUMOs) generate the HOMO filtered energy levels (HFEL) and the LUMO filtered energy levels (LFEL) through coupling with the semi-infinite CNT electrode. However, when the nitrogen is doped at the sidewall region (f doping site) instead at the cap region (b doping site), the enhancement on the cap region is weak, which is revealed as a low tunneling current and small Ipeak value.
Therefore, the NDR behavior in the N-doped capped CNT junctions can be interpreted by a rigid shift model of the LFEL and HFEL in the left and right electrodes under the applied biases (Figure 20). Under the applied biases, the alignment between LFEL and HFEL of each electrode gradually increases until Vpeak due to the fact that the applied bias leads to two different contact chemical potentials. When the applied bias reaches Vpeak, HFEL and LFEL of each electrode are well-aligned and a peak appears in the
It is concluded, that the doped nitrogen atom plays an important role in the electron transport characteristics of the designed CNT junctions by modifying their molecular orbitals so as to have the NDR behavior. Therefore, we can realize conventional Esaki-like diode using the N-doped capped CNT junctions.
It has been shown how we can design nanoelectronic component embodied with interesting device characteristics, especially rectifying diodes. Simple strategy for designing nanoelectronic diodes is creating carbon nanotube (CNT) junction and controlling their electronic structure. Several types of one-dimensional CNT junctions can be designed by organic linkages and chemical or physical doping. Each designed CNT junction show unique electron transport characteristics, Zener-, Schottky-, and Esaki-like diode.
The charge transfer between CNT and encapsulated organic molecules causes lateral shift of the transmission peaks, and the charge transfer between the encapsulated organic molecules cause vertical shift of the transmission peaks. Therefore, by controlling the charge transfer,
We could know that the tunneling barrier can be controlled by the strength of dipole moment. Therefore, the rectifying behavior of Schottky-like diode can be obtained by incorporating the peptide linkages to the metallic/semiconducting CNT junctions, where the direction of the dipole moment plays an important role in the determination of the rectifying behavior.
Finally, we showed that the doped nitrogen atoms modify the molecular orbitals so as to generate a conducting channel in the designed CNT junctions by inducing a negative differential resistance (NDR) behavior, which is a characteristic feature of the Esaki-like diode, i.e. tunneling diode. And by controlling doping level, NDR based multi-switching behaviour can be achieved.
It is concluded that the designed CNT junctions open the door to the design of nanoelectronic components embodied with interesting device characteristics. We believe that the results will give an insight into the design and implementation of various electronic logic functions based on CNTs for applications in the field of nanoelectronics.