Large-scale forest fires in the tropics, emitting vast amounts of aerosols and trace gases, drew the attention of scientists around the world in the late 80s and early 90s. A number of international collaborative research projects, such as TRACE-A (Transport and Atmospheric Chemistry near the Equator-Atlantic, ) and SAFARI-92 (South African Fire-Atmosphere Research Initiative, ), were initiated under the auspices of the International Geosphere-Biosphere Programme to investigate biomass burning emissions and their long-range transport. One of the areas of great interest was the Amazon region (Figure 1), which later led to the creation of the international Large Scale Biosphere-Atmosphere Experiment in Amazonia (LBA, ) in Brazil in 1998. Several intense observation campaigns were dedicated, not only to rainfall measurements by radar and storm structure, but also to biomass burning, monitoring of emissions and transport of aerosols and their impact on the vegetation and population of the region. However, monitoring of background concentrations of aerosols, deploying stacked filter units, had already been initiated in 1990 at the “Sierra do Navio” site (Amapá, about 190 km north of the equator) and in Cuiabá (Mato Grosso), a town located in the Brazilian savannah . The location of both sites is shown in Figure 1.
São Paulo is Brazil´s most populous State, with approximately 42 million inhabitants (21,5% of Brazil’s total population) in an area of 249 000 km². The region is diverse in terms of its geography, natural environment and economy, and can be broadly classified into three main zones. In the southeast, the Atlantic coastal strip is separated from the remainder of the State by the scarp of the Serra do Mar, containing Brazil´s largest remaining areas of Atlantic rainforest, a threatened ecosystem that has been largely eliminated in most of the Brazilian States bordering the Atlantic ocean. Located on a plateau above the scarp are the densely populated and heavily industrialized regions of metropolitan São Paulo (RMSP) and its satellite cities. Continuing inland, the largest fraction of the area of the State has an economy mostly based on agro industry. Here has been widespread conversion of natural ecosystems to agriculture. The most important single agricultural activity is sugar cane production, although there are also substantial cattle ranching, citrus cultivation and agro forestry for pulping and construction. In all regions, it is largely local emission sources that determine the chemical composition of the atmospheric aerosol, with a smaller influence of long-range transport of polluted air masses from elsewhere in Brazil.
In terms of atmospheric quality, suspended aerosol particles are (together with ozone) probably the most important atmospheric pollutant in both São Paulo city and the largely agricultural hinterland of the State. Ozone is generated during reactions involving the nitrogen oxides (NOx) and volatile organic compounds (VOCs) emitted from vehicles, biomass burning and biogenic sources. The particulates are either emitted directly (in the form of primary aerosols), or are produced during reactions involving gaseous precursors (SO2, NOx and hydrocarbons). In large urban areas, such as the Metropolitan Region of São Paulo (RMSP), anthropogenic emissions from vehicles and industrial processes are the dominant contributors to elevated aerosol levels, while biomass burning [5-7] and dust lifted from barren fields (Figure 2) during the dry winter season constitute the principal sources of aerosols in the central and western sectors of the state. The State of São Paulo is the largest producer of sugar cane in Brazil, accounting for about 60% of Brazil’s harvest , with more than 4,7 million hectares planted in 2010, of which 44% are burnt before harvesting . The sugar cane is mostly harvested from April to November. Although progress is being made in mechanization, large areas are still harvested manually, which requires burning of the crop in sectors of the plantations during the night prior to manual cutting to remove excess foliage. This practice results in large quantities of aerosols and trace gases being emitted into the atmosphere (Figure 2a), not only negatively affecting local towns, but also regions much further downwind [10-12], demonstrating the importance of monitoring aerosols throughout the State.
Along the São Paulo coast, marine aerosols are modified by the inclusion of pollutants emitted from transport, urban, and industrial sources. There are some areas where levels of anthropogenic pollution are low, and where the aerosol composition can be mainly attributed to natural origins. However, compared to metropolitan São Paulo and the interior of the State, the coastal zone has been much less well studied, with the exception of Cubatão, a heavily industrialized town near the coast close to Santos.
In the State of São Paulo, the first aerosol measurements began in Cubatão , and within the metropolitan area of São Paulo, notorious for its traffic emissions . In terms of morphology, São Paulo is among the world’s five largest cities, and is sixth largest in terms of population , with about 11,3 million inhabitants. The population of the Metropolitan Region of São Paulo (RMSP), which includes peripheral urban areas, reached an estimated 19,9 million persons in 2009 . Human activities including road transport and industry now exert an enormous impact on air quality in the region, and therefore on the health of the population . The total fleet of vehicles (cars, buses, trucks and motorcycles, powered by gasoline, ethanol and diesel) in the State of São Paulo exceeded 12,8 million in 2011, of which about 50% operate within the RMSP .
Observations from the Brazilian Lightning Detection Networks (RINDAT  and BrasilDAT at ELAT/INPE ) have shown a significantly higher lightning frequency over the RMSP and other large urban complexes within the State since the inception of the RINDAT Lightning Network in 1999 [20, 21]. This prompted a study of the impact of anthropogenic emissions on the frequency of lightning , showing a distinct increase of cloud-to-ground flashes, not only over the RMSP, but also over other large cities and densely populated or industrialized regions in the State, correlated to the occurrence of heat islands and increased concentrations of PM10.
2. Meteorology and climatology of the State of São Paulo
Since the meteorology of a region has a major impact on the dispersion or accumulation of pollutants, a brief characterization of the climate is appropriate. The State of São Paulo is located between the latitudes of about 20 and 25 South (Figure 1), thus falling into the transition zone from a tropical to a subtropical climate, with an annual rainfall total ranging between 1250 and 1650 mm in the interior, increasing to 1850 mm over the narrow coastal strip . The year can be roughly divided into two periods,
Sodar observations made during the period of June 2009 to December 2011 showed that strong nocturnal Low-Level-Jets (LLJs) develop on top of the surface radiation inversion, mostly during the relatively dry austral winter months (May – October), when stable conditions prevail [26, 27]. These LLJs generally form during the late evening at altitudes ranging from 250–500 m AGL, with maximum speeds of 12–20 m.s-1. They usually last until 08:00–09:00 Local Time (LT), when the inversion has been eroded by the solar radiation. The frequency of LLJs varied from 3 - 22 days per month, with higher frequencies and greater intensity generally during the winter months. Observations with a sodar were made at three different locations in the central region of the State,
3. Ground-level monitoring of particulates
Regular monitoring of air pollutants under the auspices of the Companhia de Tecnologia de Saneamento Ambiental (CETESB), the air quality “watchdog” in the State of São Paulo, started in the 70s, but a fully automatic monitoring network was only installed in 2000. Since then, observations are available in real time . In 2001, 29 automatic stations, the majority in the RMSP, were already in operation . From 2008 onwards, the automatic monitoring network was significantly expanded. In 2011, 42 monitoring stations in 28 towns were in operation, 19 in the RMSP and 23 in the remaining parts of the State . The majority of the stations monitor particulate matter (PM10), NO, NO2, NOx and O3, as well as meteorological parameters, while a few also measure PM2.5, SO2 and CO. The automatic air quality monitoring network is shown in Figure 3. Additionally, CETESB also maintained a network of 41 manual monitoring stations during 2011, where measurements are made of PM2.5, PM10, TSP (Total Suspended Particulates), black smoke and SO2, in various combinations . Aerosol mass concentrations are determined using either β-attenuation instruments (automatic stations) or gravimetric and reflectometric techniques (manual stations).
In accordance with recommendations of the World Health Organization , CETESB defines 5 levels of air quality: “Boa” (good), “Regular” (regular), “Inadequada” (insufficient), “Má” (bad) and “Péssimo” (extremely bad), the highest being invoked if one of the monitored pollutants exceeds the pre-defined threshold. The national air quality standards are defined in CONAMA Resolution No. 03/90 (Table 2 in ).
PM10 and TSP measurements are available since 1984 and 1985, respectively , although initially only from very few stations in the interior of the State, but gradually increasing to 41 and 11, respectively, in 2011 . Figure 4 shows the year-to-year variation of annual mean PM10 concentrations against the National Air Quality Standard (PQAr) for the RMSP and two sites in Cubatão (Figure 3, Nos. 24 and 25), which is one of the major industrial hubs in Brazil, where one site is located within the industrial suburb (No. 25) and the other in the town centre (No. 24). A significant reduction of mean annual PM10 concentrations can be noticed from 1998 onwards, confirming the success of implementation of stringent air quality control measures, administered by CETESB. However, within the industrial suburb, confined in a valley, concentrations are still about twice the PQAr. A detailed description of Cubatão, its industrial activities and their location are found in . More details on current PM10 and TSP concentrations are provided in Section 4.3.
Figure 5 demonstrates that the air quality in the interior of the State from 2002 to 2011, when a reasonable number of monitoring sites were already in operation , was generally well below the annual standard of 50 µg.m-3 for PM10, with the exception of Santa Gertrudes, just south of Rio Claro (Figure 6), where several large ceramic industries are located, notorious for emitting large quantities of aerosols. At two other monitoring sites, annual means were close to the Annual Standard. At Limeira mixed industrial activities range from metallurgical, through cellulose to ceramics, besides sugar cane and orange production and processing plants. Limeira and Santa Gertrudes are medium-sized industrial towns, about 20 and 40 km northwest of Americana (Figure 3, No. 52). The other site is in Piracicaba (Figure 3, No. 77), which also hosts mixed industrial activities, including a significant petrochemical plant. However, the exceedance in 2011 was most likely caused by major road construction works in the immediate vicinity of the monitoring site .
Although annual mean concentrations of PM in the State of São Paulo seem to be quite acceptable, it is obvious that violations of the daily Air Quality Standard do occur occasionally in several towns of the interior and within the RMSP. Comprehensive annual and specialized technical reports and publications on the air quality in the State of São Paulo, including detailed monitoring results, are available online .
4. Chemical composition of aerosols
4.1. Agro-industrial rural regions
Seasonal variability in the major soluble ion composition of atmospheric particulate matter in the principal sugar cane growing region of central São Paulo State indicates that pre-harvest burning of sugar cane plants is an important influence on the regional-scale aerosol chemistry . The size-distributed composition of ambient aerosols is used to explore seasonal differences in particle chemistry, and to show that dry deposition fluxes of soluble species, including important plant nutrients, increase during periods of biomass (sugar cane trash) burning [6, 10].
Concentrations of trace gases and aerosols were determined at six measurement sites of a regional network in São Paulo State (blue circles in Figure 6), installed in rural areas including the State´s central agricultural zone and the eastern coast  as part of an experimental research project to determine the anthropogenic component of nutrient deposition. The measurements were made over 12 months during 2008/2009 (one week of continuous sampling per month). Aerosols were collected onto 47 mm diameter Teflon filters using active samplers, and trace gases (NO2, NH3, HNO3 and SO2) were sampled using diffusion-based devices. The soluble ions NO3-, NH4+, PO43-, SO42-, Cl-, K+, Na+, Mg2+ and Ca2+ were analyzed in aqueous extracts of the aerosol filters, using ion chromatography. NO2, HNO3 and SO2 were similarly determined as NO2-, NO3- and SO42-, following aqueous extraction of the collection media. NH3 was determined using a colorimetric technique. Identification and quantification of nutrient sources was achieved using principal component analysis (PCA) followed by multiple linear regression analysis (MLRA) applied to the chemical data. Dry deposition fluxes were estimated using the measured atmospheric concentrations together with dry deposition velocities of gases and aerosols to different surface types, including tropical forest, savannah, sugar cane, pine, eucalyptus, orange, coffee, pasture and water. The annual cycle in deposition, to a sugar cane surface, of reactive nitrogen and sulphur in the gaseous, aerosol and dissolved phases is illustrated in Figure 7.
The sugar cane industry has a major impact on air quality and the characteristics of the atmospheric aerosol. During the dry season (May to October), the burning of the cane, a prerequisite of manual harvesting, has for many years resulted in very large emissions of pollutants, including high carbon content aerosols. These particles contain water-soluble organic carbon (WSOC), anions (sulphates, nitrates and chlorides), cations (potassium, ammonium, calcium, magnesium, sodium), black carbon (BC), insoluble organic carbon and trace metals. Carbonaceous material comprises the bulk of the aerosol mass, especially in fine particles [5-7, 35-39]. In 2004, the annual emission of nitrogen oxides (NOx) from sugar cane burning in Sao Paulo State was in excess of 45 Gg.N . This is not only indicative of the scale of the emissions, but also of their potential for formation of secondary aerosols (containing nitrates, amongst other components).
In 2011, annual mean PM10 concentrations measured at automatic monitoring stations in the agro-industrial interior of São Paulo State were in the range 23-91 g.m-3, with the highest values at locations affected by primary emissions from ceramics industries (Figure 5). At sites in the sugar cane production areas, annual mean PM10 concentrations were in the range of 32-41 g.m-3 . The data revealed no obvious trends in PM10 concentrations during the period 2002-2011 (Figure 5).
A proportion of the primary material emitted during sugar cane fires is in the form of the large ash fragments notorious for causing domestic soiling problems in the region. During 1995-1996, CETESB investigated deposition rates, and measured the concentrations of PAHs, PCBs, dioxins and furans. The sedimented material was collected during the harvest period using plastic funnels lined with polyurethane foam, positioned near to plantations and in the urban area of the city of Araraquara. Samples were also collected in parallel using a high volume filter-based sampler. Levels of PCBs were in the range 4-12 ng.m-3, and showed no association with levels of carbonaceous material derived from the fires. Deposition fluxes of the dioxins and furans were in the range 1-17 pg.m-2.day-1, and were higher in greater proximity to plantations, indicating that sugar cane burning was a source of these compounds. The PAHs were found in two distinct groups. Naphthalene, fluorene, phenanthrene, anthracene, fluoranthene, and pyrene were present at concentrations exceeding 30 ng.m-3, while acenaphthene, chrysene, benzo(a)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene and indeno(1,2,3,c,d)pyrene were found at up to 21 ng.m-3. Concentrations were always higher during the harvest period .
The presence of PAHs in ash from sugar cane fires was also reported by Zamperlini
Sugar cane burning is a major source of acidic gases that contribute to the formation of secondary aerosols. In Araraquara, Da Rocha
The distribution of soluble ionic material between fine (<3,5 µm) and coarse (>3,5 µm) aerosol fractions was determined by Allen
In separate work, biomass-burning aerosols were found to contribute around 60 and 25% of the mass of fine and coarse aerosols, respectively, in the Piracicaba sugar cane growing region . A high proportion of the elements K, S, Cl, Br, Fe and Si in aerosols has been linked to biomass burning , indicative of both a combustion component (emissions of K, S, Cl and Br) and a suspended soil dust component (emissions of Fe and Si).
In a study reported in , elemental analysis of individual and bulk aerosols collected in rural areas was followed by evaluation of the data using statistical hierarchical clustering, which revealed the contributions of two different types of carbonaceous material (biogenic and carbon-rich) and two aluminosilicate fractions (pure or mixed with carbon). These findings contrasted with the findings of similar work in the atmosphere of São Paulo city, where hierarchical clustering analysis revealed the presence of metal compounds, silicon-rich particles, sulphates, carbonates, chlorides, organics and biogenic particles . This reflects the very different characteristics of the aerosols found in the two regions.
Deposition rates of aerosol nutrient species to a range of natural and agricultural surfaces were reported in , using a size-segregated particle dry deposition model. Fluxes greatly exceeded those expected under pristine conditions, with deposition to tropical forest found to have increased by factors of 12,2 (NO3-), 6,2 (PO43-) and 2,6 (K+) (Figure 9). Source apportionment using principal component analysis (PCA) and multiple linear regression analysis (MLRA) revealed that in central São Paulo State, biomass burning, products of secondary reactions and soil dust re-suspension contributed 43%, 31% and 21% of PM2.5 mass, respectively. Re-suspension and biomass burning contributed 22% and 19%, respectively, to PM10 mass, and re-suspension accounted for approximately half the mass of coarse particles. At least 40% of NO3--N, 20% of phosphorus and 55% of potassium deposited originated from agriculture-related emissions.
Emissions of reactive nitrogen compounds are of concern due to their influence on both atmospheric acidity (production of HNO3 from reactions involving NO2) and the formation of photochemical oxidants such as ozone and peroxyacetyl nitrate (PAN). Reactions of acidic species with ammonia generate ammonium sulphates and nitrates, mainly in the long-lived accumulation mode size fraction. Deposition of reactive nitrogen can cause eutrophication of water bodies, as well as the release of trace metals in soils. Machado
The sources, atmospheric transport and reactions of the main inorganic reactive nitrogen (Nr) species (NO2, NH3, HNO3 and aerosol nitrate and ammonium) were investigated in a study conducted over a period of one year at six sites distributed across an area of about 130,000 km2 in São Paulo State . Oxidized forms of nitrogen were estimated to account for about 90% of dry deposited Nr, due to the emissions of nitrogen oxides from biomass burning and road transport. NO2-N was important closer to urban areas; however, HNO3-N was the largest individual component of dry deposited Nr. A simple mathematical model was developed to enable determination of total Nr dry deposition from knowledge of NO2 concentrations. The model, whose error ranged from <1% to 29%, provided a new tool for the mapping of reactive nitrogen deposition.
The sugar cane burning emissions radically alter the chemistry of precipitation water. Coelho
4.2. Metropolitan São Paulo (RMSP)
In terms of trace species, the composition of the lower troposphere in the conurbation of the RMSP differs considerably from that of the interior of the State and the coastal zone. The critical air quality issue here is the scale of the emissions from road vehicles. In 2001, the vehicle fleet consisted of 17,2% hydrated ethanol-fuelled, 76,3% gasohol-fuelled and 6,5% diesel-fuelled vehicles, with ethanol contributing 34% of the total fuel consumption . The figures for 2011 were 46,7% gasohol (cars and light commercial), 3,9% hydrated ethanol, 31,9% flex-fuel, 5,4% diesel and 12% motorcycles .
It is important to consider the relative amounts of the different fuels used, since emissions vary according to fuel, which has consequences for aerosol composition. For example, there is a larger fraction of oxygenated compounds in the secondary aerosols produced from reactions involving the aldehydes and alcohols emitted during ethanol combustion, which can affect the hygroscopicity of the particles, as well as their toxicological properties [48, 49].
The proportions of gasohol (gasoline with 22% anhydrous ethanol) and hydrated ethanol used have varied considerably in recent decades. Ethanol was first adopted as a road vehicle fuel in Brazil in 1979, due to the Brazilian National Alcohol Program (PROALCOOL), which was introduced as a response to the 1970s oil crisis. This not only reduced Brazil’s dependency on oil imports, but also helped to eliminate the use of lead-containing anti-knock additives . Sales of hydrated ethanol-fuelled vehicles peaked in the 1980s . More recently, since around 2005, the new car market has been dominated by flex-fuel vehicles equipped with engine systems able to adjust to the gasoline/ethanol mixture present in the fuel tank .
In 2011, the sources of PM10 in metropolitan São Paulo were: heavy goods vehicles (38,6%), re-suspended dusts (25%), secondary aerosols (25%), industrial processes (10%) and light duty vehicles (1,4%). Annual mean concentrations of PM10 measured at the 18 automatic monitoring stations in São Paulo ranged between 31 and 50 g.m-3 . A detailed analysis of these measurements, as well as of PM2.5, TSP and black smoke measurements made at a smaller number of locations, are provided in the CETESB report  and in earlier annual reports published by CETESB.
The pollutant source profile remains fairly constant throughout the year. Use of absolute principal factor analysis showed that the contributions of different sources to PM2.5 mass during winter and summer were: vehicle emissions (28 and 24% for the two seasons, respectively), re-suspended soil dusts (25 and 39%), oil combustion (18 and 21%), sulphates (23 and 17%) and industrial emissions (5 and 6%). Soil dusts accounted for 75-78% of the mass of coarse particles . Andrade
Organic and elemental carbon, emitted mainly from diesel vehicles, together with ammonium sulphate, make up most of the mass of fine particles [54, 55]. In  it is reported that 80% of the mass of fine (PM2.5) particles consisted of organic material, with SO42-, NO3- and NH4+ present in the fine fraction, and NO3-, SO42-, Ca2+, and Cl- predominant in coarse particles (PM2.5-10). Albuquerque
Aerosol composition similar to that of São Paulo is found in other major conurbations. In Campinas, the second largest city in the State, 100 km inland from São Paulo, fine particles were found to consist of 48% elemental carbon and 22% organic carbon, together with soluble ions and trace elements .
The PM concentrations are influenced not only by the magnitudes of emission sources, but also by ventilation and relative humidity. Miranda and Andrade  reported that higher PM10 concentrations (105 g.m-3) measured during the winter of 1999, compared to winter 2000 (60 g.m-3), were due to both better ventilation of the city during the latter period, as well as an increase in particle sizes at higher humidity. Similar findings were reported in , with lower pollutant levels associated with increased ventilation, precipitation, and relative humidity.
Primary emissions from vehicles result in large diurnal cycles in the concentrations of PM10, BC, CO, NOx and SO2 , however the diurnal trends in particle mass concentrations differ between highly polluted and less polluted periods, with concentrations higher during the daytime for the former, and during the nighttime for the latter . A possible influence of humidity on both the mass and size distribution of the Sao Paulo aerosol was suggested by the observation that while the size distribution of ammonium sulphate was unimodal during the daytime (with a maximum at 0,38 m), at night, when humidity is higher, the size distribution was bimodal (with maxima at 0,38 and 0,59 m) . Furthermore, particle growth, observed using a Scanning Mobility Particle Sizer (SMPS), has been found to increase under polluted conditions .
Although local sources are by far the most important contributors to particulate air pollution in São Paulo city, back-trajectory analysis has shown that the atmosphere of the city can also be affected by the advection of air masses from distant regions where agricultural biomass burning is practiced, especially northeast Brazil . This could explain the finding that the relative contribution of ammonium sulphate is higher under less polluted conditions .
An important consequence of the prevalence of fine mode particles in the atmosphere of the city is that the indoor environment provides little or no protection against exposure to these pollutants, since they easily infiltrate buildings. This was observed  using simultaneous indoor and outdoor measurements of a range of ionic species associated with both primary emissions (potassium, magnesium, sodium and calcium) and secondary aerosol formation (chloride, acetate, nitrate, formate, pyruvate, nitrite, sulphate, oxalate and ammonium). The measurements were made in offices, restaurants and a hotel. In the fine mode, only oxalate and ammonium showed significantly lower concentrations indoors. In the coarse mode, lower concentrations were normally found indoors (with the exception of acetate, chloride and potassium), reflecting the less efficient infiltration of larger aerosols.
Polycyclic aromatic hydrocarbons are an important component of the urban aerosols. Chrysene, benzo(e)pyrene and benzo(b)fluoranthene were found to be the predominant PAHs in PM10, originating from industry, vehicles and long-range transport . Levels of PM10 similar to those in São Paulo were measured in a city (Araraquara) situated in the rural biomass burning zone, although here PAH concentrations were lower. In both cases, dry deposition appeared to be the main mechanism of removal of PAH-containing aerosols from the atmosphere .
4.3. Coastal regions
Although measurements of atmospheric aerosol are scarce in most of the coastal regions, an exception is the industrialized town of Cubatão, located near sea level at the base of the Serra do Mar scarp, where there is a large industrial complex comprising over 20 heavy industries (petrochemical, chemical, iron and steel, fertilizer, cement, coking and others). The monitoring stations in this area register regular episodes of particulate pollution, with the emissions from the industrial installations being entrained into a sea breeze circulation, when PM10 concentrations can increase by as much as an order of magnitude . Pollutants absorbed into cloud water and precipitation are subsequently deposited to the vegetation of the Serra do Mar Atlantic rainforest, causing extensive ecological damage .
Due to extreme levels of pollution, air quality in the Cubatão region has been monitored by CETESB since the 1980s, and there are currently three sites where PM10 is continuously measured (Figure 5), and one where TSP is measured . The case of Cubatão is unique, since in contrast to the RMSP, by far the largest source of particulates is industrial emissions, rather than road transport. Guideline levels of TSP and PM10 have been frequently exceeded in the industrial zone (Vila Parisi) of Cubatão, and there has been no improvement in PM10 levels in recent years. During 2011, the annual mean PM10 concentrations in the three zones of Cubatão were 99 g.m-3 (Vila Parisi), 61 g.m-3 (Vila Mogi) and 38 g.m-3 (Centro) . At the industrial Vila Parisi site, the annual geometric mean TSP concentration was 236 g.m-3, greatly exceeding the primary and secondary air quality standards for this pollutant species (80 and 60 g.m-3, respectively).
Although industrial emissions are responsible for the largest proportion of the aerosol loading of the atmosphere near the Cubatão industrial complex, the organic fraction has an important road transport-related component, because concentrations of polycyclic aromatic hydrocarbons (PAHs) are governed by emissions from heavy duty diesel vehicles . In the same work, it was reported that a shift to greater use of biodiesel might decrease emissions of the PAHs.
In regions distant from the industrial installations, the aerosol composition reflects mainly natural sources (biogenic, terrigenous and marine). Bourotte
5. Lidar observations
In 2001, an elastic backscattering lidar system (MSP-Lidar) was installed in a suburban area of São Paulo city, on the Campus of the University of São Paulo (23°33’ S, 46°44’ W; Figure 6) and is being operated by the
In January 2004, the IPEN MSP-Lidar system was installed for 6 weeks at IPMet in Bauru (Figure 6), located in the central part of São Paulo State, to provide the first measurements of aerosol layers in the interior of the State . At the beginning of the campaign, the lidar was operated in its original configuration and the data were digitized using a digital oscilloscope with 1 GHz bandwidth and 11-bit resolution; at the end of January 2004, this device was replaced by a transient recorder, capable of simultaneous analog and photon counting measurements at higher resolution (12-bit). The system was operated on 31 different days, during periods of about 4 hours in the morning, 4 hours in the afternoon and 6-8 hours during the night, depending on the occurrence of cloud and/or precipitation. The daytime measurements had a 15-30 m spatial resolution and maximum altitude of 10 km, yielding information on the diurnal variation of the Planetary Boundary Layer (PBL), while the measurements at night had a 30-60 m resolution, reaching up to 30-35 km maximum altitude. The diurnal variation of the PBL during the austral summer could be documented, as well as some background concentrations of aerosols, because very little biomass burning takes place during the rainy period.
Figure 10 shows a typical example of the diurnal variation of the height of the PBL on a cloudless day in Bauru. It should be noted that, due to the latitude of -22,3, the lidar cannot be operated during the midday period in summer, but as a result of turbulent mixing, the PBL could easily reach a maximum height of ≥3,5 km above ground level (AGL) during the early afternoon. The top of the PBL starts decreasing well before sunset, until it stabilizes at around 1,5 km AGL during the night. Times are indicated in Local Time (LT = UT-3h).
The increased vertical range of the lidar during nocturnal operation permitted the detection of thin clouds and layers of aerosols, as shown in Figure 11. A cloud layer is clearly visible at around 4,5 km, while aerosols were detected at 3 and 5 km AGL, respectively. The top of the PBL is at about 1850 m AGL, with the faint layering being indicated in shades of green and light-blue colours.
In early 2008, the MSP-Lidar system was upgraded to a Raman lidar, and in its present 3-channel configuration it can measure elastic backscatter at 355 nm, together with nitrogen and water vapour Raman backscatters at 387 nm and 408 nm, respectively. Therefore, the PBL data now available include aerosol backscattering and extinction coefficients, as well as the Lidar Ratio (LR) and water vapour mixing ratio. Figures 12 and 13 present typical results of Raman lidar measurements recorded during night-time of 09/10 January 2008, during the austral summer season. This period of the year is characterized by a very well defined boundary layer throughout the day and relatively high humidity. The major part of aerosols and water vapour is contained within the boundary layer, while the scattering above the PBL is mainly due to molecules. Figure 12 shows the aerosol extinction and backscattering coefficient profiles at 355 nm, where one can see a residual aerosol layer between 900 m and 2000 m AGL, indicating a very pronounced presence of aerosols, overlaid by another discrete layer above it between 2500 m and 3500 m AGL. The height profile of the Lidar Ratio is shown in Figure 13a. The Lidar Ratio is about 80 sr and stable throughout the PBL up to about 3000 m AGL. The vertical profile of the lidar-derived water vapour mixing ratio can be seen in Figure 13b. The calibration of the lidar was performed using radiosonde data from the nearby São Paulo Campo de Marte airport. Although the sonde had a relatively low height resolution, integrating the water vapour content with height made such calibration possible.
The MSP-Lidar system has contributed to several studies concerning the properties of aerosols and their influence on the air quality index of the city of São Paulo. Lidar measurements conducted daily provided observations of the PBL variation, which could be compared to corresponding air quality index values from local air quality monitoring and management agencies, as well as identifying potential air dispersion conditions . It has also been deployed to monitor the long-range transport of aerosol plumes from different regions of Brazil to the RMSP and to evaluate the contribution of aerosol pollutants from remote sources. Landulfo and Lopes  have analyzed an event during the period 02 - 09 August 2007 when the AOD (Aerosol Optical Depth) and AE (Ångström Exponent) values retrieved from the AERONET sunphotometer indicated that high aerosol loads at five different locations in the Brazilian territory corresponded to biomass-burning particles. This was validated by the mean values of the Total Attenuated Backscatter Coefficient at 532 nm, the mean depolarization ratio and also the Lidar Ratio (about 70 sr) for all sites over-flown by the CALIOP sensor onboard the CALIPSO satellite.
In another case study during the dry winter season of 2008, fire plumes attributed to sugar cane fires were frequently observed by IPMet’s radars in the absence of rain echoes and documented in terms of radar reflectivity, time and location . On several occasions, IPEN’s Elastic Backscatter Lidar in São Paulo observed layers of aerosols of varying strength and heights above the city. The most significant days were selected for calculating
backward, as well as forward trajectories, deploying the Flextra 3.3 Trajectory Model , which was initiated with ECMWF historical data with a 0,25 x 0,25 grid spacing . The results showed an excellent match between the radar-detected sources of the plumes and lidar observations in São Paulo. Figure 14 presents a typical case study, when emissions from biomass fires were identified by the radars on 11 July 2008 in the central parts of the State, and were subsequently monitored by IPEN’s lidar over Metropolitan São Paulo on 14 July 2008, deploying forward and backward trajectories. The forward trajectories, initiated at different heights ranging from 930 hPa (close to ground level) up to 450 hPa (ca 6,7 km amsl) at 30 hPa intervals (only the most significant 10 heights are shown in Figure 14), indicated a transport duration of approximately 70 hours under the prevailing meteorological conditions (Figure 14b). The arrival of the plume over the RMSP on 14 July 2008, as observed by the lidar at IPEN, is shown in Figure 15.
The MSP-Lidar system in São Paulo has also been contributing to CALIPSO satellite validation procedures [75, 82]. During 2007, correlative measurements were carried out with special attention to the dry season (May-October), when most of the days have poor dispersion conditions and long distance transport is more frequent. From a total of 28 days of measurements, on only 10 days were no clouds present below 4 km. Figure 16a presents a typical example, showing the range-corrected signal retrieved by the lidar system at São Paulo on 10 October 2007 between 03:34 and 05:35 UT, which contains the CALIPSO overpass window, beginning at 04:30 UT (Figure 16b). On this day, the closest distance of the satellite ground-track from the lidar site was about 48 km. The presence of aerosol layers above the PBL at 4-5 km, 6 km and 9 km is noticeable. The same features are also observed in the CALIOP 532 nm Total Attenuated Backscattering plot, as shown in Figure 16b. Both systems detected a cirrus structure between 12 and 13 km AGL, but the strong cirrus cloud signal observed in the CALIOP “plot-curtain” is much weaker in the lidar image. The red box in Figure 16b represents the CALIPSO ground-track region over Metropolitan São Paulo with coordinates of -22,5625 latitude and -46,0247 longitude at about 04:35 UT.
Figure 17 compares the attenuated backscatter coefficient profile retrieved by CALIOP on board the CALIPSO satellite and the corrected one obtained from the ground-based MSP-Lidar system in São Paulo. The satellite profile has a 5 km horizontal resolution. The attenuated backscatter profile from the MSP-Lidar site was derived under cloud-free conditions from the range-corrected and background noise-subtracted lidar return signal. Both profiles are in good agreement, presenting similar layer patterns in the profiles observed at 5-6 km and about 7 km AGL. Since it can be assumed with reasonable confidence that, at higher altitudes, the horizontal atmospheric structure is more homogeneous, the good agreement between the two systems demonstrates the possibility that they were probing the same air masses for this specific measurement. At lower altitudes, observation of some differences between the two profiles is more likely due to local effects. In this case, the localized effects are more pronounced, and the fact that the systems are not covering the exact same region becomes evident.
5.2. Mobile Raman lidar
The mobile bi-axial Raman lidar system uses a commercial pulsed Nd:YAG laser, operating at a wavelength of 532 nm in the elastic channel and 607 nm in the Nitrogen Raman channel, with a pulse energy of 130 mJ at 20 Hz PRF. The pulse width is 25 ns, yielding a spatial resolution of 7,5 m. A detailed description of the system is found in . The system allows the determination of the optical properties of the atmosphere, including aerosol backscatter and extinction coefficients, as well as an indication of the type of aerosol present, based on the Lidar Ratio. This lidar has so far been deployed during specific campaigns at three different sites within the central region of São Paulo State,
A one-month pilot study was undertaken during August 2010 in Ourinhos (Figure 6), which is situated in one of the State’s major sugar cane producing regions, where biomass burning is a regular occurrence. The objective was to characterize the effects of these emissions on the atmosphere, considering the local circulation and the consequences for the region . In the absence of rain, the plumes were tracked by IPMet´s two S-band Doppler radars within their quantitative ranges of 240 km (BRU = Bauru, PPR = Presidente Prudente; Figure 6), using the TITAN (
During the second half of August 2010, the weather was dominated by a high pressure system, resulting in a rise in temperatures, with low humidity favoring the accumulation of pollutants in the atmosphere of the region . IPMet’s radars have a 2° beam width and a quantitative range of 240 km, generating a volume-scan every 7,5 minutes, with a resolution of 250 m radially and 1° in azimuth. Reflectivities and radial velocities are recorded at 16 elevations. However, in order to detect and track the biomass burning plumes, a special scanning cycle was configured to provide a better vertical resolution up to the anticipated detectable top of the plumes: 10,0, 8,0, 6,5, 5,0, 4,0, 3,2, 2,4, 1,6, 0,8 and 0,3, with each “sweep” (Plan Position Indicator - PPI) having 360 rays with 957 range bins each. Two different software systems were deployed,
A typical case study of a sugar cane fire in the Ourinhos region is now presented, demonstrating the integration of all types of data into one coherent event. The first echo of a smoke plume was detected by the Bauru radar on 26 August 2010 at 00:08 LT, about 35 km north-northeast of Ourinhos and about 85 km southwest of the radar (Figure 18), rapidly gaining in area and intensity (≤40 dBZ near its origin). By 00:22 LT, the TITAN Software could already identify its centroid of 10 dBZ reflectivity and tracked it until 02:45 LT, when the plume had already spread over Ourinhos, where the Raman lidar and sodar were located. As the plume moved southwards with the northerly winds, the aerosols spread out (dispersed) and the reflectivity dropped gradually, but it could still be detected by the radar until 03:46 LT, >20 km south of Ourinhos, using a reflectivity threshold of –6 dBZ .
Furthermore, it can be deduced from Figure 18a that while the plume was at a low height during the initial phase of transport, it moved very slowly (3-4 km.h-1), since the wind speed in the first few hundred meters was very low (5 m.s-1), as observed by the sodar. There was also a shift of the wind direction from easterly to northerly winds above 300 m AGL. These northerly winds were above the nighttime surface inversion, confirmed by the “Skew T x Log P” profiles of the Meso-Eta model in the 900-800 hPa layer (650–1650 m AGL) as shown in . The vertical velocity (w), measured by the sodar, indicated that downward mixing of the pollutants (aerosols), trapped above the inversion, only commenced at around 09:00-09:30 LT, since from 00:00-09:00 LT the atmosphere was extremely stable below 300 m AGL (w = 0 m.s-1).
The lidar observed the arrival of the plume at 02:40 LT between 350 and 600 m AGL (Figure 19a). The top of the PBL extended to about 2,6 km AGL, above which a very dry and relatively warm and clean air mass was advected from the west, creating an elevated inversion which blocked further upward mixing. The lowest layer ≤250 m AGL appeared clean, being trapped within the surface inversion, inhibiting downward mixing, also confirmed by the sodar measurements, indicating a very stable layer. Lidar data from the Raman Channel (non-elastic signal at 607 nm) were integrated into hourly means until 09:00 LT to obtain the AOD. The results confirmed a high aerosol load of the atmosphere, with hourly mean values of AOD varying between 0,265 and 0,288 until 07:00 LT, after which they increased to 0,433 by 09:00 LT. Hourly means of the Lidar Ratio confirmed the arrival of the plume between 02:00 and 03:00 LT (example shown in Figure 19b), while an almost 20% increase of LR to 72 sr after 07:00 LT was probably due to downward mixing of the aerosols accumulated above the inversion, also confirmed by an increase of AOD values from the Raman signal . LR values of around 70 sr suggest aerosols originating from biomass burning [90, 91].
Visual images from overpasses of the MODIS-AQUA satellite on 25 and 26 August 2010 (at 17:35 and 16:40 UT, respectively; 14:35 and 13:40 LT) showed intense smoke plumes to the west and south of the Ourinhos region, with AOD values of up to about 1,0. In the Ourinhos region, the AOD increased during the period 25-26 August, from about 0,2 to about 0,6 (Figure 20a), which is in agreement with the early afternoon lidar measurements (Figure 20b), which provided an AOD value of 0,380 during the period from 13:00 to 14:00 LT.
Aerosols collected during daytime and nighttime periods at the lidar site [85-87, 92], using low-volume filter samplers, were chemically characterized by means of ion chromatography. A higher concentration of K+ during the period from 22:00 on 25 August to 16:00 on 26 August 2010 indicated the presence of biomass-burning material (Figure 21), since K+ is a plant macronutrient released during the combustion process. Levoglucosan, a very specific chemical marker of biomass combustion, was well above average concentration during day sampling on 26 August and even higher during the following night, indicating a strong presence of biomass smoke on both days.
In the study region, ions such as magnesium (Mg2+) and calcium (Ca2+) are associated with the re-suspension of soil dust, which often accompanies biomass fires due to the intense updrafts created. On 26 August, concentrations of these species were higher during the daytime, due to the increased emissions from barren fields and unsealed roads associated with higher wind speeds (Figure 21).
Further evidence of the impact on the Ourinhos region of emissions from sugar cane fires was obtained by comparing the concentrations of organic compounds in aerosol particles collected on 26 August with those collected one day earlier. Ambient levels of polycyclic aromatic hydrocarbons (PAH), as well as PAH derivatives, such as oxy-PAH, were significantly higher on 26 August 2010 than on the previous day, confirming that emissions from sugar cane fires affected the urban atmosphere of Ourinhos.
5.3. Scanning lidar in Cubatão
An elastic backscatter lidar system, with similar characteristics to the mobile lidar, was installed in 2011 at CEPEMA-USP (
During May 2011, the system was deployed in a vertical pointing mode during an intensive field campaign. A 24-hour period was selected that demonstrated the complexity of the local situation, which is dominated by topographical effects and prevailing meteorological conditions . Vertical profiles of the Backscatter Coefficient (BSC) and the Colour Ratio were calculated for 30-minute periods from 17:30 – 19:59 and 21:42 – 23:36 LT. The BSC was highest for all frequencies between 19:30 and 19:59 LT (Figure 22a), indicating a strong inflow of aerosols, while after 21:42 LT the BSC showed much lower values (Figure 22b), representing a relatively clean air mass. At the same time, the Colour Ratio between all frequencies increased significantly, indicating the presence of small particles, especially between 0,8 and 1,3 km AGL . Ground-level observations of PM10 and PM2.5 for the 24-hour period indicate that PM10 concentrations were almost twice as high as those of PM2.5 until about 18:00 LT (Figure 23). During the same period, the sodar observed extremely low wind speeds from varying directions. However, this resulted in very stable PBL conditions, and a temperature inversion began to develop from 18:30 onwards, reaching its greatest depth and intensity at 21:30. Thereafter, it gradually dropped in height and began to erode, as the air flow from the interior intensified, until it totally dissipated by 01:00 LT , due to the katabatic warming of the descending northerly airflow, which then also reduced the aerosol concentrations at ground level (Figure 23). Figure 24a shows the development of the surface inversion at 20:00 LT, overlaid by warm air flowing from the interior, with simultaneous downward motion below 240 m AGL (Figure 24b), highlighting the complex interaction of meteorology and topography in this region. This situation clearly demonstrates the need for solid environmental impact studies
6. Impacts of aerosols
6.1. Impact of aerosols on human health
The impact of anthropogenic aerosols on human health has been acknowledged in both metropolitan and rural regions , and references therein]. In general terms, as pointed out in , in recent years the population of São Paulo State has suffered from either acute (short-term, high concentration) or chronic (long-term, lower concentration) exposure to particulate air pollutants, depending on location. In rural regions, there is acute exposure to high concentrations of biomass burning particulates present in plumes, as well as chronic exposure to these aerosols on a regional basis throughout the dry season. In metropolitan São Paulo, there is chronic exposure to particulates derived from road transport and industrial emissions, together with periodic acute exposure to extremely high levels of pollutants under conditions of thermal inversions and stationary air masses [94-96].
There have been many studies of the correlation between aerosol concentrations and human health impacts in the metropolitan regions, especially in São Paulo city [97-102]. Typical effects include asthma and pneumonia, as well as other cardiovascular and respiratory symptoms. Increased levels of PM10 were associated with increases of 6,7% and 2,2% in hospital admissions of children due to respiratory illness [96, 103]. Increments of 10 g.m-3 in PM10 concentrations resulted in increases in hospital admissions of between 0,9% and 6,7% in Sao Paulo [97, 103-105]. In the elderly, a 5,4% increase in the number of deaths was linked to a 10 g.m-3 increase in PM10 . Industrial emissions in Cubatão have been found to seriously affect the lung function of children, with respiratory airflow rates correlated with PM10 concentrations obtained for the preceding month .
In these heavily polluted regions, atmospheric particles contain components known to be carcinogenic and mutagenic, including ketones, aldehydes, quinolines, carboxylic acids, polycyclic aromatic compounds (PAHs), and nitro-PAHs. These substances have been associated with exhaust emissions from road vehicles in southeast Brazil [69, 107-109]. Benzo[a]pyrene equivalent values suggest that the cancer risk is greater for the São Paulo city aerosol than elsewhere in the State, although concentrations may not exceed World Health Organization guidelines .
Biomass burning emissions in rural regions also have a recognized influence on human health, as well as environmental impacts including modification of nutrient cycling [10, 11, 47], and effects on climate including alterations of the radiative properties of the lower atmosphere, cloud formation and precipitation [110, 111]. For these reasons, as well as due to the need to meet certification requirements of importing countries, there has been increased pressure for mechanization of harvesting, since the mechanized process does not necessarily require prior burning of the crop. Nonetheless, until recently burning has continued to be employed in mechanized areas (using simpler machinery) because it can improve economic efficiency by around 30-40% [50, 112].
A clear relationship between particulate air pollution and the occurrence of respiratory illness in sugar cane burning regions of the State has been reported [45, 113-116]. Particulate material from sugar cane burning was demonstrated to have the greatest detrimental effect on the respiratory systems of the most sensitive population groups. Cançado
Carcinogenic and mutagenic compounds are emitted during biomass burning . Concentrations of PAHs in a rural sugar cane burning region during the harvest period were in the range 0,5-8,6 ng.m-3 . The mutagenic activity of PM10 was much higher during the harvest season, when the PM10 concentration was 67 g.m-3, and the mutagenic potency was 13,45 revertants m-3. During the summer (non-burning period), the PM10 concentration was 20,9 g.m-3, and the mutagenic potency was 1,30 revertants m-3 .
6.2. Impact of aerosols on rainfall
Aerosols derived from all of the sources described above are able to alter the radiative properties of the troposphere, and can modify the processes that lead to the development of cloud condensation nuclei, cloud droplets, and ultimately precipitation [118-120]. The magnitudes of these effects depend on the size distribution, number concentration and chemical composition of the particles, and can therefore vary widely within the same region.
Dufek and Ambrizzi  used daily precipitation data collected at 59 locations in São Paulo State to investigate rainfall trends for the period 1950-1999. Although some of the findings were contradictory, an overall trend towards a wetter climate was identified, with rainfall concentrated into a smaller number of more intense events. It was suggested that these changes could be related to the presence of biomass burning aerosols, as well as changes in land use. Evidence that the aerosols probably act as cloud condensation nuclei was provided in , where a relationship was identified between water-soluble organic carbon (WSOC) in the particles and dissolved organic carbon (DOC) in rainwater.
An important point is that sugar cane production in São Paulo State has increased over this period. Between the 1990/91 and 2000/01 seasons, the harvest increased from 132 Mt to 194 Mt . It can therefore be supposed that there was also a large increase in emissions of aerosols from the burning of the crop, since manual harvesting of the cane (which requires prior burning) was the norm over the period. Mechanization of the crop (which does not involve burning) has only been introduced recently (from around 2005). The main conclusion to be drawn from this is that the trend towards a smaller number of more intense precipitation events, as reported in , could now be reversed in the interior of São Paulo State, as sugar cane burning is progressively phased out.
The climatological characterization of storm properties, such as area, volume, maximum echo top and reflectivity during two summer seasons,
The influence of anthropogenic aerosols on precipitation patterns in the region is the subject of research currently in progress as part of a thematic climate change research programme sponsored by FAPESP (the São Paulo State Research Foundation). The quantitative evaluation of changes in the rainfall pattern, such as increases or decreases of area rainfall totals, number and volume of convective cells, duration of rain events, distribution of echo top heights, etc., is in progress for a 10-year period of integrated radar observations (Bauru and Presidente Prudente radars), using the TITAN Software.
6.3. Impact of aerosols on the frequency of lightning
Westcott  documented for the first time an impact of large cities on the cloud-to-ground (CG) lightning frequency in the Midwest of the United States. This was followed up by various researchers around the world, including in Brazil  and ultimately summarized in , using 10 years of observations from the Brazilian Lightning Detection Networks (1999-2008). This research confirmed the impact of anthropogenic activities on lightning, but it also highlighted the complexity of the correlation between urban heat islands, concentrations of PM10 and SO2 in terms of weekly cycles and meteorological conditions, such as CAPE (Convective Available Potential Energy) and other microphysical parameters. One of the most important findings was that the CG frequency increases with increasing concentrations of PM10 up to a certain threshold of PM10 concentration (saturation), after which it decreases with further increases of PM10 concentrations. As the CG frequency increases due to urban impacts, the percentage of positive strokes is reduced.
7. Final considerations
This Chapter provides a review of all relevant historical data concerning the nature, concentrations and impacts of atmospheric aerosols in southeast Brazil. Highlights are the characterization of chemical, physical and optical properties of aerosols, as well as their geographic distribution within the State of São Paulo.
A significant reduction of mean annual PM10 concentrations could be noticed from 1998 onwards, confirming the success of the implementation of stringent air quality control measures, administered by CETESB. However, within the industrial suburb of Cubatão, confined in a valley, concentrations are still about twice the PQAr. After 2002, the annual mean PM10 concentrations in the RMSP and the interior of the state show relatively little year to year variation, but remain mostly below the Annual Standard (PQAr = 50 µg.m-3).
At present, sugar cane burning, together with the re-suspension of soil dust that is inevitable during the harvesting process, is a major influence on aerosol concentrations, size distribution and dry deposition in rural regions of São Paulo State. However, in this region (and elsewhere in Brazil), the practice of pre-harvest burning is being eliminated. Recent legislation (State Law no. 11.241/02) envisages the complete cessation of the practice in mechanizable areas by 2021 and in non-mechanizable areas by 2031. Furthermore, an agreement between sugar cane producers and the State government has been reached, which involves elimination of burning in mechanizable areas by 2014, and in non-mechanizable areas by 2017 [9, 126]. This will have major environmental implications, including improvements in air quality and changes in the rates of deposition of nutrient species from the atmosphere to vegetation, soils and freshwater bodies . Nonetheless, at present burning continues in 44% of the area planted with sugar cane . Tsao
Improvements in air quality in the metropolitan regions are likely to proceed at a slower pace than in the interior of the State, largely due to the dominant influence of emissions from the road transport sector. Nonetheless, emissions of aerosols and other pollutants are ultimately expected to be attenuated following progressive modernization of the vehicle fleet, and implementation of better controls on emissions from both vehicular and industrial sources.
Examples of case studies presented have demonstrated the capability of weather radars to detect, track and quantify emissions from biomass fires in the absence of rain echoes, deploying a special elevation scanning procedure to generate Volume-Scans every 7,5 min. Furthermore, satellites orbiting with lidar systems on board (e.g., MODIS-AQUA, CALIPSO, CloudSat) also have the capability to detect and quantify optical properties of aerosols.
With the gradual introduction of lidars in Brazil during recent years, it has also become possible to quantify in situ the vertical distribution and optical properties of suspended aerosols. However, in the State of São Paulo there are currently only three lidar systems available, viz., one fixed lidar each in São Paulo city and in Cubatão, supplemented by the mobile lidar for periodic deployment in the interior of the State. Additional fixed lidar installations are therefore suggested for Campinas, Rio Claro, Bauru and São José do Rio Preto (situated in an important sugar cane production region in the north of the State) as a minimum configuration for a network, together with a second mobile system in São José dos Campos to cover the industrial activities in the Paraiba Valley.