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Engineering » Vehicle Engineering » "Diesel Engine - Combustion, Emissions and Condition Monitoring", book edited by Saiful Bari, ISBN 978-953-51-1120-7, Published: April 30, 2013 under CC BY 3.0 license. © The Author(s).

Chapter 5

Structured Catalysts for Soot Combustion for Diesel Engines

By E.D. Banús, M.A. Ulla, E.E. Miró and V.G. Milt
DOI: 10.5772/54516

  1. M. V. Twigg, 2011Catalytic control of emissions from carsCatal. Today 1633341

  2. D. Fino, 2007Diesel emission control: Catalytic filters for particulate removalSci. Technol. Adv. Mater. 893100

  3. D. R. Tree, K. I. Svensson, 2007Soot processes in compression ignition enginesProg. Energy Combust. Sci 33272309

  4. M. A. Gómez-garcía, V. Pitchon, A. Kiennemann, 2005Pollution by nitrogen oxides: an approach to NOx abatement by using sorbing catalytic materials. Environ. Int. 31445467

  5. X. Lu, D. Han, Z. Huang, 2011Fuel design and management for the control of advanced compression-ignition combustion modesProg. Energy. Combust. Sci. 372011741783

  6. S. Gan, H. K. Ng, K. M. Pang, 2011Homogeneous Charge Compression Ignition (HCCI) combustion: Implementation and effects on pollutants in direct injection diesel enginesAppl. Energ. 882011559567

  7. J. P. A. Neeft, W. Schipper, G. Mul, M. Makkee, J. A. Moulijn, 1997Feasibility study towards a Cu/K/Mo/(Cl) soot oxidation catalyst for application in diesel exhaust gases. Appl.Catal. B: Environmental 11, 365 EOF

  8. M. V. Twigg, 2007Progress and future challenges in controlling automotive exhaust gas emissionsAppl. Catal. B: Environmental 70215

  9. R. M. Heck, R. J. Farrauto, 2001Automobile exhaust catalystsAppl. Catal. A: General, 221443457


  11. B.R Stanmore, ., V Tschamber, ., J.F Brilhac, . (2007) Oxidation of carbon by NOx, with particular reference to 2 and N2O. Fuel, 87 131146 .

  12. K. Krishna, M. Makkee, 2006Soot oxidation over NOx storage catalysts: Activity and deactivationCatal. Today 1144856

  13. V. G. Milt, C. A. Querini, E. E. Miró, M. A. Ulla, 2003Abatement of diesel exhaust pollutants: NOx adsorption on Co,Ba,K/CeO2 catalystsJ. Catal. 220424432

  14. Nakatani, K., Hirota, S., Takeshima, S., Itoh, K., Tanaka, T. (2002) Simultaneous PM and NOx Reduction System for Diesel Engines. SAE paper 2002-01-0957

  15. K. Itoh, T. Tanaka, S. Hirota, T. Asanuma, K. Kimura, K. Nakatani, 2003Exhaust purifying method and apparatus of an internal combustion engines. US patent, US 6,594,991.

  16. J. A. Sullivan, O. Keane, A. Cassidy, 2007Beneficial and problematic interactions between NOx trapping materials and carbonaceous particulate matterAppl. Catal. B: Environmental 75102106

  17. M. A. Peralta, M. S. Zanuttini, C. A. Querini, 2011Activity and stability of BaKCo/CeO2 catalysts for diesel soot oxidation. Appl. Catal. B: Environmental 1109098

  18. C. B. Lim, H. Kusaba, H. Einaga, Y. Teraoka, 2011Catalytic performance of supported precious metal catalysts for the combustion of diesel particulate matterCatal. Today 175106111

  19. M Sun, ., L Wang, ., B Feng, ., Z Zhang, ., G Lu, ., Y Guo, . (2011) The role of potassium in K/Co3O4 for soot combustion under loose contact. Catal. Today 175 100105 .

  20. E. D. Banús, M. A. Ulla, M. V. Galván, M. A. Zanuttini, V. G. Milt, E. E. Miró, 2010Catalytic ceramic paper for the combustion of diesel sootCatal. Comm. 124649

  21. B Azambre, ., S Collura, ., P Darcy, ., J.M Trichard, ., Da Costa P., García-García A., Bueno-López A. (2011) Effects of a Pt/Ce0.68Zr0.32O2 catalyst and 2 on the kinetics of diesel soot oxidation from thermogravimetric analyses. Fuel Process Technol 92 363371 .

  22. Z. Wang, Q. Li, L. Wang, W. Shangguan, 2012Simultaneous catalytic removal of NOx and soot particulates over CuMgAl hydrotalcites derived mixed metal oxidesAppl. Clay Sci. 55125130

  23. Q. Li, M. Meng, H. Xian, N. Tsubaki, X. Li, Y. Xie, T. Hu, J. Zhang, 2010Hydrotalcite-Derived MnxMg3−xAlO Catalysts Used for Soot Combustion, NOx Storage and Simultaneous Soot-NOx Removal. Environ. Sci. Technol. 4447474752

  24. M. Zawadzki, W. Staszak, F. E. López-suárez, M. J. Illán-gómez, A. Bueno-lópez, 2009Preparation, characterisation and catalytic performance for soot oxidation of copper-containing ZnAl2O4 spinels. Appl. Catal. A: General 3719298

  25. M. Zawadzki, W. Walerczyk, F. E. López-suárez, M. J. Illán-gómez, A. Bueno-lópez, 2011CoAl2O4 spinel catalyst for soot combustion with NOx/O2. Catal. Commun. 1212381241

  26. S. Li, R. Kato, Q. Wang, T. Yamanaka, T. Takeguchi, W. Ueda, 2010Soot trapping and combustion on nanofibrous perovskite LaMnO3 catalysts under a continuous flow of soot. Appl. Catal. B: Environmental 93383386

  27. Z. Li, M. Meng, F. Dai, T. Hu, Y. Xie, J. Zhang, 2012Performance of K and Ni substituted La1−xKxCo1−yNiyO3−δ perovskite catalysts used for soot combustion, NOx storage and simultaneous NOx-soot removal. Fuel 93606610

  28. Z. Li, M. Meng, Q. Li, Y. Xie, T. Hu, J. Zhang, 2010Fe-substituted nanometric La0.9K0.1Co1−xFexO3−δ perovskite catalysts used for soot combustion, NOx storage and simultaneous catalytic removal of soot and NOx. Chem. Eng. J. 16498105

  29. V. G. Milt, M. A. Ulla, E. E. Miró, 2005NOx trapping and soot combustion on BaCoO3−y perovskite: LRS and FTIR characterization. Appl. Catal. B: Environmental 571321

  30. H. Muroyama, S. Hano, T. Matsui, K. Eguchi, 2010Catalytic soot combustion over CeO2-based oxidesCatal. Today 153133135

  31. R. Zhang, N. Luo, B. Chen, S. Kaliaguine, 2010Soot Combustion over Lanthanum Cobaltites and Related Oxides for Diesel Exhaust TreatmentEnergy Fuels 2437193726

  32. V. G. Milt, E. D. Banús, M. A. Ulla, E. E. Miró, 2008Soot combustion and NOx adsorption on Co,Ba,K/ZrO2. Catal Today 133-135:435 EOF440 EOF

  33. M. Colombo, I. Nova, E. Tronconi, Schmeißer V., Bandl-Konradb B., Zimmermann L. (2012NO2N2O-NH3 SCR reactions over a commercial Fe-zeolite catalyst for diesel exhaust aftertreatment: Intrinsic kinetics and monolith converter modeling.Appl. Catal. B: Environmental 111-112: 106 EOF118 EOF

  34. M. Colombo, I. Nova, E. Tronconi, 20122adsorption on Fe- and Cu-zeolite catalysts: The effect of the catalyst red-ox stateAppl. Catal. B: Environmental 111-112: 433 EOF444 EOF

  35. W. Shan, F. Liu, H. He, X. Shi, C. Zhang, 2012An environmentally-benign CeO2TiO2 catalyst for the selective catalytic reduction of NOx with NH3 in simulated diesel exhaustCatal. Today, in press.

  36. W. Shan, F. Liu, H. He, X. Shi, C. Zhang, 2012A superior Ce-W-Ti mixed oxide catalyst for the selective catalytic reduction of NOx with NH3. Appl. Catal. B: Environmental 115-116: 100 EOF106 EOF

  37. H. Koga, T. Kitaoka, 2011One-step synthesis of gold nanocatalysts on a microstructured paper matrix for the reduction of 4-nitrophenolChem. Eng. J. 168420425

  38. V. Meille, 2006Review on methods to deposit catalysts on structured surfacesAppl. Catal. A: General 315117

  39. A. G. Konstandopoulosa, M. Kostogloua, 2000Reciprocating flow regeneration of soot filters. Comb. Flame, 121488500

  40. K. S. Yang, G. Mul, J. S. Choi, J. A. Moulijn, J. S. Chung, 2006Development of TiO2/Ti wire-mesh honeycomb for catalytic combustion of ethyl acetate in airAppl. Catal. A: General 3138693

  41. A. F. Ahlström-silversand, Ingemar Odenbrand C.U., (1997Thermally sprayed wire-mesh catalysts for the purification of flue gases from small-scale combustion of bio-fuel Catalyst preparation and activity studiesAppl. Catal. A: General 153177201

  42. E. D. Banús, V. G. Milt, E. E. Miró, M. A. Ulla, 2012Catalytic coating synthesized onto cordierite monolith walls. Its application to Diesel soot combustionAppl. Catalysis B: Environmental, submitted.

  43. E. D. Banús, V. G. Milt, E. E. Miró, M. A. Ulla, 2010Co,Ba,K/ZrO2 coated onto metallic foam (AISI 314) as a structured catalyst for soot combustion: Coating preparation and characterization. Appl. Catal. A: General 37995104

  44. R. M. Heck, S. Gulati, R. J. Farrauto, 2001The application of monoliths for gas phase catalytic reactionsChem. Eng. J. 82149156



  47. S. Biamino, P. Fino, D. Fino, N. Russo, C. Badini, 2005Catalyzed traps for diesel soot abatement: In situ processing and deposition of perovskite catalystAppl. Catal. B: Environmental 61297305

  48. E. Cauda, D. Fino, G. Saracco, V. Specchia, 2004Nanosized Pt-perovskite catalyst for the regeneration of a wall-flow filter for soot removal from diesel exhaust gasesTop. Catal. 30/31299303

  49. D. Fino, E. Cauda, D. Mescia, Russo, Saracco G., Specchia 2007LiCoO2 catalyst for diesel particulate abatement. Catal. Today 119: 257-261.

  50. E. Cauda, D. Mescia, D. Fino, G. Saracco, V. Specchia, 2005Diesel Particulate Filtration and Combustion in a Wall-Flow Trap Hosting a LiCrO2 Catalyst.Ind. Eng. Chem. Res. 4495499555

  51. D. Fino, P. Fino, G. Saracco, V. Specchia, 2003Innovative means for the catalytic regeneration of particulate traps for diesel exhaust cleaningChem. Eng. Sci. 58951958

  52. J. P. A. Neeft, O. P. Van Pruissen, M. Makkee, J. A. Moulijn, 1997Catalysts for the oxidation of soot from diesel exhaust gases II. Contact between soot and catalyst under practical conditionsAppl. Catal. B: Environmental 122131

  53. C. A. Neyertz, E. E. Miró, C. A. Querini, 2012K. Ce, O2 catalysts supported on cordierite monoliths: Diesel soot combustion study. Chem. Eng. J. 181-182: 93 EOF102 EOF

  54. M. E. Gálvez, S. Ascaso, I. Tobías, R. Moliner, M. J. Lázaro, 2012Catalytic filters for the simultaneous removal of soot and NOx: Influence of the alumina precursor on monolith washcoating and catalytic activityCatal. Today 19196105

  55. M.E Gálvez, ., S Ascaso, ., R Moliner, ., R Jiménez, ., X García, ., A Gordon, ., M.J Lázaro, . (2011) Catalytic filters for the simultaneous removal of soot and NOx: Effect of CO2 and steam on the exhaust gas of diesel engines. Catal. Today 176 134138 .

  56. J. P. Bortolozzi, E. D. Banús, V. G. Milt, L. B. Gutierrez, M. A. Ulla, 2010The significance of passivation treatments on AISI 314 foam pieces to be used as substrates for catalytic applicationsAppl. Surf. Sci. 257495502

  57. R. E. Raj, V. Parameswaran, B. S. S. Daniel, 2009Comparison of quasi-static and dynamic compression behavior of closed-cell aluminum foamMat. Sci. Eng. A 5261115

  58. I. Kurtbas, N. Celik, 2009Experimental investigation of forced and mixed convection heat transfer in a foam-filled horizontal rectangular channel Original. Int. J. Heat Mass Transfer 5213131325

  59. M. V. Twigg, J. T. Richardson, 2002Theory and applications of ceramic foam catalystsChem. Eng. Research. Design, 80183189

  60. E. D. Banús, V. G. Milt, E. E. Miró, M. A. Ulla, 2009Structured catalyst for the catalytic combustion of soot: Co,Ba,K/ZrO2 supported on Al2O3 foamAppl. Catal. A: General 362129138

  61. M. A. A. M. Nor, L. C. Hong, Z. A. Ahmad, H. M. Akil, 2008Preparation and characterization of ceramic foam produced via polymeric foam replication methodJ. Mat. Process. Tech. 207235239

  62. S. A. Silva, D. D. Brunelli, F. C. L. Melo, G. P. Thim, 2009Preparation of a reticulated ceramic using vegetal sponge as templatingCeramic. Int. 3515751579

  63. X. Mao, S. Wang, S. Shimai, 2008Porous ceramics with tri-modal pores prepared by foaming and starch consolidation34107112

  64. J Yu, ., X Sun, ., Q Li, ., X Li, . (2008) Preparation of Al2O3 and Al2O3-ZrO2 ceramic foams with adjustable cell structure by centrifugal slip casting. Mat. Sci. Eng. A 476 274280 .

  65. X. He, X. Zhou, B. Su, 20093D interconnective porous alumina ceramics via direct protein foamingMater. Lett. 65830832

  66. S. Barg, C. Soltmann, M. Andrade, D. Kock, G. Grathwohl, 2008Cellular Ceramics by Direct Foaming of Emulsified Ceramic Powder SuspensionsJ. Am. Cerm. Soc. 9128232829

  67. M. F. Ashby, A. G. Evans, N. A. Fleck, L. J. Gibson, J. W. Hutchinson, H. N. G. Wadley, Metal Foams: A Desing Guide. Butterworth-Heinemann. 2000United States of America.

  68. P. Ciambelli, V. Palma, P. Russo, S. Vaccaro, 2002Deep filtration and catalytic oxidation: an effective way for soot removalCatal. Today 73363370

  69. P. Russo, P. Ciambelli, V. Palma, Vaccaro (2003Simultaneous Filtration and Catalytic Oxidation of Carbonaceous ParticulatesTop. Catal 22123129

  70. P. Ciambelli, V. Palma, P. Russo, S. Vaccaro, 2002Performances of a catalytic foam trap for soot abatementCatal. Today 75471478

  71. P. Ciambelli, V. Palma, P. Russo, S. Vaccaro, 2005Issues on soot removal from exhaust gases by means of radial flow ceramic trapsChem. Eng. Sci. 6016191627

  72. V. Palma, P. Russo, M. D. Amore, P. Ciambelli, 2004Microwave regenerated catalytic foam: a more effective way for PM reductionTop. Catal. 30/31261264

  73. G. Saracco, C. Badini, N. Russo, V. Specchia, 1999Development of catalysts based on pyrovanadates for diesel soot combustionAppl. Catal. B: Environmental 21233242

  74. A. Setiabudi, B. A. A. L. Van Setten, M. Makkee, J. A. Moulijn, 2002The influence of NOx on soot oxidation rate: molten salt versus platinumAppl. Catal. B: Environmental 35159166

  75. M. Ambrogio, G. Saracco, V. Specchia, 2001Combining filtration and catalytic combustion in particulate traps for diesel exhaust treatmentChem. Eng. Sci. 5616131621

  76. G. Saracco, N. Russo, M. Ambrogio, C. Badini, V. Specchia, 2000Diesel particulate abatement via catalytic trapsCatal. Today 603341

  77. P. Ciambelli, P. Corbo, V. Palma, P. Russo, S. Vaccaro, B. Vaglieco, 2001Study of Catalytic Filters for Soot Particulate Removal from Exhaust GasesTop. Catalysis 16-17: 279 EOF284 EOF

  78. B. Caglar, D. Üner, 2007Preparation and Morphological Characterization of a Catalytic Soot Oxidation SiC Foam FilterTurkish J. Chem. 31487492

  79. B. A. A. L. Van Setten, J. Bremmer, S. J. Jelles, M. Makkee, J. A. Moulijn, 1999Ceramic foam as a potential molten salt oxidation catalyst support in the removal of soot from diesel exhaust gasCatal. Today 53613621

  80. B. A. A. L. Van Setten, C. Van Gulijk, M. Makkee, J. A. Moulijn, 2001Molten Salts Are Promising Catalysts. How to Apply in Practice?Top. Catal. 16/17275278

  81. P. Ciambelli, G. Matarazzo, V. Palma, P. Russo, Merlone Borla E., Pidria M.F. (2007Reduction of soot pollution from automotive diesel engine by ceramic foam catalytic filterTop. Catal. 42-43: 287 EOF291 EOF

  82. E. Bruneel, J. Van Brabant, M. T. Le, I. Van Driessche, 2012Deposition of a Cu/Mo/Ce catalyst for diesel soot oxidation on a sintered metal fiber filter with a CeO2 anti corrosion coatingCatal Comm., in press.

  83. G. Walther, B. Klöden, T. Büttner, Weißgärber T., Kieback B., Böhm A., Naumann D., Saberi S., Timberg L. (2008A New Class of High Temperature and Corrosion Resistant Nickel-Based Open-Cell Foams. Adv. Eng. Mater. 10803811

  84. H.J Kwon, ., Y Kim, ., I Nam, ., S.M Jung, ., J Lee, . (2010) The Hydrothermal Stability of Paper-Like Ceramic Fiber and Conventional Honeycomb-Type Cordierite Substrates Washcoated with Cu-MFI and 2O5 TiO2 Catalysts for the Selective Reduction of NOx by NH3. Top. Catal. 53: 439 EOF446 EOF .

  85. N. Bhardwaj, V. Hoang, K. L. Nguyen, 2007Effect of refining on pulp surface charge accessible to polydadmac and FTIR characteristic bands of high yield kraft fibresBiores. Technol. 98962966

  86. H. Ichiura, T. Kitaoka, H. Tanaka, 2003Removal of indoor pollutants under UV irradiation by a composite TiO2-zeolite sheet prepared using a papermaking techniqueChemosphere507983

  87. H. Ichiura, T. Kitaoka, H. Tanaka, 2002Preparation of composite TiO2-zeolite sheets using a papermaking technique and their application to environmental improvement: Part I Removal of acetaldehyde with and without UV irradiation. J. Mater. Sci. 3729372941

  88. H. Koga, H. Ishihara, T. Kitaoka, A. Tomoda, R. Suzuki, H. Wariishi, 2010The Hydrothermal Stability of Paper-Like Ceramic Fiber and Conventional Honeycomb-Type Cordierite Substrates Washcoated with Cu-MFI and 2O5TiO2 Catalysts for the Selective Reduction of NOx by NH3. J. Mat. Sci. 45: 4151-4157.

  89. H. Koga, Y. Umemura, H. Ishihara, T. Kitaoka, A. Tomoda, R. Suzuki, H. Wariishi, 2009Paper-structured fiber composites impregnated with platinum nanoparticles synthesized on a carbon fiber matrix for catalytic reduction of nitrogen oxidesAppl. Catal. B: Environmental 90699704

  90. S. Fukahori, T. Kitaoka, A. Tomoda, R. Suzuki, H. Warrishi, 2006Methanol steam reforming over paper-like composites of Cu/ZnO catalyst and ceramic fiberAppl. Catal. A: General 300155161

  91. H. Koga, S. Fukahori, T. Kiyaoka, A. Tomoda, R. Suzuki, H. Wariishi, 2006Autothermal reforming of methanol using paper-like Cu/ZnO catalyst composites prepared by a papermaking techniqueAppl. Catal. A: General 309263269

  92. H. Koga, H. Ishihara, T. Kitaoka, A. Tomoda, R. Suzuki, H. Wariishi, 2010NOx reduction over paper-structured fiber composites impregnated with Pt/Al2O3 catalyst for exhaust gas purification. J. Mater. Sci. 4541514157

  93. H. Koga, S. Fukahori, T. Kitaoka, M. Nakamura, H. Wariishi, 2008Paper-structured catalyst with porous fiber-network microstructure for autothermal hydrogen productionChem. Eng. J. 139408415

  94. S. Fukahori, H. Koga, T. Kitaoka, A. Tomoda, R. Suzuki, H. Wariishi, 2006Hydrogen production from methanol using a SiC fiber-containing paper composite impregnated with Cu/ZnO catalystAppl. Catal. A: General 310138144

  95. K. Krishna, M. Makkee, 2006Soot oxidation over NOx storage catalysts: Activity and deactivationCatal. Today 1144856

  96. J. P. Cecchini, R. M. Serra, C. M. Barrientos, M. A. Ulla, M. V. Galván, V. G. Milt, 2011Ceramic papers containing Y zeolite for toluene removalMicropor. Mesopor. Mat. 1455158

  97. R. López-fonseca, I. Landa, U. Elizundia, M. A. Gutiérrez-ortiz, J. R. González-velasco, 2007A kinetic study of the combustion of porous synthetic sootChem. Eng. J. 1294149

  98. Y. N. H. Nhon, H. M. Magan, C. Petit, 2004Catalytic diesel particulate filter evaluation of parameters for laboratory studiesAppl. Catal. B: Environmental 49127133

  99. M. A. Peralta, M. S. Gross, B. S. Sánchez, C. A. Querini, 2009Catalytic combustion of diesel soot: Experimental design for laboratory testingChem. Eng. J. 152234241

  100. L. Lizarraga, S. Souentie, A. Boreave, S. C. George, D. Anna, B. Vernoux, 2011Effect of Diesel Oxidation Catalysts on the Diesel Particulate Filter Regeneration Process.Environ. Sci.Technol. 45: 10591-10597.

  101. W. Tanthapanichakoon, T. Charinpanitkul, 2012Suppression of fugitive dust emitted from stone quarrying process using wetted wire screenSep. Purif. Technol. 921720

  102. J. C. Caroca, F. Millo, D. Vezza, T. Vlachos, A. De Filippo, S. Bensaid, N. Russo, D. Fino, 2011Detailed Investigation on Soot Particle Size Distribution during DPF Regeneration, using Standard and Bio-DieselFuels. Ind. Eng. Chem. Res. 5026502658

  103. S. Bensaid, N. Russo, 2011Low temperature DPF regeneration by delafossite catalystsCatal. Today 176417423

  104. R.F Silva, ., E De Oliveira, ., de Sousa Filho P.C., Neri C.R., Serra O.A. (2011) Diesel/biodiesel soot oxidation with CeO2 and CeO2-ZrO2-modified cordierites: a facile way of accounting for their catalytic ability in fuel combustion processes. Quimica Nova, 34 759763 .