The potential energy surfaces for the chemical reactions of group 14 carbenes were studied using density functional theory (B3LYP/LANL2DZ + dp). Five group 14 carbene species containing a seven-member ring, 7-Rea-E, where E = C, Si, Ge, Sn and Pb, were chosen as model reactants for this work. Three types of chemical reactions (water addition, imine cycloaddition and dimerization) were used to study the reactivity of these 7-Rea-E molecules. Present theoretical investigations suggest that the relative reactivity of carbenes decreases in the order: 7-Rea-C > 7-Rea-Si > 7-Rea-Ge > 7-Rea-Sn > 7-Rea-Pb. That is, the heavier the group 14 atom (E), the more stable its corresponding 7-Rea-E compound to chemical reaction. This study’s theoretical findings suggest that all of the seven-member 7-Rea-E should be readily synthesized and isolated at room temperature, since they are quite inert to chemical reaction, except for reaction with moisture. Furthermore, the group 14 7-Rea-E singlet-triplet energy splitting, as described in the configuration-mixing model of Pross and Shaik, can be used as a diagnostic tool to predict their reactivity. The results obtained allow a number of predictions to be made.
Part of the book: Chemical Reactions in Inorganic Chemistry