Quality of coke oven gas before and after cleaning
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\r\n\t[3] M. Kauranen, A. V. Zayats. Nonlinear Plasmonics. Nature Photonics, vol. 6, 2012, pp. 737-748.
\r\n\t[4] P. Dombi, Z. Pápa, J. Vogelsang et al. Strong-field nano-optics. Reviews of Modern Physics, vol. 92, 2020, pp. 025003-1 – 025003-66.
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Coke is a necessary component for the production of iron and steel. Nearly 65 % of the worldwide steel production takes place via so-called pig iron (hot-metal route), which is produced in the blast furnace from iron ore by use of coke.
The importance of coke as raw material for the steel production has been approved during the last years while the worldwide need for steel has strongly increased. Since 1990 the steel production has nearly doubled and reached 1.417 mio. t in 2010 (Worldsteel, 2012).Coke production from hard coals was increased by 70 % in the same period resulting in approx. 593 mio. t in 2010 (Re-Net, 2011)(Fig. 1).
Worldwide crude steel and coke production (Re-Net, 2011, Worldsteel, 2012)
One can assume that this trend will continue in the next future, too. That means, that similar than in the recent years, new coke making capacities will be built and older and smaller plants will be replaced by high performance coke plants, in the future. This will be the case in China, India, Southeast-Asia and South America in particular. Already today approx. 65 % of the coke worldwide is produced in China.
There is a lack of an official statistic from which one can derive the total number of coking plants worldwide. However, it is to assume that this will be in the range of 500 plants, not including so-called primitive ovens, that means smaller coking plants without any technical equipment for operation.
Three principles will still characterize prospective projects for new coking plants: improvement of economics of coke production as well as optimization of the coke quality. A third principle has prevailed during the last four decades because of more stringent becoming legislation: reduction of the impact of the coking process on the environmental, and on the ambient air in particular. Due to the legal demands, coke plant operators were obliged to improve techniques for emissions control, to revamp batteries, or, in some cases, to shut down a battery and built a new one if the new standards could not be fulfilled under economic and technical reasons.
Progress made in emission control at coking plants can be read from an improvement of air quality in the Rhine-Ruhr area in Germany, which is the center of the German cokemaking industry till today (LANUV, 2012). Besides the shrinking importance of coal use in homefiring the reduction of coke plants´emissions is the reason for the continuous decline of Benzo(a)pyrene (BaP) as a highly carcinogenic aromatic hydrocarbon in the ambient air of this area during the last 20 years(Fig. 2).
Benzo(a)pyrene (BaP) in ambient air of the Rhine-Ruhr area (LANUV, 2012)
Benzo(a)pyrene playsan important role with regard to the environmental assessment of the coking process. Very often it is used as a guide substance for polycyclic aromatic hydrocarbons (PAH) which can be emitted from leaks at the coking chambers. In order to reduce these fugitive emissions, measuring methods are necessary by which the made progress can be quantified. Reliable statements on the amount of emitted BaP are indispensable, too, for making a forecast on the BaP burden in ambient air of the surrounding.
The bulk of the worldwide coke production in 2011 was effected in conventional coking plants including a recovery of gas and coal chemicals. These plants are very often called by-product coking plants, too. Approx. 5 % of the total coke production originate from the non-recovery technology, which does not recover gas and coal chemicals. Both technologies display a quasi continuous process with charge-wise coke production in several ovens connected in a battery.
A scheme of the total process of conventional coking is shown on Fig. 3. The process can be devided in the two steps: battery operation (left side of Fig. 3), and coke oven gas (COG) cleaning and by-product plant, respectively (right side of Fig. 3).
Scheme of conventional cokemaking
By-product coking plants are comprised of single oven chambers, being 12 to 20 m long, 3 to 8 m tall, and 0.4 to 0.6 m wide, in which the input coal is heated up indirectly. Several chambers are grouped to form one battery (multi-chamber-system; Fig. 4). A single battery may consist of up to 85 ovens. The front-end sides of the individual ovens are sealed with doors. The ovens are charged through charging holes in the oven top. As an alternative, the oven can also be charged from the side via one opened door after the input coal was stamped before in order to build a formed cake (stamp charging). Subsequently to a 15 to 25 hours coking time the doors are opened and the built coke is pushed by the coke pusher machine out of the oven into a coke quench car.Then the coke is quenched in a dry or wet quenching facility. The oven chamber is sealedagain, initiating a new carbonization cycle. The gas evolving on coal carbonization leaves the oven chamber through a standpipe (offtake) and is passed on via a common gas collecting main to the gas treatment facilities and to the by-product recovery plant. The ovens are run at a slightly positive pressure of 10 to 15 mm water column.
View on the doors of a coke oven battery of the coking plant Zdzieszowice, Poland (left side); schematic drawing of the machines for battery operation (right side)
As outlined in Fig. 7, the oven chambers are heated through heating flues, located between the chambers, in which cleaned coke oven gas or blast furnace gas is combusted. The temperature in the heating flues lies between 1150 and 1350 °C usually.
Battery operation, i.e. charging and pushing is carried out by large machines (Fig. 5) which very often are running automatically.
Pusher machine of the coke plant Huckingen (left) and charging car of the former coking plant Kaiserstuhl III (right)
Coke oven gas (COG) as built during the coking process is unsuited for use as underfireing gas for the coke oven batteries and for other applications, because of technical, and of environmental related reasons in particular. The necessary cleaning is made in the so-called by-product plant which comprises a complex chemical plant. For a coking plant with an annual coke production of 1 mio. t, the design capacity for the by-product plant is about 61,000 Nm³ COG/h.
Scheme for a modern by-product plant
A general simplified process diagram is shown in Fig. 6.Coke oven gas leaving the battery ovens has a temperature of 800 to 1000 °C, and just before entering the collecting main it is sprayed with flushing liquor (ammonia water) coming from tar separation. After spraying the gas comes down to temperatures in the range of 80 °C. At this temperature most of the raw tar is condensed, therefore a separation into gas and liquid phase is possible in a downcomer. The liquid phase flows from here to the tar separation unit to separate water and crude tar; crude tar is one by-product.
The raw gas is directed to the primary gas cooler were it is cooled down to 21 °Cby indirect cooling. The next step is the electrostatic tar precipitators, where the residual amounts of tar fog are almost completely removed, down to maximum 20 mg/Nm³. After this step COG is sucked off by exhausters keeping the necessary pressure for exhausting the gas from battery and is led to the subsequentgas treatment. There exist two techniques for H2S removal from COG, in principle (see section 5.2). In Fig. 6 only the ASK process (Ammonium-Sulphur cycle process, ASK), combined with a subsequent Claus plant for sulphur production, as a high value by-product, is shown as the most common desulphurization process in Europe. In section 5.2 this technique is described more in detail.
The last optional gas treatment step is BTX and naphthaleneremoval in a scrubber using washing oil. The crude BTX is a further by-product.
Most of the water used in the by-product plant is recycled in the process. Only a small amount of waste water, which mainly represents the water content of the input coal,is produced as effluent of the ammonia still and has to be treated in biological waster water treatment plant.
Typical figuresfor the quality of coke oven gas befor and after gas cleaning are shown on Table 1. The Figures can be varied due to the coal quality and the coking process itself.
crude coke oven gas | cleaned coke oven gas | unit | |
Tar | 60- 110 | 0.1 | g/m3 |
BTX | 28 – 35 | < 5 | g/m3 |
NH3 | 7- 9 | < 0.1 | g/m3 |
H2S | 4 – 8 | < 0.5 | g/m3 |
Quality of coke oven gas before and after cleaning
The most essential features by which the non-recovery technology differs from the conventional cokemaking technology with by-product recovery are given in Fig. 7. In contrast to conventional coking by which the coke is heated indirectly by combustion of gas within the heating flues outside the oven chamber, exclusively, during non-recovery coking the necessary heat is transferred both directly and indirectly into the oven chamber as described in the following.
Principle drawings of conventional and non-recovery cokemaking (Hein, 2002).
The basis for modern non-recovery plants is the so-called Jewell-Thomson oven, several ovens of which are grouped together to form one battery (Fig. 8).The ovens are characterized by a tunnel-like shape with a rectangular ground area and an arched top. The dimensions of the chambers of modern plants run up to 14 x 3.6 x 2.8 m (L x W x H). Coal charging (up to 50 t) of the ovens is accomplished through the open pusher side door. Very often the coal is stamped before, and then the coal is charged into the hot oven chamber. Typical charging levels lie at 1000 mm.The carbonization process is started by the heat still existing from the preceding carbonization cycle. The released coke oven gas is partly burnt by addition of ambient air through the doors and passed through so-called down comers into the heating flues situated in the oven sole. By way of a further supply of air, the complete combustion of raw gas is effected here at temperatures between 1200 and 1400 °C. With plants according the state of the art, the hot waste gas is utilized to generate energy, and subsequently is subjected to desulphurization before exited into the atmosphere.The coking time in Jewell-Thomson ovens amounts to approx. 48 hours. After that time, the coke is pushed out and quenched in wet mode, normally.
Schematic drawing of the Jewell-Thomson oven (Hein, 2002) (left) and view on the ovens of the heat-recovery cokung plant of the Shanxi Xishan Coal Gasification Co. Ltd., Gujiao, China (right)
Due to the negative pressure, under which the coking process is running, emissions from leaks at the doors are avoided in principle. Dust emissions occurring during coke pushing are exhausted via a coke side shed. Very often suction devices are installed at the pusher side, too, in order to capture emissions caused during charging.
As the techniques for emission control during charging, pushing and quenching are similar to those applied at conventional coking, and fugitive emissions at the ovens are excluded by principle reasons, it is resigned to address emission related issues regarding non-recovery cokemaking in a separate section.
Typical emission sources with regard to battery operation are shown on Fig. 9. These are directed and fugitive emission sources. Fugitive emissions mainly occur from leaks at the closed openings of the coke oven batteries (doors, charging hole lids and offtakes) or are caused by non-captured emissions during coke pushing and coal charging. These emissions can not be avoided completely, also when considering closure facilies according state of the art in technology and being under best state of maintenance, and contain dust, polycyclic aromatic hydrocarbon compounds (PAH) and Benzene as most relevant components. Carcinogenic Benzo(a)pyrene is very often used as guide substance for the group of PAHs.
Schematic drawing of typical emission sources at a conventional coking plant
Emissions from directed sources are created at the stack for the off-gas from battery underfiring. The most important compounds which are emitted here are dust, NOx, SOx and CO2. Dust is emitted also by the offgas of the pushing emission control as well as during coke quenching. Emissions causedatpreparation of charging coals, and at classification of coke, respectively, are not addressed here because well-proven dust removal systems are available to cope with them.
Emissions from the by-product plant are bearing secondary importance in contrast to emission from battery operation. This is valid for emissions from open tanks, leaks in the piping system and at flanges, pressure valves, pumps, etc., as well as for the off-gas from the technical facilities for sulphur-removal (sulphuric acid plant, Claus plant). On the other hand, more relevance is to be attached to the efficiency of the devices for H2S removal from the coke oven gas (see section 5.2). Remaining H2S will influence the amount of SO2 in the off-gas at the stack of the battery in case of using cleaned coke oven gas for battery heating.
Starting, it should be emphasized that legal rules given by the European Union (EU) have a significant impact on the national legislations of the member states. While regulations of the EU becomes immediately enforceable as law in all member states, directives are only binding for member states with regard to the achievable target, while they leave it up to the member states to decide on the form and means needed to realize the commonly set targets within the framework of their national legal system.
In Germany, the most important legal rule with reagard to industrial emission control represents the Technical Instruction for Air Quality Control – Technische Anleitung zur Reinhaltung der Luft – the so-called TA Luft. The first issue of TA Luft was enacted in 1964 and was amended for several times in the following years. The TA Luftis the most essential guide for implementation the demands of the GermanFederal Immission Control Act - Bundes-Immissionsschutzgesetzes (BImSchG) – which was released in 1974.
The Federal Immission Control Act, amongst others, is based upon the two fundamental principles of "risk defense" and "precaution". The precautionary principle is expressed in the approval of new plants and flows into the demand for compliance with what is called the state of the art in technology in the construction and operation of industrial plants with special regard to environmental control.
The state of the art is basically stipulated in the TA Luft which at the same time generally prescribes ambient air quality standards that must not be exceeded in the vicinity of a new plant after its commissioning. To this effect it is required to calculate the additional burden of the pollutants, which are to be expected upon commissioning of the planned plant, by dispersion calculations (see also section 8.2). Furthermore for precaution, the TA Luft prescribes emission limit standards, especially for directed sources, which shall be examined for compliance within regular intervals.
In view of the “risk defense” principle of theFederal Imission Control Actits 22nd Decree stipulates air quality standards for various hazardous substances, the compliance of which shall be achieved, for example, by implementing so-called air pollution control plans. This area-related rule concerns all plants, that means also those for which a permission has already been granted, and may necessitate an obligation for retrofitting the plant.
The TA Luftamendments which came into force in 1986 gained special importance for the coking plants which were built in the 1980thin Germany. Although the permits for the new constructions of the coke plants Prosper, Huckingen, Salzgitter and Dillingen are dated before the enactment of TA Luft 1986, its demands have to be fulfilled by the new plants to the greatest possible extent.
Compliance with the TA Luft 1986 without any extension, that means including the demand for operation of a coke dry quenching unit, was necessary for the new construction of the coke plant Kaiserstuhl III which was operated in Dortmund between 1992 and 2000.
Due to the progresses reached in emission control in Germany since 1986, an emendment of the TA Luft came into force in the year 2002 (TA Luft, 2002). The permits of the coke plants Schwelgern and of battery no.3 of the Saar central coking plant (Dillingen) were affected from this amendment, which disclaims on dry quenching as the onlymode for coke cooling. More informations on the coking plants mentioned before will be given in section 6. The most important features of the current TA Luft with regard to emission control on coking plants will be described in the following sections.
As a measure for precaution the TA Luft sets standards for the technical equipment for emission control on industrial plants, and specifies how to operate the plant in a most environment-friendly way. Table 2 contains the most important techniques and work practice standards to apply on the coke oven batteries with regard to the TA Luft-amendments of the year 2002 (TA-Luft, 2002). Most of the standards of the GermanTA Luft were adopted by the BREF-document of the European Union (EU, 2012) nearly complete. Most of them are described in section5 more in detail.
techniques | |
- | gravity charging: emission free charging by transfer of charging gases to the main and into the neighbour oven, as an option |
- | stamp charging: combustion of not transferred gases |
- | doors with technical gas-proof sealings |
- | water-sealed lids at offtakes |
- | single chamber pressure control should be applied |
- | coke side emission control including a mobile hood and a stationary control device |
- | coke quenching by dry or wet quenching mode |
work practice standards | |
- | additional sealing of lids of charging holes |
- | regulary, and preferential automatic, cleaning of closure facilities |
Techniques for emission control and work practice standards as demanded by (TA Luft, 2002)
In order to reduce atmospheric emissions from industrial plants as far as possible TA Luft sets limit values which have to be checked regularly. Table 3 contains limit values for emissions at the outlets of directed sources of coking plants. In contrast to the US Clean Air Act (section 4.3) TA Luft contains no legal demands for fugitive emissions by setting standards for the allowed number of visible emissions.
process | emission | limit value | |
stamp charging | dust: | 10 | mg/Nm3 |
battery underfiring | dust | 10 | mg/Nm3 |
NOx | 0.50 | g/Nm3 | |
sulfur* | 0.8 | g/Nm3 | |
pushing | dust | 5 | mg/Nm3 |
or | dust | 5 | g/tcoke |
quenching | |||
dry | dust | 15 | mg/Nm3 |
wet (new plants) | dust | 10 | g/tcoke |
wet (existing plants) | dust | 25 | g/tcoke |
Emission limit values for battery operation according (TA Luft, 2002); *: sulfur content of the heating gas before combustion
Special emission limits are set for the off-gas of a sulfuricacid-plant and of a Claus-plant for sulfur recovery, if exist as part of the by-product plant.
In the European Union, there are in principle two directives that influence coke plant operation:
„IED Directive“ (EU, 2010) on industrial emissions (integrated pollution prevention and control)
„Air Quality Directive“ (EU, 2008)
As mentioned in section 4.1.1.Directives of the EU are only binding for member states with regard to the target to be achieved; they have to be transformed to the national legislation of the member state.
The IED-Directive addresses the conditions for plant operation and sets standards for emission control. This directive stipulates that the "best available technique BAT" which has to be applied is to be described in a so-called BREF document („Best available technique Reference” document) for certain industrial plants. For coking plants, the set-up of such a BREF document was finalized in the year 2000. An amendment was promulgated in 2012 (EU, 2012), and it assigns “Associated Emission Lewels AEL” to the BATs. BAT-AELs give ranges for emission lewels which can be achieved by application of emission control techniquesaccording BAT. AELs which are relevant for cokemaking operation are described on Table 4. A more detailed description of the BATs is given in section 5.
The Air Quality Directive (EU, 2008) and its so-called 4. Daughter Directive (EU, 2004) describe the targets and principles of the air quality policy pursued by the European Union. Ambient air standards which are important for cokemaking operation are given on Table 5.
process | emission | AEL/BAT | unit of measurement | remark |
charging | dust | <5 or <50 | g/tcoke or mg/Nm3 | |
visible emission | < 30 | sec | duration of visible emissions per charge | |
offgas from battery underfiring | ||||
SOx | <200 to 500 (as SO2) | mg/Nm3 | depending on the type of gas for underfiring | |
NOx | <350 to 500 (as NO2) | mg/Nm3 | for new plants | |
NOx | 500 to 650 (as NO2) | mg/Nm3 | for existing plants which are equipped by primary measures for NOx reduction | |
dust | < 1 to 20 | mg/Nm3 | ||
pushing | dust | < 10 to < 20 | mg/Nm3 | depending on filter type |
quenching | ||||
wet | dust | < 25 | g/tcoke | existing plants |
wet | dust | < 10 | g/tcoke | new plants |
dry | dust | 20 | mg/Nm3 | |
battery operation | ||||
visible emission | < 5 to 10 | % | from leaks at doors | |
adequate oven pressure regulation | ||||
work practice standards | ||||
desulphurization of COG | ||||
H2S | < 300 to 1000 | mg/Nm3 | applying absorption processes | |
H2S | < 10 | mg/Nm3 | applying wet oxidation processes |
BAT associated emission lewels (AEL) as described in the BREF document (EU, 2012)
emission | Limit value | remark | |
Benzene | 5 | µg/m3 | |
Particulate Matter PM10 | 40 | µg/m3 | |
50 | µg/m3 | daily average for max. 35 days/a | |
Particulate Matter PM2.5 | 25 | µg/m3 | from 2015 |
Benzo(a)pyrene * | 1 | ng/m3 | from 2012 |
Ambient air quality standards (limit values) of the EU (EU, 2008) as an annual averagewith reference to coking plant operation; *: (EU, 2004)
The Clean Air Act (CAA) of the United States of America was passed in the year 1990. This act of law describes standards for air quality, which exert a very strong influence on the requirements which have to be fulfilled for obtaining the permit to run an industrial plant. The so-called Residual Risk Standard (RRS) should provide an ample margin of safety to protect public health and to reduce the risk to cause cancer to a minimum.
In case of coking plants, amonst others, standards are set for the allowed number of visible emissions (leaking rates as %) from battery operation to reach this goal, as described by the US EPA (US-EPA, 1993a, 2005). For the construction of new coke plants at the green site, the CAA calls for zero visible emissions from battery operation. That means in practise, that in the USA, the non-cecovery technology is the only one, which is allowed by the USEPA for new green field plants because of the prevailing negative pressure and consequently of the prevention of leaks at the ovens.
For existing conventional coking plants the Residual Risk Standard, which is still open, has to be reached from 2020. It is to assume that the relevant legal demands will be very ambitious. During the recent 20 years the US coke oven plant operators had the chance to approach this target on different tracks, which specify different compliance timetables (Fig. 10) (Ailor, 2003; US-EPA, 1993a). While the MACT-track (Maximum Achievable Control Technology) allows less stringent standards for a long period to fulfill the highest lewel of emission standards already in 2005, operators who have chosen the LAER-track (Lowest Achievable Emissions Rate) got an extension to reach this standard only in the year 2010.
The relevant standards for the allowed visible emissions are shown on Table 6. Estimates of visible emissions should be based on the results of daily visible emission inspections using EPA Method 303 (US-EPA, 1993b).
Timetable to comply with the legal demands of the US Clean Air Act
source | MACT | LAER | remark |
from 01.01.2003 | from 01.01.2010 | ||
doors | 5.5 % | 4 % | ≥ 6 m |
doors | 5.0 % | 4 % | foundry coke |
doors | 5.0 % | 3.3 % | < 6 m |
lids | 0.6 % | 0.4 % | all plants |
offtakes | 3.0 % | 2.5 % | all plants |
charging secs per charge | 12 | 12 | all plants |
Standards for visible emissions according MACT- and LAER-track respectively for conventional coking plants
It is easily to understand that operators of older plants would have preferentially followed the MACT track as their coking plants will be no longer in operation in the year 2010, probably. After all there were only 5 conventional batteries which have to comply with emission standards equivalent to the 2010-LAER-standard in 2005.On the other hand, operators of new plants, which were equipped with modern techniques for emission control on the date of their track choice, or for which a modernisation was planned, would have preferred the LAER-track supposably. Based on informations given in the year 2003 (Ailor, 2003) the LAER-track was chosen for 40 conventional batteries.
Emissions from pushing, quenching, and combustion stacks are adressed in (US-EPA, 2003a). The most relevant figures of this rule are given on Table 7. The local authority can make an order on more stringend limits than given on Table 7 on special reason, and can setemission standards for other emitted compounds than given on Table 7 with regard to the allowed annual mass flow, aditionally.
process | emission | limit value | unit of measurement | remark |
pushing | ||||
fugitive (not captured) emissions | opacity* | < 30/35 | % | depending on oven hight * |
outlet of dedusting device | dust | 0.01 – 0.04 (5 – 20 ) | lb/tshort coke(g/t coke), | depending on type of control device |
battery underfiring | ||||
stack for offgas | opacity* | < 15/20 % | % | depending on coking time |
quenching | ||||
outlet of quench tower | dissolved solids | < 1.1 | mg/l | quench water |
Emission standards for coking plants according (US-EPA, 2003a); *: determination of opacity is made by Method 9 given by US EPA (US-EPA, 1996)
German and European legal regulations set no standards for opacity. Therefore, only the 0.02 lb/tshort (10 g/t) limit for pushing emissions from the stack when applying a moveable hood with a stationary control device can be compared with the relevant figure of 5 g/t coke set by GermanTA Luft for this technique.
In addition to the limit values as described before, the US environmental legislation sets work practice standards. These standards, for example, describe techniques which have to apply with regard to emission control and to emission monitoring, or how to operate the coking plant in a most environmental friendly way.
The philosophy of EPA´s rules for visible emissions caused from coke oven operation is based on a chain of causalities between:
number of visible emissions, and
mass flow of the emitted hazardous compound, and
concentration of the emitted hazardous compoundin ambient air, and
ambient air quality and cancer risk
due to the usual practice when rating the health risk caused by air pollutants by dose/effect relations. This means, that, amongst others, there must be a quantitative correlation between the set standards for visible emissions and the emission mass flow (mass per time) of the hazardous compound.
The latter can be calculated on base of the frequency of the visible emissions (leaking rate) and of the source strength (emission mass flow) of the visible emission (US-EPA, 2008a, 2008b). Typical source strengths given as kg BSO/h/leak as derived from from page 4-30 of (US-EPA, 2008b) are listed on Table 8. BSO means the so-called Benzene soluble (BSO) portion of the emission. By using a conversion factor for BaP/BSO of 0,00836 (US-EPA, 2008b) the relevant BaP emissions can be calculated. They are given on Table 8 too.
type of leak | kg BSO/h/leak | mg BaP/h/leak |
leaks observed according EPA 303 from the yard | 0.019 | 159 |
leaks observed from the bench* | 0.011 | 92 |
without visible emissions | 0.002 | 17 |
Emission mass flows of door leaks as given by US EPA (US-EPA, 2008b); *: for calculations according equ. 1 smaller leaks which cannot be observed from the yard but only from the bench are additionally taken into account; US EPA estimates the leaking rate of these emissions to 6 % as an average.
Applying a 4 % leaking rate (according EPA method 303) at the doors (post-NESHAP control standard according (US-EPA, 2008b)) the total BSO emissions of a model battery with 62 ovens (124 doors) can be calculatet as follows:
[(124 x 0.04) method 303 leaks x 0.019 kg/h/leak +
(124 x 0.06) bench leaks x 0.011 kg BSO/h/leak +
(124 x 0.90) no visible leaks x 0.002 kg/h/leak)] x 8760 h/a = 3 498 kg BSO/a. (1)
Considering a coke plant with a coal input of 492 000 t/a (344 000 t coke/a) a specific emission factor of 0.0071 kg BSO/t(coal) results for door emissions. By using a conversion factor for BaP/BSO of 0.00836 (US-EPA, 2008b) the specific BaP emissions from the doors amounts to 59.4 mg/t coal and 84.8 mg BaP/tcoke, resectively.By comparable evolutions emission factors for leaks at lids and offtakes as well as for charging can be received (Table 9; compare with Table 4-11 of (US-EPA, 2008b)). It is obvious that the doors are the dominant emission source out of all leaks at the battery.
US-EPA standard | BSO | |||
charging | doors | lids | offtakes | |
kg/tcoal | kg/tcoal | kg/tcoal | kg/tcoal | |
POST-NESHAP | 0.00025 | 0.0071 | 0.000044 | 0.00015 |
BaP | ||||
charging | doors | lids | offtakes | |
mg/tcoal | mg/tcoal | mg/tcoal | mg/tcoal | |
POST-NESHAP | 2.09 | 59.36 | 0.37 | 1.25 |
BaP | ||||
charging | doors | lids | offtakes | |
mg/tcoke | mg/tcoke | mg/tcoke | mg/tcoke | |
POST-NESHAP | 2.99 | 84.79 | 0.53 | 1.79 |
Specific emissions at doors according (US-EPA, 2008b)
Emission factors as given in (US-EPA, 2008b) are based on measurements carried out before the year 1980 on coking plants, which could not meet the emissions control standards of current plants. Thereby the coke-side dedusting facilities were used for capturing the emissions from the doors. The US EPA by itself designates the results of these measurements as highly uncertain.
Environmental legislations for industrial plants, like the German TA Luft (TA-Luft, 2002) or IEDof the EU (EU, 2010), demand very oftenfor application of the so-called Best Available Techniques (BAT) for emission control according the state of the art in technology, (section4.1/4.2). The following section will give a brief description of the most important techniques. Additional informations on the emission levels which can be achieved by the relevant technique are given on Table 4 (section 4.2).
BAT is an emission free charging by transfer of charging gases to the collecting main and into the neighbour oven, as an option (Fig. 11)
Principles of emission free charging of coke ovens
A reduction of total fugitive emissions from battery operation can be achieved by lessening the sealing surfaces as well as the number of oven cycles. Naturally, such measures can be achieved only when building a new battery equipped with larger chambers as they were built by 7 to 8 meter ovens in the 1980th in Germany (section 6). Larger oven chambers provide less openings per t of produced coke due a reduction of the specific sealing surface. Fig. 12 shows (top side) the reduction of the number of closure facilities (openings) which was reached by a replacement of two smaller and older plants by the new coke plant Kaiserstuhl III, while the total capacity of both variants kept constant at 2 million tonnes coke per year. The drastic reduction of fugutive emissions of Benzo(a)pyrene and Benzene,caused by less openings but also by improved techniques, can be read from Fig. 12 (bottom side).
Emission reduction by lessening the sealing surface; top side: reduction of openings; bottom side: reduction of fugitive emissions by Benzo(a)pyrene and Benzene respectively (Hein, 2010)
Construction of larger oven chambers do not favour the intention of environmental control only, but also the economics of cokemaking. Desing data of the modern high capacity batteries as running in Germany today, can be received from Table 10 in section 6.
The development of chamber heights during the last 100 years is shown very arrestingly in Fig. 13.
Development of typical heights of coke oven chambers (Hein, 2009)
In order to improve the control of fugitive emissions from leaks at the battery, optimized closure facilities at doors, charging hole and offtakes have to be applied, and a good maintenance of them is demanded. BAT are flexible doorswith springloaded sealings (Fig. 14, left side), for batteries higher than 6 m especially.An additional improvement is attainable if the pressure gradient at the sealing that constitutes the driving force for emissions could be lowered. This was done by the coke oven builders by means of gas channels in the door through which the escaping gas can flow into the direction of the gas space without greater flow resistance. All modern coke oven doors meanwhile have such gas channels as can be seen from Fig.14, right side).
At the offtakes water sealed lids are BAT in order to reduce emissions.
Modern door systems; left side: flexible doors (Krupp-Koppers, n.d.); right side: principle drawings of gas channels behind the door (Arendt et al., 2009)
A reduction of fugitive emissions can be achieved by measures to regulate the chamber pressure within the coke ovens as function of progress in carbonization. BAT, e.g. is the PROven system (Pressure Regulated Oven), which was invented by DMT (Huhn, 1995). PROven regulates the pressure within each oven chamber at a constant and slight positive pressure during coking in order to eliminate fugitive emissions as much as possible. Fig. 15 shows on the left side principles of this system, and on the right side the reduction of PAH emissions by use of PROven in contrast to a non pressure regulated oven chamber (100 % PAH) (Spitz, 2005). In the year 2011 the PROven system was installed at 15 coking plants worldwide with more than 2100 ovens (Kaiser, 2011) including the new coking plant Schwelgern.
An alternative system has been developed by Paul Wurth and is called SOPRECO (Single Oven Pressure Control System). In 2011 the SOPRECO system was installed at the coking plant Dillingen, Germany, in 50 ovens, a second battery with 50 ovens is under construction (Faust, 2010).
Emissions from battery underfiring are limited by application of the following techniques: improved desulphurization of the used coke oven gas in order to a reach a remaining sulphur content of less than < 0.8 g /Nm3 and by special heating relevant technical measures in order to comply with a NOx standard of 500 mg/Nm3. While the desulphurization is achieved by absorption or by wet oxidation of H2S (see section5.2.1.), the NOx reduction is reached by waste gas recirculation and stage wise heating, in particular (Fig. 16). The latter was necessary anyway because of the taller becoming chamber heights.
Left side: Principle of the ROven-system; right side: achievable emission reduction for PAH compounds
Principle scheme of stage wise heating
In order to minimize emissions during coke pushing, an installation of a dedusting system is required, disposing of a hood, a suction device and of a filter system. The so-called “Bandschleifenwagen” (Fig. 17) with a subsequent stationary dedusting achieved acceptance.
Drawing of the “Bandschleifenwagen” as part of the coke side dedusting device (Stoppa, 2003)
The efficiency of a modern coke side dedusting system is illustrated from Fig. 18.
Coke pushing without (left side) and with coke side dedusting (Coking Plant Prosper, Germany - right side)
BATs are wet quenching as well as dry quenching.
Wet quenching
The hot coke is treated by water spraying under the quench towerto cool it down. The caused dust is hindered to leave the tower by special baffle constructions which are installed in the tower. The so-called Coke Stabilisation Quenching (CSQ) represents an advanced quenching technology comprising a combination of spray quenching and submerging in water. The CSQ tower contains a two set of baffles and comprises a hight of 70 m, in contrast to approx. 40 m which was the maximum hight of conventional quenching towers up to now (Fig. 19).
CSQ quench tower of the coking plant Schwelgern in contrast to the quench tower of the coking plant Huckingen (top side); bottom side: baffles (Nathaus, n.d.) for dust emission control before installation in a quench tower
Dry quenching
During dry quenching the hot coke is cooled down in a closed cooling chamber by use of an inert gas which is circulated and cooled down thereby within a heat exchanger. The produced steam can be used for electricity production. A scheme of a dry quenching plant is shown in Fig. 20.
Schema of the dry quenching plantof the former coking plant Kaiserstuhl III (Stoppa et al., 1999)
Dry quenching is extended for application in countries, in which a water operated wet quenching is not possible because of meteorological reason, or which are characterized by water shortage. On the other hand, the use of dry quenching techniques is advantageously to operate in countries with high prizes for electricity.
Because of its hydrogen sulphide (H2S) content (up to 8 g/Nm3) unpurified coke oven gas (COG) is unsuited for use in many industrial applications. Typical desulphurisation processes according BAT to clean COG are (Sowa et al., 2011):
absorption/stripping processes with subsequent conversion to sulphur containing compounds,
wet oxidation processes with subsequent production of sulphur.
In Europe, the most commonly applied process is the absorptive process using a so-called ASK process (Ammonia-Sulphur cycle process, ASK; see Fig. 6 in section 2.2., too). It is a combination of H2S and NH3 removal. A first scrubber removes H2S, using deacidified water providing from the distillation. A second scrubber is in combination with the first one for the removal of NH3. The washer fluid which is loaded with H2S and NH3, respectively, is sent to a distillation unit (stripping/deacidification). This unit removes the adsorbed gases from the enriched solution; the water is mostly recirculated to the gas scrubbing. The H2S/NH3-vapours are led to the desulphurization unit, which is mostly a catalytic ammonia cracking combined with a sulphur recovery plant (Claus plant). A photo of a modern Claus plant can be seen in Fig. 21. Other options for desulphurization are the production of supheric acid or ammonia suphate. In all cases the produced chemicals are further by-products.
View on a modern Claus plant
The second absorptive process variant is the Vacuum Carbonate process commonly operated with potassium carbonate which has some tradition at West European and Asian coke plants.
The most commonly applied wet oxidative process (outside Europe) is the Stretford process. Wet oxidative processes possess a higher efficiency for H2S removal than adsorption processes (see Table 4). However, they need the addition of specific chemicals, likevanadium compounds, quinone and hydroquinone compounds as catalysts, the wastes of which have to be discharged. Usually this waste water is treated separately owing to the presence of compounds that have a detrimental effect on the biological wastewater treatment plant.
In modern by-product plants fugitive gaseous emissions are minimized by gas-tight operation of the gas treatment plant. The measures are, minimize the number of flanges, using of gas-tight flanges, or closed venting system for tanks and equipment containing aromatic hydrocarbons.By use of pumps and piping suitable to prevent leakages, a release of any effluent to the environment can be avoided.
BAT is a wastewater treatment by using efficient tar and PAH removal, using efficient ammonia stripping and biological waste water treatment with integrated nitrification and denitrificationto fulfill the common local regulations for discharge water quality. Limiting values are existing for free ammonia, NH3-N, BOD, COD, cyanides, hydrocarbons and phenol.
Today five modern coking plants comprising with high capacity batteries are in operation in Germany. These plants, the fotos of which are given on Figures 22 and 23, fulfill the highest standards for emission control techniques with regard to the state of the art. They are equipped with modern wet quenching systemsin order to comply with the legal demands of the actual TA Luft (TA-Luft, 2002) while the former coking plants August Thyssen and Kaiserstuhl III have been provided with modern dry quenching facilities.
In 2011 battery no. 1 of the coking plant Dillingen is under construction; this is a replacement of an old battery. At Huckingen a second battery is under construction as an extension.
Coking plants currently in operation in Germany which were build in the 1980th, including date of commissioning
Coking plants currently in operation in Germany which were commissioned under the influence of the TA Luft 2002, including date of commissioning
The most essential design data of the five coke plants operating today are summarized on Table 10.
Design data of the five German coke plants currently in operation (Hein, 2009)
The chamber height of 8.4 m of the new Schwelgern plant marked a new record for coke constructions. Now, the coke plant with the tallest chamber heights and the highest chamber volume worldwide is operating at the coking plant Schwelgern in Duisburg, Germany. The coking plant Saar in Dillingen is operated as stamp charging plant, and with 6.25 m hight the tallest for this technique.
The total production of the five plants was 8.15 mio. t coke in 2010.This is a sharp decrease when looking back to the year 1957 when approx. 50 mio. t coke were produced (Fig. 24).
The main cause for this change in Germany was the decline of coke sale for home firing and other applications than for pig iron making. On the other hand the coke need of the German iron and steel industry has fallen due to the reduction of the specific coke demand for the blast furnace as well as to the buying of coke from abroad, while the total hot metal production kept nearly constant since this time. The necessary adjustments in capacity were carried out in such way, that preferable older plants were shut down, which could not meet
Annual coke production in Germany since the year 1950 (Kohlenstatistik, 2012)
the more stringent environmental standards, and which were not able to reach the economics which were typical for this time.This change has faced the mining industry, in particular, as this branche was the owner of nearly 75 % of the coking plants in Germany 50 years ago.
Due to the former dominance of the mining coking plants for the coke production the most sustainable impetus for new developments in cokemaking technology came from the German mining industry till the early 1990th years. Thereby, in particular, the basics were set for the construction of high capacity batteries as realized in the five coking plants running today, by research and development carried out in technical and semi-technical testing facilities for coking trials owned by the mining industry. The research in cokemaking technologies was centralized at the Bergbau-Forschung in Essen, the nucleus of the today´s DMT GmbH & Co. KG.
Progress made in further development of cokemaking technology and its implementation in practice, in particular, would not have been successful without the innovative legacy of the German coke oven constructor companies. Out of the four prosperous German companies Dr. C. Otto, Carl Still, Heinrich Koppers and Didier Kogag Hinselmann, today only one exists, the Uhde GmbH which took over their business activities during the last 30 years step by step. German cokemaking technique is accepted worldwide, and according to this it is not surprising that more than 100000 coke ovens all over the world have been constructed by German companies.
Progress reached in emissions control on German coking plants can be described by a drastic reduction of production specific emissions caused by battery operation due to the more stringend becoming legal rules for environmental control (Fig. 25).
Reduction of specific emissions on German coking plants between 1950 and 1986
A quantitative method for measuring fugitive emissions from leakages at the battery was developed by Deutsche Montan Technologie GmbH (DMT) and its predecessor institute Bergbau-Forschung GmbH (BF) respectively. The relevant measurements included particle bound as well as gaseous compounds, and were carried out between 1980 and 2006at various coking plants of different age in Europe which additionally were different in their design and in the state of maintenance of the closure facilities.
For the measurements a complete encapsulating of the relevant source is necessary as described in the following as an example of measurements at the coke oven doors. For this the outer door zone of the coke oven door is covered (see Fig. 26, left) by a thermo-stable transparent film (foil) in order to detect the strength of visible emissions, simultaneously. Preferentially the foil is fixed on the buck stays. The gas accumulated in the collecting space has to be withdrawn and analysed. For this, the foil at its bottom contains an opening while the top of the collecting space is combined with a vertical arranged tube. Because of thermal buoyancy clean air enters the opening at the bottom while the mixture of air and the emissions looked for leave through the pipe at the top of the collecting space. Typical volume flows are in the range between 50 and 200 Nm3/h depending on the design, the dimension of the door, the magnitude of the opening at the foil´s bottom as well as on the meteorological marginal conditions. The relevant gas velocities range between 4 to 10 m/sec. From this main gas flow the sampling gas was sucked off isocinetically with a flow rate of about 2 Nm3/h.
For measurements of leakages at closed lids of the charging holes and of the offtakes, respectively, equipment for encapsulating was used, as shown on Fig.26, (right). In order to get a constant gas-flow, pressured air as carrier gas was injected into the encapsulated space.
Equipment for measurements of fugitive emissions at doors (left side), lids (right side, top) and offtakes (right side, bottom)
In all cases the sampling gas is led via a dust filter and afterwards through an additional filter containing a synthetic resin for adsorption of still remaining gaseous PAH compounds. Sampling has to be done during the whole coking cycle, which was devided in several steps with separate sampling in some trials.
The taken samples are analysed in the laboratory for PAH-compounds by means of GC/MS and HPLC, respectively, in accordance with a national standard method (VDI, 1996).
Results from measurements at single leaks are given as emission mass flow mf (mg BaP/h/closure facility) as an average of the sampling time) in a first step. The relevant figures are derived from the initially measured mass concentration (mg BaP/Nm3) in the sampling gas and the main gas volume flow (Nm3/h). To make the results more comparable the emission mass flows are converted to product specific emissions (mg BaP/tcoke) by consideration of the production rate per oven and the coking time. This figure is typical for the closure facility under investigation.
Fig.27 shows the distribution of BaP in the gaseous and on the particle phase of emissions from oven leaks, as function of total particle concentration and off-gas temperature, respectively. It could be shown, that with increasing temperature of the waste gas, the portion of BaP in the gaseous phase increases, too (Fig. 27, right). And one receives the result, also, that with increasing dust emission the portion of BaP in the gaseous phase descreases (Fig. 27, left).
Proportion of BaP in gaseous and dust boundphase in emissions from coke oven leaks
Typical emission ranges for Benzo(a)pyrene as received by the measurements with concern to leaks at coke oven doors and chamber lids, respectively, are listed in Figures 28 and 29(Eisenhut et al., 1990, 1992).
Typical ranges for Benzo(a)pyrene emissions (mg BaP/tcoke) from single leaks at coke oven doors as received from measurements
Typical ranges for Benzo(a)pyrene emissions (mg BaP/tcoke) from single leaks at charging lids as received from measurements
Fig.28 shows also factors which have influenced the measurement results. These influence factors are valid for the results of measurements at the closed lids of the charging holes, too (Fig. 29). In both cases the age of the plants, the maintenance of them, the quality of the sealing facilities and the specific sealing surface per tonne of coke, which is in the opposite direction with the oven volume, have an impact on the amount of the emissions. As the measurement have started in early 1980th the shown ranges for emissions also include results from old plants with 4 m ovens in a bad condition and antiquated techniques for emission control. These plants are no longer in operation in Europa. And also in a more generalized view, one has to state that these plants are not typical for worldwide cokemaking operation of today. By consideration of this, Table 11 contains typical emission ranges for Benzo(a)pyren for coking plants caused bysingle leaks at the batteries which are still running today. Besides emissions from leakages at closed doors and lids, Table 11 contains also emissions from closed offtakes. Consequently it is to state that the lowest BaP emissions can be received at 6 to 8 m high flexible doors which are equipped by membrane sealings. The relevant emissions per door lie in the range between 1 to 10 mg BaP per t of coke. For new plants with an excellent maintenance, emissions at single doors go down to 1 mg/tcoke. Under optimal conditions, for example if a chamber pressure regulation system is installed (chapter 5.1.4.), BaP emissions are reduced below 1 mg/tcoke. BaP emissions at the chamber lids lie in a range between 0.3 and 5 mg/tcoke. The lowest emissions can be achieved at modern and well tended plants if the lids are sealed by special fluids or pastes after closing the relevant opening at the roof of the battery. In this case emission below 1 mg/tcoke can be received. Typical BaP emissions from leaks at the offtakes are below 3 mg/tcoke. On modern plants with water sealed lids at the offtakes emissions go down below 1 mg/tcoke.
doors | control technique | lids | control technique | offtakes | control technique | unit of measurement |
10 - 45 | knife sealing | 3 - 5 | not sealed | < 3 | metal/metal | mg BaP/tcoke |
1 - 10 | membrane sealing | 0.3 - 3 | sealed | < 1 | water sealed | mg BaP/tcoke |
< 1 | improved techniques, like PROven | mg BaP/tcoke |
Product specific emissions for single leaks at the batteries of current coking plants
From Fig.30 one can derive that over three-fourth of the fugitive BaP emissions from battery leaks in total is caused by emissions at the doors.
Spread of fugitive emissions from single leaks at the battery
This is in good correlation with the Figures given bei the US EPA (Table 9 of section 4.3.2.), and is the reason why in the following section emissions from coke oven doors are concerned, only, when discussing strength of leakages, as estimated by the US EPA and DMT, respectively.
Normally,by use of only one emission figure, as received from Table 11,andmultiplication with the annual coke productionis notpossible to estimate the annual BaP emissions of the total coke oven battery. The reason for this is the inequality of the strengths of the emissions at the various sources of one type (door, lid and offtake, respectively).
Analogously to the procedure from the US EPA (see section 4.3.2.) the total emissions of the plant should be calculated on base of the frequency of the visible emissions (leaking rate; section7.4.) and of their strength (mass/h/leak), in the following. This will be done as an example for door emissions, as these emissions play the dominant role with regard to the total emissions caused by the battery (see Fig. 30 in section 7.2.)
To meet this goal varios door leaks, which strongly differ in their visible strength, were investigated as described in section7.1., however by applying shorter sampling times (up to 5 h) with a nearly constant source strength over the sampling period. Typical strengths of visible emissions at doors are shown in Fig. 31. The emissions are categorized in:
strong (st),
medium (m),
slight (sl)
non visible emissions (n.v.e.)
For each category of visible strength typical BaP emission mass-flows (mf) could be determined, the ranges of which are shown on Table 12 (see also Fig. 32 in section7.6.).
The specific mass-flows which are typical for visible emission strengths can be transfered to other plants where measurements have not been carried out. The assignment has to be done by an expert, on base of comparisons with results of measurements at comparable plants.
Four categories of visible strengths of door emissions
strength of visible emissions | strong (mfst) | medium (mfm) | slight (mfsl) | n.v.e. (mfn) | unit of measurement |
all plants | 150-600 | 50-150 | 10-40 | < 10 | mg BaP/h/leak |
plants according state of the art (membrane sealings) | 150-200 | 50-150 | 10-40 | < 10 | mg BaP/h/leak |
Typical emissions BaP mass flows mf for leaks of different visible strength at coke oven doors
The leaking rates at the different sources are determined by an inspection of the battery and counting the visible emissions according tho EPA method 303 (US-EPA, 1993b). A distinction from the EPA method is made with regard to the different strengths of the visible emission, as it is shown for door emissions in Fig.31, as an example.
Thus, the result of the determination of visible emissions will be, inpinciple:
no. k of strong emission
no. l of medium emissions
no. of slight emissions, and
n-(k+l+m) no. of none visible emissions,
whereby k,l and m are the numbers of leaks with visible emissions of different strengths, and n ist the number of doors in total.
The DMT-method for inspection of the leaking rates differs from the US-EPA 303 method by its four categories for emissionstrength while the US EPA method only results in the decision on the existence of a visible emission or not.
By mathematical combination of thenumber of leaks with their relevant emission mass flow the total emission E (mg BaP/h) of the battery (plant) with regard to emissions from door leaks can be determined, according equation 2.
E = k x mfst + l x mfm + m x mfsl + (n-k-k-m) x mfn(2)
Where mfst, mfm, mfsland mfn are the emissionmassflows of different strengths of visible emission (Table 12), k,l and m are the numbers of visible emissions of different strengths at doors, and n ist the number of doors in total. Equation no. 2 is comparable to equation no. 1 (section4.3.2.) by which relevant calculations are made by US EPA (US-EPA, 2008b). Product specific BaP emissions caused by door leaks, which are typical for the emissions of the total plant, can be derived by multiplication of the result of equation no. 2 with the annual operation time and dividing by the annual coke throughput. Results of these calculations, which often are called emission factors, are given in section 7.6., and are compared there with relevant emissions given by the US EPA.
On base of equation 2, total BaP emissions caused by all doors of a modern high capacity battery (70 ovens, 7.8m hight, 1 mio. t coke per year) are calculated (line 8 and 9 of Table 13) by applying the extreme values of the given ranges for emission mass flows according Table 12 (line 3). Leaking rates (portion of no. of visible emissions (no. v. e.) of the total no. of openingsin %) of 4 % (2 % slight and 2 % medium emissions) according the post-NESHAP standard and of 3.3 % (1 % slight and 2.2 % medium emissions) according the LAER standard are applied in order to make the results comparable with calculations of the US EPA (line 1 to 7 of Table 13).
Results given in lines 1 and 2 are derived on base of the model battery, as described in section4.3.2. (62 4 m ovens per battery with a coke capacity of 344000 t coke per year), and on leaking rates of 4 % and 3.3 % respectively, analogously to equation no. 1. These emissions will be reduced significantly when considering a high capacity battery with larger oven dimensions (line 3 and 4) due to the lower specific sealing lengths. Lines 5 to 7 contain ranges for BaP emissions caused at doors as given by a Risk Assessment Document of the US EPA (US-EPA, 2003b) for 5 US batteries which comply with the LAER standard (2010) already today (see section4.3.1. also).
The origin of the applied emission mass-flows for the calculations according equation no. 1 and no. 2 one can read from column 8 of Table 13. To make data from US EPA comparable with own results, a conversion of BSO to BaP and tshort to tmetricwas necessary.
leaking rate | batt. height | capacity | BaP | ref. of emission mass flow | |||
no. v.e. (%) | (m) | (t/a x10 3) | (mg/tcoke) | ||||
1 | model batt. | 4 | post-NESHAP | 4 | 344 | 84,8 | (US-EPA, 2008b) |
2 | model batt | 3.3 | LAER | 4 | 344 | 81,4 | (US-EPA, 2008b) |
3 | high capacity oven | 4 | post-NESHAP | 7.8 | 1000 | 30,6 | (US-EPA, 2008b) |
4 | high capacity oven | 3.3 | LAER | 7.8 | 1000 | 29,4 | (US-EPA, 2008b) |
5 | 5 US batt. | 1.58 - 2.81 | actual | 3.4 - 5 | 65 - 589 | 22 - 57 | (US-EPA, 2003b) |
6 | 5 US batt. | 5; (3.8) | MACT | 3.4 - 5 | 65 - 589 | 25 - 88 | (US-EPA, 2003b) |
7 | 5 US batt. | 3.3; (3.8) | LAER | 3.4 - 5 | 65 - 589 | 25 - 78 | (US-EPA, 2003b) |
8 | high capacity batt. | 4 | 2sl+2m | 7.8 | 1000 | 2.65 - 16.43 | DMT/Table 11 |
9 | high capacity batt. | 3.3 | 1ss+2.2m | 7.8 | 1000 | 2.66 - 16.41 | DMT/Table 11 |
*: non visible emissions are not considered |
Comparison of product specific BaP emissions (emission factors) caused by door leaks from own measurements with figures given by the US EPA (US-EPA, 2008b, 2003b).
From Table 13 one can read that all data given by the US EPA for BaP emissions from door leaks are significantly higher than those calculated by DMT. The reason for this is easily to understand and can be caused back to the higher values for the emission strengths (emission mass-flows of the single leak) as given by the US EPA (see Fig. 32 and Table 8 in section4.3.2., respectively), and to the extra addition of 6 % emissions which can be observed only from the bench according the procedure of the US EPA. And in addition, it is to remark that the total emissions of plants according the state of the art with visible emissions less than 4 % are predominantly influenced by the strength of the non visible emissions (< 10 against 17 mg BaP/h/leak). The quality of the DMT-values for BaP emission strength could be confirmed by several dispersion calculations, by which the additional load caused by coke plant emissions on the ambient air in the surrounding of the coke plant, where the actual BaP concentration was determined by measurements, could be forecasted sufficiently on base of the above mentioned emission factors. In this context, it is to remark, that emission, as published by the US EPA, will lead to an overestimation of the BaP concentration in the surrounding,if forecasting(section 8.2.) the addition load in ambient air caused by a planned coking plant, e. g. in the process for getting a license for operation.
An explanation for the differences in BaP emission strength as determined by the US EPA and DMT, respectively, can be found in the high uncertainty of the US EPA figures, and in their determination on old coking plants with low standards for emission control, according to the acertainment of the US EPA by itself (US-EPA, 2008b).
If emissions from charging lids and offtakes are taken into account, one can assert that there are only slight differences in the emissions determined by DMT and the US EPA, respectively.
Ranges for emission strength (mg BaP/h/door leak) as determined by DMT and US EPA (cross marks), respectively (US-EPA, 2008b)
A correlation between the Benzo(a)pyrene (BaP) emissions caused by a coking plant and the BaP concentration in ambient air in the surrounding of the plant could be shown by a lot of measurements. Measurements were made according (DIN-EN, 2008) by analysing the partice bound portion of the collected dust. Thereby factors could be determined, which influence the amount of concentrations, as given on Table 14, and which will be described in the following.
BaP in ambient air near coking plants is caused by: | -applied techniques for emission control on the plant |
-status of plant maintenance | |
-age of the battery and of the closure facilities | |
-local meteorological influences on spread of emissions | |
- distance of the impacted area (measuring point) from the battery |
Factors influencing BaP concentrations in amient air caused by coking plant operation
Three coking plants, located in the Rhine-Ruhr area in Germany, were under investigation. In the following they are called coking plant A, B or C.
For more than 20 years, ambient air has been examined for BaP in the surrounding of coking plant A (LANUV, 2012). The measuring station is located about 800 m away, in lee-side position to the coke plant. Measurements are taken two times or three times per week over a sampling period of 24 h. The coking plant is a modern plant yielding an annual coke production of approx. 2 million tons. The batteries are aged approx. 25 years, and fulfill the requirements imposed under the 2002 TA Luft for emission control.
Benzo(a)pyrene in ambient air near (lee-side) coking plant A as annual mean (LANUV, 2012)
Fig.33 shows the annual average concentration of BaP determined during the past years, that never fell under a BaP concentration of 1 ng/m3, which is set by the European Union as ambient air standard (EU, 2008).
The importance of coking plant´s emissions on the BaP burden in the vicinity can be proved by an evaluation of the measurements in front of the preferential wind direction at the measuring daywithin a two years’ term (Fig. 34) (Hein et al, 2003; DWD, 2003; LANUV, 2003). The mean annual BaP concentrations for the period under evaluation (1999-2000) lie at 2.2 and 2.5 ng/m3, respectively. The highest BaP concentrations occur when the wind blows from the wind direction sector between 135 and 255°, with the maximum occurring during wind directions from approx. 200°. As the measuring station stands in a direct lee-side position to the coking plant in case of a wind direction from 195°, the inevitable conclusion is that the coke plant is mainly responsible for this burden during lee-side weather situations that reaches 3.7 ng/m³ on average. This conclusion can be confirmed by the absence of any other important BaP emitter in the weather-side of the coking plant. For measurements on days marked by wind directions falling outside the specified sector, it results a mean BaP concentration of 0.6 ng/m3. This BaP concentration is mainly congruent with the BaP background load which is typical for the industrial region where the coke plant is located, roughly amounting to 0.5 ng/m3.
When discussing the influence of meteorology on measured BaP concentrations, one should not ignore that other influential factors apart from the direction of wind are to be taken into account, for example the vertical exchange of air,which is typical for the season very often. A seasonal influence on the determined BaP concentrations can be clearly seen from measurements (LANUV, 2003) in the surrounding of coking plant B with an annual capacity of approx. 1.0 mio. t coke (Fig. 35). This plant is about 25 years old, and is equipped with techniques for emission control in compliance with the legal demands of the TA Luft 2002.
Influence of wind direction on Benzo(a)pyrene concentration in ambient air near coking plant A (DWD, 2003; Hein et al., 2003; LANUV, 2003)
Benzo(a)pyrene in ambient air in lee-side of coking plant B during a two years period(LANUV, 2003)
The measurements were taken lee-side of the plant in a distance of 1000 m. Due to the larger distance of the measuring point from the plant, and to the less coking capacity, the BaP concentrations near coking plant B are lower than those near plant A. The annual BaP concentrations lie at 0.8 ng/m3 and complies with the relevant ambient air standard of 1 ng BaP/m3 as given by the EU (EU, 2004).
An influence caused by the seasonal effects, but also by improvements in the applied emission control techniques, can be also clearly seen from a three years measurement campaign in the surrounding of coking plant C, which composed of an annual capacity of approx. 1.5 mio. t coke (Fig. 36). The age of the various batteries of this coking plant, that has shutdown in 1999, was between 35 and 40 years on date of the measurements. However, the coke oven batteries including the oven machinery have been rehabilitated before the final measuring period such that they fulfilled the most essential demands imposed under the 1986 TA Luft.The measurements were carried out at a distance of approx. 250 m both on the lee-side and weather-side of the batteries. On the lee-side, the annual means for BaP ranges from 23 to 37 ng/m3, while more than 50 % of the measured values were above 10 ng/m3. The rehabilitation work carried-out during the measuring period led to a reduction in the BaP burden at the most strongly burdened measuring station on the lee-side by up to 20 % relative to the annual average. Fig.36 shows the already known seasonal influence on measuring values which, like for coke plant B, is mainly attributable to the different meteorological conditions prevailing during the summer and winter term. However, a base load of up to 6 ng/m3 was determined for the winter months at both measuring positions. Presumably, coal fires in private households which were quite popular in this region at that time mainly caused this base load.
Benzo(a)pyrene in ambient air near coking plant C (shutdown in 1999) during a three years period
The additional burdens of BaP, caused by coke plant´s emissions, in the surrounding of coking plants A and C, respectively, were calculated by applying a spread model as per Gauß, without taking account of the influence exerted by buildings on the wind field (Hein et al., 2003). The wind field was just described by the spread class statistics for the site of the coking plant. The applied emission mass flow rates were based on those ranges given in section 7.
By evulation of existing measuring data on the overall BaP burden near both coking plants, it was possible to calibrate the mathematical assumptions, and the assumed emission mass-flows in particular, by a factor of 1.18. The corrected results from calculations for the site of coking plant A are reflected in Fig. 37 (top side) in a so-called iso-line representation, which gives the total load of BaP as an annual average (for the year under investigation) near this plant, assuming a base load of 0.5 ng/m3 which was typical for the Rhine-Ruhr area in the time under investigation.
Calculated BaP concentrations (ng/m3 as an annual mean) in ambient air near German coking plants; top side: total BaP concentrations near coking plant A considering a base load of 0.5 ng BaP/m3; bottom side: calculated additional burden and measured concentrations in the surrounding of plant A and C, respectively
From Fig. 37 (top side) one may conclude that, in the period under investigation, the ambient air standard for BaP of 1ng/m3 (as a sum ofbase load and additional burden) as demanded in (EU, 2008) will be complied with in north-east of the investigated coking plant A only from a distance of approx. 1,500 m onward away from the battery center, assuming a base load of 0.5 ng/m3. The graph in the bottom of Fig. 37 shows the nearly asymptotic decline of the additional burdens by BaP,caused by battery operation, in the main direction of wind in progressive distance from both coking plants under investigation. The spread characteristics shown here can be confirmed by BaP measurements (overall load) that were taken in the environment of these plants in the past.
Inasmuch as their meteorology as well as their coke throughput rates is comparable with the two investigated coking plants, a transfer of the outlined spread behaviour to other coking plants with comparable emission control standards should be possible.
Coke will be an indispensable precursor for steel production worldwide, also in the future. A further extension of the current cokemaking capacities in the world will depend on the global economics and on the future behaviour of export willing countries to sell coke for reasonable prices, of China in particular. It is to assume, if there is need for building of additional cokemaking capacities, the relevant plants will be built in countries with an increasing steel demand. Besides for China, this will be the case for India, Southeast-Asia and South America. Another trend will be inevitable worldwide, that means the replacement of older and smaller plants by modern high capacities batteries for cokemaking. This will be necessary not only by economic but notably by ecological reasons. Worldwide the legal demands for improvements in emission control on coking plants have been tightened in the last years. Legislation for environmental control as given by the Clean Air Act in the US, by the German TA Luft or by the BREF document of the European Union are accepted as a standard for other countries. Improvements in emission control could be achieved by application of the Best Available Techniques for emission control on coking plants during the last years in Europea, and in Germany in particular. By consequent compliance with future standards, as described in the draft of the revised BREF document, further improvements in air quality in the surrounding of the plants will be achieved. At this, special importance is to be attached to emissions containing carcinogenic coumpounds, like Benzo(a)pyren (BaP), which are emitted during conventional cokemaking because of envitable leaks at the closure facilities of the oven chambers. Similar to the non-recovery technology for cokemaking, which operates under negative pressure, these fugitive emissions can be drastically reduced at conventional cokemaking, too, by application of techniques for control the pressure of the oven chamber.
In order to predict the impact of coke plant´s emissions on the ambient air in the surrounding, it is necessary to quantify their amount. The paper describes methods for measuring fugitive emissions containing Benzo(a)pyrene at single closure facilities of the coke ovens, whereby emissions from doors play a dominant role. Based on these results, an estimation of the BaP emissions of the total plant is possible. It could be shown that so-called emission factors for BaP from doors, as an average of all doors of the battery, as given by the US EPA are higher than those from own measurements. By use of untypical high emission factors for a prognosis of the impact of coke plant´s emissions on the ambient air and thus on the health risk for the people living nearby, it can happen that the importance of a coking plant is overestimated. By use of emission factors, which determination is described in this paper, for spread calculations, a sufficient forecast on the additional burden of BaP in ambient air in the surrounding of the coking plant is possible, when comparing with actual results of measurements. Additionally, parameters could be evolved which influence the impact of coke plant´s emissions on ambient air. One of them is the location of the coking plant with regard to the relevant residential area where the ambient air measurements are carried out. In case that the coking plants are located mid of spacious industrial areas, the ambient air concentration for BaP of 1 ng/m3 as set as a standard in Europe can be achieved in most cases, provided the relevant plant doesn´t exceed a capacity of maximum 2 to 3 mio. t and is equipped with techniques for emission control according the state of the art.
Everyday life is organized according to three different clocks: the solar clock which gives us light and temperature during the day, the social clock which determines the working day, and the biological clock which we notice during shift work or when we adjust to a reduced amount of daylight. In real life, the circadian clock is synchronized within 24 hours of the solar clock [1, 2].
It is known that almost all cardiovascular events occur in a circadian manner with a higher frequency in the morning after waking [3]. In the peripheral clocks of the cardiovascular tissues or cells, there is daily expression of the clock-controlled genes (CCG) synchronized and regulated by central clock [4, 5]. Disturbances of circadian rhythm can lead to cardiovascular disease.
Today we are facing a global epidemic of cardiovascular disease. In 2015 cardiovascular disease was the cause of 17.7 million deaths worldwide or 31% of total mortality. Of these 7.4 million deaths were caused by ischemic heart disease and 6.7 million by cerebrovascular diseases, according to World Health Organization (WHO) [6].
Circadian rhythm is controlled by a molecular clock located in almost every cell. A hierarchical system organizes molecular clocks—the master clock is located in the suprachiasmatic nucleus (SCN) in the hypothalamus [2, 7], while the peripheral clocks are located in each organ or cell. The central clock regulates physiological functions via the autonomic nervous system, humoral mediators, and other still unknown factors [7, 8]. In the maintenance and generation of circadian or biological rhythm in humans, a whole series of anatomical (suprachiasmatic nucleus), neurological (retinohypothalamic paths) and neuroendocrine (melatonin) systems are involved, indicating that the biology of the circadian rhythm of humans is similar to that of animals [9].
The master clock in the SCN consists of about 100,000 neurons in humans. It is the only molecular clock that receives light as an input signal from the retina. Internal clocks are synchronized with light depending on the time of day. SCN receives a direct light signal from the retina via the optic nerve from the photoreceptor called the intrinsically photoreceptive retinal ganglion cell (ipRGC), which expresses the circadian photopigment, melanopsin [10]. The signal is further transmitted to peripheral clocks via the endocrine system [11, 12]. The central clock synchronizes each of the peripheral clocks in the body, and the primary circadian hormone is melatonin [13]. The pineal gland secretes melatonin during the night. Melatonin plays an essential role in maintaining the circadian rhythm depending on the period of light or darkness. The main difference between the master and peripheral clocks is in their degree of intercellular interaction. Peripheral clocks are under the influence of the master clock from the SCN via hormones, chemical signals and other metabolites (such as food), as well as by changes in the body, such as body temperature [11, 12].
On the other hand, due to the high degree of neuron connection the master clock in the SCN is not under the influence of internal signals but only under the influence of light [14]. Peripheral tissues integrate central clock signals with environmental factors (including sleepiness, physical activity, and feeding) and their autonomic rhythms which regulate the metabolism in a circadian manner [10]. The rhythm of the peripheral clocks in humans is measured by direct measurement of physiological changes, or by determining the expression of the clock genes. Central and peripheral clocks together control the daily circadian rhythm of the metabolism [15].
Feeding time is one of the key triggers or external factors that sets the phases of the peripheral clocks [15]. Complex feedback loops connect the circadian clock with metabolic pathways and integrate these systems independently of light [10]. It is believed that the central clock regulates the metabolism by hormones (primarily cortisol and melatonin) and synaptic signaling (via the autonomic nervous system) [10]. Feeding is a circadian event that serves not only as the output of the central clock, but also as an input signal for peripheral clocks because peripheral tissues communicate with the brain through ghrelin, leptin, glucose, and insulin. Circadian feeding contributes to the interworking of the clock and metabolism, which is crucial for metabolic homeostasis [16]. The central clock rhythm is primarily related to light, whereas peripheral tissue rhythms derive from the input of signals from the central clock, external factors (light, physical activity, feeding, and sleepiness) and the availability of numerous metabolites [15]. All these signals affect the molecular clock, creating a complex correlation between the circadian clock and physiological processes [10]. SCN coordinates all cellular circadian clocks in the organs and tissues through its rhythmic outcomes, to adapt physiology to Earth’s rotation [17].
The two clock systems become desynchronized when their drivers or stimuli do not coincide because different stimuli affect the phases of the central and peripheral clocks. This mismatch disrupts the metabolism because the two clock systems coordinate interlinked metabolic pathways. Circadian rhythm mismatch increases the risk of developing metabolic diseases [15].
The central clock is primarily triggered by light, and its rhythm is often measured by determining the concentrations of melatonin, cortisol or body temperature [15]. The expression of the clock genes is disrupted in pathological conditions. Such a change may result in different tissue response to external signals and accelerate tissue damage. The loss of synchronization can lead to various diseases, including an increased incidence of cardiovascular disease [18].
The central clock genes are expressed in a circadian manner in the SCN, and light is one of the main initiators (so-called zeitgeber) and can reset the phase of the rhythm. The first circadian rhythm gene discovered was the Per gene in the fruit fly in 1971 [19, 20], while the first circadian rhythm gene discovered in the vertebrae was the CLOCK gene [21]. There are about 10 circadian rhythm genes known to regulate cyclic expression of mRNA and protein, via transcription and translation feedback loops [22]. In the SCN there are four essential proteins: ARNTL (Aryl Hydrocarbon Receptor Nuclear Translocator-Like) and CLOCK (Circadian Locomotor Output Cycles Caps) are activators, while PER (Period) and CRY (Cryptochrome) are transcription inhibitors. The feedback of the circadian rhythm gene maintains circadian oscillations in one cell at the transcriptional and posttranscriptional levels, and the transition from light to dark triggers these oscillations. The whole process of activation and repression of gene expression within the loop lasts for about 24 hours. These transcriptional factors trigger numerous physiological changes by acting on the expression of the same genes, and other clock-controlled genes [23, 24].
ARNTL and CLOCK heterodimers bind to regulatory elements of the promoters and enhancers (E-box) of the PER and CRY genes and stimulate their expression and the expression of other clock-controlled genes. Overnight the amount of PER and CRY proteins gradually increases, and heterodimers are created in the cytoplasm. The phosphorylated PER-CRY heterodimers are translocated into the nucleus where they inhibit the ARNTL-CLOCK protein complex. Therefore, during the day, transcription of PER and CRY genes is reduced, while the levels of PER and CRY protein decrease due to their degradation by ubiquitin. The PER-CRY heterodimers directly bind to the ARNTL-CLOCK complex, and as PER2 contains histone deacetylase, the chromatin structure changes, resulting in transcription termination. Also, the PER-CRY heterodimer is in interaction with RNA-binding proteins and helicase that are important in stopping transcription independently of the interaction with the ARNTL-CLOCK complex. Additionally, PER-CRY heterodimers regulate the transcription of various nucleic hormone receptors [25, 26, 27, 28].
During the day a new cycle begins by the termination of the ARNTL-CLOCK heterodimer inhibition. Casein kinase 1 (CK1) controls the amount of phosphorylation or degradation of PER-CRY heterodimers and thereby determines the amount of PER-CRY heterodimer entering the nucleus and inhibiting the ARNTL-CLOCK complex. CK1 phosphorylates the proteins and thus regulates their activity [29].
The additional negative loop is REV-ERBα that binds to the REV-ERB/ROR response element (RRE) of the ARNTL and CLOCK genes, and prevents their transcription. Also, RORα (Retinoic Acid Receptor-related Orphan Receptor) binds to the same regulatory elements of the ARNTL gene as well as REV-ERBα. With REV-ERBα degradation overnight, RORα promotes transcription of the ARNTL gene [30]. The second regulatory loop consists of ARNTL-CLOCK heterodimers which promote the transcription of the nucleic receptors REV-ERBα and RORα [31] (Figure 1).
The molecular mechanism of circadian rhythm in humans. ARNTL and CLOCK activate transcription of CRY and PER, nuclear receptors (REV-ERBα and RORα) and other clock-controlled genes. CRY and PER heterodimerize and phosphorylate by casein kinases and translate into the nucleus where they prevent binding of the ARNTL-CLOCK to the regulatory regions of target genes. In the second feedback loop, REV-ERBα prevents the transcription of ARNTL because it binds to the RRE element, while overnight the same regulatory elements bind RORα and activate transcription of ARNTL. Also, ARNT-CLOCK heterodimers activate transcription of the REV-ERBα and RORα proteins. ARNTL—aryl hydrocarbon receptor nuclear translocator-like, CLOCK—circadian locomotor output cycles kaput, CRY—cryptochrome, PER—period, P—phosphate, RORα—retinoic-related orphan receptor alpha, RRE element—REV-ERB/ROR response element, Ub—ubiquitin.
Circadian clock genes have an essential role in many physiological processes. Thus, animal models demonstrate that the ARNTL gene plays an essential role in lipid metabolism because it induces the expression of genes involved in lipogenesis in adipose tissue in a circadian manner [32]. Pancreatic beta cells have a circadian clock dependent on ARNTL and CLOCK protein oscillations, which regulate insulin secretion depending on the stage of alertness. Abnormalities of the pancreas clock may trigger the onset of diabetes [33]. It was found that CLOCK polymorphisms are associated with body weight, the risk for metabolic syndrome and insomnia in humans [9, 32], and polymorphisms of the PER2 and PER3 genes are associated with sleep disorders [34, 35]. Some variants of CRY1 and CRY2 genes are associated with metabolic syndrome, particularly hypertension and increased triglyceride levels in the blood [36]. Many variants of the circadian rhythm genes are associated with the risk factors for the development of cardiovascular diseases such as blood pressure, glucose concentration [23, 37]. An overview of the essential circadian rhythm genes with their roles is shown in Table 1 [38, 39].
Gene | Function |
---|---|
ARNTL (Aryl hydrocarbon Receptor Nuclear Translocator-Like) | Rhythmically expressed. Physically associates with CLOCK. Promotes transcription of PER and CRY. It is involved in the risk for hypertension, adipogenesis, and glucose metabolism. |
CK1ε (Casein kinase 1 ε) | Physically associates with and phosphorylates PER. Affects PER stability and nuclear localization. |
CLOCK (Circadian Locomotor Output Cycles Kaput) | Constitutively expressed. Physically associates with ARNTL. Promotes transcription of PER and CRY. It is involved in the platelet rhythmic activity, response of cardiomyocytes to fatty acids, lipid, and glucose metabolism. |
CRY1 (Cryptochrome 1) CRY2 (Cryptochrome 2) | Physically associates with and stabilizes PER. Negative regulator of Per and Cry transcription. |
PER1 (Period 1) PER2 (Period 2) PER3 (Period 3) | Physically associates with CRY. Positive regulator of ARNTL. They are involved in the aortic endothelial function. |
REV-ERBα (nuclear receptor subfamily 1 group D member 1) | Associates with regulatory elements and negative regulator of the ARNTL and CLOCK transcription. It is involved in triglyceride and lipid metabolism, and circadian activity of PAI-1. |
RORα (Retinoic-related orphan receptor alpha) | Associates with regulatory elements and positive regulator of the ARNTL. It is involved in lipid metabolism. |
TIM (Timeless) | Circadian function not known. Physically associates with CRY. Negative regulator of PER and CRY transcription in vitro. |
The essential circadian rhythm genes in mammals.
Numerous studies on animal models, as well as human populations, have confirmed the association of the circadian clock gene with metabolic syndrome and cardiovascular diseases [15, 40, 41].
The WHO data for 2017 show that cardiovascular diseases were the cause of 19.9 million deaths worldwide, and about 80% of deaths from cardiovascular diseases were due to myocardial infarction and stroke [42]. It is estimated that by 2030, 23.6 million people will die annually due to cardiovascular diseases [43].
Cardiovascular diseases are the primary cause of death in developed countries of the world, and in less developed parts of the world, this mortality is rising and overtaking mortality rates for infectious diseases [44].
There are variable and constant risk factors for cardiovascular disease. The variable risk factors are those that can be affected by therapy and lifestyle change, such as smoking, hyperlipoproteinemia, hypertension, and to some extent diabetes and homocysteinemia. The constant risk factors cannot be affected, namely age, genetic predisposition, gender, and menopause. The general risk factors which can be altered most are smoking, hypertension and hyperlipidemia, and obesity and diabetes whose prevalence has risen in the last few decades. However, some recent risk factors (fibrinogen, lipoprotein (a), homocysteine) should not be ignored. All of these contribute to total cardiovascular risk [45].
Cardiometabolic risk factors are determined by a cluster of metabolic and cardiovascular changes. Diabetes and obesity are also associated with reduced quality of life and increased economic burden on the person and society [46, 47]. Cardiovascular diseases and type 2 diabetes share common pathophysiological mechanisms of insulin resistance and risk factors for cardiovascular diseases, such as metabolic syndrome. Excessive weight plays a significant role because fatty tissue becomes an active endocrine organ that secretes low-level inflammation mediators, and these stimulate the development of metabolic syndrome and vascular diseases [32, 48, 49].
Myocardial infarction is the leading cause of mortality in developed countries and developing countries. It can be caused and triggered by different pathophysiological processes. Myocardial infarction is an inflammatory disease due to the death of myocardial cells because of complete coronary circulation interruption, which is in most cases a consequence of thrombotic occlusion of the coronary artery at the site of the activated atherosclerotic plaque. An electrocardiogram (ECG) of the ST elevation is only an indirect indicator of the fact that ischemia affects all three layers of cardiac muscle (endocardium, myocardium, and epicardium) [50].
ST-elevation myocardial infarction (STEMI) is the most severe form of acute coronary syndrome. Myocardial infarction is accompanied by increased cellular oxidative stress in the pericardial cavity [51]. The primary cause of infarction is platelet aggregation in the coronary artery. The platelet activity is the highest in the morning. Also, in the morning hours, mental and physical activity increase due to cortisol and catecholamine elevation, which increases cardiac output [45]. The biochemical markers of myocardial damage are cardiac troponin T or troponin I in serum. These biochemical markers are more reliable than those previously used, such as measurement of creatine kinase (CK). The initial increase in troponin in peripheral blood in patients with infarction occurs over 3–4 hours with a permanent increase for up to 2 weeks after infarction. In order to confirm or exclude myocardial damage, troponin T serum levels are repeated in the first 6–12 hours after severe chest pain [52].
The classification of myocardial infarction in five types was introduced in 2007 and established the clinical criteria for its exact differentiation [50]. Type 1 is related to a coronary plaque rupture, fissuring, or dissection with resulting intraluminal thrombosis. Type 2 myocardial infarction is secondary to myocardial ischemia resulting from increased oxygen demand or decreased supply. Type 3 myocardial infarction is linked to unexpected cardiac death when cardiac biomarkers are unavailable. Types 4 and 5 myocardial infarction are procedure related [53].
In the study of Saaby et al., [54] it was shown that the most significant number of patients with myocardial infarction come under Type 1 (72%). In patients with Type 1 myocardial infarction, changes in the ECG are seen either as the elevation or depression of the ST segment; the troponin T level also increases in the blood and serves as a diagnostic marker. The troponin T level in the blood is higher in patients with Type 1 myocardial infarction than Type 2 [55].
For manifestation of infarction, apart from lifestyle, a genetic background of myocardial infarction is also essential. A positive family history of myocardial infarction is a major cardiovascular risk factor [56]. Coronary artery disease and myocardial infarction have a genetic background in 50–60% of cases. Many genes are found in the genetic background of myocardial infarction. Whole genome association studies have revealed many variants of genes associated with increased risk for myocardial infarction [56]. So far the most frequently explored genes with increased risk for myocardial infarction are involved in the metabolic pathways of lipid metabolism and development of type 2 diabetes. The relationship between the circadian rhythm genes and the onset of myocardial infarction will be discussed below.
Many cardiovascular events and diseases have a circadian pattern of appearance. The normal circadian blood pressure shows the two highest values during the day, around 9 am and 7 pm, while there is a slight decrease around 3 pm. It is considered that circadian variations in the tone of coronary vessels and endothelial function play an essential role in the onset of myocardial infarction. As myocardial infarction is significant medical stress, it causes increased cortisol levels in plasma [3]. In the acute phase of myocardial infarction, the phase of the circadian clock in the ischemic part of the heart differs from the non-ischemic part of the heart. The arrhythmia may occur because of the difference in the phase of the rhythm, or different expressions of the circadian clock genes. The loss of synchronization of the circadian rhythm between organs or tissues occurs more often than we would expect [4]. Circadian regulation of physiological processes is regulated locally. Peripheral tissue clocks control tissue-specific expression [27].
Homeostatic changes, gene expression changes, and external triggers can cause a stressful environment and cause damage to the atherosclerotic plaque in the coronary arteries in the morning, when prothrombin is increased [57]. Many intrinsic vasoactive and cardioactive substances, such as angiotensin II, melatonin, plasminogen activator inhibitor 1 (PAI-1), glucocorticoids, epinephrine, norepinephrine, and nitrogen oxide, show a specific circadian pattern. The fibrinolytic system, which regulates PAI-1, shows a circadian pattern of occurrence in both healthy patients and those with ischemic heart disease. The concentration and activity of PAI-1 depend on the circadian rhythm and are the highest in the morning [28]. CLIF (Cycle-Like Factor) expression in endothelial cells creates heterodimers with CLOCK protein, and binds to the E-box of the PAI-1 gene promoter and promotes its expression, while PER2 and CRY1 inhibit expression of PAI-1 by blocking heterodimer CLOCK-CLIF. CLIF controls the circadian rhythm of PAI-1 in endothelial cells, which might explain the higher incidence of myocardial infarction in the morning [26, 58]. As a result of this, the fibrinolytic system in patients with MI might be a potential goal for chronotherapy, to treat acute cardiovascular events. The circadian clock regulates the endothelial response to vascular injury. The main factor that can be affected by potential chronotherapy is PAI-1 because it is a crucial fibrinolysis inhibitor [59]. Chronotherapy includes the accurate timing of drug taking and can improve the therapeutic efficacy of the drug, while limiting its toxicity [41]. That is why many studies support chronotherapy for cardiovascular disease by limiting pathogenesis and improving treatment after the occurrence of acute cardiovascular events [59].
It is known that melatonin levels decrease during the night in coronary heart disease and infarction. Melatonin is an antioxidant that can inhibit the action of reactive oxygen radicals during heart ischemia. It also plays a vital role in regulating blood pressure, depending on the circadian rhythm. Animal studies have shown that animals with the pineal gland removed develop hypertension. Clinical examinations have shown that in patients with hypertension melatonin drugs taken daily before bedtime reduced blood pressure [3].
The appearance of myocardial infarction has two peaks during the day. The highest incidence of myocardial infarction is during the morning, and the second peak occurs late at night [60]. The beta blockers prevent increased sympathetic activity, catecholamine concentration, heart rate, blood pressure and lack of oxygen in the heart, and these are the physiological reasons for the existence of two peaks of myocardial infarction [57, 61].
Ischemia occurs in the morning due to increased oxygen demand, whereas in the evening it is due to decreased coronary blood flow. The appearance of myocardial infarction depends on ethnic origin, and the British differ from Asians in the frequency of the infarction [3]. In the Mediterranean, the highest incidence of myocardial infarction is between midday and midnight, while in the UK the highest incidence is between midnight and midday [62]. Numerous factors might affect the later occurrence of infarction in the Mediterranean, such as the number of sunlight hours, inequality in the prevalence of risk factors for cardiovascular disease, and the habit of afternoon rest or ‘siesta’ [63]. It has also been noted that the incidence of myocardial infarction is higher in the winter [3]. The specific circadian pattern of infarction symptoms has been observed, and the correlation of the circadian rhythm gene with the infarction investigated. The role of the molecular circadian clock in myocardial activity was initially investigated on animal models. It has been observed that the clock gene mutations of the circadian rhythm affect the heart rate, myocardial contractility, energy metabolism, which altogether leads to ischemia [64, 65]. In contrast, variants of the Per2 gene in mice reduce the severity of the injury after myocardial infarction because it does not only reduce inflammatory response, but also reduces apoptosis, induces cardiovascular hypertrophy, and thus preserves cardiac function [65].
Different variations of circadian rhythm genes are associated with many risk factors for cardiovascular disease. Thus, CLOCK gene variations are associated with metabolic syndrome in humans, type 2 diabetes, and some with stroke [64, 66, 67, 68], while CRY2 and PER2 gene variations are associated with myocardial infarction [69]. Expression of CRY1 and PER2 genes in fatty tissue is associated with metabolic syndrome in humans [64, 70]. Metabolic syndrome is a significant risk factor for cardiovascular disease and contributes to the common pathophysiological processes leading to the development of diabetes and cardiovascular diseases [48]. Atherosclerotic changes in blood vessels in patients with diabetes are more severe than those with normal glucose concentration [71]. It has been shown that the risk of cardiovascular disease in diabetic patients is two to three times higher than in healthy subjects [72]. Patients with diabetes usually have a higher heart rate in sleep and lower heart rate variability over the day than people without diabetes, which causes unnecessary oxygen consumption in the myocardium, with reduced nutritional blood supply. Biological and epidemiological studies suggest a direct link between lifestyle and metabolic disorders [12], although the genetic and biochemical linkage of human circadian rhythm with metabolic disorders has not been fully explored. Accordingly, the importance of the circadian rhythm in maintaining ‘energy’ homeostasis and metabolism is evident.
A peripheral clock is also found in cardiomyocytes, and the internal molecular mechanism of cardiomyocytes, such as the circadian clock, might contribute to cardiovascular disease [73]. Similar to SCN, cardiomyocytes have a circadian expression of clock genes in response to serum shock or norepinephrine. Several genes are associated with intracellular metabolism or physiological activity that has a circadian expression in cardiomyocytes [74]. After development, cardiomyocytes do not replicate, although they possess a meager and permanent rate of renewal. Cardiomyocytes renew cellular structure with their new proteins and membrane lipids every few weeks [75]. The ischemic precondition is an adaptation of cardiomyocytes to hypoxia, and once the heart has suffered an ischemic insult, cardiomyocytes become more resistant to MI because of PER2 and hypoxia inducible factor (HIF)-1a [74]. Circadian genes regulate a group of genes encoding for cardiac metabolic enzymes, and it is considered that a significant role of circadian genes in the heart is to synchronize cardiomyocyte metabolic activity with the availability of nutrients in the blood (i.e., feeding time) [29]. It is known that PER2 plays an essential role in carbohydrate metabolism during myocardial ischemia [76].
The cardiomyocyte circadian clock affects the daily variations in the heart. Studies show that the cardiomyocyte circadian clock affects myocardial contractions, the metabolism and gene expression. This clock is vital since impairment of the cardiomyocyte circadian clock might significantly alter cardiac function, cardiovascular disease pathogenesis, and treatment strategies for cardiovascular diseases (e.g., chronopharmacology) [77]. Desynchronization between different cell types (e.g., cardiomyocytes, vascular smooth muscle cells, endothelial cells) could occur within the organs (e.g. the heart) during certain physiological or pathological conditions [78]. The cardiomyocyte circadian clock allows the heart to predict circadian rhythm by extracellular stimuli, allowing rapid and temporally response [77]. The cardiomyocyte circadian clock has a crucial role in mediating the daily rhythm in myocardial metabolism and affects the cardiovascular function [79]. The cardiomyocyte circadian clock changes during illness, and this molecular mechanism might affect the etiology of cardiovascular disease [78].
Circadian rhythm adjusts the physiological functions of an individual on a daily basis. Daily variations of physiological parameters in the cardiovascular system maintain cardiovascular function according to the needs of different activities during the day. This information suggests that we need to know not only how, but also when to treat heart disease, and also to treat pathological changes not only symptomatically but to treat non-symptomatic but potentially harmful changes in the circadian rhythm.
Understanding the pathophysiological processes involved in the onset of myocardial infarction requires additional studies to assess the crucial elements of the circadian rhythm. In today’s personalized medicine, knowledge of the circadian rhythm (i.e., the genetic background) of an individual can be significant for treatment and should be included as an essential part of the diagnostic process.
Authors declare no conflict of interest.
Edited by Jan Oxholm Gordeladze, ISBN 978-953-51-3020-8, Print ISBN 978-953-51-3019-2, 336 pages,
\nPublisher: IntechOpen
\nChapters published March 22, 2017 under CC BY 3.0 license
\nDOI: 10.5772/61430
\nEdited Volume
This book serves as a comprehensive survey of the impact of vitamin K2 on cellular functions and organ systems, indicating that vitamin K2 plays an important role in the differentiation/preservation of various cell phenotypes and as a stimulator and/or mediator of interorgan cross talk. Vitamin K2 binds to the transcription factor SXR/PXR, thus acting like a hormone (very much in the same manner as vitamin A and vitamin D). Therefore, vitamin K2 affects a multitude of organ systems, and it is reckoned to be one positive factor in bringing about "longevity" to the human body, e.g., supporting the functions/health of different organ systems, as well as correcting the functioning or even "curing" ailments striking several organs in our body.
\\n\\nChapter 1 Introductory Chapter: Vitamin K2 by Jan Oxholm Gordeladze
\\n\\nChapter 2 Vitamin K, SXR, and GGCX by Kotaro Azuma and Satoshi Inoue
\\n\\nChapter 3 Vitamin K2 Rich Food Products by Muhammad Yasin, Masood Sadiq Butt and Aurang Zeb
\\n\\nChapter 4 Menaquinones, Bacteria, and Foods: Vitamin K2 in the Diet by Barbara Walther and Magali Chollet
\\n\\nChapter 5 The Impact of Vitamin K2 on Energy Metabolism by Mona Møller, Serena Tonstad, Tone Bathen and Jan Oxholm Gordeladze
\\n\\nChapter 6 Vitamin K2 and Bone Health by Niels Erik Frandsen and Jan Oxholm Gordeladze
\\n\\nChapter 7 Vitamin K2 and its Impact on Tooth Epigenetics by Jan Oxholm Gordeladze, Maria A. Landin, Gaute Floer Johnsen, Håvard Jostein Haugen and Harald Osmundsen
\\n\\nChapter 8 Anti-Inflammatory Actions of Vitamin K by Stephen J. Hodges, Andrew A. Pitsillides, Lars M. Ytrebø and Robin Soper
\\n\\nChapter 9 Vitamin K2: Implications for Cardiovascular Health in the Context of Plant-Based Diets, with Applications for Prostate Health by Michael S. Donaldson
\\n\\nChapter 11 Vitamin K2 Facilitating Inter-Organ Cross-Talk by Jan O. Gordeladze, Håvard J. Haugen, Gaute Floer Johnsen and Mona Møller
\\n\\nChapter 13 Medicinal Chemistry of Vitamin K Derivatives and Metabolites by Shinya Fujii and Hiroyuki Kagechika
\\n"}]'},components:[{type:"htmlEditorComponent",content:'This book serves as a comprehensive survey of the impact of vitamin K2 on cellular functions and organ systems, indicating that vitamin K2 plays an important role in the differentiation/preservation of various cell phenotypes and as a stimulator and/or mediator of interorgan cross talk. Vitamin K2 binds to the transcription factor SXR/PXR, thus acting like a hormone (very much in the same manner as vitamin A and vitamin D). Therefore, vitamin K2 affects a multitude of organ systems, and it is reckoned to be one positive factor in bringing about "longevity" to the human body, e.g., supporting the functions/health of different organ systems, as well as correcting the functioning or even "curing" ailments striking several organs in our body.
\n\nChapter 1 Introductory Chapter: Vitamin K2 by Jan Oxholm Gordeladze
\n\nChapter 2 Vitamin K, SXR, and GGCX by Kotaro Azuma and Satoshi Inoue
\n\nChapter 3 Vitamin K2 Rich Food Products by Muhammad Yasin, Masood Sadiq Butt and Aurang Zeb
\n\nChapter 4 Menaquinones, Bacteria, and Foods: Vitamin K2 in the Diet by Barbara Walther and Magali Chollet
\n\nChapter 5 The Impact of Vitamin K2 on Energy Metabolism by Mona Møller, Serena Tonstad, Tone Bathen and Jan Oxholm Gordeladze
\n\nChapter 6 Vitamin K2 and Bone Health by Niels Erik Frandsen and Jan Oxholm Gordeladze
\n\nChapter 7 Vitamin K2 and its Impact on Tooth Epigenetics by Jan Oxholm Gordeladze, Maria A. Landin, Gaute Floer Johnsen, Håvard Jostein Haugen and Harald Osmundsen
\n\nChapter 8 Anti-Inflammatory Actions of Vitamin K by Stephen J. Hodges, Andrew A. Pitsillides, Lars M. Ytrebø and Robin Soper
\n\nChapter 9 Vitamin K2: Implications for Cardiovascular Health in the Context of Plant-Based Diets, with Applications for Prostate Health by Michael S. Donaldson
\n\nChapter 11 Vitamin K2 Facilitating Inter-Organ Cross-Talk by Jan O. Gordeladze, Håvard J. Haugen, Gaute Floer Johnsen and Mona Møller
\n\nChapter 13 Medicinal Chemistry of Vitamin K Derivatives and Metabolites by Shinya Fujii and Hiroyuki Kagechika
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