\\n\\n
More than half of the publishers listed alongside IntechOpen (18 out of 30) are Social Science and Humanities publishers. IntechOpen is an exception to this as a leader in not only Open Access content but Open Access content across all scientific disciplines, including Physical Sciences, Engineering and Technology, Health Sciences, Life Science, and Social Sciences and Humanities.
\\n\\nOur breakdown of titles published demonstrates this with 47% PET, 31% HS, 18% LS, and 4% SSH books published.
\\n\\n“Even though ItechOpen has shown the potential of sci-tech books using an OA approach,” other publishers “have shown little interest in OA books.”
\\n\\nAdditionally, each book published by IntechOpen contains original content and research findings.
\\n\\nWe are honored to be among such prestigious publishers and we hope to continue to spearhead that growth in our quest to promote Open Access as a true pioneer in OA book publishing.
\\n\\n\\n\\n
\\n"}]',published:!0,mainMedia:null},components:[{type:"htmlEditorComponent",content:'
Simba Information has released its Open Access Book Publishing 2020 - 2024 report and has again identified IntechOpen as the world’s largest Open Access book publisher by title count.
\n\nSimba Information is a leading provider for market intelligence and forecasts in the media and publishing industry. The report, published every year, provides an overview and financial outlook for the global professional e-book publishing market.
\n\nIntechOpen, De Gruyter, and Frontiers are the largest OA book publishers by title count, with IntechOpen coming in at first place with 5,101 OA books published, a good 1,782 titles ahead of the nearest competitor.
\n\nSince the first Open Access Book Publishing report published in 2016, IntechOpen has held the top stop each year.
\n\n\n\nMore than half of the publishers listed alongside IntechOpen (18 out of 30) are Social Science and Humanities publishers. IntechOpen is an exception to this as a leader in not only Open Access content but Open Access content across all scientific disciplines, including Physical Sciences, Engineering and Technology, Health Sciences, Life Science, and Social Sciences and Humanities.
\n\nOur breakdown of titles published demonstrates this with 47% PET, 31% HS, 18% LS, and 4% SSH books published.
\n\n“Even though ItechOpen has shown the potential of sci-tech books using an OA approach,” other publishers “have shown little interest in OA books.”
\n\nAdditionally, each book published by IntechOpen contains original content and research findings.
\n\nWe are honored to be among such prestigious publishers and we hope to continue to spearhead that growth in our quest to promote Open Access as a true pioneer in OA book publishing.
\n\n\n\n
\n'}],latestNews:[{slug:"intechopen-maintains-position-as-the-world-s-largest-oa-book-publisher-20201218",title:"IntechOpen Maintains Position as the World’s Largest OA Book Publisher"},{slug:"all-intechopen-books-available-on-perlego-20201215",title:"All IntechOpen Books Available on Perlego"},{slug:"oiv-awards-recognizes-intechopen-s-editors-20201127",title:"OIV Awards Recognizes IntechOpen's Editors"},{slug:"intechopen-joins-crossref-s-initiative-for-open-abstracts-i4oa-to-boost-the-discovery-of-research-20201005",title:"IntechOpen joins Crossref's Initiative for Open Abstracts (I4OA) to Boost the Discovery of Research"},{slug:"intechopen-hits-milestone-5-000-open-access-books-published-20200908",title:"IntechOpen hits milestone: 5,000 Open Access books published!"},{slug:"intechopen-books-hosted-on-the-mathworks-book-program-20200819",title:"IntechOpen Books Hosted on the MathWorks Book Program"},{slug:"intechopen-s-chapter-awarded-the-guenther-von-pannewitz-preis-2020-20200715",title:"IntechOpen's Chapter Awarded the Günther-von-Pannewitz-Preis 2020"},{slug:"suf-and-intechopen-announce-collaboration-20200331",title:"SUF and IntechOpen Announce Collaboration"}]},book:{item:{type:"book",id:"1770",leadTitle:null,fullTitle:"Gel Electrophoresis - Principles and Basics",title:"Gel Electrophoresis",subtitle:"Principles and Basics",reviewType:"peer-reviewed",abstract:"Most will agree that gel electrophoresis is one of the basic pillars of molecular biology. This coined terminology covers a myriad of gel-based separation approaches that rely mainly on fractionating biomolecules under electrophoretic current based mainly on the molecular weight. In this book, the authors try to present simplified fundamentals of gel-based separation together with exemplarily applications of this versatile technique. We try to keep the contents of the book crisp and comprehensive, and hope that it will receive overwhelming interest and deliver benefits and valuable information to the readers.",isbn:null,printIsbn:"978-953-51-0458-2",pdfIsbn:"978-953-51-4309-3",doi:"10.5772/2205",price:139,priceEur:155,priceUsd:179,slug:"gel-electrophoresis-principles-and-basics",numberOfPages:378,isOpenForSubmission:!1,isInWos:1,hash:"279701f6c802cf02deef45103e0611ff",bookSignature:"Sameh Magdeldin",publishedDate:"April 4th 2012",coverURL:"https://cdn.intechopen.com/books/images_new/1770.jpg",numberOfDownloads:227344,numberOfWosCitations:103,numberOfCrossrefCitations:39,numberOfDimensionsCitations:118,hasAltmetrics:1,numberOfTotalCitations:260,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"May 26th 2011",dateEndSecondStepPublish:"June 23rd 2011",dateEndThirdStepPublish:"October 28th 2011",dateEndFourthStepPublish:"November 27th 2011",dateEndFifthStepPublish:"March 26th 2012",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6,8,9",editedByType:"Edited by",kuFlag:!1,editors:[{id:"123648",title:"Dr.",name:"Sameh",middleName:null,surname:"Magdeldin",slug:"sameh-magdeldin",fullName:"Sameh Magdeldin",profilePictureURL:"https://mts.intechopen.com/storage/users/123648/images/475_n.jpg",biography:"Sameh Magdeldin is senior researcher in the Medical School,\nNiigata University, Japan, and academic associate professor in\nthe Physiology Department, Suez Canal University (SCU), Egypt.\nHe received his M.V.Sc. and Ph.D. in Physiology and his second\nPh.D. in Proteomics in July 2012. He has expertise in shotgun proteomics analysis, reversed-phase chromatography and label-free comparative proteomics\napproaches. Dr. Magdeldin has published outstanding articles on aquaporin research using proteomics technology. He also created the outstanding “All and\nNone” methodology for analyzing large-throughput proteomics data published\nin a highly respected proteomics journal. He currently serves as a guest editor,\nassociate editor and peer reviewer for several international journals. Dr. Magdeldin received several grants and awards, such as the national encouraging prize,\n8th HUPO congress young investigator award, JSN award, grant-in-aid for young\nscientists and young researcher overseas grant from the Japan Society for the\nPromotion of Science (JSPS).",institutionString:null,position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"2",totalChapterViews:"0",totalEditedBooks:"5",institution:{name:"Niigata University",institutionURL:null,country:{name:"Japan"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"410",title:"Biotechnology",slug:"biochemistry-genetics-and-molecular-biology-microbiology-biotechnology"}],chapters:[{id:"35087",title:"Introduction to Agarose and Polyacrylamide Gel Electrophoresis Matrices with Respect to Their Detection Sensitivities",doi:"10.5772/38573",slug:"introduction-to-agarose-and-polyacrylamide-gel-electrophoresis-matrices-with-respect-to-their-detect",totalDownloads:31980,totalCrossrefCites:10,totalDimensionsCites:17,signatures:"Patricia Barril and Silvia Nates",downloadPdfUrl:"/chapter/pdf-download/35087",previewPdfUrl:"/chapter/pdf-preview/35087",authors:[{id:"118087",title:"Dr.",name:"Silvia",surname:"Nates",slug:"silvia-nates",fullName:"Silvia Nates"},{id:"118134",title:"Dr.",name:"Patricia",surname:"Barril",slug:"patricia-barril",fullName:"Patricia Barril"}],corrections:null},{id:"35088",title:"Gel-Electrophoresis and Its Applications",doi:"10.5772/38479",slug:"gel-electrophoresis-and-its-applications",totalDownloads:17184,totalCrossrefCites:2,totalDimensionsCites:4,signatures:"Pulimamidi Rabindra Reddy and Nomula Raju",downloadPdfUrl:"/chapter/pdf-download/35088",previewPdfUrl:"/chapter/pdf-preview/35088",authors:[{id:"117476",title:"Prof.",name:"Rabindra",surname:"Reddy",slug:"rabindra-reddy",fullName:"Rabindra Reddy"},{id:"118369",title:"Mr.",name:"Raju",surname:"Nomula",slug:"raju-nomula",fullName:"Raju Nomula"}],corrections:null},{id:"35089",title:"Principles of Nucleic Acid Separation by Agarose Gel Electrophoresis",doi:"10.5772/38654",slug:"principles-of-nucleic-acid-separation-by-agarose-gel-electrophoresis",totalDownloads:35382,totalCrossrefCites:4,totalDimensionsCites:10,signatures:"Muhittin Yılmaz, Cem Ozic and İlhami Gok",downloadPdfUrl:"/chapter/pdf-download/35089",previewPdfUrl:"/chapter/pdf-preview/35089",authors:[{id:"118546",title:"Dr.",name:"Muhitdin",surname:"Yilmaz",slug:"muhitdin-yilmaz",fullName:"Muhitdin Yilmaz"},{id:"143191",title:"Dr.",name:"Cem",surname:"Ozic",slug:"cem-ozic",fullName:"Cem Ozic"},{id:"143193",title:"PhD.",name:"İlhami",surname:"Gok",slug:"ilhami-gok",fullName:"İlhami Gok"}],corrections:null},{id:"35090",title:"Discriminatory Power of Agarose Gel Electrophoresis in DNA Fragments Analysis",doi:"10.5772/36891",slug:"discriminatory-power-of-agarose-gel-electrophoresis-in-dna-fragment-analysis",totalDownloads:31746,totalCrossrefCites:2,totalDimensionsCites:2,signatures:"Seow Ven Lee and Abdul Rani Bahaman",downloadPdfUrl:"/chapter/pdf-download/35090",previewPdfUrl:"/chapter/pdf-preview/35090",authors:[{id:"110308",title:"Dr.",name:"Seow Ven",surname:"Lee",slug:"seow-ven-lee",fullName:"Seow Ven Lee"}],corrections:null},{id:"35091",title:"Gel Electrophoresis of Proteins",doi:"10.5772/37514",slug:"gel-electrophoresis-of-proteins",totalDownloads:10408,totalCrossrefCites:1,totalDimensionsCites:2,signatures:"Laura García-Descalzo, Eva García-López, Alberto Alcázar, Fernando Baquero and Cristina Cid",downloadPdfUrl:"/chapter/pdf-download/35091",previewPdfUrl:"/chapter/pdf-preview/35091",authors:[{id:"113044",title:"Dr.",name:"Cristina",surname:"Cid",slug:"cristina-cid",fullName:"Cristina Cid"},{id:"138425",title:"Dr.",name:"Fernando",surname:"Baquero",slug:"fernando-baquero",fullName:"Fernando Baquero"},{id:"138426",title:"Dr.",name:"Laura",surname:"Garcia-Descalzo",slug:"laura-garcia-descalzo",fullName:"Laura Garcia-Descalzo"},{id:"138427",title:"Dr.",name:"Eva",surname:"Garcia-Lopez",slug:"eva-garcia-lopez",fullName:"Eva Garcia-Lopez"},{id:"138428",title:"Dr.",name:"Alberto",surname:"Alcazar",slug:"alberto-alcazar",fullName:"Alberto Alcazar"}],corrections:null},{id:"35092",title:"Gel Electrophoresis of Protein - From Basic Science to Practical Approach",doi:"10.5772/38062",slug:"gel-electrophoresis-of-protein-from-basic-science-to-practical-approach",totalDownloads:6268,totalCrossrefCites:0,totalDimensionsCites:1,signatures:"Gholamreza Kavoosi and Susan K. 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Derived from the Greek word, ἐμβολισμός, this term most literally means “interposition.” Yet, regardless of how benign this etymological derivation may appear, the clinical context is quite the opposite—a symbol of much dreaded morbidity and mortality. Whether the embolus consists of a blood clot, a fat globule, a bubble of gas, amniotic fluid, or even an iatrogenic or traumatic foreign body, the unfavorable connotations persist even if the patient has few or no associated symptoms and requires no intervention.The primary goal of this book is to provide the reader with an overview of the most common types of embolic phenomena encountered in clinical practice, including some of the key related diagnostic and therapeutic considerations. 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For a long time, before using electronic devices of navigation, sailors used to check their progresses using points of interest (POIs) as marks of their journey. These were particular points rich in information (a cape, an island ….) allowing the sailors to reduce uncertainty about its position. This is a typically cognitive process which allowed the sailors to mark out their route and see how they were progressing. Metaphorically, the term may be used in the study of decision-making to describe the cognitive work of the decision maker watching out for indications to ensure that his line of thought progresses in such a way as to enable him to make a final choice: that of deciding the course of action to be embarked upon.1
This chapter sets out to analyse several strategies or several models drawn up to give an insight into the decision-making process which, by definition (since several choices are possible), always takes place in a context of uncertainty. A large part of the cognitive activity of the decision maker is directed at lessening this, by processing the information available in various ways. It is structured in four parts. The first part presents decision-making as a form of conduct and behaviour, so enabling it to be studied from the point of view of psychology. The second part, for the benefit of readers who are unfamiliar with these questions, analyses two commonly used decision-making models which, notwithstanding their differences, have this much in common: they make it possible to give an account of individual decisions. The third part, in a more innovative way, undertakes to study a very particular type of super-individual decision that concerning groups of human beings exposed to risk situations. How do those responsible for safety, whatever their particular role, take their decisions to avoid the generalisation of harmful consequences? Their ways of approach, very different from individual strategies, open up new perspectives. Situations like this have two advantages for researchers: (1) substantive (i.e. do the actions carried out lead to satisfactory responses to the critical case?); (2) epistemological (i.e. how does one represent or conceptualise these situations?). The fourth part attempts to analyse the consequences of a development of this kind. The epistemological questions they give rise to are so important that they radically change the traditional decision-making models. This being so, there is a need for a changed paradigm amounting to no less than a “scientific revolution” of the kind described in Kuhn’s famous work.
For psychologists, more than just behaviour—a term which might suggest a certain automatism of response—decision-making is a specific form of conduct. First of all, the choice of this term underlines the fact that such processes must not be reduced to the extremely visible and observable aspects of the explicit choice of one course of action in preference to other (often many other) possible ones. Secondly, it introduces a constructivist option. The decision is constructed progressively and that which marks its culmination (the choice of the course of action to be embarked upon) is necessarily preceded and justified (sometimes in an approximate or erroneous way) by phases implying cognitive information-processing activities (perception, attention, memory, etc.) which “explain” the choice arrived at. Decision-making is also a process which presupposes freedom of choice, which is defined in time and consists of several stages. The two principal operations are the search for information and the assessment of its importance, which we will call weighting.
One of the best known definitions of the entire process of decision-making is that of MacCrimmon [1], characterised by the accumulation of stages identified in his account of the subject. A decision maker “observes a gap between an existing state and a desired state and has the motivation as well as the potential to reduce this gap, while more than one possibility of action exists which may not be immediately available, a kind of action requiring an irreversible allocation of resources [cognitive in this case], and while the benefits [consequences] associated with each choice are completely uncertain” [1]. Each choice consists, according to him, of resolving a problem (MacCrimmon uses the expression “decision problem”).
A definition is rarely neutral, and this one, formulated with members of the managerial class in mind, is characterised by a series of operations to be carried out successively, therefore presupposing the existence of a (meta-) process of control and integration, and of verification by retrospective loops, not mentioned in the formulation but nonetheless indispensable to ensure the validity of the whole construct.
It is not surprising that MacCrimmon’s definition does not totally suit psychologists who are more interested in the previous stage: knowledge of the mental processes and the choice of the strategies planned by the decision makers. Among them, there are some who will criticise this definition for being too segmental, cumulative and prescriptive, and for its failure to give a more important place to the conditions of the time (in economics), the physical environment of the time (in the determination of risk-management strategies), social dimensions (judicial decisions), the pressures of the world of the time (political decisions) which have a determining influence on choices. Strictly focused on rationality, a definition of this kind leaves little room for motivation, sensitivity, desire, emotions, not to mention pleasure, and so on.
We will consider two principles as being justified both by the evidence and by observations so that the analytic processes may continue to have an acceptable level of general applicability. Decision-making takes place: (1) in an environment or context which is an integral part of the problem but of which the role is too often minimised if not totally hidden; (2) epistemologically, decision-making is constructivist in nature, which means that it progressively develops and becomes more refined on the basis of representations of the world which become all the more operative as the occasions multiply and the information becomes more diverse. Decision-making in this perspective is therefore an illustrative example of a type of conduct resulting from the putting into play of dynamic processes [2].
We owe the introduction of the topological dimension in decision-making to Lewin (1890–1947) and his field theory [3, 4]. The characteristics present in the field are a component to be taken into consideration, and this leads to a very broad view of the decision which cannot be limited to dealing with certain intangible visible indications or to reproducing learning processes. In elaborating any concrete decision, the information is extracted from a context, and some of this information, according to its nature or intensity, will be accepted as valid by the decision maker on a cognitive basis. Each piece of information used must be assessed in accordance with the context and, where applicable, with the framework in which it happens to be inserted [5]; these two characteristics give it a “salience” [6] of variable intensity. As Lewin has shown, the field which contains all these pieces is not homogenous; it has hills or rough areas which are characteristic points because they are the cause of certain dynamisms.
With regard to decision-making, the two most well-known models (among the various existing) are summarised here: that of the economic decision and that of the behavioural decision [7].
Economics was the first discipline to formalise decision-making in the full meaning of the term, that is, by establishing a binding axiomatised system [8]. We shall limit ourselves here to indicate in a summary way the salient elements of a branch of study which is still extremely active. The economist’s problem consists of assessing among n mutually exclusive actions {a1…….an} that will give the greatest satisfaction in a given situation, on the one hand, and to a specified decision maker, on the other hand. Therefore, the objective consists of ordering the outcomes (1) according to the preferences of the decision maker (a3 > a8 > a1, etc.). To do this, the decision maker constructs a “decision tree” containing “routes” and “stages” (called knots) which represent possible pathways to be followed. At each knot, the decision maker must opt for a way which will bring him to the next stage and so on to the end (to the “leaves”) which indicates the expected consequences of each action. (For a more complete presentation, see [7] Chapter 2). Each of the end points is evaluated numerically taking its frequency into account [assessment of the probability (p) that it will take place taking uncertainty into account] and the subjective value (i.e. for the decision maker concerned) of the utility u of the consequences attached to it. It should be noted that, even though the context is that of economics, the consequences are not determined in monetary amounts (objective references) but in subjective units of utility (u) [the satisfaction it can afford]. The value attached to the same sum of money varies in fact according to the individual fortune already possessed so that utility is a more general reference than monetary value. The two indices are combined in a multiplied form, that is, p*u. The outcome (leaf) which has the highest p*u numerical value is that deemed to constitute the best consequence. Climbing the tree in reverse therefore makes it possible to determine the “best” action to be executed. This model, known as subjective expected utility (SEU), therefore refers to a numerical validation criterion ultimately obtained by the observance of axiomatic properties.
Psychology was the second discipline to set itself the task of modelling decision-making. Although it took the preceding concepts as a basis, this school of thought has led to a very different model form. In 1953–1954, the psychologist Ward Edwards [9, 10], applying the validation methods used in psychology, in particular predictive validity, installed a team of researchers in a Las Vegas casino to study the decision-making of professional players. These persons who live off gambling takings consequently on decisions made in a context defined clearly by rules (those of the game) but where chance also plays a part represented an appropriate sample of decision makers who have, in a short time to decide and to assume the effects of their choices. The initial objective of the team of psychologists was to verify the SEU theory, but it became apparent that the players’ decisions were not based on any of the axiomatic elements necessary for the determination of p*q and consequently were not related to the SEU criterion. The decisions taken were based on behavioural information processing in which knowledge, learning and intuition seemed to play an important role. A new investigational pathway was therefore opened up under the name of Behavioural Decision-Making (BDT) [11].
Very soon, Simon [12] underlined the fundamental differences existing between these two conceptions of decision-making, that of economics, which is axiomatic and organised with a view to attaining an end (maximise p*u), and that of psychology, which also identifies an objective to be achieved but sets out to achieve it in a procedural way (implement relevant information-processing procedures). These procedures, which would later be called cognitive, were to lead to new modelling forms [13] used even in economics with behavioural economics [14]. The frontiers between the disciplines had therefore become permeable, a very welcome development.
Schematically, the decision-making process consists of transforming all kinds of semantic units present at the mechanism entry point into behavioural forms of action choosing which mark the outcome of the process. Between these two extreme points, there is an organised network of information which will undergo processing. Seen from the topological point of view only, the decision consists of processing an intermediate system which is a generalisation of the notion of intermediate variable (or intervening variable or mediating variable) often used in psychology and defined as “a hypothetical variable postulated to account for the way in which a set of independent variables control a set of dependent variables”.2 The notion of an intermediate system is nothing other than the generalisation of that of the intermediate variable with the retention of the epistemological notions of postulated and hypothetical entities (based on the decision maker’s knowledge), on the one hand, and causality, on the other hand (i.e. the incoming variables influence the outgoing ones and so produce effects). Functionally, this intermediate system, which from the methodological point of view is a construct, constitutes a reserve of informational resources organised in the form of networks or “dormant” information clusters. When judiciously activated by the decision maker, these networks make more effective decision-making possible.
This is demonstrated by work in the area of Management Science on the complex entities constituted by enterprises in which the “right” decisions make it possible to achieve competitive advantages and the blossoming of the company. It has been shown in [15] that the management of an intermediate system in American small and medium enterprises (SME) enables this enviable objective to be achieved. At this point in our account, we may consider the decision maker as an agent who picks and processes information from a system at a half-way point between perception and action, a kind of reservoir holding pertinent indications drowned in a mass of information items most of which have no causal relationship with the question under consideration. Such a task can only be difficult.
There are many works dealing with the difficulties, mistakes, false ideas, shortcuts and approximations affecting the action choices of decision makers [6, 13, 16], leading them to making poor-quality decisions. Therefore, as not to over-encumber this account, we will not list all these but rather classify them under three headings: structural difficulties, information-picking difficulties and processing difficulties, each category being illustrated by a single commentary.
Structural difficulties are those corresponding to inaccurate or erroneous mental representations of the global organisation of the intermediate system, more often than not implicitly considered as being simpler than it is in reality. This is the case when the decision maker (cognitively) elaborates a decision tree which is not exhaustive and when (in the actual situation) he finds himself confronted with the task of implementing real eventualities but ones not forming part of the initial plan. The decision tree has two functions, one to classify, and the other to predict. Used principally in Economics and Biology [17], it is the forerunner of classification algorithms and has a predictive value with regard to the choice of action, for any new observation.
Information-picking difficulties are frequent. The information items of use for decision-making are not, in real situations, isolated and salient as they might be in a laboratory experiment. To use them, the decision maker is obliged to search for them on the basis of their salience (or saliency), which therefore entails the necessity of a prior mental representation. Salience is a function of the purposes assigned to the action. The point is to pick salient information for a very specific decision and not to decide by using the most obtrusive (visible) elements in a given field. This latter strategy leads to a decision bias called salience bias [6, 7, 8, 9, 10, 11, 12, 13] consisting of processing extremely visible information items but ones not relevant to the question under consideration.
Processing difficulties become sensitive at the junctions of the different cognitive operations implemented in succession to determine the action chosen. Three principal difficulties become evident: (1) the very poor cognitive capacities of human beings in assessing and processing uncertainty, an unavoidable element in decision-making situations. Seen as disconcerting and subversive, it is often excluded from the process, something which leads to an “over-confidence” bias [6]. This bias is noticeable in the assessment of risks (generally under-estimated) quite as much as, in the opposite direction the possibility (overestimated) of winning the jackpot in the lottery.
The decisions presented in the preceding sections are characterised by having been taken in a stable, defined informational context, that is, invariable throughout cognitive processing and ending in the choice of a single action, a behaviour marking the end, satisfactory more often than not, of processing operations. These situations are modelled on a limited number of variables, the pertinence of which is based on laboratory studies, sometimes of an experimental kind, but which have always undergone epistemological reductionism [18] guaranteeing their permanence and high level of general applicability. All other variables, particular or inconstant, are removed from the model.
There are decisions of another kind, which one could describe as super-individual as they concern at one and the same time a great number of persons, which must be taken in very different conditions. They cannot be processed in a laboratory nor reduced to a few variables, so they must be considered as global in nature and their complexity must be taken into account. Unlike the laboratory strategy where variables are isolated, the entity being studied can only be seen in a global way and cannot be reduced epistemologically without distortions. Another distinctive feature: the entities under study become modified under the influence of the processing operations, giving rise to a temporal dimension (evolution capacity) and a high degree of lability in the choice of “active” variables liable to be used in taking the decision. In such cases, therefore, momentary characteristics are what one is trying to define.
One of the examples (and a very recurrent one in the summer period) which best illustrates this conjunction of complexity and dynamism can be found in the management of forest fires. These phenomena give rise to management difficulties linked to the difficulty of anticipating developments (uncertainty) and the unstable components of the fire (changes in intensity and direction). The decisions regarding the actions to be taken to contain and manage the fire and extinguish the flames are very difficult cognitively. A new element has been introduced into the situation: that of the interactions at all levels between different variables; interactions of a kind and extent which develop with time, the progress of the event and the measures undertaken at the previous stages by the action teams. The intensity of the wind, its direction, the degree of dryness of the ground, the nature of the forests, and so on determine the characteristics of the fire and the way it will develop. The interpretation in substantive terms (i.e. in terms of the present situation) of the interactions is cognitively difficult, and the decisions taken as a consequence may be qualitatively poor [19].
The finding of identical difficulties in very different contexts (political, legal, economic, environmental, technological decisions, etc.) where human beings perform poorly must lead one to consider the various perspectives applied to studies on decision-making. The necessary and legitimate search for the most efficient action to solve a problem, as discussed by MacCrimmon, has led researchers to design research plans inspired by the exact sciences (e.g. physics and chemistry) or disciplines, such as biology, which verify their hypotheses concerning certain very specific variables, in an appropriate place perfectly protected against external influences: the laboratory. The history of Science, in its present state, shows in fact that for certain situations (but not all), such a choice produces the safest information. Such an approach, while being perfectly scientific, cannot be implemented in a generalised way to all the psychological problems of decision-making. Certain very recent decisions, such as those concerning climate change (cf. Section 5.1) or the management of industrial or ecological disasters, cannot usefully be subjected to epistemological reduction, a crucial process in laboratory studies. In other words, it is no longer possible to isolate certain variables and manipulate them to verify their causal status.
Must one then search for other scientific approaches? If so, there will have to be a turnaround in epistemology too. The phenomena under review will have to be assessed as global entities (holistic option), to be considered in their natural state rather than in a laboratory, in the conditions in which they actually occur, and if possible in statu nascendi (at the moment in which they occur). The management of maritime disasters with the threat of pollution require urgent decisions. These two recommendations are in line with the principles defined by Gestalt psychology in the first half of the twentieth century [3]. These were advanced over and over again at the time but could never be measured or assessed for want of methodological options other than experimentation. The epistemological change which will make it possible, in part, to overcome this difficulty consists of conceptualising the situation being studied as a dynamic complex system.
In 1968, the biologist Ludwig von Bertalanffy (1901–1972) published a work in which he presented the notion of a “system” as a very extensive holistic entity [20]. “Systems everywhere around us,” he observed. Only the analytical traditions inherited from previous centuries prevent us from seeing them and approaching research questions by including this aspect of globality rather than destroying it at the outset by concentrating on certain variables.
This original contribution, which highlights the potential richness of the systemic way of thinking, has been completed by the work of Cilliers on the functioning of systems [21] and on the epistemological characteristics arising out of them [22]. For this author, a complex system is an entity presenting ten specific characteristics [21]. Among the most important, we would instance the presence of numerous interacting variables where the interactions are not linear. This means that proportionality is no longer the rule so that even a very small variation introduced into the system may have major effects when exiting. This corresponds to the case found in 1972 by the meteorologist Lorenz known as the “butterfly effect”, thus opening the way to new forms of non-Newtonian determinism.
Let us also consider certain characteristics of the system itself, independent of the decision maker who can only take note of them and include them in his decision. The system has a history, it is composed of networks which reflect it, it has resources available to it which in the absence of human intervention determine its “behaviour”, it is usually open to the environment, has self-organisation capacities and can regulate itself because of the existence of control loops. One could say that it is endowed with an “epistemological personality”, so that the decision maker is first of all an analyst and a manager of both the resources of and directions taken by the system, before being able to choose the appropriate action.
Up to the present day, very wide sectors of scientific psychology have chosen to apply the experimental paradigm in their research practices as a guarantee of the validity and replicability of their conclusions. This is, of course, not an erroneous choice, but it has now become apparent that its application is impossible in certain situations where nonetheless the intervention of psychologists is required.
The most illustrative case of conceptualising psychological issues in terms of complex systems is that of climate change. Climate is a complex system, it possesses all the properties defined in [21] characterising this type of organisation. The global state of the system depends on multiple interacting variables most of which are nonlinear, climate evolves, “integrates” characteristics which cause it to organise itself, to change its “behaviour” and global configuration. Among these factors for change, the production of carbon dioxide by human beings is one of the best identified factors (even if still the subject of ideological disputes) in global warming. Although human beings have no variable available to them which would enable them to act directly (as would an independent variable) to limit the harmful effects of global warming as required, they must nonetheless take decisions to influence its future course, and with regard to this, the contributions of psychologists are welcome.
The very well-known American Psychological Association (APA) has set up a task force which in 2008–2009 worked on the problem of “global climate change” and all its individual and collective psychological consequences. The objective was therefore much broader than decision-making, as is shown in the final report on the work of this commission which appeared in a special number of the American Psychologist [23]. Questions concerning the forecasting of the development of climate and the perception of risks are considered but, although it underlies many points in this work, the complex system notion is not explicitly mentioned. The phrase “addressing a multi-faceted phenomenon and a set of challenges” present in the title is, however, entirely consistent with the spirit of complex systems.
Putting psychological objects into perspective by reference to complex systems opens up the way to a new paradigm. The old experimental-type paradigm, as we have seen, cannot account for certain important decisions. The new paradigm must enable a better understanding of them. It would seem that we are at present on the threshold of a “scientific revolution” [24, 25] made all the more apparent by this necessary change.
A paradigm is defined as “a philosophical and theoretical framework of a scientific school or discipline within which theories, laws and generalisations and the experience performed in support of them are formulated”.3 The function of a paradigm, as this definition highlights, consists of ensuring the required coherence of the research approach and verifying the compatibility between the different components necessary for scientific knowledge (the hypotheses, the data observed, the methodological tools applied to process them and the theories constructed on the basis of the results, respectively). A paradigm is the overall structure containing compatible entities.
As emphasised in [21], thinking in terms of complex systems implies avoiding the “reductionism” linked to the initial choice of certain variables forming part of a greater complex. In the experimental paradigm, only those initially considered relevant will be used and where applicable verified. This choice being initial, even if supported by hypotheses and observations, is a determining factor in the construction of knowledge. In addition, the said variables are tested in an isolated way one from the other and then put into use “artificially” outside their natural environment. This procedure eliminates from the field the knowledge produced by a great number of interactions, which could prove decisive. The paradigm of complex systems is a complete change of perspective. The decisions studied with a view to their consequences are studied globally, on the ground, in their natural environment and in specific circumstances. The importance of the results obtained is a function of the activity of networks which, as for the nervous system, become observation “units.”
This approach does not set out to establish general conclusions (conclusions applicable in all circumstances) regarding decision-making, since to do this, it would be necessary to ignore many specific items of information, which exist and are active in the specific situation to be dealt with and which in fact are often decisive in the taking the decision.
How should one assess, measure, or quantify the activity of a complex system with a view to predicting its development and being able to decide accordingly? Physicists, the first to deal with this question when it had to be answered in their discipline, refer to the laws of thermodynamics (particularly the second law) regarding energy. This energy dimension, present in all systems, makes comparisons possible by calculating, for each system, its level of entropy. The size of the latter was for a long time interpreted as a degree of disorder, but, unlike in the experimental approaches which scrupulously avoid it, systemic disorder can here have a positive connotation. It is considered as a possible generator of further states differing one from the other while order, once it has been determined, is immutable and results in one state only.
The transposing of the laws of thermodynamics into psychology has made it possible to highlight their relevance but at a meta-psychological level: that of the global psychological development of human beings [25] and this direction is too general to characterise a particular system. Researchers should therefore direct their efforts to looking for multiple indicators. Since this work has been published, the needs for identifying patterns of information have been emphasised as a heuristic way to manage complex systems [26]. For instance, artificial intelligence and human cognition (“humanised computing”) are articulated to create tools either for treating psychological disorders [27] or allowing recognition of psychological entities (emotions) using non-linear relationships [28].
The educational system as a vector of knowledge and the diversity of the contributions it makes to different pupils is an example of the differentiated functioning of a complex system, which produces measurable effects, satisfactory or otherwise. How should such a system be characterised based on the observable results it provides? In particular, when a country applies one and the same generalised system to pupils belonging to different cultures (so-called “minority” groups), what can be said of the performance of the system where total assimilation on the one hand and extreme diversification on the other hand must both be considered as mistakes? The functioning of the educational system of Chile with regard to a “minority” group with a strong attachment to its land, culture and identity (the Mapuche) was studied in an initial contribution [29]. This highlights the importance of teachers possessing the two cognitive registers (that of the “minority” concerned and that of the “majority”). Considered more globally, this conclusion illustrates the arguments advanced above on the management of the intermediate system (cf. Section 3.3).
A second contribution [30] deals with the use of icons to assess how a system (school system in this case) functions with regard to the different demands represented by different groups of pupils. The term icon was chosen to stand for homogenous configurations of information which appear at the “surface” of the system and which indicate how it functions with regard to the diverse needs of users. Let us suppose, for example, that one of these icons includes several items of information signalling a lack of mastery of the written language, the decision maker, after analysis, can then proceed to choosing the action most suitable for the sub-groups concerned.
The fact that these icons are products of the systems and not just observations or perceptions differentiates them from the normal function of icons, which is pictorial in kind. Systemic icons, it is true, also “represent” but, as they are produced functionally, they do much more than this and can justifiably be described as cognitive icons as they enable knowledge. In short, while physicists referred to the energy of systems in order to differentiate them, the Human Sciences refer to cognition as a global act making it possible to assign significance to sub-sets of information (icons) which therefore draw their significance from the totality of the system while at the same time participating in it.
Changes in society today are leading psychologists to deal with the management of complex situations which are very different from those that traditionally formed part of their area of activity. Two major developments characterise contemporary psychology: (1) new fields of activity (perception of risks, management of disasters or traumatic events, climate change, etc. (2) The importance of a global reference both in the definition of the phenomena studied and at the level of the people who find themselves involved (often large groups of the population). These changes must logically lead to an adaptation of the research and intervention strategies because the experimental method, so useful in the study of certain problems, is no longer applicable while the reliability it provided with regard to its conclusions still remains an imperative.
This chapter has attempted to present a difficult but promising approach: that of the use of dynamic complex systems to construct adaptable, appropriate, and evolutive decisions. It emphasises the necessity, once certain situations have presented themselves, of a change of paradigm so that complexity is recognised as a component in research as it already is in the forms of conduct being studied, rather than being somewhat ineptly eliminated from the start. Epistemological and methodological advances are necessary in order to develop the paradigm of complex systems in psychology, a paradigm which is already a reference in other branches of the human sciences.
As the typical 1D carbon materials, carbon nanotubes (CNTs) (Figure 1a) and carbon nanofibers (CNFs) have been widely investigated in the past two decades because of their merits, such as outstanding mechanical strength, large surface-to-volume ratio, and extraordinary electrical conductivity [1, 2, 3, 4]. At the same time, graphene (Figure 1b), a recently discovered 2D sp2 carbon, displays outstanding physical and chemical properties such as high specific surface areas (about 2620 m2 g−1), great lightweight, and fast electron transport kinetics [5, 6, 7]. Nevertheless, their physical and chemical performances inevitably decrease compared to the theoretical prediction result from the existence of the van der Waals interaction, generating easy self-aggregation and stacking during the synthesis process [8]. Therefore, the 3D nanocarbon hybrids (such as CNT/graphene, CNF/graphene, CNT/CNF hybrids) are studied by a large number of the research groups, aiming at overcoming these shortcomings and a synergistic integration of their inherent properties in the new hybrid materials [9, 10, 11]. These nanocarbon hybrids have an interconnected network of carbon structure, resulting in a synergistic effect in enhanced conductivity in comparison with the individual components, and the special 3D structure significantly provides a variety of applications, such as field-effect transistors [12, 13], electron field emitters [14, 15, 16], sensors [17, 18, 19, 20], fuel cell [21, 22, 23], batteries [24, 25], and supercapacitors [26, 27, 28, 29, 30].
Schematic diagrams of graphene and carbon nanotube.
To date, a number of techniques and methods have been utilized for the fabrication of nanocarbon hybrid, such as mixing process of surface-treated carbon materials (including solution processing [31, 32], vacuum filtration [33, 34], layer-by-layer self-assembly method [35, 36]), hydrothermal method [37], multi-step approaches using combinations of decorated carbon materials and CVD [10], and multi-step and one-step chemical vapor deposition [38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48]. Among all the nanocarbon hybrid fabrication approaches reported, CVD techniques are considered as the most versatile and promising way for nanocarbon composite production with reasonable structure and mechanical strength, which has attracted tremendous research attention during the recent decades. As a sophisticated synthesis method for both laboratory research and industry production, conventional CVD (shown in Figure 2) is applied in many areas, such as thin-film coating, crystal growth, and powder production and also suitable for the synthesis of nanocarbon materials. The mechanism of conventional CVD generally includes two steps, initially thermal decomposition of gaseous precursor [10], organic solvents [47], or solid feedstock [9, 28] and thereafter reassembly of carbon atoms into sp2 carbon nanostructures under the effective catalysis such as Cu [8], Fe [12], Co [28, 44], Ni [24], or their mixture [11, 49] at high temperature. Compared with other approaches, CVD technique significantly fabricated well-interconnected three-dimensional nanocarbon materials without needing sophisticated chemical routes with solvents and highly toxic agents during synthesis process. Zhu et al. [50] reported that the seamless, covalently bonded three-dimensional nanocarbon architecture was fabricated on the surface of Cu foil via simple two-step CVD methods. It is worth noting that although different aforementioned methods are employed for the production of nanocarbon hybrids, a facile and simple approach for controllable growth of three-dimensional carbonaceous nanomaterials is still a big challenge.
Schematic diagrams of CVD technique.
In this chapter, we present a summary of the researches about nanocarbon hybrid in recent years, with a focus on the popular fabrication techniques. Moreover, the merits and demerits and effect of experimental parameters of these CVD methods are presented in detail. Finally, we discuss the development trend, challenges, and performance applications of nanocarbon hybrids in the further.
Up to now, varied approaches have been used for the fabrication of 3D nanocarbon hybrids, and the preparation technology generally could be categorized into four different approaches (shown in Figure 3): mixing process of surface-treated carbon materials, hydrothermal method, multi-step approaches using combinations of decorated carbon materials and CVD, and multi-step and one-step chemical vapor deposition. In addition, early researches on the construction of 3D hybrids focus on mixing process, which includes solution processing, vacuum filtration, and layer-by-layer self-assembly methods. Compared to other methods, hydrothermal route is an appropriate way to the mass preparation of graphene-carbon nanotube hybrids because of the easy operation and mild experimental environment. Moreover, the composites consisted of carbon nanotube and carbon nanofiber mainly produced by utilizing the multi-step approaches using combinations of decorated carbon materials and CVD method. Especially, multi-step and one-step chemical vapor deposition is considered as a simple and promising way to build 3D hybrids with hierarchical structure and stability.
Classification of 3D nanocarbon hybrids synthesis techniques.
As the early hybridization approaches, solution processing, vacuum filtration, layer-by-layer self-assembly methods, and so on could be classified into the facile mixing process. Altogether 1D carbon nanomaterial incorporation of 2D nanomaterial with a facile mixing process exhibits a synergistic effect in enhanced properties. However, the nanocarbon hybrids are synthesized by utilizing various methods to mix modified carbon-based feedstocks, which generally need sophisticated chemical routes with solvents and highly toxic agents [31, 33, 34, 35, 36]. Furthermore, this kind of techniques suffers from poor controllability, leading to the restriction of practical application due to the aggregation and stacking of carbon-based materials [51].
With regard to hydrothermal method, firstly, the carbon feedstocks are dissolved and the mixed solution is transferred into a heating instrument. Secondly, the hydrothermal treatment is performed at low temperature, and the final product is obtained after centrifugation, washing, and freeze-drying process. Although this method has merits of mild conditions and scale-up synthesis, it is not suitable for the industrial production due to the time-consuming fault and defective products. Besides, the obtained 3D nanostructures are chiefly based on weak interconnection between individual nanocarbon components instead of owning powerful bonding, leading to robust 3D architecture [52].
Chemical vapor deposition is considered as the most promising approach of the preparation of graphene, CNTs, and CNFs on the substrate surface. Thus, it is always employed to facilitate the growth of CNTs on the decorated carbon materials, leading to the 3D hierarchical composite. For example, most of the reported 3D carbon nanotube/carbon nanofiber hierarchical composites are typically prepared by a multi-step route, which first needs electrospinning technique and post-carbonization for the preparation of CNFs, followed by decorating the CNFs with metal catalyst nanoparticles, and eventually the CNT growth is promoted by using toxic organic gases or solvent as carbon source during the CVD process [10, 22]. This kind of CVD-based methods has distinctive advantages: efficiency, convenience, and high yield. However, the stable and suitable decorated carbon materials that always need sophisticated pretreatment are vital to the construction of 3D carbon hybrids.
Multi-step chemical vapor depositions have been utilized in recent years to integrate individual 1D with 2D carbon nanomaterials to achieve controllable configurations of 3D nanostructures. Recently, Tang et al. successfully fabricated graphene-carbon nanotube composite on exfoliated vermiculite (EV) substrate by the multi-step CVD method (as shown in Figure 4). The whole CVD process could be divided into two steps: firstly, the aligned CNTs are synthesized at 650°C by using C2H4 as carbon source, and, secondly, the uniform graphene sheet directly grows on the surface of substrate at a higher temperature of 950°C by utilizing the hydrocarbon—CH4, resulting in the in situ synthesis of graphene-carbon nanotube-graphene sandwiches [53]. In other methods of the successful fabrication of 3D hybrids, the obtained component materials are always entangled with each other, and the ordered 3D packing architecture is hardly available. Nevertheless, this multi-step way successfully integrates low-dimensional materials into 3D ordered, controllable, and well-connected structures [50]. Additionally, the morphology and nanostructure could be well controlled by adjusting the experimental parameters due to the separated CVD processes. It is a pity that the multi-step process always requires strict growth conditions and large consumption of power (high temperature) for the growth of nanocarbon materials.
Scheme for the two-step CVD synthesis of graphene/carbon nanotubes hybrids.
Recently, tremendous efforts have been made to produce 3D nanocarbon hybrid via simultaneously in situ growing of 1D and 2D carbon nanomaterials on the surface of substrate during the CVD method. For example, Dong et al. (illustrated in Figure 5) reported that graphene/carbon nanotube hybrids were synthesized by a facile single-step CVD route employing ethanol (C2H5OH) as feedstock on the surface of Cu substrate decorated with Si nanoparticles, and the property and shape of hybrid could be varied by adjusting the fabrication environment (e.g., Si nanoparticles, temperature, and annealing time). The single-step route has the merits of better electrical conductivity and lesser defect density than the multi-step methods [43]. Additionally, although this one-step process effectively decreases the consumption of power, they still need high temperature, flammable gases, or toxic chemicals for the in-situ growth of 3D architecture.
Scheme for the one-step CVD synthesis of graphene/carbon nanotubes hybrids.
It is known that substrate is the important part in the conventional CVD method, and the choice of substrate is essential to the morphology, nanostructure, and applications for carbonaceous nanomaterials. We generally use single transition metal substrate (Fe, Co, Ni, Cu, palladium (Pd) [41], ruthenium (Ru) [54]) as the catalyst for the preparation of graphene, and Fe, Co, Ni, and Cu are of great interest, because of the low cost and availability.
Remarkably, to build the uniform 3D architecture, single metal substrate is not enough for the CVD growth process. Hence, substrate embedded with metal nanoparticles serves as the bifunctional catalyst to facilitate the synthesis of different dimensional carbon materials, and the crucial issue for the in situ growth of 3D hybrids depends on the stability of catalyst nanoparticles during the deposition process. In CVD methods, the metal nanoparticles for the growth of hybrids could be obtained by a variety of ways, such as spin coating [47], electron evaporation [50], template etching [55, 56], and so on. Moreover, the covalent C–C bonding between different dimensional carbon materials, which is of paramount importance for 3D nanostructure, is probable to be achieved by such methods [57, 58, 59]. Nguyen et al. fabricated graphene/carbon nanotube composite by employing the Cu substrate-embedded Fe nanoparticles as the catalyst in the simple CVD approach [15]. In which Cu foil served as the template for the graphene sheet preparation. Additionally iron nanoparticles served as the catalyst for the CNT preparation. Besides, similar report indicated that the diameter, density, and quality of CNTs of composite could be defined by the size of the catalyst nanoparticles [45]. And various densities of catalyst nanoparticles had a different effect on the purity, thermal stability, and defects of 3D carbon hybrids [59].
Although low-dimensional carbon nanomaterials’ nanostructure and diameter in 3D architecture is directly related to the size and nature of catalyst nanoparticles, it also could be indirectly determined by adjusting growth temperature in CVD technique. The different growth of CNF/CNT hybrid was fabricated due to the different carbon source decomposition and diffusion rate at various growth temperatures in the study of Park et al. [24]. Furthermore, the growth temperature is also crucial for the defects and properties of 3D carbon nanomaterials. Lin et al. [57] found that at different growing temperatures, the various architecture of sample could be produced by indirectly changing the number of layers of graphene and packing density of CNTs. And the ratio of the ID/IG (Raman spectroscopy analysis), defects, and surface area increased with the decrease of growth temperature, leading to the increased specific capacitance. As a result, it is crucial to seek the appropriate growth temperature for the growth of well-developed 3D composite.
In the CVD approach, hydrogen (H2), argon (Ar), and nitrogen (N2) are utilized for the growth of carbon materials in the high-temperature annealing process, and the influence of variety of gases in the conventional CVD process is different. As for Ar and N2, they serve as the carrier gas to introduce the vapor into the CVD furnace under a suitable flow rate. As for H2, it has multifunctional effects in the practical CVD environment. First, it is believed that H2 removes surface impurities (such as S and P) and defects which can cause local variations of carbon solubility in the metal substrate in the high-temperature process [13, 60]. And it also enables the reduction process of metal oxides for producing enough catalyst nanoparticles at the high temperature [10, 22, 24]. Yan et al. [49] fabricated mesoscopic 3D composite comprised of graphene and CNTs under the effect of Ni-Co catalysts which was produced at 800°C in H2 atmosphere. Unlike the conventional CVD synthesis of individual 1D or 2D carbon nanostructure, H2 also plays an important role in building nanostructure of 3D hierarchical hybrids, especially for graphene/CNT composite. For example, there were two simultaneous reactions appearing during the construction of 3D graphene/CNT hybrids in the previous report [8]. On one time, the methane decomposed with the increasing temperature and thereafter facilitates the CNT growth out of islands of metal catalyst. Simultaneously, hydrogenation process appeared on the surface of graphene sheet (shown in Figure 6). In this process, graphene sheet was effectively etched under the atmosphere of H2 and transformed into CH4 at the point of connection with the catalyst nanoparticles (Ni nanoparticle + C graphene +2H2 → Ni + CH4) [61]. Furthermore, the morphology of the hybrids was adjusted via varying the H2 flow rate to change the two contrary reactions in the CVD method. Consequently, the high density of CNTs grown on the surface of graphene sheet under the suitable flow rate of H2, implying that the rate of H2 etching optimized the 3D nanocarbon formation.
Schematics illustrating direct CNT growth on planar graphene under H2 etching.
So far, quite a few investigations have been dedicated to the fabrication of 3D carbonaceous hybrids by using various carbon sources, and studies have illustrated that the carbon sources can also be basically classified into the three categories: hydrocarbon compounds (CH4 [45, 58], C2H2 [11, 50], C2H4 [10], C3H8 [43]), liquid carbon sources (ethanol [47], pyridine [22], toluene [41]), and solid feedstock (melamine [49], Prussian blue [9], camphor [62]) and so on. According to the relevant reports, diverse carbonaceous hybrids choose various carbon sources as feedstock for the basic supply of 3D architecture. With respect to CNT/CNF hybrids, hydrocarbon compounds are always considered as feedstocks of CNTs on the surface of obtained CNFs. With respect to CNT/graphene or CNF/graphene composites, hydrocarbon compounds, liquid carbon sources, and solid feedstock are all used as precursors for the growth of hierarchical architecture. Notably, for the synthesis of graphene, the present CVD technique requires high growth temperature, typically 1000°C [63, 64, 65]. Since it is more environment-friendly, convenient, and economical for industrial fabrication, a low-temperature route is greatly desirable. Liquid and solid carbon sources decompose at a lower temperature relative to major gaseous carbon sources. Therefore, liquid and solid feedstock could be a better choice for the growth of 3D CNT/graphene or CNF/graphene hybrids because of the quick carbon diffusivity through metal catalysts and covering on the surface at lower temperature. Moreover, during the dehydrogenation process of liquid or solid carbon sources, the overall dehydrogenation barrier and nucleation barrier are much lower than that of gaseous carbon source from the relevant report [66]. Recently, low temperature (800°C) one-step CVD synthesis of 3D hybrids composed by CNTs and graphene sheet are demonstrated by using melamine as the single solid carbon source [56]. Nevertheless, 3D hybrid growth at lower temperature still remains a challenge.
Three-dimensional nanocarbon hybrids have been used for a variety of applications, for example, transparent and flexible electrodes and field-effect transistors [12, 13, 14, 15, 16, 47], sensors [17, 18, 19, 20], fuel cell [67], batteries [9, 11, 44, 55], supercapacitors [10, 50, 51], and so on.
Because of the outstanding mechanical, electrical, and thermal properties, low dimensional nanocarbon materials have recently attracted enormous interest for potential application in transparent and flexible nanoelectronics [68, 69, 70]. Furthermore, 3D graphene-based hybrids which offset shortcomings of pure graphene received a large number of attentions in particular for two applications: transparent and flexible electrodes and field-effect transistors. Kim et al. [13] successful synthesized single-walled carbon nanotubes (SWCNT)/graphene hybrids on the Cu foil coated with CNTs. Notably, compared to pure CNT (58.78 ± 36.17 cm2/V s) and graphene (341.7 ± 259.4 cm2/V s), SWCNT-graphene hybrids possessed higher field-effect mobilities (μ) (394.46 ± 176.27 cm2/V s) and better output characteristics (Figure 7), suggesting that the electrical conductivity of this hybrids dramatically increased compared to individual carbon material. As for transparent and flexible device applications, the hybrids showed the low sheet resistance (300 Ω/sq) with 96.4% optical transparency which is largely lower than the monolayer graphene (∼1 kΩ/sq) grown by CVD method, indicating that composite is a promising material in developing high-performance transparent and flexible devices. Additionally, the hybrids possessed improved mechano-electrical property result from the CNT growth and obtained hybrid demonstrated that at an applied field of 4.0 V/μm, the hybrid exhibited a current density of 1.33 mA cm−2 [15], implying superiority than that of pure CNT materials on indium tin oxide films (ITO) glass [71]. And it probably replaces the ITO films, the most common transparent and flexible electrodes, as an alternative material with properties including high on/off ratios and outstanding electrical conductivity for high-performance flexible device in the future.
Output characteristics (IDS − VDS) of graphene, SWCNT-graphene hybrid film, and SWCNT. Reproduced with permission from ref. [13].
In the practical application, the higher active and stable catalysts are crucial to the high electrochemical performance of fuel cell. Compared to the pure Pt-graphene cathode material, the Pt-3D nanocarbon composite cathode exhibits much smaller oxygen reduction reaction (ORR) charge transfer resistance and higher maximum power density in the direct methanol fuel cell [23] and proton exchange membrane fuel cells [21]. Moreover, due to the expensive cost and poor durability, as the spread anode and cathode electro-catalysts for ORR, Pt-based materials are hampered in the commercialization. Significantly, the CNT/CNF composite acts as the effective Pt-free ORR catalyst with a comparable activity, cheap price, and better thermal stability and durability, and the unique 3D network results in the enhanced electrochemical performance [22], implying 3D hybrid materials are becoming increasing competitive in the fuel cell applications.
Carbon-based materials (such as CNTs, CNFs, graphene), with their merits of reversible lithium-carbon reaction, low-intercalation potential with Li+, high-coulumbic efficiencies, and low-capacity fade, are excellent choices as electrode materials of lithium-ion batteries [72, 73]. Nevertheless, the cycling performance and high-rate capability of individual material are not as satisfactory as expected, possibly owing to the large contact resistance of easy self-aggregation and stacking. Moreover, hybrids consisting of various low dimensional carbon materials, which favor different oriented diffusion of the lithium ion and the 3D nanocarbon architecture, are beneficial to the electrons’ collection and transport around the cycling process, leading to high electrical conductivity and chemical stability. For example, the 3D nanocarbon hybrid anode exhibited significantly enhanced reversible capacity (300 mA h g−1), outstanding cycling stability, and lower electrolyte resistance and contact resistances in contrast with the individual CNF material [11]. Additionally, by building 3D carbon network, at current densities of 0.36, 0.6, 1.2, 2.4, and 6 mA/cm2, the rate performance of graphene/CNF hybrids reached about 420, 385, 329, 229, and 189 mA h g−1, (as shown in Figure 8), which were superior to those of other pure nanocarbon performances [44]. Therefore, hybridization of the different low-dimensional carbon nanomaterials is an effective route to provide fast ion/electron transfer and higher Li storage capability, and the hierarchical 3D carbonaceous architecture is also promising for Li-ion battery applications in the future.
Comparison of the rate capabilities of CNF/GNS, GNS, CNT, commercial natural graphite discharged at C/5, CNF (30 nm in diameter), CNF/natural graphite, and natural graphite spheres. Reproduced with permission from ref. [44].
Because of the large energy density, capacity (1673 mA h g−1), low cost, and environmental benignity of sulfur, lithium-sulfur (Li-S) batteries are investigated by a large number of research groups. However, the “shuttling effect” which always triggers an inevitable sulfur loss in practical Li-S battery applications, leading to an increase in internal resistance, low cycling capacity, and poor coulombic efficiency. To solve this problem, porous carbon materials, e.g., CNTs and graphene, also have been utilized to capture and encapsulate sulfur, blocking the high solubility of polysulfides during the Li-S battery applications [74, 75]. And compared to pure CNT which is always hindered by problems of easy self-aggregation, enormous interface resistance, and poor S-storage ability, the 3D hybrids composed of CNTs and graphene are more suitable for the cathode of high-rate performance for Li-S batteries. The hybrid structure exhibits unique advantages: (i) the well-connected junction between the CNTs and graphene sheets enable rapid electron transfer; (ii) robust nanostructure provides flexibility and mechanical robustness, which effectively buffers volume changes during the cycling process [9]. Zhao et al. reported that graphene/CNT composite cathode possessed remarkable performance: a reversible capacity (928 mA h g−1) at 1 C capacity and at a high current rate of 5 C, the capacity as high as about 650 mA h g−1 could be obtained even after 100 cycles with a coulombic efficiency of about 92% in Li-S battery applications [76]. Furthermore, it is worth noting that electrochemical performance and catalytic activity have significantly improved nitrogen doping according to a relevant report, thus nitrogen-doped 3D hybrids also applied in the Li-S batteries. Tang et al. employed glucose and dicyandiamide as the carbon and nitrogen feedstocks to prepare the nitrogen-doped nanocarbon hybrid by a one-step chemical vapor deposition process technique, and the result (1314 mA h g−1 at 0.2 C, a capacity retention of 97% after 200 cycles at a high rate of 2 C) exhibited the improved cyclic and rate performances [9]. These experimental results also indicate that the nitrogen-doped 3D nanostructure has the potential toward promising Li-S batteries.
A variety of nanocarbon materials, e.g., CNTs, graphene, or mesoporous and activated carbon possess enormous specific surface areas yet are limited by low performance owing to aggregation and internal resistance, leading to decreased capacitance than theoretical prediction [77]. To overcome the aforementioned disadvantages, 3D composites are considered as attractive materials for supercapacitor application by inhibiting the agglomeration and improving the electrolyte electrode accessibility and the electrode conductivity. Relevant report demonstrated that the capacitance (653.7 μF cm−2) at 10 mV s−1 of 3D CNT/graphene-based supercapacitor was superior to the graphene electrode (99.6 μF cm−2) [8]. Zhou et al. fabricated supercapacitor based on polyaniline/carbon nanotube/carbon nanofiber (PANI/CNT/CNF) electrode [30]. Compared with pure PANI/CNF, the hybrids showed higher specific capacitance and energy density, superior rate capability, and lower ion diffusion/transport resistance (shown in Figure 9).
(A) GCD curves of CNF, CNT/CNF, PANI/CNF, and PANI/CNT/CNF film electrodes at a current density of 0.3 a g−1, respectively. (B) GCD curves of PANI/CNT/CNF film electrodes at different current densities. (C) Specific capacitance vs. current density for PANI/CNF and PANI/CNT/CNF film electrodes. (D) Charging/discharging cycling stability of PANI/CNT/CNF film electrodes at a current density of 15 a g−1. Reproduced with permission from ref. [30].
Meanwhile, due to the merits—high theoretical capacity, low cost, and natural abundance—diverse potential metal oxides, e.g., RuO2 [78], MnO2 [79], NiO [80], and Co3O4 [81] are regarded as the potential materials for pseudocapacitors. Particularly, as one of the most promising pseudocapacitor materials, when the MnO2 combined with 3D carbon hybrid, the drawbacks such as weak conductivity, low specific surface area, and brittleness of metal oxide electrodes are effectively alleviated, resulting in higher electrochemical performances [26, 27]. Wang et al. synthesized nanocarbon hierarchical composites (CNTs/CNFs) decorated with MnO2 for flexible supercapacitors [10]. And the 3D nanocarbon hybrid/MnO2 electrodes showed large better specific capacitance, cycling stability, maximum energy density, and rate capability than the CNF/MnO2 electrodes. These enhanced electrochemical performances of hybridized-based electrodes indicate that the designed hierarchical structures of composites support a large special surface area for the reaction between electrolyte ions and metal oxides. Simultaneously, the special 3D nanostructures improve the electrode nanomaterials’ electronic conductivity and facilitate transport channels for electrolyte ions. It is no doubt that 3D nanocarbon hybrids will have a crucial impact on the emerging materials of high-performance supercapacitor applications.
To combine the merits of each building block, 3D nanocarbon structures (CNT/graphene, CNF/graphene, CNT/CNF hybrids) have been prepared by a variety of methods. The synthesis procedure, merits, and demerits of different approaches reported in the literatures are discussed in this chapter. Among them, chemical vapor deposition is regarded as the most promising fabrication method, and nicely hybrid architectures are achievable by this way. Nevertheless, there are various drawbacks and challenges in the practice synthesis. One of the great challenges in the CVD synthesis of the three-dimensional nanocarbon hybrids is convenience or simpleness when compared to preparation methods of individual nanocarbon materials. A simple scalable CVD method to fabricate controllable architecture of 3D nanocarbon hybrid is still crucial to industrial production. Furthermore, a variety of applications have been presented in this chapter. Compared to individual nanocarbon components, the superior performances of 3D nanocarbon hybrids signify their promising and wide application in the future, and 3D hybrid electrode materials are becoming more competitive in energy storage applications. It is worth mentioning that studies on the growth mechanism of 3D nanostructure which is necessary for the full understanding of CVD growth process is seldom reported from the relevant literatures. And some crucial problem still remained to be solved, particularly the interactions between various individual components and structure control in the future.
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His current research interest includes power electronics, control of electrical machines, artificial intelligence and Renewable energies.",institutionString:"University of Béchar",institution:{name:"University of Béchar",country:{name:"Algeria"}}},{id:"99749",title:"Dr.",name:"Abdel Hafid",middleName:null,surname:"Essadki",slug:"abdel-hafid-essadki",fullName:"Abdel Hafid Essadki",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"École Nationale Supérieure de Technologie",country:{name:"Algeria"}}},{id:"101208",title:"Prof.",name:"Abdel Karim",middleName:"Mohamad",surname:"El Hemaly",slug:"abdel-karim-el-hemaly",fullName:"Abdel Karim El Hemaly",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/101208/images/733_n.jpg",biography:"OBGYN.net Editorial Advisor Urogynecology.\nAbdel Karim M. A. El-Hemaly, MRCOG, FRCS � Egypt.\n \nAbdel Karim M. A. El-Hemaly\nProfessor OB/GYN & Urogynecology\nFaculty of medicine, Al-Azhar University \nPersonal Information: \nMarried with two children\nWife: Professor Laila A. Moussa MD.\nSons: Mohamad A. M. El-Hemaly Jr. MD. Died March 25-2007\nMostafa A. M. El-Hemaly, Computer Scientist working at Microsoft Seatle, USA. \nQualifications: \n1.\tM.B.-Bch Cairo Univ. June 1963. \n2.\tDiploma Ob./Gyn. Cairo Univ. April 1966. \n3.\tDiploma Surgery Cairo Univ. Oct. 1966. \n4.\tMRCOG London Feb. 1975. \n5.\tF.R.C.S. Glasgow June 1976. \n6.\tPopulation Study Johns Hopkins 1981. \n7.\tGyn. Oncology Johns Hopkins 1983. \n8.\tAdvanced Laparoscopic Surgery, with Prof. Paulson, Alexandria, Virginia USA 1993. \nSocieties & Associations: \n1.\t Member of the Royal College of Ob./Gyn. London. \n2.\tFellow of the Royal College of Surgeons Glasgow UK. \n3.\tMember of the advisory board on urogyn. FIGO. \n4.\tMember of the New York Academy of Sciences. \n5.\tMember of the American Association for the Advancement of Science. \n6.\tFeatured in �Who is Who in the World� from the 16th edition to the 20th edition. \n7.\tFeatured in �Who is Who in Science and Engineering� in the 7th edition. \n8.\tMember of the Egyptian Fertility & Sterility Society. \n9.\tMember of the Egyptian Society of Ob./Gyn. \n10.\tMember of the Egyptian Society of Urogyn. \n\nScientific Publications & Communications:\n1- Abdel Karim M. El Hemaly*, Ibrahim M. Kandil, Asim Kurjak, Ahmad G. Serour, Laila A. S. Mousa, Amr M. Zaied, Khalid Z. El Sheikha. \nImaging the Internal Urethral Sphincter and the Vagina in Normal Women and Women Suffering from Stress Urinary Incontinence and Vaginal Prolapse. Gynaecologia Et Perinatologia, Vol18, No 4; 169-286 October-December 2009.\n2- Abdel Karim M. El Hemaly*, Laila A. S. Mousa Ibrahim M. Kandil, Fatma S. El Sokkary, Ahmad G. Serour, Hossam Hussein.\nFecal Incontinence, A Novel Concept: The Role of the internal Anal sphincter (IAS) in defecation and fecal incontinence. Gynaecologia Et Perinatologia, Vol19, No 2; 79-85 April -June 2010.\n3- Abdel Karim M. El Hemaly*, Laila A. S. Mousa Ibrahim M. Kandil, Fatma S. El Sokkary, Ahmad G. Serour, Hossam Hussein.\nSurgical Treatment of Stress Urinary Incontinence, Fecal Incontinence and Vaginal Prolapse By A Novel Operation \n"Urethro-Ano-Vaginoplasty"\n Gynaecologia Et Perinatologia, Vol19, No 3; 129-188 July-September 2010.\n4- Abdel Karim M. El Hemaly*, Ibrahim M. Kandil, Laila A. S. Mousa and Mohamad A.K.M.El Hemaly.\nUrethro-vaginoplasty, an innovated operation for the treatment of: Stress Urinary Incontinence (SUI), Detursor Overactivity (DO), Mixed Urinary Incontinence and Anterior Vaginal Wall Descent. \nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/ urethro-vaginoplasty_01\n\n5- Abdel Karim M. El Hemaly, Ibrahim M Kandil, Mohamed M. Radwan.\n Urethro-raphy a new technique for surgical management of Stress Urinary Incontinence.\nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/\nnew-tech-urethro\n\n6- Abdel Karim M. El Hemaly, Ibrahim M Kandil, Mohamad A. Rizk, Nabil Abdel Maksoud H., Mohamad M. Radwan, Khalid Z. El Shieka, Mohamad A. K. M. El Hemaly, and Ahmad T. El Saban.\nUrethro-raphy The New Operation for the treatment of stress urinary incontinence, SUI, detrusor instability, DI, and mixed-type of urinary incontinence; short and long term results. \nhttp://www.obgyn.net/urogyn/urogyn.asp?page=urogyn/articles/\nurethroraphy-09280\n\n7-Abdel Karim M. El Hemaly, Ibrahim M Kandil, and Bahaa E. El Mohamady. Menopause, and Voiding troubles. \nhttp://www.obgyn.net/displayppt.asp?page=/English/pubs/features/presentations/El-Hemaly03/el-hemaly03-ss\n\n8-El Hemaly AKMA, Mousa L.A. Micturition and Urinary\tContinence. Int J Gynecol Obstet 1996; 42: 291-2. \n\n9-Abdel Karim M. El Hemaly.\n Urinary incontinence in gynecology, a review article.\nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/abs-urinary_incotinence_gyn_ehemaly \n\n10-El Hemaly AKMA. Nocturnal Enuresis: Pathogenesis and Treatment. \nInt Urogynecol J Pelvic Floor Dysfunct 1998;9: 129-31.\n \n11-El Hemaly AKMA, Mousa L.A.E. Stress Urinary Incontinence, a New Concept. Eur J Obstet Gynecol Reprod Biol 1996; 68: 129-35. \n\n12- El Hemaly AKMA, Kandil I. M. Stress Urinary Incontinence SUI facts and fiction. Is SUI a puzzle?! http://www.obgyn.net/displayppt.asp?page=/English/pubs/features/presentations/El-Hemaly/el-hemaly-ss\n\n13-Abdel Karim El Hemaly, Nabil Abdel Maksoud, Laila A. Mousa, Ibrahim M. Kandil, Asem Anwar, M.A.K El Hemaly and Bahaa E. El Mohamady. \nEvidence based Facts on the Pathogenesis and Management of SUI. http://www.obgyn.net/displayppt.asp?page=/English/pubs/features/presentations/El-Hemaly02/el-hemaly02-ss\n\n14- Abdel Karim M. El Hemaly*, Ibrahim M. Kandil, Mohamad A. Rizk and Mohamad A.K.M.El Hemaly.\n Urethro-plasty, a Novel Operation based on a New Concept, for the Treatment of Stress Urinary Incontinence, S.U.I., Detrusor Instability, D.I., and Mixed-type of Urinary Incontinence.\nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/urethro-plasty_01\n\n15-Ibrahim M. Kandil, Abdel Karim M. El Hemaly, Mohamad M. Radwan: Ultrasonic Assessment of the Internal Urethral Sphincter in Stress Urinary Incontinence. The Internet Journal of Gynecology and Obstetrics. 2003. Volume 2 Number 1. \n\n\n16-Abdel Karim M. El Hemaly. Nocturnal Enureses: A Novel Concept on its pathogenesis and Treatment.\nhttp://www.obgyn.net/urogynecolgy/?page=articles/nocturnal_enuresis\n\n17- Abdel Karim M. El Hemaly. Nocturnal Enureses: An Update on the pathogenesis and Treatment.\nhttp://www.obgyn.net/urogynecology/?page=/ENHLIDH/PUBD/FEATURES/\nPresentations/ Nocturnal_Enuresis/nocturnal_enuresis\n\n18-Maternal Mortality in Egypt, a cry for help and attention. The Second International Conference of the African Society of Organization & Gestosis, 1998, 3rd Annual International Conference of Ob/Gyn Department � Sohag Faculty of Medicine University. Feb. 11-13. Luxor, Egypt. \n19-Postmenopausal Osteprosis. The 2nd annual conference of Health Insurance Organization on Family Planning and its role in primary health care. Zagaziz, Egypt, February 26-27, 1997, Center of Complementary Services for Maternity and childhood care. \n20-Laparoscopic Assisted vaginal hysterectomy. 10th International Annual Congress Modern Trends in Reproductive Techniques 23-24 March 1995. Alexandria, Egypt. \n21-Immunological Studies in Pre-eclamptic Toxaemia. Proceedings of 10th Annual Ain Shams Medical Congress. Cairo, Egypt, March 6-10, 1987. \n22-Socio-demographic factorse affecting acceptability of the long-acting contraceptive injections in a rural Egyptian community. Journal of Biosocial Science 29:305, 1987. \n23-Plasma fibronectin levels hypertension during pregnancy. The Journal of the Egypt. Soc. of Ob./Gyn. 13:1, 17-21, Jan. 1987. \n24-Effect of smoking on pregnancy. Journal of Egypt. Soc. of Ob./Gyn. 12:3, 111-121, Sept 1986. \n25-Socio-demographic aspects of nausea and vomiting in early pregnancy. Journal of the Egypt. Soc. of Ob./Gyn. 12:3, 35-42, Sept. 1986. \n26-Effect of intrapartum oxygen inhalation on maternofetal blood gases and pH. Journal of the Egypt. Soc. of Ob./Gyn. 12:3, 57-64, Sept. 1986. \n27-The effect of severe pre-eclampsia on serum transaminases. The Egypt. J. Med. Sci. 7(2): 479-485, 1986. \n28-A study of placental immunoreceptors in pre-eclampsia. The Egypt. J. Med. Sci. 7(2): 211-216, 1986. \n29-Serum human placental lactogen (hpl) in normal, toxaemic and diabetic pregnant women, during pregnancy and its relation to the outcome of pregnancy. Journal of the Egypt. Soc. of Ob./Gyn. 12:2, 11-23, May 1986. \n30-Pregnancy specific B1 Glycoprotein and free estriol in the serum of normal, toxaemic and diabetic pregnant women during pregnancy and after delivery. Journal of the Egypt. Soc. of Ob./Gyn. 12:1, 63-70, Jan. 1986. Also was accepted and presented at Xith World Congress of Gynecology and Obstetrics, Berlin (West), September 15-20, 1985. \n31-Pregnancy and labor in women over the age of forty years. Accepted and presented at Al-Azhar International Medical Conference, Cairo 28-31 Dec. 1985. \n32-Effect of Copper T intra-uterine device on cervico-vaginal flora. Int. J. Gynaecol. Obstet. 23:2, 153-156, April 1985. \n33-Factors affecting the occurrence of post-Caesarean section febrile morbidity. Population Sciences, 6, 139-149, 1985. \n34-Pre-eclamptic toxaemia and its relation to H.L.A. system. Population Sciences, 6, 131-139, 1985. \n35-The menstrual pattern and occurrence of pregnancy one year after discontinuation of Depo-medroxy progesterone acetate as a postpartum contraceptive. Population Sciences, 6, 105-111, 1985. \n36-The menstrual pattern and side effects of Depo-medroxy progesterone acetate as postpartum contraceptive. Population Sciences, 6, 97-105, 1985. \n37-Actinomyces in the vaginas of women with and without intrauterine contraceptive devices. Population Sciences, 6, 77-85, 1985. \n38-Comparative efficacy of ibuprofen and etamsylate in the treatment of I.U.D. menorrhagia. Population Sciences, 6, 63-77, 1985. \n39-Changes in cervical mucus copper and zinc in women using I.U.D.�s. Population Sciences, 6, 35-41, 1985. \n40-Histochemical study of the endometrium of infertile women. Egypt. J. Histol. 8(1) 63-66, 1985. \n41-Genital flora in pre- and post-menopausal women. Egypt. J. Med. Sci. 4(2), 165-172, 1983. \n42-Evaluation of the vaginal rugae and thickness in 8 different groups. Journal of the Egypt. Soc. of Ob./Gyn. 9:2, 101-114, May 1983. \n43-The effect of menopausal status and conjugated oestrogen therapy on serum cholesterol, triglycerides and electrophoretic lipoprotein patterns. Al-Azhar Medical Journal, 12:2, 113-119, April 1983. \n44-Laparoscopic ventrosuspension: A New Technique. Int. J. Gynaecol. Obstet., 20, 129-31, 1982. \n45-The laparoscope: A useful diagnostic tool in general surgery. Al-Azhar Medical Journal, 11:4, 397-401, Oct. 1982. \n46-The value of the laparoscope in the diagnosis of polycystic ovary. Al-Azhar Medical Journal, 11:2, 153-159, April 1982. \n47-An anaesthetic approach to the management of eclampsia. Ain Shams Medical Journal, accepted for publication 1981. \n48-Laparoscopy on patients with previous lower abdominal surgery. Fertility management edited by E. Osman and M. Wahba 1981. \n49-Heart diseases with pregnancy. Population Sciences, 11, 121-130, 1981. \n50-A study of the biosocial factors affecting perinatal mortality in an Egyptian maternity hospital. Population Sciences, 6, 71-90, 1981. \n51-Pregnancy Wastage. Journal of the Egypt. Soc. of Ob./Gyn. 11:3, 57-67, Sept. 1980. \n52-Analysis of maternal deaths in Egyptian maternity hospitals. Population Sciences, 1, 59-65, 1979. \nArticles published on OBGYN.net: \n1- Abdel Karim M. El Hemaly*, Ibrahim M. Kandil, Laila A. S. Mousa and Mohamad A.K.M.El Hemaly.\nUrethro-vaginoplasty, an innovated operation for the treatment of: Stress Urinary Incontinence (SUI), Detursor Overactivity (DO), Mixed Urinary Incontinence and Anterior Vaginal Wall Descent. \nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/ urethro-vaginoplasty_01\n\n2- Abdel Karim M. El Hemaly, Ibrahim M Kandil, Mohamed M. Radwan.\n Urethro-raphy a new technique for surgical management of Stress Urinary Incontinence.\nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/\nnew-tech-urethro\n\n3- Abdel Karim M. El Hemaly, Ibrahim M Kandil, Mohamad A. Rizk, Nabil Abdel Maksoud H., Mohamad M. Radwan, Khalid Z. El Shieka, Mohamad A. K. M. El Hemaly, and Ahmad T. El Saban.\nUrethro-raphy The New Operation for the treatment of stress urinary incontinence, SUI, detrusor instability, DI, and mixed-type of urinary incontinence; short and long term results. \nhttp://www.obgyn.net/urogyn/urogyn.asp?page=urogyn/articles/\nurethroraphy-09280\n\n4-Abdel Karim M. El Hemaly, Ibrahim M Kandil, and Bahaa E. El Mohamady. Menopause, and Voiding troubles. \nhttp://www.obgyn.net/displayppt.asp?page=/English/pubs/features/presentations/El-Hemaly03/el-hemaly03-ss\n\n5-El Hemaly AKMA, Mousa L.A. Micturition and Urinary\tContinence. Int J Gynecol Obstet 1996; 42: 291-2. \n\n6-Abdel Karim M. El Hemaly.\n Urinary incontinence in gynecology, a review article.\nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/abs-urinary_incotinence_gyn_ehemaly \n\n7-El Hemaly AKMA. Nocturnal Enuresis: Pathogenesis and Treatment. \nInt Urogynecol J Pelvic Floor Dysfunct 1998;9: 129-31.\n \n8-El Hemaly AKMA, Mousa L.A.E. Stress Urinary Incontinence, a New Concept. Eur J Obstet Gynecol Reprod Biol 1996; 68: 129-35. \n\n9- El Hemaly AKMA, Kandil I. M. Stress Urinary Incontinence SUI facts and fiction. Is SUI a puzzle?! http://www.obgyn.net/displayppt.asp?page=/English/pubs/features/presentations/El-Hemaly/el-hemaly-ss\n\n10-Abdel Karim El Hemaly, Nabil Abdel Maksoud, Laila A. Mousa, Ibrahim M. Kandil, Asem Anwar, M.A.K El Hemaly and Bahaa E. El Mohamady. \nEvidence based Facts on the Pathogenesis and Management of SUI. http://www.obgyn.net/displayppt.asp?page=/English/pubs/features/presentations/El-Hemaly02/el-hemaly02-ss\n\n11- Abdel Karim M. El Hemaly*, Ibrahim M. Kandil, Mohamad A. Rizk and Mohamad A.K.M.El Hemaly.\n Urethro-plasty, a Novel Operation based on a New Concept, for the Treatment of Stress Urinary Incontinence, S.U.I., Detrusor Instability, D.I., and Mixed-type of Urinary Incontinence.\nhttp://www.obgyn.net/urogyn/urogyn.asp?page=/urogyn/articles/urethro-plasty_01\n\n12-Ibrahim M. Kandil, Abdel Karim M. El Hemaly, Mohamad M. Radwan: Ultrasonic Assessment of the Internal Urethral Sphincter in Stress Urinary Incontinence. The Internet Journal of Gynecology and Obstetrics. 2003. Volume 2 Number 1. \n\n13-Abdel Karim M. El Hemaly. Nocturnal Enureses: A Novel Concept on its pathogenesis and Treatment.\nhttp://www.obgyn.net/urogynecolgy/?page=articles/nocturnal_enuresis\n\n14- Abdel Karim M. El Hemaly. 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