In the last decade, energy crisis has become the most important topic for researchers. Energy requirements have increased drastically. To overcome the issue of energy crisis in near future, numerous efforts and sources have been developed. Therefore, solar energy has been considered the most promising energy source compared to other energy sources. There were different kinds of photovoltaic devices developed, but perovskite solar cells have been considered the most efficient and promising solar cell. The perovskite solar cells were invented in 2009 and crossed an excellent power conversion efficiency of 25%. However, it has a few major drawbacks, such as the presence of highly toxic lead (Pb) and poor stability. Hence, numerous efforts were made toward the replacement of Pb and highly stable perovskite solar cells in the last few years. Bismuth halide perovskite solar cell is one type of the replacement introduced to overcome these issues. In this chapter, I have reviewed the role of bismuth halide perovskite structures and their optoelectronic properties toward the development of perovskite solar cells.
Part of the book: Bismuth
In the last few decades, the energy demand has been increased dramatically. Different forms of energy have utilized to fulfill the energy requirements. Solar energy has been proven an effective and highly efficient energy source which has the potential to fulfill the energy requirements in the future. Previously, various kind of solar cells have been developed. In 2013, organic–inorganic metal halide perovskite materials have emerged as a rising star in the field of photovoltaics. The methyl ammonium lead halide perovskite structures were employed as visible light sensitizer for the development of highly efficient perovskite solar cells (PSCs). In 2018, the highest power conversion efficiency of 23.7% was achieved for methyl ammonium lead halide based PSCs. This obtained highest power conversion efficiency makes them superior over other solar cells. The PSCs can be employed for practical uses, if their long term stability improved by utilizing some novel strategies. In this chapter, we have discussed the optoelectronic properties of the perovskite materials, construction of PSCs and recent advances in the electron transport layers for the fabrication of PSCs.
Part of the book: Recent Advances in Nanophotonics