Chapters authored
Crude Distillation Unit (CDU)
The chapter considers the technology of the crude distillation unit in general. The crude distillation unit is at the front-end of the oil refinery. The desalting process and distillation of crude oil are included in the crude distillation unit (CDU). The desalting process of crude oil is imperative to ensure the good quality of crude oil, that is, to remove impurities before its transfer to refining. This procedure minimizes or eliminates harmful substances such as sulfur, water, salts, and even mechanical impurities, which ensures a long operation of pipelines. However, the desalting process is only part of the distillation unit. The other phase of this unit is as already mentioned above is: distillation. Distillation is a more physical than a chemical process. The distillation process is characterised by mass-thermal transfer of materials, which leads to the obtaining of fractions. The distillation in the crude distillation unit is carried out consecutively in two ways: atmospheric and vacuum. In the Russian Federation, we classify oil refining plants in general as follows: fuel, fuel-oil, fuel-petrochemical, and fuel-oil-petrochemical. Also, regardless of the profile of the refinery, great importance is given to the crude distillation unit. The crude distillation unit, if well modeled and organized, makes it possible to obtain already more light products at this stage; therefore, there is a reduction of heavy residues, the refinement of which requires more expensive processes such as hydrocracking or catalytic cracking. The oil topping column K-1, within this framework, has been adopted in several oil refining plants in addition to the main column commonly referred to as K-2. The principal purpose of column K-1 is the separation of light gasoline and the major part of dissolved gases from crude oil. This first step of distillation at K-1 has the effect of normalizing the amount of gasoline hydrocarbons and stabilizing the operation of the main column K-2 despite possible fluctuations in the composition of crude oil. Besides, the CDU equipped with column K-1 demonstrates an increase in some valuable products such as methane, ethane, naphtha, etc.
Part of the book: Analytical Chemistry