Part of the book: Ionic Liquids
Part of the book: Ionic Liquids
Part of the book: Ionic Liquids
In this chapter, we briefly introduce our recent work related to the topic of ultralight paper-based electrodes for energy applications. Herein, the ultralight paper-based counter electrodes containing commercial poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) and homemade graphene dots (GDs) are synthesized for preparing flexible dye-sensitized solar cells (DSSCs). Because the GDs/PEDOT:PSS composite can well fill the porosity of paper substrate, the flexible DSSC with GDs/PEDOT:PSS-coated paper electrode exhibits much higher cell efficiency than that of DSSC using paper electrode with Pt. The features of lightweight, low-cost, space-saving (high flexibility), high machinability (easy-cutting) and environmental friendly would make the GDs/PEDOT:PSS-coated paper electrodes highly potential in portable/wearable electronic applications.
Part of the book: Novel Nanomaterials
In recent decades, plenty of nanomaterials have been investigated as electrocatalysts for the replacement of the expensive platinum (Pt) counter electrode in dye-sensitized solar cells (DSSCs). The key function of the electrocatalyst is to reduce tri-iodide ions to iodide ions at the electrolyte/counter electrode interface. The performance of the electrocatalyst is usually determined by two key factors, i.e., the intrinsic heterogeneous rate constant and the effective electrocatalytic surface area of the electrocatalyst. The intrinsic heterogeneous rate constant of the electrocatalyst varies by different types of materials, which can be roughly divided into five groups: non-Pt metals, carbons, conducting polymers, transition metal compounds, and their composites. The effective electrocatalytic surface area is determined by the nanostructure of the electrocatalyst. In this chapter, the nanostructural design and engineering on different types of Pt-free electrocatalysts will be systematically introduced. Also, the relationship between various nanostructures of electrocatalysts and the pertinent physical/electrochemical properties will be discussed.
Part of the book: Nanostructures
Nanoscale electromechanical and energy harvesting devices based on few-layer and monolayer two-dimensional (2D) materials with non-symmetric configuration have received enormous attention in recent years. Specifically, piezoelectric and triboelectric devices based on 2D materials for energy harvesting, physical/chemical sensing, healthcare, and optoelectronics applications have been a growing interest. In this chapter, the typical preparation methods of 2D-layered materials, such as exfoliation methods and chemical vapor phase deposition (CVD), will be discussed first. Then, various characterization techniques by atomic microscopic analysis for 2D materials will be provided briefly. Finally, future aspects of developing 2D piezoelectric and triboelectric devices and their potential applications will be introduced.
Part of the book: Applied Electromechanical Devices and Machines for Electric Mobility Solutions
Sustainable energy technology has received enormous attention in recent years. Specifically, electrochemical water splitting is considered to be the cleanest technique for the production of promising fuels, for example, hydrogen and oxygen, where transition metal (di)chalcogenides (TMCs) as electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) have been a growing interest. In this chapter, the typical preparation methods of TMCs such as chemical vapor phase deposition (CVD) and solvothermal synthesis are introduced. Then, several TMC materials for catalyzing HER and OER are reviewed. Most importantly, this chapter also introduced some in situ approaches to realize the mechanism of electrocatalytic behavior toward HER and OER. Finally, the conclusion and futuristic prospects of TMCs in HER and OER are discussed.
Part of the book: Advanced Functional Materials
Nowadays, the requirement of energy increases every year, however, the major energy resource is fossil fuel, a limiting source. Dye-sensitized solar cells (DSSCs) are a promising renewable energy source, which could be the major power supply for the future. Recently, the transition metal component has been demonstrated as potential material for counter electrode of platinum (Pt)-free DSSCs owing to their excellent electrocatalytic ability and their abundance on earth. Furthermore, the transition metal components exist different special nanostructures, which provide high surface area and various electron transport routs during electrocatalytic reaction. In this chapter, transition metal components with different nanostructures used for the application of electrocatalyst in DSSCs will be introduced; the performance of electrocatalyst between intrinsic heterogeneous rate constant and effective electrocatalytic surface area are also be clarified. Final, the advantages of the electrocatalyst with different dimensions (i.e., one to three dimension structures) used in DSSCs are also summarized in the conclusion.
Part of the book: Solar Cells
Lightweight, flexible, wearable, and portable electronic gadgets have drawn significant attention in modern electronics industry. To power these gadgets, great efforts have been made to develop highly efficient energy-storage equipment. Among various power sources, a supercapacitor, acting as a bridge between the conventional battery and electrolytic capacitor, has been considered a promising portable energy storage device because of its high power density, fast charge/discharge rate, adequate operational safety, and excellent working lifetime. Hybrid supercapacitors, which combine redox materials with carbon-based materials, exhibit tremendous potential to fulfill the requirement of practical applications. In this chapter, we will review recent reports focusing on composite materials (i.e. metal oxide, metal hydroxide, and metal dichalcogenide composited with carbon materials) for the application in supercapacitors. The conclusion and futuristic prospects and challenges of highly efficient supercapacitors are briefly discussed.
Part of the book: Novel Nanomaterials