Radiochemical
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More than half of the publishers listed alongside IntechOpen (18 out of 30) are Social Science and Humanities publishers. IntechOpen is an exception to this as a leader in not only Open Access content but Open Access content across all scientific disciplines, including Physical Sciences, Engineering and Technology, Health Sciences, Life Science, and Social Sciences and Humanities.
\\n\\nOur breakdown of titles published demonstrates this with 47% PET, 31% HS, 18% LS, and 4% SSH books published.
\\n\\n“Even though ItechOpen has shown the potential of sci-tech books using an OA approach,” other publishers “have shown little interest in OA books.”
\\n\\nAdditionally, each book published by IntechOpen contains original content and research findings.
\\n\\nWe are honored to be among such prestigious publishers and we hope to continue to spearhead that growth in our quest to promote Open Access as a true pioneer in OA book publishing.
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Simba Information has released its Open Access Book Publishing 2020 - 2024 report and has again identified IntechOpen as the world’s largest Open Access book publisher by title count.
\n\nSimba Information is a leading provider for market intelligence and forecasts in the media and publishing industry. The report, published every year, provides an overview and financial outlook for the global professional e-book publishing market.
\n\nIntechOpen, De Gruyter, and Frontiers are the largest OA book publishers by title count, with IntechOpen coming in at first place with 5,101 OA books published, a good 1,782 titles ahead of the nearest competitor.
\n\nSince the first Open Access Book Publishing report published in 2016, IntechOpen has held the top stop each year.
\n\n\n\nMore than half of the publishers listed alongside IntechOpen (18 out of 30) are Social Science and Humanities publishers. IntechOpen is an exception to this as a leader in not only Open Access content but Open Access content across all scientific disciplines, including Physical Sciences, Engineering and Technology, Health Sciences, Life Science, and Social Sciences and Humanities.
\n\nOur breakdown of titles published demonstrates this with 47% PET, 31% HS, 18% LS, and 4% SSH books published.
\n\n“Even though ItechOpen has shown the potential of sci-tech books using an OA approach,” other publishers “have shown little interest in OA books.”
\n\nAdditionally, each book published by IntechOpen contains original content and research findings.
\n\nWe are honored to be among such prestigious publishers and we hope to continue to spearhead that growth in our quest to promote Open Access as a true pioneer in OA book publishing.
\n\n\n\n
\n'}],latestNews:[{slug:"intechopen-supports-asapbio-s-new-initiative-publish-your-reviews-20220729",title:"IntechOpen Supports ASAPbio’s New Initiative Publish Your Reviews"},{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"}]},book:{item:{type:"book",id:"5934",leadTitle:null,fullTitle:"Selected Studies in Biodiversity",title:"Selected Studies in Biodiversity",subtitle:null,reviewType:"peer-reviewed",abstract:"The present book offers an overall up-to-date overview of the biological diversity, comprising many interesting chapters focussing on the different aspects of biodiversity. Most of the chapters include findings of investigations and observations on biodiversity, whilst a few are based on statistically and theoretically derived information. The book produced sufficient information on the occurrence and distribution of many plant and animal species or groups of organisms with environmental estimates from a wide variety of interesting terrestrial and aquatic habitats. With 18 interesting and elaborately prepared chapters, the present book would definitely be an ideal source of scientific information to the advanced students, junior researchers, scientists and a portion of the public involved in ecology and other research areas involving biodiversity studies. It will also help to the development of the growing awareness of the close linkage between the conversation of biodiversity and economic development.",isbn:"978-1-78923-233-2",printIsbn:"978-1-78923-232-5",pdfIsbn:"978-1-83881-261-4",doi:"10.5772/66032",price:139,priceEur:155,priceUsd:179,slug:"selected-studies-in-biodiversity",numberOfPages:400,isOpenForSubmission:!1,isInWos:null,isInBkci:!1,hash:"769199b9338f44051322d1c76ea2c84b",bookSignature:"Bülent Şen and Oscar Grillo",publishedDate:"June 20th 2018",coverURL:"https://cdn.intechopen.com/books/images_new/5934.jpg",numberOfDownloads:24338,numberOfWosCitations:31,numberOfCrossrefCitations:29,numberOfCrossrefCitationsByBook:0,numberOfDimensionsCitations:58,numberOfDimensionsCitationsByBook:0,hasAltmetrics:1,numberOfTotalCitations:118,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"November 2nd 2016",dateEndSecondStepPublish:"November 23rd 2016",dateEndThirdStepPublish:"September 16th 2017",dateEndFourthStepPublish:"October 16th 2017",dateEndFifthStepPublish:"December 16th 2017",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"196641",title:"Dr.",name:"Bülent",middleName:null,surname:"Şen",slug:"bulent-sen",fullName:"Bülent Şen",profilePictureURL:"https://mts.intechopen.com/storage/users/196641/images/system/196641.png",biography:"Bülent Şen graduated from Science Faculty of Ankara University and granted by The Turkish Government to carry out his post-graduate studies abroad. He was accepted by Bristol University (United Kingdom) and he completed his Ph.D. course under the supervision of world-famous phycologist professor F.E.Round. He continued to produce researchers both on algal ecology and algal culture since then and one of his conspicuous research brought him an award of Bold Award Committee (USA ) in 1991. He supervised many MSc and Ph.D. thesis and produced over 100 articles and five books. He became a professor in 1994 and was appointed as a dean of Fisheries Faculty. He has been vice rector between 2008-2012. Professor SEN is a member of Board of Turkish Journal of Botany published by The Scientific and Technological Research Council of Turkey. He has also been a member of many international phycological associations and editor of NWSA Journal.",institutionString:"Fırat University",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"0",totalChapterViews:"0",totalEditedBooks:"1",institution:null}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:{id:"51992",title:"PhD.",name:"Oscar",middleName:null,surname:"Grillo",slug:"oscar-grillo",fullName:"Oscar Grillo",profilePictureURL:"https://mts.intechopen.com/storage/users/51992/images/1749_n.jpg",biography:"Dr. Oscar Grillo is a food technologist with an international PhD in applied and environmental botany. Since 2003 he has been working as a researcher at the Stazione Sperimentale di Granicoltura per la Sicilia, a governmental institute of agronomic research, mainly working with computer vision applied to food matrices and plant structures. Currently, he is collaborating with the Sardinian Germplasm Bank of the Biodiversity Conservation Centre of the University of Cagliari on projects devoted to wild plant seed characterization and identification by image analysis. He also works as a supervisor for many MSc and PhD students. He is the author of about 50 research works published in many peer-reviewed journals and about 70 international conference papers. Dr. Grillo is a referee for a few peer-reviewed journals, and many times was invited as a visiting professor by national and international universities and research centres. In 2011 he was the co-editor of five volumes published by InTech, and in 2014 the editor of the last one.",institutionString:null,position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"1",totalChapterViews:"0",totalEditedBooks:"7",institution:null},coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"841",title:"Biodiversity",slug:"environmental-sciences-ecology-biodiversity"}],chapters:[{id:"56873",title:"Impacts of Climate Change and Climate Variability on Wildlife Resources in Southern Africa: Experience from Selected Protected Areas in Zimbabwe",doi:"10.5772/intechopen.70470",slug:"impacts-of-climate-change-and-climate-variability-on-wildlife-resources-in-southern-africa-experienc",totalDownloads:3374,totalCrossrefCites:7,totalDimensionsCites:14,hasAltmetrics:1,abstract:"Climate change and variability pose a threat to wildlife resources in semi-arid savannahs. With examples from selected protected areas in Southern Africa, this chapter highlights studies on detected climate changes particularly rainfall and temperature, outlines the predicted and observed impacts of climate change and variability on wildlife resources in savannah ecosystems and highlights the adaptation and mitigation strategies and implications for conservation. Literature indicates that Southern Africa is characterised by highly variable, erratic and unpredictable rainfall and increasing temperature coupled with an increasing trend in climate-related extreme events such as frequent droughts, cyclones and heat waves. Drought, in particular, has led to death in several wildlife species. This has implications on long-term survival of the species. Changes in rainfall and temperature patterns influence habitat quality and consequently abundance of distribution of wildlife species. Large herbivores such as elephants and hippopotamus in particular are vulnerable to climate change due to their ecology, whereas other species are less vulnerable. Climate-related extreme events, coupled with other anthropogenic stressors, interact to influence changes in abundance and distribution of wildlife resources. Understanding the influence of these climatic factors on wildlife resources is vital for adaptive management and protection of biodiversity.",signatures:"Olga L. Kupika, Edson Gandiwa, Shakkie Kativu and Godwell\nNhamo",downloadPdfUrl:"/chapter/pdf-download/56873",previewPdfUrl:"/chapter/pdf-preview/56873",authors:[{id:"202318",title:"Ms.",name:"Olga Laiza",surname:"Kupika",slug:"olga-laiza-kupika",fullName:"Olga Laiza Kupika"},{id:"202328",title:"Prof.",name:"Edson",surname:"Gandiwa",slug:"edson-gandiwa",fullName:"Edson Gandiwa"},{id:"202330",title:"Prof.",name:"Shakkie",surname:"Kativu",slug:"shakkie-kativu",fullName:"Shakkie Kativu"},{id:"202334",title:"Prof.",name:"Godwell",surname:"Nhamo",slug:"godwell-nhamo",fullName:"Godwell Nhamo"}],corrections:null},{id:"58231",title:"Biological Conservation and Nature Protection Strategies in Spanish Atlantic Region",doi:"10.5772/intechopen.72515",slug:"biological-conservation-and-nature-protection-strategies-in-spanish-atlantic-region",totalDownloads:966,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:0,abstract:"Despite the fact that the loss of biodiversity continues to be an unresolved problem at a global level, it is possible to identify new alternatives and initiatives in biodiversity conservation. From the environmental strategic framework created worldwide, an important World Network of Biosphere Reserves has been implemented under UNESCO’s Man and the Biosphere (MAB) Programme, which in the European Union in general, and in Spain in particular, is strongly interrelated with Natura 2000 network that is created under Directive 92/43/EEC. In the present work, the importance of the Spanish Atlantic region for biodiversity is assessed, contextualizing the networks of protected areas created in this territory and valuing the created synergies that have favored the start-up of projects and agreements aimed at reducing the loss of biodiversity and achieving sustainability.",signatures:"Javier Ferreiro da Costa and Pablo Ramil-Rego",downloadPdfUrl:"/chapter/pdf-download/58231",previewPdfUrl:"/chapter/pdf-preview/58231",authors:[{id:"61861",title:"Mr.",name:"Pablo",surname:"Ramil-Rego",slug:"pablo-ramil-rego",fullName:"Pablo Ramil-Rego"},{id:"212065",title:"Dr.",name:"Javier",surname:"Ferreiro da Costa",slug:"javier-ferreiro-da-costa",fullName:"Javier Ferreiro da Costa"}],corrections:null},{id:"57718",title:"Methods for Biodiversity Assessment: Case Study in an Area of Atlantic Forest in Southern Brazil",doi:"10.5772/intechopen.71824",slug:"methods-for-biodiversity-assessment-case-study-in-an-area-of-atlantic-forest-in-southern-brazil",totalDownloads:2828,totalCrossrefCites:2,totalDimensionsCites:8,hasAltmetrics:0,abstract:"Populations and species are disappearing due to disturbances in the environment caused by human activities. Given, the obvious risk of loss of diversity, it is increasingly necessary to take actions concerning preservation, in which safety features are necessary for measuring the variation of diversity in space and time. The aim of this study was to evaluate the structure and diversity in the arboreal component and natural regeneration in an area of Araucaria Forest in Southern Brazil. The vegetation sampling was performed by analyzing 180 subunits of 10 × 10 m, where all the arboreal individuals and natural regeneration were inventoried. Different alpha and beta indexes of diversity were calculated. The Margalef, Shannon, and the Beta indexes were underestimated, possibly influenced by the size of sample unit. Index Menhinick represented the diversity in a very real form, even in small sampling units. The indexes of Simpson and MacIntosh denote low dominance and the equity indexes showed high uniformity in species.",signatures:"Maria Raquel Kanieski, Solon Jonas Longhi and Philipe Ricardo\nCasemiro Soares",downloadPdfUrl:"/chapter/pdf-download/57718",previewPdfUrl:"/chapter/pdf-preview/57718",authors:[{id:"219216",title:"Dr.",name:"Maria Raquel",surname:"Kanieski",slug:"maria-raquel-kanieski",fullName:"Maria Raquel Kanieski"},{id:"220250",title:"Dr.",name:"Solon Jonas",surname:"Longhi",slug:"solon-jonas-longhi",fullName:"Solon Jonas Longhi"},{id:"220251",title:"Dr.",name:"Philipe Ricardo",surname:"Casemiro Soares",slug:"philipe-ricardo-casemiro-soares",fullName:"Philipe Ricardo Casemiro Soares"}],corrections:null},{id:"57691",title:"Seabed Biodiversity Shifts Identify Climate Regimes: The 2011 Climate Regime Shift and Associated Cascades",doi:"10.5772/intechopen.71599",slug:"seabed-biodiversity-shifts-identify-climate-regimes-the-2011-climate-regime-shift-and-associated-cas",totalDownloads:1028,totalCrossrefCites:2,totalDimensionsCites:2,hasAltmetrics:0,abstract:"Using search programs for a long-term SCUBA taxonomic database (3865 dives) for Strait of Georgia seabed sites, 1077 taxa were screened to select rare or highly abundant taxa and to present the data according to climate regime categories. Ocean Niño Index (ONI) climate regime shifts are defined here as the year of the end of the first La Niña closely paired with an El Niño by ≤2 months separation, where anomalies for both El Niño and La Niña exceed 1.0 on the ONI scale. For both rare and abundant taxa, patterns of increased or decreased abundance frequently correspond to years defining climate regimes. Cascading effects of climate regime shifts may occur via changes in community composition. The sea star wasting disease (SSWD) syndrome eliminated urchin predators so that urchins have decreased abundance of a kelp species that is nursery habitat for spot prawns. We conclude that 2011 was a climate regime shift. This 2011 regime shift coincided with loss of 11 seabed species in the Strait of Georgia, none of them at their southern range extreme.",signatures:"Jeffrey B. Marliave, Donna M. Gibbs, Laura A. Borden and Charles J.\nGibbs",downloadPdfUrl:"/chapter/pdf-download/57691",previewPdfUrl:"/chapter/pdf-preview/57691",authors:[{id:"58445",title:"Dr.",name:"Jeffrey",surname:"Marliave",slug:"jeffrey-marliave",fullName:"Jeffrey Marliave"},{id:"58447",title:"Mr.",name:"Charles",surname:"Gibbs",slug:"charles-gibbs",fullName:"Charles Gibbs"},{id:"58448",title:"Mrs.",name:"Donna",surname:"Gibbs",slug:"donna-gibbs",fullName:"Donna Gibbs"},{id:"217091",title:"M.Sc.",name:"Laura",surname:"Borden",slug:"laura-borden",fullName:"Laura Borden"}],corrections:null},{id:"60787",title:"Safeguarding Marine Biodiversity in a Changing World: Maltese Small-Scale Fisheries and Alien Species",doi:"10.5772/intechopen.76609",slug:"safeguarding-marine-biodiversity-in-a-changing-world-maltese-small-scale-fisheries-and-alien-species",totalDownloads:904,totalCrossrefCites:1,totalDimensionsCites:2,hasAltmetrics:0,abstract:"Right in the center of the Mediterranean Sea, the Maltese Islands are well situated for monitoring regional marine biodiversity changes. Among the latter are the increasing alien species coming in through the Suez Channel and the Straits of Gibraltar or brought in through various anthropogenic vectors. The non-native species that turn into invasive do not only affect native marine communities but also the aging and shrinking Maltese small-scale fisheries (SSF) community. SSF are predicted to go extinct and with them their well-known colorful artisanal fishing boats with the eyes of Osiris, which were thought to protect them. In the meantime, large-scale fishing activities have been growing through EU and national legislations, promoting profits over long-term conservation of natural resources and cultural heritage of small fishing communities. This chapter considers the relevance of a changing marine environment and the challenges ahead to safeguard Mediterranean biodiversity, which provides its goods and services to man. The role of well-managed sustainable small-scale fisheries in overcoming some of these challenges is considered.",signatures:"Adriana Vella and Noel Vella",downloadPdfUrl:"/chapter/pdf-download/60787",previewPdfUrl:"/chapter/pdf-preview/60787",authors:[{id:"203424",title:"Ph.D.",name:"Adriana",surname:"Vella",slug:"adriana-vella",fullName:"Adriana Vella"},{id:"203509",title:"Dr.",name:"Noel",surname:"Vella",slug:"noel-vella",fullName:"Noel Vella"}],corrections:null},{id:"55991",title:"Biodiversity of Amphipoda Talitridae in Tunisian Wetlands",doi:"10.5772/intechopen.69523",slug:"biodiversity-of-amphipoda-talitridae-in-tunisian-wetlands",totalDownloads:1136,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Although wetlands were remarkable habitats with their fauna and flora diversity, few studies have been devoted to the study of amphipod biodiversity in this ecosystem type. The amphipod communities of six wetland types belonging to 117 stations were studied with respect to species composition, abundance and their relationship with environmental parameters. Amphipods were collected during spring. At each station, eight quadrats of 50 × 50 cm2 were randomly placed. Animals were preserved in alcohol at 70°C. In the laboratory, the specimens collected were identified and counted. Physicochemical parameters (organic matter, particle size, heavy metals) of sampled soils were determined. The results showed that the highest species richness was observed in lagoons with the presence of eight species namely Orchestia montagui, Orchestia gammarellus, Orchestia mediterranea, Orchestia stephenseni, Orchestia cavimana, Platorchestia platensis, Deshayesorchestia deshayesii and Talitrus saltator, whereas in the hill lakes and dams banks, no specimens were collected. The biodiversity of amphipod species depends on climatic (temperature, humidity) and edaphic (organic matter, particle size, heavy metals) factors.",signatures:"Jelassi Raja, Khemaissia Hajer and Nasri-Ammar Karima",downloadPdfUrl:"/chapter/pdf-download/55991",previewPdfUrl:"/chapter/pdf-preview/55991",authors:[{id:"201013",title:"Dr.",name:"Raja",surname:"Jelassi",slug:"raja-jelassi",fullName:"Raja Jelassi"},{id:"202179",title:"Dr.",name:"Hajer",surname:"Khemaissia",slug:"hajer-khemaissia",fullName:"Hajer Khemaissia"},{id:"202180",title:"Prof.",name:"Karima",surname:"Nasri-Ammar",slug:"karima-nasri-ammar",fullName:"Karima Nasri-Ammar"}],corrections:null},{id:"55746",title:"Biodiversity Restoration and Renewable Energy from Hydropower: Conflict or Synergy?",doi:"10.5772/intechopen.69134",slug:"biodiversity-restoration-and-renewable-energy-from-hydropower-conflict-or-synergy-",totalDownloads:934,totalCrossrefCites:1,totalDimensionsCites:1,hasAltmetrics:1,abstract:"Hydropower plants have a negative impact on biodiversity by transforming stream habitat and hydrology and thereby affecting aquatic organisms negatively. The negative effects can be mitigated by releasing water into the old river bed. This study investigates if the measure of releasing water creates costs and if ecological conditions at the old river bed contribute to such an impact. To this end, we used the cost-minimization framework in economics for deriving hypotheses. Tests were made with data from a survey to 76 hydropower plants in Sweden with questions on existence of a cost, size of the plant, type of water release from reservoirs, characteristics of the dried downstream old river bed, and official statistics on ecological status of the downstream dried segments. The results showed that 42% of the plants reported no cost, measured as impact on electricity production, from release of water into downstream old river bed. We applied logit and probit models to explain the probability of a cost. Significant results were obtained were the electricity produced and program for minimum water discharges increase the probability of loss in electricity production, but favorable ecological conditions in the old river bed decrease the probability of a cost.",signatures:"Wondmagegn Tafesse Tirkaso, Ing‐Marie Gren, Leonard Sandin,\nJoel Segersten, David Spjut and Erik Degerman",downloadPdfUrl:"/chapter/pdf-download/55746",previewPdfUrl:"/chapter/pdf-preview/55746",authors:[{id:"201941",title:"Prof.",name:"Ing-Marie",surname:"Gren",slug:"ing-marie-gren",fullName:"Ing-Marie Gren"}],corrections:null},{id:"60711",title:"Determinants of Orchid Occurrence: A Czech Example",doi:"10.5772/intechopen.74851",slug:"determinants-of-orchid-occurrence-a-czech-example",totalDownloads:1006,totalCrossrefCites:2,totalDimensionsCites:4,hasAltmetrics:0,abstract:"Orchids are an endangered plant group, protected in the whole world. Questions of their conservation are therefore highly discussed, but not all factors affecting their survival and distribution are known so far. The purpose of this study was to determine the environmental factors influencing the existence of certain orchid species in their localities in our model area—South Bohemia. Our data were analyzed using the MaxEnt program, which produces species distribution models (SDMs) and allows predicting potential occurrence of orchids in yet unknown localities. This program also determines the environmental factors affecting species presence. This is important for better protection of orchids, because only by knowing these factors, we can find new localities or improve management plans. We studied two orchid species growing in South Bohemia: Dactylorhiza majalis and Platanthera bifolia. The main factors affecting their occurrence were the consolidated layer of ecosystems, habitat heterogeneity, cover of arable land, and vertical heterogeneity. We determined areas, where new sites are most likely to be discovered and show them in the maps of the area. This approach can help in finding new localities of orchids and in understanding, which environmental factors influence the occurrence of these endangered orchid species.",signatures:"Zuzana Štípková, Kristina Kosánová, Dušan Romportl and Pavel\nKindlmann",downloadPdfUrl:"/chapter/pdf-download/60711",previewPdfUrl:"/chapter/pdf-preview/60711",authors:[{id:"61312",title:"Prof.",name:"Pavel",surname:"Kindlmann",slug:"pavel-kindlmann",fullName:"Pavel Kindlmann"},{id:"227131",title:"MSc.",name:"Zuzana",surname:"Štípková",slug:"zuzana-stipkova",fullName:"Zuzana Štípková"},{id:"227132",title:"MSc.",name:"Kristina",surname:"Kosánová",slug:"kristina-kosanova",fullName:"Kristina Kosánová"},{id:"227133",title:"Dr.",name:"Dušan",surname:"Romportl",slug:"dusan-romportl",fullName:"Dušan Romportl"}],corrections:null},{id:"57597",title:"Dark-Colored Forest Bee Apis mellifera in Siberia, Russia: Current State and Conservation of Populations",doi:"10.5772/intechopen.71603",slug:"dark-colored-forest-bee-apis-mellifera-in-siberia-russia-current-state-and-conservation-of-populatio",totalDownloads:951,totalCrossrefCites:0,totalDimensionsCites:2,hasAltmetrics:0,abstract:"A comprehensive research of two dark-colored forest bee populations in Siberia, identified during a screening study, was conducted using morphometric and molecular genetic methods. The first population is an isolated Yenisei population located in the taiga zone in the Krasnoyarsk Territory, on which bees have not been imported for a long time (50–60 years). The second population is located in the northern areas of the Tomsk region, where beekeeping is more developed. All studied bees had a variant PQQ of the COI–COII mtDNA locus. However, some morphometric parameters of some bee colonies deviated from the Apis mellifera mellifera standard, which is probably due to the features of population formation. As a result of the analysis of the variability of 18 microsatellite loci, possible potential DNA markers specific for determining the bee subspecies and/or ecotypes of the dark-colored forest bee have been identified. An algorithm for the search and a comprehensive study of the dark-colored forest bee are proposed.",signatures:"Nadezhda V. Ostroverkhova, Aksana N. Kucher, Olga L. Konusova,\nEkaterina S. Gushchina, Vadim V. Yartsev and Yury L. Pogorelov",downloadPdfUrl:"/chapter/pdf-download/57597",previewPdfUrl:"/chapter/pdf-preview/57597",authors:[{id:"180112",title:"Ph.D.",name:"Nadezhda",surname:"Ostroverkhova",slug:"nadezhda-ostroverkhova",fullName:"Nadezhda Ostroverkhova"},{id:"180249",title:"Ms.",name:"Olga",surname:"Konusova",slug:"olga-konusova",fullName:"Olga Konusova"},{id:"180342",title:"Prof.",name:"Aksana",surname:"Kucher",slug:"aksana-kucher",fullName:"Aksana Kucher"},{id:"222119",title:"Ms.",name:"Ekaterina",surname:"Gushchina",slug:"ekaterina-gushchina",fullName:"Ekaterina Gushchina"},{id:"222120",title:"Dr.",name:"Vadim",surname:"Yartsev",slug:"vadim-yartsev",fullName:"Vadim Yartsev"},{id:"222121",title:"Dr.",name:"Yury",surname:"Pogorelov",slug:"yury-pogorelov",fullName:"Yury Pogorelov"}],corrections:null},{id:"56778",title:"Integration of Ecological and Socioeconomic Factors in Securing Wildlife Dispersal Corridors in the Kavango-Zambezi Transfrontier Conservation Area, Southern Africa",doi:"10.5772/intechopen.70443",slug:"integration-of-ecological-and-socioeconomic-factors-in-securing-wildlife-dispersal-corridors-in-the-",totalDownloads:1116,totalCrossrefCites:1,totalDimensionsCites:4,hasAltmetrics:1,abstract:"Transfrontier conservation areas (TFCAs) are being established throughout southern Africa to integrating biodiversity conservation and rural development at the transboundary landscape scale. Among the nine TFCAs that have been established over the past 20 years, the Kavango-Zambezi (KAZA) TFCA) is the most grandiose in terms of size (≈ 520,000 Km2), number of partner countries involved (five), elephant (Loxodonta africana) population (≈ 199,031, which is the largest on the African continent), and encompasses 36 protected areas of various categories, interspaced by communal and private lands. The TFCA concept aims to ensure that key ecological processes continue to function where borders have divided ecosystems, and wildlife migration corridors. Attainment of this ecological objective is however being constrained by the anthropogenic threats, mostly poaching, and habitat fragmentation. These threats are being aggravated by the increasing human population, climate variability and underdeveloped rural livelihoods. To restore ecological processes, the following tactics have been recommended: (a) strengthening of transboundary law enforcement to effectively reduce poaching, and illegal offtake of timber; (b) establishment of “Stepping Stones” in the form of conservancies and fishing protected zones at wildlife crossing point on the major river systems; (c) reducing dependence on wood-fuel, and ensuring sustainable provision of affordable and reliable modern sources of energy; (d) adoption of the commodity-based trade standards in the production of beef for the export market to reduce the impact of veterinary fences on the dispersing wildlife; (e) implementation of early-season burning around all the sensitive biomes to protect them from the destructive late dry season fires; (f) adoption of conservation agriculture as a tool for improving land husbandry, intensification of agriculture, and decreasing the likelihood of cutting down forested areas to plant new agriculture fields; and (g) reducing the impact of climate variability on wildlife by providing artificial water – guided by environmental impact assessments. To enhance the socioeconomic development of the local communities and win them as allies in securing the wildlife dispersal corridors, the following actions should be adopted: (a) promotion of community-private partnerships in ecotourism development – alongside the establishment of a revolving loan fund to enable local communities’ access flexible source of capital for investment in ecotourism and auxiliary business opportunities; (b) promotion of biodiversity stewardship as an incentive for the local communities to commit their land to the sustenance of the wildlife dispersal corridors; (c) reducing human wildlife conflicts, through macro, meso and micro-level land-use planning to spatially delineate land committed to various categories, including protected areas, wildlife dispersal areas, and developed and communal areas; and (d) promotion of harmonised enabling policies and legislation to facilitate slowing down of human population growth, which is one of the prime triggers of habitat fragmentation in the KAZA TFCA.",signatures:"Simon M. Munthali, Nicholas Smart, Victor Siamudaala, Morris\nMtsambiwa and Eleanor Harvie",downloadPdfUrl:"/chapter/pdf-download/56778",previewPdfUrl:"/chapter/pdf-preview/56778",authors:[{id:"76161",title:"Dr.",name:"Simon Muchina",surname:"Munthali",slug:"simon-muchina-munthali",fullName:"Simon Muchina Munthali"}],corrections:null},{id:"61062",title:"Usefulness of Plant Biodiversity in the Cities of Togo",doi:"10.5772/intechopen.76776",slug:"usefulness-of-plant-biodiversity-in-the-cities-of-togo",totalDownloads:1258,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"In an increasingly urbanized environment, the need for greenery and flowers is being more and more felt for esthetic reasons and ecological benefits. In Togo, more than six hundred species of horticultural plants are identified and composed of approximately 59% of dicotyledons (49 families, 145 genera, and 315 species) and 37.37% of monocotyledons. Pteridophytes and gymnosperms account for less than 6%. The spectrum of morphological types indicates that herbs are account for 55%, while trees and shrubs represent 15%. More than 50% of the species of this flora is exotic horticulture. A species distribution is made according to their decorative parts and their place of use. Across the country, 55 plantings are recorded and unevenly distributed in cities. Apart from their ornamental purpose, ornamental plants are used for feeding, traditional and industrial cosmetics in psychotherapy, horticultural therapy, and in traditional and conventional medicine. In this study, 79 species from 39 families are reported as medicinal plants. The Apocynaceae and Fabaceae (six species), the Euphorbiaceae and Liliaceae (five species), the Arecaceae and Verbenaceae (four species) are the best represented families. Production systems in ornamental horticulture in Togo are very diverse in terms of speculation, access to land (variable surfaces, direct or indirect forms of tenure, acquisition methods, land use, etc.) and socio-economic profiles of farmers (men, women, young, old, people with little or no qualifications, rural to urban, etc.). The family horticultural production system, which represents over 90% of 55 horticultural farms of this study, is the main production system. It is characterized by areas of less than 0.1 hectare and farms in relative land insecurity (97% of land used belongs to the state). Throughout the system, there is a salaried labor representing 5–8% of turnover. Temporary and permanent employees are paid on weekends or at the end of the month. Farmers use gardening equipment and processing plant more or less modern including clippers, shears, pruners, and sprayers. Production units provide direct employment (more than 3 employees per unit) and directly to several hundred people. Horticulture in urban and peri-urban areas improves the living conditions of farmers (income) and the population (embellishment of streets, maintenance or creation of green area buffer) despite some negative externalities associated particularly with the use of prohibited pesticides and uncontrolled use of spaces along the roads. Its survival is threatened by many constraints, including the extension of urban housing and road building. In Togo, beneficial effects of ornamental horticulture may be more noticeable if the political authorities, private stakeholders, and the researchers work together to organize the sector. It could thus participate effectively in the formal economy and the emergence of true development plans at the municipal level.",signatures:"Radji Raoufou and Kokou Kouami",downloadPdfUrl:"/chapter/pdf-download/61062",previewPdfUrl:"/chapter/pdf-preview/61062",authors:[{id:"160134",title:"Dr.",name:"Aboudou Raoufou",surname:"Radji",slug:"aboudou-raoufou-radji",fullName:"Aboudou Raoufou Radji"}],corrections:null},{id:"57889",title:"Towards an Integrative Taxonomy of the Genus Alstroemeria (Alstroemeriaceae) in Chile: A Comprehensive Review",doi:"10.5772/intechopen.71823",slug:"towards-an-integrative-taxonomy-of-the-genus-alstroemeria-alstroemeriaceae-in-chile-a-comprehensive-",totalDownloads:1243,totalCrossrefCites:5,totalDimensionsCites:6,hasAltmetrics:0,abstract:"The genus Alstroemeria encompasses approximately 80 species endemic to South America, with 2 centers of diversity (Chile and Brazil). In Chile, Alstroemeria represents one of the most diverse genera of vascular monocotyledons, comprising more than 50 recognized or accepted taxa (36 species, 11 subspecies and 10 varieties) from which ca. 82% are endemic to the Mediterranean zone of central Chile, one of the world’s diversity hotspots. The taxonomy of the genus is very difficult due to the great variability of the vegetative and floral traits. Moreover, a number of taxa have been recently described and several nomenclatural changes have been proposed. In order to elucidate the taxonomy of some Chilean complexes of Alstroemeria, an integrative approach including morphology, colorimetry, cytogenetic, multivariate statistical analyses of morphological variation and DNA-molecular studies have been conducted. In this chapter, we review the literature concerning these approaches; a checklist of the species growing in Chile is provided including all published names, references to the original protologues, accepted names, synonyms and the biogeographic status (endemic or native) of the accepted taxa; maps illustrating the diversity of the genus in South America and its distribution in Chile were constructed.",signatures:"Victor L. Finot, Carlos M. Baeza, Eduardo Ruiz, Oscar Toro and Pedro\nCarrasco",downloadPdfUrl:"/chapter/pdf-download/57889",previewPdfUrl:"/chapter/pdf-preview/57889",authors:[{id:"51657",title:"Dr.",name:"Victor",surname:"Finot",slug:"victor-finot",fullName:"Victor Finot"},{id:"218963",title:"Dr.",name:"Carlos M.",surname:"Baeza",slug:"carlos-m.-baeza",fullName:"Carlos M. Baeza"},{id:"218964",title:"Dr.",name:"Eduardo",surname:"Ruiz",slug:"eduardo-ruiz",fullName:"Eduardo Ruiz"},{id:"224011",title:"Mr.",name:"Pedro",surname:"Carrasco",slug:"pedro-carrasco",fullName:"Pedro Carrasco"},{id:"224013",title:"Dr.",name:"Oscar",surname:"Toro",slug:"oscar-toro",fullName:"Oscar Toro"}],corrections:null},{id:"60808",title:"Ecosystem Services Provided by the Little Things That Run the World",doi:"10.5772/intechopen.74847",slug:"ecosystem-services-provided-by-the-little-things-that-run-the-world",totalDownloads:1712,totalCrossrefCites:5,totalDimensionsCites:10,hasAltmetrics:1,abstract:"Highest extinction risk and consequently biodiversity loss are predicted to occur in invertebrates, specifically insects, and these declines are expected to cascade onto ecosystem functioning and human well-being. Although this knowledge is intrinsically present in more traditional communities, in more urban environments, mapping ecosystem services can be an important tool to raise people’s awareness on the importance of preserving insect diversity. After an extensive revision of the available literature, we used a rule-based approach to assess the provisioning, regulating and maintenance, and cultural services delivered by insects. We followed the Common International Classification of Ecosystem Services (CICES) and identified several potential indicators that may help underpin the mapping and valuation of the services delivered by insects. From our search, we extracted a total of 73 indicators, divided as 17 Provisional indicators, 27 Regulation and Maintenance indicators, and 29 Cultural indicators. We concluded that insects are providers of services in the three major ‘Sections’ of ecosystem services defined by CICES. Despite the lack of recognition of provisioning and cultural services, the indicators provided may help to raise awareness on the importance of the little things the run the world, in order to preserve traditional and technological uses of insects and their services.",signatures:"Olga Maria Correia Chitas Ameixa, António Onofre Soares, Amadeu\nM.V.M. Soares and Ana I. Lillebø",downloadPdfUrl:"/chapter/pdf-download/60808",previewPdfUrl:"/chapter/pdf-preview/60808",authors:[{id:"194620",title:"Prof.",name:"Amadeu",surname:"M.V.M. Soares",slug:"amadeu-m.v.m.-soares",fullName:"Amadeu M.V.M. Soares"},{id:"220986",title:"Dr.",name:"Olga",surname:"Ameixa",slug:"olga-ameixa",fullName:"Olga Ameixa"},{id:"220987",title:"Dr.",name:"António",surname:"Soares",slug:"antonio-soares",fullName:"António Soares"},{id:"220988",title:"Dr.",name:"Ana",surname:"Lillebø",slug:"ana-lillebo",fullName:"Ana Lillebø"}],corrections:null},{id:"60753",title:"Commercial Harvesting of Marula (Sclerocarya Birrea) in Swaziland: A Quest for Sustainability",doi:"10.5772/intechopen.76606",slug:"commercial-harvesting-of-marula-sclerocarya-birrea-in-swaziland-a-quest-for-sustainability",totalDownloads:1250,totalCrossrefCites:1,totalDimensionsCites:2,hasAltmetrics:0,abstract:"All across sub-Saharan Africa rural communities, and especially women, are harvesting natural products for income generation purposes. In recent times, the degradation of ecosystems in terms of loss of biodiversity has become a major concern, especially when the harvesting of the species in question has become commercialized as is the case of marula harvesting in Swaziland. This chapter reports on some of the findings of a study conducted to explore the impact of commercial harvesting on the future availability of marula. If current levels of harvesting are unchecked, overconsumption or even depletion of marula in Swaziland will deepen the existing poverty levels among the rural poor, particularly women, who are proportionately more dependent on marula for their livelihoods.",signatures:"Alfred Francis Murye and André J. Pelser",downloadPdfUrl:"/chapter/pdf-download/60753",previewPdfUrl:"/chapter/pdf-preview/60753",authors:[{id:"50604",title:"Prof.",name:"Andre",surname:"Pelser",slug:"andre-pelser",fullName:"Andre Pelser"},{id:"228756",title:"Dr.",name:"Alfred",surname:"Murye",slug:"alfred-murye",fullName:"Alfred Murye"}],corrections:null},{id:"61616",title:"Synopsis of Mangle Species in Mexico",doi:"10.5772/intechopen.76975",slug:"synopsis-of-mangle-species-in-mexico",totalDownloads:1187,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"The objective of this documentary research work is to contribute to better knowledge of the mangrove species that are located in our country, as well as to provide readers with written and illustrated information on these species. The species described are Avicennia bicolor Standl., Avicennia germinans (L.) L., Conocarpus erectus L., Laguncularia racemosa (L.) Gaertner, Rhizophora harrisonii Leechm., and Rhizophora mangle L. The mangroves present in Mexico comprise three families, four genera, and six species. They have a distribution in the 17 coastal states of the country, the largest number of species in the state of Chiapas. The data obtained that are included in the information are identity, distribution, taxonomy, diagnosis, distribution, uses, and protection. In the case of Avicennia bicolor Standl. and Rhizophora Harrisonii Leechm., the information is more scarce, since their distribution is limited to the state of Chiapas.",signatures:"Basáñez Muñoz Agustín de Jesús, Serrano Solis Arturo, Martínez\nCortés Esmeralda, Cuervo López Liliana, Capistrán Barradas\nAscención and Naval Ávila Celina",downloadPdfUrl:"/chapter/pdf-download/61616",previewPdfUrl:"/chapter/pdf-preview/61616",authors:[{id:"120695",title:"Dr.",name:"Arturo",surname:"Serrano",slug:"arturo-serrano",fullName:"Arturo Serrano"},{id:"219218",title:"M.Sc.",name:"Agustin",surname:"Basañez",slug:"agustin-basanez",fullName:"Agustin Basañez"},{id:"231695",title:"Ms.",name:"Esmeralda",surname:"Martinez",slug:"esmeralda-martinez",fullName:"Esmeralda Martinez"},{id:"231696",title:"Dr.",name:"Liliana",surname:"Cuervo",slug:"liliana-cuervo",fullName:"Liliana Cuervo"},{id:"231697",title:"Dr.",name:"Ascencion",surname:"Capistran",slug:"ascencion-capistran",fullName:"Ascencion Capistran"},{id:"231698",title:"Dr.",name:"Celina",surname:"Naval",slug:"celina-naval",fullName:"Celina Naval"}],corrections:null},{id:"57678",title:"Positive Rules Can Lead to Positive Behaviours: Students’ Perceptions of Messages on Information Boards in Protected Areas",doi:"10.5772/intechopen.71602",slug:"positive-rules-can-lead-to-positive-behaviours-students-perceptions-of-messages-on-information-board",totalDownloads:1024,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"The main purpose of this research was to investigate primary school students’ perceptions of pictograms displayed in protected areas. The aim was to determine if and how students understand the concept of protected areas and the role pictograms and comic strips, displayed on information panels in protected areas, play in understanding (un)acceptable human activities in such areas. Altogether, 353 fourth-graders and fifth-graders (8–11 years of age) from central Slovenia filled in the questionnaire. Students were randomly assigned to one of three treatment groups faced with a set of positive pictograms, negative pictograms or a comic strip and asked to answer two open questions. Many students participating in the research perceived protected areas as areas where many human activities are prohibited. The concept of protected areas was sufficiently understood by 36.8% of the students. The results confirmed the main hypothesis that students faced with a set of positive pictograms perceived protected areas as areas where a number of human activities are acceptable, but they also realized which activities are unacceptable. Similar results were obtained for students faced with the comic strip. On the other hand, those faced with negative pictograms tended to be more preoccupied with listing unacceptable human activities and were able to list significantly fewer acceptable activities.",signatures:"Gregor Torkar, Saša Mezek and Janez Jerman",downloadPdfUrl:"/chapter/pdf-download/57678",previewPdfUrl:"/chapter/pdf-preview/57678",authors:[{id:"216053",title:"Dr.",name:"Gregor",surname:"Torkar",slug:"gregor-torkar",fullName:"Gregor Torkar"}],corrections:null},{id:"56942",title:"Prey Selection of Pseudorasbora parva (Temminck and Schlegel, 1846) in a Freshwater Ecosystem (Lake Eğirdir/Turkey)",doi:"10.5772/intechopen.70471",slug:"prey-selection-of-pseudorasbora-parva-temminck-and-schlegel-1846-in-a-freshwater-ecosystem-lake-e-ir",totalDownloads:1223,totalCrossrefCites:1,totalDimensionsCites:2,hasAltmetrics:0,abstract:"In the present study, food spectrum of the topmouth gudgeon, Pseudorasbora parva and it food preference to different prey species were investigated in Lake Eğirdir, Turkey. Fish specimens were collected in April, May, June, July and August (2010–2011). Diet analysis was carried out on 88 fish specimens. The benthic larvae of Chironomus sp., the corophiid amphipod Chelicorophium curvispinum and the zooplankter Nitocra hibernica were found to dominate food items. In addition, the fish consumed zooplankton (especially cladocera and copepoda), phytoplankton, annelida, malacostraca and insecta species. Unindentified eggs were also found in the stomachs. Phytoplankton, particularly Gomphonema (V = 0.255, X2 = 13.058, p < 0.01) sp. due to its abundance, was a significant component in the 8.0- to 8.9-cm length sized topmouth gudgeon with distinct preference to the cladocerans Daphnia cucullata (V = 0.191, X2 = 7.331, p < 0.01) and Bosmina longirostris (V = 0.228, X2 = 10.404, p < 0.01), annelids (V = 0.201, X2 = 8.105, p < 0.01) and Trichoptera larvae (V = 0.157, X2 = 4.963, p < 0.01) in 2010 food diet. In return, invasive species topmouth gudgeon is preferable to Cladoceran in the diet of other planktivorous fish (especially Anatolian endemics Aphanius anatoliae type) in Lake Eğirdir. High value of Shannon diversity index was determined in May (H′=1.80) and August (H′=1.70). Fullness index was highest in April, whereas feeding density was lowest in July. Schoener’s indices of diet overlap were estimated between different size classes and months for topmouth gudgeon. The high value of these indices (C = 0.87) indicates that the species principally feeds on the similar in the size classes >8 cm (8.0–8.9 cm, 9.0–9.9 cm, 10.0–10.9 cm, 11.0–11.9 cm).",signatures:"Meral Apaydin Yağci, Ahmet Alp, Abdulkadir Yağci, Vedat Yeğen\nand Mehmet Ali Turan Koçer",downloadPdfUrl:"/chapter/pdf-download/56942",previewPdfUrl:"/chapter/pdf-preview/56942",authors:[{id:"183600",title:"Associate Prof.",name:"Meral",surname:"Apaydın Yağcı",slug:"meral-apaydin-yagci",fullName:"Meral Apaydın Yağcı"},{id:"207341",title:"Prof.",name:"Ahmet",surname:"Alp",slug:"ahmet-alp",fullName:"Ahmet Alp"},{id:"207342",title:"MSc.",name:"Abdulkadir",surname:"Yağcı",slug:"abdulkadir-yagci",fullName:"Abdulkadir Yağcı"},{id:"207343",title:"Dr.",name:"Vedat",surname:"Yeğen",slug:"vedat-yegen",fullName:"Vedat Yeğen"},{id:"207344",title:"Dr.",name:"Mehmet Ali Turan",surname:"Koçer",slug:"mehmet-ali-turan-kocer",fullName:"Mehmet Ali Turan Koçer"}],corrections:null},{id:"56977",title:"Importance of Underutilized Field Crops for Increasing Functional Biodiversity",doi:"10.5772/intechopen.70472",slug:"importance-of-underutilized-field-crops-for-increasing-functional-biodiversity",totalDownloads:1203,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:"Despite the suggestions to include two or three crops into crop rotation that is widely considered to support the richer biodiversity on fields, industrial field crop production systems are still based mainly on monoculture, where the farmers produce permanently mainly one crop. Review and analyses of different possibilities showed that more diverse functional (also important for diverse nutritional and health products of food) biodiversity of underutilized field crops needs to be established, especially if beneficial social and economic effects of introducing underutilized crops into small-scale farms are taken into account. We can conclude that functional biodiversity based on rich crop rotations associated with underutilized crops increases biodiversity in the soil and has an effect on richer and sustainable behavior of cultural plants with good balance of pests and plant diseases.",signatures:"Franc Bavec, Urška Lisec and Martina Bavec",downloadPdfUrl:"/chapter/pdf-download/56977",previewPdfUrl:"/chapter/pdf-preview/56977",authors:[{id:"170270",title:"Prof.",name:"Franc",surname:"Bavec",slug:"franc-bavec",fullName:"Franc Bavec"}],corrections:null}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},subseries:null,tags:null},relatedBooks:[{type:"book",id:"2719",title:"Biodiversity Enrichment in a Diverse World",subtitle:null,isOpenForSubmission:!1,hash:"819b482d198dba210de22b9d66be3d79",slug:"biodiversity-enrichment-in-a-diverse-world",bookSignature:"Gbolagade Akeem Lameed",coverURL:"https://cdn.intechopen.com/books/images_new/2719.jpg",editedByType:"Edited by",editors:[{id:"142349",title:"Dr.",name:"Lameed",surname:"Gbolagade Akeem",slug:"lameed-gbolagade-akeem",fullName:"Lameed Gbolagade Akeem"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1369",title:"Changing Diversity in Changing Environment",subtitle:null,isOpenForSubmission:!1,hash:"a9f3c1cbb7119a88079a1c07838455f8",slug:"changing-diversity-in-changing-environment",bookSignature:"Oscar Grillo and Gianfranco Venora",coverURL:"https://cdn.intechopen.com/books/images_new/1369.jpg",editedByType:"Edited by",editors:[{id:"51992",title:"PhD.",name:"Oscar",surname:"Grillo",slug:"oscar-grillo",fullName:"Oscar Grillo"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3821",title:"Biodiversity",subtitle:"The Dynamic Balance of the Planet",isOpenForSubmission:!1,hash:"7233b40924b0a40793d6f2bd6db38356",slug:"biodiversity-the-dynamic-balance-of-the-planet",bookSignature:"Oscar Grillo",coverURL:"https://cdn.intechopen.com/books/images_new/3821.jpg",editedByType:"Edited by",editors:[{id:"51992",title:"PhD.",name:"Oscar",surname:"Grillo",slug:"oscar-grillo",fullName:"Oscar Grillo"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1850",title:"Diversity of Ecosystems",subtitle:null,isOpenForSubmission:!1,hash:"ee698d03ccce547bc8cdb4f13ebb2822",slug:"diversity-of-ecosystems",bookSignature:"Mahamane Ali",coverURL:"https://cdn.intechopen.com/books/images_new/1850.jpg",editedByType:"Edited by",editors:[{id:"103960",title:"Prof.",name:"Mahamane",surname:"Ali",slug:"mahamane-ali",fullName:"Mahamane Ali"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3007",title:"Biodiversity Conservation and Utilization in a Diverse World",subtitle:null,isOpenForSubmission:!1,hash:"29534b458d8a76a366f9ab1e70038d1a",slug:"biodiversity-conservation-and-utilization-in-a-diverse-world",bookSignature:"Gbolagade Akeem Lameed",coverURL:"https://cdn.intechopen.com/books/images_new/3007.jpg",editedByType:"Edited by",editors:[{id:"142349",title:"Dr.",name:"Lameed",surname:"Gbolagade Akeem",slug:"lameed-gbolagade-akeem",fullName:"Lameed Gbolagade Akeem"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"2272",title:"The Functioning of Ecosystems",subtitle:null,isOpenForSubmission:!1,hash:"7e5a5f3530094a30a6870fab307c18cb",slug:"the-functioning-of-ecosystems",bookSignature:"Mahamane Ali",coverURL:"https://cdn.intechopen.com/books/images_new/2272.jpg",editedByType:"Edited by",editors:[{id:"103960",title:"Prof.",name:"Mahamane",surname:"Ali",slug:"mahamane-ali",fullName:"Mahamane Ali"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"6893",title:"Endemic Species",subtitle:null,isOpenForSubmission:!1,hash:"3290be83fff5bc015f5bd3d78ae9c6c7",slug:"endemic-species",bookSignature:"Eusebio Cano Carmona, Carmelo Maria Musarella and Ana Cano Ortiz",coverURL:"https://cdn.intechopen.com/books/images_new/6893.jpg",editedByType:"Edited by",editors:[{id:"87846",title:"Dr.",name:"Eusebio",surname:"Cano Carmona",slug:"eusebio-cano-carmona",fullName:"Eusebio Cano Carmona"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1591",title:"Infrared 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by",editors:[{id:"4782",title:"Prof.",name:"Bishnu",surname:"Pal",slug:"bishnu-pal",fullName:"Bishnu Pal"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"371",title:"Abiotic Stress in Plants",subtitle:"Mechanisms and Adaptations",isOpenForSubmission:!1,hash:"588466f487e307619849d72389178a74",slug:"abiotic-stress-in-plants-mechanisms-and-adaptations",bookSignature:"Arun Shanker and B. 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\r\n\tThe importance of education and care in the early stages of life has long been debated and documented. However, in a world that faces ongoing crises and challenges, early childhood education is in a constant quest for pedagogies that respond to acute problems such as:
\r\n\r\n\ta. Environmental crises which result in food & water shortages
\r\n\tb. The growth of digital environments which can educate and empower as well as exploit and destroy (mobile learning, STEM education, tablets, etc.).
\r\n\tc. Social, racial, class, and gender-based discriminations that restrict the developmental potential and the prosperity perspectives
\r\n\td. Health hazards and illnesses such as the laters COVID-19 pandemic.
\r\n\te. Armed conflicts with casualties and displacements of populations seeking refuge
\r\n\tf. Lack of physical spaces that will support and nourish development and learning, etc.
\r\n\tEducation in the post-modern era strives to address the above issues and develop policies, curricula, methodologies, and strategies to contribute to an environmentally and socially sustainable future. It embraces multiple perspectives and worldviews and seeks to touch on inequalities and discriminations in favor of equity. In this direction, children’s s agency lies at the heart of democratic approaches. Educational processes adopt forms of interactions that actualize learning as “becoming” and place it in a continuum between past, present, and future. This book intends to feature innovative approaches that employ transformative elements (targets, methods, materials, ideas, etc.) and embrace the concept of child development as “becoming” in an ever-changing and challenging world.
\r\n\r\n\tWe invite authors to contribute original research or research review papers that present innovative approaches addressing personal and social transformation. All aspects of early childhood education will be considered, including research methodology for the early years.
",isbn:"978-1-80355-949-0",printIsbn:"978-1-80355-948-3",pdfIsbn:"978-1-80355-950-6",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!1,isSalesforceBook:!1,isNomenclature:!1,hash:"351c41dca5c8c997f15e758f2e035178",bookSignature:"Dr. Maria Ampartzaki and Associate Prof. Michail Kalogiannakis",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/11281.jpg",keywords:"Early Childhood Education, Preschool, STEAM, Environmental Sustainability, Social Sciences, Social Sustainability, ICT, Digital Devices, Education for Equity, Gender Issues, Post-modern Epistemology, Social Constructivism",numberOfDownloads:65,numberOfWosCitations:0,numberOfCrossrefCitations:0,numberOfDimensionsCitations:0,numberOfTotalCitations:0,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"November 16th 2021",dateEndSecondStepPublish:"December 14th 2021",dateEndThirdStepPublish:"February 12th 2022",dateEndFourthStepPublish:"May 3rd 2022",dateEndFifthStepPublish:"July 2nd 2022",dateConfirmationOfParticipation:null,remainingDaysToSecondStep:"8 months",secondStepPassed:!0,areRegistrationsClosed:!0,currentStepOfPublishingProcess:5,editedByType:null,kuFlag:!1,biosketch:"Dr. Maria Ampartzaki is an Assistant Professor in Early Childhood Education in the Department of Preschool Education at the University of Crete. Her research interests include ICT in education, science education in the early years, inquiry-based and art-based learning, teachers’ professional development, action research, and the Pedagogy of Multiliteracies, among others. She has run and participated in several funded and non-funded projects on the teaching of Science, Social Sciences, and ICT in education.",coeditorOneBiosketch:"Michail Kalogiannakis is an Associate Professor of the Department of Preschool\r\nEducation, University of Crete in Greece. He graduated from the Physics Department\r\nof the University of Crete and continued his post-graduate studies at the University\r\nParis-7 and University Paris-5 and received his Ph.D. degree at the University Paris 5.\r\nHis research interests include science education in early childhood, science teaching\r\nand learning, e-learning, the use of ICT in science education, and games simulations.",coeditorTwoBiosketch:null,coeditorThreeBiosketch:null,coeditorFourBiosketch:null,coeditorFiveBiosketch:null,editors:[{id:"422488",title:"Dr.",name:"Maria",middleName:null,surname:"Ampartzaki",slug:"maria-ampartzaki",fullName:"Maria Ampartzaki",profilePictureURL:"https://mts.intechopen.com/storage/users/422488/images/system/422488.jpg",biography:"Dr Maria Ampartzaki is an Assistant Professor in Early Childhood Education in the Department of Preschool Education at the University of Crete. Her research interests include ICT in education, science education in the early years, inquiry-based and art-based learning, teachers’ professional development, action research, and the Pedagogy of Multiliteracies, among others. She has run and participated in several funded and non-funded projects on the teaching of Science, Social Sciences, and ICT in education. She also has the experience of participating in five Erasmus+ projects.",institutionString:"University of Crete",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"0",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"University of Crete",institutionURL:null,country:{name:"Greece"}}}],coeditorOne:{id:"260066",title:"Associate Prof.",name:"Michail",middleName:null,surname:"Kalogiannakis",slug:"michail-kalogiannakis",fullName:"Michail Kalogiannakis",profilePictureURL:"https://mts.intechopen.com/storage/users/260066/images/system/260066.jpg",biography:"Michail Kalogiannakis is an Associate Professor of the Department of Preschool Education, University of Crete, and an Associate Tutor at School of Humanities at the Hellenic Open University. He graduated from the Physics Department of the University of Crete and continued his post-graduate studies at the University Paris 7-Denis Diderot (D.E.A. in Didactic of Physics), University Paris 5-René Descartes-Sorbonne (D.E.A. in Science Education) and received his Ph.D. degree at the University Paris 5-René Descartes-Sorbonne (PhD in Science Education). His research interests include science education in early childhood, science teaching and learning, e-learning, the use of ICT in science education, games simulations, and mobile learning. He has published over 120 articles in international conferences and journals and has served on the program committees of numerous international conferences.",institutionString:"University of Crete",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"0",totalChapterViews:"0",totalEditedBooks:"0",institution:{name:"University of Crete",institutionURL:null,country:{name:"Greece"}}},coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"23",title:"Social Sciences",slug:"social-sciences"}],chapters:[{id:"81575",title:"Caring about Early Childhood Education",slug:"caring-about-early-childhood-education",totalDownloads:15,totalCrossrefCites:0,authors:[null]},{id:"80874",title:"Postmodernist Ideas and Their Translation into a Critical Pedagogy for Young Children",slug:"postmodernist-ideas-and-their-translation-into-a-critical-pedagogy-for-young-children",totalDownloads:38,totalCrossrefCites:0,authors:[{id:"338161",title:"Dr.",name:"John",surname:"Wilkinson",slug:"john-wilkinson",fullName:"John Wilkinson"}]},{id:"82431",title:"Next-Generation Science and Engineering Teaching Practices in a Preschool Classroom",slug:"next-generation-science-and-engineering-teaching-practices-in-a-preschool-classroom",totalDownloads:12,totalCrossrefCites:0,authors:[null]}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},personalPublishingAssistant:{id:"440212",firstName:"Elena",lastName:"Vracaric",middleName:null,title:"Ms.",imageUrl:"https://mts.intechopen.com/storage/users/440212/images/20007_n.jpg",email:"elena@intechopen.com",biography:"As an Author Service Manager, my responsibilities include monitoring and facilitating all publishing activities for authors and editors. From chapter submission and review to approval and revision, copyediting and design, until final publication, I work closely with authors and editors to ensure a simple and easy publishing process. I maintain constant and effective communication with authors, editors and reviewers, which allows for a level of personal support that enables contributors to fully commit and concentrate on the chapters they are writing, editing, or reviewing. I assist authors in the preparation of their full chapter submissions and track important deadlines and ensure they are met. I help to coordinate internal processes such as linguistic review, and monitor the technical aspects of the process. As an ASM I am also involved in the acquisition of editors. Whether that be identifying an exceptional author and proposing an editorship collaboration, or contacting researchers who would like the opportunity to work with IntechOpen, I establish and help manage author and editor acquisition and contact."}},relatedBooks:[{type:"book",id:"6942",title:"Global Social Work",subtitle:"Cutting Edge Issues and Critical Reflections",isOpenForSubmission:!1,hash:"222c8a66edfc7a4a6537af7565bcb3de",slug:"global-social-work-cutting-edge-issues-and-critical-reflections",bookSignature:"Bala Raju Nikku",coverURL:"https://cdn.intechopen.com/books/images_new/6942.jpg",editedByType:"Edited by",editors:[{id:"263576",title:"Dr.",name:"Bala",surname:"Nikku",slug:"bala-nikku",fullName:"Bala Nikku"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"6926",title:"Biological Anthropology",subtitle:"Applications and Case Studies",isOpenForSubmission:!1,hash:"5bbb192dffd37a257febf4acfde73bb8",slug:"biological-anthropology-applications-and-case-studies",bookSignature:"Alessio Vovlas",coverURL:"https://cdn.intechopen.com/books/images_new/6926.jpg",editedByType:"Edited by",editors:[{id:"313084",title:"Dr.",name:"Alessio",surname:"Vovlas",slug:"alessio-vovlas",fullName:"Alessio Vovlas"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1591",title:"Infrared Spectroscopy",subtitle:"Materials Science, Engineering and Technology",isOpenForSubmission:!1,hash:"99b4b7b71a8caeb693ed762b40b017f4",slug:"infrared-spectroscopy-materials-science-engineering-and-technology",bookSignature:"Theophile Theophanides",coverURL:"https://cdn.intechopen.com/books/images_new/1591.jpg",editedByType:"Edited by",editors:[{id:"37194",title:"Dr.",name:"Theophile",surname:"Theophanides",slug:"theophile-theophanides",fullName:"Theophile Theophanides"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3161",title:"Frontiers in Guided Wave Optics and Optoelectronics",subtitle:null,isOpenForSubmission:!1,hash:"deb44e9c99f82bbce1083abea743146c",slug:"frontiers-in-guided-wave-optics-and-optoelectronics",bookSignature:"Bishnu Pal",coverURL:"https://cdn.intechopen.com/books/images_new/3161.jpg",editedByType:"Edited by",editors:[{id:"4782",title:"Prof.",name:"Bishnu",surname:"Pal",slug:"bishnu-pal",fullName:"Bishnu Pal"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"371",title:"Abiotic Stress in Plants",subtitle:"Mechanisms and Adaptations",isOpenForSubmission:!1,hash:"588466f487e307619849d72389178a74",slug:"abiotic-stress-in-plants-mechanisms-and-adaptations",bookSignature:"Arun Shanker and B. Venkateswarlu",coverURL:"https://cdn.intechopen.com/books/images_new/371.jpg",editedByType:"Edited by",editors:[{id:"58592",title:"Dr.",name:"Arun",surname:"Shanker",slug:"arun-shanker",fullName:"Arun Shanker"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3092",title:"Anopheles mosquitoes",subtitle:"New insights into malaria vectors",isOpenForSubmission:!1,hash:"c9e622485316d5e296288bf24d2b0d64",slug:"anopheles-mosquitoes-new-insights-into-malaria-vectors",bookSignature:"Sylvie Manguin",coverURL:"https://cdn.intechopen.com/books/images_new/3092.jpg",editedByType:"Edited by",editors:[{id:"50017",title:"Prof.",name:"Sylvie",surname:"Manguin",slug:"sylvie-manguin",fullName:"Sylvie Manguin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"72",title:"Ionic Liquids",subtitle:"Theory, Properties, New Approaches",isOpenForSubmission:!1,hash:"d94ffa3cfa10505e3b1d676d46fcd3f5",slug:"ionic-liquids-theory-properties-new-approaches",bookSignature:"Alexander Kokorin",coverURL:"https://cdn.intechopen.com/books/images_new/72.jpg",editedByType:"Edited by",editors:[{id:"19816",title:"Prof.",name:"Alexander",surname:"Kokorin",slug:"alexander-kokorin",fullName:"Alexander Kokorin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"2270",title:"Fourier Transform",subtitle:"Materials Analysis",isOpenForSubmission:!1,hash:"5e094b066da527193e878e160b4772af",slug:"fourier-transform-materials-analysis",bookSignature:"Salih Mohammed Salih",coverURL:"https://cdn.intechopen.com/books/images_new/2270.jpg",editedByType:"Edited by",editors:[{id:"111691",title:"Dr.Ing.",name:"Salih",surname:"Salih",slug:"salih-salih",fullName:"Salih Salih"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"117",title:"Artificial Neural Networks",subtitle:"Methodological Advances and Biomedical Applications",isOpenForSubmission:!1,hash:null,slug:"artificial-neural-networks-methodological-advances-and-biomedical-applications",bookSignature:"Kenji Suzuki",coverURL:"https://cdn.intechopen.com/books/images_new/117.jpg",editedByType:"Edited by",editors:[{id:"3095",title:"Prof.",name:"Kenji",surname:"Suzuki",slug:"kenji-suzuki",fullName:"Kenji Suzuki"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3828",title:"Application of Nanotechnology in Drug Delivery",subtitle:null,isOpenForSubmission:!1,hash:"51a27e7adbfafcfedb6e9683f209cba4",slug:"application-of-nanotechnology-in-drug-delivery",bookSignature:"Ali Demir Sezer",coverURL:"https://cdn.intechopen.com/books/images_new/3828.jpg",editedByType:"Edited by",editors:[{id:"62389",title:"PhD.",name:"Ali Demir",surname:"Sezer",slug:"ali-demir-sezer",fullName:"Ali Demir Sezer"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}]},chapter:{item:{type:"chapter",id:"50181",title:"Radiation Effects in Polyamides",doi:"10.5772/62464",slug:"radiation-effects-in-polyamides",body:'\nPolyamides (PAs) are linear semicrystalline polymers containing amide groups -CO-NH- in the chains. The nomenclature applied for PA uses numbers to describe the number of carbons between acid and amine function groups including the carbon of the carboxylic acid. Two types of polyreactions are used for their preparation. The first, polyaddition, is based on a lactam as the starting reactant. After opening the lactam ring breaking peptide bond, the created end groups -C(O)- and -N(H)- are coupled with -N(H)- and -C(O)- groups originating from other cleaved molecules of the lactam. This is the case of PA-6 when ε-caprolactam is used.\n
The same result can be reached using the corresponding amino acid. However, the cleavage of water molecules is required, which is the characteristic for a polycondensation mechanism. Therefore, polycondensation is the second polyreaction used to prepare PAs. The most commonly applied reaction is the polycondensation of dicarboxylic acids with diamines (e.g., adipic acid with hexamethylene diamine giving PA-66).
In such a case, the structure of the PA corresponds to the repetition of structure unit consisting of one of each monomer, so that they alternate in the chain unlike for a PA chain synthesized from a monomer as single starting reactant. Many demanding applications require a careful control of the synthesis as well as processing conditions considering the resulting molecular mass.
\nVariation of the starting reactants enables a large scale of PAs differing in properties from hard and tough PA to soft and flexible to be acquired. Depending on the type, PAs absorb different amounts of moisture, which affect the mechanical as well as dimensional characteristics. In general, PAs are characterized by high rigidity, hardness, abrasion resistance, thermal stability, good sliding properties, stress cracking resistance, barrier properties against oxygen, smells, and oils. The disadvantages of PA types involve a weak stability in the presence of UV radiation, oxidizing agents, strong acids, and bases, high shrinkage in molten section, degradation in electrical and mechanical properties due to high moisture absorptivity, and high notch sensitivity. The various particular properties of PAs enable various PAs to be processed into various items. They are most frequently used in the textile industry, electrotechnics, and automotive industry as engineering plastics either virgin or composites with modifying fillers. Depending on the type of the product application, the manufacturers can adjust the properties of initial materials to some extent. Besides physical modification, involving admixture of proper additives, the chemical modification of PA can also be applied. According to PA type, a high melting temperature within 170°C up to 290°C occurs. Therefore, the homogenous admixture of intended agents into the melt is possible only for sufficiently thermally stable substances. When the chemical modification of PA requires the generation of radicals (e.g., grafting various functional groups or crosslinking initiated by organic peroxides), then this modification cannot be always carried out in melt due to a weak thermal stability of some substances participating in the process. In particular, peroxides will be thermally destroyed well before the PA is melted. This handicap can be overcome using a proper radiation technology enabling such a modifying process in the solid state. Presenting a technology of one step, the radiation technologies have been largely applied during the last decades and have brought a wider spectrum of properties or design variations.
\nBecause PA-6 and PA-66 comprise most of the world’s market (~80%) [1], the effects of radiation modification involving them have been frequently investigated. Concerning some conflicting reports on electron beam effect on polymers found in scientific sources, in general, it could be said that variations in gel content in PAs irradiated with identical doses may not be the same. The reason is that the competing reactions, chain scission and recombination, can be affected by several factors, among others polymer type with its molecular characteristics. However, under irradiation, the most decisive factors are time and dose rate. The presence of oxygen provokes some side reactions and the consequence is a complex process. The oxygen effect can be hardly eliminated completely even if the irradiation is carried out in an inert atmosphere. Within the simultaneous process of recombination and scission macroradicals, the most important factor is the stationary concentration of the macroradicals.
\nTherefore, although the doses are the same, the results may differ if different electron beam sources and PA types are used. From this aspect, every comparison can be of framing character only. The same can be said regarding γ or proton exposure.
\nThe effect of electron beam on PAs depends on several factors, such as installed parameters of the accelerator, absorbed dose, rate of the dose, environment of irradiation, geometry of irradiated object, temperature, and postradiation treatment. Concerning the environment, air is used mostly and an inert atmosphere is less common but more thrifty towards the polymer. Under irradiation of polymers, free radicals are created. Subsequently, two main actions take place, that is, recombination of the radicals resulting in crosslinking and oxidation resulting in polymer degradation. Both processes run in parallel [2], competing mutually, and the results depend on concrete conditions.
\nWhat exactly occurs when a PA is irradiated with an electron beam? An interaction occurs primarily in hydrocarbon sequences (R). The complete action involves three basic steps: initiation (generation of free radicals), propagation, and termination. In general, the following scheme can describe such processes.
\nInitiation:
Propagation:
The generated radicals can take part in the destruction of the next hydrocarbon sequences, and hydroperoxides start the formation of new radicals and intermediates. In the presence of oxygen, the creation of carbonyl and aldehyde groups is significant as well.
\nTermination:
\nIn the case of PA-6, the splitting of H0 from ethylene group occurs most probably in the vicinity of the –NH–CO– sequence:
\nHowever, abstraction of hydrogen can occur in any other place within the hydrocarbon sequence as well.
\nPropagation takes place according to the above-mentioned steps. Termination of the radicals can occur as follows:
\na) Crosslinking:
b) Disproportionation:
c) Oxidation and following degradation:
Besides the above-mentioned irradiation conditions, the formation of intermediates and final products can be affected by the polymer structure, so that the products can be variable because of some side reactions.
\nIn general, the modification of semicrystalline polymers by energetic radiation in the solid phase below the melting temperature of the crystallites is characterized by changes proceeding preferentially or, in many cases, almost exclusively in the amorphous phase [3,4]. Within the pre-crosslinking phase, there is the branching in the polymer [5] as revealed by the solution viscosity measurement for PA-6 [6,7] and glass fiber-reinforced PA-6 (PA-6/GF) with 30% GF [7], indicating an increase in the molecular weight due to the recombination of macroradicals at the polymer chain centers (Figure 1). Consequently also, viscosity increases in normal cases.
\nDependence of viscosity number for virgin PA-6 and PA-6 in PA-6/GF on electron beam absorbed dose. Adapted from Porubská et al. [
A measurable portion of insoluble gel occurs at approximately 200 kGy (gel point) when the irradiation is conducted in air (Figure 2).
\nDependence of gel content on absorbed electron beam dose for virgin PA-6 and PA-6/GF (30%) composite [
This gel point is confirmed in several studies [7–10], although a low gel content for PA-6 was measured under the 150 kGy dose as well [11,12]. Some specific results in experiments with electron beam irradiation of PA-6 and PA-6,6 tyre cords and calendered fabrics are published by Aytaç et al. [13] when, contrariwise, some decrease in limiting viscosity number with increasing dose was observed within doses of 0 to 75 kGy. The measured data are explained by sufficient time for oxygen to diffuse into the samples during the foregoing calendering as well as by a low dose rate (25 Gy/pass). Under those conditions, radiolytic and oxidative degradation occur. The following strength testing confirmed the objectivity of the results.
\nIrradiation temperature | \n||||
---|---|---|---|---|
RT | \n0.63 | \n0.49 | \n0.39 | \n1.3 | \n
50°C | \n0.60 | \n0.61 | \n0.50 | \n1.2 | \n
70°C | \n0.49 | \n0.46 | \n0.50 | \n0.91 | \n
80°C | \n0.29 | \n0.23 | \n0.40 | \n0.58 | \n
Radiochemical
Besides dose, temperature at the irradiation site also plays a role. As study [10] demonstrated that the crosslinking effect grows with increasing dose and temperature. Corresponding experiments with PA-6 film irradiated over a range of 15 to 1200 kGy (and at a dose rate of 4.48 kGy/min) were carried out at different temperatures from room temperature (RT) to 80°C involving the glass transition temperature (
The ratio
The final amount of the gel in polymer is limited. Generally, in virgin PA, the gel portion grows dramatically beyond the gel point and, in a certain phase, becomes stabilized. The reason is that a balance between the scission and recombination occurs, as the increasing viscosity in the matrix due to crosslinks breaks the mobility of the radicals to recombine. Although the gel content remains the same, the decrease of the swelling [17] or molecular weight between crossbonds [10] with increasing doses indicates that the network becomes denser [7] as seen in \nTable 2.
\nDose (kGy) | \nRT | \n50°C | \n70°C | \n80°C | \n
---|---|---|---|---|
300 | \n41,000 | \n31,500 | \n31,900 | \n40,300 | \n
400 | \n30,800 | \n23,600 | \n23,900 | \n30,250 | \n
600 | \n20,500 | \n15,700 | \n15,900 | \n20,100 | \n
800 | \n15,400 | \n11,800 | \n11,900 | \n15,100 | \n
1000 | \n12,300 | \n9500 | \n9500 | \n12,100 | \n
Average molecular weight between crosslinks (Mc) in PA-6 samples irradiated at different temperatures and doses [10]. With permission of Elsevier.
Irradiation experiments were also conducted in an inert (nitrogen) atmosphere and also with the annealing what led to lower chain scission and increased crosslinking reaction [18].
\nThe crosslinking agents for polymers, including PAs, are molecules that contain two or more double bonds per molecule, such as triallyl cyanurate (TAC), triallyl isocyanurate (TAIC), and trimethylolpropane trimethacrylate (TMPTMA). The energy of electron beam easily cleaves them into radicals formatting cross-bonds. Then, the crosslinking agent can increase the crosslinking rate and shift the gel point to a much lower absorbed dose [6] because of the higher efficiency of free radical production. The presence of a filler (e.g., GF reinforcement) in the PA matrix can also modify the crosslinking rate, even if contrarily [7] in comparison to the crosslinking agents. The filler increases the viscosity of the matrix, which leads to a retardation of the cross-bond formation when compared to virgin PA due to slower macroradical recombination, leaving more time for disproportionation.
\nConcerning gel formation, the application of electron beam irradiation on incompatible polymeric blends or layers in laminates to generate free radicals and the following interaction, the grafting, between the components to improve their compatibility, can vary from case to case. Gel point shifts depending on the character of the polymeric components as well as possible crosslinking agent addition are shown in several works involving PA-6 [19–21]. Rare data on electron beam effect on gel creation in PA-12 can be found for ethylene propylene diene monomer (EPDM)/PA-12/maleated EPDM blend and these do not show any PA-in origin gel up to 200 kGy [22].
\nIt is worth mentioning that crosslinking becomes easier as the number of methylene groups between the amide groups increases [23,24]. This finding is based on the gel measurement on PA-6, PA-610, and PA-12 irradiated under the same conditions. This conclusion is understandable because, as mentioned above, the initiation starts through a hydrocarbon sequence. The longer the hydrocarbon sequence, the more probable the hydrogen abstraction occurs.
\nDifferential scanning calorimetry (DSC) is a useful tool to examine the structural variations in irradiated polymeric materials. Two basic types of data can be obtained from DSC curves, melting or crystallization temperature (
Because PAs are semicrystalline polymers, DSC is used often to characterize them. As mentioned previously, the crosslinking mainly occurs in the amorphous phase. The effects of dose on the
Variation of the first and second melting temperatures with absorbed electron beam dose for virgin PA-6 [
Variation of the first and second melting enthalpy with absorbed electron beam dose for virgin PA-6 [
Such behavior is typical for the second run of irradiated crosslinkable polymers after melting and following the crystallization of a previously crosslinked material. The decrease of
The effect of irradiation on crystallinity is linked with the values of the melting enthalpy directly proportionally, and some decrease is observed for virgin PA-6 with rising dose (Figure 4). The higher value of Δ
DSC melting endotherms of first melting (150–250°C) for PA-6 irradiated with electron beam.
The endotherms of irradiated samples become wider with increasing dose as a consequence of the progressive lamella thinning and amorphization that took place under electron beam irradiation. Additionally, the enlargement in the peaks indicates that the distribution of crystallite size becomes broader while the unit endotherm surface (Δ
PA-6 included in a multilayer film and irradiated in nitrogen applying a dose in the range of 0 to 150 kGy shows only a small total decrease in melting temperature at approximately 1°C and the crystallinity is diminished from 25.3% to 21.5% [18].
\nThe influence of the crosslinking agent TAC on PA-6 irradiated with relatively low doses up to 100 kGy demonstrates a more pronounced effect on
The development of thermal characteristics with dose can somewhat vary when PA is part of a blend or composite. PAs are often used as reinforced composites or filled with various fillers, with GF being the most common reinforcing additive. There is not much information on the crosslinking of reinforced PAs (PA/GF) in the scientific literature. Concerning the changes in the melting temperature (Figure 6) and enthalpy of PA-6/GF (Figure 7) with rising dose, they are much less pronounced for PA-6/GF composite compared to virgin PA-6 (Figures 3 and 4), indicating that the presence of GF partially eliminates the irradiation effects on PA. This conclusion arises from the dependences in Figure 2 as well.
\nVariation of the first and second melting temperatures with absorbed electron beam dose for PA-6/GF(30%) composite [
Variation of the first and second melting enthalpy with absorbed electron beam dose for PA-6/GF (30%) composite [
The examination of (PP/PA-6+talc) composite with or without a compatibilizer or a crosslinking agent TAIC, applying a dose in range of 0 to 200 kGy [25], reveals a decrease in
The behavior of PA-66 is similar to PA-6 in principle. Injection-molded PA-66 samples irradiated with 200 and 500 kGy doses show the decrease in initial
Data on PA-12 melting characteristics are found for EPDM/PA-12/maleated EPDM blend after being irradiated with 25 to 100 kGy doses [22]. Melting temperature does not show any change and the crystallinity is more or less also the same. However, such a narrow dose range does not allow the estimation of further development under higher doses.
\nThe molecular and supermolecular structure of a polymer determines its properties. When any variation occurs in the structure, it should manifest itself in some changes of the properties. Electron beam activates significant structural changes, namely, scission and crosslinking as well as oxidative degradation if irradiated in air. Each particular property of a polymer is unequally sensitive towards the structural modification; therefore, it is important for examination to be focused exactly. Tensile properties, such as Young’s modulus, strength at yield or break, elongation at yield or break, and flexural and impact parameters, reflect these variations well.
\nIn general, when virgin PA is irradiated, the development of the tensile parameters follows the general framework that modulus and stress at yield are progressive, whereas stress at break and elongation are regressive. The scale of measured values is a question of the quality of the irradiated PA. The shape of stress-strain curves for the same PA remains similar irrespective of the absorbed dose [16].
\nThe dimensional stability on load, the stiffness, is one important parameter for design engineers. In thermoplastics, the shape stability is affected by the crystallinity content to a great extent. Within the tensile properties, Young’s modulus is the corresponding testing parameter for stiffness. As mentioned in Section 2.1, electron beam irradiation in the solid state results in crosslink formation primarily in the amorphous phase or at the crystal boundaries [3,4]. In addition, for thermoplastics, an observable increase in the strength parameters occurs when the gel content is at or more than 50 wt% [4]. Thus, unless the crystalline phase is substantially degraded, notable changes in the modulus will not occur as evident from the dependences of Young’s modulus for virgin PA-6 and PA-6/GF composite (Figure 8).
\nVariation of Young’s modulus with absorbed electron beam dose for virgin PA-6 and PA-6/GF (30%) composite [
In reality, regarding a large fluctuation in the standard deviation (brought on by GF dispersion within the PA matrix) for the composite, any variations of Young’s modulus are statistically nonsignificant to be presented. Concerning virgin PA-6, the increase in the modulus is evident at 500 kGy dose when the gel content is more than 50%. In another study [11], a steady increase in the modulus of virgin PA-6 is measured within the dose range of 100 to 500 kGy. However, in this case, the gel point is measureable already at approximately 100 kGy and 50% growth in the gel content can be estimated at approximately 150 kGy. The relative increase in the modulus at a 500 kGy dose is approximately the same (28% over the initial rate) as the above-mentioned result. When the crosslinking agent is added to the polymer to increase the gel formation, the limit of 50% gel is achieved earlier. Therefore, the higher modulus is observed when compared to the virgin polymer [11], as the crystalline phase, being not yet impaired, is supported by the sufficient gel portion.
\nThe modulus and yield tensile strength of injection-molded PA-66 irradiated in the range of 0 to 500 kGy are found to increase over the unexposed samples with dose but displays a maximum at 200 kGy. Similar results are obtained in the elongation development; however, beyond 200 kGy, the elongation is reduced below the initial value [15] due to crosslinking.
\nThe influence of the crosslinking agent can also be demonstrated on tensile strength and elongation of PA-6 exposed to irradiation within the range of 0 to 100 kGy. These characteristics are kept the same [6], because this dose range does not involve the gel point yet. However, the addition of the crosslinking agent increases the tensile strength and a decrease in the elongation immediately from 40 kGy, indicating that the corresponding gel point is lower than 40 kGy in this case. The higher the crosslinking agent concentration, the greater the effect is found.
\nThe importance of the selection of the crosslinking agent is reflected by the experiment where PA-66 is doped with 1% TAC, TAIC, or TMPTMA when irradiated with doses up to 600 kGy [12] in air. The tensile strength for virgin PA-66 and PA-66 with TAC exhibits a similar pattern of initial rise up to 200 kGy followed by a gradual reduction up to 600 kGy. In the case of PA with TMPTMA, the tensile strength reduces continually. In the case of TAIC, in contrast, the strength rises throughout the whole range of irradiation. The elongation of PA-66 virgin as well as PA-66 with TAC or TMPTMA reduces displaying a sharp decrease at 100 kGy for the PA containing the agents and a more moderate decrease for virgin PA-66 up to 300 kGy. Beyond these doses, the corresponding values change negligibly. The elongation of PA-66 with TAIC follows a completely different course. It gradually drops over the entire range of dosage and the resulting elongation is the highest when compared to others (Figure 9). This possibly indicates that, despite having the highest gel content, the network is less dense, with TAIC saving more elasticity compared to others.
\nRelative variation of elongation of PA-66 with and without crosslinking agents with dose of e-beam. Adapted from Pramanik et al. [
Concerning the modulus (Figure 10), this increases beyond 200 kGy sharply for virgin PA-66 in compliance with the above-mentioned finding that at least 50% gel is needed to contribute towards the modulus increase [4].
\nRelative variation of tensile modulus of PA-66 with and without crosslinking agents with dose of e-beam. Adapted from Pramanik et al. [
The addition of the crosslinking agents increases the modulus over the virgin PA-66 in the order of TAIC>TAC>TMPTMA, although the dependences follow individual courses. The crosslinking efficacy of the agents in PA-66 is of the same order as well.
\nThe effect of another agent, glycidyl methacrylate (GMA), is similar [21]. PA-6 doped and then irradiated with a dose in the range of 0 to 200 kGy in nitrogen to condensate mutually shows a modulus at 100 and 200 kGy, which is 36% and 45%, respectively, above the unexposed virgin PA-6. At the same time, the corresponding tensile strength is determined to be approximately 15% over the virgin PA-6.
\nRadiation technology is used in an effort to improve the deficient compatibility of different polymers in blends or composites and to model the resulting properties to a certain extent due to the binding of each other through free radicals generated in the components. PA-6 and linear low-density polyethylene (LLDPE) are typical immiscible polymers. The morphologic examination of the mixture of the PA-6/LLDPE/GMA exposed to electron beam under nitrogen atmosphere within the range of 5 to 200 kGy displays a reduced diameter of the dispersion particles and an increase in the interfacial adhesion. The elongation at break of the blend irradiated at 100 kGy is approximately four times higher than that of the virgin PA-6. This parameter is strongly reduced when the blend is irradiated at 200 kGy, which is supposed to be the crosslinking of LLDPE [20]. The tensile strength and modulus increase with rising irradiation dose nonlinearly.
\nElectron beam irradiation of multilayer film LDPE/PA-6/LDPE with doses up to 125 kGy in nitrogen results in the increase of the tensile strength and the decrease of the elongation [18].The growth is more rapid up to 50 kGy and then is more moderate. In contrast, the elongation decreases presenting a mirror curve to the strength. This phenomenon is explained by the formation of carbonyl groups in LDPE in the case of the low doses, which facilitate the miscibility of the LDPE with PA-6. On the contrary, at high doses, the presence of crosslinked LDPE would most likely introduce microregions of immiscibility with the PA-6.
\nThe preparation of a thermoplastic elastomer from an immiscible blend consisting of the EPDM, maleated EPDM, and PA-12 is another demonstration of the utility of electron beam irradiation [22]. The irradiation was conducted up to 100 kGy in nitrogen so that PA-12 chain scission occurred generating free radicals but no crosslinking and led to a mutual link of the components and from disastrous mechanical properties to desired ones. The increase is quoted for Young’s modulus, tensile strength, and elongation; in addition, the recyclability of the thermoplastic elastomer is gained for three cycles at least.
\nWaste polymers can be used again when they are combined with other appropriate components. Therefore, waste PA copolymer PA-66/PA-6 blended with acrylonitrile butadiene rubber and subjected to electron beam irradiation shows tensile strength and elongation, depending on dose and composition, at levels between the parameters of those individual components. The obtained compatibility matches with scanning electron microscopy (SEM) images [26].
\nA composite consisting of ethylene-vinyl acetate copolymer (EVA) flame retarded by a combination of cellulose acetate butyrate microencapsulated ammonium polyphosphate, PA-6, and TAIC reveals a drastic increase in tensile strength by 62% over the initial value at 160 kGy. Beyond this dose, the tensile strength falls, whereas the elongation at break decreases continually from the beginning [27].
\nAdhesive joints in composite items often involve PAs. Polycarbonate (PC) sheet covered with PA-6 being irradiated with dose of 43 to 432 kGy [28] displays variation in the fracture stress and elasticity of the joint as dependence on dose differing from the neat components. Whereas the fracture stress for the composite increases up to approximately 120 kGy and levels beyond this, the strain falls with rising dose up to 220 kGy and then increases. Some optimum in the characteristics could be found according to topical design requirements.
\nYoung’s modulus of composite (PP/PA-6+talc) with or without a compatibilizer or crosslinking agent TAIC, applying a dose of 0 to 200 kGy [25], gives the dependence on dose with composition. Whereas the modulus of the mixture containing all components accounts for only 73% (PP/PA-6+talc) before irradiation, it exceeds the other mixtures after 200 kGy irradiation. Qualitatively, the same tendency is observed for tensile strength, too. These results indicate that, with a combination of suitable composition and electron irradiation, materials could be designed with the desired properties.
\nFurther research in this field is open and not all efforts lead to desired results. For example, experiments with composites of monomer casting PA-6 containing 2% nanofillers as particle carbon or silicon carbide or carbon shortcut fibers with no crosslinking agent give only 6% increase in tensile strength and Young’s modulus when irradiated by electron beam with 20 kGy dose [29].
\nThe weakness of PAs as semicrystalline materials is quantified for a low impact strength or toughness. After virgin PA-6 is electron irradiated, a considerable deterioration of these parameters is found. The Izod impact strength falls sharply with the rising dose, and after absorbing 600 kGy, the impact strength retains 31% of the initial level only. The addition of the crosslinking agents changes this uniformly decreasing behavior. According to the agent type, the dependence of Izod impact strength on dose is of variable character, reaching a maximum at 400 kGy followed by a sharp decline beyond this dose [11]. However, the net result is a decrease when compared to the nonirradiated sample. A rather different situation occurs for PA-66 [12]. The Izod impact strength of virgin PA-66 is reduced at 100 kGy to 68% of the initial value and then displays a leveling effect up to 300 kGy, and beyond this dose, a sharp decrease is followed by no significant change at higher doses. Again, the crosslinking agents have a variable influence and result in a dependence including smaller fluctuations in comparison to the virgin PA-66. An observation of the fracture surface leads to the finding that both virgin and crosslinker-doped PA-66 irradiated up to 300 kGy show ductile failure, whereas the materials irradiated with doses of 400 to 600 kGy indicate brittle failure. One of the several reasons why electron irradiation lowers the impact strength may be a certain obstruction in the dissipation of the impact energy when the initial amorphous phase is progressively crosslinked and restricted in the chain motion and relaxation. The contribution of oxidative degradation becomes more evident in the reduction at higher doses.
\nThe flexural characteristics for PA-6 reveal an analogous behavior with the corresponding tensile strength and tensile modulus (i.e., they increase with dose) [11]. The increase in the flexural modulus at 500 kGy is 13% over the initial level and the flexural strength 20%, respectively. The addition of effective crosslinking agents TAIC and TAC raises these values. In the case of PA-66, the flexural modulus increases up to 400 kGy by 40% and then it falls sharply, remaining still at an increase of 20% over the initial level [12]. The same crosslinking agents as in the PA-6 increase the flexural modulus, almost copying the behavior of virgin PA-66 at a higher level.
\nThe irradiation of composite (PP/PA-6+talc) with 0 to 200 kGy doses leads to an increase in flexural strength by 18%; when the composite contains also the compatibilizer and crosslinking agent TAIC, the increase is higher by 137%. Both corresponding flexural moduli are increased by 24% and 200%, respectively [25].
\nIt can be concluded that, besides irradiation conditions, the mechanical properties in blends of PA with other polymers or modifiers are dependent on the character of all components and the interactions between them induced by the irradiation.
\nThe thermal resistance of polymers is usually measured by heat deflection temperature (HDT) and Vicat softening temperature. There are other specific tests adjusted to the factual requirements of manufacturers. However, they are used by narrow groups of design engineers and in the framework of quality testing.
\nThe HDT (or heat distortion temperature) is the temperature at which a polymer sample deforms under a specified load. It might be expected that parameter HDT will increase with rising dose. In fact, for PA-6 irradiated within 0 to 500 kGy, it is found that there is a progressive growth up by 9°C at 500 kGy. All the related values appear near 50°C, the
Variation of HDT with absorbed electron beam dose for virgin PA-6 and PA-6/GF (30%) composite. Adapted from Porubská et al. [
A different situation is in GF-reinforced PA-6. The presence of GF restrains the segmental motion of the polymer chains, and therefore, the initial HDT (190°C) observed for the compositePA-6/GF is much higher than virgin PA-6 (47°C). Unlike the virgin PA, the HDT values for PA-6/GF decreases in response to irradiation, with a decrease of 6°C at the highest dose [7]. Analogous results can be assumed for other composites as well.
\nHow much crosslinking can affect HDT for PA-6 is seen from the electron beam irradiation of PA-6 containing 2% TAC. Whereas the HDT before exposure is 120°C, after absorbing 80 kGy dose, this figure increases up to 170°C [6] due to ~96% gel content (Figure 12).
\nVariation of HDT with absorbed dose for PA-6 at 2% TAC level. Adapted from Dadbin et al. [
The irradiation of composite (PP/PA-6+talc) in the range of 0 to 200 kGy displays the rise in HDT depending on the dose from 63°C for the nonirradiated sample to 72°C for that irradiated with 200 kGy. However, when compatibilizer and crosslinking agent TAIC is incorporated in the composite, the HDT gives value of 84°C [25].
\nThe Vicat softening temperature (or Vicat hardness) is taken as the temperature at which the specimen is penetrated to a depth of 1 mm by a flat-ended needle with a 1 mm2 cross-section. There is not much information on the effect of electron irradiation on the Vicat softening temperature for PAs in the scientific sources. Unlike the HDT, the Vicat temperature for virgin PA-6 (186°C) reaches a maximum (190°C) at the lowest dose of 50 kGy and then decreases with increasing dose nearly returning to its original level (187°C) [7]. The mentioned increase is possibly related to the release of physical entanglements due to the supplied energy from the electron radiation. That enables the involvement of some released segments in amorphous phase into the crystalline phase and its enlargement. A moderate increase in the melting enthalpy/crystallinity at 50 kGy dose corresponds to this. The decrease in the Vicat temperature at a higher dose is assigned to the progressive disruption of the surface structure and the thinning of the lamellae what is obvious also from the lower melting onset (Figure 3). The softening temperature for PA-6/GF composite is less pronounced, with a total decrease of only 2°C (Figure 6). This observation corresponds to the different crystallinities of both materials (PA-6/GF > PA-6).
\nGenerally, PAs tend to absorb water due to the nonbinding interactions of water molecules with polar groups in the matrix. The water present in PA acts as a plasticizer. The water absorption affects the dimensional stability and mechanical properties of the polymers, whereas humidity in PA matrix can support hydrolytic destruction and can also be a source of oxygen when PAs are processed or irradiated accelerating the polymer oxidative degradation. Therefore, water absorptivity is one of the crucial parameters affecting the PA properties. That is why the comparison of some characteristic values for various PAs requires a standard conditioning (temperature, humidity, and time) before the PA is tested.
\nThe entry of water molecules into a PA matrix is controlled by diffusion. The penetration of the matrix by water molecules requires enough space inside the matrix for the translation motion of water molecules. The space is formed by vacancies due to the rotating movement of segments of macromolecule chains. The fewer the restrictions of motion in the polymer segments, the more vacancies are created. Because the crosslinking shortens the chain sequences between the cross-points and thus restricts the segmental rotation, water molecule mobility in the polymer should be more difficult suppressing water diffusion. This supposition is confirmed empirically. Water absorption in PA-6 irradiated in range of 0 to 600 kGy decreases throughout all doses from 2.3% to 1.7% at the highest dose [11]. As expected, the decline is greater with the incorporation of the crosslinking agents TAIC or TAC (Figure 13).
\nVariation of water absorption for PA-6 without and with 1% crosslinking agents with dose of e-beam radiation [
Because the concentration of the effective crosslinking agent affects the gel content, it is expected to influence water absorption in the PA correspondingly. Such an example is shown in PA-6 doped with 1%, 2%, and 3% TAC [6]. The measured data confirmed this supposition and the largest decrease at 80 kGy is read for PA-6 with 3%>2%>1% TAC. The decline of water absorption compared to virgin PA-6 irradiated within 0 to 200 kGy occurs also after adding approximately 3% GMA under identical conditions [21]. Similarly, injection-molded PA-66 reveals a lowering of water absorption when irradiated in the range of 0 to 500 kGy, but the PA-66 dipped in TAC solution before the irradiation shows a further decrease in this parameter [15].
\nIn polymer chemistry, as for electron irradiation, γ-irradiation is employed to initiate chemical reactions also in the solid phase without the addition of initiator. The purpose can be to initiate the crosslinking of individual polymers or the grafting of various monomers onto PA chains. Basically with γ-irradiation of PAs, the same processes run as those with electron irradiation. However, some differences occur due to variable conditions.
\nγ-Ray radiation differs from electron beam mainly by a much slower rate of dose due to γ-rays being always of less energy than 10 MeV. Therefore, γ-irradiation requires a longer period to supply the same dose as an electron beam. When a polymer is γ-irradiated in air, enough time is available for generated radicals to react with oxygen. Therefore, considerable oxidative degradation can be expected along with crosslinking. In contrast, an inert atmosphere during irradiation as well as after the irradiation suppresses oxidative degradation and supports crosslinking. However, the oxidative degradation cannot be excluded absolutely due to some portion of oxygen (and possibly also humidity) present in the polar PA matrix. These anticipations were confirmed and both chain scission and crosslinking are observed to occur in PA-6 under γ-irradiation in either air or inert atmosphere, with chain scission prevailing over crosslinking if irradiation proceeds in air [30].
\nA thorough comparison is provided by a recent study [31] examining PA-6 and GF-reinforced PA-6 (30% GF) irradiated with different γ-ray doses in the range of 0 to 500 kGy in either air or inert atmosphere. As displayed in Figure 14, it can be seen that the irradiation in air generates a small amount of gel in PA-6 only, whereas no gel is found in the PA-6/GF composite.
\nDependence of gel content in PA-6 and PA-6/GF composite on absorbed dose when γ-irradiated in air or inert atmosphere.
In the PA-6, the crosslinked portion irradiated in air increases slightly with the rising absorbed dose. Concerning the gel point, a calculation following the Charlesby-Pinner equation [14] using the experimental data and taking into consideration the experimental errors gives an estimation that the gel point is to be in the vicinity of a dose of 300 kGy for the PA-6 irradiated in both atmospheres. Such gel point is somewhat higher compared to 200 kGy dose value determined for the same materials irradiated with electron beam in air [7]. The irradiation of PA-6 in argon atmosphere produced considerably more gel in comparison to exposure in air. It demonstrates oxygen influence. The absence of oxygen (or low content of it) affords better facilities to form crosslinks from generated macroradicals because the macroradicals are not attacked. In argon atmosphere, the gel point for PA-6 as well as PA-6/GF is observed to be approximately 300 kGy. However, also in inert atmosphere, PA-6 shows more gel (65%) than PA-6/GF (45%) for the ultimate dose of 500 kGy. The lower gel content in the composite confirms the retarding action of the filler on the networking of the PA matrix. Simultaneously measured solution viscosity for PA-6 increases up to 200 kGy, and above this dose, the viscosity could not already be measured correctly due to the incomplete dissolution of the PA-6 polymer indicating incoming gel point. The increase of the PA-6 solution viscosity below 200 kGy indicates growth in the molecular mass via the recombination of the secondary macroradicals formed on PA-6 chains, which leads to branching as pre-crosslinking stage up to the gel point [5,6]. Whereas the irradiation of PA-6/GF in air did not generate any gel within the applied dose, viscosity increased (see \nTable 3), illustrating some recombination of the macroradicals and relating growth in molecular mass. The solubility of the PA-6/GF matrix was observed within all doses corresponding with no gel content. The reduction of the viscosity beyond 350 kGy is attributed to the continuing branching of already branched chains. A consequence is that the amount of the particles and the corresponding gyration radius of the macromolecules decrease, reducing the viscosity.
\nDose (kGy) | \nViscosity number (mL/g)\n | \n|
---|---|---|
PA-6 | \nPA-6/GF | \n|
0 | \n143 | \n130 | \n
50 | \n146 | \n131 | \n
100 | \n154 | \n133 | \n
350 | \n— | \n212 | \n
500 | \n— | \n180 | \n
Viscosity number of PA-6 and PA-6/GF irradiated with γ-rays in air (solvent formic acid, dose rate of 9.5 kGy/h).
Gupta and Pandey [30] presented a similar fact when, irradiating in air, the chain scission of PA-6 prevailed over crosslinking. Because γ-irradiation took a longer time (from 5 to 52 h), during this period, oxygen could attack the produced macroradicals. The result was the overbalance of scission due to oxidation over crosslinking. In addition, the presence of GF hindered the diffusion of the macroradicals in the matrix, so that the branching was supported and crosslinking was suppressed.
\nAn opposite effect can occur as reported by Aytaç et al. [13] for PA-6 and PA-6,6 tyre cords being calendered and then γ-irradiated within 0 to 75 kGy in air. As already mentioned about the electron exposure of those materials (Section 2.1), also the γ-irradiation of those PAs led to the reduction of the limiting viscosity number with increasing dose. This demonstrates how any pretreatment of material subsequently subjected to the irradiation can be important. In general, calendering itself can start mechano-oxidative degradation leading to the decrease in molecular mass as well as in the corresponding viscosity. In addition, during the calendering, the diffusion of oxygen into the PAs is more facile, as the molecular movement in matrix is increased at higher temperature. From this point of view, the decrease in the limiting viscosity number is expected. The decrease is larger than that under comparable exposure to electron beam, indicating more deteriorative effect of γ-irradiation in comparison to electron beam. Corresponding dependences of the breaking strength on dose show a lower strength, too, in conformity with the viscosity results.
\nPAs are combined with other polymers in various microfiltration membranes especially to enhance the mechanical properties. The membranes are exposed to γ-irradiation to be sterilized. Such a membrane involving PA-66 as reinforcing part was put in Pyrex glass, purged with argon, and, after adding deionized water again, purged with argon and sealed. The glass with the membrane was γ-irradiated in the range of 0 to 100 kGy and then several characteristics were tested [32]. At first sight, this is different from the PA-6 and PA-6,6 cords mentioned previously [13]. However, also in this case, the reduced viscosity as a function of dose displays a decrease with dose (Figure 15).
\nEvolution of reduced viscosity of PA-66 as a function of γ-irradiation doses [
The downward trend of the reduced viscosity indicates the decrease in molecular mass due to chain scission despite the exposure being conducted in argon purged deionized water. The authors [32] suggested that the viscosity reduction could be due to the chains connecting different lamellae. However, the water medium is a rich source of oxygen and could be the main reason in supporting oxidative degradation. Free radicals generated by γ-rays induce the cleavage of water molecules. In addition, water penetrates PA relatively easy acting as a plasticizer, and the applied dose within 10 to 100 kGy is sufficient to attain the dissociation energy for water producing oxygen (HO-H ~498 kJ mol-1 and O-H ~428 kJ mol-1) and that is comparable to the dissociation energy for H-C cleavage (H-C ~339 kJ mol-1, H-CH ~452 kJ mol-1, and H-CH2 ~473 kJ mol-1) [33]. That is why corresponding tensile properties (Young’s modulus, stress at break, elongation, and energy at break) [32] mirrors the course of the decreasing viscosity.
\nRadicals generated during irradiation are capable of surviving in the polymer matrix for a long time as found by Menchaca et al. [34,35] after 6 years from exposure of PA-6,12 crystalline fibers with applied low dose of 1 to 25 kGy at ambient conditions. The survival of frozen free radicals in the matrix demonstrated itself by the changes in some properties as thermal and morphology characteristics; the melting temperature decreased and the crystallinity increased with the period of storing. It indicates that formed shorter chains generated thinner lamellae and integrated into the crystalline phase.
\nApplying γ-irradiation can also lead to an improvement in the compatibilization of immiscible polymers in a blend. An example is the blend of PA-6 with LDPE either irradiated or nonirradiated [36]. The structure and properties of the blends with γ-irradiated LDPE differ significantly compared to PA-6 blends with the nonirradiated materials. The difference was ascribed to the formation of functionalized groups on the polyethylene chain during irradiation in air and these interact with PA. However, when analogous blends of LDPE/PA-6 are irradiated in vacuum [37], crosslinking is achieved mainly in the PE component, whereas the main effect on PA-6 is chain branching.
\nA comparison of DSC characteristics for PA-6 and composite PA-6/GF after being γ-irradiated in air or in inert [31] within 0 to 500 kGy can provide some framework observations. Similar to Section 2.2, both first and second heating runs give complementary information. First, the effect of irradiation dose on
Variation of the first melting temperature of PA-6 and composite PA-6/GF (30%) with absorbed dose of γ-irradiation in air and inert atmosphere. Adapted from Porubská et al. [
The effect of GF presence consists of a certain soft increase of sensitivity towards irradiation, which is in certain contradiction with lower gel formation. It may mean that the presence of GF can act as a nucleating agent. If so, the crystallites are formed especially around the fiber surface. However, during exposure, the fiber surface is more heated than the matrix and some destruction in crystalline portion occurs in this area. That is why the noticeable decrease in
The figures of melting heat Δ
Variation of the first melting enthalpy of PA-6 and composite PA-6/GF (30%) with absorbed dose of γ-irradiation in air and inert atmosphere. Adapted from Porubská et al. [
It can be seen that the values of Δ
Variation of the second melting enthalpy of PA-6 and composite PA-6/GF (30%) with absorbed dose of γ-irradiation in air and inert atmosphere. Adapted from Porubská et al. [
All samples show a decrease in remelting temperature
Variation of the second melting temperature of PA-6 and composite PA-6/GF (30%) with absorbed dose of γ-irradiation in air and inert atmosphere. Adapted from Porubská et al. [
Similar to electron beam irradiation, the presence of crosslinking agents can modify the crystallinity of γ-irradiated PAs, too. Electrospun PA-66 fibers exposed in nitrogen atmosphere with 20 and 50 kGy dose do not display any change in crystallinity, whereas the addition of TAC raises the crystallinity and this increases with applied dose [38]. This fact is interpreted as the consequence of a TAC-induced crosslinking and formation of a tighter network. Thermal stability measured as weight loss depending on temperature is lower with TAC than without it. After irradiation, the stability with TAC improves, however, without achievement of stability for nonadditive PA-66, whereby the dose of 20 kGy provides better result than 50 kGy.
\nThe exposure of PA-66 to various doses of γ-rays ranging from 100 to 1250 kGy shows an increase in the crystalline nature of the polymer at higher doses as a result of significant decrease in the peak width of X-ray diffraction (XRD) patterns [39]. Higher doses induce more macromolecular fragments of higher mobility and these can integrate easily into crystalline phase modifying supermolecular structure.
\nWaste PA finds exploitation in various material combinations. Hassan et al. [40] studied the effect of γ-irradiation on blends containing waste PA-6/PA-66 copolymer and ground rubber from tires with various ratios of these incompatible components. The blends irradiated in the range of 0 to 200 kGy give the melting temperature and crystallinity decreasing with increasing dose due to the crosslinking at interphase. The visible side shoulder in the endotherm for 100 kGy is missing in the 200 kGy endotherm and microphotographs show a relatively smooth fracture surface. Thermal stability measured by thermogravimetry is a little worse after irradiation. Montmorillonite clay is then added into the blend to formulate nanocomposite [41]. The composite after being γ-irradiated between 0 and 200 kGy obtains a markedly magnified thermal stability. When 12% montmorillonite is present in the mixture, the DSC data indicate the increase in the melting temperature with dose with reverse order of the onset in melting endotherm. The crystallinity is observed to be highest for the 100 kGy dose and the corresponding endotherm outlines multiplicity. The increase of montmorillonite portion to 18% leads to a decrease in the melting temperature. Also, the temperature onset falls. In this case, the highest crystallinity belongs to the nonirradiated composite and is followed by the 200 kGy dose. The dose of 100 kGy corresponds to the lowest crystallinity with the most structured melting endotherm. The multiplicity of the endotherm indicates a new element in the supermolecular structure as a consequence of γ-irradiation. Another composite consisting of the same polymer components PA-6/PA-6,6 copolymer and ground rubber but with added carbon black was examined by the same authors [42], applying the same doses of 0 to 200 kGy. As reported, the content of carbon black within 6% to 24% improves the thermal stability in both cases without and with γ-irradiation. The melting temperature and crystallinity of the composite with 12% carbon black decrease with rising dose slightly more when compared to 18%. The melting endotherm becomes smoother and the composite irradiated with 200 kGy presents a homogeneous fracture surface. Such studies are useful in optimizing a filler portion regarding other required properties. Usually, some compromise is necessary.
\nThe development of mechanical properties of PAs irradiated with γ-rays is, as usual, linked to changes in the molecular and supermolecular characteristics. Evaluating the behavior of PA-6 and composite PA-6/GF γ-irradiated in air [31] concludes that the Young’s modulus of PA-6 is soft decreasing with rising irradiation dose, whereas, for the nonirradiated composite PA-6/GF, the values are almost identical with the material irradiated with the highest dose (Figure 20).
\nVariations of Young’s modulus for virgin PA-6 and composite PA-6/GF γ-irradiated in air.
For both materials, the dependencies exhibit a shallow minimum around the gel point as a result of the superposition of the two opposite effects, namely, branching, chain scission, and cross-bond formation. These effects are more evident for PA-6 in comparison to the composite PA-6/GF. At first sight, it seems to be a misinterpretation. However, one has to take into consideration generally lower figures for PA-6 modulus and a small variation leads to a larger relative variation than in the case of the composite. Overall marginal variations of modulus are linked to a low gel content for PA-6 and no gel for PA-6/GF (Section 3.1) as well as small changes in crystallinity (Section 3.2). Because the level of crystallinity and crosslinking determines the modulus value, a significant variation of the modulus values should not be expected as demonstrated in Figure 20.
\nTesting tensile strength reveals that yield point can be observed only for PA-6, and the composite PA-6/GF exhibits brittle behavior without signs of yielding. A considerable decrease of yield stress from 71 to 51 MPa is observed already at the lowest dose of 50 kGy and then the curve leveled off up to the highest dose of 500 kGy. The tensile strength at break for PA-6 does not vary considerably with rising irradiation dose. This result is attributed to the gel content (Section 3.1), which contributes to retain the strength at break with no significant variation in the whole dose range compensating the strength decrease induced by degradative influence of γ-irradiation in air. In contrast to PA-6, all exposed PA-6/GF samples showed a little reduction in tensile strength at break. The reason is the different gel formation; whereas no gel was measured in the composite, a certain amount of gel was determined in PA-6 beyond gel point. Therefore, zero gel in PA-6/GF could not compensate the decrease in the strength due to the degradation of the polymer matrix.
\nVariations in elongation at yield for PA-6 as well as for the composite are negligible and this parameter for PA-6/GF is identical with the elongation at break. For PA-6, the starting elongation at break at ~147% increased to 240% already at 50 kGy without any change for the other doses. Such mild increase in the elongation at break is caused by the minor decrease of crystalline portion as well as the lamellae thinning as a result of oxidative degradation with the consequence of easier plastic deformation. In addition, at low gel content (maximum ~17%), shorter recombined chains act in the matrix as plasticizers and increase its deformability. The effect is not observed for the composite PA-6/GF, as it is overlapped by enhanced brittleness of the material due to the presence of the anisotropic GF.
\nConcerning irradiation in an inert argon atmosphere, a comparison of effect on the moduli is demonstrated in Figure 21.
\nComparison of variations of Young’s modulus for virgin PA-6 and composite PA-6/GF γ-irradiated by 500 kGy dose.
When PA-6 and PA-6/GF were irradiated in inert atmosphere, the relevant moduli showed lower values in comparison to the materials exposed to γ-irradiation in air. In consideration of the marginally changing results of Δ
The reduction of tensile strength for both samples is more enhanced when irradiated in inert atmosphere. As displayed in Figure 22, the changes are rather small, except for yield, where the extent of changes is close to the values for Young’s modulus.
\nComparison of variations of tensile strength for virgin PA-6 and composite PA-6/GF γ-irradiated by 500 kGy dose.
The changes in elongation at break and at yield (in the latter case only for PA-6) are shown in Figure 23.
\nComparison of variations of elongation for virgin PA-6 and composite PA-6/GF γ-irradiated by 500 kGy dose.
The elongation at yield for PA-6 irradiated with 500 kGy in inert atmosphere increased for up to quintuple value, whereas irradiation in air led to negligible change. In contrast, the elongation at break is higher after irradiation in air when compared to irradiation of PA-6 in inert atmosphere, and this is lower than for the unexposed sample. Irradiation of PA-6/GF in air led to the elongation at break with no change, whereas a little increase is observed when irradiated in inert atmosphere. This indicates some increase of the matrix deformability due to a low crosslinking level.
\nConcerning exposure in inert atmosphere, similar data are given for electrospun PA-66 fibers irradiated in nitrogen atmosphere with 20 and 50 kGy dose. Tensile stress lowers with dose, whereas an increase is observed after adding the crosslinking agent TAC [38]. The same is reported for Young’s modulus.
\nNotched impact strength of PAs is often unfavorable property. An examination of this aspect was demonstrated by Charpy notched impact test being carried out for both PA-6 and PA-6/GF irradiated within 0 to 500 kGy in air [31]. The dependence of the impact strength on dose reveals a different behavior. The PA-6 curve shows a maximum at 50 kGy. The corresponding impact strength is 80% higher compared to the initial value. This can be attributed to the perturbation of initial physical nodes in amorphous phase and branching, which facilitates more elastic dissipation of impact energy and supports a deceleration of crack propagation. Higher doses form a network, although not a dense one, but it supports the absorbing impact because of its elasticity. Whereas oxidation-degradation occurs simultaneously, the result represents a superposition of the positive contribution of elasticity and a negative oxidation-degradation under irradiation. At 500 kGy, the final impact strength for PA-6 is 1.5 times higher than the starting value. However, an opposite trend is observed for the PA-6/GF composite. In this case, the impact strength decreases mildly with rising dose up to 82% of the initial value linking the zero gel observed (Figure 14) and more or less constant crystallinity (Figures 17 and 18). As evidenced by SEM photos, although easier GF dewetting in nonirradiated composite may act as an obstacle for crack propagation at impact, after irradiation, higher GF adhesion makes the material more compact and less resistant to impact failure.
\nBlends containing waste PA-6/PA-66 copolymer and ground rubber from tires irradiated within 0 to 200 kGy in air show lower values in tensile strength and elongation compared to the unexposed sample, whereas elastic modulus is changed little. All the variations are a function of the component ratio [40]. When montmorillonite clay is involved in the blend, formulating a nanocomposite, a decrease in tensile strength, and an elongation at break is observed for each dose in comparison to the starting material. However, the courses of both parameters are a function of the montmorillonite portion, indicating an optimum for 12% clay. Concerning modulus, a decrease is measured regardless of dose, but the differences between the compositions are not large [41]. The same doses of 0 to 200 kGy were applied on the mixture of the above-mentioned polymer components PA-6/PA-66 copolymer and ground rubber with the addition of carbon black [42]. The tensile strength of nonirradiated sample is observed to be higher than the irradiated samples, except the dose of 50 kGy being above the initial material. However, irradiation led to a decrease in elongation for all doses compared to that unexposed. For the latter case, the addition of carbon black increased elongation significantly; for others, there was a slower increase. In both tensile characteristics, the differences between doses 100 and 200 kGy are marginal, whereas the variations are more profound for the dose of 50 kGy. The dependences of the parameters on carbon black portion within 6% to 24% are almost flat.
\nγ-Rays are applied in the field of flame retardation of polymers, too. The recent study of Sonnier et al. [43] demonstrates for blend PP/PA-6/crosslinking agent that, depending on the type of retardation, the best flame-retarded blend before irradiation can become the worst one after irradiation at a higher dose. In this case, a dose up to 100 kGy was used. Testing of the dependence of Young’s modulus on temperature provided results similar for all blends at RT for whatever the dose, and these decreased slowly when the temperature increased. Above 150°C, the decrease was faster. Heat distortion of the blends accelerated with rising dose, whereas the distortion was not observed for nonirradiated blend. It is concluded that, if heat shielding effect is applied to provide the flame retardation, the top protective layer can be disrupted and heat release rate will increase to a considerable extent. In such case, the barrier layer is not capable to prevent the subsequent transfer of heat.
\nLow doses of γ-radiation are often used for the sterilization of food packaging. Polymers used to package food intended for irradiation must receive relevant approvals. Evaluation of e-beam, γ- and X-ray treatment on the chemistry and safety of polymers used with prepackaged irradiated foods showed that the three forms of irradiation have virtually indistinguishable effects on polymers irradiated in vacuum [44]. However, γ-irradiation in air results in facilitated damage due to slow dose rate providing enough time to oxidative degradation. It is accepted, in general, that the foods in contact with irradiated polymeric materials should not be endangered by radiolytic products with adverse impact on health.
\nPAs are governed by excellent barrier performance. That is why several works are devoted to the issue of food packaging involving PAs. An examination of various plastic multilayer PA-6 films, used for meat and cheese, after being irradiated (up to 12 kGy) reveals that the release of ε-caprolactam from exposed PA-6 is of a much higher extent compared to that of nonirradiated samples, indicating chain scission [45]. Félix et al. [46] conducted a migration assay at 40°C for 10 days focusing on the effect of γ-irradiation with 12 kGy dose on ε-caprolactam migration from multilayer PA-6 films into food simulants. The results revealed that the irradiation caused almost no changes in ε-caprolactam levels, with the exception of olive oil, which showed an increase in the caprolactam level. However, all the tested films were within the legislation and did not exceed limits for ε-caprolactam migration. Park et al. [47] reported that 5 kGy γ-irradiation significantly increased the formation of ε-caprolactam in PA-6 from 70.76 to 164.10 ppm. The formation of ε-caprolactam ranged between 122 and 164 ppm in the dose range of 5 to 200 kGy.
\nBarrier five-layer food packaging films, consisting of two outer PA-6 layers (~15%) and a middle LDPE layer (50%), after being irradiated with a larger range of doses of 5 to 60 kGy were analyzed focusing on volatile and nonvolatile radiolytic products and sensory changes [48]. The data show that a large number of radiolytic products are produced such as hydrocarbons, alcohols, carbonyl compounds, and carboxylic acid but also amide type of products. These substances are detected even at the lower doses of 5 and 10 kGy. Most of the substances are assumed to come from LDPE because that is used also as recycled. The type and concentration of radiolytic products increase progressively with the absorbed dose. In addition, irradiation dose appears to influence the sensory properties of table water in contact with the films being classified according to stricter requirements.
\nIn another study [49], the authors analyzed 13 different multilayer polymeric materials for food used before and after their exposure to γ-radiation regarding the profile of volatile compounds released from the polymeric materials. Thermosealed bags of different materials were filled with either air or nitrogen to evaluate the oxygen influence. One third of the samples were analyzed without irradiation, whereas the rest were irradiated at 15 and 25 kGy. Half of the samples were processed just after preparation and the other half was stored for 8 months at RT before analysis. Significant differences between nonirradiated and irradiated bags were found. Sixty to 80 compounds were released and identified per sample. Independent of the filling gas, the results of nonirradiated materials were almost identical. In contrast, the chromatographic profile and the odor of irradiated bags filled with nitrogen were completely different from those filled with air. The migration of compounds from irradiated materials to the vapor phase was much lower than the limits established in the relevant EU Commission Regulation.
\nCompared to electron and γ-irradiation, there is far less information on proton beam irradiation in the scientific sources. One possible reason is that proton irradiation is used mostly in the medical domain for therapy and production of isotope-labeled pharmaceutical preparations.
\nCurrently, proton beam is used as a direct writing method using focused proton beam to decorate resistant polymers at the nanolevel. In comparison to electron beam, the proton writing offers a unique advantage consisting of the fact that proton penetrates materials more deeply, maintains a straight line, and makes three-dimensional structures with vertical and smooth walls as well as low roughness. This advantage is a consequence of a greater proton mass when compared to electron.
\nUnlike PAs, some works dealing with other polymers (PMMA, PDMS, fluorinated PI, PP, PTFE, PS, LDPE, PP, PET, and PVC) can be found. Semicrystalline PAs are not typical materials for optical or decorative purposes because of their nontransparency. Maybe this is why studies on PAs irradiated with proton beam are rare if not missing.
\nConcerning polymers, it is known that also protons affect the polymers mainly through scission and crosslinking of macromolecule chains. Solitary data on PA-6 irradiated by proton beam in air can be found in the paper dealing with Fourier transform infrared (FTIR) spectroscopy comparison of electron with proton beam impact [50]. When irradiating the same PA-6 with an equal dose of 500 kGy, the proton beam generates less gel (57.5%) than the electron beam (67.6%). Therefore, the first DSC melting temperature is a little higher for a proton-irradiated sample (217.6°C) than for an electron-irradiated one (216.9°C). Accordingly, the crystallinity for proton-irradiated PA-6 is slightly higher when compared to the corresponding electron-irradiated PA-6, but the difference in the mentioned thermal characteristics is marginal. FTIR spectroscopy shows some differences in the postirradiation species related to nonidentical gel formation. The proton beam irradiation results in a finer structure of some absorption bands, particularly in the range of 400 to 1650 cm-1, indicating the generation of structures that are more varied. The consequence is that the cleavage of PA-6 macromolecules by the proton beam produces fragments containing amine groups and terminal methyl groups, whereas the increase in concentration of these groups in electron-irradiated PA-6 appears to be insignificant in comparison to virgin PA-6. Based on the finding, besides crosslinking [Equation (11)] and oxidation degradation [Equations (13) and (14)], a possible parallel scenario can occur when proton beam interacts with PA:
a) Unsaturated structures formation:
The double bond can occur between any carbons within the ethylene segments.
b) Amine species formation:
c) Both methyl-ended and shorter amide chain formation:
The processes reflect some differences also in tensile properties as seen in \nTable 4.
\nTensile property | \nRelative change after 500 kGy dose | \n|
---|---|---|
PA-6/EB | \nPA-6/PB | \n|
Young’s modulus | \n1.256 | \n1.167 | \n
Tensile strength at break | \n1.582 | \n1.398 | \n
Elongation at yield | \n1.075 | \n2.077 | \n
Relative changes of selected tensile properties for PA-6 irradiated by electron (PA-6/EB) and proton (PA-6/PB) beams in air towards properties of nonirradiated PA-6.
A thorough comparison of the advantages versus disadvantages of the proton beam irradiation in comparison to other radiation technologies in the domain of PAs cannot be concluded unless more data are available.
\nGiven the global grand challenges such as urban mobility, poverty alleviation, endemic violent conflict and the worsening of the ecological crisis, the current complex multidimensional corporate framework intensified the requirements of corporate social engagements. Thus, a common refrain of businesses nowadays is the necessity of adopting socially and ecologically responsible behaviours while ensuring their growth. Besides, since innovation is a key factor to heighten the company’s growth and competitive advantage, firms should invest in innovative as well as social matters to gain legitimacy and to respond to the different interested actors’ expectations. With the fourth industrial revolution, innovation has been the driver of sustainability. It shapes future production, strengthens competitiveness and improves human well-being as well as decreases the environmental damage [1]. Numerous examples of new innovative products and methods such as the BioMat project between Faurecia and Mitsubishi Chemical or the Flaxpreg project, developed in collaboration with PSA Peugeot-Citröen, Lineo and the French University of Reims Champagne Ardenne, show the strong bonds between innovation and corporate social engagements. Moreover, it underscores the crucial role of collaborations and strategic partnerships in developing a competitive advantage.
Innovation could help to better satisfy the needs of different stakeholders’ groups and to go beyond their expectations by getting involved in more strategic CSR policies. Innovation could, therefore, drive more socially responsible projects. According to [2] it is an urgent need to solve the socio-ecological problems. In a similar vein, [3] pointed out that innovation is commonly considered as the most viable path to support and strengthen the current standards of living while treating and overcoming environmental crises. Therefore, numerous studies assumed that innovation supports social practices [4, 5, 6], which complies with the circular economy (CE) plan launched by the European Commission in 2014. This plan aims to unlock the related growth while boosting the European Union competitiveness using new business opportunities as well as novel methods of production and consumption. Nevertheless, due to resources scarcity, conflicting interests, and the riskiness of innovative investments, firms might face difficulties to balance and define their priorities. For instance, [3] pointed out the lack of an innovative potential broad overview in the field of circular economic-related technological developments.
Due to the importance of the innovative and social strategies application, numerous investigations about these two crucial investments were conducted. Nevertheless, very few studies have explored the innovation-corporate social responsibility (CSR henceforth) association. These studies show mixed results. While certain studies tested the synergetic effect that might occur between innovation and CSR, others have debated their positive or deleterious linkage. For instance, London [7] claimed that understanding and analyzing community problems help to identify which efficient solutions should be applied and which resource can be used for social benefit. Through this identification, firms can generate new approaches and products that allow them to create new markets. Therefore, social needs are determinant factors of corporate innovation orientations and success, while innovation is the solution to solve social matters. Yet, according to Mithani [8], managers’ engagement in CSR can weaken innovation investment initiatives. He argued that corporate innovation and social investment effects on economic growth follow a specific pecking order in the Indian market. This lack of convergent empirical evidence was explained in previous research by three main reasons:
First, the diversity of innovation classifications such as the process and product innovation [9], the responsible innovation [10] or the exploratory and exploitative innovation [11]. According to Desjardins [12] there are 10 types of innovation.
Second, the dynamism of the CSR conception. Indeed, the CSR concept has been developing since its appearance [13]. Each version responds to certain criteria that influence innovation differently. These versions can be classified into two fields: the strategic CSR and the responsive CSR [9, 14, 15, 16, 17, 18]. As a result, the CSR-innovation direct linkage alters depending on the CSR conception that - on its turn - changes based on the legal and social framework as well as the corporate commitment and proficiency.
Third, the moderating and mediating effects of several factors such as corporate cognitive-governance or ethnic and cultural diversity. For instance, Costa et al. [11] pointed out that innovation and CSR synergy occurs only if the enterprise has a high level of social commitment. In a similar vein, Domínguez-Escrig et al. [19] highlighted the association between Stewardship behaviours and innovation success. Their findings show a mediating role of radical innovation in managers’ social behaviours and innovation success relationship.
Due to the importance of the innovative and social strategies application, further investigations about the linkage between these two crucial investments have to be conducted. One explanation of this lack of interest is the intricacy of the CSR concept and its misunderstanding. Weller [20] pointed out that numerous managers who implement ethical strategies and socially responsible ones do not understand their meaning. Dahlsrud [21] provided in his study 37 different definitions of CSR. Despite the complexity of the various CSR descriptions and corporate frameworks, academic research and international organizations have shared five common CSR dimensions. Using coding schemes, he claimed that the different used terms refer generally to these dimensions, which are the stakeholder dimension, the social dimension, the economic dimension, the voluntariness dimension, and the environmental dimension. In fact, the divers’ used dialects are the real reason beyond the lack of one universality definition. These confluent definitions enable us to understand the construction of CSR in specific contexts. Yet, they fail to give guidance on how to face CSR challenges and how to consider it while developing business strategies.
The current chapter contributes to this debate on CSR definition. Specifically, we focus on the development of CSR conception over time and how it does shape our understanding of the CSR-Innovation association. Then we analyze how taking into account the cognitive and individual characteristics of top managers, and board directors could help to set a more inclusive framework of this association.
Our chapter is organized as the following. Section (2) presents the evolvement of the CSR and innovation nexus based on the evolutionary CSR concept. In this section, we distinguish between the strategic and responsive CSR. We analyze the moderating effects of the managerial characteristics on CSR-innovation association in section (3). In the penultimate section, we present our empirical investigation. The last section concludes the chapter.
Since the second half of the 20th century, the corporate responsibility towards ecological and social matters has attracted a lot of interest, especially with the meta-environments in which firms operate nowadays [22, 23].
First, corporate sustainability has been presented as an exception [24]. In order to survive, firms have to provide continuously several resources and energies mobilized in a strategic plan, consistent with the framework rules and norms; otherwise, it will eventually fade. In other words, companies need to allocate their resources to create value and competitive advantage through a greater network development as well as an innovation encouragement [25]. According to the slack resources theory, due to the resources scarcity firms should arbitrate to select sustainable investments. Nevertheless, combining the divergent goals of stakeholders to find the optimal resources allocation function is the hardest mission for every company.
With the increase of multiple pressures and law evolvement, firms’ ethical and social practices no longer present a simple voluntary decision, which explains the CSR development over time. Visser [13] considered that CSR versions missed the promotion of our community and ecosystem health, quite the contrary, they made it worse. Specifically, they failed to introduce innovative tools dealing with the existing environmental issues. He argued that the CSR understanding has been evolving according to overlapping ages1: The age of Greed, the age of philanthropy, the Marketing age and the Management age. While the three first ages have introduced a responsive CSR stream, the management age has established CSR in the core of business. It generates a strategic CSR.
When the firm is involved in CSR activities that meant to exclusively respond to stakeholders’ basic needs and reporting standards, its CSR policy is responsive. However, when more pioneering initiatives are undertaken and going beyond standards and regulations, CSR activities are strategic [9, 27, 28]. We should also mention that another more civil version of CSR is taking place, namely the transformative CSR [13]. Nonetheless, we consider that this version is still in an embryonic stage for the profit-oriented enterprises.
The coexistence of these ages depends on the space–time setting. Hence, to explain the CSR and Innovation nexus we have to understand the evolvement of the CSR concept and its continuous interaction with corporate innovation.
The responsive CSR concept has been used in recent studies. Porter and Kramer [14] considered CSR as responsive if it has two goals: good corporate citizenship and risk mitigation. Put differently responsive CSR has no specific plan and strategy that allow the firm to create a competitive advantage. Indeed, there is no specific study that provides a clear development of responsive CSR conception. Vishwanathan et al. [18] described the non-strategic side of CSR as a blind spot to CSR researchers. Indeed, investigations’ focus has been oriented to the strategic CSR. Researchers consider that firms which do not apply CSR strategically are applying it responsively.
This narrow development of responsive CSR made the firms’ classification absolute. From a theoretical perception, a company is whether strategic or responsive, while in reality, it can be both especially since responsive CSR versions can share some strategic CSR criteria. We should point out there is no sole definition of the strategic CSR, which makes the responsive CSR understanding more blurred. For instance, Visser [13] argued that responsive CSR is meant to orient its activities in specific areas that are not specifically related to the core business. He identified the following forms of non-strategic CSR: the defensive, charitable and promotional CSR strategies.
Bocquet et al. [9] found that responsive CSR lessens the different corporate innovation types while strategic CSR promotes them. In contrast, Bocquet et al. [17] underlined the positive effect of the responsive CSR on the technological innovation for the SMEs. Thus, to give better insights into these controversial results, we analyze the interaction between innovation and the responsive CSR version previously mentioned.
In the following, we address the different strategies of responsive CSR and their influence on innovation strategies.
As business requires creativity, it is assumed to be naturally innovative [29]. Yet, what makes the ages different is to which goal this business creativity is directed. The first age of the CSR development is the age greed, in which CSR was perceived as a tool to serve shareholders’ interests by taking into account only aligned stakeholders’ interests. During this age, and consistent with the shareholder theory, CSR activities were defensive as they were undertaken only to protect the financial result.
For example, according to “Fortune” magazine, the American company Enron was one of the most innovative firm from 1996 to 2001. It was listed among the 100 best American companies by the same magazine. Enron practice of CSR was widely known, specifically its green model. It built a great image that hides the true nature of its practices. However, its collapse was unavoidable since it was the result of greed. Some studies considered the Enron scandal as a juncture in the CSR understanding [30, 31]. They analyzed the CSR evolution after the post-Enron era.
After the 2008 Crisis, economic actors realized that they misunderstood CSR conception. Miller [32] considered the confusion between legitimate economic rationality and greed, more specifically excessive desire, is the main trigger of crisis. It is straightforward to see that Enron only acted socially responsible when it is financially profitable. Hence its scandal has been one of the greatest examples of CSR in the age of greed.
Even though CSR activities also have to generate cash-flows, considering the financial performance as the sole gain could never foster sustainability and innovation. Indeed, enhancing financial performance provides more funds for innovation investments. Nevertheless, defensive CSR cannot provide a good understanding of multiple needs of different groups, which increases agency conflicts. Furthermore, it cannot rebuild the corporate reputation, which in return threatens innovation success, especially in casino economies2 where high-risk levels are taken. Bertrand et al. [33] described the defensive CSR as a “poor vector” of innovation.
The second age of the CSR development is the philanthropic age, where CSR is presented as a charitable action. Carnegie [34] claimed in his article “The Gospel of Wealth” that wealthy investors have to use their fortune for the community’s well-being and empowerment. In line with Stiglitz’s [35], wealth should be distributed equally to avoid the inequality costs and, therefore, recession. Put differently, we need charities to drive growth. The charitable actions can help innovation improvement. Bereskin and Hsu [36] emphasized that the corporate philanthropy with universities and non-profit organization improves the corporate research partnerships and strengthen its network. Thus, innovation efficiency is increased. Charity and philanthropy are mobilized to establish collaborations. Yet, to take advantage of the corporate philanthropy and boost corporate creativity, a long-term strategy of charity should be elaborated [37]. Otherwise, the charity can lead to waste the financial resources and consequently limits innovation investments.
Despite the beatific view of charitable CSR, it has failed to face systemic problems and solve social and ecological matters. This failure was due to two main reasons.
First, charitable activities’ goals do not incorporate the improvement of the financial performance and since companies are for-profit organizations, increasing their gain, and using their cash flows to create a competitive advantage should be out of the question. Therefore, non-strategic social actions can damage the corporate competitive position. Protecting and improving financial results should be neither out nor the core of the CSR scope. In other words, companies should capture private benefits from their social strategies while responding to the philanthropic criterion, which is one of the strategic CSR dimensions, named ‘specificity’ [38].
The second reason is the limited capacity of firms to respond to all social and ecological needs. Non-strategic philanthropy is like trying to fill a bucket, which is leaking from the inside. Porter and Kramer [14] underlined that no business is able to solve all of society’s challenges or bear its costs. Therefore, each company has to select issues that cross its business and field of knowledge. Furthermore, CSR actions must fit the corporate missions and goals. Investing in generic social issues with no dynamic effects and which are neither significantly influenced by the enterprise’s operations nor affect its long-term competitiveness is a waste of corporate wealth. De Silva and Wright [39] indicated that strategic philanthropy is most often associated with open innovation. Accordingly, profit companies are likely to collaborate and co-create value with non-profit organizations through open innovation approaches.
The Marketing CSR also called promotional CSR is another form of responsive CSR. A promotional CSR is a reputation-building CSR. It encompasses social practices public relations’ opportunities with the aim of enhancing corporate reputation and brand image. It focuses generally on the stakeholders’ perception of the company and tries to find an optimal strategy that satisfies the interested actors and gives the firm a sound depiction. Therefore, it improves the financial result, provides more environmental support, reduces reputational risk, and builds a greater trust level [40, 41, 42, 43, 44]. The main aim of promotional CSR is to guarantee and promote more ‘Visibility’. Singh and Dhir [45], cause-related marketing has become an emerging field of research.
According to the founder of Virgin Group Richard Branson, “Young people today want to see change. They want a better world”3. Hence, being socially responsible is the best promotional way used by firms to achieve stakeholders’ satisfaction. Promotional CSR should start from the inside with an integrated marketing model. Moreover, it is likely to promote exploratory innovation, especially with the reputational risk mitigation. Lefebvre [46] underlined that social marketing is an evolutionary concept planned to foster innovation. Responsible marketing is most often positively associated with more marketing innovation. However, in practice, markets-makers and practitioners face challenges to align social/human and business issues. Hence, the spread of innovation that aims to solve the relative concerns become harder Lefebvre [47].
This CSR version might look sound. Nevertheless, it has several deficiencies. According to Singh and Dhir [45], around two-thirds of customers believe that companies’ spending on marketing is quite large compared to the social matters spending. They are not focusing much on real social issues. With limited knowledge of social or environmental matters, firms might apply CSR actions for greenwashing. Indeed, without a real social goal, using chaotic and disordered actions in a responsive way can only have a short-term impact. Thus, ensuring a corporate gain from the applied action might be harder. In the worst cases, CSR leads to antithetical results. Esper and Barin Cruz [48] discussed how CSR could be a hypocrisy tool to influence the market perception. With the presence of a large gap between the way in which a company shows off and the way in which it acts, stakeholders could be manipulated and suffer manoeuvering hypocrisy, which leads to social scandals and trust collapse.
This CSR’s poor understanding and active talking about CSR commitment while covering profitable practices that are socially and environmentally dubious trapped not only small businesses but also multinationals. Volkswagen test cheating, Siemens bribe scandal, BAE corruption scandal, General Motors defective ignition switches, Mitsubishi products falsified data, as well as Wells Fargo account fraud scandal and so on, are businesses that have gone responsibly astray. Brenkert [49] pointed out that we need to rethink CSR efforts to close the immoral gaps.
To conclude, a large body of research has highlighted the negative results of cosmetic CSR practices. In fact, CSR can be considered as a double-edged sword. It could generate extra costs that hamper corporate survival and innovativeness. Hence, firms have to select the appropriate social practices that foster the firm’s position and enhance its profit and growth. In other words, companies should view CSR strategically.
Under the high social pressure, several firms have undertaken CSR initiatives that go beyond CSR regulations and standards to gain the stakeholders’ trust. CSR could have positive influences if it is used strategically. According to the institutional theory, the corporate framework is based on the cohesion of the interdependent components. Hence, enterprises are affected and could affect their environment. To face CSR challenges and reach the optimal CSR practices effects firms should classify social acts into three main streams [14]:
The generic social impact is generated by social matters which are not affected by the company’s actions. The CSR practices do not influence the company competitiveness. Investing in this category is by no means strategic.
The value chain social impact: where we find the possible actions through which the firm can influence its environment. Given the tremendous social issues, no firm has the capacity to solve the whole social problems. Therefore, it should select social programs that can be affected by the company’s actions. The value chain social impact actions can be strategic or responsive it depends on the ability of the company to benefit the community while reinforcing its strategy.
The third stream is the social dimensions of competitive context: In this category, we find the social issues that influence significantly the firms’ competitiveness. The CSR actions under this group are strategic.
Based on this classification companies should select more strategic CSR activities that affect the competitive context of the company and improve the social environment. Along the same line, Burke and Logsdon [38] pointed out that social action could create a measurable economic benefit under the five following conditions: the centrality, the specificity, the proactivity, the voluntarism, and the visibility. To establish strategic CSR companies’ social actions should be within its field of knowledge. In other words, firms have to prioritize social issues based on their salience to the business activity. Enterprises have to create a shared value, to capture private benefits due to social actions. These actions should be in line with the corporate environmental evolvement and should reflect the firm’s anticipation of its framework evolution.
The efficiency of these actions will depend closely on the identification of the key stakeholders; the firm has to be concerned about their interests. More recently, Vishwanathan et al. [18] introduced a more inclusive framework for strategic CSR where they considered strategic CSR as the intersection between the social enhancing activities and the financial performance-enhancing actives. Accordingly, financial performance enhancement is a multidimensional result that depends on all CSR determinants, namely the firm’s reputation enhancement, the stakeholder reciprocation, the risk mitigation, and the innovation capacity improvement.
Strategic CSR conception was developed first by Burke et al. [50]. It means relating CSR to the corporate core business, the implementation of social management systems, and the setting of social targets, auditing, and reporting. In the same line, Athanasopoulou and Selsky [51] defined strategic CSR as a continuous process that takes into account its own effect. More precisely, a company can pursue its business goals while considering the stakeholders’ engagement through strategic CSR [52]. Thus, the efficient implementation of CSR strategies depends on corporate activities, skills, and capabilities. While other CSR versions can have different opposite linkage with innovation depending on their strategic application, innovation enhancement is one of the strategic CSR pillars. Vishwanathan et al. [18] explained how strategic CSR enhances the firm reputation, increases stakeholder reciprocation, mitigates firm risk, and strengthen innovation capacity. These effects cannot be achieved through the non-strategic CSR.
The reputation enhancement: It is one of the most used mechanisms to explain the positive effect of CSR on the firm’s competitive position and financial performance increasing. The legitimacy theory and the signal theory give it a robust theoretical foundation. Axjonow et al. [40] described CSR as a tool for reputation management. Indeed, if CSR succeeds to improve financial performance through enhancing the corporate reputation, then it has satisfied one of the strategic CSR pillars. Abugre and Anlesinya [53] stressed that reputation enhancement is a mechanism that mediates the CSR and financial performance link. For Zerbini [27] and Janney and Gove [54], reputation is a strategic asset. In the 21st century, social reputation and digital reputation play an important role in the CSR promotion
The stakeholder reciprocation: One of the main and well-known theories that have supported the CSR positive effect is the Stakeholder theory [55]. Applying strategic management aim to optimize the different stakeholders’ satisfaction. McWilliams and Siegel [56] indicated that when firms are engaged in CSR, their actions should be beneficial to at least certain stakeholders. Hence, selecting the key stakeholder groups is crucial to apply strategic CSR. While the reputation improvement mechanism has to be visible externally, the stakeholders’ reciprocation mechanism aim is creating benefit for the existent stakeholders. This mechanism has to improve the cooperation between the firm and its stakeholders [18].
Lins et al. [57] found that during crises trust between stakeholders and companies is built through socially responsible investment (SRI). Employees’ productivity is higher for socially responsible firms and creditors have more faith in these firms’ transparency. In the same line, Hasan et al. [58] concluded that social considerations of the principal stakeholders are precious especially for firms that dispose of higher discretionary cash levels. Similarly, Govindan et al. [59] proved that CSR practices influence the suppliers’ selection, which affects corporate competitiveness.
The risk mitigation: CSR strategies should reduce information asymmetry [43], which limits the agency conflicts. Harjoto and Laksmana [42] pointed out that CSR serves as a control mechanism for corporate risk. Consistent with Vishwanathan et al. [18], CSR engagement leads to get in touch with diverse stakeholders, which extends the company’s connections and gives access to new information. This information reduces corporate-specific risk. Besides, Mayberry [44] marked that CSR strategies reduce firms’ risk and grant insurance-like benefits. Recently the environmental risk was given greater consideration, Zhou et al. [60] focused on the carbon risk management as one of [61] emphasized that natural resources such as the water for the food and beverage sector create conflicts between industries and stakeholders. Indeed, legislation in Europe has been considering the social risk management through several enacted laws. Jung et al. [62] documented a positive relationship between the carbon risk and the cost of the corporate debt. Failing to respond to the Carbon Disclosure Project increases the environmental risk, which leads to an increase in the debt cost.
The innovation capacity improvement: Previous research and practitioners endorse that innovation enhances corporate competitiveness. It enables companies to differentiate and overcome competitors. Nevertheless, innovation is risky. Its success requires some specific capacities such as the deep comprehension and support from the stakeholders, which can be achieved through the strategic social practices. For instance, Flammer [63] highlighted how responsible companies are favoured and receive more government procurement contracts due to the stakeholders’ interest consideration. Moreover, employees are more motivated, they feel safer and more comfortable in responsible firms, which drives better information sharing. Furthermore, the stakeholders’ synergy, built through CSR, promotes identifying new opportunities. Interacting and understanding stakeholders’ needs should lead to greater innovation opportunities detection. Cegarra-Navarro et al. [64] presented, in their alternative model, innovation enhancement as a CSR mechanism that improves financial performance. Their results support the mediating role of innovation in the CSR-CFP relationship, which is confirmed by Bocquet et al. [9]. Halkos and Skouloudis [65] underlined that strategic CSR is a multifaceted construct that provides a variety of opportunities to innovate regardless of the innovation type. Strategic CSR should lead to thinking-out-of-the-box in a way that improves the corporate creativity and enhances innovation capacities.
It is straightforward to notice that the enhancement of the innovation capacity influences its intensity and initiative. The other mechanisms also can affect innovation success. For instance, a better relational with different stakeholders groups helps the firm to understand their desire and expectations and generates more innovation opportunities. In a similar stream, Porter and Kramer [14] underlined that strategic CSR is a source of innovation and competitive advantage creation. Its effect on innovation can be more pronounced when the company improves its CSR process, which in turn drives social innovation [66]. One of the examples that can show how strategic CSR fosters innovation is Denmark’s biggest energy company Orsted. In 2012 and after the financial crisis the price of natural gas was dropping by 90%. To face these circumstances, Oersted’s board hired as a new CEO Henrik Poulsen a former executive at LEGO. While several companies adopted crisis management strategies to overcome the situation, Poulsen detected the opportunity and need for crucial change. The company at this level switched based on their new innovative responsible strategy from black energy to the green one. It was a radical transformation with the new core business, new management methods and new process that grants sustainable growth.
Similarly, Ecolab was a company that sells food safety services and cleaners with a modest growth level, around 10% annually in the early 2000s. When Douglas M. Baker Jr. became the CEO in 2004 he felt that moving to the adjacent markets will not provide the desired growth. In line with Bocquet et al. [9], strategic CSR has to understand and consider the stakeholders while making strategies. Ecolab started its transformation by asking customers among others to understand the real needs and what is really lacking in the market. Through this understanding and collaboration with Nalco Company, Ecolab was able to present new products and cover $12 billion market cap in 2011.
These examples not only reflect the strong positive association between the strategic CSR and the innovation but also reveal the vital role of the managerial characteristics of this relation.
CSR and innovation are the key drivers of responsible and sustainable competitive advantages. Hence during this last decade investigations about their linkage presented a significant strand of research. Based on several real examples, studies [17, 67, 68, 69] highlighted the crucial influence of the managerial characteristics (the entrepreneurial orientations, cognition, perspective, culture, and so on) on the CSR and innovation nexus. Indeed, managers’ characteristics provide the exact CSR age to which the firm belongs. Yang et al. [68] focused on the managerial cognition association with the CSR and innovation link. According to their study, the proactive environmental strategy focus is positively linked to two factors the managers’ perceived business and social pressures. This association prompts the corporate innovation capacities. Similarly, Pedersen et al. [69] tested the mediating effect of organizational values such as the management style or the organizational structure and culture on the CSR and innovation nexus. They concluded that the CSR and innovation association depends deeply on the managers’ rooted values and flexibility.
The age of CSR in which the company is positioned depends on the managerial characteristics. Furthermore, managers’ perspective is able to create the appropriate climate to facilitate the CSR conception transformation. However, this managerial perspective can be oriented due to the legal and social framework pressure, consistent with the institutional theory. Scott [70] indicated that the normative, regulative, and cognitive elements form different kinds of pressures shape the managers’ cognition in strategy establishment. Indeed, the existence of unavoidable restraints can make the CSR and environmental management unsustainable [71].
System builders such as the corporate innovators, managers and board members are the main actors that orient the firms’ decision-making. Their attitudes and actions influence corporate strategies and the interaction between its decisions. The CEO position is considered as the highest in the company’s organogram. Hence, we focus on its traits’ effects on the CSR-innovation nexus. Cho and Kim [72] mentioned that the CEO’s career is significantly affected by risky strategies such as innovation, research and development, CSR and capital expenditures. Consequently, young and less experienced CEOs are less likely to undertake innovative or social investments. Nevertheless, the exploitation of the old knowledge and the CEOs’ willingness to preserve their value and success may alleviate this negative impact. In a similar vein, Lin et al., [73] provided evidence for the positive association between the CEO educational degree and innovation initiative. Bendell and Huvaj [74] emphasized that CEOs with high tenure are more likely to invest in innovation when they adopt CSR strategies. Their position allows them to bring more attention to the organizational network with different external stakeholders, which increases their innovation incentive. They concluded that the CSR and innovation linkage is strong when CEOs have long execution periods. Thus, the CEO experience, knowledge and network moderate the CSR–innovation linkage, which explains the universities current development. We notice that universities’ curricula, specifically management and corporate programs have been updated and have become more focused on social performance and CSR. Managers aim to acquire legitimacy through their social practices while gaining competitive advantages through innovation.
Board diversity in large companies plays a crucial role in the decision-making process. Indeed, the directors’ attributes such as gender, nationality, age, educational level and independency mediate the innovation-CSR linkage [17, 75].
The gender diversity more specifically the gender equality, which is one of the CSR components, forms a responsible innovation pillar, according to the European Commission report.4 Several previous studies stressed that female directors are more risk-averse and avoid risky investments [76]. Thus, they invest less in innovation. Nevertheless, this risk aversion is influenced by the female manager experience. With their specific knowledge and higher flexibility [77], women presence on the board creates complementarity which promotes innovation. Elstad and Ladegard [78] underlined that the presence of women on the board influences the decision- making dynamism. Attia et al. [79] pointed out that gender diversity can enhance corporate product innovation. The presence of women can create better interaction and greater complementarity between R&D teams.
Another pillar of responsible innovation is the Governance dimension. The CSR-governance is associated with the presence of independent directors. Besides, the presence of foreign directors provides greater community involvement [80]. These criteria reflect the company’s transparency and social performance, which affect the stakeholders’ trust and reduces corporate risk and consequently improves innovation. According to Attia et al. [79], independent directors’ presence fosters the innovation intensity and process innovation.
The educational level also is one of the board diversity forms. Haniffa and Cooke [81] focused on the ethnic and cultural background of the board’s members. They argued that a higher educational level is associated with better stakeholders understanding. This understanding helps the board members to predict the adequate innovation fields. Moreover, a higher educational level provides a better knowledge, which foster innovation.
Digitalization has been speeded since the ending of the 20th century. This development presented the trigger of the fourth industrial revolution. A revolution based on the interaction and the fusion of the real sphere, the digital sphere, and the biological one. What makes this revolution exceptional is its high speed that has no historical precedent. With an exponential rather than a linear pace, industries in every region have to update their systems of management, production and governance to face the depth of the environmental changes [82]. The world economic forum [83] project aims to accelerate sustainable production. This project is based on using innovation to drive efficiency, decreases the environmental damages, boost competitiveness and enhancing the human well-being. Hence, to reach this goal, shaping future production and promoting new levels of collaborations is required. Through the interactions between the different interested actors, an informational and knowledge exchange process occurs, which in turn generates greater innovations [84]. Soto-Acosta et al. [85] pointed out that digital technologies created new tools of communication that can enhance the management of knowledge and the corporate network. Besides, they focused on open innovation importance. Indeed, collaborating or including stakeholders in the decision-making process helps to open the company’s view [86]. Hence, it boosts the social strategic engagement while improving innovative capacities. Moreover, corporate innovation interacts with the management systems. Singh et al. [87] claimed that transformational leadership increases the employees’ motivation and enhances their communication which helps them to realize their green potentialities and boost green innovation, thereby ensuring their competitive position. Del Giudice et al. [88] presented a detailed analysis of human resources management and the open innovation link in modern enterprises. Human dimensions are pivots of innovativeness and social and ecological commitment. Projects such as CAYLEY, FlaxPreg, VOILIN, and so on are great examples that show the vital role of collaboration, inclusion and networks enhancement to generate sustainable innovative projects and to improve creativity.
With the fast evolvement of the corporate framework and under the fourth revolution circumstances, new industries are emerging while others are fading. Hence, having better knowledge will enhance corporate abilities to predict future development. Nevertheless, having knowledge does not grant its efficient use. Del Giudice et al. [89] pointed out the importance of collaboration and information sharing in enhancing knowledge use. They shed light on the role played by new technologies in harmonizing the corporate knowledge needs and the informational flows.
The dynamism of the CSR conception was one of the reasons that explain the CSR-innovation ambiguous link. According to Vishwanathan et al. [18], the corporate innovative capacity should present one of the strategic CSR pillars. Hence, assuming a positive linear link between CSR and innovation is expected if the CSR measure is a strategic one. In our investigation, we attempt to extend the previous studies by using a more flexible semi-parametric model to seize the shape of the innovation effect on the CSR index. This method relaxes the econometric assumptions, thereby, grants more accurate results that are inspired by reality. We use the ESG index and its components to measure CSR, while we consider the natural logarithm of patents as the innovation proxy. The aim of this study is to verify whether the current ESG index and its components reflect strategic CSR measures. Put differently, how can companies include CSR in their strategies and orient their innovativeness toward the social and ecological commitment, thereby, generate innovative projects that create shared value. Our main assumptions are:
H: The corporate innovativeness does not affect CSR linearly. Thus, CSR is not always presented in the core of the companies strategies.
To reach our goal, this section will be as flows. First, we present our sample and data. Second, the variables descriptions followed the methodology and Model. Finally, we present and analyze the empirical results.
To test the effect of corporate innovation on the CSR scores, we conduct our study on the SBF 120 French companies. Thanks to the French Parliament enacted Grenelle Acts in 2010 large French companies have to communicate their CSR activities, which enable us to have a clearer view of the CSR strategies for these companies. Our panel data, which covers the period from 2010 to 2016, are collected from two main sources. The Bloomberg database was employed to measure the CSR through the ESG score and its components. Besides, we use the annual sectorial survey of the National Institute of Statistics and Economic studies to determine the corporate innovation through patents number.
Tables 1 and 2 present the variables’ description used to conduct our study. In Table 1, we consider the Natural logarithm of patents (Ln_PA + 1) as an innovation proxy, which is the independent variable. The CSR measures are the dependent variables. The ESG presents the global score of the CSR while the specific environmental, social and governance scores are presented respectively by the ENV, SOC and GOV. Table 2 describes our controls. Based on the prior research, we selected the board specifies, the ownership structure and the financial performance variables.
Abbreviation | Description | Type | Previous studies |
---|---|---|---|
PAT | Number of patents | Discrete | Mishra [90]; Raghupathi [91] |
Ln_PA + 1 | Natural logarithm of PAT+1 | Continuous | |
ESG | CSR disclosure score | Continuous | Wang and Sarkis [92]; Ji et al. [93]; Hoang et al. [94] |
ENV | Environment disclosure score | Continuous | |
SOC | Social disclosure score | Continuous | |
GOV | Governance disclosure score | Continuous |
The dependent and independent variables description.
Abbreviation | Description | Type |
---|---|---|
B_SIZE | Number of the board members | Discrete |
WO_B | % of women on the board | Continuous |
B_AGE | Board average age | Continuous |
ESG_ BONUS | Remuneration for CSR policies | Dummy |
Ln_TE | Natural logarithm of total employees | Continuous |
ROA | Return on assets | Continuous |
LEV | Debt book to total asset ratio | Continuous |
INDP_B | % of independent on the board | Continuous |
Duality | Board duality | Dummy |
IN_PROP | % of the institutional investors’ share of capital | Continuous |
STAT_PROP | % of the state’s share of capital | Continuous |
FAM_PROP | % of the family’s share of capital | Continuous |
The controls description.
Imposing the linear econometric assumption of innovation effect on the CSR might not be accurate especially with the dynamism of the CSR conception. Aiming to define a pragmatic shape, we use in this study a semi-parametric model. Through this method, we relax constraints for the innovation effect while maintaining the linearity assumption for the controls. Hence, our model is as follows:
CSR refers to the CSR variables (ESG, ENV, SOC, GOV) defined previously. Innovation is measured by the Ln_PA + 1 and controls matrix includes all the controls variables presented in Table 2. Finally,
The n index refers to the number of observations and J presents the roughness of the objective function. This function optimum depends on the minimization of residuals squared and the maximum possible smoothing of the innovation function. The
The
Follows an approximate χ2 distribution, the null hypothesis of this test supposes the equality between likelihoods. The degree of freedom is determined through the difference between the numbers of parameters of each model. Put differently, if the semi-parametric regression has a higher number of parameters then the linear regression is not appropriate.
In Table 3 we present the descriptive statistics of our study. We focus on the averages of our variables and their dispersion.
Variable | Mean | Std. Dev. | Max | Min |
---|---|---|---|---|
Patents | 59.672 | 250.853 | 2448 | 0 |
Ln_PA + 1 | 1.128 | 1.949 | 7.803 | 0 |
ESG | 43.474 | 12.942 | 68.182 | 5.785 |
ENV | 36.656 | 14.042 | 67.442 | 1.55 |
SOC | 49.193 | 14.469 | 80.702 | 3.509 |
GOV | 58.368 | 9.032 | 76.786 | 14.286 |
B_SIZE | 12.627 | 3.419 | 23 | 4 |
WO_B | .237 | .125 | .579 | 0 |
B_AGE | 58.573 | 4.952 | 68.778 | 15.384 |
ESG_ BONUS | .184 | .387 | 1 | 0 |
Ln_TE | 10.027 | 1.775 | 13.071 | 0 |
ROA | 3.798 | 10.585 | 276 | −23.067 |
LEV | 25.677 | 16.223 | 96.083 | −80.736 |
INDP_B | .538 | .204 | 1 | 0 |
Duality | .203 | .402 | 1 | 0 |
IN_PROP | .408 | .248 | .907 | 0 |
STAT_PROP | .04 | .15 | .922 | 0 |
FAM_PROP | .089 | .182 | .805 | 0 |
Variables description and summary statistics.
With an average of 59.67, the SBF120 companies have innovative potentialities. Nevertheless, the patents number presents a significant dispersion with a high standard deviation. For the CSR measures, the average of the ESG scores is 43.474, more precisely; the highest mean of the ESG components is the governance score with an average of 58.37 against only 36.656 the lowest for the environmental score. These statistics shed light on the environmental current issues and the required efforts needed by these companies to improve their environmental disclosure. Besides, we found that 18.4% of companies are using a remuneration bonus policy to enhance the ESG performance this might drive more attention to the ESG matters and help companies to view CSR more strategically.
For the percentage of women’s presence on the board, we register an average of 23.7%. After the Copé-Zimmermann enacted law in 2011, this average has increased considerably compared to prior periods. Nevertheless, the female directors occupy rarely executive positions. The board average age is 58.57 years old. It is also a positive signal on the degree of expertise of the directors as most of them have been board members in the past or have a business experience. However, with such a high average age, modern trends might not be appreciated. On one hand, this might reduce conflicts during the decision making process. On the other hand, it risks neglecting the youth population trends and views. Concerning the board independency, on average more than half of the boards’ members are independent (53.8%), which reflect a great level of transparency. Besides, this help to open the companies view and have an outsider perception.
To reach the aim of this investigation, Table 4 as well as Figures 1–4 reflect the innovation effect on the CSR proxies.
ESG | ENV | SOC | GOV | |
---|---|---|---|---|
Ln _PA + 1 | 3.881* (2.127) | 7.214*** (2.269) | 0.756*** (0.268) | −0.972 (1.684) |
B_SIZE | 1.090*** (0.142) | 0.829*** (0.170) | 1.127*** (0.170) | 1.034*** (0.092) |
WO_B | 16.796*** (3.701) | 10.495** (4.448) | 12.046*** (4.495) | 9.774*** (2.398) |
B_AGE | −0.373*** (0.117) | −0.212 (0.141) | −0.200 (0.141) | −0.174** (0.076) |
ESG_ BONUS | 3.486*** (1.139) | 2.410** (1.334) | 2.646* (1.368) | 5.458*** (0.738) |
Ln_TE | 0.977*** (0.257) | 0.906*** (0.310) | 0.810** (0.314) | −0.053 (0.167) |
ROA | −0.048 (0.037) | −0.046 (0.043) | 0.009 (0.044) | −0.006 (0.024) |
LEV | 0.024 (0.029) | −0.011 (0.035) | −0.025 (0.036) | −0.030 (0.019) |
INDP_B | 14.759*** (2.336) | 20.352*** (2.802) | 10.912*** (2.823) | 11.209*** (1.516) |
Duality | 0.621 (1.094) | −0.627 (1.320) | 1.478 (1.335) | 0.460 (0.710) |
IN_PROP | 8.487*** (2.034) | 9.379*** (2.412) | 8.183*** (2.448) | 1.941 (1.319) |
STAT_PROP | 1.462 (2.748) | 8.959*** (3.259) | −1.502 (3.365) | −0.194 (1.779) |
FAM_PROP | 0.794 (2.733) | 6.353* (3.366) | −9.121*** (3.397) | 4.445** (1.772) |
FOR_PROP | 2.426 (2.127) | −2.032 (2.506) | 6.783*** (2.518) | 1.085 (1.380) |
_cons | 24.007 (7.161) | 9.370 (8.568) | 25.675*** (8.529) | 47.106*** (4.652) |
Number of obs | 681 | 648 | 657 | 681 |
pilot goodness-of-fit chi2 (P-value) | 64.78 (0.0016) | 57.34 (0.0000) | 22.71 (0.9458) | 79.38 (0.0000) |
Log restricted-likelihood (P-value) | −2404.585 (0.0000) | −2375.429 (0.0000) | −2421.249 (0.0000) | −2132.486 (0.0000) |
LR test vs. linear model: chibar2 (P-value) | 7.14 (0.0038) | 7.09 (0.0039) | _ | 5.95 (0.0074) |
The innovation effects on the CSR proxies.
p-value < 10%.
p-value < 5%.
p-value < 1%.
Values between the parentheses presents the standard errors of the estimated coefficients.
Innovation effect on the ESG scores.
Innovation effect on the Environmental scores.
Innovation effect on the Social scores.
Innovation effect on the Governance scores.
Figure 1 presents the innovation effect on the global ESG score. According to its result, we underline the generally positive impact of innovation on the CSR scores, which is consistent with Table 4 coefficient (significant at the 10% level). Indeed, this graph can be divided into three main parts based on the innovation intensity (when Ln _PA + 1 less than 4; between 4 and 5, and higher than 5). In the first part, an increase in corporate innovation enhances CSR slightly. Firms belonging to the first category of innovation intensity tend to consider ESG matters while innovating. The second part reflects a negative association between CSR and innovation. Companies in the second category are inventing without focusing on the ESG issues quite the contrary their innovation might reduce their ESG scores. In other words, those companies are not applying CSR strategically. They only focus on CSR matters if it grants financial benefits. Finally, the last category is where innovation can boost ESG scores. At this level of innovation, we found a remarkable positive effect of the corporate innovativeness on CSR. The most innovative companies are those that apply CSR strategically. They put CSR in the core of their innovation process. We might assume their adoption of open innovation, which allow companies to share knowledge and better understand stakeholders, consequently improves ESG scores. The positive effect of this third category is confirmed not only for the ESG global score but also its components. Nevertheless, it is not the case of the two first categories. While Figure 3 supports the linear shape between social engagement and innovation, Figures 2 and 4 show similar curves’ shapes with different flattening level. Innovation is always socially beneficial.
Concerning the controls’ linear effect on the CSR scores, we should drive attention to the positive influence of the board diversity and boar size in enhancing the CSR engagement. Moreover, the ESG remuneration fosters the ESG scores. Its effect is more pronounced in the governance score. Besides, we find a non-significant influence of the board duality and the financial variables. Furthermore, foreign ownership only increases social commitment. The family ownership decreases it while enhancing the governance scores. Finally, we point out the state and institutional ownership effect on boosting environmental engagement.
The evolvement of social and ecological requirements created a dynamic corporate framework that leads to alternate business practices. This evolution has widened the CSR scope. Hence, CSR went from a defensive or a philanthropic extra activity to a part of the core business. These successive mutations influenced the CSR-innovation link. In this chapter, we analyzed the evolvement of the CSR conception based on four ages: the age of greed, the age of philanthropy, the marketing age and the management age. Moreover, we presented the links between the different CSR versions and corporate innovation. This link is associated with corporate competitiveness.
CSR forms a road map for an emerging innovation paradigm if it is strategically perceived. Indeed, the CSR and innovation nexus is influenced by the managerial perspectives, which are the cores of the CSR understanding and innovation initiatives. However, the managers’ social commitment is not an independent factor. It is affected by the institutional framework. In other words, it depends on the legal, social and economic pressures as well as the digital transformation. With an economic system similar to a Matryoshka doll, decision-makers have to predict future evolutions through strengthening their social network. They have to identify the right moments and persons with whom they should collaborate to create shared value, enhance their innovativeness and improve their environment comprehension. Regulators should consider the continuous evolvement of the business-work and the technological improvement to control the irresponsible behaviours. They can help firms to identify the appropriate timing of the CSR and innovation synergetic effect occurrence.
Finally, we draw attention that the strategic CSR version is not the last one. Nowadays, a transformative CSR is taking place. The difference between these two CSR versions is that while strategic CSR has been included in the core business, the transformative CSR is the trigger of the business. Investors are creating new social start-ups where business innovativeness is driven by social and ecological matters. Thus, their innovativeness is a responsible innovation.
Authors are listed below with their open access chapters linked via author name:
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\\n\\nJim Van Os 2015-18
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\\n\\nFei Wei 2016-18
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\\n\\nQi Xie 2016-18
\\n\\nXin-She Yang 2017, 2018
\\n\\nYulong Yin 2015, 2017, 2018
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She obtained her Ph.D. from Universiti Putra Malaysia in 2010 with a National Science Fellowship awarded from the Ministry of Science, Technology and Innovation Malaysia and has been actively involved in research ever since. Her main research interests include analysis of carriage and transmission of multidrug resistant bacteria in non-conventional settings, besides an interest in natural products for antimicrobial testing. She is heavily involved in the elucidation of mechanisms of reversal of resistance in bacteria in addition to investigating the immunological analyses of diseases, development of vaccination and treatment models in animals. 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Prior to his academic appointment, Dr. Lai worked as a Senior Scientist at the Ministry of Science, Technology and Innovation, Malaysia. His current research areas include antimicrobial resistance and plant-pathogen interaction. His particular interest lies in the study of the antimicrobial mechanism via membrane disruption of essential oils against multi-drug resistance bacteria through various biochemical, molecular and proteomic approaches. 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Over the past few decades, no major new types of antibiotics have been produced and almost all known antibiotics are increasingly losing their activity against pathogenic microorganisms. The levels of multi-drug resistant bacteria have also increased. It is known that worldwide, more than 60% of all antibiotics that are produced find their use in animal production for both therapeutic and non-therapeutic purposes. The use of antimicrobial agents in animal husbandry has been linked to the development and spread of resistant bacteria. Poultry products are among the highest consumed products worldwide but a lot of essential antibiotics are employed during poultry production in several countries; threatening the safety of such products (through antimicrobial residues) and the increased possibility of development and spread of microbial resistance in poultry settings. This chapter documents some of the studies on antibiotic usage in poultry farming; with specific focus on some selected bacterial species, their economic importance to poultry farming and reports of resistances of isolated species from poultry settings (farms and poultry products) to essential antibiotics.",book:{id:"6978",slug:"antimicrobial-resistance-a-global-threat",title:"Antimicrobial Resistance",fullTitle:"Antimicrobial Resistance - A Global Threat"},signatures:"Christian Agyare, Vivian Etsiapa Boamah, Crystal Ngofi Zumbi and\nFrank Boateng Osei",authors:[{id:"182058",title:"Dr.",name:"Christian",middleName:null,surname:"Agyare",slug:"christian-agyare",fullName:"Christian Agyare"},{id:"261271",title:"MSc.",name:"Crystal Ngofi",middleName:null,surname:"Zumbi",slug:"crystal-ngofi-zumbi",fullName:"Crystal Ngofi Zumbi"},{id:"261272",title:"MSc.",name:"Frank Boateng",middleName:null,surname:"Osei",slug:"frank-boateng-osei",fullName:"Frank Boateng Osei"},{id:"261273",title:"Dr.",name:"Vivian Etsiapa",middleName:null,surname:"Boamah",slug:"vivian-etsiapa-boamah",fullName:"Vivian Etsiapa Boamah"}]},{id:"49246",doi:"10.5772/61300",title:"Chitosan as a Biomaterial — Structure, Properties, and Electrospun Nanofibers",slug:"chitosan-as-a-biomaterial-structure-properties-and-electrospun-nanofibers",totalDownloads:4727,totalCrossrefCites:27,totalDimensionsCites:63,abstract:"Chitosan is a polysaccharide derived from chitin; chitin is the second most abundant polysaccharide in the world, after cellulose. Chitosan is biocompatible, biodegradable and non-toxic, so that it can be usedin medicalapplications such as antimicrobial and wound healing biomaterials. It also used as chelating agent due to its ability to bind with cholesterol, fats, proteins and metal ions.",book:{id:"4648",slug:"concepts-compounds-and-the-alternatives-of-antibacterials",title:"Concepts, Compounds and the Alternatives of Antibacterials",fullTitle:"Concepts, Compounds and the Alternatives of Antibacterials"},signatures:"H. M. Ibrahim and E.M.R. El- Zairy",authors:[{id:"90645",title:"Dr.",name:"Hassan",middleName:null,surname:"Ibrahim",slug:"hassan-ibrahim",fullName:"Hassan Ibrahim"},{id:"175694",title:"Dr.",name:"Enas",middleName:null,surname:"El- Zairy",slug:"enas-el-zairy",fullName:"Enas El- Zairy"}]},{id:"70919",doi:"10.5772/intechopen.90891",title:"Antimicrobial Effect of Titanium Dioxide Nanoparticles",slug:"antimicrobial-effect-of-titanium-dioxide-nanoparticles",totalDownloads:1817,totalCrossrefCites:21,totalDimensionsCites:47,abstract:"The widespread use of antibiotics has led to the emergence of multidrug-resistant bacterial strains, and therefore a current concern for food safety and human health. The interest for new antimicrobial substances has been focused toward metal oxide nanoparticles. Specifically, titanium dioxide (TiO2) has been considered as an attractive antimicrobial compound due to its photocatalytic nature and because it is a chemically stable, non-toxic, inexpensive, and Generally Recognized as Safe (GRAS) substance. Several studies have revealed this metal oxide demonstrates excellent antifungal and antibacterial properties against a broad range of both Gram-positive and Gram-negative bacteria. These properties were significantly improved by titanium dioxide nanoparticles (TiO2 NPs) synthesis. In this chapter, latest developments on routes of synthesis of TiO2 NPs and antimicrobial activity of these nanostructures are presented. Furthermore, TiO2 NPs favor the inactivation of microorganisms due to their strong oxidizing power by free radical generation, such as hydroxyl and superoxide anion radicals, showing reductions growth against several microorganisms, such as Escherichia coli and Staphylococcus aureus. Understanding the main mechanisms of antimicrobial action of these nanoparticles was the second main purpose of this chapter.",book:{id:"9521",slug:"antimicrobial-resistance-a-one-health-perspective",title:"Antimicrobial Resistance",fullTitle:"Antimicrobial Resistance - A One Health Perspective"},signatures:"Carol López de Dicastillo, Matias Guerrero Correa, Fernanda B. Martínez, Camilo Streitt and Maria José Galotto",authors:[{id:"244902",title:"Dr.",name:"Carol",middleName:null,surname:"Lopez De Dicastillo",slug:"carol-lopez-de-dicastillo",fullName:"Carol Lopez De Dicastillo"},{id:"315494",title:"Mr.",name:"Matias",middleName:null,surname:"Guerrero Correa",slug:"matias-guerrero-correa",fullName:"Matias Guerrero Correa"},{id:"315495",title:"Ms.",name:"Fernanda",middleName:null,surname:"B. Martínez",slug:"fernanda-b.-martinez",fullName:"Fernanda B. Martínez"},{id:"315496",title:"Mr.",name:"Camilo",middleName:null,surname:"Zuñiga",slug:"camilo-zuniga",fullName:"Camilo Zuñiga"},{id:"315497",title:"Dr.",name:"Maria José",middleName:null,surname:"Galotto",slug:"maria-jose-galotto",fullName:"Maria José Galotto"}]},{id:"65613",doi:"10.5772/intechopen.84411",title:"The Methods for Detection of Biofilm and Screening Antibiofilm Activity of Agents",slug:"the-methods-for-detection-of-biofilm-and-screening-antibiofilm-activity-of-agents",totalDownloads:9283,totalCrossrefCites:15,totalDimensionsCites:26,abstract:"Biofilm producer microorganisms cause nosocomial and recurrent infections. Biofilm that is a sticky exopolysaccharide is the main virulence factor causing biofilm-related infections. Biofilm formation begins with attachment of bacteria to biotic surface such as host cell or abiotic surface such as prosthetic devices. After attachment, aggregation of bacteria is started by cell-cell adhesion. Aggregation continues with the maturation of biofilm. Dispersion is started by certain conditions such as phenol-soluble modulins (PSMs). By this way, sessile bacteria turn back into planktonic form. Bacteria embedded in biofilm (sessile form) are more resistant to antimicrobials than planktonic bacteria. So it is hard to treat biofilm-embedded bacteria than planktonic forms. For this reason, it is important to detect biofilm. There are a few biofilm detection and biofilm production methods on prosthetics, methods for screening antibacterial effect of agents against biofilm-embedded microorganism and antibiofilm effect of agents against biofilm production and mature biofilm. The aim of this chapter is to overview direct and indirect methods such as microscopy, fluorescent in situ hybridization, and Congo red agar, tube method, microtiter plate assay, checkerboard assay, plate counting, polymerase chain reaction, mass spectrometry, MALDI-TOF, and biological assays used by antibiofilm researches.",book:{id:"8427",slug:"antimicrobials-antibiotic-resistance-antibiofilm-strategies-and-activity-methods",title:"Antimicrobials, Antibiotic Resistance, Antibiofilm Strategies and Activity Methods",fullTitle:"Antimicrobials, Antibiotic Resistance, Antibiofilm Strategies and Activity Methods"},signatures:"Sahra Kırmusaoğlu",authors:[{id:"179460",title:"Associate Prof.",name:"Sahra",middleName:null,surname:"Kırmusaoğlu",slug:"sahra-kirmusaoglu",fullName:"Sahra Kırmusaoğlu"}]},{id:"63397",doi:"10.5772/intechopen.80624",title:"Antibiotic Resistance in Lactic Acid Bacteria",slug:"antibiotic-resistance-in-lactic-acid-bacteria",totalDownloads:2486,totalCrossrefCites:12,totalDimensionsCites:21,abstract:"Most starter cultures belong to the lactic acid bacteria group (LAB) and recognized as safe by the US Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA). However, LAB may act as intrinsic or extrinsic reservoirs for antibiotic resistance (AR) genes. This fact may not constitute a safety concern itself, as the resistance gene transfer is vertical. Nevertheless, external genetic elements may induce changes that favor the horizontal transfer transmission of resistance from pathogens as well as from the human intestinal microbiota, which represents a severe safety issue. Some genus of AR LAB includes Enterococcus, Lactobacillus, Lactococcus, Leuconostoc, Pediococcus, and Streptococcus isolated from fermented meat and milk products. Currently, the WHO recommends that LAB used in the food industry should be free of resistance. Therefore, the objective of this chapter is to present an overview of the LAB antibiotic resistance and some methods to determine the same.",book:{id:"6978",slug:"antimicrobial-resistance-a-global-threat",title:"Antimicrobial Resistance",fullTitle:"Antimicrobial Resistance - A Global Threat"},signatures:"Yenizey M. 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After attachment, aggregation of bacteria is started by cell-cell adhesion. Aggregation continues with the maturation of biofilm. Dispersion is started by certain conditions such as phenol-soluble modulins (PSMs). By this way, sessile bacteria turn back into planktonic form. Bacteria embedded in biofilm (sessile form) are more resistant to antimicrobials than planktonic bacteria. So it is hard to treat biofilm-embedded bacteria than planktonic forms. For this reason, it is important to detect biofilm. There are a few biofilm detection and biofilm production methods on prosthetics, methods for screening antibacterial effect of agents against biofilm-embedded microorganism and antibiofilm effect of agents against biofilm production and mature biofilm. The aim of this chapter is to overview direct and indirect methods such as microscopy, fluorescent in situ hybridization, and Congo red agar, tube method, microtiter plate assay, checkerboard assay, plate counting, polymerase chain reaction, mass spectrometry, MALDI-TOF, and biological assays used by antibiofilm researches.",book:{id:"8427",slug:"antimicrobials-antibiotic-resistance-antibiofilm-strategies-and-activity-methods",title:"Antimicrobials, Antibiotic Resistance, Antibiofilm Strategies and Activity Methods",fullTitle:"Antimicrobials, Antibiotic Resistance, Antibiofilm Strategies and Activity Methods"},signatures:"Sahra Kırmusaoğlu",authors:[{id:"179460",title:"Associate Prof.",name:"Sahra",middleName:null,surname:"Kırmusaoğlu",slug:"sahra-kirmusaoglu",fullName:"Sahra Kırmusaoğlu"}]},{id:"62553",title:"Antibiotic Use in Poultry Production and Its Effects on Bacterial Resistance",slug:"antibiotic-use-in-poultry-production-and-its-effects-on-bacterial-resistance",totalDownloads:7327,totalCrossrefCites:43,totalDimensionsCites:92,abstract:"A surge in the development and spread of antibiotic resistance has become a major cause for concern. Over the past few decades, no major new types of antibiotics have been produced and almost all known antibiotics are increasingly losing their activity against pathogenic microorganisms. The levels of multi-drug resistant bacteria have also increased. It is known that worldwide, more than 60% of all antibiotics that are produced find their use in animal production for both therapeutic and non-therapeutic purposes. The use of antimicrobial agents in animal husbandry has been linked to the development and spread of resistant bacteria. Poultry products are among the highest consumed products worldwide but a lot of essential antibiotics are employed during poultry production in several countries; threatening the safety of such products (through antimicrobial residues) and the increased possibility of development and spread of microbial resistance in poultry settings. 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Kocazeybek",authors:[{id:"179460",title:"Associate Prof.",name:"Sahra",middleName:null,surname:"Kırmusaoğlu",slug:"sahra-kirmusaoglu",fullName:"Sahra Kırmusaoğlu"},{id:"248288",title:"Prof.",name:"Bekir",middleName:null,surname:"Kocazeybek",slug:"bekir-kocazeybek",fullName:"Bekir Kocazeybek"},{id:"406463",title:"Dr.",name:"Nesrin",middleName:null,surname:"Gareayaghi",slug:"nesrin-gareayaghi",fullName:"Nesrin Gareayaghi"}]},{id:"63397",title:"Antibiotic Resistance in Lactic Acid Bacteria",slug:"antibiotic-resistance-in-lactic-acid-bacteria",totalDownloads:2486,totalCrossrefCites:12,totalDimensionsCites:21,abstract:"Most starter cultures belong to the lactic acid bacteria group (LAB) and recognized as safe by the US Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA). However, LAB may act as intrinsic or extrinsic reservoirs for antibiotic resistance (AR) genes. This fact may not constitute a safety concern itself, as the resistance gene transfer is vertical. Nevertheless, external genetic elements may induce changes that favor the horizontal transfer transmission of resistance from pathogens as well as from the human intestinal microbiota, which represents a severe safety issue. Some genus of AR LAB includes Enterococcus, Lactobacillus, Lactococcus, Leuconostoc, Pediococcus, and Streptococcus isolated from fermented meat and milk products. Currently, the WHO recommends that LAB used in the food industry should be free of resistance. Therefore, the objective of this chapter is to present an overview of the LAB antibiotic resistance and some methods to determine the same.",book:{id:"6978",slug:"antimicrobial-resistance-a-global-threat",title:"Antimicrobial Resistance",fullTitle:"Antimicrobial Resistance - A Global Threat"},signatures:"Yenizey M. Álvarez-Cisneros and Edith Ponce-Alquicira",authors:[{id:"256345",title:"Dr.",name:"Yenizey Merit",middleName:null,surname:"Alvarez Cisneros",slug:"yenizey-merit-alvarez-cisneros",fullName:"Yenizey Merit Alvarez Cisneros"},{id:"256347",title:"Dr.",name:"Edith",middleName:null,surname:"Ponce-Alquicira",slug:"edith-ponce-alquicira",fullName:"Edith Ponce-Alquicira"}]},{id:"49246",title:"Chitosan as a Biomaterial — Structure, Properties, and Electrospun Nanofibers",slug:"chitosan-as-a-biomaterial-structure-properties-and-electrospun-nanofibers",totalDownloads:4726,totalCrossrefCites:27,totalDimensionsCites:63,abstract:"Chitosan is a polysaccharide derived from chitin; chitin is the second most abundant polysaccharide in the world, after cellulose. Chitosan is biocompatible, biodegradable and non-toxic, so that it can be usedin medicalapplications such as antimicrobial and wound healing biomaterials. It also used as chelating agent due to its ability to bind with cholesterol, fats, proteins and metal ions.",book:{id:"4648",slug:"concepts-compounds-and-the-alternatives-of-antibacterials",title:"Concepts, Compounds and the Alternatives of Antibacterials",fullTitle:"Concepts, Compounds and the Alternatives of Antibacterials"},signatures:"H. M. Ibrahim and E.M.R. El- Zairy",authors:[{id:"90645",title:"Dr.",name:"Hassan",middleName:null,surname:"Ibrahim",slug:"hassan-ibrahim",fullName:"Hassan Ibrahim"},{id:"175694",title:"Dr.",name:"Enas",middleName:null,surname:"El- Zairy",slug:"enas-el-zairy",fullName:"Enas El- Zairy"}]}],onlineFirstChaptersFilter:{topicId:"897",limit:6,offset:0},onlineFirstChaptersCollection:[{id:"81704",title:"Quorum Sensing Inhibition Based Drugs to Conquer Antimicrobial Resistance",slug:"quorum-sensing-inhibition-based-drugs-to-conquer-antimicrobial-resistance",totalDownloads:22,totalDimensionsCites:0,doi:"10.5772/intechopen.104125",abstract:"Quorum sensing is the cell to cell communication mechanism in microorganism through signalling molecules. Regulation of virulence factor, sporulation, proteolytic enzymes production, biofilm formation, auto-inducers, cell population density are key physiological process mediated through quorum-sensing (QS) signalling. Elevation of innate immune system and antibiotic tolerance of pathogens is highly increased with perspective of quorum-sensing (QS) activity. Development of novel drugs is highly attractive scenario against cell-cell communication of microbes. Design of synthetic drugs and natural compounds against QS signal molecules is vital combat system to attenuate microbial pathogenicity. Quorum sensing inhibitors (QSIs), quorum quenchers (QQs), efflux pump inhibitors (EPIs) act against multi-drug resistance strains (MDR) and other pathogenic microbes through regulation of auto-inducers and signal molecule with perceptive to growth arrest both in-vitro and in-vivo. QQs, QSIs and EPIs compounds has been validated with various animal models for high selection pressure on therapeutics arsenal against microbe’s growth inhibition. Promising QSI are phytochemicals and secondary metabolites includes polyacetylenes, alkaloids, polyphenols, terpenoids, quinones.",book:{id:"11373",title:"The Global Antimicrobial Resistance Epidemic - Innovative Approaches and Cutting-Edge Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11373.jpg"},signatures:"Kothandapani Sundar, Ramachandira Prabu and Gopal Jayalakshmi"},{id:"82372",title:"Unlocking the Potential of Ghost Probiotics in Combating Antimicrobial Resistance",slug:"unlocking-the-potential-of-ghost-probiotics-in-combating-antimicrobial-resistance",totalDownloads:20,totalDimensionsCites:0,doi:"10.5772/intechopen.104126",abstract:"Antimicrobial resistance is a global concern that requires immediate attention. Major causes of development of antimicrobial resistance in microbial cells are overuse of antimicrobials along the food chain especially in livestock, in preventing infections as well as misuse of antimicrobials by patients. Probiotics could be a viable alternative to antibiotics in the fight against antimicrobial resistance. Probiotic strains can act as a complement to antimicrobial therapy, improving antimicrobial function and enhancing immunity. However, there are safety concerns regarding the extensive use of live microbial cells especially in immunocompromised individuals; these include microbial translocation, inhibition of other beneficial microorganisms and development of antimicrobial resistance, among other concerns. Inevitably, ghost probiotics have become the favored alternative as they eliminate the safety and shelf-life problems associated with use of probiotics. Ghost probiotics are non-viable microbial cells (intact or broken) or metabolic products from microorganisms, which when administered in adequate amounts have biologic activity in the host and confer health benefits. Ghost probiotics exert biological effects similar to probiotics. However, the major drawback of using ghost probiotics is that the mechanism of action of these is currently unknown, hence more research is required and regulatory instruments are needed to assure the safety of consumers.",book:{id:"11373",title:"The Global Antimicrobial Resistance Epidemic - Innovative Approaches and Cutting-Edge Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11373.jpg"},signatures:"Abigarl Ndudzo, Sakhile Ndlovu, Nesisa Nyathi and Angela Sibanda Makuvise"},{id:"82178",title:"Managing Antimicrobial Resistance beyond the Hospital Antimicrobial Stewardship: The Role of One Health",slug:"managing-antimicrobial-resistance-beyond-the-hospital-antimicrobial-stewardship-the-role-of-one-heal",totalDownloads:16,totalDimensionsCites:0,doi:"10.5772/intechopen.104170",abstract:"Infections caused by micro-organisms affect the health of people and animals, causing morbidity and mortality, with Asia and Africa as the epicenters. Some of the infectious diseases are emerging and re-emerging in nature. Examples include viral hepatitis, Lassa fever, Ebola, yellow fever, tuberculosis, covid-19, measles, and malaria, among others. Antimicrobials have been playing an important role in the treatment of infections by these microbes. However, there has been a development of resistance to these antimicrobials as a result of many drivers. This write-up used secondary data to explore the management of antimicrobial resistance (AMR) beyond the hospital antimicrobial resistance steward using the one health concept. The findings showed AMR to be a transboundary, multifaceted ecosystem problem affecting both the developed and developing countries. It is also one of the top ten global public health threats facing mankind. Globally, AMR will cost over US$100 trillion in output loss by 2050, about 700,000 deaths a year, and 4,150,000 deaths in Africa by 2050. About 2.4 million people could die in high-income countries between 2015 and 2050 without a sustained effort to contain AMR. The drivers of AMR are beyond the hospital and hospital AMR stewardship. Therefore, the need for one health concept to manage it.",book:{id:"11373",title:"The Global Antimicrobial Resistance Epidemic - Innovative Approaches and Cutting-Edge Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11373.jpg"},signatures:"Istifanus Anekoson Joshua, Mathew Bobai and Clement Sokfa Woje"},{id:"81918",title:"Machine Learning for Antimicrobial Resistance Research and Drug Development",slug:"machine-learning-for-antimicrobial-resistance-research-and-drug-development",totalDownloads:53,totalDimensionsCites:0,doi:"10.5772/intechopen.104841",abstract:"Machine learning is a subfield of artificial intelligence which combines sophisticated algorithms and data to develop predictive models with minimal human interference. This chapter focuses on research that trains machine learning models to study antimicrobial resistance and to discover antimicrobial drugs. An emphasis is placed on applying machine learning models to detect drug resistance among bacterial and fungal pathogens. The role of machine learning in antibacterial and antifungal drug discovery and design is explored. Finally, the challenges and prospects of applying machine learning to advance basic research on and treatment of antimicrobial resistance are discussed. Overall, machine learning promises to advance antimicrobial resistance research and to facilitate the development of antibacterial and antifungal drugs.",book:{id:"11373",title:"The Global Antimicrobial Resistance Epidemic - Innovative Approaches and Cutting-Edge Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11373.jpg"},signatures:"Shamanth A. Shankarnarayan, Joshua D. Guthrie and Daniel A. Charlebois"},{id:"81891",title:"Alternatives to Antibiotics in Semen Extenders Used in Artificial Insemination",slug:"alternatives-to-antibiotics-in-semen-extenders-used-in-artificial-insemination",totalDownloads:29,totalDimensionsCites:0,doi:"10.5772/intechopen.104226",abstract:"Antimicrobial resistance is a serious global threat requiring a widespread response. Both veterinarians and medical doctors should restrict antibiotic usage to therapeutic use only, after determining the sensitivity of the causal organism. However, the addition of antibiotics to semen extenders for animal artificial insemination represents a hidden, non-therapeutic use of antimicrobial substances. Artificial insemination for livestock breeding is a huge global enterprise with hundreds of million sperm doses prepared annually. However, reporting of antimicrobial resistance in semen is increasing. This review discusses the consequences of bacteria in semen samples, as well as the effect of antimicrobial substances in semen extenders on bacteria in the environment and even on personnel. Alternatives to antibiotics have been reported in the scientific literature and are reviewed here. The most promising of these, removal of the majority of bacteria by colloid centrifugation, is considered in detail, especially results from an artificial insemination study in pigs. In conclusion, colloid centrifugation is a practical method of physically removing bacteria from semen, which does not induce antibiotic resistance. Sperm quality in stored semen samples may be improved at the same time.",book:{id:"11373",title:"The Global Antimicrobial Resistance Epidemic - Innovative Approaches and Cutting-Edge Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11373.jpg"},signatures:"Jane M. Morrell, Pongpreecha Malaluang, Aleksandar Cojkic and Ingrid Hansson"},{id:"81699",title:"Efflux Pumps among Urinary E. coli and K. pneumoniae Local Isolates in Hilla City, Iraq",slug:"efflux-pumps-among-urinary-e-coli-and-k-pneumoniae-local-isolates-in-hilla-city-iraq",totalDownloads:13,totalDimensionsCites:0,doi:"10.5772/intechopen.104408",abstract:"Urinary tract infections (UTI) are the most common bacterial infections affecting humans. Escherichia coli and Klebsiella pneumoniae were common enterobacteria engaged with community-acquired UTIs. Efflux pumps were vital resistance mechanisms for antibiotics, especially among enterobacteria. Overexpression of an efflux system, which results in a decrease in antibiotic accumulation, is an effective mechanism for drug resistance. The ATP-binding cassette (ABC) transporters, small multidrug resistance (SMR), and multidrug and toxic compound extrusion (MATE) families, the major facilitator superfamily (MFS), and the resistance-nodulation- cell division (RND) family are the five superfamilies of efflux systems linked to drug resistance. This chapter highlights the results of studying the prevalence of efflux pump genes among local isolates of E. coli and K. pneumoniae in Hilla City, Iraq. class RND AcrAB-TolC, AcrAD-TolC, and AcrFE-TolC genes detected by conventional PCR of E. coli and K. pneumoniae respectively. The result revealed approximately all studied efflux transporter were found in both E. coli and K. pneumoniae in different percentages. Biofilm formation were observed in 50(100%) of K. pneumoniae and 49(98%) of E. coli isolates were biofilm former and follow: 30(60%), 20(40%) were weak, 12(24%), 22(44%) were moderate and 7(14%) and 8(16%) were Strong biofilm former for E. coli and K. pneumoniae, respectively.",book:{id:"11373",title:"The Global Antimicrobial Resistance Epidemic - Innovative Approaches and Cutting-Edge Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11373.jpg"},signatures:"Hussein Al-Dahmoshi, Sahar A. Ali and Noor Al-Khafaji"}],onlineFirstChaptersTotal:13},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:0,limit:8,total:null},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:90,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:108,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:33,numberOfPublishedChapters:330,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:14,numberOfPublishedChapters:145,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:9,numberOfPublishedChapters:141,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:124,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:112,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:22,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:11,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:"2753-6580",doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"14",title:"Artificial Intelligence",doi:"10.5772/intechopen.79920",issn:"2633-1403",scope:"Artificial Intelligence (AI) is a rapidly developing multidisciplinary research area that aims to solve increasingly complex problems. In today's highly integrated world, AI promises to become a robust and powerful means for obtaining solutions to previously unsolvable problems. This Series is intended for researchers and students alike interested in this fascinating field and its many applications.",coverUrl:"https://cdn.intechopen.com/series/covers/14.jpg",latestPublicationDate:"July 5th, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:9,editor:{id:"218714",title:"Prof.",name:"Andries",middleName:null,surname:"Engelbrecht",slug:"andries-engelbrecht",fullName:"Andries Engelbrecht",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRNR8QAO/Profile_Picture_1622640468300",biography:"Andries Engelbrecht received the Masters and PhD degrees in Computer Science from the University of Stellenbosch, South Africa, in 1994 and 1999 respectively. He is currently appointed as the Voigt Chair in Data Science in the Department of Industrial Engineering, with a joint appointment as Professor in the Computer Science Division, Stellenbosch University. Prior to his appointment at Stellenbosch University, he has been at the University of Pretoria, Department of Computer Science (1998-2018), where he was appointed as South Africa Research Chair in Artifical Intelligence (2007-2018), the head of the Department of Computer Science (2008-2017), and Director of the Institute for Big Data and Data Science (2017-2018). In addition to a number of research articles, he has written two books, Computational Intelligence: An Introduction and Fundamentals of Computational Swarm Intelligence.",institutionString:null,institution:{name:"Stellenbosch University",institutionURL:null,country:{name:"South Africa"}}},editorTwo:null,editorThree:null},subseries:{paginationCount:7,paginationItems:[{id:"22",title:"Applied Intelligence",coverUrl:"https://cdn.intechopen.com/series_topics/covers/22.jpg",editor:{id:"27170",title:"Prof.",name:"Carlos",middleName:"M.",surname:"Travieso-Gonzalez",slug:"carlos-travieso-gonzalez",fullName:"Carlos Travieso-Gonzalez",profilePictureURL:"https://mts.intechopen.com/storage/users/27170/images/system/27170.jpeg",biography:"Carlos M. Travieso-González received his MSc degree in Telecommunication Engineering at Polytechnic University of Catalonia (UPC), Spain in 1997, and his Ph.D. degree in 2002 at the University of Las Palmas de Gran Canaria (ULPGC-Spain). He is a full professor of signal processing and pattern recognition and is head of the Signals and Communications Department at ULPGC, teaching from 2001 on subjects on signal processing and learning theory. His research lines are biometrics, biomedical signals and images, data mining, classification system, signal and image processing, machine learning, and environmental intelligence. He has researched in 52 international and Spanish research projects, some of them as head researcher. He is co-author of 4 books, co-editor of 27 proceedings books, guest editor for 8 JCR-ISI international journals, and up to 24 book chapters. He has over 450 papers published in international journals and conferences (81 of them indexed on JCR – ISI - Web of Science). He has published seven patents in the Spanish Patent and Trademark Office. He has been a supervisor on 8 Ph.D. theses (11 more are under supervision), and 130 master theses. He is the founder of The IEEE IWOBI conference series and the president of its Steering Committee, as well as the founder of both the InnoEducaTIC and APPIS conference series. He is an evaluator of project proposals for the European Union (H2020), Medical Research Council (MRC, UK), Spanish Government (ANECA, Spain), Research National Agency (ANR, France), DAAD (Germany), Argentinian Government, and the Colombian Institutions. He has been a reviewer in different indexed international journals (<70) and conferences (<250) since 2001. He has been a member of the IASTED Technical Committee on Image Processing from 2007 and a member of the IASTED Technical Committee on Artificial Intelligence and Expert Systems from 2011. \n\nHe has held the general chair position for the following: ACM-APPIS (2020, 2021), IEEE-IWOBI (2019, 2020 and 2020), A PPIS (2018, 2019), IEEE-IWOBI (2014, 2015, 2017, 2018), InnoEducaTIC (2014, 2017), IEEE-INES (2013), NoLISP (2011), JRBP (2012), and IEEE-ICCST (2005)\n\nHe is an associate editor of the Computational Intelligence and Neuroscience Journal (Hindawi – Q2 JCR-ISI). He was vice dean from 2004 to 2010 in the Higher Technical School of Telecommunication Engineers at ULPGC and the vice dean of Graduate and Postgraduate Studies from March 2013 to November 2017. He won the “Catedra Telefonica” Awards in Modality of Knowledge Transfer, 2017, 2018, and 2019 editions, and awards in Modality of COVID Research in 2020.\n\nPublic References:\nResearcher ID http://www.researcherid.com/rid/N-5967-2014\nORCID https://orcid.org/0000-0002-4621-2768 \nScopus Author ID https://www.scopus.com/authid/detail.uri?authorId=6602376272\nScholar Google https://scholar.google.es/citations?user=G1ks9nIAAAAJ&hl=en \nResearchGate https://www.researchgate.net/profile/Carlos_Travieso",institutionString:null,institution:{name:"University of Las Palmas de Gran Canaria",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"13633",title:"Prof.",name:"Abdelhamid",middleName:null,surname:"Mellouk",slug:"abdelhamid-mellouk",fullName:"Abdelhamid Mellouk",profilePictureURL:"https://mts.intechopen.com/storage/users/13633/images/1567_n.jpg",institutionString:null,institution:{name:"Paris 12 Val de Marne University",institutionURL:null,country:{name:"France"}}},{id:"109268",title:"Dr.",name:"Ali",middleName:null,surname:"Al-Ataby",slug:"ali-al-ataby",fullName:"Ali Al-Ataby",profilePictureURL:"https://mts.intechopen.com/storage/users/109268/images/7410_n.jpg",institutionString:null,institution:{name:"University of Liverpool",institutionURL:null,country:{name:"United Kingdom"}}},{id:"3807",title:"Dr.",name:"Carmelo",middleName:"Jose Albanez",surname:"Bastos-Filho",slug:"carmelo-bastos-filho",fullName:"Carmelo Bastos-Filho",profilePictureURL:"https://mts.intechopen.com/storage/users/3807/images/624_n.jpg",institutionString:null,institution:{name:"Universidade de Pernambuco",institutionURL:null,country:{name:"Brazil"}}},{id:"38850",title:"Dr.",name:"Efren",middleName:null,surname:"Gorrostieta Hurtado",slug:"efren-gorrostieta-hurtado",fullName:"Efren Gorrostieta Hurtado",profilePictureURL:"https://mts.intechopen.com/storage/users/38850/images/system/38850.jpg",institutionString:null,institution:{name:"Autonomous University of Queretaro",institutionURL:null,country:{name:"Mexico"}}},{id:"239041",title:"Dr.",name:"Yang",middleName:null,surname:"Yi",slug:"yang-yi",fullName:"Yang Yi",profilePictureURL:"https://mts.intechopen.com/storage/users/239041/images/system/239041.jpeg",institutionString:null,institution:{name:"Virginia Tech",institutionURL:null,country:{name:"United States of America"}}}]},{id:"23",title:"Computational Neuroscience",coverUrl:"https://cdn.intechopen.com/series_topics/covers/23.jpg",editor:{id:"14004",title:"Dr.",name:"Magnus",middleName:null,surname:"Johnsson",slug:"magnus-johnsson",fullName:"Magnus Johnsson",profilePictureURL:"https://mts.intechopen.com/storage/users/14004/images/system/14004.png",biography:"Dr Magnus Johnsson is a cross-disciplinary scientist, lecturer, scientific editor and AI/machine learning consultant from Sweden. \n\nHe is currently at Malmö University in Sweden, but also held positions at Lund University in Sweden and at Moscow Engineering Physics Institute. \nHe holds editorial positions at several international scientific journals and has served as a scientific editor for books and special journal issues. \nHis research interests are wide and include, but are not limited to, autonomous systems, computer modeling, artificial neural networks, artificial intelligence, cognitive neuroscience, cognitive robotics, cognitive architectures, cognitive aids and the philosophy of mind. \n\nDr. Johnsson has experience from working in the industry and he has a keen interest in the application of neural networks and artificial intelligence to fields like industry, finance, and medicine. \n\nWeb page: www.magnusjohnsson.se",institutionString:null,institution:{name:"Malmö University",institutionURL:null,country:{name:"Sweden"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"13818",title:"Dr.",name:"Asim",middleName:null,surname:"Bhatti",slug:"asim-bhatti",fullName:"Asim Bhatti",profilePictureURL:"https://mts.intechopen.com/storage/users/13818/images/system/13818.jpg",institutionString:null,institution:{name:"Deakin University",institutionURL:null,country:{name:"Australia"}}},{id:"151889",title:"Dr.",name:"Joao Luis Garcia",middleName:null,surname:"Rosa",slug:"joao-luis-garcia-rosa",fullName:"Joao Luis Garcia Rosa",profilePictureURL:"https://mts.intechopen.com/storage/users/151889/images/4861_n.jpg",institutionString:null,institution:{name:"University of Sao Paulo",institutionURL:null,country:{name:"Brazil"}}},{id:"103779",title:"Prof.",name:"Yalcin",middleName:null,surname:"Isler",slug:"yalcin-isler",fullName:"Yalcin Isler",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRyQ8QAK/Profile_Picture_1628834958734",institutionString:null,institution:{name:"Izmir Kâtip Çelebi University",institutionURL:null,country:{name:"Turkey"}}}]},{id:"24",title:"Computer Vision",coverUrl:"https://cdn.intechopen.com/series_topics/covers/24.jpg",editor:{id:"294154",title:"Prof.",name:"George",middleName:null,surname:"Papakostas",slug:"george-papakostas",fullName:"George Papakostas",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002hYaGbQAK/Profile_Picture_1624519712088",biography:"George A. Papakostas has received a diploma in Electrical and Computer Engineering in 1999 and the M.Sc. and Ph.D. degrees in Electrical and Computer Engineering in 2002 and 2007, respectively, from the Democritus University of Thrace (DUTH), Greece. Dr. Papakostas serves as a Tenured Full Professor at the Department of Computer Science, International Hellenic University, Greece. Dr. Papakostas has 10 years of experience in large-scale systems design as a senior software engineer and technical manager, and 20 years of research experience in the field of Artificial Intelligence. Currently, he is the Head of the “Visual Computing” division of HUman-MAchines INteraction Laboratory (HUMAIN-Lab) and the Director of the MPhil program “Advanced Technologies in Informatics and Computers” hosted by the Department of Computer Science, International Hellenic University. He has (co)authored more than 150 publications in indexed journals, international conferences and book chapters, 1 book (in Greek), 3 edited books, and 5 journal special issues. His publications have more than 2100 citations with h-index 27 (GoogleScholar). His research interests include computer/machine vision, machine learning, pattern recognition, computational intelligence. \nDr. Papakostas served as a reviewer in numerous journals, as a program\ncommittee member in international conferences and he is a member of the IAENG, MIR Labs, EUCogIII, INSTICC and the Technical Chamber of Greece (TEE).",institutionString:null,institution:{name:"International Hellenic University",institutionURL:null,country:{name:"Greece"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"1177",title:"Prof.",name:"António",middleName:"J. R.",surname:"José Ribeiro Neves",slug:"antonio-jose-ribeiro-neves",fullName:"António José Ribeiro Neves",profilePictureURL:"https://mts.intechopen.com/storage/users/1177/images/system/1177.jpg",institutionString:null,institution:{name:"University of Aveiro",institutionURL:null,country:{name:"Portugal"}}},{id:"220565",title:"Dr.",name:"Jucheng",middleName:null,surname:"Yang",slug:"jucheng-yang",fullName:"Jucheng Yang",profilePictureURL:"https://mts.intechopen.com/storage/users/220565/images/5988_n.jpg",institutionString:null,institution:{name:"Tianjin University of Technology",institutionURL:null,country:{name:"China"}}},{id:"29299",title:"Prof.",name:"Serestina",middleName:null,surname:"Viriri",slug:"serestina-viriri",fullName:"Serestina Viriri",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYOalQAG/Profile_Picture_1620817405517",institutionString:null,institution:{name:"University of KwaZulu-Natal",institutionURL:null,country:{name:"South Africa"}}},{id:"315933",title:"Dr.",name:"Yalın",middleName:null,surname:"Baştanlar",slug:"yalin-bastanlar",fullName:"Yalın Baştanlar",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y00002qpr7hQAA/Profile_Picture_1621430127547",institutionString:null,institution:{name:"Izmir Institute of Technology",institutionURL:null,country:{name:"Turkey"}}}]},{id:"25",title:"Evolutionary Computation",coverUrl:"https://cdn.intechopen.com/series_topics/covers/25.jpg",editor:{id:"136112",title:"Dr.",name:"Sebastian",middleName:null,surname:"Ventura Soto",slug:"sebastian-ventura-soto",fullName:"Sebastian Ventura Soto",profilePictureURL:"https://mts.intechopen.com/storage/users/136112/images/system/136112.png",biography:"Sebastian Ventura is a Spanish researcher, a full professor with the Department of Computer Science and Numerical Analysis, University of Córdoba. Dr Ventura also holds the positions of Affiliated Professor at Virginia Commonwealth University (Richmond, USA) and Distinguished Adjunct Professor at King Abdulaziz University (Jeddah, Saudi Arabia). Additionally, he is deputy director of the Andalusian Research Institute in Data Science and Computational Intelligence (DaSCI) and heads the Knowledge Discovery and Intelligent Systems Research Laboratory. He has published more than ten books and over 300 articles in journals and scientific conferences. Currently, his work has received over 18,000 citations according to Google Scholar, including more than 2200 citations in 2020. In the last five years, he has published more than 60 papers in international journals indexed in the JCR (around 70% of them belonging to first quartile journals) and he has edited some Springer books “Supervised Descriptive Pattern Mining” (2018), “Multiple Instance Learning - Foundations and Algorithms” (2016), and “Pattern Mining with Evolutionary Algorithms” (2016). He has also been involved in more than 20 research projects supported by the Spanish and Andalusian governments and the European Union. He currently belongs to the editorial board of PeerJ Computer Science, Information Fusion and Engineering Applications of Artificial Intelligence journals, being also associate editor of Applied Computational Intelligence and Soft Computing and IEEE Transactions on Cybernetics. Finally, he is editor-in-chief of Progress in Artificial Intelligence. He is a Senior Member of the IEEE Computer, the IEEE Computational Intelligence, and the IEEE Systems, Man, and Cybernetics Societies, and the Association of Computing Machinery (ACM). Finally, his main research interests include data science, computational intelligence, and their applications.",institutionString:null,institution:{name:"University of Córdoba",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null,editorialBoard:[{id:"111683",title:"Prof.",name:"Elmer P.",middleName:"P.",surname:"Dadios",slug:"elmer-p.-dadios",fullName:"Elmer P. 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