Mario Alfonso Murillo-Tovar

By Hugo Saldarriaga-Noreña, Rebecca López-Márquez, Mario Alfonso Murillo-Tovar, Mónica Ivonne Arias-Montoya, Jorge Antonio Guerrero-Álvarez and Josefina Vergara-Sánchez

Polycyclic aromatic hydrocarbons (PAHs) are formed in natural processes during combustion of biomass (e.g., forest fires) and by anthropogenic activities at high temperatures. In according with the suggestion the major sources of PAHs in the environment. The main sources of PAHs come basically from heat and power generation (e.g., coal, gas, wood, and oil), industrial processes (e.g., coke production), refuse burning and vehicle emissions. Human exposure to airborne PAHs can result from these processes, as well as from emissions from other sources, such as cooking, smoking, and materials containing PAHs (e.g., petroleum products and fuels). The potential serious health effects resulting from acute and chronic human exposure to PAHs are of concern. For this reason, the identification and quantification of PAHs in airborne particles have been a real challenge, given the multiple impacts that these substances represent for human health. In the last decade, multiple technological developments have been implemented, ranging from sampling systems, extraction and analysis of these compounds with the aim of obtaining more accurate and reliable results. This chapter was prepared to describe and to assess the state of the art about the evolution and application of sampling, extraction and analysis methodologies for the determination of PAHs in airborne particles.

Part of the book: Hydrocarbon Pollution and its Effect on the Environment

By José Gustavo Ronderos-Lara, Hugo Saldarriaga-Noreña, Pedro Guillermo Reyes-Romero, Luis Alberto Chávez-Almazán, Josefina Vergara-Sánchez, Mario Alfonso Murillo-Tovar and César Torres-Segundo

In recent years, the presence of organic pollutants has received great attention due to their effects on public health and biota. Within this set of compounds, a new range of compounds that are characterized by their high persistence and low degradation have been identified, called Emerging Compounds. Emerging pollutants include a wide variety of products for daily use of different structures, domestic and industrial applications, such as: pesticides, industrial and personal hygiene products, hormones, and drugs, most of which are toxic, persistent and bioaccumulative. A characteristic of these types of pollutants is that current wastewater treatment plants are unable to remove them; they are designed to remove organic matter and nutrients in higher concentrations. In Mexico there is little information on the concentration levels of these compounds, due to the lack of public policies aimed at providing resources to institutions and researchers trained to carry out this type of study. On the other hand, the technological infrastructure of the wastewater treatment plants is insufficient for the country’s demand. This situation represents one of the greatest challenges for the authorities responsible for the management of water resources, in the immediate time if it is intended to preserve said resource and therefore take care of the health of the population.

Part of the book: Emerging Contaminants

By Marilú Barrera Olivarez, Mario Alfonso Murillo Tovar, Josefina Vergara Sánchez, María Luisa García Betancourt, Francisco Martín Romero, América María Ramírez Arteaga, Gabriella Eleonora Moeller Chávez and Hugo Albeiro Saldarriaga Noreña

The mobility of heavy metals in aquatic environments, impacted by discharges from mining waste, is one of the major processes causing metal pollution mainly by arsenic (As), cadmium (Cd), lead (Pb), zinc (Zn) and iron (Fe), which could be risky for biota and human health. The heavy metals contained in mining waste constituted by large amounts of sulfides can reach the aquatic compartments by acid mine drainage and runoff and eventually become deposited in sediments and associated with colloidal material, being this one of the main reservoirs and ways of transport. However, the mobility of heavy metal is influenced by their specific chemical properties and undergo several physicochemical phenomena as sorption, oxidation–reduction, hydrolysis and this can be influenced by water flow, the size and composition of geological material. Hence, this work aims to review the processes and mechanism involved in the fate and transport of heavy metals from mining-waste to aquatic compartments and the methods used for identification of the specific chemical species associated with their mobility and ecological risk.

Part of the book: Water Quality