The effect of substitution on the potential energy surfaces of RE13 ☰ PR (E13 = B, Al, Ga, In, Tl; R = F, OH, H, CH3, SiH3, SiMe(SitBu3)2, SiiPrDis2, Tbt, and Ar* is studied using density functional theory (M06-2X/Def2-TZVP, B3PW91/Def2-TZVP and B3LYP/LANL2DZ + dp). The theoretical results demonstrate that all triply bonded RE13 ☰ PR compounds with small substituents are unstable and spontaneously rearrange to other doubly bonded isomers. That is, the smaller groups, such as R 〓 F, OH, H, CH3 and SiH3, neither kinetically nor thermodynamically stabilize the triply bonded RE13 ☰ PR compounds. However, the triply bonded R’E13☰PR´ molecules, possessing bulkier substituents (R´ = SiMe(SitBu3)2, SiiPrDis2, Tbt and Ar*), are found to have a global minimum on the singlet potential energy surface. In particular, the bonding character of the R’E13☰PR´ species is well defined by the valence-electron bonding model (model [II]). That is to say, R’E13☰PR´ molecules that feature groups are regarded as R′-E13P-R′. The theoretical evidence shows that both the electronic and the steric effects of bulkier substituent groups play a prominent role in rendering triply bonded R′E13☰PR′ species synthetically accessible and isolable in a stable form.
Part of the book: Phosphorus
The effect of substitution on the potential energy surfaces of RAl☰SbR (R = F, OH, H, CH3, SiH3, SiMe(SitBu3)2, SiiPrDis2, Tbt, and Ar*) is investigated using density functional theories (M06-2X/Def2-TZVP, B3PW91/Def2-TZVP, and B3LYP/LANL2DZ + dp). The theoretical results demonstrated that all the triply bonded RAl☰SbR compounds with small substituents are unstable and can spontaneously rearrange to other doubly bonded isomers. That is, the smaller groups, such as R = F, OH, H, CH3 and SiH3, neither kinetically nor thermodynamically stabilize the triply bonded RAl☰SbR compounds. However, the triply bonded R’Al☰SbR´ molecules that feature bulkier substituents (R´ = SiMe(SitBu3)2, SiiPrDis2, Tbt, and Ar*) are found to possess the global minimum on the singlet potential energy surface and are both kinetically and thermodynamically stable. In particular, the bonding characters of the R’Al☰SbR´ species agree well with the valence-electron bonding model (model) as well as several theoretical analyses (the natural bond orbital, the natural resonance theory, and the charge decomposition analysis). That is to say, R’Al☰SbR´ molecules that feature groups are regarded as R′─Al Sb─R′. Their theoretical evidence shows that both the electronic and the steric effects of bulkier substituent groups play a decisive role in making triply bonded R′Al☰SbR′ species synthetically accessible and isolable in a stable form.
Part of the book: Basic Concepts Viewed from Frontier in Inorganic Coordination Chemistry