Chapters authored
Pathways Towards High-Stable, Low-Cost and Efficient Perovskite Solar Cells
The power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) have been reached the initial value when they emerged as dye sensitized solar cell (DSSC) in 2012. Immediately, the interests were drawn in this field worldwide. The researchers have improved the efficiency of PSCs up-to 22%, which was originally started from its initial value of 3.8%, just in 7 years. The rendering of long‐term stabilization and effective cost have special importance for PSCs since the instability issue remained idle in spite of those recently increased efficiency values attained by various research groups. In this way, the better improvements of PSC may increase extraordinary exhibitions as compared to alternate solar cells like organic solar cell (OSC) or DSSC devices. This chapter begins with a general discussion on the requirement for an economical clean energy conversion device. In section 2, fundamental properties of PSC are fit together with their device architecture and working mechanism. In section 3 proceeds with a review on fundamental photovoltaic parameters joined by current-voltage hysteresis. Furthermore, the stability and cost issues will be discussed in Sections 4 and 5. In the end of this chapter, we are discussing the challenges and opportunities based on the chapter content.
Part of the book: Emerging Solar Energy Materials
Quest for Lead-Free Perovskite-Based Solar Cells
Today, the perovskite solar cells (PSCs) are showing excellent potentials in terms of simple processing, abundance of materials, and architectural integration, as well as very promising device’s power conversion efficiencies (PCEs), rocketed from 3.8% in 2009 to 23.3% in 2018. However, the toxic lead (Pb) element containing the chemical composition of typically used organic-inorganic halide perovskites hinders the practical applications of PSCs. This chapter starts with a general discussion on the perovskite crystal structure along with the serious efforts focused on Pb replacement in these devices. Section 2 will elaborate the fundamental features of tin (Sn)-based perovskites together with their performance in the PSCs. Other alternative elements, such as copper (Cu), germanium (Ge), bismuth (Bi), and antimony (Sb), will be discussed in Section 3. The end will summarize the challenges and opportunities based on the chapter contents.
Part of the book: A Guide to Small-Scale Energy Harvesting Techniques