Neerish Revaprasadu

By Joseph Adeyemi Adekoya, Kehinde Olurotimi Ogunniran, Tolutope Oluwasegun Siyanbola, Enock Olugbenga Dare and Neerish Revaprasadu

Metallic nanoparticles are gradually emerging as important materials because of their novel shape and size-dependent chemical and physical properties that differ drastically from their bulk counterparts. The main challenges in the field of nano-chemistry are the rational control and manipulation of synthesis to derive materials with one of their dimensions in nanometer regime, and upscale production of nanomaterials for device fabrication. This chapter reviews the fundamentals of the quantum properties of metals and quantum mechanical size effects with special focus on clusters of Pd, Pt, Au and Ag. Effects of reduction in size of metal nanoparticles to nanoscale on their various properties (structural, thermal, mechanical, chemical, electronic, magnetic and optical) are reviewed. The chapter concludes with a review of select medical applications of metal nanoparticles.

Part of the book: Noble and Precious Metals

By Zikhona Tshemese, Siphamandla C. Masikane, Sixberth Mlowe and Neerish Revaprasadu

For over a decade, ionic liquids (ILs) have attracted enormous attention from scientists across the globe. The history of these compounds traces back to 1914 where the inception of the first IL with a melting point of 12°C was made. Years later, a progression of the remarkable related compounds have been discovered. Out of many analogous compounds realized from time to time, the imidazolium class of ionic liquid is the most studied because of their air and moisture stability. The physicochemical properties of ILs differ significantly depending on the anionic/cationic species and alkyl chain length. ILs have found application in many scientific fields the most recent being good solvents and stabilizing agents in the nanomaterial synthesis. Studies have showed that ILs not only stabilize as synthesized nanomaterials but also provide environmentally green routes towards nanomaterials engineering.

Part of the book: Recent Advances in Ionic Liquids

By Owonubi J. Shesan, Agwuncha C. Stephen, Anusionwu G. Chioma, Revaprasadu Neerish and Sadiku E. Rotimi

Fiber-matrix interaction at the interphase is one very important property that is of great concern to all polymer scientists involved in polymer composites. Many of the failures can be traced to the type of interfacial interaction existing in the composites. That is why highlighting the factors that dictate the type of and the extent of interactions at the interphases become very necessary. Natural fiber polymer composites have found application in many fields of human endeavors. To continue this growth being experienced, the factors that determine the formation of good interaction at the interphase most be understood, so that they can be manipulated for a better result.

Part of the book: Renewable and Sustainable Composites

By Owonubi J. Shesan, Agwuncha C. Stephen, Anusionwu G. Chioma, Revaprasadu Neerish and Sadiku E. Rotimi

Natural fiber composites are designed for different purposes including structural and non-structural ones. These natural fiber composites vary greatly in their properties including mechanical properties. Mechanical properties which include the tensile and flexural properties are highly dependent on factors such as matrix type, filler type, processing, post processing treatment and many more, factors which are quite application specific. However, many research works develop their natural fiber composite before considering the possible applications. This chapter intends to X-ray the factors that affect the mechanical properties as it relates to structural and biomedical applications and suggest ways of improving the mechanical properties.

Part of the book: Renewable and Sustainable Composites

By Siphamandla C. Masikane and Neerish Revaprasadu

In the last decade, there has been an increasing trend in the exploitation of indium chalcogenides in various applications which range from water splitting reactions in renewable energy to degradation of dyes in environmental rehabilitation. This trend is attributed to the interesting and unique properties of indium chalcogenide nanomaterials which can be easily tuned through a common approach: particle size, shape and morphology engineering. In this chapter, we outline the preferred attributes of indium chalcogenide nanomaterials which are deemed suitable for recent applications. Furthermore, we explore recent reaction protocols which have been reported to yield good quality indium chalcogenide nanomaterials of multinary configurations, e.g. binary and ternary compounds, among others.

Part of the book: Post-Transition Metals