Chapters authored
Pitting Corrosion Resistance and Inhibition of Lean Austenitic Stainless Steel Alloys
The pitting corrosion behavior of 301, 304 and 316 austenitic stainless steels in 2M H2SO4 at 0–1.5% NaCl concentrations was investigated through potentiodynamic polarization and optical microscopy analysis. Electrochemical analysis of the pitting corrosion inhibition and surface protection properties of rosemary oil and aniline on the stainless was also performed. The corrosion rate, pitting potential, passivation potential, metastable pitting potential and surface morphology of both steels where significantly altered by changes in chloride concentration, differences in alloy composition and metallurgical properties of the steels. 316 steel had the lowest corrosion rate and highest pitting corrosion resistance followed by 301 steel. The surface morphology of 316 steel was slightly altered at 1.5% NaCl concentration while 301 steel appears to etch with grain boundaries appearing at higher chloride concentration. 304 steel showed no resistance to pitting after 0% NaCl coupled with relatively significant increase in corrosion rate values. Its surface morphology showed the presence of corrosion pits with respect to chloride and inhibitor concentration. Rosemary oil and aniline significantly reduced the corrosion rates values of the stainless steels and with consequent increase in their pitting corrosion resistance; however the compounds had no positive influence on the pitting corrosion behavior of 304 steel.
Part of the book: Austenitic Stainless Steels
Use of Sustainable Materials in Self-Healing Concrete
Vulnerability to cracks is one of the major flaws of concrete infrastructure. The need to reduce the repair cost of this defect birthed the need for self-healing concrete. The incidence of cracks on concrete structures is a big threat to the stability of bridges, concrete roads, and other concrete infrastructures. This review assessed the use of self-healing technology on concrete using sustainable material as an active method of healing crack. This was done with the view of improving the stability, strength, and sustainability of infrastructure for national growth. The outcome of the review showed three prominent methods used in self-healing technology, which include autogenous healing, encapsulation of polymeric material, and microbial production of calcium-carbonate (biotechnological approaches). The review also revealed that calcium carbonate is a versatile material that can be used in crack healing for the filling of voids and improves the porosity of the concrete. The success of using the autogenous healing method depends on the diameter of the crack induced in the concrete structure. Additionally, this method can operate independently in different conditions regardless of the crack position. Correspondingly, lowering the water-cement ratio improves the autogenous healing process. The use of encapsulation of polymeric material and microbial production of calcium-carbonate methods showed that the presence of water and humidity is a critical factor to be considered. However, biotechnology using microbial action is prone to the production of ammonium ions (NH4+) through ureolytic activity, which results in nitrogen oxide emission into the atmosphere. Congruently, this may affect the durability of the concrete. Based on the uniqueness of this technology, it is recommended for the construction of sustainable infrastructure now and in the foreseeable future.
Part of the book: Strength of Materials